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At least 649 records · Page 36Linked to original sources
USGS1968

Environments of generation of some base-metal ore deposits

The origin of the ore fluids, their dissolved constituents, the force that drives them, and the causes for deposition of their constituents are reviewed for five districts: Providencia, Mexico; Mississippi Valley (Pb-Zn); Salton Sea geothermal system; Red Sea geothermal system; Nonesuch Shale, Michigan. The compositions (chemical and isotopic) and temperatures, determined directly for brines and from fluid inclusions for ancient deposits, reveal significant differences between the Providencia deposit (close magmatic affiliations) and the others, in which connate water and constituents dissolved from country rock appear to be important. Deposits formed by complex processes, with multiple sources for materials, may well be more common than simple 'end-member' deposits.

Economic Geology↗
USGS1968

Environment of ore deposition at the Mex-Tex deposits, Hansonburg District, New Mexico, from studies of fluid inclusions

These deposits , in Pennsylvanian limestone and shale, contain barite, fluorite, low-silver galena with "J-type" lead, and quartz, and only minor amounts of other minerals. Mineralization occurs in veins, in blankets of bedded, rhythmically banded "coontail" ore , and in vuggy, coarsely crystalline open-space fillings in tectonic and solution channels in limestone adjacent to faults. Except for widespread silicification, the mineralization is very similar to that of the southern Illinois deposits . The main stages of hypogene mineralization are: 1) sphalerite, pyrite, galena and chalcopyrite; 2) five easily recognizable substages of fluorite with intermittent quartz and barite; and 3) late calcite.More than 500 primary and 2,500 pseudosecondary inclusions , mainly from fluorite, were studied on the freezing and heating microscope stages. Some primary inclusions contain organic matter. Gross supercooling indicates slow ore - fluid movement. Recognizable planes of pseudo-secondaries (each containing 20-200 inclusions ) yield data essentially identical with coeval primaries, but the few planes of presumed secondaries do not.The first three substages of fluorite formed from fluids that were essentially constant in temperature at 186°-205° C (assumed pressure correction +10° C), but increased in salinity from aproximately 10 up to 15 weight percent salts. Succeeding substages formed at gradually decreasing temperatures (to about 140° C) and increasing salinity (maximum 17%), with breaks marking several individual substages. A few inclusions in an early barite have anomalously low homogenization temperatures. Coarse selenite has primary inclusions full of fresh water and hence is presumed to be supergene.These data do not prove any given theory or origin for the fluids or the deposits , but they do place some limits on possible mechanisms of origin.

New Mexico↗
USGS1971

Fluid-inclusion evidence on the environment of formation of mineral deposits of the southern Appalachian valley

Approximately 1,330 fluid inclusions were studied in samples of ore and gangue minerals from both massive ore and late-stage vugs from a series of Appalachian deposits and five active mines in the East Tennessee zinc districts. Most primary inclusions in sphalerite, fluorite, dolomite, and quartz from East Tennessee homogenized at 82 degrees -149 degrees C. Most primary inclusions in fluorite, barite, and sphalerite from the Central Kentucky, Central Tennessee, and Sweetwater barite districts, ranged from 72 degrees -132 degrees C. Pressure corrections to be added are probably less than 10 degrees C.Freezing data were obtained as a crude measure of the salinity of the inclusion fluids. With few exceptions, all primary inclusions contained very strongly saline brines (mostly >20 weight percent salts), with appreciable amounts of at least some salts other than NaCl, and some contained immiscible globules of oil. The exceptions include several quartz, fluorite, calcite, and barite samples that contained only moderately saline brines (12-16 percent), and some inclusions containing essentially fresh water, in vug calcite. Secondary inclusions had lower salinities than adjacent primaries. Eight primary inclusions in the differently colored outer millimeter of one Central Kentucky fluorite had low salinity (4-6 percent).The data indicate that all these deposits formed from hot, saline brines, with sphalerite forming from slightly hotter and more saline fluids than later gangue minerals. This places severe restrictions on possible modes of origin and makes deeply circulating connate brines the most probable ore fluids. The data give no information on the cause or direction of fluid circulation, which would be controlled by topography, salinity, and temperature during ore deposition, and they permit wide latitude in the construction of possible models. Other observations, on "colloform" textures, seem to indicate the admixture of at least small amounts of surface waters with the brines.

