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At least 631 records · Page 35Linked to original sources

Distribution of a suite of elements including arsenic and mercury in Alabama coal

Arsenic and other elements are unusually abundant in Alabama coal. This conclusion is based on chemical analyses of coal in the U.S. Geological Survey's National Coal Resources Data System (NCRDS; Bragg and others, 1994). According to NCRDS data, the average concentration of arsenic in Alabama coal (72 ppm) is three times higher than is the average for all U.S. coal (24 ppm). Of the U.S. coal analyses for arsenic that are at least 3 standard deviations above the mean, approximately 90% are from the coal fields of Alabama. Figure 1 contrasts the abundance of arsenic in coal of the Warrior field of Alabama (histogram C) with that of coal of the Powder River Basin, Wyoming (histogram A), and the Eastern Interior Province including the Illinois Basin and nearby areas (histogram B). The Warrior field is by far the largest in Alabama. On the histogram, the large 'tail' of very high values (> 200 ppm) in the Warrior coal contrasts with the other two regions that have very few analyses greater than 200 ppm.

Alabama↗

Water-quality data from lakes in the Yukon Flats, Alaska, 2010-2011

Over a two-year period (2010–2011), in-place measurements were made and water-quality samples were collected from 122 lakes in the Yukon Flats, Alaska, during a U.S. Geological Survey lake biological diversity inventory. The U.S. Geological Survey National Research Program performed the chemical analyses on the retrieved water-quality samples. Results from the analyses of water samples for dissolved carbon gases and carbon isotopes, hydrogen and oxygen stable isotopes, dissolved organic carbon, and major cations and anions, along with supporting site data, are presented in this report.

Alaska↗

Characterization of Northern California petroleum by stable carbon isotopes

The purpose of this study is to characterize natural occurrences of petroleum at the surface and in the subsurface within northern California in order to define and map petroleum systems for U.S. Geological Survey energy resource assessments. Furthermore, the chemical characterization and mapping of natural petroleum occurrences could also be used to discriminate natural occurrences from accidental oil spills during the activities of extraction or transportation of petroleum. Samples include petroleum from exploratory well tests, producing fields, natural seeps, and oil-stained rocks, and condensates from gas wells. Most of the sample localities are in northern California but a few samples from central and southern California are included for comparison (table 1). Even though other analyses were performed, only stable carbon isotope (δ13C) data are presented here for brevity and because δ13C values are one of the most discriminating characteristics of California petroleum.

California↗

Integrated investigations of environmental effects of historical mining in the Basin and Boulder Mining Districts, Boulder River watershed, Jefferson County, Montana

The Boulder River watershed is one of many watersheds in the western United States where historical mining has left a legacy of acid mine drainage and elevated concentrations of potentially toxic trace elements. Abandoned mine lands commonly are located on or affect Federal land. Cleaning up these Federal lands will require substantial investment of resources. As part of a cooperative effort with Federal land-management agencies, the U.S. Geological Survey implemented an Abandoned Mine Lands Initiative in 1997. The goal of the initiative was to use the watershed approach to develop a strategy for gathering and communicating the scientific information needed to formulate effective and cost-efficient remediation of affected lands in a watershed. The watershed approach is based on the premise that contaminated sites that have the most profound effect on water and ecosystem quality within an entire watershed should be identified, characterized, and ranked for remediation. The watershed approach provides an effective means to evaluate the overall status of affected resources and helps to focus remediation at sites where the most benefit will be gained in the watershed. Such a large-scale approach can result in the collection of extensive information on the geology and geochemistry of rocks and sediment, the hydrology and water chemistry of streams and ground water, and the diversity and health of aquatic and terrestrial organisms. During the assessment of the Boulder River watershed, we inventoried historical mines, defined geological conditions, assessed fish habitat, collected and chemically analyzed hundreds of water and sediment samples, conducted toxicity tests, analyzed fish tissue and indicators of physiological malfunction, examined invertebrates and biofilm, and defined hydrological regimes. Land- and resource-management agencies are faced with evaluating risks associated with thousands of potentially harmful mine sites, and this level of effort is not always feasible for every affected watershed. The detailed work described in this report can help Federal land-management agencies decide which characterization efforts would be most useful in characterization of other affected watersheds.

