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Projecting stream water quality using Weighted Regression on Time, Discharge, and Season (WRTDS): An example with drought conditions in the Delaware River Basin

Future water availability depends on understanding the responses of constituent concentrations to hydrologic change. Projecting future water quality remains a methodological challenge, particularly when using discrete observations with limited temporal resolution. This study introduces Weighted Regression on Time, Discharge, and Season for Projection (WRTDS-P), a novel, computationally efficient method that enables the projection of daily stream water quality under varying hydrologic conditions using commonly available discrete monitoring data. WRTDS-P model performance was validated using 39 sites in the Delaware River Basin (DRB) and four key constituents: specific conductance (SC), nitrate (NO 3 − ), magnesium (Mg 2+ ) and calcium (Ca 2+ ). Projections were tested against holdout data from the final 1 to 5 years of each time series, demonstrating robust predictive capability, with median Nash-Sutcliffe efficiencies of 0.67 for SC, 0.56 for NO 3 − , 0.65 for Ca 2+ , and 0.79 for Mg 2+ . Model uncertainty was correlated with indicators of hydrologic or geochemical mass-sinks, such as groundwater storage and adsorption in wetland soils. Drought scenario analyses for SC used ranges of reduced discharge including flows from the 1965 drought of record. Scenarios predicted widespread increases of SC, especially in southern DRB streams where baseline SC levels are already elevated. Fractional increases of SC were more uniformly distributed, indicating potential risk to sensitive ecosystems. Notably, drought-induced SC increases were positively correlated with interannual SC trends, indicating that hydrologic extremes could exacerbate ongoing salinization. This work provides a transferable and interpretable framework for projecting future water quality and assessing hydrologic risk to water resources and aquatic ecosystems.

Delaware, New Jersey, New York, Pennsylvania

Four-band image mosaic of the Colorado River Corridor downstream of Glen Canyon Dam in Arizona, derived from the May 2021 airborne image acquisition

In May 2021, the U.S. Geological Survey’s Grand Canyon Monitoring and Research Center acquired airborne multispectral high-resolution data for the Colorado River in the Grand Canyon, Arizona. The image data, which consist of four spectral bands (red, band 1; green, band 2; blue, band 3; and near infrared, band 4) with a ground resolution of 20 centimeters, are available as 16-bit unsigned-integer GeoTIFF files in Sankey and others (2024) (available online at https://doi.org/10.5066/P9BBGN6G ). The image files are projected in the State Plane Coordinate System, using the central Arizona zone (202) with the North American Datum of 1983 National Adjustment of 2011. The assessed spatial accuracy for these data is based on 47 ground-control points that were independent from the ground-control points used by the contractor for aerotriangulation and is reported at the 95-percent confidence level as 0.514 meter (m) and a root mean square error of 0.297 m. The intended uses of this dataset are primarily in support of scientific research and monitoring applications. Examples of these applications include high-resolution spatial and temporal change detection of the river channel, geomorphic landforms, riparian vegetation, and backwater and nearshore habitat, as well as other ecosystem-wide mapping. These imagery data also serve as reference material for field science mission planning, as base data for field data collection including community science activities, and as a highly detailed guide for technical boat operation during science activities such as reconnaissance for nighttime missions and navigating rapids during low flows.

Arizona, Nevada, Utah

Advancing subsurface investigations beyond the borehole with passive seismic horizontal-to-vertical spectral ratio and electromagnetic geophysical methods at transportation infrastructure sites in New Hampshire

