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SUTRA— A code for simulation of saturated-unsaturated, variable-density groundwater flow with solute or energy transport—Documentation of the version 4.0 enhancements—Freeze-thaw capability, saturation and relative-permeability relations, spatially varying properties, and enhanced budget and velocity outputs

Version 4.0 of the Saturated-Unsaturated Transport (SUTRA) software code provides the capability to simulate the freezing and thawing of groundwater during energy transport simulations under saturated and unsaturated conditions. In addition to the types of hydrogeologic processes that SUTRA has been able to simulate in the past, this version can be used to study the effects of the freeze-thaw process on the flow and energy dynamics of hydrogeologic systems. The freeze-thaw simulation capability accounts for the latent heat of fusion and allows thermal property values to vary with changing total-water saturation, liquid-water saturation, and ice saturation. It allows the effective permeability of the porous medium to change as a result of freezing and thawing. This version also provides several user-selectable relations for the dependence of total-water saturation on fluid pressure, the dependence of liquid-water saturation on temperature during freezing and thawing, and the dependence of relative permeability on liquid saturation, as well as three user-selectable formulae for defining the bulk thermal conductivity of a mixture of solid grains, liquid water, ice, and air. For unsaturated simulations without freezing, the selectable total-water saturation relations eliminate the need for the user to program these and their associated relative-permeability functions, as had been required in previous SUTRA versions. Optional nonlinear dependence of fluid density on temperature, which covers the range from supercooled (about −50 degrees Celsius) to superheated (about 400 degrees Celsius), is also provided. Additionally, this version makes it possible to spatially vary parameters that, in previous versions of SUTRA, were required to be spatially uniform: solid-matrix properties, adsorption parameters, and parameters for production of solute mass or energy. Spatial variation is also allowed for the newly included freeze-thaw process parameters. Additional enhancements provide (1) output of water-mass and energy budgets that include values of all component terms in the governing balance equations, and (2) output of Darcy velocities (fluid fluxes), in addition to the velocity output provided by previous SUTRA versions. These enhanced outputs allow fuller interpretation of simulation results, especially for freeze-thaw phenomena. The set of processes simulated by this version of SUTRA are useful for studying a wide range of hydrogeologic system types, conditions, and questions. For cryohydrogeologic simulations, however, this version of the code is limited in that (1) it does not simulate thermomechanical effects of freeze-thaw, (2) pressure changes due to water density change during freezing are neglected, (3) ice saturation cannot exceed the initial porosity of the simulated medium, and (4) cryosuction, the migration of liquid water toward freezing fronts, is neglected. Furthermore, this version does not account for air flow or for water vaporization and sublimation under unsaturated conditions.

Techniques and Methods

Development of a hydrologic flow model of the Zuñi Salt Lake and surrounding areas, west-central New Mexico

The terminal Zuñi Salt Lake is in a maar in west-​central New Mexico and contains hypersaline water that has long been used by Native Americans for religious purposes and the collection of salt. The U.S. Geological Survey (USGS), in cooperation with the Zuni Tribe of the Zuni Reservation, New Mexico, and Bureau of Reclamation, developed the Zuñi Salt Lake hydrologic flow model to simulate the steady-state conditions of the lake and surrounding groundwater-flow system. The model is a tool that can be used to analyze the potential hydrologic responses to resource development in the region under different water-use scenarios, which can support negotiations that could help protect future use of the lake. The USGS modular hydrologic model, MODFLOW 6, was used to simulate the hydrologic system of the lake and surrounding areas. To define the layering of the model, a three-dimensional hydrogeologic framework was constructed, which included seven informal hydrogeologic units and the locations of faults that truncate and offset the units. Calibration of the model was performed using the iterative ensemble smoother included in a parameter estimation software suite (PEST++). The iterative ensemble smoother approach resulted in a posterior parameter ensemble of model realizations with parameter and simulated values that show similar success in matching observations. Groundwater flux to the Zuñi Salt Lake simulated by using the posterior parameter distribution ranged from 26 to 730 acre-feet per year with a mean, median, and standard deviation of 530, 570, and 170 acre-feet per year, respectively. The relative contribution of groundwater discharge to the lake was simulated using a particle-tracking model for MODFLOW (MODPATH) to be from, in order of decreasing contribution, the Mesaverde, Cenozoic, Mancos, and Dakota hydrogeologic units. Simulations of future conditions using the ensemble of models can provide an empirical estimate of forecast uncertainty without substantial additional analysis.