Montana↗

Ground-water quality beneath an urban residential and commercial area, Montgomery, Alabama, 1999-2000

The Black Warrior River aquifer, which is composed of the Coker, Gordo, and Eutaw Formations, supplies more than 50 percent of the ground water used for public water supply in the Mobile River Basin. The city of Montgomery, Alabama, is partially built upon a recharge area for the Black Warrior River aquifer, and is one of many major population centers that depend on the Black Warrior River aquifer for public water supply. To represent the baseline ground-water quality in the Black Warrior River aquifer, water samples were collected from 30 wells located in a low-density residential or rural setting; 9 wells were completed in the Coker Formation, 9 wells in the Gordo Formation, and 12 wells in the Eutaw Formation. To describe the ground-water quality beneath Montgomery, Alabama, water samples also were collected from 30 wells located in residential and commercial areas of Montgomery, Alabama; 16 wells were completed in the Eutaw Formation, 8 wells in alluvial deposits, and 6 wells in terrace deposits. The alluvial and terrace deposits directly overlie the Eutaw Formation with little or no hydraulic separation. Ground-water samples collected from both the rural and urban wells were analyzed for physical properties, major ions, nutrients, metals, volatile organic compounds, and pesticides. Samples from the urban wells also were analyzed for bacteria, chlorofluorocarbons, dissolved gases, and sulfur hexafluoride. Ground-water quality beneath the urban area was compared to baseline water quality in the Black Warrior River aquifer.Compared to the rural wells, ground-water samples from urban wells contained greater concentrations or more frequent detections of chloride and nitrate, and the trace metals aluminium, chromium, cobalt, copper, nickel, and zinc. Pesticides and volatile organic compounds were detected more frequently and in greater concentrations in ground-water samples collected from urban wells than in ground-water samples from rural wells.The Spearman rho test was used to check for statistically significant covariance among urban ground-water quality and land-use type. The number of pesticides and volatile organic compounds detected and concentrations of nickel increased as the percentage of residential land use increased. Greater nickel concentrations also were associated with a greater number of volatile organic compounds detected. As the percentage of commercial land use increased, the numbers of pesticides and volatile organic compounds detected decreased. The number of pesticides detected in the urban ground-water samples increased as concentrations of nitrite plus nitrate increased; the number of pesticides detected and the concentrations of nitrite plus nitrate decreased as the age of the ground water increased. These correlations may indicate that, with time, pesticides and nitrate are removed from the ground-water system by physical, chemical, or biological processes.The effects of surficial geology on the occurrence of pesticides and volatile organic compounds was investigated by calculating frequencies of detection. The detection frequency for pesticides was greater for urban samples collected from wells where the surficial geology is sand than for urban samples collected from wells where the surficial geology is clay. The frequency of detection of volatile organic compounds did not show this relation.

Water-Resources Investigations Report↗

Characterization of feed coals and coal combustion byproducts from the Wyodak-Anderson coal zone, Powder River Basin, Wyoming