Kentucky, Tennessee, Virginia↗
USGS1979

Environment of ore deposition in the Creede mining district, San Juan Mountains, Colorado; Part IV, source of fluids, from oxygen, hydrogen, and carbon isotope studies

The hydrogen isotopic composition of fluids responsible for formation of the near-surface silver-base metal vein deposits at Creede was measured by direct analysis of inclusion fluids in sphalerite, quartz, and rhodochrosite and was estimated from analyses of illite and chlorite. The oxygen isotopic composition was determined directly on inclusion fluids in sphalerite and was estimated from analyses of quartz, illite, rhodochrosite, siderite, and adularia. The carbon isotopic composition was estimated from analyses of rhodochrosite and siderite. The ranges in isotopic composition for water and CO 2 in the fluids associated with the formation of each of the minerals is given below (number of determinations given in parentheses):Mineral delta D (sub H 2 ) O ppm delta 18 O (sub H 2 ) O ppm delta 13 C (sub CO 2 ) ppmSphalerite -81 to -54 (4) -10.1 to -4.5 (4)Quartz -97 to -86 (4) -5.9 to 1.8 (18)Illite -62 to -50 (8) -1.6 to 1.2(7)Chlorite -64 to -55 (10) -2.2 to 0.8 (10)Adularia 4.2 (1)Rhodochrosite -82 to -78 (2) 4.2 to 9.4 (9) -5.7 to -4.2 (9)Siderite 4.9 to 9.9 (6) -6.9 to -2.7 (6)The delta D (sub H 2 ) O and delta 18 O (sub H 2 ) O values of fluids associated with the formation of sphalerite, quartz, illite/chlorite, and carbonate minerals differ substantially from one another, and these differences appear to have been maintained throughout the depositional history, regardless of the positions of the minerals in the paragenetic sequence.The data suggest that waters from three coexisting reservoirs fed the vein system alternately and episodically during vein formation, and apparently there was little mixing of the fluids from the different reservoirs. The hydrogen, oxygen, and carbon isotope data suggest that the carbonate waters were deep seated, probably dominantly magmatic, in origin. The sphalerite and illite/chlorite waters must have been dominantly meteoric in origin and substantially oxygen shifted by exchange with the volcanic country rocks. The quartz waters were also oxygen shifted meteoric waters but were some 40 per mil lower in deuterium content than the sphalerite and illite/chlorite waters.We propose that the quartz fluids entered the vein system from reservoirs beneath the mountainous areas to the north in the vicinity of the present Continental Divide, but that the sphalerite and illite/chlorite fluids entered the vein system from a topographically low area to the south along the structural moat of the Creede caldera. The difference in delta D between the two meteoric waters may reflect differences in altitude of the recharge areas for the two reservoirs or may be clue to isotopic evolution of the closed-basin lake and interstitial waters in the moat surrounding the Creede caldera.

Colorado↗
USGS2013

Improved geomagnetic referencing in the Arctic environment

Geomagnetic referencing uses the Earth’s magnetic field to determine accurate wellbore positioning essential for success in today's complex drilling programs, either as an alternative or a complement to north-seeking gyroscopic referencing. However, fluctuations in the geomagnetic field, especially at high latitudes, make the application of geomagnetic referencing in those areas more challenging. Precise crustal mapping and the monitoring of real-time variations by nearby magnetic observatories is crucial to achieving the required geomagnetic referencing accuracy. The Deadhorse Magnetic Observatory (DED), located at Prudhoe Bay, Alaska, has already played a vital role in the success of several commercial ventures in the area, providing essential, accurate, real-time data to the oilfield drilling industry. Geomagnetic referencing is enhanced with real-time data from DED and other observatories, and has been successfully used for accurate wellbore positioning. The availability of real-time geomagnetic measurements leads to significant cost and time savings in wellbore surveying, improving accuracy and alleviating the need for more expensive surveying techniques. The correct implementation of geomagnetic referencing is particularly critical as we approach the increased activity associated with the upcoming maximum of the 11-year solar cycle. The DED observatory further provides an important service to scientific communities engaged in studies of ionospheric, magnetospheric and space weather phenomena.

