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At least 649 records · Page 36Linked to original sources

Atmospheric correction at AERONET locations: A new science and validation data set

This paper describes an Aerosol Robotic Network (AERONET)-based Surface Reflectance Validation Network (ASRVN) and its data set of spectral surface bidirectional reflectance and albedo based on Moderate Resolution Imaging Spectroradiometer (MODIS) TERRA and AQUA data. The ASRVN is an operational data collection and processing system. It receives 50 ?? 50 km 2 ; subsets of MODIS level 1B (L1B) data from MODIS adaptive processing system and AERONET aerosol and water-vapor information. Then, it performs an atmospheric correction (AC) for about 100 AERONET sites based on accurate radiative-transfer theory with complex quality control of the input data. The ASRVN processing software consists of an L1B data gridding algorithm, a new cloud-mask (CM) algorithm based on a time-series analysis, and an AC algorithm using ancillary AERONET aerosol and water-vapor data. The AC is achieved by fitting the MODIS top-of-atmosphere measurements, accumulated for a 16-day interval, with theoretical reflectance parameterized in terms of the coefficients of the Li SparseRoss Thick (LSRT) model of the bidirectional reflectance factor (BRF). The ASRVN takes several steps to ensure high quality of results: 1) the filtering of opaque clouds by a CM algorithm; 2) the development of an aerosol filter to filter residual semitransparent and subpixel clouds, as well as cases with high inhomogeneity of aerosols in the processing area; 3) imposing the requirement of the consistency of the new solution with previously retrieved BRF and albedo; 4) rapid adjustment of the 16-day retrieval to the surface changes using the last day of measurements; and 5) development of a seasonal backup spectral BRF database to increase data coverage. The ASRVN provides a gapless or near-gapless coverage for the processing area. The gaps, caused by clouds, are filled most naturally with the latest solution for a given pixel. The ASRVN products include three parameters of the LSRT model (kL, kG, and kV), surface albedo, normalized BRF (computed for a standard viewing geometry, VZA = 0, SZA = 45??), and instantaneous BRF (or one-angle BRF value derived from the last day of MODIS measurement for specific viewing geometry) for the MODIS 500-m bands 17. The results are produced daily at a resolution of 1 km in gridded format. We also provide a cloud mask, a quality flag, and a browse bitmap image. The ASRVN data set, including 6 years of MODIS TERRA and 1.5 years of MODIS AQUA data, is available now as a standard MODIS product (MODASRVN) which can be accessed through the Level 1 and Atmosphere Archive and Distribution System website ( http://ladsweb.nascom.nasa.gov/data/search.html). It can be used for a wide range of applications including validation analysis and science research. ?? 2006 IEEE.

IEEE Transactions on Geoscience and Remote Sensing↗

Density of river otters (Lontra canadensis) in relation to energy development in the Green River Basin, Wyoming

Exploration and extraction of oil and natural gas have increased in recent years and are expected to expand in the future. Reduction in water quality from energy extraction may negatively affect water supply for agriculture and urban use within catchments as well as down river. We used non-invasive genetic techniques and capture–recapture modeling to estimate the abundance and density of North American river otters ( Lontra canadensis ), a sentinel species of aquatic ecosystems, in Southwestern Wyoming. While densities in two of three river reaches were similar to those reported in other freshwater systems in the western US (1.45–2.39 km per otter), otters appeared to avoid areas near energy development. We found no strong difference in habitat variables, such as overstory cover, at the site or reach level. Also, fish abundance was similar among the three river reaches. Otter activity in our study area could have been affected by elevated levels of disturbance surrounding the industrial gas fields, and by potential surface water contamination as indicated by patterns in water conductivity. Continued monitoring of surface water quality in Southwestern Wyoming with the aid of continuously recording devices and sentinel species is warranted.