The U.S. Geological Survey (USGS) determined the physical and chemical properties of more than 260 feed coal and coal combustion byproducts from two coal-fired power plants. These plants utilized a low-sulfur (0.23-0.47 wt. % S) and low ash (4.9-6.3 wt. % ash) subbituminous coal from the Wyodak-Anderson coal zone in the Tongue River Member of the Paleocene Fort Union Formation, Powder River Basin, Wyoming. Fifty-three samples of bituminous coal were collected and analyzed from a Kentucky power plant, which used several sources of bituminous coals from the Appalachian and Illinois Basins. Based on scanning electron microscopy (SEM) and X-ray diffraction (XRD) analyses of feed coal samples collected and analyzed from 1996 through the late 2000s, two mineral suites were identified: (1) a primary or detrital suite consisting of quartz (including beta-form grains), biotite, feldspar, and minor zircon; and (2) a secondary authigenic mineral suite containing alumino-phosphates (crandallite and gorceixite), kaolinite, carbonates (calcite and dolomite), quartz, anatase, barite, and pyrite. The detrital mineral suite is interpreted, in part, to be of volcanic origin, whereas the authigenic mineral suite is interpreted, in part, to be the result of the alteration of the volcanic minerals. The mineral suites have contributed to the higher amounts of barium, calcium, magnesium, phosphorus, sodium, strontium, and titanium in the Powder River Basin feed coals in comparison to eastern US coals. XRD analysis indicates that (1) fly ash is mostly aluminate glass, perovskite, lime, gehlenite, quartz, and phosphates with minor amounts of periclase, anhydrite, hematite, and spinel group minerals; and (2) bottom ash is predominantly quartz, plagioclase (albite and anorthite), pyroxene (augite and fassaite), rhodonite, and akermanite, and spinel group minerals. Microprobe and SEM analyses of fly ash samples revealed quartz, zircon, and monazite, euhedral laths of corundum with merrillite, hematite, dendritic spinels/ferrites, wollastonite, and periclase. The abundant calcium and magnesium mineral phases in the fly ash are attributed to the alteration of carbonate, clay, and phosphate minerals in the feed coal during combustion. The calcium- and magnesium-rich and alumino-phosphate mineral phases in the coal combustion byproducts can be attributed to volcanic minerals deposited in peat-forming mires. Dissolution and alteration of these detrital volcanic minerals occurred either in the peat-forming stage or during coalification and diagenesis, resulting in the authigenic mineral suite. The presence of free lime (CaO) in fly ash produced from Wyodak-Anderson coal acts as a self-contained “scrubber” for SO 3 , where CaO + SO 3 form anhydrite either during combustion or in the upper parts of the boiler. Considering the high lime content in the fly ash and the resulting hydration reactions after its contact with water, there is little evidence that major amounts of leachable metals are mobilized in the disposal or utilization of this fly ash.

Wyoming↗

Willamette Basin Comprehensive Study of Water and Related Land Resources: Appendix B--Hydrology

The study was undertaken to plan for the proper development of water and related land resources of the Willamette Basin in Oregon. Appendix B , along with Appendices A and C, provides supporting data for the functional Appendices D through L. Climate is first discussed, including the climatic significance of geographical features such as the Pacific Ocean, the Columbia Gorge, and the Coast and Cascade Ranges, climatic elements (e.g. , temperature, precipitation, evaporation), and meteorological aspects of major storms--rain, wind, and snow. A description of water resources , their distribution, and their variation at different times are presented. These resources are described in terms of factors influencing the occurrence of water . Specifically reviewed here are surface waters, groundwater, the relationship between surface and groundwater, management programs, and water rights and legal restrictions. Lastly, the adequacy of hydrologic data is reviewed. Statistical and interpretive hydrologic data necessary for broadscale water resources planning are provided. Data assembled are those concerning climate, streamflow, lakes and glaciers, chemical-quality, sediment, stream temperature, and groundwater. Geologic and soils mapping are briefly discussed, and a list of references is provided.

Report↗

Water-quality data for the Flaming Gorge Reservoir area, Utah and Wyoming, 1969-72

This report presents the basic data that were collected by the U.S. Geological Survey during a study of the chemical quality of water in Flaming Gorge Reservoir. An interpretive report will follow. The basic data were collected from the reservoir during six sampling runs between October 1970 and September 1972. The reservoir was sampled for chemical analyses at 17 sites. Chemical and physical data were measured in situ at 34 sites. The sites are shown in figure 1 and the data are listed in tables 1 and 3-6.

Utah↗

Water-quality, phytoplankton, and trophic-status characteristics of Big Base and Little Base lakes, Little Rock Air Force Base, Arkansas, 2003-2004