New Mexico

Summary of annual repeat magnetotelluric surveys of the Geysers geothermal field

As part of a multi-year project, funded by the California Energy Commission, annual magnetotelluric (MT) surveys have been collected at The Geysers geothermal field in northern California with the goal of measuring temporal changes within the steam field. The repeat surveys started in 2021 and repeated a 2017 survey (Peacock et al., 2020) with further extension to the southern part of the geothermal field. Temporal variations in the MT transfer functions are observed to be spatially coherent and compartmentalized. Mapping residual phase tensor ellipses demonstrates the direction of maximum change is often aligned with existing fracture orientations. Three dimensional inversion of the MT data, using the inversion results from previous years as the starting model, indicates that the steam reservoir has generally become more resistive over time (~10%), suggesting more steam in the field. A few pockets within the steam field have become more electrically conductive over time and are collocated with injection wells, suggesting either more fluid content in those zones, less steam, or more saline fluids.

California

Abandonment of the Upper Devonian Greenland Gap Group and Scherr Formation and revision of the Upper Devonian Brallier and Foreknobs Formations in the central Valley and Ridge Province

This study revises the lithostratigraphic framework of the Upper Devonian interval traditionally assigned to the Greenland Gap Group across the central Appalachian Valley and Ridge Province. The work aims to modernize and standardize lithostratigraphic nomenclature, establish a new reference section and demonstrate how the revised stratigraphy improves edge-matching of 1:24,000 scale geologic maps and supports compilation mapping at scales of 1:100,000 and larger. The revision eliminates the names Greenland Gap Group, Scherr Formation and the Minnehaha Springs Member of the Scherr Formation; reassigns all strata previously designated as Scherr Formation by Dennison (1970) to the upper Brallier Formation; and abandons the basal Mallow Member of the Foreknobs Formation, placing its strata within the upper Brallier as originally defined by Butts (1918). The contact between the Brallier and Foreknobs formations is placed at the base of the first mappable, ridge-forming package of fine- to coarse-grained, cross-bedded, sandstone beds, often containing rounded quartz pebbles with minor interbeds of shale and siltstone. This contact may be gradational in places but, even in absence of good exposure, can usually be distinguished topographically in recently produced lidar-derived imagery as having elevated relief due to the presence of more resistant, compositionally mature coarse-grained sandstone-rich strata. Applying this criterion for mapping the contact between the Brallier and Foreknobs formations has resulted in reconciliation of mismatches of geologic contacts along several 7.5-minute quadrangle boundaries in the states of Virginia, West Virginia, Maryland and Pennsylvania. A new reference section at Baker, West Virginia showcases the contacts between the Harrell Shale, Brallier Formation, Foreknobs Formation and Hampshire Formation. A digital outcrop model of the reference section is provided for future preservation.

Maryland, Pennsylvania, Virginia, West Virginia

Water use permits as of July 2024 and reported water use near the North Unit of Theodore Roosevelt National Park, North Dakota, 1980–2023

