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At least 631 records · Page 35Linked to original sources

Quantifying the stormwater runoff volume reduction benefits of urban street tree canopy

Trees in the urban right-of-way areas have increasingly been considered part of a suite of green infrastructure practices used to manage stormwater runoff. A paired-catchment experimental design (with street tree removal as the treatment) was used to assess how street trees affect major hydrologic fluxes in a typical residential stormwater collection and conveyance network. The treatment consisted of removing 29 green ash (Fraxinus pennsylvanica) and two Norway maple (Acer platanoides) street trees from a medium-density residential area. Tree removal resulted in an estimated 198 m3 increase in surface runoff volume compared to the control catchment over the course of the study. This increase accounted for 4% of the total measured runoff after trees were removed. Despite significant changes to runoff volume (p ≤ 0.10), peak discharge was generally not affected by tree removal. On a per-tree basis, 66 L of rainfall per m2 of canopy was lost that would have otherwise been intercepted and stored. Runoff volume reduction benefit was estimated at 6376 L per tree. These values experimentally document per-capita retention services rendered by trees over a growing season with 42 storm events. These values are within the range reported by previous studies, which largely relied on simulation. This study provides catchment scale evidence that reducing stormwater runoff is one of many ecosystem services provided by street trees. This study quantifies these services, based on site conditions and a mix of deciduous species, and serves to improve our ability to account for this important yet otherwise poorly constrained hydrologic service. Engineers, city planners, urban foresters, and others involved with the management of urban stormwater can use this information to better understand tradeoffs involved in using green infrastructure to reduce urban runoff burden.

Wisconsin↗

Effect of heat and singeing on stable hydrogen isotope ratios of bird feathers and implications for their use in determining geographic origin

Rationale Stable hydrogen isotope ( δ 2 H) ratios of animal tissues are useful for assessing movement and geographic origin of mobile organisms. However, it is uncertain whether heat and singeing affects feather δ 2 H values and thus subsequent geographic assignments. This is relevant for birds of conservation interest that are burned and killed at concentrating solar‐energy facilities that reflect sunlight to a receiving tower and generate a solar flux field. Methods We used a controlled experiment to test the effect of known heat loads (exposure to 200, 250 or 300°C for 1 min) on the morphology and δ 2 H values of feathers from two songbird species. Subsequently, we examined the effects of singeing on δ 2 H values of feathers from three other songbird species that were found dead in the field at a concentrating solar‐energy facility. Results Relative to control samples, heating caused visual morphological changes to feathers, including shriveling at 250°C and charring at 300°C. The δ 2 H values significantly declined by a mean of 27.8‰ in experimental samples exposed to 300°C. There was no statistically detectable difference between δ 2 H values of the singed and unsinged portions of field‐collected feathers from the same bird. Conclusions Limited singeing that did not dramatically alter the feather morphology did not substantially affect δ 2 H values of feathers from these songbirds. However, higher temperatures induced charring and reduced δ 2 H values. Therefore, severely charred feathers should be avoided when selecting feathers for δ 2 H‐based assessment of geographic origin.

Rapid Communications in Mass Spectrometry↗

Overwinter and prespawning movements by a vulnerable freshwater pelagophilic minnow

The decline of pelagophil minnows is related to river fragmentation across the southern Great Plains landscape. Because we know little about pelagophil movement patterns and timing, we aimed to quantify the movements of the vulnerable Arkansas River shiner (ARS) during the winter (November–March) and prespawning (April–June) seasons. We tagged 4233 ARS using visible implant elastomer, passive integrated transponder, or p-Chip micro-transponder tags in 2018–2020. We sampled to recapture tagged fish weekly during the winter and biweekly during the spring. Tagged fish exhibited a downstream movement bias and movement was weakly related to increasing temperature, discharge, and photoperiod during winter, however most of the variability was explained by a random individual effect. Larger individuals moved greater distances than smaller fish. Upstream movements by a migratory portion of the population appeared to begin around late February based on the presence of fish at previously unoccupied sites. However, the first long-distance (30-km) upstream movement by a tagged fish was documented in late May. We show evidence that some ARS may be resident fish at sites throughout winter and spring of multiple years. To conserve freshwater pelagophil minnows, our results indicate water management strategies improving river connectivity in late winter through the spawning season may benefit spawning by migratory individuals, whereas lateral connectivity might benefit the resident portion of the population. Research efforts under experimental flows could provide insight to improved recovery options.

