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Simulated ground-motion records for the seismic assessment of monumental masonry structures

Earthquakes are natural disasters that can cause widespread devastation and loss of life. Simulated ground-motion records can be useful in regions with limited seismic stations or a history of damaging but infrequent earthquakes. This is especially true in areas with a high concentration of heritage masonry structures, which are especially susceptible to damage, as simulated records can be crucial in predicting their seismic response and protecting these buildings from seismic damage. Despite the importance of simulated earthquakes, few studies have investigated how effective they are compared to real earthquakes when assessing the structural response of heritage buildings. To address this knowledge gap, we employ two different simulation methods of the Mw 6.2 Faial earthquake, which occurred on July 9th, 1998, in the Azores, to replicate the recorded time-series at four available stations within an epicentral distance of 150 km. The study has two objectives: first, to validate the simulated records of the 1998 Faial earthquake using alternative stochastic ground-motion simulation approaches, and second, to determine how these approaches impact the seismic assessment of historic masonry structures. To accomplish these objectives, this study uses real and simulated ground-motion datasets to conduct non-linear response history analyses of the São Francisco Church, a monumental structure in Horta that sustained damage during the Faial earthquake. The results show that both simulation approaches yield structural responses similar to the observed records.

Conference Paper

Analysis of nutrients in the surface waters of the Georgia–Florida Coastal Plain study unit, 1970–91

During the early phase of the Georgia-Florida National Water Quality Assessment study, existing information on nutrients was compiled and analyzed in order to evaluate the nutrient concentrations within the 61,545 square mile study unit. Evaluation of the nutrient concentrations collected at surface-water sites between October 1, 1970, and September 30, 1991, utilized the environmental characteristics of land resource provinces, land use, and nonpoint and point-source discharges within the study unit. Long-term trends were investigated to determine the temporal distribution of nutrient concentrations. In order to determine a level of concern for nutrient concentrations, the U.S. Environmental Protection Agency (USEPA) guidelines were used: (1) for nitrate concentrations, the maximum contaminant level in public-drinking water supplies (10 mg/L); (2) for ammonia concentrations, the chronic exposure of aquatic organisms to un-ionized ammonia (2.1 mg/L); (3) for total-phosphorus concentrations, the recommended concentration in flowing water to discourage excessive growth of aquatic plants (0.1 mg/L); and (4) for kjeldahl concentrations, however, no guidelines were available. For sites within the 10 major river basins, median nutrient concentrations were enerally below USEPA guidelines, except for total-phosphorus concentrations where 45 percent of the medians exceeded the guideline. The only median ammonia concentration that exceeded the guideline occurred at the Swift Creek site (3.4 mg/L), in the Suwannee River basin, perhaps due to wastewater discharges. For all sites within the Withlacoochee, Aucilla, and St. Marys River basins, median concentrations of nitrate, ammonia, and total phosphorus were below the USEPA guidelines. Nutrient data at each monitoring site within each major basin were aggregated for comparisons of median nutrient concentrations among major basins. The Ochlockonee and Hillsborough River basins had the highest median nutrient concentrations, the Aucilla River basin had the lowest. Median concentrations of nitrate and ammonia among all major basins were below USEPA guidelines. The median total-phosphorus concentrations for the following river basins exceeded the USEPA guideline: Hillsborough, St. Johns, Suwannee, Ochlockonee, Satilla, Altamaha, and Ogeechee. Although nutrient concentrations within the study unit were low, long-term increasing trends were found in all four nutrients. All 18 study-unit wide nitrate trends had increasing slopes ranging from less than 0.01 to 0.07 (mg/L)/yr. The range in slope for the 13 ammonia trends was -0.03 to 0.01 (mg/L)/yr with 6 increasing trends in the northern part of the study unit. Of the 17 total-phosphorus trends found in the study unit, 10 were found at sites where the median concentration exceeded the USEPA guideline. At these 10 sites, 4 sites had increasing trends with slopes ranging from less than 0.01 to 0.07 (mg/L)/yr, 5 sites had decreasing trends with slopes ranging from -0.01 to -0.24 (mg/L)/yr, and one site showed a seasonal concentration trend. Median nutrient concentrations were significantly different among the four land resource provinces: Southern Piedmont, Southern Coastal Plain, Coastal Flatwoods, and Central Florida Ridge. As a result, nutrient concentrations among basins with similar nutrient inputs but located within different land resource provinces are not expected to be the same due to differences in the combination of factors such as soil permeability, runoff rates, and stream channel slopes. This concept is an important consideration in designing a surface-water quality network within the study area. For the most part, the Coastal Flatwoods showed the lowest median nutrient concentrations and the Southern Coastal Plain had the highest median nutrient concentrations. Lower median nitrate concentrations in surface-water basins were associated with the forest/wetland land-use category and higher median concentrations of nitrate and ammonia with the urban category when land-use percentages were classified into four land-use categories (agriculture, forest/wetland, mixed, and urban). These results were reasonable based on expected high nutrient inputs from urban areas and low inputs from forested and wetland areas. However, the lack of association between high nutrient concentrations and the agricultural land-use category was not expected since high nutrient inputs are generally needed for agriculture production.

