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At least 631 records · Page 35Linked to original sources

The USGS National crustal model for seismic hazard studies: 2019 update

The United States Geological Survey (USGS) National Crustal Model (NCM) is being developed to assist in the modeling of seismic hazards across the conterminous United States, specifically by improving estimates of site response. The NCM is composed of geophysical profiles, extending from the Earth’s surface into the upper mantle, constructed from 5 primary elements: 1) depth to bedrock and basement; 2) 3D geologic framework; 3) petrologic and mineral physics database; 4) 3D temperature model; and 5) calibration of a porosity and attenuation model. Parameters needed to estimate site response for existing ground motion models (GMMs), including the time-averaged velocity in the upper 30 meters (VS30) and the depths to 1.0 and 2.5 km/s shear-wave velocity (Z1.0 and Z2.5), can be extracted from the NCM. As GMMs develop, other metrics could also be extracted or derived from the NCM such as fundamental frequency, a fully frequency-dependent site response function, or 3D geophysical volumes for wavefield simulations. Application of the NCM may also benefit other aspects of seismic hazard analysis including better accounting for path-dependent attenuation and geometric spreading and more accurate estimation of earthquake source properties such as hypocentral location and stress drop.

Conference Paper↗

The significance of observations at active volcanoes; A review and annotated bibliography of studies at Kilauea and Mount St. Helens

Study of active volcanoes yields information of much broader significance than to only the discipline of volcanology. Some applications are 1) interpretation of lava-flow structures, stratigraphic complexities, and petrologic relations in older volcanic units; 2) interpretation of bulk properties of the mantle and constraints on partial melting and deep magma transport; 3) interpretation of geophysical characteristics of potentially active volcanic systems; 4) direct determination of physical properties of molten and solidified basalt, and of intensive variables (e.g., oxygen fugacity and temperature) accompanying cooling and crystallization; 5) quantitative assessment of crystal fractionation and magma mixing, 6) tests of theoretical and experimental geochemical, geophysical, and rheologic models of volcanic behavior; and 7) confirmation in nature of laboratory experiments related to crystallization in igneous systems. The critical factors that make real-time study of volcanic activity valuable are that the location and timing of events are known, and that molten rock and gases are available for direct observation and sampling for subsequent study. Observations made over a period of time make it possible to calculate rates of magma transport, storage, and crystallization, as well as to quantitatively determine elastic and inelastic deformation and the build up and decay of stress within the active volcanic system. Discussion of these topics is keyed to an annotated bibliography from which quantitative information on properties and processes may be obtained. Emphasis is on Hawaii's active basaltic volcanoes for which the most information is available. Additional references are made to research at Mount St. Helens, one of the first real-time studies of an active volcano of dacitic composition.

Hawaii, Washington↗

Tertiary igneous rocks and Laramide structure and stratigraphy of the Spanish Peaks Region, South-Central Colorado: Road log and descriptions from Walsenburg to La Veta

The Spanish Peaks are located in the western part of the Raton basin in south-central Colorado, southwest of Walsenburg. The two peaks, West Spanish Peak (WSP, 13,626 feet) and East Spanish Peak (ESP, 12,683 feet), are located on the upland part of the far western edge of the Great Plains physiographic region. East of Spanish Peaks, a deeply dissected plateau extends into the Great Plains. The Raton basin, an asymmetric structure of Laramide age, underlies and surrounds the Spanish Peaks. The basin extends north from Ute Park, New Mexico, to Huerfano Park, Colorado. The juncture of steeply dipping western and gently dipping eastern limbs of the Raton basin forms the basin axis, known locally as the La Veta syncline. The La Veta syncline extends north-northwest into Huerfano Park, between the Sangre de Cristo and Wet Mountains. These features and others such as the Laramide orogeny, igneous rocks, and an overview of petrology are discussed.

Colorado↗

Finalization of the Confocal Laser Scanning Microscopy (CLSM) working group

A working group in Commission II to investigate applications of confocal laser scanning microscopy (CLSM) for organic petrology investigations has finalized with publication of the manuscript “Characterization of bituminite in Kimmeridge Clay by confocal laser scanning and atomic force microscopy” in the International Journal of Coal Geology. The manuscript is available via Open Access from https://doi.org/10.1016/j.coal.2022.103927 and also from the Commission II working group (WG) webpage https://www.iccop.org/workinggroup/confocal-laser-scanning-microscopy-clsm/. A report detailing the full history and results from the WG also is available from the Commission II WG webpage. The working group investigated the application of CLSM to an organic-rich (44 wt.% TOC), thermally immature sample (VRo 0.42%) of the Kimmeridge Clay Formation. CLSM imaging and spectroscopy and atomic force microscopy (AFM) were used to characterize bituminite.

