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At least 613 records · Page 34Linked to original sources

Walden Pond, Massachusetts: Environmental setting and current investigations

Introduction Walden Pond, in Concord, Massachusetts, is famous among lakes because of its unique social history. Walden was the setting for American naturalist Henry David Thoreau's well-known essay 'Walden; or, Life in the Woods,' first published in 1854. Thoreau lived and wrote at Walden Pond from July 1845 to September 1847. In 'Walden,' Thoreau combined highly admired writing on Transcendental philosophy with pioneering observations of aquatic ecology and physical aspects of limnology, the study of lakes. Because Thoreau also defended so effectively the value of living close to nature in the Walden woods, the pond is considered by many to be the birthplace of the American conservation movement. Visitors come from all over the world to the pond, which has been designated a National Historic Landmark, and its fame has resulted in a major fund drive to preserve the surrounding woods. Walden Pond has no surfacewater inflow or outflow, and much of its ground-water contributing area likely is preserved within the Walden Pond Reservation area (fig. 1). Only 15 miles from Boston, the pond is unusually clear and pristine for an urban-area lake. However, point sources of nutrients near the pond, and a large annual visitor attendance, concentrated during the summer when the swimming beach (fig. 2) is open, may contribute a nutrient load sufficient to change the pond environment. The occurrence of nuisance algal species, a recent beach closing, and an awareness of water-quality problems suffered by other ponds in the region raise concerns about the risk of ecological change at Walden Pond. Despite the role of Walden Pond as a cultural and environmental icon, little is known about the pond's ecological features, such as its internal nutrient cycling or the structure of its food web, nor have consistent measurements been made to determine whether these features are changing or are stable. Production rates of aquatic plants in lakes and ponds naturally undergo a slow increase as plant nutrients, organic matter, and soil are leached and eroded from the surrounding watershed. This process is known as eutrophication. The term 'cultural eutrophication' refers to an accelerated form of the natural process in which extra soil and nutrients are derived from people's use of fertilizer, rerouting of surface drainage, and disposal of domestic and industrial waste. Cultural eutrophication can lead to excessive growth of aquatic plants, pond filling by decayed plants and eroded soils, reduced water clarity, and depletion of dissolved oxygen in deep water with subsequent loss of cold-water fish habitat. In order to document the longterm ecological health of Walden Pond, the U.S. Geological Survey (USGS), working in cooperation with the Massachusetts Department of Environmental Management (MDEM), is investigating factors that could contribute to cultural eutrophication of Walden. Through measurements of mass balance of nutrients and oxygen in the pond's deep water, the investigation will establish a baseline data set on Walden's trophic state, which is a measure of the pond's ability to support plant growth. The baseline data will be used to detect trends and give early warning of trophic changes or trophic response to pond remediation projects. This Fact Sheet provides background information on the environmental setting, limnological features, and cultural eutrophication of Walden Pond, and describes the joint USGS/MDEM study.

Massachusetts↗

A simple predictive model for salt marsh internal deterioration under sea-level rise and sediment deficits: Application to Chesapeake Bay

Salt marshes are dynamic biogeomorphic systems reliant on autochthonous and allochthonous input to maintain their three-dimensional configuration. Sea-level rise, subsidence, and sediment deficits can lead to submergence, open-water expansion, and ultimately loss of the vegetated marsh plain and associated ecosystem services. Widely used management-focused models focus on vegetation zonation in response to sea level but neglect sediment transport processes and geomorphic change. Process-based research models attempt to represent complex physical and biogeomorphic interactions but operate on spatiotemporal scales that are not directly transferable to restoration or management. Here we bridge these two paradigms and present a novel geomorphic model (UBMorph) based on the sediment-based lifespan concept that accounts for sea-level rise and open-water expansion to predict changes in salt marsh area in Chesapeake Bay. Model parameters such as surface accretion rate and elevation-to-areal loss fraction are selected using a separate, fully coupled biogeomorphic model (MarshMorpho2D) and the predicted lifespan is then compared with high marsh coverage from a zonation model (SLAMM). Across all of Chesapeake Bay, UBMorph estimates an overall loss of 404 km 2 (37%) of vegetated marsh area under a dynamic 3–12 mm/y sea-level rise scenario (between 2010 and 2110). We then demonstrate a management-focused application of UBMorph and SLAMM used in tandem, for developing both a marsh condition and restoration model of the Chesapeake Bay portion of Maryland. The restoration model, which includes hydrologic intervention and sediment placement actions, indicates that ~ 400 km 2 of marsh require either no intervention or low effort hydrologic intervention presently, whereas if no action is taken, over 700 km 2 will require high effort intervention by 2070. This synthesis of research models with management-focused decision models demonstrates a tangible advance in bridging the gap between process-based research and restoration needs.