Florida, Georgia

High frequency and region-scale simulations of large (Mw7+) earthquakes on the southern Whidbey Island fault, Washington, USA

We simulate ground shaking in western Washington State from hypothetical M w 7.0–7.5 earthquakes on the southern Whidbey Island fault (SWIF). Ground motions are modeled considering kinematic source distributions on a complex fault plane, a 3D seismic velocity model, and region‐specific soil velocity models. We run simulations with varying model resolutions, including regional‐scale simulations with a maximum‐modeled frequency of ∼1 Hz and local‐scale simulations with a maximum‐modeled frequency of ∼2.5 Hz. Additional local‐scale simulations are run considering high‐resolution surface topography. We explore how source parameters (i.e., magnitude, hypocenter location, and dip direction) and 3D velocity structure impact peak shaking intensity and its variability. In particular, we find that earthquakes on the SWIF would likely produce strong shaking throughout the populated Puget Lowland, including in the cities of Everett, Seattle, Bellevue, and Tacoma, Washington. Simulated short‐period ( T ≤ 2 s) spectral accelerations are strong throughout the Puget Lowland, and long‐period shaking ( T ≥ 5 s) is strong in the deep regional sedimentary basins, especially the Everett and Seattle basins. Source parameters strongly influence intra‐ and interevent variability in response, primarily through changes in source and site geometry, as well as rupture directivity. We also note a potential coupling between rupture directivity and basin effects, wherein directivity pulses are seemingly guided through the region’s deep, interconnected sedimentary basins. Overall, this work highlights the impacts of 3D source, path, and site effects on seismic hazard in the U.S. Pacific Northwest and substantially expands the catalog of simulated ground motions for Puget Sound area crustal faults.

Washington

A great tsunami earthquake component of the 1957 Aleutian Islands earthquake

The great 1957 Aleutian Islands earthquake ruptured ∼1200 km of the plate boundary along the Aleutian subduction zone and produced a destructive tsunami across Hawaiʻi. Early seismic and tsunami analyses indicated that large megathrust fault slip was concentrated in the western Aleutian Islands, but tsunami waves generated by slip in the west cannot explain the large observed runup in Hawaiʻi far to the southeast. Recently mapped 1957 geologic deposits on eastern Aleutian Islands suggest occurrence of very large nearby slip. Jointly modeling tsunami runup along the eastern Aleutian and Hawaiian Islands together with tide gauge recordings across the Pacific resolves 12-26 m shallow slip along 600 km of the eastern Aleutian Islands in addition to modest, deeper western slip inferred from seismic records. The eastern near-trench slip results in an M W 8.3-8.6 tsunami earthquake component of the M W 8.6-8.8 rupture, comparable in size to the adjacent 1946 Aleutian tsunami earthquake to the east. The reexamination of the 1957 rupture confirms the tsunami hazards posed by the eastern Aleutian subduction zone to Hawaiʻi and lays the groundwork for investigation of large prehistoric earthquakes through modeling tsunami runup inferred from stratigraphic observations to constrain their rupture processes.