Starting in the early 2000s, increasing oil and gas development in western North Dakota created a need for additional water resources from surface-water and groundwater sources near the North Unit of Theodore Roosevelt National Park. To summarize the use of water in that area, the U.S. Geological Survey, in cooperation with the National Park Service, developed a map of surface-water and groundwater resources, aquifers, and water-use diversions, and plotted water-use trends from 1980 to 2023. Reported water used from permits in the map area has more than doubled since 2020, increasing from about 750 acre-feet in 2020 to about 2,300 acre-feet in 2022 and 2,000 acre-feet in 2023. Surface water provided the primary source of reported water used for the study period with an average of about 410 acre-feet per year from 1980 through 2017 and about 1,330 acre-feet per year from 2018 through 2023. After 2011, groundwater sourced from the Little Missouri River, Tobacco Garden Creek, Fox Hills, Fort Union, and Dakota aquifers became a larger portion of total annual reported water use from permits in the map area. From 1980 through 2015, water use for irrigation averaged 86 percent of the total annual reported surface-water and groundwater use in the map area. Starting in 2011, however, industrial uses became a proportionally larger total use of water, and in 2015, became the highest reported volume of water use in the map area. From 2011 to 2023, industrial use designated for water depots increased from 50 acre-feet to about 1,370 acre-feet, accounting for about 70 percent of total reported water use in the map area in 2023.

North Dakota

Geologic map of the northwest flank of Mauna Loa volcano, Island of Hawai‘i, Hawaii

Mauna Loa, the largest active volcano on Earth, has erupted 34 times since written descriptions became available in A.D. 1832. The most recent eruption of Mauna Loa occurred on November 27, 2022, after a 38 year hiatus; it lasted for 12 days. Some eruptions began with only brief seismic unrest, whereas others followed several months to a year of increased seismicity. Once underway, Mauna Loa’s eruptions can produce lava flows that may reach the sea in less than 24 hours, severing roads and utilities. For example, lava flows that erupted from the Southwest Rift Zone in 1950 advanced at an average rate of 9.3 kilometers per hour (5.8 miles per hour); all three lobes reached the ocean within ~24 hours. Near the eruptive vents, the flows likely traveled even faster. In terms of eruption frequency, pre-eruption warning, and rapid flow emplacement, Mauna Loa has great volcanic-hazard potential for the Island of Hawai‘i. Volcanic hazards on Mauna Loa can be anticipated, and risk substantially mitigated, by documenting its past activity to refine our knowledge of the hazards, and by alerting the public and local government officials of our findings and their implications for hazards assessments and risk. The map of the north and west flanks of Mauna Loa shows the distribution and relation of volcanic and surficial sedimentary deposits. It incorporates previously reported work published as generalized small-scale maps and a more detailed map. Within the mapped area, lava has flowed from three different source regions: the Northeast Rift Zone (22 percent), the summit (64 percent), and radial vents (14 percent). All three have different points of origin which, in turn, affect the flow characteristics and periodicity of activity. The map area includes the uppermost part of the NERZ and extends from the highest elevation––13,040 feet at the south end of the Kokoolau quadrangle, just below the summit caldera––to the sea northwest and west of the summit. Lava that erupts from the north and west flanks typically flows to the west, northwest, or north, depending on the vent location. Both morphologic lava flow types—‘a‘ā and pāhoehoe—are present. Pāhoehoe units tend to spread out or widen in low-slope regions, such as in the saddle regions between Mauna Loa and Mauna Kea or between Mauna Loa and Hualālai. In comparison, ʻaʻā flows generally produce narrower flow lobes that have higher relief. This map is the fifth in a series of five maps that will cover Mauna Loa volcano. NOTE: Map sheet 1 contains lines and type with overprint. This feature may be turned on or off in the Adobe Acrobat page display preferences.

Hawaii

Investigating the influence of climate and volcanic surface aging on fluvial erosion: A case study of Réunion Island, Indian Ocean

Precipitation is one of the dominant drivers of landscape erosion and evolution; however, the effects of typical rainfall compared with less frequent, high-magnitude precipitation events on erosion remain unclear. Volcanic islands are ideal locations to study such phenomena due to their simple geometries, nontectonic construction, and strong spatiotemporal rainfall gradients. However, spatial variation in surface age, created during their construction, often complicates their degradation histories by introducing temporal changes in erosion rates as drainage networks develop. Réunion Island (western Indian Ocean) presents a clear example of this, with an east–west gradient in both surface age and mean annual precipitation, as well as infrequent cyclones that alter the background rainfall pattern. In this study, we analyze the effects of surface age, average rainfall, and rainfall variability on basin development and fluvial erosion across the island. We calculate basin-averaged values of basin morphology, age, precipitation, river discharge, eroded volumes, and erosion rates, and use these to analyze the dominant drivers of landscape evolution through a series of correlation analyses. Our results indicate a temporal dependence on the influence of precipitation, with young surfaces being dominantly eroded by high-rainfall events and older surfaces eroded by mean annual rainfall patterns. Furthermore, we show that drainage development of shield volcanoes follows similar trends to other volcano types, and suggest that surface permeability and groundwater structure are important controls on runoff-driven erosion on shield volcanoes. These results add new components to the question of how precipitation impacts erosion.