Maryland, Virginia↗

Lake Number, a quantitative indicator of mixing used to estimate changes in dissolved oxygen

Lake Number, L N , values are shown to be quantitative indicators of deep mixing in lakes and reservoirs that can be used to estimate changes in deep water dissolved oxygen (DO) concentrations. L N is a dimensionless parameter defined as the ratio of the moments about the center of volume of the water body, of the stabilizing force of gravity associated with density stratification to the destabilizing forces supplied by wind, cooling, inflow, outflow, and other artificial mixing devices. To demonstrate the universality of this parameter, L N values are used to describe the extent of deep mixing and are compared with changes in DO concentrations in three reservoirs in Australia and four lakes in the U.S.A., which vary in productivity and mixing regimes. A simple model is developed which relates changes in L N values, i.e., the extent of mixing, to changes in near bottom DO concentrations. After calibrating the model for a specific system, it is possible to use real-time L N values, calculated using water temperature profiles and surface wind velocities, to estimate changes in DO concentrations (assuming unchanged trophic conditions).

Wisconsin↗

Microbially mediated barite dissolution in anoxic brines

Fluids injected into shale formations during hydraulic fracturing of black shale return with extraordinarily high total-dissolved-solids (TDS) and high concentrations of barium (Ba) and radium (Ra). Barite, BaSO 4 , has been implicated as a possible source of Ba as well as a problematic mineral scale that forms on internal well surfaces, often in close association with radiobarite, (Ba,Ra)SO 4 . The dissolution of barite by abiotic processes is well quantified. However, the identification of microbial communities in flowback and produced water necessitates the need to understand barite dissolution in the presence of bacteria. Therefore, we evaluated the rates and mechanisms of abiotic and microbially-mediated barite dissolution under anoxic and hypersaline conditions in the laboratory. Barite dissolution experiments were conducted with bacterial enrichment cultures established from produced water from Marcellus Shale wells located in northcentral Pennsylvania. These cultures were dominated by anaerobic halophilic bacteria from the genus Halanaerobium . Dissolved Ba was determined by ICP-OES and barite surfaces were investigated by SEM and AFM. Our results reveal that: 1) higher amounts of barium (up to ∼5 × ) are released from barite in the presence of Halanaerobium cultures compared to brine controls after 30 days of reaction, 2) etch pits that develop on the barite (001) surface in the presence of Halanaerobium exhibit a morphology that is distinct from those that form during control experiments without bacteria, 3) etch pits that develop in the presence of Halanaerobium exhibit a morphology that is similar to the morphology of etch pits formed in the presence of strong organic chelators, EDTA and DTPA, and 4) experiments using dialysis membranes to separate barite from bacteria suggest that direct contact between the two is not required in order to promote dissolution. These results suggest that Halanaerobium increase the rate of barite dissolution in anoxic and high ionic strength solutions. Additionally, the increase in rate occurs without direct microbe-mineral contact suggesting that metabolites secreted by the bacteria may be responsible for promotion of dissolution. The findings of this study have implications for understanding barium cycling in marine/hypersaline environments, release of barium (and associated radium) from waste solids generated from energy and mining industries, as well as potential for developing new anti-scaling chemicals.