Alaska

Temporal and spatial comparison of coal mine ventilation methane emissions and mitigation quantified using PRISMA satellite data and on-site measurements

Emission monitoring at the facility level (bottom-up, BU) is key for accurate reporting of coal mine methane (CMM) emissions. Recent advances in aerial and satellite observations (top-down, TD) indicate that these methods have the potential to support CMM emissions monitoring and reporting of, as well as track the effectiveness of, mitigation actions. That said, studies have shown discrepancies between BU and TD estimations. Performing TD monitoring with concurrent BU measurements at the same mines may help address the observed discrepancies and improve quantification methods to narrow the gap between BU and TD data. This paper presents a comparison of concurrent BU-TD methane emission fluxes monitored from two ventilation shafts at a southwestern Virginia, USA, longwall mine to complement the existing body of studies on satellite-based monitoring of coal mines by incorporating continuous ground-based monitoring with concurrent TD monitoring of methane emission fluxes to address the gap and provide valuable insights into temporal emission patterns. The shafts were monitored on multiple dates between 2020 and 2023. BU monitoring was performed at the exhaust fans, while TD quantifications used PRISMA hyperspectral satellite data and two different wind reanalysis datasets (i.e., GEOS-FP and ERA5). This mine also offered a unique opportunity for BU-TD comparisons before and after ventilation air methane (VAM) oxidizer operation, which was installed at one of the shafts in 2022. The results showed that TD-estimated mean fluxes were generally lower than BU data, which were attributed to quantification difficulties associated with the low albedo caused by heavy vegetation and the terrain of the area. However, despite the discrepancies in mean emissions, both the interquartile range and the data range of the distributions generally overlapped, and the estimates correctly showed the emission trends.

Virginia

Chemical evolution and estimated flow velocity of water in the Trinity Aquifer, south-central Texas

Three permeable zones with varying lithology and water chemistry compose the Trinity aquifer, a principal source of water in the 5,500- square-mile study area in south-central Texas. The upper permeable zone locally yields small quantities of water to wells and was not included in this study. The middle permeable zone primarily is composed of limestone with minor amounts of dolostone. Terrigenous sand and marine limestone, with minor amounts of dolostone, are the principal lithologic units in the lower permeable zone. Dissolved solids concentrations range from 329 to 1,820 milligrams per liter in water samples from the middle permeable zone and from 518 to 3,030 milligrams per liter in water samples from the lower permeable zone. Principal hydrochemical facies in the middle permeable zone are calcium magnesium bicarbonate and calcium magnesium sulfate. Hydrochemical facies in ground-water samples from the lower permeable zone vary. Tritium concentrations as large as 5.3 tritium units in the southeastern part of the study area are indicative of relatively recent recharge. Results of a geochemical mass balance simulation along a flowpath in the middle permeable zone indicate a mass transfer of 4.25 millimoles per liter of dolomite dissolved, 5.74 millimoles per liter of gypsum dissolved, 0.46 millimole per liter of sodium chloride dissolved, 8.07 millimoles per liter of calcite precipitated, and 0.67 millimole per liter of calcium-for-sodium cation exchange between solid and aqueous phases. These results support dedolomitization as a principal chemical process in the middle permeable zone of the Trinity aquifer. Results of a simulation along a flowpath in the lower permeable zone indicate a mass transfer of 0.41 millimole per liter of dolomite dissolved, 0.001 millimole per liter of gypsum dissolved, 9.58 millimoles per liter of sodium chloride dissolved, 1.09 millimoles per liter of calcite precipitated, and 1.11 millimoles per liter of sodium-forcalcium cation exchange between solid and aqueous phases. Lower permeable zone processes indicate sodium chloride dissolution, dedolomitization, and cation exchange. Ground-water-flow velocities determined from adjusted carbon-14 ages, calculated using NETPATH, for selected flowpaths in the middle and lower permeable zones were about 1.7 feet per year and less than about 4.4 feet per year, respectively.

Texas

Water-quality study of a reach of the Merced River in Yosemite National Park and vicinity, California, April 1973 through September 1974