ICCP News↗

The Confocal Laser Scanning Microscopy Working Group of the ICCP: Final report 2021

This report summarizes the activities and results of the Confocal Laser Scanning Microscopy (CLSM) working group (WG) of the International Committee for Coal and Organic Petrology (ICCP), from its inception in September, 2015, to the present day (September, 2021). The purpose of this report is to document the history of the working group and to compile and evaluate its results. The CLSM WG examined an immature, organic-rich sample of Kimmeridge Clay, which was characterized via CLSM imaging and spectroscopy. In addition, mechanically polished and broad ion beam (BIB) milled sample preparations were characterized via atomic force microscopy. Highlights of findings from the CLSM WG include: the interpreted presence of Botryococcus; incomplete blocking of laser light from highly reflective materials; surface roughening and surface flattening induced by differential BIB milling dependent on location and scale of measurement; substitution of uranium for iron in sulfides; red-shift of reflectance and auto-fluorescence from below the sample surface; positive alteration from laser-induced photo-oxidation of the sample surface including fluorescence blue-shift; blueshift associated to higher fluorescence intensity regions in amorphous organic matter; need for fluorescence spectroscopy standardization as applied via CLSM; and the suitability of CLSM to predict solid bitumen reflectance via calibration to an extant data set. Due to the inability of WG members to continue participating in a WG format, the CLSM WG is hereby finalized. This report represents the final product of WG activity, with the aim to summarize the information included herein for a future peer-reviewed manuscript.

Final Report↗

Andesite sills in the Red Mountain area, Scapegoat Wilderness, Lewis and Clark County, Montana

Sills 2-200 ft (0.6-60 in) thick in the Red Mountain area of the Scapegoat Wilderness in northwest Montana consist of altered andesite, basaltic andesite, and dacite and occur over a stratigraphic range of 8,000 ft (2,400 m) in the Helena and Snowslip Formations. The approximate compositional range of the sills is 50-80 percent plagioclase, 0-25 percent orthoclase, and 5-30 percent amphibole, pyroxene, and biotite; the uppermost sill contains about 15 percent quartz in the groundmass. Accessory minerals include quartz, magnetite, ilmenite, apatite, and pyrite. The petrology and alteration of the sills distinguish them from other sills in the region. Field observations and laboratory studies consisting of chemical, isotopic and X-ray analyses, and petrographic and mineralogic investigations suggest that the sills may have been emplaced in Precambrian Y time at about the same time as the extrusion of the Purcell Lava in the vicinity of Glacier National Park. Alternatively, the sills may represent a Precambrian igneous event not previously recognized in the Belt basin.

Montana↗

Fifth special report of the Hawaiian Volcano Observatory of the Hawaiian Volcano Research Association and the U.S. Geological Survey: Abrasion hardness

After reviewing the work of sclerometry, this paper shows that yielding and relative softness are the mechanical basis of what should be called malacometry. The experiments have been made with diamond drills, ring cuts, end millers and grinding wheels. Auerbach's "limited scope of the Mohs list" is quantitatively confirmed. The wear of diamonds is examined. A program is carried out, for rotary or annular abrasion by diamond under three applications of energy, each progressively slower. A selected commercial talc is the control substance of softness value 100. The instruments used are synchronous motors, drill presses, wheel grinders, and watchmaker lathes. Some 200 minerals, woods, metals, glasses and plastics were originally measured. Hardness tables and curves are shown for comparison with volumetric abradability. For a Mohs succession the softer substances abrade relatively more under higher energy of contact friction, and any one substance shows higher relative values under lower energy of attrition; in other words, under slower scratching. An artificially cut diamond octahedron gives more consistent results than a natural crystal, under light pressures. Standard successions of relative abradability measurements do not hold good under different energies of attack. Functions of plasticity, brittleness, cleavage, powder lubricity, ductility and the like introduce various anomalies, and constancy of pressure varies with variable yielding. The supposition that rhythmic instrumental abrading will hold its mechanical constants, while the substance attacked yields in accord with its own surface molecular mobility relative to a control substance, is only approximately true. At low energies the approximation is better than at high, but at high speeds the wear of tool is less. Hence the advantage of using with slow speed a replaceable tool. Substances of different categories such as steels and woods, differ in behavior from minerals. The Mohs System has the great advantage of extending the controls from mineral to mineral up through the whole scale, and is purely qualitative. It is not numerically quantitative at all in terms of equal units. A principal result of this investigation is that 80 per cent of the Mohs Scale, Numbers 3 to 10, are by common consent within 1 per cent of a malacometric scale numbered 1 to 100. The scientists who determined this relation were the sclerometry investigators of the nineteenth century, who mistakenly thought that the wide intervals of sclerometry are between the hard minerals. They used the reciprocals of the measures of yielding. The simple scratch tester finally arrived at is quite different from the instruments of Parts II and III. It eliminates diamond drilling, retains the Mohs controls and utilizes a dental grinding wheel and a modern low speed motor. The object of this research has been to design a simple instrument for many uses, especially for the mechanic's shop. It is planned for manufacture at an early date. The author is indebted to Dr. Earl Ingerson, Chief, Geochemistry and Petrology Branch, for critical correction and approval of this paper, by authority of the Director, U. S. Geological Survey.