Réunion Island

Site response in the Walnut Creek–Concord region of the San Francisco Bay, California: Ground motion amplification in a fault-bounded basin

Thirty‐seven portable accelerometers were deployed in the eastern San Francisco Bay communities of Walnut Creek and Concord to study site response in a fault‐bounded, urban, sedimentary basin. Local earthquakes were recorded for a period of two years from 2017 to 2019 resulting in 101 well‐recorded events. Site response is estimated by two methods: the reference site spectral ratio method and a source‐site spectral inversion method. The reference site spectral ratio method allows investigation of the variability of site amplification with source azimuth and frequency. The source‐site spectral inversion method yields the best least‐squares fit to site response for a database of ground‐motion records. Both methods show substantial amplification in the Walnut Creek–Concord basin below 2 Hz indicating strong surface‐wave development. Greater amplification is seen for sources aligned along the long axis of the basin. Inversion using close‐in sources at short distances yields lower amplification at longer periods than the entire data set due to reduced surface‐wave generation for steeper angles of incidence. Inversion of site response spectra for shallow shear‐wave velocity using a global search algorithm yields V S30 values consistent with generalized mapping results based on geology and topography but with greater variability due to local site variations. 3D finite‐element modeling shows greater amplification in the Walnut Creek–Concord basin with a basin‐edge effect likely contributing to higher ground motions. Topography is also seen to lead to increased scattering and shadowing effects.

California

Simulation of the impacts of spring diversions on streamflow in the Strawberry Creek watershed, San Bernardino County, California, using an integrated hydrological model

The Strawberry Creek watershed, in the San Bernardino Mountains of southern California, features a group of natural springs known as Arrowhead Springs that have been augmented with diversions in the form of sub-horizontal borings and tunnels. Understanding the effects of these structures on streamflow through groundwater capture is crucial for managing surface-water resources in this watershed. In this study, we constructed the Strawberry Creek integrated hydrological model to increase this understanding. The Strawberry Creek integrated hydrological model is an integrated surface runoff and groundwater model, GSFLOW to simulate surface runoff and infiltration and groundwater flow. The model has 263 rows and 176 columns in each of its three layers. The model area includes the Strawberry Creek and four adjacent watersheds. The precipitation-runoff modeling system was calibrated using two streamflow gaging stations, and the groundwater and surface-water flow model was calibrated to the reported spring diversion discharge and a sparse number of groundwater-level measurements. The Strawberry Creek integrated hydrological model was run with and without diversions active, and simulated streamflow was compared, indicating that in the headwaters of Strawberry Creek, about 35 percent of the diversion flow was captured from base flow.

California

Floods of February 1989 in Tennessee

Rainfall amounts of over 5 inches the night of February 13 and the morning of February 14, 1989, caused flooding in areas of Middle and West Tennessee. The towns of Lebanon in Middle Tennessee and Obion in West Tennessee were most severely affected. Most of the business district in Lebanon and many residential areas in Obion were flooded. Recurrence intervals for 24-hour rainfall totals were as high as 25 years at some sites but most peak discharges had recurrence intervals of less than 10 years. Rainfall amounts for the period February 13-20, 1989, peak stages and discharges for this flood, the peak of record, and a list of discharge measurements made during the flood are documented in this report.

Tennessee

Slip rate for the Rose Canyon fault through San Diego, California, based on analysis of GPS data: Evidence for a potential Rose Canyon–San Miguel-Vallecitos fault connection?