The U.S. Geological Survey (USGS), in cooperation with the New Hampshire Department of Transportation (NHDOT), surveyed transportation infrastructure sites using rapidly deployable geophysical methods to assess benefits added to a comprehensive site characterization with traditional geotechnical techniques. Horizontal-to-vertical spectral-ratio (HVSR) passive-seismic and electromagnetic-induction (EMI) methods were applied at 4 sites including a roadway-stream crossing, roadway-bridge rail-trail crossing, commuter-parking expansion, and a railroad-adjacent river-cutbank slope-failure site. Additionally, ground-penetrating-radar (GPR) was used at the slope-failure site. Typically, subsurface geotechnical properties are determined from boring data; however, borings are often spaced hundreds of feet apart, potentially missing important spatial variability between boreholes. Geotechnical site characterization including geophysical surveys helped provide a more accurate characterization by using continuous or near continuous profiling. Three-component ambient noise measured with HVSR methods were used to determine resonance frequency and estimate sediment thickness. The method works when there is a strong shear-wave acoustic impedance contrast (> 2:1) between sediment and bedrock. Sediment thickness estimates from HVSR measurements were combined with boring data to make detailed maps of the bedrock surface altitude. The bulk electrical conductivity of the subsurface was indirectly measured with EMI methods and was used to identify lithologic variations, shallow bedrock, and conductive groundwater. Ground penetrating radar, which transmits pulses of electromagnetic energy into the subsurface and records the amplitude and timing of reflected signals, was used to identify bedding and changes in lithology or water content. By combining geophysical and boring data analyses, transportation projects produced more spatially comprehensive representations of geotechnical subsurface conditions than would be determined using conventional borings alone.

New Hampshire

Influence of new residential construction varying in housing density on bird species, human tolerance guilds, and communities

Human population growth and changing settlement patterns fuel the development of urban fringe lands worldwide, with implications for biodiversity. We conducted a 12-year study of birds in the fast-developing urban fringe lands of the central Puget Sound region, Washington, USA, to examine the effect of development configuration on birds. We hypothesized that lower-intensity conservation developments, compared to higher-intensity planned community developments, would benefit the overall bird community, as well as native forest birds (avoiders of human development) and avian generalist species (adapters to human development), but that higher-intensity planned community developments would benefit synanthropic species (exploiters of human development). We fit single-species and multi-species occupancy models to test these hypotheses. Consistent with our hypotheses, we found that a greater proportion of the overall community, avoiders, and adapters occupied lower-intensity conservation developments compared to higher-intensity planned community developments. However, we did not detect an effect of development type on the exploiter guild, and we found that species in the exploiter guild are variable in their response to the configuration of suburban developments. We also hypothesized that human tolerance guilds would be a useful predictor of individual species responses to development type. This hypothesis was somewhat supported: we found that, for avoiders, 87% of species in the guild had the same response to development type as the overall guild; for adapters, 63% had the same response as the overall guild, and for exploiters, only 44% had the same response as the overall guild. Our results indicate that the configuration of suburban developments can have a meaningful impact on bird communities, particularly on those species that are most sensitive to any level of development.

Washington

Evidence of mineral alteration in a salt marsh subterranean estuary: Implications for carbon and trace element cycling

Subterranean estuaries (STE) in salt marshes are biogeochemically active zones where interactions between terrestrial groundwater and seawater drive complex cycling of carbon and trace elements, influenced by mineral dissolution. These systems, characterized by fine-grained organic-rich peat overlying permeable coastal aquifers, play a crucial role as a blue carbon sink, yet their geochemical dynamics remain poorly understood. We investigated dissolved trace elements, carbon, silica, and radium isotopes in a salt marsh STE (Sage Lot Pond, Waquoit Bay, MA) over seasonal and annual cycles. Our results reveal that groundwater and estuarine water circulation through marsh peat and aquifer sediments leads to enrichments of dissolved organic and inorganic carbon (DOC and DIC), Si, Ba, and Mn, with variable source/sink behavior of Fe and net removal of U. Submarine groundwater discharge dominated Ba fluxes, whereas pore water drainage from marsh peat acted as the main sink for U and source of Si. Fe cycling was variable, with terrestrial Fe largely removed as groundwater passed through the STE, consistent with Fe-sulfide and amorphous phase formation. Radium isotope ratios identified two distinct subsurface flow pathways, influenced by metal-oxide cycling and organic matter breakdown. Si production was decoupled from DIC, suggesting Si originates from mineral alteration, whereas DIC results from both mineral weathering and microbial respiration. Silicate mineral alteration, coupled with marsh pore water drainage, accounts for up to 16% of annual DIC exports (66 g C m −2 y −1 ), highlighting the importance of STEs in coastal carbon and trace element cycling, especially as marshes face environmental change.