Conference Paper↗
USGS2011

Episodic soil succession on basaltic lava fields in a cool, dry environment

Holocene- to late Pleistocene-aged lava flows at Craters of the Moon National Monument and Preserve provide an ideal setting to examine the early stages of soil formation under cool, dry conditions. Transects were used to characterize the amount and nature of soil cover on across basaltic lava flows ranging in age from 2.1 to 18.4 ka. Results indicate that on flows <13 ka, very shallow organic soils (Folists in Soil Taxonomy) are the dominant soil type, providing an areal coverage of up to &sim;25%. On flows &ge;13.9 ka, deeper mineral soils including Entisols, Aridisols, and Mollisols become dominant and the areal extent increases to &ge;95% on flows older than 18.4 ka. These data suggest there are two distinct pedogenic pathways associated with lava flows of the region. The first pathway is illustrated by the younger flows, where Folists dominate. In the absence of a major source of loess, relatively little mineral material accumulates and soils provide only minor coverage of the lava flows. Our results indicate that this pathway of soil development has not changed appreciably over the past &sim;10 ka. The second pedogenic pathway is illustrated by the flows older than 13.9 ka. These flows have been subject to deposition of large quantities of loess during and after the last regional glaciation, resulting in almost complete coverage. Subsequent pedogenesis has given rise to Aridisols and Mollisols with calcic and cambic horizons and mollic epipedons. This research highlights the importance of regional climate change on the evolution of Craters of the Moon soilscapes.

Idaho↗
USGS2005

Modeling tritium transport through a deep unsaturated zone in an arid environment

Understanding transport of tritium ( 3 H) in unsaturated zones is critical to evaluating options for waste isolation. Tritium typically is a large component of low-level radioactive waste (LLRW). Studies at the U.S. Geological Survey's Amargosa Desert Research Site (ADRS) in Nevada investigate 3 H transport from a closed LLRW facility. Two boreholes are 100 and 160 m from the nearest waste trench and extend to the water table at 110 m. Soil-water vapor samples from the deep boreholes show elevated levels of 3 H at all depths. The objectives of this study were to (i) test source thermal and gas-advection mechanisms driving 3 H transport and (ii) evaluate model sensitivity to these mechanisms and to selected physical and hydraulic properties including porosity, tortuosity, and anisotropy. A two-dimensional numerical model incorporated a non-isothermal, heterogeneous domain of the unsaturated zone and instantaneous isotopic equilibrium. The TOUGH2 code was used; however, it required modification to account for temperature dependence of both the Henry's law equilibrium constant and isotopic fractionation with respect to tritiated water. Increases in source temperature, pressure, and porosity enhanced 3 H migration, but failed to match measured 3 H distributions. All anisotropic simulations with a source pressure component resembled, in shape, the upper portion of the 3 H distribution of the nearest borehole. Isotopic equilibrium limited migration of 3 H, while effects of radioactive decay were negligible. A 500 Pa pressure increase above ambient pressure in conjunction with a high degree of anisotropy (1:100) was necessary for simulated 3 H transport to reach the nearest borehole.

Vadose Zone Journal↗
USGS2006

Characterization of unsaturated zone hydrogeologic units using matrix properties and depositional history in a complex volcanic environment

Characterization of the physical and unsaturated hydrologic properties of subsurface materials is necessary to calculate flow and transport for land use practices and to evaluate subsurface processes such as perched water or lateral diversion of water, which are influenced by features such as faults, fractures, and abrupt changes in lithology. Input for numerical flow models typically includes parameters that describe hydrologic properties and the initial and boundary conditions for all materials in the unsaturated zone, such as bulk density, porosity, and particle density, saturated hydraulic conductivity, moisture-retention characteristics, and field water content. We describe an approach for systematically evaluating the site features that contribute to water flow, using physical and hydraulic data collected at the laboratory scale, to provide a representative set of physical and hydraulic parameters for numerically calculating flow of water through the materials at a site. An example case study from analyses done for the heterogeneous, layered, volcanic rocks at Yucca Mountain is presented, but the general approach for parameterization could be applied at any site where depositional processes follow deterministic patterns. Hydrogeologic units at this site were defined using (i) a database developed from 5320 rock samples collected from the coring of 23 shallow (<100 m) and 10 deep (500–1000 m) boreholes, (ii) lithostratigraphic boundaries and corresponding relations to porosity, (iii) transition zones with pronounced changes in properties over short vertical distances, (iv) characterization of the influence of mineral alteration on hydrologic properties such as permeability and moisture-retention characteristics, and (v) a statistical analysis to evaluate where boundaries should be adjusted to minimize the variance within layers. Model parameters developed in this study, and the relation of flow properties to porosity, can be used to produce detailed and accurate representations of the core-scale hydrologic processes ongoing at Yucca Mountain.