A 25-mile (40-kilometre) reach of the Merced River was studied to provide the National Park Service with water-quality data prior to the operation of a new sewage-treatment plant. Data were collected periodically at four Merced River and two inflow stations. Discharge varied seasonally with highest flow occurring at the time of spring snowmelt runoff. Lowest flow occurred during late summer, coinciding with high park visitor use and elevated water temperature. Water-quality variables investigated were discharge, temperature, major chemical constituents, selected trace metals, specific conductance, suspended sediment, turbidity, dissolved oxygen, pH, alkalinity, carbon dioxide, total organic carbon, nitrogen, phosphorus, algal growth potential, coliform bacteria, periphyton, and benthic invertebrates. Diel measurements were made at some stations to delineate daily fluctuations in selected water-quality variables. Results indicate that water in the reach of the Merced River studied was of good quality. The river had low concentrations of dissolved solids (8 to 41 milligrams per litre) and low alkalinity values (2 to 24 milligrams per litre of alkalinity as CaCO 3 ). Mean concentrations of nitrogen and phosphorus were highest in the Merced River at Rancheria Flat. Algal growth potential tests showed that phosphorus was limiting algal growth at Happy Isles Bridge, El Capitan Bridge, and South Fork Merced River, whereas nitrogen was limiting growth at Rancheria Flat. Input of excessive nitrogen and phosphorus concentrations in the Merced River during the summer low-flow period, and mixing with warm tributary inflow could cause excessive algal growth and production. The algal types found were diatoms, green algae, and blue-green algae. Biomass/chlorophyll a ratios in the Merced River were low (0.3 to 7.7). Benthic invertebrates consisted chiefly of Diptera, Ephemeroptera, and Plecoptera.

California

Geophysical identification of potential groundwater – surface water interactions in the Bonita Peak Mining District, San Juan County, Colorado

This report includes the results and interpretation of geophysical investigations to aid in the location, identification, and conceptual site model (CSM) development of the near surface groundwater and surface water hydrology of the Upper Cement Creek and California Gulch of the Animas Rivers within the Bonita Peak Mining Districts (BPMD). Mine influenced water (MIW) from numerous mine adits within the BPMD has altered the geochemistry and ecology of these ground and surface waters. Many studies of varying scales have investigated the geology, hydrogeology, geochemistry, and aqueous chemistry of these adits and impacted areas. Field investigations using non-invasive geophysical methods were conducted in the summer of 2019 to aid in identifying potential groundwater inputs to these streams and further the CSM of the near surface within and along these streams. Two field deployments were completed in August and September of 2019. In August 2019, Phase 1 was completed using multifrequency electromagnetic induction (EMI) and thermal infrared imaging (TIR) to measure the bulk electrical conductivity, magnetic susceptibility, and the temperature response at known and suspected groundwater seeps into the Upper Cement Creek and California Gulch stretches of these alpine streams. Results and interpretation from Phase 1 were used to co-locate stretches of these streams for further detailed fiber optic distributed temperature system (FODTS) monitoring of the temperature dynamics for submeter identification of potential groundwater seeps during Phase 2. Phase 2 included additional EMI measurements, FODTS measurements, and repeated some Phase 1 measurements for improved data quality. All these data were used for the combined qualitative interpretation identifying seep locations. The data from both Phase 1 and Phase 2 are available in the USGS data release at: https://www.sciencebase.gov/catalog/item/5f18a30082cef313ed84879b. These data include detailed near-surface electrical conductivity and magnetic susceptibility mapping, discrete TIR imaging, and several kilometers of FODTS data. These data were georeferenced and used to identify potential groundwater seeps into these streams. The results indicate a complex near surface geophysical and hydrogeologic regime. Seeps are classified and spatially correlated to the EMI, TIR, and geochemical sampling results. This report is a thorough compilation of the geophysical field efforts in the summer of 2019, the data processing, and interpretations of these data. These data alone should not be used for final interpretations of the complex hydrogeology within these alpine systems. Rather, these data should be combined with other known data from various investigations to further refine the CSM and guide decisions for future investigations, watershed protective measures, and other site decisions. Geographical information system (GIS) layers of these results are available to project managers for such integration and combined interpretations.

Colorado

A novel drive-point multilevel system to investigate PFAS and other contaminants of global concern in the hyporheic zone of a wastewater effluent dominated stream

