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At least 631 records · Page 35Linked to original sources

Electrical conductivity of electrolytes applicable to natural waters from 0 to 100 degrees C

The electrical conductivities of 34 electrolyte solutions found in natural waters ranging from (10 -4 to 1) mol•kg -1 in concentration and from (5 to 90) °C have been determined. High-quality electrical conductivity data for numerous electrolytes exist in the scientific literature, but the data do not span the concentration or temperature ranges of many electrolytes in natural waters. Methods for calculating the electrical conductivities of natural waters have incorporated these data from the literature, and as a result these methods cannot be used to reliably calculate the electrical conductivity over a large enough range of temperature and concentration. For the single-electrolyte solutions, empirical equations were developed that relate electrical conductivity to temperature and molality. For the 942 molar conductivity determinations for single electrolytes from this study, the mean relative difference between the calculated and measured values was 0.1 %. The calculated molar conductivity was compared to literature data, and the mean relative difference for 1978 measurements was 0.2 %. These data provide an improved basis for calculating electrical conductivity for most natural waters.

Journal of Chemical and Engineering Data↗

Biochemical composition of three algal species proposed as food for captive freshwater mussels

To identify potential diets for rearing captive freshwater mussels, the protein, carbohydrate (CHO), and lipid contents of two green algae, Neochloris oleoabundans, Bracteacoccus grandis, and one diatom, Phaeodactylum tricornutum, were compared at different growth stages. The fatty acid and sterol composition were also identified. Protein was greatest (55-70%) for all species at late log growth stage (LL), and declined in late stationary (LS) growth. CHO was greatest at LS stage for all species (33.9-56.4% dry wt). No significant change in lipid levels occurred with growth stage, but tended to increase in N. oleoabundans. Mean lipid content differed significantly in the order: N. oleoabundans > P. tricornutum > B. grandis. Total fatty acids (TFA) were higher at LS stage compared to other stages in the two green algae, and stationary stage in the diatom. Mean unsaturated fatty acids (UFA) as %TFA was significantly higher in N. oleoabundans than the other species. The green algae contained high percentages of C-18 polyunsaturated fatty acids (PUFAs), while the diatom was abundant in C-16 saturated and mono-unsaturated fatty acids and C-20 PUFA fatty acids. Growth stage had no effect on sterol concentration of any species. B. grandis showed significantly higher sterol levels than the other species except P. tricornutum at S stage. B. grandis was characterized by predominantly ??5, C-29 sterols, while N. oleoabundans synthesized ??5,7, ??5,7,22, and ??7, C-28 sterols. P. tricornutum produced primarily a ??5,22, C-28 sterol, and a small amount of a ??7,22, C-28 sterol.

Journal of Applied Phycology↗

Basis for paleoenvironmental interpretation of magnetic properties of sediment from Upper Klamath Lake (Oregon): Effects of weathering and mineralogical sorting

Studies of magnetic properties enable reconstruction of environmental conditions that affected magnetic minerals incorporated in sediments from Upper Klamath Lake. Analyses of stream sediment samples from throughout the catchment of Upper Klamath Lake show that alteration of Fe-oxide minerals during subaerial chemical weathering of basic volcanic rocks has significantly changed magnetic properties of surficial deposits. Titanomagnetite, which is abundant both as phenocrysts and as microcrystals in fresh volcanic rocks, is progressively destroyed during weathering. Because fine-grained magnetite is readily altered due to large surface-to-volume ratios, weathering causes an increase in average magnetic grain size as well as reduction in the quantity of titanomagnetite both absolutely and relative to hematite. Hydrodynamic mineralogical sorting also produces differences in magnetic properties among rock and mineral grains of differing sizes. Importantly, removal of coarse silicate and Fe-oxide grains by sorting concentrated extremely fine-grained magnetite in the resulting sediment. The effects of weathering and sorting of minerals cannot be completely separated. These processes combine to produce the magnetic properties of a non-glacial lithic component of Upper Klamath Lake sediments, which is characterized by relatively low magnetite content and coarse magnetic grain size. Hydrodynamic sorting alone causes significant differences between the magnetic properties of glacial flour in lake sediments and of fresh volcanic rocks in the catchment. In comparison to source volcanic rocks, glacial flour in the lake sediment is highly enriched in extremely fine-grained magnetite.