Little Rock Air Force Base is the largest C-130 base in the Air Force and is the only C-130 training base in the Department of Defense. Little Rock Air Force Base is located in central Arkansas near the eastern edge of the Ouachita Mountains, near the Mississippi Alluvial Plain, and within the Arkansas Valley Ecoregion. Habitats include upland pine forests, upland deciduous forest, broad-leaved deciduous swamps, and two small freshwater lakes?Big Base Lake and Little Base Lake. Big Base and Little Base Lakes are used primarily for recreational fishing by base personnel and the civilian public. Under normal (rainfall) conditions, Big Base Lake has a surface area of approximately 39 acres while surface area of Little Base Lake is approximately 1 acre. Little Rock Air Force Base personnel are responsible for managing the fishery in these two lakes and since 1999 have started a nutrient enhancement program that involves sporadically adding fertilizer to Big Base Lake. As a means of determining the relations between water quality and primary production, Little Rock Air Force Base personnel have a need for biological (phytoplankton density), chemical (dissolved-oxygen and nutrient concentrations), and physical (water temperature and light transparency) data. To address these monitoring needs, the U.S. Geological Survey in cooperation with Little Rock Air Force Base, conducted a study to collect and analyze biological, chemical, and physical data. The U.S. Geological Survey sampled water quality in Big Base Lake and Little Base Lake on nine occasions from July 2003 through June 2004. Because of the difference in size, two sampling sites were established on Big Base Lake, while only one site was established on Little Base Lake. Lake profile data for Big Base Lake indicate that low dissolved- oxygen concentrations in the hypolimnion probably constrain most fish species to the upper 5-6 feet of depth during the summer stratification period. Dissolved-oxygen concentrations in Big Base Lake below a depth of 6 feet generally were less than 3 milligrams per liter for summer months that were sampled in 2003 and 2004. Some evidence indicates that phosphorus was limiting primary production during the sampling period. Dissolved nitrogen constituents frequently were detected in water samples (indicating availability) but dissolved phosphorus constituents-orthophosphorus and dissolved phosphorus-were not detected in any samples collected at the two lakes. The absence of dissolved phosphorus constituents and presence of total phosphorus indicates that all phosphorus was bound to suspended material (sediment particles and living organisms). Nitrogen:phosphorus ratios on most sampling occasions tended to be slightly higher than 16:1, which can be interpreted as further indication that phosphorus could be limiting primary production to some extent. An alkalinity of 20 milligrams per liter of calcium carbonate or higher is recommended to optimize nutrient availability and buffering capacity in recreational fishing lakes and ponds. Median values for water samples collected at the three sites ranged from 12-13 milligrams per liter of calcium carbonate. Alkalinities ranged from 9-60 milligrams per liter of calcium carbonate, but 13 of 17 samples collected at the deepest site had alkalinities less than 20 milligrams per liter of calcium carbonate. Results of three trophic-state indices, and a general trophic classification, as well as abundant green algae and large growths of blue-green algae indicate that Big Base Lake may be eutrophic. Trophic-state index values calculated using total phosphorus, chlorophyll a, and Secchi disc measurements from both lakes generally exceeded criteria at which lakes are considered to be eutrophic. A second method of determining lake trophic status-the general trophic classification-categorized the three sampling sites as mesotrophic or eutrophic. Green algae were found to be in abundance throughout mos

Scientific Investigations Report↗

Two-event genesis of Butte lode veins: Geologic and geochronologic evidence from ore veins, dikes, and host plutons

The long-standing ore-genesis model for world-class deposits of the Butte mining district, Montana, is of deep pre-Main Stage porphyry Cu-Mo and overlying Main Stage Ag-Zn-Cu-zoned lode veinsformed from discrete hydrothermal systems related to rhyolite dikes. The lode-specific model describes metals zones that formed in the lode veins as hydrothermal processes diminished in intensity (changing temperature and chemical characteristics) outward from the district center. New geologic and multi-method geochronologic studies pro- vide new timing constraints on the lode veins and reevaluation of geologic relations (Lund and others, 2018), leading to a new model for formation of the lode veins and their relations to stockwork Cu-Mo deposits and igneous events.