Massachusetts

Static and dynamic strain in the 1886 Charleston, South Carolina, earthquake

During the 1886 Mw 7.3 Charleston, South Carolina, earthquake, three railroads emanating from the city were exposed to severe shaking. Expansion joints in segmented railroad tracks are designed to allow railroad infrastructure to withstand a few parts in 10,000 of thermoelastic strain. We show that, in 1886, transient contractions exceeding this limiting value buckled rails, and transient extensions pulled rails apart. Calculated values for dynamic strain in the meizoseismal region are in reasonable agreement with those anticipated from the relation between strain and moment magnitude proposed by Barbour et al. (2021) and exceed estimated tectonic strain released by the earthquake by an order of magnitude. Almost all of the documented disturbances of railroad lines, including evidence for shortening of the rails, can thus be ascribed to the effects of dynamic strain changes, not static strain. Little or no damage to railroads was reported outside the estimated 10 −4 dynamic strain contour. The correspondence between 10 −3 and 2×10 −4 contours of dynamic strain and Mercalli intensity 9 and 8, anticipated from the dependence of each quantity on peak ground velocity, suggests it may be possible to use railroad damage to quantitatively estimate shaking intensity. At one location, near Rantowles, ≈20 km west of Charleston, a photograph of buckled track taken one day after the earthquake has been cited as evidence for shallow dextral slip and has long focused a search for a causal fault in this region. Photogrammetric analysis reveals that the buckle was caused by transient contraction of <10 cm with no dextral offset. Our results further weaken the evidence for faulting in the swamps and forests south of the Ashley River in 1886, hitherto motivated by the photograph and limited macroseismic evidence for high‐intensity shaking.

South Carolina

Assessing legacy nitrogen in groundwater using numerical models of the Long Island aquifer system, New York

Nitrogen transported along groundwater flow paths in coastal aquifers can contribute substantially to nitrogen loading into surface water receptors, particularly in hydrologic systems dominated by groundwater discharge. Nitrogen entrained in the aquifer is a function of land use and associated nitrogen sources at the time of groundwater recharge, which may differ considerably from present-day sources. Legacy nitrogen can result in substantial discrepancies between observed present-day nitrogen loading to surface water receptors and loading estimated from present-day sources. Additionally, legacy nitrogen can continue to discharge into surface waters after nitrogen mitigation actions have been undertaken. Here, we use a numerical modeling framework to compare three methods of estimating time-varying historical nitrogen loads to four water bodies (receptors) on eastern Long Island, New York. The methods span a range of data requirements and process complexity, from instantaneous receptor loads calculated from steady-state groundwater contributing areas, to transient loads estimated by explicitly simulating legacy groundwater nitrogen transport over a century with large changes in nitrogen sources and hydrologic conditions. The effects of legacy nitrogen on estimated receptor loads varied temporally and spatially within the study area. Depending on antecedent nitrogen inputs and hydrologic conditions, historical annual nitrogen loads estimated from transient simulations accounting for legacy nitrogen can be quite similar (<10% difference) or substantially different (±100%) from those estimated from simpler instantaneous methods. Continued input of present-day nitrogen sources using methods that account for legacy nitrogen results in asymptotic increases in receptor nitrogen loads over time, indicating that simulated present-day receptor nitrogen loads are not in equilibrium with present-day inputs. For these receptors in disequilibrium, models simulating transient groundwater nitrogen transport could be used to account for legacy nitrogen lag times to help resource managers evaluate the potential effectiveness of proposed nitrogen mitigation actions.

EarthArXiv

Riverscape heterogeneity shapes population diversity for a migratory fish

Habitat patch dynamics can scale up to influence population demography and diversity with implications for resilience to environmental stochasticity. But how the spatial arrangement and size of habitat patches interact with other components of habitat heterogeneity to shape population diversity at larger spatial scales is not well understood. For riverine fishes, there is increasing evidence that tributary streams provide critical demographic support to main stem rivers. However, the extent to which main stem rivers rely on demographic contributions from tributaries, and the factors underlying this dependence, have not been assessed. Here, we used genetic stock identification to evaluate the effect of tributaries on population diversity of Yellowstone cutthroat trout ( Oncorhynchus virginalis bouvieri ) occupying the main stem Snake River, Wyoming, USA. We found that the main stem relied almost entirely on tributaries for demographic support, but main stem composition varied spatially among river sections. Distance between habitat patches, catchment area, and groundwater availability acted in concert to determine the contribution of specific tributaries to the main stem, but contributions were ultimately modulated by habitat connectivity. We also found evidence for multi-scale spatial structure in tributary contributions, providing insight into untested drivers of main stem river population diversity. Our results demonstrate how spatially discrete and distributed riverscape attributes influence population diversity at broader spatial scales, illustrating how ecosystem resilience emerges from the dynamic, two-way exchange of individuals and energy across habitat networks. Management plans for large rivers that address the ecological contributions of tributaries may be needed to achieve optimal outcomes. Similarly, conservation strategies that exclusively focus on headwater streams may fail to capture the broader habitat requirements necessary to maintain robust cold-water fish populations and associated recreational fisheries, particularly under global environmental change.