Report of the Hawaiian Volcano Observatory↗

Chemical variability in the Lakeview Mountains pluton, southern California batholith: A comparison of the methods of correspondence analysis and extended Q-mode factor analysis

An extended method of Q -mode factor analysis that has been described previously offers a number of important advantages over conventional Q -mode factor analysis and correspondence analysis when applied to compositional data. Among these are the ability to compute the compositions, in the original units of the data, represented by the reference axes. The only special requirement of the data is that the values for each observation sum to a constant. Mathematically derived reference axes, such as the principal-components and varimax axes, commonly represent compositions that are partly negative. Even where no negative values are present, these compositions are comparatively difficult to interpret in petrologic terms and impossible or inappropriate to include in petrogenetic models. A model has been developed for the Lakeview Mountains pluton which employs vectors representing the compositions of melanocratic schlieren, leucocratic schlieren, and inclusions as the reference axes. When the effect of the inclusions is removed, the compositional zoning in the pluton is like that found in otherwise similar plutons in the Sierra Nevada batholith. The genetic implication of the model is that the inclusions were separated from the magma at least in its marginal parts. In the central part of the pluton, the inclusions were either separated to a lesser extent than in the marginal parts, or were reincorporated into the magma.

California↗

Updates to and applications of the USGS National Crustal Model for seismic hazard studies

The U.S. Geological Survey (USGS) National Crustal Model (NCM) is being developed to assist in the modeling of seismic hazards across the conterminous United States. The NCM is composed of a grid of geophysical profiles, extending from the Earth’s surface into the upper mantle. It is constructed from a 3D geologic framework and geophysical rules defined by: (1) a petrologic and mineral physics database; (2) a 3D temperature model; and (3) a calibrated rock type- and age-dependent porosity model. Parameters needed to estimate site response for existing ground motion models (GMMs), including the time-averaged velocity in the upper 30 meters ( V S 30 ) and the depths to 1.0 and 2.5 km/s shear-wave velocity ( Z 1.0 and Z 2.5 ), can be extracted from the NCM. As GMMs develop, other metrics could also be extracted or derived from the NCM such as sediment thickness and travel times, fundamental frequency, a fully frequency-dependent site response function, or 3D geophysical volumes for wavefield simulations. Application of the NCM may also benefit other aspects of seismic hazard analysis including better accounting for path-dependent attenuation and geometric spreading, more accurate estimation of earthquake source properties such as hypocentral location and stress drop, and calculation of crustal strength profiles that inform estimates of the base of seismicity.

Conference Paper↗

Volcanoes of the Mojave: The 2022 Desert Symposium field trip road log

Basalt lava fields, some decorated with scoria ‘cinder’ cones, are scattered around the Mojave Desert. Most basalt fields are short-lived, but the Cima volcanic field is unique in having eruptions that span ~7.5 m.y., including the youngest eruption in the Mojave Desert at ~12 ka. Xenolith-bearing basalts that include both mantle and deep crustal rocks are known in several fields. All basalt fields except Cima are restricted to the active eastern California shear zone, and many lie directly on active faults, indicating a direct relation between faults and volcanism. The field trip will visit the Pisgah, Dish Hill, Amboy, Cima, and Bicycle Lake volcanic fields, and it will enable examination of the physical volcanology in the basalt fields, including the types of eruptions (effusive and explosive) and the resulting deposits (lava flows, scoria cones, and tuff cones). It will also review the petrology, paleomagnetism, remote sensing, and planetary geology studies conducted at each volcanic field, and how these studies influenced the development of each of these study areas.