Wyoming↗

Transcriptome signatures of wastewater effluent exposure in larval zebrafish vary with seasonal mixture composition in an effluent-dominated stream

Wastewater treatment plant (WWTP) effluent-dominated streams provide critical habitat for aquatic and terrestrial organisms but also continually expose them to complex mixtures of pharmaceuticals that can potentially impair growth, behavior, and reproduction. Currently, few biomarkers are available that relate to pharmaceutical-specific mechanisms of action. In the experiment reported in this paper, zebrafish ( Danio rerio ) embryos at two developmental stages were exposed to water samples from three sampling sites (0.1 km upstream of the outfall, at the effluent outfall, and 0.1 km below the outfall) during base-flow conditions from two months (January and May) of a temperate-region effluent-dominated stream containing a complex mixture of pharmaceuticals and other contaminants of emerging concern. RNA-sequencing identified potential biological impacts and biomarkers of WWTP effluent exposure that extend past traditional markers of endocrine disruption. Transcriptomics revealed changes to a wide range of biological functions and pathways including cardiac, neurological, visual, metabolic, and signaling pathways. These transcriptomic changes varied by developmental stage and displayed sensitivity to variable chemical composition and concentration of effluent, thus indicating a need for stage-specific biomarkers. Some transcripts are known to be associated with genes related to pharmaceuticals that were present in the collected samples. Although traditional biomarkers of endocrine disruption were not enriched in either month, a high estrogenicity signal was detected upstream in May and implicates the presence of unidentified chemical inputs not captured by the targeted chemical analysis. This work reveals associations between bioeffects of exposure, stage of development, and the composition of chemical mixtures in effluent-dominated surface water. The work underscores the importance of measuring effects beyond the endocrine system when assessing the impact of bioactive chemicals in WWTP effluent and identifies a need for non-targeted chemical analysis when bioeffects are not explained by the targeted analysis.

Iowa↗

Development and evaluation of geochemical methods for the sourcing of archaeological maize

Strontium (Sr)-isotope values on bone from deer mice pairs from 12 field sites in the Chaco Canyon area, New Mexico, were compared with isotope values of synthetic soil waters from the same fields. The data indicate that mice obtain Sr from near-surface sources and that soil samples collected at depths ranging from 25 to 95 cm contain Sr that is more accessible to the deep roots of maize; thus, synthetic soil solutions provide better data for the sourcing of archaeological maize. However, the Sr-isotope composition of mice may be more valuable in sourcing archaeological remains of animals such as rabbit, turkey, and deer. In a separate study, five Native American maize (Zea mays L. ssp. mays) accessions grown out at New Mexico State University Agricultural Science Center, Farmington, New Mexico were used to determine if soil-water metal pairs partition systematically into cobs and kernels. The sampled maize included landraces from three Native American groups (Acoma, Hopi, Zuni) that still occupy the Four Corners area. Two cobs each were picked from 10 plants of each landrace. Partitioning of the Ba/Mn, Ba/Sr, Ca/Sr, and K/Rb metal pairs from the soil water to the cob appears to behave in a systematic fashion. In addition, 51 rare earth element (REE) pairs also appear to systematically partition from the soil water into cobs; however, the ratios of the REE dissolved in the soil waters are relatively invariant; therefore, the distribution coefficients that describe the partitioning of REE from the soil water to the cob may not apply to archeological cobs grown under chemically heterogeneous conditions. Partitioning of Ba/Rb, Ba/Sr, Mg/P, and Mn/P metal pairs from the soil water to kernels also behaves in a systematic fashion. Given that modern Native American landraces were grown under optimal environmental conditions that may not have been duplicated by prehistoric Native Americans, the distribution coefficients obtained in this study should be used with caution. ?? 2007 Elsevier Ltd. All rights reserved.

Journal of Archaeological Science↗

Can machine learning accelerate process understanding and decision-relevant predictions of river water quality?

The global decline of water quality in rivers and streams has resulted in a pressing need to design new watershed management strategies. Water quality can be affected by multiple stressors including population growth, land use change, global warming, and extreme events, with repercussions on human and ecosystem health. A scientific understanding of factors affecting riverine water quality and predictions at local to regional scales, and at sub-daily to decadal timescales are needed for optimal management of watersheds and river basins. Here, we discuss how machine learning (ML) can enable development of more accurate, computationally tractable, and scalable models for analysis and predictions of river water quality. We review relevant state-of-the art applications of ML for water quality models and discuss opportunities to improve the use of ML for emerging computational and mathematical methods for model selection, hyperparameter optimization, incorporating process knowledge into ML models, improving explainablity, uncertainty quantification, and model-data integration. We then present considerations for using ML to address water quality problems given their scale and complexity, available data and computational resources, and stakeholder needs. When combined with decades of process understanding, interdisciplinary advances in knowledge-guided ML, information theory, data integration, and analytics can help address fundamental science questions and enable decision-relevant predictions of riverine water quality.