Oklahoma↗

Cytonuclear genetics of experimental fish hybrid zones inside Biosphere 2

Two species of mosquitofish (family Poeciliidae ) known to hybridize in nature were introduced into freshwater habitats inside Biosphere 2, and their population genetics were monitored after 2 years. Within four to six generations, nuclear and cytoplasmic markers characteristic of Gambusia holbrooki had risen greatly in frequency, although some Gambusia affinis alleles and haplotypes were retained primarily in recombinant genotypes, indicative of introgressive hybridization. The temporal cytonuclear dynamics proved similar to population genetic changes observed in replicated experimental hybrid populations outside of Biosphere 2, thus indicating strong directional selection favoring G. holbrooki genotypes across the range of environments monitored. When interpreted in the context of species-specific population demographies observed previously, results suggest that the extremely rapid evolution in these zones of secondary contact is attributable primarily to species differences in life-history traits.

PNAS↗

Effects of resource chemistry on the composition and function of stream hyporheic biofilms.

Fluvial ecosystems process large quantities of dissolved organic matter as it moves from the headwater streams to the sea. In particular, hyporheic sediments are centers of high biogeochemical reactivity due to their elevated residence time and high microbial biomass and activity. However, the interaction between organic matter and microbial dynamics in the hyporheic zone remains poorly understood. We evaluated how variance in resource chemistry affected the microbial community and its associated activity in experimentally grown hyporheic biofilms. To do this we fed beech leaf leachates that differed in chemical composition to a series of bioreactors filled with sediment from a sub-alpine stream. Differences in resource chemistry resulted in differences in diversity and phylogenetic origin of microbial proteins, enzyme activity, and microbial biomass stoichiometry. Specifically, increased lignin, phenolics, and manganese in a single leachate resulted in increased phenoloxidase and peroxidase activity, elevated microbial biomass carbon:nitrogen ratio, and a greater proportion of proteins of Betaproteobacteria origin. We used this model system to attempt to link microbial form (community composition and metaproteome) with function (enzyme activity) in order to better understand the mechanisms that link resource heterogeneity to ecosystem function in stream ecosystems.

Frontiers in Microbiology↗

Detecting cover crop end-of-season using VENµS and sentinel-2 satellite imagery

Cover crops are planted during the off-season to protect the soil and improve watershed management. The ability to map cover crop termination dates over agricultural landscapes is essential for quantifying conservation practice implementation, and enabling estimation of biomass accumulation during the active cover period. Remote sensing detection of end-of-season (termination) for cover crops has been limited by the lack of high spatial and temporal resolution observations and methods. In this paper, a new within-season termination (WIST) algorithm was developed to map cover crop termination dates using the Vegetation and Environment monitoring New Micro Satellite (VENµS) imagery (5 m, 2 days revisit). The WIST algorithm first detects the downward trend (senescent period) in the Normalized Difference Vegetation Index (NDVI) time-series and then refines the estimate to the two dates with the most rapid rate of decrease in NDVI during the senescent period. The WIST algorithm was assessed using farm operation records for experimental fields at the Beltsville Agricultural Research Center (BARC). The crop termination dates extracted from VENµS and Sentinel-2 time-series in 2019 and 2020 were compared to the recorded termination operation dates. The results show that the termination dates detected from the VENµS time-series (aggregated to 10 m) agree with the recorded harvest dates with a mean absolute difference of 2 days and uncertainty of 4 days. The operational Sentinel-2 time-series (10 m, 4–5 days revisit) also detected termination dates at BARC but had 7% missing and 10% false detections due to less frequent temporal observations. Near-real-time simulation using the VENµS time-series shows that the average lag times of termination detection are about 4 days for VENµS and 8 days for Sentinel-2, not including satellite data latency. The study demonstrates the potential for operational mapping of cover crop termination using high temporal and spatial resolution remote sensing data.