The Rose Canyon fault is the southern extension of the larger Newport–Inglewood–Rose Canyon fault system, which represents a major structural boundary in the Inner Continental Borderland (ICB) offshore of southern California. Ten to fifteen percent of total plate boundary motion in southern California is thought to be accommodated by the faults of the ICB, but the exact distribution of slip is uncertain. With an onshore segment, the Rose Canyon fault offers an opportunity to measure the slip rate using traditional geodetic methods. In this study, we use Global Positioning System (GPS) surface velocities from a combined campaign and continuous GPS network to constrain elastic models of the Rose Canyon fault. We then compare the observed surface velocities with proposed conceptual models of regional fault connections that facilitate the transfer of slip into the Rose Canyon fault to assess how well the observations are explained by the models. The results of elastic half‐space models suggest that the Rose Canyon fault may be slipping toward the higher end of geologic estimates, with the preferred model indicating a slip rate of 2.4 ± 0.5 mm/yr. Although limited in terms of near‐fault benchmarks, we find an improved model fit using an asymmetrical elastic half‐space model and a higher slip rate, suggesting a potential rheological contrast across the Rose Canyon fault, similar to observations from the northern Newport–Inglewood fault segments. Observed GPS surface velocities, background seismicity, and gravity anomalies south of San Diego Bay point toward a more easterly trace for the Rose Canyon fault, suggesting a possible connection with the San Miguel–Vallecitos fault system. Such a connection could increase the potential rupture lengths of future earthquakes and have important consequences for regional seismic hazards.

California

End-user needs for remote sensing wetlands of the Prairie Pothole Region of North America

The Prairie Pothole Region (PPR) of North America comprises globally important grassland and wetland ecosystems critical for numerous populations of migratory birds. Due to the importance of this region for migratory birds, and particularly waterfowl, and the threats of habitat loss due to intensifying agriculture, there is a mature and diverse system of conservation organizations, agencies, and partnerships that spends hundreds of millions of dollars annually on habitat conservation to support migratory bird populations. Remote sensing can be a powerful tool for observing and evaluating global change at large scales as well as expanding inferences from field studies to the broader landscape with statistical models. However, development and utilization of these tools has lagged behind their demand for several reasons, including concerns over spatial and temporal resolution and accuracy of products; perception of a misalignment with decision-maker needs; technological barriers such as skill sets of conservation professionals, computing resources, data access, and usability. In this report, we summarize the needs of conservation professionals and scientists who use or want to use remote sensing data products to inform science about wetland change and conservation of wetlands in the PPR. We assembled this information through several methods leading up to, during, and following a January 2026 PPR Wetland Remote Sensing Workshop. The workshop included United States and Canadian scientists, conservation professionals, and policy experts. Our goal was to bring together end-users and remote sensing product developers jointly to explore reducing the lag between product development and utilization of products to inform science and conservation. Specifically, we aimed to identify gaps in wetland remote sensing that limit effective monitoring, management, and conservation in the PPR, and to develop a framework that outlines pathways to address these gaps by fostering collaboration, improving communication networks, encouraging discussion, and building on existing and ongoing efforts. This report summarizes our participants’ descriptions of end-user needs and the outcomes of the workshop.

Prairie Pothole region

Effects of snowmobile use on snowpack chemistry in Yellowstone National Park, 1998

Snowmobile use in Yellowstone National Park has increased substantially in the past three decades. In areas of greatest snowmobile use, elevated levels of by-products of gasoline combustion such as ammonium and benzene have been detected in snowpack samples. Annual snowpacks and snow-covered roadways trap deposition from local and regional atmospheric emissions. Snowpack samples representing most of the winter precipitation were collected at about the time of maximum annual snow accumulation at a variety of locations in the park to observe effects of a range of snowmobile traffic levels. Concentrations of organic and inorganic compounds in snow samples from pairs of sites located directly in and off snow-packed roadways used by snowmobiles were compared to concentrations in samples collected at nearby off-road sites. Concentrations of ammonium were 2 to 5 times higher for the in-road snow compared to off-road snow for each pair of sites. Thus, concentrations decreased rapidly with distance from roadways. In addition, concentrations of ammonium, nitrate, sulfate, benzene, and toluene in snow were positively correlated with snowmobile use.