Hydrological Processes↗

Methods for quantifying interactions between groundwater and surface water

Driven by the need for integrated management of groundwater (GW) and surface water (SW), quantification of GW–SW interactions and associated contaminant transport has become increasingly important. This is due to their substantial impact on water quantity and quality. In this review, we provide an overview of the methods developed over the past several decades to investigate GW–SW interactions. These methods include geophysical, hydrometric, and tracer techniques, as well as various modeling approaches. Different methods reveal valuable information on GW–SW interactions at different scales with their respective advantages and limitations. Interpreting data from these techniques can be challenging due to factors like scale effects, heterogeneous hydrogeological conditions, sediment variability, and complex spatiotemporal connections between GW and SW. To facilitate the selection of appropriate methods for specific sites, we discuss the strengths, weaknesses, and challenges of each technique, and we offer perspectives on knowledge gaps in the current science.

Annual Review of Environment and Resources↗

Interdisciplinary science approach for harmful algal blooms (HABs) and algal toxins—A strategic science vision for the U.S. Geological Survey

Executive Summary Algal blooms in water, soils, dusts, and the environment have captured national attention because of concerns associated with exposure to algal toxins for humans and animals. Algal blooms naturally occur in all surface-water types and are important primary producers for aquatic ecosystems. However, excessive algae growth can be associated with many harmful effects ranging from aesthetic to toxicity concerns, so this excessive growth is commonly called a harmful algal bloom (HAB). Ecological imbalances that can lead to excessive algal growth, such as increased nutrient availability to waterbodies from natural and anthropogenic sources, are well documented in scientific literature. On the other hand, fundamental scientific understandings of environmental causes and controls leading to algal toxin production, environmental exposures, and adverse health outcomes for humans and animals could benefit from more attention by U.S. Geological Survey (USGS) scientists. Understanding when, why, and how the toxin is produced by individual algal cells or communities and why the toxin is released to the surrounding waterbody requires fundamental research to determine a toxin’s role, whether it provides competitive advantage or if other potential reasons exist for toxin production and release, such as secretions from otherwise benign biological processes. This research will require groundbreaking scientific discovery about underlying biologic and abiotic (non-living) processes commonly complicated by local variation in land use, microbial species composition, and ecosystem structure of the surrounding watershed. Although underlying processes by which HABs form may be similar from one waterbody to another, individual waterbodies may be controlled by local factors for HAB development and toxin production that are unique to the watershed. Consequently, many fundamental science gaps exist that prevent informed mitigation and prevention of toxic HAB events. There are also gaps in understanding local conditions that control algal growth unique to specific watersheds. Addressing these science gaps is needed to inform evidence-based decisions that protect human and animal health and that reduce recreational and socioeconomic losses.

Circular↗

New Method for Electrical Conductivity Temperature Compensation

Electrical conductivity (κ) measurements of natural waters are typically referenced to 25 °C (κ 25 ) using standard temperature compensation factors (α). For acidic waters (pH < 4), this can result in a large κ 25 error (δκ 25 ). The more the sample temperature departs from 25 °C, the larger the potential δκ 25 . For pH < 4, the hydrogen ion transport number becomes substantial and its mode of transport is different from most other ions resulting in a different α. A new method for determining α as a function of pH and temperature is presented. Samples with varying amounts of H 2 SO 4 and NaCl were used to develop the new α, which was then applied to 65 natural water samples including acid mine waters, geothermal waters, seawater, and stream waters. For each sample, the κ and pH were measured at several temperatures from 5 to 90 °C and κ 25 was calculated. The δκ 25 ranged from −11 to 9% for the new method as compared to −42 to 25% and −53 to 27% for the constant α (0.019) and ISO-7888 methods, respectively. The new method for determining α is a substantial improvement for acidic waters and performs as well as or better than the standard methods for circumneutral waters.