Remote Sensing↗

The influence of precipitation, vegetation and soil properties on the ecohydrology of sagebrush steppe rangelands on the INL site

The INL Site and other landscapes having sagebrush steppe vegetation are experiencing a simultaneous change in climate and floristics that result from increases in exotic species. Determining the separate and combined/interactive effects of climate and vegetation change is important for assessing future changes on the landscape and for hydrologic processes. This research uses the 72 experimental plots established and initially maintained for many years as the “Protective Cap Biobarrier Experiment” by Dr. Jay Anderson and the Stoller ESER program, and the experiment is also now referred to as the “INL Site Ecohydrology Study.” We are evaluating long-term impacts of different plant communities commonly found throughout Idaho subject to different precipitation regimes and to different soil depths. Treatments of amount and timing of precipitation (irrigation), soil depth, and either native/perennial or exotic grass vegetation allow researchers to investigate how vegetation, precipitation and soil interact to influence soil hydrology and ecosystem biogeochemistry. This information will be used to improve a variety of models, as well as provide data for these models.

Report↗

Proceedings of the Fiscal Year 2022 Annual Reporting Meeting to the Glen Canyon Dam Adaptive Management Program

(Hartwell) This report is prepared primarily to account for work conducted and products delivered in FY 2022 by GCMRC and to inform the Technical Work Group of science conducted by GCMRC and its cooperators in support of the Glen Canyon Dam Adaptive Management Program (GCDAMP). It includes a summary of accomplishments, modifications to work plans, results, and recommendations related to projects included in GCMRC’s FY 2021-23 Triennial Work Plan. This work was done to support the 11 resource goals identified in the Glen Canyon Dam Long-Term Experimental and Management Plan (LTEMP) Environmental Impact Statement and Record of Decision (Table 1).

Arizona↗

Microforms in gravel bed rivers: Formation, disintegration, and effects on bedload transport

This research aims to advance current knowledge on cluster formation and evolution by tackling some of the aspects associated with cluster microtopography and the effects of clusters on bedload transport. The specific objectives of the study are (1) to identify the bed shear stress range in which clusters form and disintegrate, (2) to quantitatively describe the spacing characteristics and orientation of clusters with respect to flow characteristics, (3) to quantify the effects clusters have on the mean bedload rate, and (4) to assess the effects of clusters on the pulsating nature of bedload. In order to meet the objectives of this study, two main experimental scenarios, namely, Test Series A and B (20 experiments overall) are considered in a laboratory flume under well-controlled conditions. Series A tests are performed to address objectives (1) and (2) while Series B is designed to meet objectives (3) and (4). Results show that cluster microforms develop in uniform sediment at 1.25 to 2 times the Shields parameter of an individual particle and start disintegrating at about 2.25 times the Shields parameter. It is found that during an unsteady flow event, effects of clusters on bedload transport rate can be classified in three different phases: a sink phase where clusters absorb incoming sediment, a neutral phase where clusters do not affect bedload, and a source phase where clusters release particles. Clusters also increase the magnitude of the fluctuations in bedload transport rate, showing that clusters amplify the unsteady nature of bedload transport. A fourth-order autoregressive, autoregressive integrated moving average model is employed to describe the time series of bedload and provide a predictive formula for predicting bedload at different periods. Finally, a change-point analysis enhanced with a binary segmentation procedure is performed to identify the abrupt changes in the bedload statistic characteristics due to the effects of clusters and detect the different phases in bedload time series using probability theory. The analysis verifies the experimental findings that three phases are detected in the bedload rate time series structure, namely, sink, neutral, and source. ?? ASCE / JUNE 2004.