California↗

Recent applications of the USGS National Crustal Model for Seismic Hazard Studies

The U.S. Geological Survey is developing the National Crustal Model (NCM) for seismic hazard studies to facilitate modeling site, path, and source components of seismic hazard across the conterminous United States. The NCM is composed of a 1km grid of geophysical profiles, extending from the Earth’s surface into the upper mantle. It is constructed from a threedimensional (3D) geologic framework and geophysical rules that use (1) a petrologic and mineral physics database; (2) a 3D temperature model; and (3) a calibrated rock type- and age-dependent porosity model. Parameters needed to estimate site response for existing ground motion models (GMMs), including the time-averaged velocity in the upper 30 meters (VS30), the depths to 1.0 and 2.5 km/s shear-wave velocity (Z1.0 and Z2.5), and sediment thickness, can be computed from the NCM. As GMMs continue to improve in the future, other metrics could also be extracted or derived from the NCM, such as fundamental period, site attenuation (ko), a fully frequency-dependent site response function, or 3D geophysical volumes for wavefield simulations. Application of the NCM may also benefit other aspects of seismic hazard analysis, including better accounting for path-dependent attenuation and geometric spreading, more accurate estimation of earthquake source properties such as hypocentral location and stress drop, and calculation of crustal strength profiles that inform estimates of the base of seismicity.

conterminous United States↗

Exposure of a late cretaceous layered mafic-felsic magma system in the central Sierra Nevada batholith, California

New U-Pb zircon ages for the Lamarck Granodiorite, associated synplutonic gabbro and diorite plutons, and two large mafic intrusive complexes that underlie them in the Sierra Nevada batholith are 92??1 Ma. These ages establish the Late Cretaceous as a period of extensive mafic-felsic magmatism in the central part of the batholith, and confirm the significance of mafic magmatism in the evolution of the voluminous silicic plutions in the Sierran arc. The lack of significant zircon inheritance in any of the units analyzed supports isotopic evidence that the Lamarck and other Late Cretaceous Sierran plutons were derived predominantly from young crust. Recognition of an extensive mafic-felsic magma system in the Sierra Nevada batholith emphasizes the importance of basaltic liquids in the evolution of continental crust in arc settings. ?? 1995 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

Deep drilling at the Siljan Ring impact structure: oxygen-isotope geochemistry of granite

The Siljan Ring is a 362-Ma-old impact structure formed in 1700-Ma-old I-type granites. A 6.8-km-deep borehole provides a vertical profile through granites and isolated horizontal diabase sills. Fluid-inclusion thermometry, and oxygen-isotope compositions of vein quartz, granite, diabase, impact melt, and pseudotachylite, reveal a complex history of fluid activity in the Siljan Ring, much of which can be related to the meteorite impact. In granites from the deep borehole, ??18O values of matrix quartz increase with depth from near 8.0 at the surface to 9.5??? at 5760 m depth. In contrast, feldspar ??18O values decrease with depth from near 10 at the surface to 7.1??? at 5760 m, forming a pattern opposite to the one defined by quartz isotopic compositions. Values of ??18O for surface granites outside the impact structure are distinct from those in near-surface samples from the deep borehole. In the deep borehole, feldspar coloration varies from brick-red at the surface to white at 5760 m, and the abundances of crack-healing calcite and other secondary minerals decrease over the same interval. Superimposed on the overall decrease in alteration intensity with depth are localized fracture zones at 4662, 5415, and 6044 m depth that contain altered granites, and which provided pathways for deep penetration of surface water. The antithetic variation of quartz and feldspar ??18O values, which can be correlated with mineralogical evidence of alteration, provides evidence for interaction between rocks and impact-heated fluids (100-300?? C) in the upper 2 km of the pluton. Penetration of water to depths below 2 km was restricted by a general decrease in impact-fracturing with depth, and by a 60-m-thick diabase sill at 1500 m depth that may have been an aquitard. At depths below 4 km in the pluton, where water/rock ratios were low, oxygen isotopic compositions preserve evidence for limited high-temperature (>500?? C) exchange between alkali feldspar and fluids. The high-temperature exchange may have been a post-impact event involving impact-heated fluids, or a post-magmatic event. ?? 1990 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