Contaminants found in treated wastewater discharged to streams, including pharmaceuticals and per- and polyfluoroalkyl substances (PFAS), are of global concern due to their deleterious effects on aquatic ecosystems and potential impacts to human health. Hyporheic zones have strong potential for contaminant attenuation. Assessing this potential requires collection of physical and biogeochemical data within the hyporheic zone. This study tested the applicability of a novel drive-point multilevel system (DP-MLS) for quantifying head profiles and characterizing contaminant concentrations in the hyporheic zone of a temperate region effluent dominated stream (EDS). DP-MLS, each with 4 ports, were installed in the stream bed at two sites, DS-1 and DS-2, 0.2 and 4.7 km downstream of the effluent outfall, respectively. Head profiles were measured and groundwater collected for analysis of pharmaceuticals and PFAS temporally over two years. The DP-MLS withstood rapid changes in stage, ice formation, and floating debris. Vertical hydraulic gradients (VHG) were generally upward but varied in magnitude indicating heterogeneity in hydraulic conductivity and variability in flow conditions. Upward VHG were also about 2X larger at DS-1 than at DS-2. Contaminant concentration profiles consistently showed penetration of pharmaceuticals and PFAS to 1 m below the bed at DS-2 while there was less penetration, lower groundwater concentrations, and more temporal variability in concentrations at DS-1. Integration of the physical and chemical data suggests weaker upwelling conditions at DS-2 are more easily reversed during periods of high stream stage, which could facilitate migration of wastewater contaminants into the bed. However, further studies incorporating other transport processes and reach scale dynamics are required to fully characterize these exchanges. Overall, this study demonstrates the efficacy of these novel DP-MLSs for characterization of the hyporheic zone and provides new insights into the occurrence, composition, and persistence of wastewater derived contaminants in the hyporheic zone of a well-studied EDS.

Iowa

Fairweather transform boundary Oligocene to present orogenesis: Fairweather Range vertical extrusion and rotation of the Yakutat microplate at ca. 3 Ma

Oblique-slip along transform fault boundaries is often partitioned between a strike-slip system and thrust faults that accommodate contraction. However, topography along the Yakutat-North American transform (Fairweather fault), is asymmetric with low-terrain above active thrusts on the western, Yakutat side of the transform and high topography on the continental side with peaks >4500 m (Mount Fairweather: 4671 m) to the west of the Border Ranges fault, limited recorded earthquakes >M4, and no apparent reverse faults to generate the highest terrain. In this study we compile, for the first time, published U-Pb zircon, 40 Ar/ 39 Ar and K-Ar (hornblende, muscovite, and biotite) and U-Th/He and fission-track (zircon and apatite) bedrock ages (109) from 75 samples to investigate the exhumation history of the Fairweather Range region, complemented by a published detrital sample (ZFT and AFT) and 13 new 40 Ar/ 39 Ar (hornblende, biotite, and K-feldspar) ages on 9 bedrock samples from both sides of the Fairweather fault. Additionally, we examined published seismicity and geodetic data of the Fairweather region and assessed if plate paleo-vectors correlate with the cooling history of the Fairweather Range. Cooling age, seismic, and block-motion patterns indicate the Fairweather Range has been vertically extruded between the Fairweather and the Border Ranges faults as a coherent block since ca. 25 Ma. The pre-6 Ma Pacific plate motion (N30°W) aligns with the N33°W strike of the Fairweather Fault whereas a hypothetical pre-6 Ma Yakutat microplate paleo-vector of (N39°W) does not: indicating a post-6 Ma timing for Yakutat microplate counter-clockwise rotation (9°). We infer that rotation and impingement of the Yakutat microplate along the Fairweather fault at ca. 3 Ma led to the development of the Fairweather restraining bend and increased cooling rates. The resultant thickened Fairweather welt and the ∼30 km thick southeast end of the Yakutat microplate compounded double-indenter tectonics into Alaska's southeast convergent corner

Tectonophysics

Updating the crustal fault model for the 2023 National Seismic Hazard Model for Alaska

We present the crustal fault model for Alaska, based on geologic observations, as a primary input for the 2023 revision of the U.S. Geological Survey National Seismic Hazard Model. We update the 2013 Alaska Quaternary fault and fold database to produce a simplified model of 105 fault sections and four fault zone polygons with basic geologic parameters including slip sense and rate. Significant updates include the following: (1) a slip rate of ∼53 mm/year on the Queen Charlotte Fault indicating it accommodates all of the plate boundary motion; (2) quantified slip rates on megathrust splay faults in the southern Prince William Sound region and near Kodiak Island; (3) improved details of structures in the Chugach-St. Elias orogen; (4) revision of the Castle Mountain Fault from right-lateral slip to a predominantly reverse fault; (5) improved Interior Alaska tectonic models that clarify relationships between the Denali, Totschunda, and thrust faults on both sides of the Alaska Range; (6) identified large earthquake sources in the eastern Brooks Range; and (7) omission of the Chatham Strait section of the Denali Fault. The fault model underscores that the collision of the Yakutat microplate is the dominant driver of active crustal faulting in most of Alaska.