Journal of Hydraulic Engineering↗

Evaluation of catch-and-release regulations on Brook Trout in Pennsylvania streams

In 2004, the Pennsylvania Fish and Boat Commission implemented catch-and-release (CR) regulations on headwater stream systems to determine if eliminating angler harvest would result in an increase in the number of adult (≥100 mm) or large (≥175 mm) Brook Trout Salvelinus fontinalis . Under the CR regulations, angling was permitted on a year-round basis, no Brook Trout could be harvested at any time, and there were no tackle restrictions. A before-after–control-impact design was used to evaluate the experimental regulations. Brook Trout populations were monitored in 16 treatment (CR regulations) and 7 control streams (statewide regulations) using backpack electrofishing gear periodically for up to 15 years (from 1990 to 2003 or 2004) before the implementation of the CR regulations and over a 7–8-year period (from 2004 or 2005 to 2011) after implementation. We used Poisson mixed models to evaluate whether electrofishing catch per effort (CPE; catch/100 m 2 ) of adult (≥100 mm) or large (≥175 mm) Brook Trout increased in treatment streams as a result of implementing CR regulations. Brook Trout CPE varied among sites and among years, and there was no significant effect (increase or decrease) of CR regulations on the CPE of adult or large Brook Trout. Results of our evaluation suggest that CR regulations were not effective at improving the CPE of adult or large Brook Trout in Pennsylvania streams. Low angler use, high voluntary catch and release, and slow growth rates in infertile headwater streams are likely the primary reasons for the lack of response.

Pennsylvania↗

Silicic lunar volcanism: Testing the crustal melting model

Lunar silicic rocks were first identified by granitic fragments found in samples brought to Earth by the Apollo missions, followed by the discovery of silicic domes on the lunar surface through remote sensing. Although these silicic lithologies are thought to make up a small portion of the lunar crust, their presence indicates that lunar crustal evolution is more complex than originally thought. Models currently used to describe the formation of silicic lithologies on the Moon include in situ differentiation of a magma, magma differentiation with silicate liquid immiscibility, and partial melting of the crust. This study focuses on testing a crustal melting model through partial melting experiments on compositions representing lithologies spatially associated with the silicic domes. The experiments were guided by the results of modeling melting temperatures and residual melt compositions of possible protoliths for lunar silicic rocks using the thermodynamic modeling software, rhyolite-MELTS. Rhyolite-MELTS simulations predict liquidus temperatures of 950–1040 °C for lunar granites under anhydrous conditions, which guided the temperature range for the experiments. Monzogabbro, alkali gabbronorite, and KREEP basalt were identified as potential protoliths due to their ages, locations on the Moon (i.e., located near observed silicic domes), chemically evolved compositions, and the results from rhyolite-MELTS modeling. Partial melting experiments, using mixtures of reagent grade oxide powders representing bulk rock compositions of these rock types, were carried out at atmospheric pressure over the temperature range of 900–1100 °C. Because all lunar granite samples and remotely sensed domes have an elevated abundance of Th, some of the mixtures were doped with Th to observe its partitioning behavior. Run products show that at temperatures of 1050 and 1100 °C, melts of the three protoliths are not silicic in nature (i.e., they have <63 wt% SiO 2 ). By 1000 °C, melts of both monzogabbro and alkali gabbronorite approach the composition of granite, but are also characterized by immiscible Si-rich and Fe-rich liquids. Furthermore, Th strongly partitions into the Fe-rich, and not the Si-rich glass in all experimental runs. Our work provides important constraints on the mechanism of silicic melt formation on the Moon. The observed high-Th content of lunar granite is difficult to explain by silicate liquid immiscibility, because through this process, Th is not fractionated into the Si-rich phase. Results of our experiments and modeling suggests that silicic lunar rocks could be produced from monzogabbro and alkali gabbronorite protoliths by partial melting at T < 1000 °C. Additionally, we speculate that at higher pressures ( P ≥ 0.005 GPa), the observed immiscibility in the partial melting experiments would be suppressed.

American Mineralogist↗

Molecular orbital (SCF-Xα-SW) theory of metal-metal charge transfer processes in minerals