Wyoming

Helium detection as a guide for uranium exploration

Helium, a byproduct of radioactive decay, may prove to be a valuable indicator of the presence and distribution of uranium deposits. Recent technological advances permit the development of instrumentation not previously adapted for this purpose. Commercially available equipment can provide high sensitivity at low cost and allow reasonable mobility for field use. A truck-mounted mass-spectrometer, tuned for helium-4, permits immediate adjustment or modification of sampling patterns in response to accumulating data. The inlet system of the spectrometer has been designed to allow flexibility in gas analyses from various sample types--soil gas, atmosphere, or gases in water. Sensitivity of the instrument is better than 50 parts of helium per 10 9 parts of gas. Replicate samples and standards can be analyzed in only 3 minutes. Helium in soil gas is being used for the initial evaluation of the technique. A hollow probe, as much as 2 m long, is driven into the ground; and a 10-cc syringe is used to purge the probe and extract the gas. This sample is then injected into the inlet system and introduced into the spectrometer at constant pressure. The output signal is displayed on a chart recorder. Investigations can be performed on a qualitative, relative basis, or on a quantitative basis by comparison to calibrated helium standards. Preliminary field testing includes studies of the responses to variations in wind speed, temperature, barometric pressure, moisture, and sampling depth over extended time periods, as well as studies of geologic controls on the helium content in soil gas. Surveys over known uranium occurrences reveal some anomalous helium distributions. This report describes an updated technological approach to an old idea: that of using helium, a byproduct of uranium radioactive decay, as an exploration tool for uranium. Helium is the sixth most abundant gas found in the earth's atmosphere (Table 1). It is an inert gas and very mobile, mixing rapidly. When the alpha particles from the radioactive decay of uranium and thorium pick up two electrons, atoms of the isotope helium-4 are formed. Several helium-4 atoms are produced from each decay series of U-238, U-235, and Th-232 (fig. 1). The half-lives of the parent isotopes are5also shown in figure 1. One gram of uranium will produce ~10 5 atoms of helium-4 per second, and one gram of thorium produces ~2.5 x 10 4 atoms of helium-4 per second (fig. 2). Calculations of the helium produced from the crust and mantle reveal that 1,125 x 10 30 atoms per year are produced, but only 7 x 10 30 atoms per year escape from the earth (Damon and Kulp, 1958). More is being produced than is being lost; in fact, the total atmospheric content of helium could be produced in only 2 million years (MacDonald, 1963)! However, all the crustal and mantle helium-4 does not degas into the atmosphere as it is formed. It is trapped in crystal lattices and in pore spaces within the earth. What this means is that there is excess helium-4 in the earth--excess, that is, compared to the atmospheric concentration in equilibrium with the helium-4 escape rate into space and the helium-4 flux from the crust and mantle (Nicolet, 1957). Near-surface pockets of high helium-4 concentrations are known, and some natural gas fields are so enriched that they are the source for commercial production of helium. Work by Roberts and others (1975) has shown high helium concentration in the soil gas associated with geothermal areas; and work by Clark and Kugler (1973), Dyck (1975), and Goldak (1974), for example, has noted high helium concentrations in soils and waters in the vicinity of uranium deposits. These latter studies certainly indicate the potential of helium detection for use as an exploration tool for uranium.

Open-File Report

Do Graviquakes exist?