Wyoming

Bayesian ETAS modeling for the Pacific Northwest: Uncovering effects of tectonic regimes, regional differences, and swarms on aftershock parameters

The Pacific Northwest (PNW) of North America has high seismic hazard due to numerous earthquake sources under populated areas. It hosts several tectonic regimes and subregional seismic zones that are hypothesized to have different patterns of earthquake and aftershock occurrence. It is also predisposed to earthquake swarms, which can complicate the statistical modeling of these patterns. We present the first statistical seismicity model of the PNW catalog using the epidemic‐type aftershock sequence (ETAS) framework. We develop a Bayesian inference procedure that provides a stable estimation of both ETAS parameters and their uncertainties for different sets of PNW earthquakes, even those with very sparse catalogs. The Bayesian approach allows us to investigate how parameter estimates change between the intraslab and crustal tectonic regimes, the northern and southern PNW, and when swarms are included and excluded from the catalog. We also utilize our Bayesian framework to calculate parameter estimates under different prior beliefs about PNW seismicity, as well as to propagate catalog measurement errors into ETAS parameter estimates. We discuss the implications of parameter differences across the region for aftershock forecasting for the PNW.

Pacific Northwest

Simulation of the impacts of spring diversions on streamflow in the Strawberry Creek watershed, San Bernardino County, California, using an integrated hydrological model

The Strawberry Creek watershed, situated in the San Bernardino Mountains of southern California, features a group of natural springs known as Arrowhead Springs that have been augmented with diversions in the form of sub-horizontal borings and tunnels. Understanding the impact of these structures on streamflow through groundwater capture is crucial for managing surface-water resources in this watershed. In this study we constructed the Strawberry Creek integrated hydrological model (SCIHM) to increase this understanding. The SCIHM is an integrated surface runoff and groundwater model that uses the coupled groundwater and surface-water flow model (GSFLOW), which is based on the integration of the precipitation-runoff modeling system (PRMS) and the modular groundwater flow model commonly called MODFLOW, version MODFLOW-2005 software to simulate surface runoff and infiltration and groundwater flow. The model has three layers, 263 rows, and 176 columns. The model area includes the Strawberry Creek and four adjacent watersheds. The PRMS model was calibrated using two streamflow gaging stations and the GSFLOW model was calibrated to reported spring diversion discharge and a sparse number of groundwater-level measurements. The SCIHM was run with and without diversions active and simulated streamflow was compared, finding that in the headwaters of Strawberry Creek about 35 percent of the diversion flow was captured from base flow.

EarthArXiv

Resurvey of the Marble Canyon and Bridge Canyon dam sites in Grand Canyon National Park—Changes in sediment storage and evidence supporting the occurrence of bedrock incision through the mid-20th century

The Bureau of Reclamation developed an extensive plan for a network of dams, water tunnels, and hydropower plants in and around Grand Canyon, Arizona, in the 1940s through 1960s. The two largest of these planned dams were the Marble Canyon and Bridge Canyon Dams on the Colorado River. Though these dams were ultimately never built, Reclamation conducted extensive topographic, bathymetric, and subsurface exploration work at the sites proposed for these dams in the 1940s and 1950s. Resurveys of these dam sites were conducted between 1998 and 2021 to determine the changes in sediment storage at these dam sites caused by the upstream construction and operation of Glen Canyon Dam and by the recession of Lake Mead, the reservoir impounded by Hoover Dam. The resurveys of the Marble Canyon dam sites indicate that the post-1950s changes in sediment storage at these dam sites are broadly consistent with flux-based estimates of voluminous sand erosion from Marble Canyon since the 1963 closure of Glen Canyon Dam. These resurveys also suggest that the pre-dam longitudinal variation in sediment thickness over bedrock played a key role in determining the locations of the sand erosion induced by Glen Canyon Dam; more sand eroded from locations where more sand was present in the 1950s. The resurvey of the Bridge Canyon dam sites indicates that the Colorado River’s incision of the Lake Mead delta is regulated both by bed-sediment grain size and downstream hydraulic controls. Finally, analyses of bed-sediment thickness and sedimentological data at the dam sites, and observations of bed scour and gravel transport, suggest that sufficient bedrock was exposed to allow bedrock incision during commonly recurring pre-dam snowmelt floods that entrained small boulders into transport.