A number of mixed valence iron oxides and silicates (e.g., magnetite, ilvaite) exhibit thermally induced electron delocalization between adjacent Fe 2+ and Fe 3+ ions and optically induced electronic transitions which are assigned to Fe 2+ &rarr;Fe 3+ intervalence charge transfer. In this paper, the mechanism of electron delocalization (i.e., polarons versus itinerant electrons) and the nature of optically induced intervalence charge-transfer in minerals are investigated using molecular orbital theory. SCF-X&alpha;-SW molecular orbital calculations were done for several mixed-valence (Fe 2 O 10 ) 15&minus; clusters corresponding to edgesharing Fe 2+ and Fe 3+ coordination polyhedra. A spinunrestricted formalism was used so that the effect of ferromagnetic versus antiferromagnetic coupling of adjacent Fe 2+ and Fe 3+ cations could be determined. The molecular orbital results can be related to the polaron theory of solid state physics and the perturbation theory formalism used by Robin and Day (1967) and others to describe electron transfer in mixed valence compounds. Intervalence charge-transfer results from the overlap of Fe(3d) orbitals across the shared edges of adjacent FeO 6 polyhedra to give weak Fe-Fe bonds. Electron delocalization, however, requires that adjacent Fe cations be ferromagnetically coupled. Antiferromagnetic coupling results in distinguishable Fe 2+ and Fe 3+ cations. Electronic transitions between the Fe-Fe bonding and Fe-Fe antibonding orbitals results in the optically-induced intervalence charge transfer bands observed in the electronic spectra of mixed valence minerals. Such transitions are predicted to be polarized along the metal-metal bond direction, in agreement with experimental observations.

Physics and Chemistry of Minerals↗

Enhanced precipitation promotes decomposition and soil C stabilization in semiarid ecosystems, but seasonal timing of wetting matters

Aims Changing precipitation regimes in semiarid ecosystems will affect the balance of soil carbon (C) input and release, but the net effect on soil C storage is unclear. We asked how changes in the amount and timing of precipitation affect litter decomposition, and soil C stabilization in semiarid ecosystems. Methods The study took place at a long-term (18 years) ecohydrology experiment located in Idaho. Precipitation treatments consisted of a doubling of annual precipitation (+200 mm) added either in the cold-dormant season or in the growing season. Experimental plots were planted with big sagebrush ( Artemisia tridentata ), or with crested wheatgrass ( Agropyron cristatum ). We quantified decomposition of sagebrush leaf litter, and we assessed organic soil C (SOC) in aggregates, and silt and clay fractions. Results We found that: (1) increased precipitation applied in the growing season consistently enhanced decomposition rates relative to the ambient treatment, and (2) precipitation applied in the dormant season enhanced soil C stabilization. Conclusions These data indicate that prolonged increases in precipitation can promote soil C storage in semiarid ecosystems, but only if these increases happen at times of the year when conditions allow for precipitation to promote plant C inputs rates to soil.

Plant and Soil↗

Patterns of denitrification potential in tidal freshwater forested wetlands

Limited evidence for spatial patterns of denitrification in tidal freshwater forested wetlands (TFFWs), seemingly due to high spatial variability in the process, is surprising considering the various spatial gradients of its biogeochemical and hydrogeomorphic controls in these ecosystems. Because certain physical environmental gradients may be useful for the prediction of denitrification in TFFWs, we measured denitrification and ecosystem attributes in hummock-hollow microtopography of TFFWs along longitudinal riverine positions (upper, middle, and lower tidal river sites, and nearby upstream nontidal forested floodplains) of the adjoining Pamunkey and Mattaponi Rivers, Virginia. We tested differences by river, site, and plot in denitrification enzyme activity (DEA) and substrate limitations of denitrification potential (DP). The Pamunkey River carries greater river nitrate concentrations, and we found less nitrate limitation of DP and greater soil nitrate in hollows of this river. DEA in tidal hummocks was positively correlated with soil organic matter, nitrogen, and carbon, with the highest rates in lower tidal sites. Hummocks also promoted greater oxygen-controlled substrate limitation of DP, whereby experimental aeration stimulated DP under subsequent inundation more in hummocks than hollows. Additionally, tidal sites had greater DEA than nontidal sites, inferred to be caused by a combination of higher moisture, organic, and nutrient content. Our results indicate that the increasing nitrogen concentrations in these rivers will increase denitrification more on the Mattaponi River by alleviating its greater nitrogen limitation compared to the Pamunkey River, and modification to sedimentation, inundation, or microtopography from sea level rise may alter denitrification gradients in TFFWs and upstream low-elevation nontidal floodplains.