Journal of Paleolimnology↗

Thermal signature, eruption style, and eruption evolution at Pele and Pillan on Io

The Galileo spacecraft has been periodically monitoring volcanic activity on Io since June 1996, making it possible to chart the evolution of individual eruptions. We present results of coanalysis of Near-Infrared Mapping Spectrometer (NIMS) and solid-state imaging (SSI) data of eruptions at Pele and Pillan, especially from a particularly illuminating data set consisting of mutually constraining, near-simultaneous NIMS and SSI observations obtained during orbit C9 in June 1997. The observed thermal signature from each hot spot, and the way in which the thermal signature changes with time, tightly constrains the possible styles of eruption. Pele and Pillan have very different eruption styles. From September 1996 through May 1999, Pele demonstrates an almost constant total thermal output, with thermal emission spectra indicative of a long-lived, active lava lake. The NIMS Pillan data exhibit the thermal signature of a “Pillanian” eruption style, a large, vigorous eruption with associated open channel, or sheet flows, producing an extensive flow field by orbit C10 in September 1997. The high mass eruption rate, high liquidus temperature (at least 1870 K) eruption at Pillan is the best candidate so far for an active ultramafic (magnesium-rich, “komatiitic”) flow on Io, a style of eruption never before witnessed. The thermal output per unit area from Pillan is, however, consistent with the emplacement of large, open-channel flows. Magma temperature at Pele is ≥1600 K. If the magma temperature is 1600 K, it suggests a komatiitic-basalt composition. The power output from Pele is indicative of a magma volumetric eruption rate of ∼250 to 340 m 3 s −1 . Although the Pele lava lake is considerably larger than its terrestrial counterparts, the power and mass fluxes per unit area are similar to active terrestrial lava lakes.

Journal of Geophysical Research E: Planets↗

Topographic stress perturbations in southern Davis Mountains, west Texas 1. Polarity reversal of principal stresses

We have applied a previously developed analytical stress model to interpret subsurface stress conditions inferred from acoustic televiewer logs obtained in two municipal water wells located in a valley in the southern Davis Mountains near Alpine, Texas. The appearance of stress-induced breakouts with orientations that shift by 90° at two different depths in one of the wells is explained by results from exact solutions for the effects of valleys on gravity and tectonically induced subsurface stresses. The theoretical results demonstrate that above a reference depth termed the hinge point, a location that is dependent on Poisson's ratio, valley shape, and magnitude of the maximum horizontal tectonic stress normal to the long axis of the valley, horizontal stresses parallel to the valley axis are greater than those normal to it. At depths below this hinge point the situation reverses and horizontal stresses normal to the valley axis are greater than those parallel to it. Application of the theoretical model at Alpine is accommodated by the fact that nearby earthquake focal mechanisms establish an extensional stress regime with the regional maximum horizontal principal stress aligned perpendicular to the valley axis. We conclude that the localized stress field associated with a valley setting can be highly variable and that breakouts need to be examined in this context when estimating the orientations and magnitudes of regional principal stresses.

Texas↗

The crustal structure from the Altai Mountains to the Altyn Tagh fault, northwest China