Applied Geochemistry↗

Structural control of coalbed methane production in Alabama

Thin-skinned structures are distributed throughout the Alabama coalbed methane fields, and these structures affect the production of gas and water from coal-bearing strata. Extensional structures in Deerlick Creek and Cedar Cove fields include normal faults and hanging-wall rollovers, and area balancing indicates that these structures are detached in the Pottsville Formation. Compressional folds in Gurnee and Oak Grove fields, by comparison, are interpreted to be detachment folds formed above decollements at different stratigraphic levels. Patterns of gas and water production reflect the structural style of each field and further indicate that folding and faulting have affected the distribution of permeability and the overall success of coalbed methane operations. Area balancing can be an effective way to characterize coalbed methane reservoirs in structurally complex regions because it constrains structural geometry and can be used to determine the distribution of layer-parallel strain. Comparison of calculated requisite strain and borehole expansion data from calliper logs suggests that strain in coalbed methane reservoirs is predictable and can be expressed as fracturing and small-scale faulting. However, refined methodology is needed to analyze heterogeneous strain distributions in discrete bed segments. Understanding temporal variation of production patterns in areas where gas and water production are influenced by map-scale structure will further facilitate effective management of coalbed methane fields.Thin-skinned structures are distributed throughout the Alabama coalbed methane fields, and these structures affect the production of gas and water from coal-bearing strata. Extensional structures in Deerlick Creek and Cedar Cove fields include normal faults and hanging-wall rollovers, and area balancing indicates that these structures are detached in the Pottsville Formation. Compressional folds in Gurnee and Oak Grove fields, by comparison, are interpreted to be detachment folds formed above decollements at different stratigraphic levels. Patterns of gas and water production reflect the structural style of each field and further indicate that folding and faulting have affected the distribution of permeability and the overall success of coalbed methane operations. Area balancing can be an effective way to characterize coalbed methane reservoirs in structurally complex regions because it constrains structural geometry and can be used to determine the distribution of layer-parallel strain. Comparison of calculated requisite strain and borehole expansion data from calliper logs suggests that strain in coalbed methane reservoirs is predictable and can be expressed as fracturing and small-scale faulting. However, refined methodology is needed to analyze heterogeneous strain distributions in discrete bed segments. Understanding temporal variation of production patterns in areas where gas and water production are influenced by map-scale structure will further facilitate effective management of coalbed methane fields.

International Journal of Coal Geology↗

Geologic framework and hydrogeology of the Rio Rico and Nogales 7.5’ quadrangles, upper Santa Cruz Basin, Arizona, with three-dimensional hydrogeologic model

Rapid population growth and declining annual recharge to aquifers in the upper Santa Cruz Basin area of southern Arizona, have increased the demand for additional groundwater resources. This demand is predicted to escalate in the future because of higher temperatures, longer droughts, less aquifer recharge, and decreased river and stream base flow. We conducted geologic studies to help evaluate and better understand groundwater resources in the basin. Results of these studies are presented in this report, which summarizes the basin geologic framework and hydrogeology, and presents a threedimensional (3D) hydrogeologic model for the Rio Rico and Nogales 7.5′ quadrangles. Three major hydrogeologic units are displayed in the 3D model; a lower basement confining unit, consisting of Jurassic, Cretaceous, and Tertiary (Paleocene and Oligocene) rocks; a middle unit composed entirely of the Miocene Nogales Formation; and an upper unit consisting of late Miocene to Holocene surficial deposits. The Nogales Formation and the late Miocene to Holocene sediments are the main aquifers in the upper Santa Cruz Basin. The 3D model integrates the hydrogeologic units and faults to define the geometry, structure, and thickness of the aquifer system that provides water to Nogales and surrounding communities of southernmost Arizona. The report includes an EarthVision 3D Viewer, consisting of software enabling the user to view data interactively in 3D space to help explain the internal complexities of the basin geometry, structure, stratigraphy, and hydrology. The 3D model is a synthesis of geologic data from geologic maps, cross sections, and lithologic descriptions and interpretations; and geophysical data including gravity, magnetic data, and airborne electromagnetic data.

Arizona↗

Epizootic ulcerative syndrome caused by Aphanomyces invadans in captive bullseye snakehead Channa marulius collected from south Florida, USA

Epizootic ulcerative syndrome (EUS) caused by the oomycete Aphanomyces invadans is an invasive, opportunistic disease of both freshwater and estuarine fishes. Originally documented as the cause of mycotic granulomatosis of ornamental fishes in Japan and as the cause of EUS of fishes in southeast Asia and Australia, this pathogen is also present in estuaries and freshwater bodies of the Atlantic and gulf coasts of the USA. We describe a mass mortality event of 343 captive juvenile bullseye snakehead Channa marulius collected from freshwater canals in Miami-Dade County, Florida. Clinical signs appeared within the first 2 d of captivity and included petechiae, ulceration, erratic swimming, and inappetence. Histological examination revealed hyphae invading from the skin lesions deep into the musculature and internal organs. Species identification was confirmed using a species-specific PCR assay. Despite therapeutic attempts, 100% mortality occurred. This represents the first documented case of EUS in bullseye snakehead fish collected from waters in the USA. Future investigation of the distribution and prevalence of A. invadans within the bullseye snakehead range in south Florida may give insight into this pathogen-host system.