Virginia↗

Evaluation of simple geochemical indicators of aeolian sand provenance: Late Quaternary dune fields of North America revisited

Dune fields of Quaternary age occupy large areas of the world's arid and semiarid regions. Despite this, there has been surprisingly little work done on understanding dune sediment provenance, in part because many techniques are time-consuming, prone to operator error, experimental, highly specialized, expensive, or require sophisticated instrumentation. Provenance of dune sand using K/Rb and K/Ba values in K-feldspar in aeolian sands of the arid and semiarid regions of North America is tested here. Results indicate that K/Rb and K/Ba can distinguish different river sands that are sediment sources for dunes and dune fields themselves have distinctive K/Rb and K/Ba compositions. Over the Basin and Range and Great Plains regions of North America, the hypothesized sediment sources of dune fields are reviewed and assessed using K/Rb and K/Ba values in dune sands and in hypothesized source sediments. In some cases, the origins of dunes assessed in this manner are consistent with previous studies and in others, dune fields are found to have a more complex origin than previously thought. Use of K/Rb and K/Ba for provenance studies is a robust method that is inexpensive, rapid, and highly reproducible. It exploits one of the most common minerals found in dune sand, K-feldspar. The method avoids the problem of using simple concentrations of key elements that may be subject to interpretative bias due to changes in mineralogical maturity of Quaternary dune fields that occur over time.

Quaternary Science Reviews↗

Experimental evidence for the effects of polyphenolic compounds from Dictyoneurum californicum Ruprecht (Phaeophyta: Laminariales) on feeding rate and growth in the red abalone Haliotus rufescens Swainson

The effects of polyphenolic compounds from brown algae on grazing and growth rate of the California red abalone Haliotis rufescens Swainson were examined. Abalone consumed three phenolic-poor algal species, Laminaria sinclarii (Harvey) Farlow, Macrocystis pyrifera Agardh, and Nereocystis luetkeana Postels et Ruprecht (mean phenolic content = 0.52% dry mass), at a greater rate than two phenolic-rich species, Dictyoneurum californicum Ruprecht and Cystoseira osmundacea Agardh (mean phenolic content = 4.60% dry mass). This inverse relationship between phenolic content and consumption rate also existed after the algae were macerated and the liquid portion of the blended slurry incorporated in agar discs. However, the correlation between grazing rate and phenolic content imprpve d in this latter experiment, thus suggesting that abalone grazing was deterred significantly by the morphology of L. sinclarii and, to a lesser extent, of M. pyrifera . Polyphenolics extracted from D. californicum reduced abalone grazing rates by 90% when incorporated into agar discs at a concentration of 6 mg·ml −1 . Although abalone were unable to maintain body mass when fed ad libitum on macerated M. pyrifera incorporated into agar discs, polyphenolics from D. californicum further inhibited shell growth when added to the discs at 5 mg·ml −1 . The abalone ate less of the phenol-containing discs than of the discs lacking phenolics. Our results support findings of several prior studies that polyphenolic compounds from brown algae deter grazing by coastal zone herbivores in the northeast Pacific Ocean.

Journal of Experimental Marine Biology and Ecology↗

Significant results from using earth observation satellites for mineral and energy resource exploration