Environmental Science & Technology↗

The Bathy-drone: An autonomous unmanned drone-tethered sonar system

A unique drone-based system for underwater mapping (bathymetry) was developed at the University of Florida. The system, called the “Bathy-drone”, comprises a drone that drags, via a tether, a small vessel on the water surface in a raster pattern. The vessel is equipped with a recreational commercial off-the-shelf (COTS) sonar unit that has down-scan, side-scan, and chirp capabilities and logs GPS-referenced sonar data onboard or transmitted in real time with a telemetry link. Data can then be retrieved post mission and plotted in various ways. The system provides both isobaths and contours of bottom hardness. Extensive testing of the system was conducted on a 5 acre pond located at the University of Florida Plant Science and Education Unit in Citra, FL. Prior to performing scans of the pond, ground-truth data were acquired with an RTK GNSS unit on a pole to precisely measure the location of the bottom at over 300 locations. An assessment of the accuracy and resolution of the system was performed by comparison to the ground-truth data. The pond ground truth had an average depth of 2.30 m while the Bathy-drone measured an average 21.6 cm deeper than the ground truth, repeatable to within 2.6 cm. The results justify integration of RTK and IMU corrections. During testing, it was found that there are numerous advantages of the Bathy-drone system compared to conventional methods including ease of implementation and the ability to initiate surveys from the land by flying the system to the water or placing the platform in the water. The system is also inexpensive, lightweight, and low-volume, thus making transport convenient. The Bathy-drone can collect data at speeds of 0–24 km/h (0–15 mph) and, thus, can be used in waters with swift currents. Additionally, there are no propellers or control surfaces underwater; hence, the vessel does not tend to snag on floating vegetation and can be dragged over sandbars. An area of more than 10 acres was surveyed using the Bathy-drone in one battery charge and in less than 25 min.

Drones↗

Challenge theme 7: Information support for management of border security and environmental protection: Chapter 9 in United States-Mexican Borderlands: Facing tomorrow's challenges through USGS science

Historically, international borders were located far from the major political and economic capitals of their countries and rarely received adequate planning or infrastructure development. Today, as a result of global economics and increased movement of goods between nations, border regions play a much greater role in commerce, tourism, and transportation. For example, Mexico is the second largest destination for United States exports (Woodrow Wilson Center Mexico Institute, 2009). The rapid population and economic growth along the United States–Mexican border, undocumented human border crossings, and the unique natural diversity of resources in the Borderlands present challenges for border security and environmental protection. Assessing risks and implementing sustainable growth policies to protect the environment and quality of life greatly increase in complexity when the issues cross an international border, where social services, environmental regulations, lifestyles, and cultural beliefs are unique for each country. Shared airsheds, water and biological resources, national security issues, and disaster management needs require an integrated binational approach to assess risks and develop binational management strategies.

United States-Mexico Borderlands↗

Topographic controls on the chemistry of subsurface stormflow

Models are needed that describe how topography and other watershed characteristics affect the chemical composition of runoff waters, yet little spatially distributed data exist to develop such models. A topographically driven flushing mechanism for nitrate (NO3-) and dissolved organic carbon has been described in recent literature; however, this mechanism has not yet been thoroughly tested. A 24 ha catchment in the Catskill Mountains of New York was clearcut in the winter of 1996-97, resulting in elevated NO3- concentrations in soil water, groundwater and streamflow. We sampled shallow subsurface stormflow (SSSF) and streamflow six times during the spring and summer of 1998, 1 year after the harvest. We used a spatially distributed network of piezometers to investigate the relationship between topography and SSSF chemistry. Several indices of topography were computed, including the commonly employed topographic index of Beven and Kirkby (1979; Hydrological Sciences Bulletin 24: 43-69). Topographic index was positively correlated with NO3- concentrations in SSSF. The strength of the NO3- -topography relationship was best explained by antecedent soil temperature and antecedent precipitation conditions. Results suggest a topographically driven flushing of high NO3- shallow soil at the site during storm events. Copyright ?? 2001 John Wiley & Sons, Ltd.

Hydrological Processes↗

Workshops report for mesophotic and deep benthic community fish, mobile invertebrates, sessile invertebrates and infauna