[1] We present a new crustal section across northwest China based on a seismic refraction profile and geologic mapping. The 1100‐km‐long section crosses the southern margin of the Chinese Altai Mountains, Junggar Accretional Belt and eastern Junggar basin, easternmost Tianshan Mountains, and easternmost Tarim basin. The crustal velocity structure and Poisson's ratio (σ), which provide a constraint on crustal composition, were determined from P and S wave data. Despite the complex geology, the crustal thickness along the entire profile is nearly uniform at 50 km. The thickest crust (56 km) occurs at the northern end of the profile beneath the Altai Mountains and the thinnest (46 km) crust is beneath the Junggar basin. Beneath surficial sediments, the crust is found to have three layers with P wave velocities ( V p ) of 6.0–6.3, 6.3–6.6, and 6.9–7.0 km/s, respectively. The southern half of the profile, including the eastern Tianshan Mountains and eastern margin of the Tarim basin, shows low P wave velocities and σ = 0.25 to a depth of 30 km, which suggests a quartz‐rich, granitic upper crustal composition. The northern half of the profile below the Altai Mountains and Junggar Accretional Belt has a higher Poisson's ratio of σ = 0.26–0.27 to a depth of 30 km, indicative of an intermediate crustal composition. The entire 1100‐km‐long profile is underlain by a 15–30 km thick high velocity (6.9–7.0 km/s; σ = 0.26–0.28) lower‐crustal layer that we interpret to have a bulk composition of mafic granulite. At the southern end of the profile, a 5‐km‐thick midcrustal low‐velocity layer ( V p = 5.9 km/s, σ = 0.25) underlies the Tianshan and the region to the south, and may be indicative of a near‐horizontal detachment interface. P n velocities are ∼7.7–7.8 km/s between the Tianshan and the Junggar basin, and ∼7.9–8.0 km/s below the Altai Mountains and eastern margin of the Tarim basin. We interpret the consistent three‐layer stratification of the crust to indicate that the crust has undergone partial melting and differentiation after Paleozoic terrane accretion. The thickness (50 km) of the crust appears to be related to compression resulting from the Indo‐Asian collision.

Altai Mountains↗

Nearshore wave-induced cyclical flexing of sea cliffs

[1] Evolution of a tectonically active coast is driven by geomorphically destructive energy supplied by ocean waves. Wave energy is episodic and concentrated; sea cliffs are battered by the geomorphic wrecking ball every 4-25 s. We measure the response of sea cliffs to wave assault by sensing the ground motion using near-coastal seismometers. Sea cliffs respond to waves in two distinct styles. High-frequency motion (20 Hz) reflects the natural frequency of the sea cliff as it rings in response to direct wave impact. Low-frequency motion in the 0.1-0.05 Hz (10-20 s) band consistently agrees with the dominant nearshore wave period. Integrating microseismic velocities suggests 50 ??m and 10 ??m displacements in horizontal and vertical directions, respectively. Displacement ellipsoids exhibit simultaneous downward and seaward sea cliff motion with each wave. Video footage corroborates the downward sea cliff flex in response to the imposed water load on the wave cut platform. Gradients in displacement amplitudes documented using multiple seismometers suggest longitudinal and shear strain of the flexing sea cliff on the order of 0.5-4 ?? strains during each wave loading cycle. As this sea cliff flexure occurs approximately 3 million times annually, it has the potential to fatigue the rock through cyclical loading. Local sea cliff retreat rates of 10 cm/yr imply that a given parcel of rock is flexed through roughly 109 cycles of increasing amplitude before exposure to direct wave attack at the cliff face. Copyright 2005 by the American Geophysical Union.

Journal of Geophysical Research F: Earth Surface↗

Effects of tributary debris on the longitudinal profile of the Colorado River in Grand Canyon

The Colorado River in Grand Canyon has long been known as a "rapids-and-pools" river, with the rapids owing their existence primarily to tributary debris flows. The debris flows deposit subaerial debris fans that constrict the channel laterally and, when they enter the river, raise the bed elevation. The rapids are short-wavelength (???0.1 to ???1 km), small-amplitude (??????5 m) convexities in the river's longitudinal profile, arising from the shallow gradient in the upstream pool and the steep gradient through the rapid itself. Analysis of the entire longitudinal profile through Grand Canyon reveals two long-wavelength (???100 km), large-amplitude (15-30 m) river profile convexities: the eastern canyon convexity between river mile (RM) 30 and RM 80 and the western canyon convexity between RM 150 and RM 250. Convexities of intermediate scale are also identified in the longitudinal profile. These longer-wavelength, larger-amplitude convexities have strong spatial correlations with high rates of debris flow occurrence, high densities of Holocene debris fans, the largest debris fans along the river, and alluvial thicknesses of 10 m or more. River profile convexities are unstable and require an active and powerful geologic process to maintain them, in this case the abundant, frequent, and voluminous Holocene debris flow activity in Grand Canyon. At all wavelengths the most likely cause for these river profile convexities is Holocene aggradation of the riverbed beneath them, driven by the coarse particles of tributary debris flows. Large enough debris flows will slow river flow for kilometers upstream, causing it to drop much of its suspended load. Integrated over time and all of the tributary point source contributions, this process will build short-wavelength convexities into long-wavelength convexities. For most if not all of the Holocene the Colorado River has been dissipating most of its energy in the rapids and expending the remainder in transporting fine sediment through Grand Canyon, with little or no regional incision of bedrock.