The “Graviquake” model, proposed in 2015 as an alternative to the elastic dislocation model, posits that normal faults are passive features dominated by coseismic gravitational collapse into a dilated crustal wedge, and that normal faulting is fundamentally distinct from strike‐slip and reverse faulting. Developed using finite‐element modeling before the 2016 central Apennines earthquake sequence, the model was revamped based on interpreted Differential Interferometric Synthetic Aperture Radar data from these events and used as evidence for a gravitational collapse episode. However, this interpretation relies on miscalculated elevation changes and is not corroborated by independent geophysical and seismological observations. Our analysis exposes fundamental flaws in the Graviquake model. By assuming that faults are passive players, it underrepresents the dynamic role of strain accumulation and release in rocks adjacent to faults. The hypothesized rapid expulsion of overpressurized fluids appears inconsistent with observed diffusion rates and lacks supporting seismological evidence. Part of the uplifted–subsided volume imbalance is likely an artifact arising from data processing, and in part is a transient effect due to the delayed response of the lower crust. Moment tensor analyses detect no isotropic components indicative of gravitational collapse, and observed ground motion and stress‐drop levels remain fully consistent with elastic dislocation theory. In addition, finite‐element modeling of normal faulting replicates observed surface deformation without invoking a collapsing wedge. The Graviquake model proposes a representation of normal‐faulting mechanics that differs significantly from established models and observations. Gravity does play a role in normal faulting, but the elastic dislocation theory remains the definitive framework of fault mechanics. Reinterpreting the 2016 earthquakes as a cascade of gravitational episodes, based on incorrect data processing and modeling, fails to substantiate the Graviquake hypothesis. Persistence in advocating this model could mislead seismic hazard assessment and undermine our understanding of normal faulting.

Bulletin of the Seismological Society of America

Mapping eelgrass (Zostera marina) cover and biomass at Izembek Lagoon, Alaska, using in-situ field data and Sentinel-2 satellite imagery

The U.S. Geological Survey and the U.S. Fish and Wildlife Service have developed a three-tiered strategy for monitoring eelgrass ( Zostera marina ) beds at Izembek Lagoon, Alaska, that targets different spatial and temporal scales. The broadest-scale monitoring (tier-1) uses satellite imagery about every 5 years to delineate the spatial extent of eelgrass beds throughout the lagoon. This report describes the most recent (mid-2020s) tier-1 eelgrass monitoring at Izembek Lagoon. The monitoring effort began by canvasing all satellite imagery collected during summer, under clear daytime skies and at low-tide, since the last tier-1 effort in 2006. Two eelgrass maps of Izembek Lagoon were generated by first creating maps of spectrally unique classes from two Sentinel-2 satellite images collected on July 1, 2016, and August 14, 2020, then attributing those spectral classes with information about eelgrass conditions based on field data. Specifically, maps depicting various eelgrass metrics, such as percentage of cover and modeled biomass, were generated using summaries of the ground data that spatially intersected each spectral class. Comparisons of the 2016 and 2020 Sentinel-2 maps showing eelgrass distributional extent, as well as a 2006 Landsat map, indicated that areas where eelgrass presence may have declined during 2006–20 were most prevalent in the central part of Izembek Lagoon. More recently, during 2016-20, areas of possible biomass decline were more prevalent in the southern part of the lagoon. Monitoring eelgrass conditions at Izembek Lagoon with satellite imagery and concurrent ground data allows conditions to be compared over time, but the influences of tide levels, growing season phenology, and spatiotemporal co-registration accuracy should be considered when designing and interpreting change detection analyses.

Alaska

Quality of groundwater used for domestic supply in the Gilroy-Hollister basin and surrounding areas, California, 2022