Montana↗

Crude oil degradation as an explanation of the depth rule

Previous studies of crude oil degradation by water washing and bacterial attack have documented the operation of these processes in many different petroleum basins of the world. Crude oil degradation substantially alters the chemical and physical makeup of a crude oil, changing a light paraffinic low-S "mature" crude to a heavy naphthenic or asphalt base, "immature appearing" high-S crude. Rough calculations carried out in the present study using experimentally determined solubility data of petroleum in water give insight into the possible magnitude of water washing and suggest that the process may be able to remove large amounts of petroleum in small divisions of geologic time. Plots of crude oil gravity vs. depth fail to show the expected correlation of increasing API gravity (decreasing specific gravity) with depth below 2.44 km (8000 ft.). Previous studies which have been carried out to document in-reservoir maturation have used crude oil gravity data shallower than 2.44 km (8000 ft.). The changes in crude oil composition as a function of depth which have been attributed to in-reservoir maturation over these shallower depths, are better explained by crude oil degradation. This study concludes that changes in crude oil composition that result from in-reservoir maturation are not evident from existing crude oil gravity data over the depth and temperature range previously supposed, and that the significant changes in crude oil gravity which are present over the shallow depth range are due to crude oil degradation. Thus the existence of significant quantities of petroleum should not necessarily be ruled out below an arbitrarily determined depth or temperature limit when the primary evidence for this is the change in crude oil gravity at shallow depths. ?? 1980.

Chemical Geology↗

Chapter B. Physical, Chemical, and Biological Responses of Streams to Increasing Watershed Urbanization in the Piedmont Ecoregion of Georgia and Alabama, 2003

As part of the U.S. Geological Survey National Water-Quality Assessment Program?s effort to assess the physical, chemical, and biological responses of streams to urbanization, 30 wadable streams were sampled near Atlanta, Ga., during 2002?2003. Watersheds were selected to minimize natural factors such as geology, altitude, and climate while representing a range of urban development. A multimetric urban intensity index was calculated using watershed land use, land cover, infrastructure, and socioeconomic variables that are highly correlated with population density. The index was used to select sites along a gradient from low to high urban intensity. Response variables measured include stream hydrology and water temperature, instream habitat, field properties (pH, conductivity, dissolved oxygen, turbidity), nutrients, pesticides, suspended sediment, sulfate, chloride, Escherichia coli (E. coli) concentrations, and characterization of algal, invertebrate and fish communities. In addition, semipermeablemembrane devices (SPMDs)?passive samplers that concentrate hydrophobic organic contaminants such as polycyclicaromatic hydrocarbons (PAHs)?were used to evaluate water-quality conditions during the 4 weeks prior to biological sampling. Changes in physical, chemical, and biological conditions were evaluated using both nonparametric correlation analysis and nonmetric multidimensional scaling (MDS) ordinations and associated comparisons of dataset similarity matrices. Many of the commonly reported effects of watershed urbanization on streams were observed in this study, such as altered hydrology and increases in some chemical constituent levels. Analysis of water-chemistry data showed that specific conductance, chloride, sulfate, and pesticides increased as urbanization increased. Nutrient concentrations were not directly correlated to increases in development, but were inversely correlated to percent forest in the watershed. Analyses of SPMD-derived data showed that bioassays and certain chemical constituents such as pyrene and benzophenanthrene, both PAHs found in coal tar, were strongly correlated with measures of watershed urbanization. Hydrologic variability metrics indicated that as urban development increased, streams became flashier, with characteristic high flows having shorter duration. The hydrologic effects associated with urbanization were greatest during the fall and least apparent during the winter. No correlations were observed between increasing urbanization and stream temperature or changes in stream habitat. Algal, invertebrate, and fish communities exhibited statistically significant changes as watersheds became increasingly urban, with the strongest responses observed in the invertebrate community followed by fishes, then algal diatom communities. Invertebrate communities were the most responsive to increasing urbanization with Ephemeroptera, Plecoptera, and Tricoptera taxa, especially Plecoptera (stoneflies) responding negatively and most strongly to increasing urbanization. Invertebrate communities were influenced more significantly by water quality, although significant responses to altered hydrology also were noted. In terms of the fish community, the percentage of cyprinids present in the stream was the only Index of Biotic Integrity metric that responded negatively to increases in watershed urbanization. Fish community response to urbanization was intermediate relative to algae and invertebrates with respect to significant metric responses as well as the overall community response to increasing urbanization. Measures of hydrologic variability were the most influential environmental variables affecting the algal community. Although sites were originally chosen to represent a gradient of increasing urbanization, a cluster analysis performed on the component metrics of the urban index categorized sites into four distinct groups. Multivariate analysis based on nonmetric MDS and related analyses of data ma

Alabama, Georgia↗

The effects of land use on fluvial sediment chemistry for the conterminous U.S. - Results from the first cycle of the NAWQA Program: Trace and major elements, phosphorus, carbon, and sulfur