Origin of xenoliths in the trachyte at Puu Waawaa, Hualalai Volcano, Hawaii

Rare dunite and 2-pyroxene gabbro xenoliths occur in banded trachyte at Puu Waawaa on Hualalai Volcano, Hawaii. Mineral compositions suggest that these xenoliths formed as cumulates of tholeiitic basalt at shallow depth in a subcaldera magma reservoir. Subsequently, the minerals in the xenoliths underwent subsolidus reequilibration that particularly affected chromite compositions by decreasing their Mg numbers. In addition, olivine lost CaO and plagioclase lost MgO and Fe2O3 during subsolidus reequilibration. The xenoliths also reacted with the host trachyte to form secondary mica, amphibole, and orthopyroxene, and to further modify the compositions of some olivine, clinopyroxene, and spinel grains. The reaction products indicate that the host trachyte melt was hydrous. Clinopyroxene in one dunite sample and olivine in most dunite samples have undergone partial melting, apparently in response to addition of water to the xenolith. These xenoliths do not contain CO2 fluid inclusions, so common in xenoliths from other localities on Hualalai, which suggests that CO2 was introduced from alkalic basalt magma between the time CO2-inclusion-free xenoliths erupted at 106??6 ka and the time CO2-inclusion-rich xenoliths erupted within the last 15 ka.

Hawaii↗

Transmission electron microscopy of subsolidus oxidation and weathering of olivine

Olivine crystals in basaltic andesites which crop out in the Abert Rim, south-central Oregon have been studied by high-resolution and analytical transmission electron microscopy. The observations reveal three distinct assemblages of alteration products that seem to correspond to three episodes of olivine oxidation. The olivine crystals contain rare, dense arrays of coherently intergrown Ti-free magnetite and inclusions of a phase inferred to be amorphous silica. We interpret this first assemblage to be the product of an early subsolidus oxidation event in the lava. The second olivine alteration assemblage contains complex ordered intergrowths on (001) of forsterite-rich olivine and laihunite (distorted olivine structure with Fe3+ charge balanced by vacancies). Based on experimental results for laihunite synthesis (Kondoh et al. 1985), these intergrowths probably formed by olivine oxidation between 400 and 800??C. The third episode of alteration involves the destruction of olivine by low-temperature hydrothermal alteration and weathering. Elongate etch-pits and channels in the margins of fresh olivine crystals contain semi-oriented bands of smectite. Olivine weathers to smectite and hematite, and subsequently to arrays of oriented hematite crystals. The textures resemble those reported by Eggleton (1984) and Smith et al. (1987). We find no evidence for a metastable phase intermediate between olivine and smectite ("M" - Eggleton 1984). The presence of laihunite exerts a strong control on the geometry of olivine weathering. Single laihunite layers and laihunite-forsteritic olivine intergrowths increase the resistance of crystals to weathering. Preferential development of channels between laihunite layers occurs where growth of laihunite produced compositional variations in olivine, rather than where coherency-strain is associated with laihunite-olivine interfaces. ?? 1990 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

The tholeiite to alkalic basalt transition at Haleakala Volcano, Maui, Hawaii

Previous studies of alkalic lavas erupted during the waning growth stages (<0.9 Ma to present) of Haleakala volcano identified systematic temporal changes in isotopic and incompatible element abundance ratios. These geochemical trends reflect a mantle mixing process with a systematic change in the proportions of mixing components. We studied lavas from a 250-m-thick stratigraphic sequence in Honomanu Gulch that includes the oldest (∼1.1 Ma) subaerial basalts exposed at Haleakaka. The lower 200 m of section is intercalated tholeiitic and alkalic basalt with similar isotopic (Sr, Nd, Pb) and incompatible element abundance ratios (e.g., Nb/La, La/Ce, La/Sr, Hf/Sm, Ti/Eu). These lava compositions are consistent with derivation of alkalic and tholeiitic basalt by partial melting of a compositionally homogeneous, clinopyroxene-rich, garnet lherzolite source. The intercalated tholeiitic and alkalic Honomanu lavas may reflect a process which tapped melts generated in different portions of a rising plume, and we infer that the tholeiitic lavas reflect a melting range of ∼10% to 15%, while the intercalated alkalic lavas reflect a range of ∼6.5% to 8% melting. However, within the uppermost 50 m of section. 87 Sr/ 86 Sr decreases from 0.70371 to 0.70328 as eruption age decreased from ∼0.97 Ma to 0.78 Ma. We infer that as lava compositions changed from intercalated tholeiitic and alkalic lavas to only alkalic lavas at ∼0.93 Ma, the mixing proportions of source components changed with a MORB-related mantle component becoming increasingly important as eruption age decreased.