Vadose Zone Journal↗
USGS2009

Transport of tritium contamination to the atmosphere in an arid environment

Soil–plant–atmosphere interactions strongly influence water movement in desert unsaturated zones, but little is known about how such interactions affect atmospheric release of subsurface water-borne contaminants. This 2-yr study, performed at the U.S. Geological Survey's Amargosa Desert Research Site in southern Nevada, quantified the magnitude and spatiotemporal variability of tritium (3H) transport from the shallow unsaturated zone to the atmosphere adjacent to a low-level radioactive waste (LLRW) facility. Tritium fluxes were calculated as the product of 3H concentrations in water vapor and respective evaporation and transpiration water-vapor fluxes. Quarterly measured 3H concentrations in soil water vapor and in leaf water of the dominant creosote-bush [ Larrea tridentat a (DC.) Coville] were spatially extrapolated and temporally interpolated to develop daily maps of contamination across the 0.76-km2 study area. Maximum plant and root-zone soil concentrations (4200 and 8700 Bq L−1, respectively) were measured 25 m from the LLRW facility boundary. Continuous evaporation was estimated using a Priestley–Taylor model and transpiration was computed as the difference between measured eddy-covariance evapotranspiration and estimated evaporation. The mean evaporation/transpiration ratio was 3:1. Tritium released from the study area ranged from 0.12 to 12 μg d−1 and totaled 1.5 mg (8.2 × 1010 Bq) over 2 yr. Tritium flux variability was driven spatially by proximity to 3H source areas and temporally by changes in 3H concentrations and in the partitioning between evaporation and transpiration. Evapotranspiration removed and limited penetration of precipitation beneath native vegetation and fostered upward movement and release of 3H from below the root zone.

Vadose Zone Journal↗
USGS2013

Tritium plume dynamics in the shallow unsaturated zone in an arid environment

The spatiotemporal variability of a tritium plume in the shallow unsaturated zone and the mechanisms controlling its transport were evaluated during a 10-yr study. Plume movement was minimal and its mass declined by 68%. Upward-directed diffusive-vapor tritium fluxes and radioactive decay accounted for most of the observed plume-mass declines. Effective isolation of tritium ( 3 H) and other contaminants at waste-burial facilities requires improved understanding of transport processes and pathways. Previous studies documented an anomalously widespread (i.e., theoretically unexpected) distribution of 3 H (>400 m from burial trenches) in a dry, sub-root-zone gravelly layer (1–2-m depth) adjacent to a low-level radioactive waste (LLRW) burial facility in the Amargosa Desert, Nevada, that closed in 1992. The objectives of this study were to: (i) characterize long-term, spatiotemporal variability of 3 H plumes; and (ii) quantify the processes controlling 3 H behavior in the sub-root-zone gravelly layer beneath native vegetation adjacent to the facility. Geostatistical methods, spatial moment analyses, and mass flux calculations were applied to a spatiotemporally comprehensive, 10-yr data set (2001–2011). Results showed minimal bulk-plume advancement during the study period and limited Fickian spreading of mass. Observed spreading rates were generally consistent with theoretical vapor-phase dispersion. The plume mass diminished more rapidly than would be expected from radioactive decay alone, indicating net efflux from the plume. Estimates of upward 3 H efflux via diffusive-vapor movement were >10× greater than by dispersive-vapor or total-liquid movement. Total vertical fluxes were >20× greater than lateral diffusive-vapor fluxes, highlighting the importance of upward migration toward the land surface. Mass-balance calculations showed that radioactive decay and upward diffusive-vapor fluxes contributed the majority of plume loss. Results indicate that plume losses substantially exceeded any continuing 3 H contribution to the plume from the LLRW facility during 2001 to 2011 and suggest that the widespread 3 H distribution resulted from transport before 2001.