In 1991, the U.S. Geological Survey (USGS) began the first cycle of its National Water Quality Assessment (NAWQA) Program. The Program encompassed 51 river basins that collectively accounted for more than 70% of the total water use (excluding power generation), and 50% of the drinking water supply in the U.S. The basins represented a variety of hydrologic settings, rock types (geology), land-use categories, and population densities. One aspect of the first cycle included bed sediment sampling; sites were chosen to represent baseline and important land-use categories (e.g., agriculture, urban) in each basin. In total, over 1200 bed sediment samples were collected. All samples were size-limited (< 63????m) to facilitate spatial and/or temporal comparisons, and subsequently analyzed for a variety of chemical constituents including major (e.g., Fe, Al,) and trace elements (e.g., Cu, Zn, Cd), nutrients (e.g., P), and carbon. The analyses yielded total (??? 95% of the concentrations present), rather than total-recoverable chemical data. Land-use percentages, upstream underlying geology, and population density were determined for each site and evaluated to asses their relative influence on sediment chemistry. Baseline concentrations for the entire U.S. also were generated from a subset of all the samples, and are based on material collected from low population (??? 27??p km- 2) density, low percent urban (??? 5%), agricultural or undeveloped areas. The NAWQA baseline values are similar to those found in other national and global datasets. Further, it appears that upstream/underlying rock type has only a limited effect (mostly major elements) on sediment chemistry. The only land-use category that appears to substantially affect sediment chemistry is percent urban, and this result is mirrored by population density; in fact, the latter appears more consistent than the former.

Science of the Total Environment↗

Recent experimental data may point to a greater role for osmotic pressures in the subsurface

Uncertainty about the origin of anomalous fluid pressures in certain geologic settings has caused researchers to take a second look at osmosis, or flow driven by chemical potential differences, as a pressure‐generating process in the subsurface. Interest in geological osmosis has also increased because of an in situ experiment by Neuzil (2000) suggesting that Pierre Shale could generate large osmotic pressures when highly compacted. In the last few years, additional laboratory and in situ experiments have greatly increased the number of data on osmotic properties of argillaceous formations, but they have not been systematically examined. In this paper we compile these data and explore their implications for osmotic pressure generation in subsurface systems. Rather than base our analysis on osmotic efficiencies, which depend strongly on concentration, we calculated values of a quantity we term osmotic specific surface area ( A so ) that, in principle, is a property of the porous medium only. The A so values are consistent with a surprisingly broad spectrum of osmotic behavior in argillaceous formations, and all the formations tested exhibited at least a modest ability to generate osmotic pressure. It appears possible that under appropriate conditions some formations can be highly effective osmotic membranes able to generate osmotic pressures exceeding 30 MPa (3 km of head) at porosities as high as ∼0.1 and pressures exceeding 10 MPa at porosities as high as ∼0.2. These findings are difficult to reconcile with the lack of compelling field evidence for osmotic pressures, and we propose three explanations for the disparity: (1) Our analysis is flawed and argillaceous formations are less effective osmotic membranes than it suggests; (2) the necessary subsurface conditions, significant salinity differences within intact argillaceous formations, are rare; or (3) osmotic pressures are unlikely to be detected and are not recognized when encountered. The last possibility, that osmotic pressures routinely escape detection or are attributed to other mechanisms, has important implications for understanding subsurface flow regimes.

Water Resources Research↗

Map showing general chemical quality of surface water in the Richfield Quadrangle, Utah

This is one of a series of maps that describe the geology and related natural resources of the Richfield 2° quadrangle, Utah. The purpose of this map is to show the general chemical quality of surface water in the area by ranges of dissolved-solids concentrations. Data used to compile this map were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Rights. In those areas where little or no surface-water-quality data are available, ranges of dissolved-solids concentrations of the water are inferred on the basis of such factors as geology (Stokes, 1964), precipitation, topography, known ground-water quality, and water uses – all of which affect the chemical quality of surface water. Additional information about the chemical quality of surface water in various parts of the Richfield 2° quadrangle may be found in the following reports: Hahl and Cabell (1965), Hahl and Mundorff (1968), Stephens (1974, 1976), Cruff and Mower (1976), and Cruff(1977)