Hawaii↗

Multiphase inclusions in plagioclase from anorthosites in the Stillwater Complex, Montana: implications for the origin of the anorthosites

Multiphase inclusions, consisting of clinopyroxene+ilmenite+apatite, occur within cumulus plagioclase grains from anorthosites in the Stillwater Complex, Montana, and in other rocks from the Middle Banded series of the intrusion. The textures and constant modal mineralogy of the inclusions indicate that they were incorporated in the plagioclase as liquid droplets that later crystallized rather than as solid aggregates. Their unusual assemblage, including a distinctive manganiferous ilmenite and the presence of baddeleyite (ZrO2), indicates formation from an unusual liquid. A process involving silicater liquid immiscibility is proposed, whereby small globules of a liquid enriched in Mg, Fe, Ca, Ti, P, REE, Zr and Mn exsolved from the main liquid that gave rise to the anorthosites, became trapped in the plagioclase, and later crystallized to form the inclusions. The immiscibility could have occurred locally within compositional boundaries around crystallizing plagioclase grains or it could have occurred pervasively throughout the liquid. It is proposed that the two immiscible liquids were analogous, n terms of their melt structures, to immiscible liquid pairs reported in the literature both in experiments and in natural basalts. For the previously reported pairs, immiscibility is between a highly polymerized liquid, typically granitic in composition, and a depolymerized liquid, typically ferrobasaltic in composition. In the case of the anorthosites, the depolymerized liquid is represented by the inclusions, and the other liquid was a highly polymerized aluminosilicate melt with a high normative plagioclase content from which the bulk of the anorthosites crystallized. Crystallization of the anorthosites from this highly polymerized liquid accounts for various distinctive textural and chemical features of the anorthosites compared to other rocks in the Stillwater Complex. A lack of correlation between P contents and chondrite-normalized rare earth element (REE) ratios of plagioclase separates indicates that the amount of apatite in the inclusions is too low to affect the REE signature of the plagioclase separates. Nevertheless, workers should use caution when attempting REE modelling studies of cumulates having low REE contents, because apatite-bearing inclusions can potentially cause problems. ?? 1993 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

Hydrothermal alteration and mass exchange in the hornblende latite porphyry, Rico, Colorado

The Rico paleothermal anomaly, southwestern Colorado, records the effects of a large hydrothermal system that was active at 4 Ma. This hydrothermal system produced the deep Silver Creek stockwork Mo deposit, which formed above the anomaly's heat source, and shallower base and precious-metal vein and replacement deposits. A 65 Ma hornblende latite porphyry is present as widespread sills throughout the area and provided a homogenous material that recorded the effects of the hydrothermal system up to 8 km from the center. Hydrothermal alteration in the latite can be divided into a proximal facies which consists of two assemblages, quartz-illite-calcite and chlorite-epidote, and a distal facies which consists of a distinct propylitic assemblage. Temperatures were gradational vertically and laterally in the anomaly, and decreased away from the centra heat source. A convective hydrothermal plume, 3 km wide and at least 2 km high, was present above the stock-work molybdenum deposit and consisted of upwelling, high-temperature fluids that produced the proximal alteration facies. Distal facies alteration was produced by shallower cooler fluids. The most important shallow base and precious-metal vein deposits in the Rico district are at or close to the boundary of the thermal plume. Latite within the plume had a large loss of Na2O, large addition of CaO, and variable SiO2 exchante. Distal propylitized latite samples lost small amounts of Na2O and CaO and exchanged minor variable amounts of SiO2. The edge of the plume is marked by steep Na2O exchange gradients. Na2O exchange throughout the paleothermal anomaly was controlled by the reaction of the albite components in primary plagioclase and alkali feldspars. Initial feldspar alteration in the distal facies was dominated by reaction of the plagioclase, and the initial molar ratio of reactants (alkali feldspar albite component to plagioclase albite component) was 0.35. This ratio of the moles of plagioclase to alkali feldspar albite components that reacted evolved to 0.92 as the reaction progressed. Much of the alkali feldspar albite component in the proximal facies reacted while the, primary plagioclase was still unreacted, but the ratio for these assemblages increased to 1.51 when the plagioclase entered the reaction paragenesis. Plagioclase reaction during distal propylitic alteration resulted in pseudomorphic albite mixed with illite and a loss of Na2O. CaO is lost in the distal facies as hornblende reacts to chlorite, although some calcium may be fixed in calcite. CaO is added to the proximal facies as the quantity of chlorite replacing hornblende increases and epidote and calcite are produced. ?? 1994 Springer-Verlag.

Contributions to Mineralogy and Petrology↗