A large number of Earth-observation satellites orbit our world several times each day, providing new information about the land and sea surfaces and the overlying thin layer of atmosphere that makes our planet unique. Meteorological satellites have had the longest history of experimental use and most are now considered operational. The geologic information collected by the Landsat, Polar Orbiting Geophysical Observatory (POGO), Magsat, Heat Capacity Mapping Mission (HCMM) and Seasat land and ocean observation systems is being thoroughly tested, and some of these systems are now approaching operational use. Landsat multispectral images provide views of large areas of the Earth under uniform lighting conditions and can be obtained at a variety of scales and formats. Not only do the Landsat data provide highly useful images showing surficial materials and structures such as folds and faults, but also measurements and computer-derived ratios of the brightness of different rock types, alteration zones, and mineral associations. These data have led to the finding of a variety of new ore deposits. In addition, the combination of Landsat digital data and aeromagnetic data has extended the use of Landsat as an exploration tool which can be used to readily relate surface features to subsurface anomalies. Magsat data, now being collected, are helping refine information on major crustal anomalies that were first recognized during the analysis of POGO data. The more nearly circular orbit, lower altitude, and increased sophistication of its vector magnetometer enable Magsat to provide more precise information than POGO. Information of this type is required to develop crustal models. Although Magsat is designed to operate for only 4&ndash;8 months, the number of orbits that it should be able to make will be sufficient to accomplish its mission and to record a major magnetic storm expected in 1980. HCMM is a two-band visible to near-IR (0.55&ndash;1.1 &mu;m) and thermal infrared (10.2&ndash;12.5 &mu;m) system designed to measure reflected solar energy, determine the heat capacity of rocks and to monitor soil moisture, thermal effluents, plant canopy temperatures and snow cover. Launched in April 1978, it is in sun-synchronous, circular orbit at an altitude of 620 km. It is a relatively low-resolution system with an instantaneous field of view (IFOV) of 500&ndash;600 m and a swath width of 716 km. However, the system is designed to detect objects in the range of 260&deg;&ndash;340&deg; K with a sensitivity (NE&delta;T) of 0.4&deg;K at 280&deg;. Recording the thermal radiation of urban heat islands and high thermal inertia of quartzite strata in the Appalachian region are two examples of its land applications. Launched in June 1978, Seasat operated for only 100 days, but successfully acquired much information over both sea and land. The collection of synthetic aperture radar (SAR) imagery and radar altimetry was particularly important to geologists. Although there are difficulties in processing and distributing these data in a timely manner, initial evaluations indicate that the radar imagery supplements Landsat data by increasing the spectral range and offering a different look angle. The radar altimeter provides accurate profiles over narrow strips of land (1 km wide) and has demonstrated usefulness in measuring icecap surfaces (Greenland, Iceland, and Antarctica). The Salar of Uyuni in southern Bolivia served as a calibration site for the altimeter and has enabled investigators to develop a land-based smoothing algorithm that is believed to increase the accuracy of the system to 10 cm. Data from the altimeter are currently being used to measure subsidence resulting from ground water withdrawal in the Phoenix-Tucson area.

Advances in Space Research↗

The effect of temperature on experimental and natural chemical weathering rates of granitoid rocks

The effects of climatic temperature variations (5-35??C) on chemical weathering are investigated both experimentally using flow-through columns containing fresh and weathered granitoid rocks and for natural granitoid weathering in watersheds based on annual solute discharge. Although experimental Na and Si effluent concentrations are significantly higher in the fresh relative to the weathered granitoids, the proportional increases in concentration with increasing temperature are similar. Si and Na exhibit comparable average apparent activation energies (E(a)) of 56 and 61 kJ/mol, respectively, which are similar to those reported for experimental feldspar dissolution measured over larger temperature ranges. A coupled temperature-precipitation model, using an expanded database for solute discharge fluxes from a global distribution of 86 granitoid watersheds, produces an apparent activation energy for Si (51 kJ/mol), which is also comparable to those derived from the experimental study. This correlation reinforces evidence that temperature does significantly impact natural silicate weathering rates. Effluent K concentrations in the column study are elevated with respect to other cations compared to watershed discharge due to the rapid oxidation/dissolution of biotite. K concentrations are less sensitive to temperature, resulting in a lower average E(a) value (27 kJ/mol) indicative of K loss from lower energy interlayer sites in biotite. At lower temperatures, initial cation release from biotite is significantly faster than cation release from plagioclase. This agrees with reported higher K/Na ratios in cold glacial watersheds relative to warmer temperate environments. Increased release of less radiogenic Sr from plagioclase relative to biotite at increasing temperature produces corresponding decreases in 87Sr/86Sr ratios in the column effluents. A simple mixing calculation using effluent K/Na ratios, Sr concentrations and 87Sr/86Sr ratios for biotite and plagioclase approximates stoichiometric cation ratios from biotite/plagioclase dissolution at warmer temperatures (35??C), but progressively overestimates the relative proportion of biotite with decreasing temperature. Ca, Mg, and Sr concentrations closely correlate, exhibit no consistent trends with temperature, and are controlled by trace amounts of calcite or exchange within weathered biotite. The inability of the watershed model to differentiate a climate signal for such species correlates with the lower temperature dependence observed in the experimental studies.

Geochimica et Cosmochimica Acta↗