Two workshops with subject matter experts in the appropriate fields, were held in November and December 2021 to elicit guidance and feedback from the broader mesophotic and deep benthic scientific community. These workshops focused on best practices/approaches and identifying data gaps relative to habitat assessment and evaluation goals of the Mesophotic and Deep Benthic Community (MDBC) restoration portfolio. The first workshop was a combined effort of the Habitat Assessment and Evaluation (HAE) Project Team and the Deepwater Horizon (DWH) Program. Industrial Economics, Inc. (IEc) provided extensive workshop planning, organizing, execution, and facilitation support during all stages of the workshop. Based on a questionnaire sent to scientists in August, 2021, the workshop focused on fish and mobile invertebrate habitat associations, abundance trends, community metrics, and food web functionality. Topical presentations and discussions focused not only on demersal fish and mobile invertebrates that are directly associated with mesophotic and deep benthic habitats, but also considered water column species and communities that benefit from these habitats more broadly. The second workshop, intended to complement the first workshop, focused on identifying best practices and critical information gaps for key community metrics, larval dispersal modeling, connectivity, effects and variability of environmental parameters, and recovery trajectories of corals, infauna, and other sessile invertebrates. Through literature review, internal HAE scientists considered these topics to be critical for restoration success. Products from the literature review included topical summaries (see Appendix B) that summarized the current state-of-the-science and provided the framework for the workshop. Information generated from the workshops will assist the MDBC HAE Project, and more broadly the DWH Program, identify data gaps and develop a suite of best practices for restoration activities.

DWH MDBC Summary Report↗

Council monitoring and assessment program (CMAP) compilation of existing habitat and water quality monitoring and mapping assessments for the Gulf of Mexico Region

This report is a deliverable to the RESTORE Council for Task 7: Document the existing baseline habitat and water quality conditions prior to implementation of the restoration projects; these baseline conditions will serve as a basis for measuring change/progress after restoration. It is the second in a series of CMAP reports. The first report describes the process and development of the CMAP monitoring program inventory, herein the Inventory (NOAA and USGS, 2019). The goals and objectives for the Inventory were to identify and document existing habitat and water quality monitoring, and mapping programs, data, and protocols in the GoM. The Inventory built upon existing databases, such as the Ocean Conservancy (Love, 2015), Global Change Monitoring Portal (GCMP; GCMP, 2017), and Gulf of Mexico Alliance (GOMA) databases (GOMA, 2013), including habitat and water quality monitoring programs at national, regional, State and local scales. This second report identifies and catalogs existing water quality, habitat and mapping assessments within the Gulf of Mexico. This assessment catalog, herein the Catalog, was intended to supplement the Inventory to identify the best available science necessary for restoration, conservation or management activities. Both the Inventory and the Catalog databases will be accessible to the Council and the greater GoM restoration, monitoring, management, and academic communities through a searchable web-based tool.