Utah↗

Data on uranium and radium in ground water in the United States, 1954 to 1957

This report is one of a series resulting from a study by the U.S. Geological Survey to determine the occurrence and distribution of naturally radioactive substances in water. From 1954-57 uranium and radium concentrations were determined in 561 samples, mainly of ground water, having wide geologic and geographic distribution. These concentrations, together with data on the hydrologic and geologic environment, the beta-gamma activity, and the chemical characteristics of each sample, are tabulated by States. The conterminous United States was subdivided into 10 geotectonic regions to facilitate statistical interpretation of the occurrence of uranium and radium in fresh water in approximately homogeneous geologic provinces. For each geotectonic region, the range and median were determined for the concentrations of radium and uranium; for regions from which sufficient data were available, log-normal frequency distribution curves were calculated and superimposed on histograms of radium and uranium concentrations in the samples. An "anomaly threshold" is suggested for both radioelements for each region analyzed statistically. The western stable region had the greatest median and highest "anomaly threshold" for uranium. This region also had the highest "anomaly threshold" for radium, but the largest median for radium was found for samples collected in the Ozark-Ouachita system. The median concentration for uranium was lowest for the Atlantic and Gulf Coastal Plain and the Pacific orogenic belt. This latter region also had the lowest median-radium content.

Professional Paper↗

Geology and ground-water resources of the lower Lodgepole Creek drainage basin, Nebraska, with a section on chemical quality of the water

The area described is almost wholly in Nebraska and is the drainage basin of Lodgepole Creek from the Wyoming State line to the Colorado State line, a distance along the stream valley of about 95 miles. It covers about 1,950 square miles. The purposes of the study were to ascertain the characteristics, thickness, and extent of the water-bearing formations and to obtain and interpret data on the origin, quality, quantity, movement, availability, and use of ground water in the area. The rocks exposed in the drainage basin are the Brule formation of Oligocene (Tertiary) age, the Ogallala formation of Pliocene (Tertiary) age, and alluvium of Pleistocene and Recent (Quaternary) age. The Brule formation is mainly a siltstone, which yields an average of 950 gallons per minute (gpm) to irrigation wells tapping its fractured zones or reworked material; the maximum reported discharge is 2,200 gpm. The Ogallala formation underlies most of the area. It consists of lenticular beds of clayey, silty, sandy, and gravelly materials and supplies water to all wells on the upland, including a few large-discharge wells, and to many irrigation and public-supply wells in the valley of Lodgepole Creek. The yield of irrigation wells tapping the Ogallala formation ranges from 90 to 1,600 gpm and averages about 860 gpm. The alluvium is present in the valleys of Lodgepole Creek and its tributaries and consists mainly of heterogeneous . mixtures of silt, sand, and gravel, and lenticular bodies of these materials. Between the Colorado State line and Chappell, Nebr., irrigation wells derive most of their water from the alluvium. However, between Chappell and Sidney most of the irrigation wells tap both the alluvium and permeable zones in the underlying Brule formation, and in much of the valley west of Sidney, where the water table is beneath the bottom of the alluvium, irrigation wells derive water from the underlying Brule or Ogallala formations. Irrigation wells obtaining water chiefly from the alluvium have a yield ranging from 130 to 1,200 gpm, averaging about 770 gpm. In the Lodgepole Creek valley below Sidney the depth to water generally is less than 20 feet and, in many places, less than 10. In much of this part of the area the water table extends to the land surface or to the root zone of the vegetation, and discharge by evapotranspiration is high. In the valley of Lodgepole Creek between Sidney and the Wyoming State line, the depth to water generally ranges from less than 10 feet near the stream to more than 100 along the edge of the valley. In the upland the depth to water ranges from about 80 to about 300 feet. Recharge to the ground-water reservoir is derived chiefly from precipitation; other sources are seepage from irrigation systems and streams, and subsurface inflow of ground water. Water that infiltrates to the water table generally moves toward Lodgepole Creek in a downstream direction and is discharged into the stream through springs and seeps. However, within an area of at least 400 square miles in the northern part of the lower Lodgepole Creek drainage basin, ground water moves toward the valley of the North Platte River. Water is discharged from the ground-water reservoir into streams, by evapotranspiration, through wells, and by subsurface outflow. During the 1951-52 water year about 13,000 acre-feet of ground water left the area as streamflow. An estimated 20,000 acre-feet of water annually is discharged by the transpiration of grasses and trees growing along the creek bottom, and about 1,000 acre-feet of water leaves as subsurface outflow. During the period 1950-51 about 68,000 acre-feet of water was pumped from wells in the area for all uses. Of this amount; about 35,000 acre-feet in 1950 and 23,300 acre-feet in 1951 were used to irrigate about 15,560 and 15,790 acres. Nearly one-fourth of this water percolated back to the ground-water reservoir. These acreages, however, included about 2,100 acres irrigated in p