Florida↗

Spring viremia of carp

pring viremia of carp (SVC) is an important disease affecting cyprinids, mainly common carp Cyprinus carpio . The disease is widespread in European carp culture, where it causes significant morbidity and mortality. Designated a notifiable disease by the Office International des Epizooties, SVC is caused by a rhabdovirus, spring viremia of carp virus (SVCV). Affected fish show destruction of tissues in the kidney, spleen and liver, leading to hemorrhage, loss of water-salt balance and impairment of immune response. High mortality occurs at water temperatures of 10 to 17°C, typically in spring. At higher temperatures, infected carp develop humoral antibodies that can neutralize the spread of virus and such carp are protected against re-infection by solid immunity. The virus is shed mostly with the feces and urine of clinically infected fish and by carriers. Waterborne transmission is believed to be the primary route of infection, but bloodsucking parasites like leeches and the carp louse may serve as mechanical vectors of SVCV. The genome of SVCV is composed of a single molecule of linear, negative-sense, single-stranded RNA containing 5 genes in the order 3¹-NPMGL-5¹ coding for the viral nucleoprotein, phosphoprotein, matrix protein, glycoprotein, and polymerase, respectively. Polyacrylamide gel electrophoresis of the viral proteins, and sequence homologies between the genes and gene junctions of SVCV and vesicular stomatitis viruses, have led to the placement of the virus as a tentative member of the genus Vesiculovirus in the family Rhabdoviridae . These methods also revealed that SVCV is not related to fish rhabdoviruses of the genus Novirhabdovirus . In vitro replication of SVCV takes place in the cytoplasm of cultured cells of fish, bird and mammalian origin at temperatures of 4 to 31°C, with an optimum of about 20°C. Spring viremia of carp can be diagnosed by clinical signs, isolation of virus in cell culture and molecular methods. Antibodies directed against SVCV react with the homologous virus in serum neutralization, immunofluorescence, immunoperoxidase, or enzyme-linked immunosorbent assays, but they cross-react to various degrees with the pike fry rhabdovirus (PFR), suggesting the 2 viruses are closely related. However, SVCV and PFR can be distinguished by certain serological tests and molecular methods such as the ribonuclease protection assay.

Diseases of Aquatic Organisms↗

Hydrological information products for the Off-Project Water Program of the Klamath Basin Restoration Agreement