Journal of Geophysical Research F: Earth Surface↗

February 2003 marine atmospheric conditions and the bora over the northern Adriatic

A winter oceanographic field experiment provided an opportunity to examine the atmospheric marine conditions over the northern Adriatic. Mean February winds are from a northeasterly direction over most of the Adriatic and a more northerly direction along the western coast. Wind speeds are fastest in jets over the NE coast during bora events and weakest in the mid-northwestern Adriatic. Diurnal air temperature cycles are smallest on the NE coast and largest in the midwestern Adriatic. The maximum sea-air difference is +10??C on the eastern coast and near zero on the midwestern Adriatic. Boras are northeasterly (from) wind events that sweep off Croatia and Slovenia, bringing slightly colder and drier air over the northern Adriatic. The main bora season is December to March. Winter 2002-2003 was normal for bora events. Synoptic-scale temporal variations are correlated over the northern Adriatic. Fastest Bora winds and highest wind stress over the northern Adriatic is concentrated in four topographically controlled jets. The strongest is the Senj Jet, while the Trieste Jet extends across the entire northern Adriatic. Between each two jets is a weak wind zone. The greatest mean net heat loss is in bora jets in the NE Adriatic, where it was -438 W m-2 and is weakest in the midwestern northern Adriatic, where it was near zero. Wind stress is concentrated over the NE half of Adriatic in four bora jets, while wind stress is weak in the NW Adriatic. There is significant variation in wind stress mean and standard deviation structure over the northern Adriatic with each bora event. Copyright 2006 by the American Geophysical Union.

Journal of Geophysical Research C: Oceans↗

Surface drifter derived circulation in the northern and middle Adriatic Sea: Response to wind regime and season

More than 120 satellite-tracked drifters were deployed in the northern and middle Adriatic (NMA) Sea between September 2002 and November 2003, with the purpose of studying the surface circulation at mesoscale to seasonal scale in relation to wind forcing, river runoff, and bottom topography. Pseudo-Eulerian and Lagrangian statistics were calculated from the low-pass-filtered drifter velocity data between September 2002 and December 2003. The structure of the mean circulation is determined with unprecedented high horizontal resolution by the new data. In particular, mean currents, velocity variance, and kinetic energy levels are shown to be maximal in the Western Adriatic Current (WAC). Separating data into seasons, we found that the mean kinetic energy is maximal in fall, with high values also in winter, while it is significantly weaker in summer. High-resolution Local Area Model Italy winds were used to relate the drifter velocities to the wind fields. The surface currents appear to be significantly influenced by the winds. The mean flow during the northeasterly bora regime shows an intensification of the across-basin recirculating currents. In addition, the WAC is strongly intensified both in intensity and in its offshore lateral extension. In the southeasterly sirocco regime, northward flow without recirculation dominates in the eastern half of the basin, while during northwesterly maestro the WAC is enhanced. Separating the data into low and high Po River discharge rates for low-wind conditions shows that the WAC and the velocity fluctuations in front of the Po delta are stronger for high Po River runoff. Lagrangian covariance, diffusivity, and integral time and space scales are larger in the along-basin direction and are maximal in the southern portion of the WAC. Copyright 2006 by the American Geophysical Union.