Alabama, Florida, Georgia, Louisiana, Mississippi,↗

The United States National Climate Assessment - Alaska Technical Regional Report

The Alaskan landscape is changing, both in terms of effects of human activities as a consequence of increased population, social and economic development and their effects on the local and broad landscape; and those effects that accompany naturally occurring hazards such as volcanic eruptions, earthquakes, and tsunamis. Some of the most prevalent changes, however, are those resulting from a changing climate, with both near term and potential upcoming effects expected to continue into the future. Alaska's average annual statewide temperatures have increased by nearly 4&deg;F from 1949 to 2005, with significant spatial variability due to the large latitudinal and longitudinal expanse of the State. Increases in mean annual temperature have been greatest in the interior region, and smallest in the State's southwest coastal regions. In general, however, trends point toward increases in both minimum temperatures, and in fewer extreme cold days. Trends in precipitation are somewhat similar to those in temperature, but with more variability. On the whole, Alaska saw a 10-percent increase in precipitation from 1949 to 2005, with the greatest increases recorded in winter. The National Climate Assessment has designated two well-established scenarios developed by the Intergovernmental Panel on Climate Change (Nakicenovic and others, 2001) as a minimum set that technical and author teams considered as context in preparing portions of this assessment. These two scenarios are referred to as the Special Report on Emissions Scenarios A2 and B1 scenarios, which assume either a continuation of recent trends in fossil fuel use (A2) or a vigorous global effort to reduce fossil fuel use (B1). Temperature increases from 4 to 22&deg;F are predicted (to 2070-2099) depending on which emissions scenario (A2 or B1) is used with the least warming in southeast Alaska and the greatest in the northwest. Concomitant with temperature changes, by the end of the 21st century the growing season is expected to lengthen by 15-25 days in some areas of Alaska, with much of that corresponding with earlier spring snow melt. Future projections of precipitation (30-80 years) over Alaska show an increase across the State, with the largest changes in the northwest and smallest in the southeast. Because of increasing temperatures and growing season length, however, increased precipitation may not correspond with increased water availability, due to temperature related increased evapotranspiration. The extent of snow cover in the Northern Hemisphere has decreased by about 10 percent since the late 1960s, with stronger trends noted since the late 1980s. Alaska has experienced similar trends, with a strong decrease in snow cover extent occurring in May. When averaged across the State, the disappearance of snow in the spring has occurred from 4 to 6 days earlier per decade, and snow return in fall has occurred approximately 2 days later per decade. This change appears to be driven by climate warming rather than a decrease in winter precipitation, with average winter temperatures also increasing by about 2.5&deg;F. The extent of sea ice has been declining, as has been widely published in both national and scientific media outlets, and is projected to continue to decline during this century. The observed decline in annual sea ice minimum extent (September) has occurred more rapidly than was predicted by climate models and has been accompanied by decreases in ice thickness and in the presence of multi-year ice. This decrease was first documented by satellite imagery in the late 1970s for the Bering and Chukchi Seas, and is projected to continue, with the potential for the disappearance of summer sea ice by mid- to late century. A new phenomenon that was not reported in previous assessments is ocean acidification. Uptake of carbon dioxide (CO2) by oceans has a significant effect on marine biogeochemistry by reducing seawater pH. Ocean acidification is of particular concern in Alaska, because cold sea water absorbs CO2 more rapidly than warm water, and a decrease in sea ice extent has allowed increased sea surface exposure and more uptake of CO2 into these northern waters. Ocean acidification will likely affect the ability of organisms to produce and maintain shell material, such as aragonite or calcite (calcium carbonate minerals structured from carbonate ions), required by many shelled organism, from mollusks to corals to microscopic organisms at the base of the food chain. Direct biological effects in Alaska further along the food chain have yet to be studied and may vary among organisms. Some of the potentially most significant changes to Alaska that could result from a changing climate are the effects on the terrestrial cryosphere - particularly glaciers and permafrost. Alaskan glaciers are changing at a rapid rate, the primary driver appearing to be temperature. Statewide, glaciers lost 13 cubic miles of ice annually from the 1950s to the 1990s, and that rate doubled in the 2000s. However, like temperature and precipitation, glacier ice loss is not spatially uniform; most glaciers are losing mass, yet some are growing (for example Hubbard Glacier in southeast Alaska). Alaska glaciers with the most rapid loss are those terminating in sea water or lakes. With this increasing rate of melt, the contribution of surplus fresh water entering into the oceans from Alaska's glaciers, as well as those in neighboring British Columbia, Canada, is approximately 20 percent of that contributed by the Greenland Ice Sheet. Permafrost degradation (that is, the thawing of ice-rich soils) is currently (2012) impacting infrastructure and surface-water availability in areas of both discontinuous and continuous ground ice. Over most of the State, the permafrost is warming, with increasing temperatures broadly consistent with increasing air temperatures. On the Arctic coastal plain of Alaska, permafrost temperatures showed some cooling in the 1950s and 1960s but have been followed by a roughly 5&deg;F increase since the 1980s. Many areas in the continuous permafrost zone have seen increases in temperature in the seasonally active layer and a decrease in re-freezing rates. Changes in the discontinuous permafrost zone are initially much more observable due to the resulting thermokarst terrain (land surface formed as ice rich permafrost thaws), most notable in boreal forested areas. Climate warming in Alaska has potentially broad implications for human health and food security, especially in rural areas, as well as increased risk for injury with changing winter ice conditions. Additionally, such warming poses the potential for increasing damage to existing water and sanitation facilities and challenges for development of new facilities, especially in areas underlain by permafrost. Non-infectious and infectious diseases also are becoming an increasing concern. For example, from 1999 to 2006 there was a statistically significant increase in medical claims for insectbite reactions in five of six regions of Alaska, with the largest percentage increase occurring in the most northern areas. The availability and quality of subsistence foods, normally considered to be very healthy, may change due to changing access, changing habitats, and spoilage of meat in food storage cellars. These and other trends and potential outcomes resulting from a changing climate are further described in this report. In addition, we describe new science leadership activities that have been initiated to address and provide guidance toward conducting research aimed at making available information for policy makers and land management agencies to better understand, address, and plan for changes to the local and regional environment. This report cites data in both metric and standard units due to the contributions by numerous authors and the direct reference of their data.