Alaska, Yukon

Limited evidence of late Quaternary tectonic surface deformation in the eastern Tennessee seismic zone, USA

The ~300-km-long eastern Tennessee seismic zone (ETSZ), USA, is the second-most seismically active region east of the Rocky Mountains. Seismicity generally occurs below the Paleozoic fold-and-thrust belt within the Mesoproterozoic basement, at depths of 5–26 km, and earthquake magnitudes during the instrumental record have been moment magnitude ( M w )≤4.8. Evidence of surface deformation may not exist or be difficult to detect because of the vegetated and soil-mantled landscape, landslides, locally steep topography, anthropogenic landscape modification, or long, irregular recurrence intervals between surface-rupturing earthquakes. Despite the deep seismicity, analog models indicate that accumulation of strike-slip or oblique-slip displacement at depth could be expected to propagate upward through the Paleozoic section, producing a detectable surficial signal of distributed faulting. To identify potential surface deformation, we interrogated the landscape at different spatial scales. We evaluated morphotectonic and channel metrics, such as channel sinuosity and catchment-scale hypsometry. Additionally, we mapped possible fault-related topographic features on 1-m lidar. Finally, we integrated our observations with available bedrock and Quaternary surficial mapping and subsurface geophysical data. At a regional scale, most morphotectonic and channel metrics have a strong lithologic control. Within smaller regions of similar lithology, we observe changes in landscape metrics like channel sinuosity and catchment-scale hypsometry that spatially correlate with new lineaments identified in this study and previously mapped east–west Cenozoic faults. These faults have apparent left-lateral offsets, are optimally oriented to slip in the current stress field, and match kinematics from recent focal mechanisms, but do not clearly preserve evidence of late Pleistocene or Holocene tectonic surface deformation. Most newly mapped lineaments might be explained by either tectonic or non-tectonic origins, such as fluvial or karst processes. We also re-evaluated a previously described paleoseismic site and interpret that the exposure does not record evidence of late Pleistocene faulting but instead is explained by fluvial stratigraphy.

Tennessee

Trace elements in some rocks and slag from the Yemen Arab Republic and their bearing on the iron ore near Sa'dah

Thirty-seven samples of rocks, saprolite, laterite, gossan, and slag were collected in the Yemen Arab Republic during June-July 1975 when field work was conducted to refine an interpretation of the regional geology made from LANDSAT-1 images by M. J. Grolier. These samples we reanalyzed in the laboratories of the U. S. Geological Survey, and the results were interpreted for use in programs of economic development as a guide for the evaluation of mineral resources in the Yemen Arab Republic. The work was undertaken as part of the program of the U. S. Agency for International Development with the cooperation of the Mineral and Petroleum Authority, Ministry of Economy, Yemen Arab Republic.

Open-File Report

Mine waste as a potential source of critical minerals and other commodities: Examples from the Four Corners states, USA

The growing demand for critical minerals and other mineral resources has raised concerns about possible supplies of these essential commodities. Mine waste is a potential source of these essential commodities. We compiled a geospatial database of publicly available data of the largest non-fuel mine waste features (>200,000 m 2 in areal extent) in the Four Corners states of the United States, where most of those features are from porphyry Cu deposits. The combined volume of those large porphyry Cu mine waste features is approximately 17 cubic kilometers, 60% of which is ore-related material such as tailings. Using publicly available data on density, grade, and previous recovery values, we estimate the contained endowments of Ag, As, Au, Bi, Cu, Mo, Re, S, Sb, Se, Te, and W. These estimates indicate endowments within ore-related mine wastes are collectively comparable to endowments of giant to supergiant deposits. If fully recovered, these commodities could meet current global demand from less than 1 year (Sb) to more than 200 years (Re), underscoring the enormous untapped resource potential of mine waste.

Arizona, Colorado, New Mexico, Utah

Hydrogeologic framework and extent of saltwater intrusion in Kings, Queens, and Nassau Counties, Long Island, New York