Journal of Geophysical Research C: Oceans↗

Acoustic bed velocity and bed load dynamics in a large sand bed river

Development of a practical technology for rapid quantification of bed load transport in large rivers would represent a revolutionary advance for sediment monitoring and the investigation of fluvial dynamics. Measurement of bed load motion with acoustic Doppler current profiles (ADCPs) has emerged as a promising approach for evaluating bed load transport. However, a better understanding of how ADCP data relate to conditions near the stream bed is necessary to make the method practical for quantitative applications. In this paper, we discuss the response of ADCP bed velocity measurements, defined as the near-bed sediment velocity detected by the instrument's bottom-tracking feature, to changing sediment-transporting conditions in the lower Missouri River. Bed velocity represents a weighted average of backscatter from moving bed load particles and spectral reflections from the immobile bed. The ratio of bed velocity to mean bed load particle velocity depends on the concentration of the particles moving in the bed load layer, the bed load layer thickness, and the backscatter strength from a unit area of moving particles relative to the echo strength from a unit area of unobstructed bed. A model based on existing bed load transport theory predicted measured bed velocities from hydraulic and grain size measurements with reasonable success. Bed velocities become more variable and increase more rapidly with shear stress when the transport stage, defined as the ratio of skin friction to the critical shear stress for particle entrainment, exceeds a threshold of about 17. This transition in bed velocity response appears to be associated with the appearance of longer, flatter bed forms at high transport stages.

Journal of Geophysical Research F: Earth Surface↗

Modeling the evolution of channel shape: Balancing computational efficiency with hydraulic fidelity

The cross-sectional shape of a natural river channel controls the capacity of the system to carry water off a landscape, to convey sediment derived from hillslopes, and to erode its bed and banks. Numerical models that describe the response of a landscape to changes in climate or tectonics therefore require formulations that can accommodate evolution of channel cross-sectional geometry. However, fully two-dimensional (2-D) flow models are too computationally expensive to implement in large-scale landscape evolution models, while available simple empirical relationships between width and discharge do not adequately capture the dynamics of channel adjustment. We have developed a simplified 2-D numerical model of channel evolution in a cohesive, detachment-limited substrate subject to steady, unidirectional flow. Erosion is assumed to be proportional to boundary shear stress, which is calculated using an approximation of the flow field in which log-velocity profiles are assumed to apply along vectors that are perpendicular to the local channel bed. Model predictions of the velocity structure, peak boundary shear stress, and equilibrium channel shape compare well with predictions of a more sophisticated but more computationally demanding ray-isovel model. For example, the mean velocities computed by the two models are consistent to within ???3%, and the predicted peak shear stress is consistent to within ???7%. Furthermore, the shear stress distributions predicted by our model compare favorably with available laboratory measurements for prescribed channel shapes. A modification to our simplified code in which the flow includes a high-velocity core allows the model to be extended to estimate shear stress distributions in channels with large width-to-depth ratios. Our model is efficient enough to incorporate into large-scale landscape evolution codes and can be used to examine how channels adjust both cross-sectional shape and slope in response to tectonic and climatic forcing. Copyright 2008 by the American Geophysical Union.

Journal of Geophysical Research F: Earth Surface↗

Compositions of modern dust and surface sediments in the Desert Southwest, United States

Modern dusts across southwestern United States deserts are compositionally similar to dust-rich Av soil horizons (depths of 0-0.5 cm and 1-4 cm at 35 sites) for common crustal elements but distinctly different for some trace elements. Chemical compositions and magnetic properties of the soil samples are similar among sites relative to dust sources, geographic areas, and lithologic substrates. Exceptions are Li, U, and W, enriched in Owens Valley, California, and Mg and Sr, enriched in soils formed on calcareous fan gravel in southeast Nevada. The Av horizons are dominated by dust and reflect limited mixing with substrate sediments. Modern dust samples are also similar across the region, except that Owens Valley dusts are higher in Mg, Ba, and Li and dusts both there and at sites to the north on volcanic substrates are higher in Sb and W. Thus, dust and Av horizons consist of contributions from many different sources that are well mixed before deposition. Modern dusts contain significantly greater amounts of As, Cd, Cr, Cu, Ni, Pb, and Sb than do Av horizons, which record dust additions over hundreds to thousands of years. These results suggest that modern dust compositions are influenced by anthropogenic sources and emissions from Owens (dry) Lake after its artificial desiccation in 1926. Both modern dusts and Av horizons are enriched in As, Ba, Cu, Li, Sb, Th, U, and W relative to average crustal composition, which we interpret to indicate that the geologic sources of dust in the southwestern United States are geochemically distinctive.