Arizona

Characterization of groundwater resources near the southeastern part of Puget Sound, Washington

More than 1 million people live within the active model area (AMA) in the southeastern part of the lowlands surrounding Puget Sound, or Puget Lowland, Washington, and groundwater is the source for approximately one-half of their public, domestic, and irrigation water demands. The 887-square-mile AMA, located in King and Pierce Counties, represents the area of analysis for the conceptual hydrogeologic framework and numerical groundwater-flow models within the study area and includes the Puyallup River and Chambers-Clover Creek watersheds. To assess the potential hydrologic and anthropogenic impacts to groundwater and the connected surface-water resources, conceptual and numerical groundwater-flow models of groundwater flow were developed by the U.S. Geological Survey Washington Water Science Center in close cooperation with 18 water-resource agencies and stakeholders. This multichapter volume documents the development of the conceptual and numerical groundwater-flow models of groundwater flow. Chapters A, B, and C provide an overall introduction to the multichapter volume (Chapter A), the conceptual hydrogeologic framework (Chapter B), and the groundwater budget (Chapter C). Chapters D and E describe numerical groundwater-flow model construction and calibration (Chapter D) and the numerical groundwater-flow model results (Chapter E). Collectively, these reports present a characterization and simulation tool for groundwater resources near the southeastern part of Puget Sound, Washington.

Scientific Investigations Report

Properties of solid bitumen formed during hydrous, anhydrous, and brine pyrolysis of oil shale: Implications for solid bitumen reflectance in source-rock reservoirs

Solid bitumen reflectance (BR o in %) is widely used as a thermal maturity proxy in source-rock reservoirs, yet solid bitumen texture and physical attributes may be affected by varying environmental constraints during its formation, e.g., water saturation, mineral catalysis, or salinity. Herein we investigated the development of solid bitumen properties during artificial maturation using three diverse (lacustrine to marine) oil shale samples containing abundant amorphous H-rich sedimentary organic matter (bituminite). The oil shales were treated via pyrolysis (320 °C, 72 h) using hydrous, anhydrous, and brine conditions, causing the development of a newly formed solid bitumen in the experiment residues from the thermal conversion of bituminite. The properties of the newly formed solid bitumen then were evaluated via geochemical screening tests, optical and electron microscopy, and infrared spectroscopy. Experimental residues also were treated via solvent extraction, allowing characterization of the effects of extraction on solid bitumen. Results showed that bituminite with higher resin and asphaltene components evolved to a solid bitumen with higher reflectance (as a percentage of the original value) when exposed to the same heat treatment, relative to bituminite with higher saturate and aromatic components. Aromatization of solid bitumen also was generally more pronounced in the presence of deionized water relative to anhydrous conditions, supporting prior observations. These results suggest the compositions of primary sedimentary organic matter, and the local concentration of water, affect the development of solid bitumen during thermal advance, potentially explaining the origin of multiple solid bitumen populations with varying reflectance in source-rock reservoir samples or in a single microscope field. Experiments using brine were inconclusive regarding enhanced/decreased aromatization, which could be attributed to the salinities of the brines used in the tests. Extraction of residues caused a consistent increase in BR o values, suggesting that migrating or expelled oils could cause an increase in BR o via natural solvation and absent an increase in temperature. This work provides insights into the development and evolution of BR o in source-rock reservoirs as a function of the composition of the original bituminite and changing environmental conditions, with potentially broad application for petroleum prospecting and resource estimation.

Colorado