More than 2 million Californians rely on groundwater from domestic wells for drinking-water supply. This report summarizes a 2022 California Groundwater Ambient Monitoring and Assessment Priority Basin Project (GAMA-PBP) water-quality survey of 33 domestic and small-system drinking-water supply wells in the Gilroy-Hollister Valley groundwater basin and the surrounding areas, where more than 20,000 residents are estimated to utilize privately owned domestic wells. The study area includes the Llagas subbasin in the north, the North San Benito subbasin in the south, and the surrounding uplands. The study was focused on groundwater resources used for domestic drinking-water supply, which are mostly drawn from shallower parts of aquifer systems rather than those of groundwater resources used for public drinking-water supply in the same area. This assessment characterized the quality of ambient groundwater in the aquifer before filtration or treatment, rather than the quality of drinking water delivered to the tap. To provide context, the measured concentrations of constituents in groundwater were compared to Federal and California State regulatory and non-regulatory benchmarks for drinking-water quality. A grid-based method was used to estimate the areal proportions of groundwater resources used for domestic drinking wells that have water-quality constituents present at high concentrations (above the benchmark), moderate concentrations (between one-half of the benchmark and the benchmark for inorganic constituents, or between one-tenth of the benchmark and the benchmark for organic constituents), and low concentrations (less than one-half or one-tenth the benchmark for inorganic and organic constituents, respectively). This method provides statistically representative results at the study-area scale and permits comparisons to other GAMA-PBP study areas. In the study area, inorganic constituents in groundwater were greater than regulatory benchmarks (U.S. Environmental Protection Agency [EPA] or State of California maximum contaminant levels [MCLs]) for public drinking-water quality in 24 percent of domestic groundwater resources. The inorganic constituents present at concentrations greater than MCLs for drinking water were nitrate (as nitrogen), barium, chromium, and selenium. Total dissolved solids (TDS) or manganese were present at concentrations greater than the secondary maximum contaminant levels (SMCLs) that the State of California uses as aesthetic-based benchmarks in 48 percent of domestic groundwater resources. No volatile organic compounds or pesticide constituents were present at concentrations greater than regulatory benchmarks. Total coliform bacteria and enterococci were detected in 4 percent of domestic groundwater resources. Per- and polyfluoroalkyl substances (PFAS) were detected in 19 percent of domestic groundwater resources, and 10 percent had concentrations greater than recently enacted (April 2024) EPA MCLs. Physical and chemical factors from natural and anthropogenic sources that could affect the groundwater quality were evaluated using results from statistical testing of associations between constituent concentrations and potential explanatory variables. In this study, relevant physical factors include well construction characteristics, groundwater age, site proximity to groundwater recharge or discharge zones, and potential sources of contamination. Relevant chemical factors include the initial chemistry of the recharge water, the mineralogy of the aquifer sediments, and the subsequent shifts in chemistry as biologic and geologic reactions alter groundwater in the subsurface. Nitrate concentrations were correlated to agricultural land use, distance from the boundary of the Gilroy-Hollister Valley groundwater basin, and the proportion of modern (post-1950s) water captured by the well. Denitrification under anoxic redox conditions can mitigate some nitrate derived from fertilizer application. Total dissolved solids primarily were derived from water-rock interactions with soils and aquifer materials in the study area, but there were high concentrations where agricultural practices contributed additional TDS. Mineralogy of aquifer sediments and rocks also affect barium, selenium, boron, and chromium concentrations in the Gilroy-Hollister Valley groundwater basin. PFAS were positively correlated with urban land use and the proportion of modern water captured by the well.

California

Using public participatory geographic information systems (PPGIS) to explore uses and values for Mojave Trails National Monument, California

Many people ascribe a variety of values to public lands and waters, but some values are more difficult to assess and quantify than others. Public participatory geographic information systems (PPGIS) are tools that have been used to help quantify and map the public’s diverse values for a landscape. This work describes the first known Office of Management and Budget–approved use of PPGIS by a Department of the Interior bureau. The U.S. Geological Survey developed an internet-based application to aid in gathering PPGIS data, called Values Mapping for Planning in Regional Ecosystems (VaMPIRE). Further, this work describes the first pilot of the VaMPIRE application in coordination with the Bureau of Land Management to collect spatial data and other survey data regarding the public’s uses of and values for locations within Mojave Trails National Monument. We emailed the link to the VaMPIRE application to an interested party email list in 2024 with 207 valid emails and received 74 responses; we also received 47 responses from members of an off-roading social media group. Of the list of 16 value options, recreation was the most popular value for the monument, followed by wilderness and inspirational. Over 1,000 points were placed throughout the monument, indicating locations people use or value, with the locations spread throughout the entire monument. Additionally, most survey respondents stated their ability to receive benefits in locations they mapped would not change in response to a hypothetical scenario related to recreational facility development. This report describes exploratory results from the first use of the VaMPIRE tool in Mojave Trails National Monument and includes reflections on how the process went and considerations for future use of VaMPIRE.