Journal of Geophysical Research F: Earth Surface↗

The 2007 M5.4 Alum Rock, California, earthquake: Implications for future earthquakes on the central and southern Calaveras Fault

[1] The similarity of seismograms recorded by two seismic stations demonstrate that the 31 October 2007 moment magnitude M 5.4 Alum Rock earthquake is a repeat of a 1955 M L 5.5 earthquake. Both occurred on Oppenheimer et al.'s (1990) Zone V “stuck patch” on the central Calaveras fault, providing new support for their model of Calaveras fault earthquake activity. We suggest that Zone V fails only in a family of recurring M ∼ 5.4–5.5 earthquakes. The 1955 and 2007 earthquakes are the penultimate and ultimate Zone V events. Earthquakes in 1891 and 1864 are possible earlier Zone V events. The next Zone V event is not expected in the next few decades, assuming a time‐dependent recurrence model: the mean forecast date is 2064 (2035–2104, 95% confidence range). We further suggest that Zones I, II, III, and IV fail in recurring M ∼ 5.1–5.3, M ∼ 5.6–5.8, M ∼ 6.1–6.3, and M ∼ 4.9–5.0 earthquakes, respectively. If our earthquake recurrence model is correct, the next Zone I event is overdue and could occur anytime, and M 5–6 earthquakes should not occur on Zones II, III, and IV before 2014, 2012, and 2026, respectively. We cannot rule out the possibility that Zone VI, which lies at the southern end of the Mission Seismic Trend, where the southern Hayward and central Calaveras faults appear to connect at depth, fails aseismically or in large events on the southern Hayward fault, such as last occurred in 1868, or in large events on the adjoining northern Calaveras fault segment.

California↗

Azimuthal seismic anisotropy of 70 Ma Pacific‐plate upper mantle

Plate formation and evolution processes are predicted to generate upper mantle seismic anisotropy and negative vertical velocity gradients in oceanic lithosphere. However, predictions for upper mantle seismic velocity structure do not fully agree with the results of seismic experiments. The strength of anisotropy observed in the upper mantle varies widely. Further, many refraction studies observe a fast direction of anisotropy rotated several degrees with respect to the paleospreading direction, suggesting that upper mantle anisotropy records processes other than 2D corner flow and plate‐driven shear near mid‐ocean ridges. We measure 6.0 ± 0.3% anisotropy at the Moho in 70 Ma lithosphere in the central Pacific with a fast direction parallel to paleospreading, consistent with mineral alignment by 2D mantle flow near a mid‐ocean ridge. We also find an increase in the strength of anisotropy with depth, with vertical velocity gradients estimated at 0.02 km/s/km in the fast direction and 0 km/s/km in the slow direction. The increase in anisotropy with depth can be explained by mechanisms for producing anisotropy other than intrinsic effects from mineral fabric, such as aligned cracks or other structures. This measurement of seismic anisotropy and gradients reflects the effects of both plate formation and evolution processes on seismic velocity structure in mature oceanic lithosphere, and can serve as a reference for future studies to investigate the processes involved in lithospheric formation and evolution.

Journal of Geophysical Research B: Solid Earth↗

Paleomagnetic constraints on the geometry and timing of deformation at Yucca Mountain, Nevada

Paleomagnetic data from Miocene ash flow sheets indicate that southern Yucca Mountain has undergone about 30° of clockwise vertical-axis rotation since emplacement of the Tiva Canyon Member of the Paintbrush Tuff at about 13 Ma. Declinations of remanent magnetization from 32 sites in the reversely magnetized Tiva Canyon Member display a systematic southward increase over the 25 km north–south extent of Yucca Mountain. Probable errors in estimating structural attitudes are a major source of uncertainty in determining the amount of rotation between any two sites. Analysis of tilt-corrected directions of remanent magnetization from the Tiva Canyon sites indicates that structural attitudes determined from outcrop patterns on geologic maps are generally more accurate than field measurements of attitudes of compaction foliation or contacts. Attitudes determined from map patterns apparently minimize effects of (1) initial dips, (2) poorly defined compaction foliation, and (3) tilting that occurred after compaction but before blocking of remanence; however, such attitudes cannot accurately represent tilting related to unmapped local structures. Rotations implied by data from three older ash flow sheets, the Topopah Spring Member of the Paintbrush Tuff (seven sites), and the Prow Pass (four sites) and Bullfrog (three sites) Members of the Crater Flat Tuff are generally consistent with the amount and sense of rotation documented by data from the Tiva Canyon Member. Uncertainties in the declinations of tilt-corrected site mean directions from these older units preclude evaluating whether older units have undergone more rotation than the Tiva Canyon Member.