Nevada↗
USGS2018

Long-term soil-water tension measurements in semi-arid environments: A method for automated tensiometer refilling

Tensiometer-equipped data acquisition systems measure and record positive and negative soil-water pressures. These data contribute to studies in hillslope hydrology, including analyses of rainfall runoff, near-surface hydrologic response, and slope stability. However, the unique ability of a tensiometer to rapidly and accurately measure pre- and post-saturation subsurface pressures requires maintenance techniques that have precluded their application to unattended sensor networks in semiarid regions. Under suction, the de-aired water in the tensiometer is drawn from a porous cup. Under positive pressure, dissolved gases from pore water infiltrates the cup. Over time, both contribute to unreliable readings and/or poor signal response through cavitation. To address this problem, we used commercially available equipment to develop a simple system of solenoid valves and a water reservoir that enable automated in situ tensiometer refilling. We tested the system at two post-wildfire hydrologic monitoring sites in the Angeles National Forest, southern California. We present example results from 3 mo of monitoring and show how the tensiometers can be refilled by a remote trigger. By remotely refilling the tensiometer, we were able to continuously monitor quasi-saturated soil pore-water pressures without making repeated and costly maintenance visits.

Vadose Zone Journal↗
USGS2014

Arsenic speciation and sorption in natural environments

Aqueous arsenic speciation, or the chemical forms in which arsenic exists in water, is a challenging, interesting, and complicated aspect of environmental arsenic geochemistry. Arsenic has the ability to form a wide range of chemical bonds with carbon, oxygen, hydrogen, and sulfur, resulting in a large variety of compounds that exhibit a host of chemical and biochemical properties. Besides the intriguing chemical diversity, arsenic also has the rare capacity to capture our imaginations in a way that few elements can duplicate: it invokes images of foul play that range from sinister to comedic (e.g., “inheritance powder” and arsenic-spiked elderberry wine). However, the emergence of serious large-scale human health problems from chronic arsenic exposure in drinking water has placed a high priority on understanding environmental arsenic mobility, toxicity, and bioavailability, and chemical speciation is key to these important questions. Ultimately, the purpose of arsenic speciation research is to predict future occurrences, mitigate contamination, and provide successful management of water resources.

Reviews in Mineralogy and Geochemistry↗
USGS2004

Movement behavior, dispersal, and the potential for localized management of deer in a suburban environment

We examined the potential for localized management of white-tailed deer ( Odocoileus virginianus ) to be successful by measuring movements, testing site fidelity, and modeling the effects of dispersal. Fifty-nine females were radiomarked and tracked during 1997 through 2000 in Irondequoit, New York, USA, a suburb of Rochester. We constructed home ranges for those deer with A greater than or equal to 18 reclocations/season. Fifty percent minimum convex polygons (MCP) averaged 3.9 (SE = 0.53) ha in the summer and 5.3 (SE = 0.80) ha in the winter. Deer showed strong fidelity to both summer and winter home ranges, and 30 of 31 females showed overlap of summer and winter home ranges. Annual survival was 64%; the major cause of mortality was deer-automobile collisions. Average annual dispersal rates were <15% for yearlings and adults. Using matrix population modeling, we explored the role of female dispersal in sustaining different management objectives in adjacent locales of approximately 1,000 ha. Modeling showed that if female dispersal was 8%, culling would have to reduce annual survival to 58% to maintain a population just under ecological carrying capacity and reduce survival to 42% to keel) the population at one-half carrying capacity. With the same dispersal, contraception Would need to be effective in 32% of females if the population is near carrying capacity and 68% if the population is at one-half of carrying capacity. Movement behavior data and modeling results lend support to the use of a localized approach to management of females that emphasizes neighborhood-scale manipulation of deer populations, but our research suggests that dispersal rates in females could be critical to long-term success.

New York↗
USGS1997

Effects of spring environment on nesting phenology and clutch size of Black Brant

We studied the effects of timing of spring snowmelt on nesting phenology, nest site selection, and clutch size of Black Brant (Branta bernicla nigricans) breeding at the Tutakoke river colony, Yukon-Kuskokwim Delta, Alaska. In late springs, brant nested later: however, time between peak arrival at Tutakoke and nest initiation (6 to 12 days) was similar in early and late springs. Nest initiation was more synchronized in late springs than early springs. Height of nests relative to spring meltwater levels was lower in late springs than early springs, indicating that the interval between snowmelt and nest initiation was shorten reduced availability of nest sites and increased nesting synchrony in late years may result in greater competition for available nest sites and reduced site fidelity. Clutch size was greater in late springs than in early springs. This increase in clutch size may result from greater accumulation of endogenous reserves on spring staging areas in late springs, or from demographic changes in the breeding population.

Condor↗