In 2016, the U.S. Geological Survey began a multiyear cooperative study with the New York State Department of Environmental Conservation to evaluate the sustainability of Long Island’s sole-source aquifer system through hydrogeologic mapping, compilation of groundwater chloride concentrations, and groundwater flow modeling. In the initial phase of the islandwide study, the hydrogeologic framework and extent of saltwater intrusion in aquifers in Kings, Queens, and Nassau Counties on western Long Island, N.Y., were investigated. The aquifer system underlying western Long Island has been under stress from pumping of public, irrigation (golf course), and industrial supply wells. Saltwater intrusion has occurred from surrounding embayments (East River, Long Island Sound, Jamaica Bay, and the Atlantic Ocean) due to pumping. Eighteen boreholes were drilled and cores taken during 2019–21 to collect hydrogeologic, geochemical, and geophysical data to delineate the complex subsurface hydrogeology and extent of saltwater intrusion within the study area. Evaluation of the new cores, reexamination of legacy core descriptions, and analysis of borehole geophysical logs was used to refine the previously published hydrogeologic framework of Pleistocene and Cretaceous unconsolidated sediments in the area, including delineation of a previously undefined hydrogeologic unit between the Magothy aquifer and the Raritan confining unit, herein named the “upper Raritan aquifer.” The upper Raritan aquifer was first recognized in southeastern Nassau County from an analysis of about 50 closely spaced boreholes with high-resolution core descriptions and gamma-ray (gamma) logs. Further analysis of borehole logs across the study area indicated that the upper Raritan aquifer was also present in Kings and Queens Counties. Nuclear magnetic resonance (NMR) logging was used for the first time on Long Island to provide estimates of the hydraulic properties of the major aquifer and confining units. Unlike other geophysical logs that record responses to the rock matrix and fluid properties and are strongly dependent on mineralogy, NMR logs record responses to the presence of hydrogen protons in the formation fluid to determine water fraction and pore-size distribution. NMR log analysis provided estimates of the clay-bound, capillary-bound, and mobile water fractions and hydraulic conductivity of aquifers and confining units penetrated by five wells in Nassau County. Pumpage for public-supply and industrial wells on Long Island began in the 1870s with small, localized suppliers of populated areas in Kings and Queens Counties. By 1904–16, pumpage for public water supply in Kings County averaged 21 million gallons per day, and averaged 37 million gallons per day in Queens County, mostly from the upper glacial aquifer. Saltwater intrusion was reported as early as the beginning of the 20th century and included the upper glacial-Jameco-Magothy and Lloyd-North Shore aquifer systems. By 1936, pumping in central Kings County created a major cone of depression in the water table extending to the south shore of much of Kings County and into southwestern Queens County. Saltwater intrusion has caused the shutdown of public-supply wells in Kings, Queens, and Nassau Counties. A large saltwater intrusion wedge in the Lloyd aquifer was indicated in southern Queens County in the early part of the 20th century, and the saltwater interface may have been onshore predevelopment. Most of Kings and Queens Counties are intruded with saltwater in both the upper glacial-Jameco-Magothy and Lloyd-North Shore aquifers systems. Saltwater increased during the 20th century and continues to increase to the present (2023) in the Lloyd-North Shore aquifer system in Great Neck and Manhasset Neck in northern Nassau County. A major wedge of saltwater intrusion in the upper glacial-Jameco-Magothy aquifer in southwestern Nassau County appears to be increasing.

New York

Effects of storm-water runoff on local ground-water quality, Clarksville, Tennessee