Journal of Geophysical Research↗

Magnetic susceptibility and relation to initial 87Sr/86Sr for granitoids of the central Sierra Nevada, California

Measurement of the magnetic susceptibility of more than 6000 samples of granitic rock from the Mariposa 1° by 2° quadrangle, which crosses the central part of the Sierra Nevada batholith between 37° and 38°N latitude, shows that magnetic susceptibility values are above 10 −2 SI units in the east and central parts of the batholith and drop abruptly to less than 10 −3 SI units in the western foothills. In a narrow transitional zone, intermediate values (10 −3 to 10 −2 ) prevail. Magnetic susceptibility appears to decrease slightly westward within the zones of both high and low values. Magnetic susceptibility in plutonic rocks is chiefly a function of the abundance of magnetite, which depends, in turn, on the total iron content of the rocks and their oxidation ratio. Lower magnetic susceptibilities of felsic members of Sierran intrusive suites and of some felsic rock units relative to adjacent mafic rock units commonly reflect differences in total iron content, but the differences of magnetic susceptibility that define the regional pattern generally are much larger and are determined chiefly by the oxidation ratios of the rocks. The relatively unaltered condition of the samples and restriction of δ 18 O to the range of +7 to +10.3‰ indicate that neither hydrothermal fluids nor subsolidus alteration were important in modifying oxidation ratios. Correlations of magnetic susceptibility with initial 87 Sr/ 86 Sr suggest that oxidation ratios have been inherited from the source regions for the magmas from which the rocks crystallized. Reduction of Fe 3+ to Fe 2+ by organic carbon or other reducing substances may also have affected magnetic susceptibility.

Journal of Geophysical Research↗

Relation of peralkaline magmatism to heterogeneous extension during the Middle Miocene, southeastern Nevada

Volcanism migrated southward in the northern Basin and Range province in the Oligocene and early Miocene to produce voluminous calcalkaline silicic ash flow tuffs. Alkaline volcanism became dominant by middle Miocene (17–14 Ma) as smaller volumes of rhyolite-trachyte-basalt suites were erupted from the relatively small Kane Springs Wash caldera complex including the Narrow Canyon, Boulder Canyon, and Kane Springs Wash calderas in southeastern Nevada. Only minor extension affected the Kane Wash area before the end of calcalkaline activity, but extension expressed by rate of progressive stratal tilt peaked (15–13.5 Ma) with peralkaline magmatism (14.7–14.4 Ma). Variations in distribution, degree, style, and timing of deformation demonstrate heterogeneous extension in the Kane Wash area. Only minor extension and tilting persisted post-middle Miocene (<12 Ma). All major eruptive sources overlap domains of rapid extension. Most of the eruptive volumes from the two oldest calderas of the complex apparently pooled within their calderas, creating outflow deficits. Denudation faulting associated with magmatic tumescence may have followed preexisting active extensional fault systems to unload magma chambers, thus triggering eruptions into structural depressions. Evolution of alkaline magmas is demonstrated by progressive increases in peralkalinity and high field strength elements such as Zr, Y, and Nb. Nd, Pb, and Sr isotopic compositions provide evidence that significantly less crustal interaction affected middle Miocene peralkaline magmas than pre-middle Miocene calcalkaline magmas. ε Nd values are −5 to −7 for peralkaline magmas and −7 to −11 for calcalkaline magmas; 208 Pb/ 204 Pb ratios are 38.2–38.6 for peralkaline magmas and 38.5–38.9 for calcalkaline magmas. Regional cooling, short duration of magmatism, small volumes of magma, and local extension caused less crustal interaction in peralkaline Kane Wash magmas than in earlier magmas. North of the Kane Wash area, older more voluminous calcalkaline magmas intruded hotter crust for a longer period and thus interacted with the crust to a greater degree in spite of synvolcanic extension.

Journal of Geophysical Research↗