The Klamath Basin Restoration Agreement (KBRA) was developed by a diverse group of stakeholders, Federal and State resource management agencies, Tribal representatives, and interest groups to provide a comprehensive solution to ecological and water-supply issues in the Klamath Basin. The Off-Project Water Program (OPWP), one component of the KBRA, has as one of its purposes to permanently provide an additional 30,000 acre-feet of water per year on an average annual basis to Upper Klamath Lake through "voluntary retirement of water rights or water uses or other means as agreed to by the Klamath Tribes, to improve fisheries habitat and also provide for stability of irrigation water deliveries." The geographic area where the water rights could be retired encompasses approximately 1,900 square miles. The OPWP area is defined as including the Sprague River drainage, the Sycan River drainage downstream of Sycan Marsh, the Wood River drainage, and the Williamson River drainage from Kirk Reef at the southern end of Klamath Marsh downstream to the confluence with the Sprague River. Extensive, broad, flat, poorly drained uplands, valleys, and wetlands characterize much of the study area. Irrigation is almost entirely used for pasture. To assist parties involved with decisionmaking and implementation of the OPWP, the U.S. Geological Survey (USGS), in cooperation with the Klamath Tribes and other stakeholders, created five hydrological information products. These products include GIS digital maps and datasets containing spatial information on evapotranspiration, subirrigation indicators, water rights, subbasin streamflow statistics, and return-flow indicators. The evapotranspiration (ET) datasets were created under contract for this study by Evapotranspiration, Plus, LLC, of Twin Falls, Idaho. A high-resolution remote sensing technique known as Mapping Evapotranspiration at High Resolution and Internalized Calibration (METRIC) was used to create estimates of the spatial distribution of ET. The METRIC technique uses thermal infrared Landsat imagery to quantify actual evapotranspiration at a 30-meter resolution that can be related to individual irrigated fields. Because evaporation uses heat energy, ground surfaces with large ET rates are left cooler as a result of ET than ground surfaces that have less ET. As a consequence, irrigated fields appear in the Landsat images as cooler than nonirrigated fields. Products produced from this study include total seasonal and total monthly (April-October) actual evapotranspiration maps for 2004 (a dry year) and 2006 (a wet year). Maps showing indicators of natural subirrigation were also provided by this study. "Subirrigation" as used here is the evapotranspiration of shallow groundwater by plants with roots that penetrate to or near the water table. Subirrigation often occurs at locations where the water table is at or above the plant rooting depth. Natural consumptive use by plants diminishes the benefit of retiring water rights in subirrigated areas. Some agricultural production may be possible, however, on subirrigated lands for which water rights are retired. Because of the difficulty in precisely mapping and quantifying subirrigation, this study presents several sources of spatially mapped data that can be used as indicators of higher subirrigation probability. These include the floodplain boundaries defined by stream geomorphology, water-table depth defined in Natural Resources Conservation Service (NRCS) soil surveys, and soil rooting depth defined in NRCS soil surveys. The two water-rights mapping products created in the study were "points of diversion" (POD) and "place of use" (POU) for surface-water irrigation rights. To create these maps, all surface-water rights data, decrees, certificates, permits, and unadjudicated claims within the entire 1,900 square mile study area were aggregated into a common GIS geodatabase. Surface-water irrigation rights within a 5-mile buffer of the study area were then selected and identified. The POU area was then totaled by water right for primary and supplemental water rights. The maximum annual volume (acre-feet) allowed under each water right also was calculated using the POU area and duty (allowable annual irrigation application in feet). In cases where a water right has more than one designated POD, the total volume for the water right was equally distributed to each POD listed for the water right. Because of this, mapped distribution of diversion rates for some rights may differ from actual practice. Water-right information in the map products was from digital datasets obtained from the Oregon Water Resources Department and was, at the time acquired, the best available compilation of water-right information available. Because the completeness and accuracy of the water-right data could not be verified, users are encouraged to check directly with the Oregon Water Resources Department where specific information on individual rights or locations is essential. A dataset containing streamflow statistics for 72 subbasins in the study area was created for the study area. The statistics include annual flow durations (5-, 10-, 25-, 50-, and 95-percent exceedances) and 7-day, 10-year (7Q10) and 7-day, 2-year (7Q2) low flows, and were computed using regional regression equations based on measured streamflow records in the region. Daily streamflow records used were adjusted as needed for crop consumptive use; therefore the statistics represent streamflow under more natural conditions as though irrigation diversions did not exist. Statistics are provided for flow rates resulting from streamflow originating from within the entire drainage area upstream of the subbasin pour point (referring to the outlet of the contributing drainage basin). The statistics were computed for the purpose of providing decision makers with the ability to estimate streamflow that would be expected after water conservation techniques have been implemented or a water right has been retired. A final product from the study are datasets of indicators of the potential for subsurface return flow of irrigation water from agricultural areas to nearby streams. The datasets contain information on factors such as proximity to surface-water features, geomorphic floodplain characteristics, and depth to water. The digital data, metadata, and example illustrations for the datasets described in this report are available on-line from the USGS Water Resources National Spatial Data Infrastructure (NSDI) Node Website http://water.usgs.gov/lookup/getgislist or from the U.S. Government website DATA.gov at http://www.data.gov with links provided in a Microsoft® Excel® workbook in appendix A.

California;Oregon↗

Dynamics within geyser conduits, and sensitivity to environmental perturbations: insights from a periodic geyser in the El Tatio Geyser Field, Atacama Desert, Chile

Despite more than 200 years of scientific study, the internal dynamics of geyser systems remain poorly characterized. As a consequence, there remain fundamental questions about what processes initiate and terminate eruptions, and where eruptions begin. Over a one-week period in October 2012, we collected down-hole measurements of pressure and temperature in the conduit of an exceptionally regular geyser (132 s/cycle) located in the Chilean desert. We identified four stages in the geyser cycle: (1) recharge of water into the conduit after an eruption, driven by the pressure difference between water in the conduit and in a deeper reservoir; (2) a pre-eruptive stage that follows the recharge and is dominated by addition of steam from below; (3) the eruption, which occurs by rapid boiling of a large mass of water at the top of the water column, and decompression that propagates boiling conditions downward; (4) a relaxation stage during which pressure and temperature decrease until conditions preceding the recharge stage are restored. Eruptions are triggered by the episodic addition of steam coming from depth, suggesting that the dynamics of the eruptions are dominated by geometrical and thermodynamic complexities in the conduit and reservoir. Further evidence favoring the dominance of internal processes in controlling periodicity is also provided by the absence of responses of the geyser to environmental perturbations (air pressure, temperature and probably also Earth tides).