California

Pesticide occurrence in shallow groundwater in three regions of agricultural land use: Baldwin County, the Wiregrass region, and the Tennessee River valley region of Alabama, 2009–20

As part of a cooperative investigation between the U.S. Geological Survey and the Alabama Department of Agriculture and Industries, a network of 22 groundwater wells were sampled from 2014 through 2020 for about 230 pesticide and pesticide degradate compounds. Wells were located in three regions of intensive agricultural land use in Alabama: Baldwin County, the Wiregrass region, and the Tennessee River valley region. Metolachlor sulfonic acid, a degradate of the herbicide metolachlor, was the most frequently detected compound, occurring in about 70 percent of the samples. Three other compounds, metolachlor, atrazine, and 2-chloro-4-isopropylamino-6-amino-s-triazine, were also detected in more than half of the samples. Metolachlor and its degradates accounted for 33 of the 50 greatest compound concentrations study-wide, including the maximum pesticide concentration across all compounds (62,500 nanograms per liter). The frequency and magnitude of detections of many specific pesticide compounds varied among the three regions, but all detected pesticide concentrations were well below the U.S. Environmental Protection Agency maximum contaminant levels and applicable human health benchmarks. Sample results were combined with results of previous (2009–13) sampling to provide a continuous time-series of data for 2009–20. More than half of the 289 pesticide compounds analyzed during 2009–20 were not detected in any samples. Only four compounds were detected at great enough frequency throughout the 10 sampling years to evaluate patterns of change through time. Metolachlor and its degradate, metolachlor sulfonic acid, were frequently detected in all regions. Atrazine and its degradate, 2-chloro-4-isopropylamino-6-amino-s-triazine, were also detected in wells from all regions, but the variability and magnitude of concentrations were greatest in the Tennessee River valley region. No apparent temporal pattern in concentrations was found.

Alabama

Characterization of hydrogeologic units using matrix properties, Yucca Mountain, Nevada

Determination of the suitability of Yucca Mountain, in southern Nevada, as a geologic repository for high-level radioactive waste requires the use of numerical flow and transport models. Input for these models includes parameters that describe hydrologic properties and the initial and boundary conditions for all rock materials within the unsaturated zone, as well as some of the upper rocks in the saturated zone. There are 30 hydrogeologic units in the unsaturated zone, and each unit is defined by limited ranges where a discrete volume of rock contains similar hydrogeologic properties. These hydrogeologic units can be easily located in space by using three-dimensional lithostratigraphic models based on relation- ships of the properties with the lithostratigraphy. Physical properties of bulk density, porosity, and particle density; flow properties of saturated hydraulic conductivity and moisture-retention characteristics; and the state variables (variables describing the current state of field conditions) of saturation and water potential were determined for each unit. Units were defined using (1) a data base developed from 4,892 rock samples collected from the coring of 23 shallow and 8 deep boreholes, (2) described lithostratigraphic boundaries and corresponding relations to porosity, (3) recognition of transition zones with pronounced changes in properties over short vertical distances, (4) characterization of the influence of mineral alteration on hydrologic properties such as permeability and moisture-retention characteristics, and (5) a statistical analysis to evaluate where boundaries should be adjusted to minimize the variance within layers. This study describes the correlation of hydrologic properties to porosity, a property that is well related to the lithostratigraphy and depositional and cooling history of the volcanic deposits and can, therefore, be modeled to be distributed laterally. Parameters of the hydrogeologic units developed in this study and the relation of flow properties to porosity that are described can be used to produce detailed and accurate representations of the core-scale hydrologic processes ongoing at Yucca Mountain.

Nevada

Integration of rupture directivity models for the US National Seismic Hazard Model

Several rupture directivity models (DMs) have been developed in recent years to describe the near-source spatial variations in ground motion amplitudes related to propagation of rupture along the fault. We recently organized an effort towards incorporating these directivity effects into the USGS National Seismic Hazard Model (NSHM), by first evaluating the community's work and potential methods to implement directivity adjustments into probabilistic seismic hazard analysis (PSHA). Guided by this evaluation and comparison among the considered DMs, we selected an approach that can be readily implemented into the USGS hazard software, that provides an azimuthally varying adjustment to the median ground motion and its aleatory variability. This method allows assessment of the impact on hazard levels and provides a platform to test the DM amplification predictions using a generalized coordinate system, necessary for consistent calculation of source-to-site distance terms for complex ruptures. We give examples of the directivity-related impact on hazard, progressing from a simple, hypothetical rupture, to more complex fault systems, composed of multiple rupture segments and sources. The directivity adjustments were constrained to strike-slip faulting, where DMs have good agreement. We find that rupture directivity adjustments using a simple median and aleatory adjustment approach can impact hazard both from a site perspective and on a regional scale, increasing shaking off the end of the fault trace up to 30--40\% and potentially reducing it for sites along strike. Statewide hazard maps of California show that the change in shaking along major faults can be a factor to consider for assessing long-period (>ls) near-source effects within the USGS NSHM going forward, reaching up to 10--20\%. Finally, we suggest consideration of minimum parameter ranges and baseline requirements as future DMs are developed to minimize single approach adaptations, to enable more consistent application within both ground motion and hazard studies.