Storm-related water-quality data were collected at a drainage-well site and at a spring site in Clarksville, Tennessee, to define the effects of storm-water runoff on the quality of ground water in the area. A dye-trace test verified the direct hydraulic connection between the drainage well and Mobley Spring. Samples of storm run off and spring flow were collected at these sites for nine storms during the period February to October 1988. Water samples were collected also from Mobley Spring and two other springs and two observation wells in the area during dry-weather conditions to assess the general quality of ground water in an urban karst terrain. Evaluation of the effect of storm-water runoff on the quality of local ground water is complicated by the presence of other sources of contaminants in the area Concentrations and load for most major constituents were much smaller in storm-water runoff at the drainage well than in the discharge of Mobley Spring, indicating that much of the chemical constituent load discharged from the spring comes from sources other than the drainage well. However, for some of the minor constituents associated with roadway runoff (arsenic, copper, lead, organic carbon, and oil and grease), the drainage well contributed relatively large amounts of these constituents to local ground water during storms. The close correlation between concentrations of total organic carbon and concentrations of most trace metals at the drainage-well and Mobley Spring sites indicates that these constituents are transported together. Many trace metals were flushed early during each runoff event. Mean storm loads for copper, lead, zinc, and four nutrient species (total nitrogen, ammonia nitrogen, total phosphorus, and orthophosphorus) in storm-water runoff at the drainage-well site were lower than mean storm load predicted from an existing regression model. The overprediction by the model may be a result of the small size of the drainage area relative to the range of drainage areas used in the development of the models, or to the below-normal amounts of rainfall during the period of sampling for this investigation. Loads& in storm-water runoff for 22 constituents were extrapolated from sampled storms to total loads for the period February to October 1988. Calculated loads for trace metals for the period ranged from 0.030pound.s for cadmium to 12pound.s for strontium. Loads of the primary nutrients ranged from 0.97pounds for nitrite as nitrogen to 34pounds of organic nitrogen. Storm-water quality at the drainage-well and Mobley Spring sites was compared to background water quality of the local aquifer; as characterized by dry-weather samples from three springs and two observation wells in the Clarksville area. Concentrations of total-recoverable cadmium, chromium, copper, lead, and nickel were higher in many stormwater samples from both the drainage-well and Mobley Spring sites than in samples from any other site. In addition, concentrations of total organic carbon, methylene blue active substances, and total-recoverable oil and grease were generally higher in storm-water samples from the drainage-well site than in any ground-water sample. Densities of fecal coliform and fecal streptococcus bacteria and concentrations of total recoverable iron, manganese, and methylene blue active substances in storm samples from the drainage-well site exceeded the maximum contaminant levels listed in Tennessee’s drinking-water standards (1988) by as much as 2,500 and 5,500 colonies per 100 milliliters, and 2.7, 0.29, and 0.05 milligrams per liter, respectively. Densities of fecal coliform and fecal streptococcus bacteria and concentrations of total-recoverable iron, manganese, and lead in storm samples from Mobley Spring exceeded the maximum contaminant levels by as much as 500 and 4,500 colonies per 100 milliliters, and 18.7,0.65, and 0.02 milligrams per liter, respectively. For iron, manganese, and bacteria, these undesirable levels are not necessarily attributable to storm-water recharge, because concentrations of these constituents also exceeded drinking-water standards in one or more of the dry-weather samples from selected springs and observation wells in the area.

Tennessee

Water-quality assessment of south-central Texas: Occurrence and distribution of volatile organic compounds in surface water and ground water, 1983-94, and implications for future monitoring

The study area of the South-Central Texas study unit of the National Water-Quality Assessment Program comprises the Edwards aquifer in the San Antonio region and its catchment area. The first phase of the assessment includes evaluation of existing water-quality data for surface water and ground water, including volatile organic compounds, to determine the scope of planned monitoring. Most analyses of volatile organic compounds in surface water are from the National Pollutant Discharge Elimination System sites in San Antonio, Texas. Nine volatile organic compounds were detected at the six sites. The three compounds with the most detections at National Pollutant Discharge Elimination System sites are 1,2,4-trimethylbenzene, toluene, and xylene. Analysis of volatile organic compounds in ground water was limited to Edwards aquifer wells. Twenty-eight volatile organic compounds were detected in samples from 89 wells. The five most commonly detected compounds in samples from wells, in descending order, are tetrachloroethene, trichloroethene, bromoform, chloroform, and dibromochloromethane. Detections of volatile organic compounds in surface water and ground water within the South-Central Texas study area are limited to site-specific sources associated with development; therefore, planned monitoring for possible detections of volatile organic compounds as part of the National Water-Quality Assessment Program will emphasize areas of expanding population and development. Monitoring of volatile organic compounds is planned at National Pollutant Discharge Elimination System sites, at basic fixed surface-water sites, and in the ground-water study-unit surveys.

Texas

Prospectivity modeling of the NASA VIPER landing site at Mons Mouton near the Lunar South Pole

We use a high-resolution digital elevation model and a numerical thermal model to produce a variety of inputs for a water-ice prospectivity model for the Volatiles Investigating Polar Exploration Rover (VIPER) landing site. These input data are maps of topography, surface slope, surface aspect, surface curvature, maximum temperature, depth to ice stability, permanently shadowed regions (PSRs), distance to PSRs, and PSR density. This model predicts where water ice is most likely within the top meter of regolith, assuming plausible relationships between ice concentration and the various inputs. The model is designed to be adjusted in near-real time as data are collected during the VIPER mission. As such, it is a tool for both analyzing data from the mission as well as planning operations. Since the current model, at this point, relies only on orbital remote sensing, the final version will also be a tool to extrapolate the VIPER mission results across the lunar poles.

Planetary Science Journal