Water Supply Paper↗

Geology and ground-water resources of the upper Lodgepole Creek drainage basin, Wyoming, with a section on chemical quality of the water

The principal sources of ground-water supply in the upper Lodgepole Creek drainage basin-the part of the basin west of the Wyoming-Nebraska State line-are the Brule formation of Oligocene age, the Arikaree formation of Miocene age, the Ogallala formation of Pliocene age, and the unconsolidated deposits of Quaternary age. The Brule formation is a moderately hard siltstone that generally is not a good aquifer. However, where it is fractured or where the upper part consists of pebbles of reworked siltstone, it will yield large quantities of water to wells. Many wells in the Pine Bluffs lowland, at the east end of the area, derive water from the Brule. The Arikaree formation, which consists of loosely to moderately cemented fine sand, will yield small quantities of water to wells but is not thick enough or permeable enough to supply sufficient water for irrigation. Only a few wells derive water from it. The Ogallala formation consists of lenticular beds of clay, silt, sand, and gravel which, in part, are cemented with calcium carbonate. Only the lower part of the formation is saturated. Nearly all the wells in the upland part of the area tap the Ogallala, but they supply water in amounts sufficient for domestic and stock use only. Two of the wells have a moderately large discharge, and other wells of comparable discharge probably could be drilled in those parts of the upland where the saturated part of the Ogallala is fairly thick. Most of the unconsolidated deposits of Quaternary age are very permeable and, where a sufficient thickness is saturated, will yield large quantities of water to wells. These deposits are a significant source of water supply in the southeastern part of the area. The Chadron formation of Oligocene age, which underlies the Brule formation, is a medium- to coarse-grained sandstone where it crops out in the Islay lowland. No wells tap the Chadron, but it probably would yield small quantities of water to wells. It lies at a relatively shallow depth beneath most of the Islay lowland, near the west end of the area, and at a depth of about 800 feet beneath the Pine Bluffs lowland. In the latter area it probably is finer grained and may not be permeable enough to yield water to wells. All the ground water in the area is derived from precipitation. It is estimated that about 5 percent of the precipitation infiltrates directly to the zone of saturation. The remainder either is evaporated immediately; is retained by the soil, later to be evaporated or transpired; or is discharged by overland flow to the surface drainage courses. Most of the water that reaches the surface drainage courses eventually sinks to the zone of saturation or is evaporated. The slope of the water table and the movement of ground water are generally eastward. The depth to water ranges from less than 10 feet in parts of the valley to about 300 feet in the upland areas. In much of the Pine Bluffs lowland, the depth to water is less than 50 feet. Ground water not pumped from wells within the area is discharged by evapotranspiration where the water table is close to the land surface, by outflow into streams, or by underflow eastward beneath the State line. The chemical quality of ground water from the principal sources is remarkably uniform, and the range in concentration of dissolved constituents is narrow. In general, the water is of the calcium bicarbonate type, is hard (hardness as CaC03 is as high as 246 ppm), and contains less than about 400 parts per million of dissolved solids, which is a moderate mineralization. Silica constitutes a large proportion of the dissolved solids. The water is suitable for irrigation and, except for iron in water from some wells that tap the Ogallala formation, meets the drinking water standards of the U.S. Public Health Service for chemical constituents. Because the water is siliceous, alkaline, and hard, it is unsuitable for many industrial uses unless treated.

Water Supply Paper↗