Alaska↗

EAARL Topography-Padre Island National Seashore

This Web site contains 116 Lidar-derived bare earth topography maps and GIS files for Padre Island National Seashore-Texas. These Lidar-derived topography maps were produced as a collaborative effort between the U.S. Geological Survey (USGS) Florida Integrated Science Center (FISC) St. Petersburg, Florida, the National Park Service (NPS) Gulf Coast Network, Inventory and Monitoring Program, and the National Aeronautics and Space Administration (NASA) Wallops Flight Facility. One objective of this research is to create techniques to survey coral reefs and barrier islands for the purposes of geomorphic change studies, habitat mapping, ecological monitoring, change detection, and event assessment. As part of this project, data from an innovative instrument under development at the NASA Wallops Flight Facility, the NASA Experimental Airborne Advanced Research Lidar (EAARL) are being used. This sensor has the potential to make significant contributions in this realm for measuring subaerial and submarine topography wthin cross-environment surveys. High spectral resolution, water-column correction, and low costs were found to be key factors in providing accurate and affordable imagery to costal resource managers.

Texas↗

The hydrothermolysis of the picrate anion: Kinetics and mechanism

The hydrothermolysis of the picrate anion in aqueous solution has been studied at 260-325??C in liquid water. At starting pH values above 12, the disappearance of picrate begins immediately and is first order in OH-. At lower pH, there is an induction period preceding the disappearance, and over the pH range 6.7-11.9 there is no pH dependence in the developed reaction phase. Added borate and silicate salts promote the reaction, suggesting their acting as nucleophiles at hydrothermal conditions. Nitrite is an initial product, while acetate is a final product and reflective of a vigorous oxidative sequence consuming the intermediate products. A reaction sequence consistent with the results at the lower pH includes initiation of a chain process by displacement of nitrite by water, followed by nucleophilic displacement of nitrite by nitrite such that a nitro group is replaced by an O-N=O group. The ester then rapidly hydrolyzes, and the net reaction is the production of an additional nitrite with each cycle. A simple modeling of this system satisfactorily fits the experimental findings. ?? 2002 Elsevier Science B.V. All rights reserved.

Thermochimica Acta↗

Validation of eDNA markers for New Zealand mudsnail surveillance and initial eDNA monitoring at Mississippi River Basin sites

The performance of newly developed New Zealand mudsnail ( Potamopyrgus antipodarum ; NZMS) genetic markers for environmental (eDNA) analysis of water were compared across two laboratories. The genetic markers were tested in four quantitative polymerase chain reaction assays targeting two regions of the NZMS mitochondrial genome, specifically the cytochrome c oxidase subunit 1 (coi) and cytochrome b (cytb) genes. In a blind study, analysts tested each sample eight times with each assay. There were 10 expected-negative samples from the Black River in La Crosse, Wisconsin, 10 expected-positive samples from the Black Earth Creek in Black Earth, Wisconsin, and 10 known-positive samples from the Black River spiked with NZMS DNA. Previously extracted samples, kept at the Upper Midwest Environmental Sciences Center, were pooled by sample location and then equal quantities were distributed between the Upper Midwest Environmental Sciences Center and the Molecular Conservation Genetics Laboratory at the University of Wisconsin-Stevens Point for analysis. The assays tested were (1) the assay targeting cytb with a minor groove binder probe described by Goldberg and others (2013), (2) the cytb assay with a modified double-quenched probe, (3) an assay targeting coi with a double-quenched probe, and (4) a duplex reaction combining the modified cytb assay and the coi assay. Samples were considered positive for the presence of NZMS DNA when quantitative polymerase chain reaction amplification and probe signal was higher than the normalized threshold value above baseline fluorescence. For the duplex assay, samples were considered positive only when both probe signals were higher than the normalized threshold value above baseline fluorescence. Positive results were then confirmed by sequencing the products. All four assays detected the DNA of NZMS in all expected-positive and known-positive samples in both labs. The modified cytb assay, the coi assay, and the duplex assay all failed to detect the DNA of NZMS in all expected-negative samples in both labs. The cytb assay, as described by Goldberg and others (2013), failed to detect the DNA of NZMS in all expected-negative samples for the Molecular Conservation Genetics Laboratory, but some reactions resulted in positive detection in late cycles for 9 of the 10 expected-negative samples at the Upper Midwest Environmental Sciences Center. Amplicons for expected-negative samples with positive reactions were sent for sequencing, and none were confirmed as NZMS. Six amplicons failed to give readable sequences, and three gave sequences without similarity to any known sequence in GenBank. Amplicons from each assay for one representative positive sample were sequenced and identified as NZMS with greater than 99 percent identity. The duplex assay was chosen as the most efficient assay and was used at the Upper Midwest Environmental Sciences Center to analyze triplicate samples from 29 streams in Wisconsin, 8 streams in Illinois, and 8 streams in Iowa. In order to verify results, additional triplicate samples were collected from two of the streams in Iowa and two of the streams in Wisconsin for analysis at the Molecular Conservation Genetics Laboratory. All samples at all sites were negative for NZMS DNA.