Earthquake Spectra

Alteration mapping in granitic gneiss using handheld geophysical and geochemical instruments: Implications for iron oxide-apatite and rare earth elements exploration

The Adirondack Mountains of New York, U.S.A. contain iron oxide-apatite (IOA) mineral deposits with variable concentrations of rare earth elements (REE). The IOA mineral deposits are typically hosted in the Lyon Mountain Granite Gneiss and are spatially correlated with extensive Na metasomatism (albitization) of the surrounding country rocks, although some mineral deposits also occur in metagabbro, paragneiss, and anorthosite hosts. The location of albitization zones is key to finding new IOA mineral deposits and better understanding the mineralization processes associated with their genesis. However, the Na alteration zones are generally not visibly identifiable in outcrop or hand specimens because the color and textural changes are subtle and are thus difficult to map. Here, we discuss the results from testing two spectroscopic techniques (handheld, field gamma-ray spectroscopy, and portable X-ray fluorescence (pXRF)) to characterize albitization zones surrounding IOA mineral deposits. The gamma-ray and pXRF spectrometers successfully distinguished the relative intensity of alteration in the Lyon Mountain Granite Gneiss based on the K abundance. The measured K content decreases towards the IOA mineral deposits, and the magnitude and width of the gradient are similar along the strike of each mineral deposit. Elevated Th and U values are present in host rocks adjacent to REE-bearing IOA mineral deposits. The pXRF and gamma-ray spectrometer K values are remarkably consistent with laboratory-based, whole-rock XRF compositional data and, therefore, useful for semi-quantitative analysis. Notably, albitization aureoles are consistent around REE-rich and REE-poor mineral deposits, suggesting that saline fluids are essential for the petrogenesis of IOA mineral deposits but may not be critical to REE mineralization. Ultimately, this study demonstrates the utility of handheld gamma-ray and pXRF spectrometry for identifying otherwise cryptic albitization gradients associated with IOA mineral deposits in granitic gneiss.

New York

Assessment of western Oregon debris-flow hazards in burned and unburned environments

In the steep and mountainous environment of western Oregon, debris flows pose a considerable threat to property, infrastructure and life. Wildfire is commonly known to increase the susceptibility of steep slopes to debris flows, but the extent of this process in the western Cascades is not well understood. The US Geological Survey (USGS) currently estimates postfire debris-flow likelihood and triggering rainfall thresholds using a model calibrated to a southern California inventory of debris flows generated by excess runoff within the first year after fire. Because of a lack of available data, this model has not been tested in western Oregon, or in locations where postfire debris flows initiate via other mechanisms (e.g., shallow landslides or in-channel failures). Using repeat field observations and aerial imagery, we developed two new debris-flow inventories within and adjacent to the perimeters of five 2020 wildfires in western Oregon: Archie Creek, Holiday Farm, Beachie Creek, Lionshead and Riverside. The first inventory focuses on postfire debris flows (2020–2022); the second focuses on debris flows prior to fires (1995–2020). Our inventories of prefire and postfire debris flows were used to document initiation mechanisms in Oregon's western Cascades and to evaluate the effects of wildfire. We found that wildfire changed the distribution of debris-flow initiation mechanisms in the western Cascades. After the wildfires, annual rates of runoff-generated debris flows increased by 22% and the number of shallow landslide-initiated debris flows decreased by 17% relative to before the wildfires. Despite this shift, shallow landsliding was the dominant debris-flow initiation mechanism in both unburned and burned environments. We found the performance of the current USGS debris-flow likelihood model was degraded relative to other previously tested locations across the intermountain western United States. Our results highlight the need for improved postfire hazard assessment in western Oregon based on regional model calibration that is tuned to the dominant debris-flow initiation mechanisms.

Oregon