Illinois, Iowa, Wisconsin↗

Morphologic evolution of the wilderness area breach at Fire Island, New York—2012–15

Introduction Hurricane Sandy, which made landfall on October 29, 2012, near Atlantic City, New Jersey, had a significant impact on the coastal system along the south shore of Long Island, New York. A record significant wave height of 9.6 meters (m) was measured at wave buoy 44025 , approximately 48 kilometers offshore of Fire Island, New York. Surge and runup during the storm resulted in extensive beach and dune erosion and breaching of the Fire Island barrier island system at two locations, including a breach that formed within the Otis Pike Fire Island High Dune Wilderness area on the eastern side of Fire Island. The U.S. Geological Survey (USGS) has a long history of conducting morphologic change and processes research at Fire Island. One of the primary objectives of the current research effort is to understand the morphologic evolution of the barrier system on a variety of time scales (from storm scale to decade(s) to century). A number of studies that support the project objectives have been published. Prior to Hurricane Sandy, however, little information was available on specific storm-driven change in this region. The USGS received Hurricane Sandy supplemental funding (project GS2–2B: Linking Coastal Processes and Vulnerability, Fire Island, New York, Regional Study) to enhance existing research efforts at Fire Island. The existing research was greatly expanded to include inner continental shelf mapping and investigations of processes of inner shelf sediment transport; beach and dune response and recovery; and observation, analysis, and modeling of the newly formed breach in the Otis Pike High Dune Wilderness area, herein referred to as the wilderness breach. The breach formed at the site of Old Inlet, which was open from 1763 to 1825. The location of the initial island breaching does not directly correspond with topographic lows of the dunes, but instead the breach formed in the location of a cross-island boardwalk that was destroyed during Hurricane Sandy. From 2013 to November 2015, bathymetric data were collected by the USGS St. Petersburg Coastal and Marine Science Center during three surveys of the breach channel and tidal shoals, and shoreline positions on each side of the breach (also collected by the National Park Service). Additionally, pre-storm topography/bathymetry EAARL–B light detection and ranging (lidar) data were collected by the USGS the day prior to Hurricane Sandy’s landfall. These data serve as a baseline for change analyses during four subsequent periods: June 2013, June 2014, October 2014, and May 2015. The June 2013 single-beam bathymetry data were collected in collaboration with the U.S. Army Corps of Engineers (USACE), using the Lighter Amphibious Resupply Cargo (LARC) vessel, and included the ebb shoal and breach channel. The USGS collected and processed the three additional bathymetric datasets using personal watercraft equipped with single-beam echo sounders and backpack Global Positioning System (GPS) over shallow flood shoals. Eastern and western breach shorelines were surveyed weekly to monthly beginning on November 6, 2012 (by the National Park Service [NPS], and USGS St. Petersburg Coastal and Marine Science Center), with measurements made every few weeks for the first year and every few months after October 2013. The NPS and researchers from Stony Brook University monitored the breach by collecting field data of the breach channel bathymetry, conducting aerial photographic overflights, and performing water-quality analyses (see http://po.msrc.sunysb.edu/GSB/ ). The aerial photography collected and rectified by Stony Brook University is used extensively in our morphologic change description to examine changes to breach shorelines (supplementing shoreline data collected in the field), channel width, and orientation. Due to the uncertainties and the variation in survey methods, a rigorous quantitative analysis was not performed. However, average calculations of various breach metrics allow a qualitative analysis of breach development and evolution. This report presents an overview of the data collected and a summary discussion of the observed changes to the breach system and the seasonal wave climatology associated with the breach morphodynamic response.

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