Atacama Desert↗

Quantification of sucralose in groundwater well drinking water by silylation derivatization and gas chromatography-mass spectrometry

Sucralose is an increasingly popular artificial sweetener and has been found in the environment in groundwater, surface water, and wastewater treatment plant effluent. Its chemical properties make it strongly recalcitrant in the environment and it has been used as a conservative tracer of human wastewater in recent years. Most current methods of sucralose analysis use high performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS) instrumentation. In this study, we describe an analytical method using silylation derivatization and gas chromatography mass spectrometry (GC-MS) for the quantification of sucralose in groundwater samples. This method employs a deuterium-labeled internal standard to account for reaction and sample processing imprecision. The deuterated internal standard as well as experiments using negative ion chemical ionization gas chromatography-mass spectrometry strongly indicate that sucralose is derivatized at all five hydroxyl positions with trimethyl silyl groups. A previously developed GC-MS method with derivatization of sucralose in environmental samples did not employ an internal standard for quantification. As such, this method represents a more robust methodological approach for sucralose quantification in environmental samples. The method detection limit based on a set of 15 method blanks was calculated to be 21.8 ng L −1 , which is competitive with most methods in the published literature and sufficient to detect sucralose in water with ∼0.1% wastewater contribution. The method was applied to 37 groundwater samples from drinking water wells in California's Central Valley, in which five samples (13.5%) were found to contain sucralose at concentrations greater than the 21.8 ng L −1 detection limit.

Analytical Methods↗

Microbial water quality during the northern migration of Sandhill Cranes (Grus canadensis) at the central Platte River, Nebraska

The central Platte River is an important resource in Nebraska. Its water flows among multiple channels and supports numerous beneficial uses such as drinking water, irrigation for agriculture, groundwater recharge, and recreational activities. The central Platte River valley is an important stopover for migratory waterfowl and cranes, such as the Whooping ( Grus americana ) and Sandhill Cranes ( Grus canadensis ), in their annual northward traversal of the Central Flyway. Waterfowl, cranes, and other migratory birds moving across international and intercontinental borders may provide long-range transportation for any microbial pathogen they harbor, particularly through the spread of feces. Samples were collected weekly in the study reach from three sites (upstream, middle, and downstream from the roosting locations) during the spring of 2009 and 2010. The samples were analyzed for avian influenza, Escherichia coli, Cryptosporidium, Giardia, Campylobacter , and Legionella . Analysis indicates that several types of fecal indicator bacteria and a range of viral, protozoan, and bacterial pathogens were present in Sandhill Crane excreta. These bacteria and pathogens were present at a significantly higher frequency and densities in water and sediments when the Sandhill Cranes were present, particularly during evening roosts within the Platte River environment.

Nebraska↗

A model to locate potential areas for lake sturgeon spawning habitat construction in the St. Clair–Detroit River System

In response to a need for objective scientific information that could be used to help remediate loss of fish spawning habitat in the St. Clair River and Detroit River International Areas of Concern, this paper summarizes a large-scale geographic mapping investigation. Our study integrates data on two variables that many riverine fishes respond to in selecting where to spawn in these waters (water flow velocity and water depth) with available maps of the St. Clair–Detroit River System (SC–DRS). Our objectives were to locate and map these two physical components of fish habitat in the St. Clair and Detroit rivers and Lake St. Clair using a geographic information system (GIS) and to identify where, theoretically, fish spawning habitat could be remediated in these rivers. The target fish species to which this model applies is lake sturgeon (Acipenser fulvescens), but spawning reefs constructed for lake sturgeon in this system have been used for spawning by 17 species of fish. Our analysis revealed areas in each river that possessed suitable water velocity and depth for fish spawning and therefore could theoretically be remediated by the addition of rock-rubble substrate like that used at two previously remediated sites in the Detroit River at Belle Isle and Fighting Island. Results of our analysis revealed that only 3% of the total area of the SC–DRS possesses the necessary combination of water depth and high flow velocity to be indicated by the model as potential spawning habitat for lake sturgeon.

Michigan, Ontario↗

The A and m coefficients in the Bruun/Dean equilibrium profile equation seen from the Arctic

The Bruun/Dean relation between water depth and distance from the shore with a constant profile shape factor is widely used to describe shoreface profiles in temperate environments. However, it has been shown that the sediment scale parameter (A) and the profile shape factor (m) are interrelated variables. An analysis of 63 Arctic erosional shoreface profiles shows that both coefficients are highly variable. Relative frequency of the average m value is only 16% by the class width 0.1. No other m value frequency exceeds 21%. Therefore, there is insufficient reason to use average m to characterize Arctic shoreface profile shape. The shape of each profile has a definite combination of A and m values. Coefficients A and m show a distinct inverse relationship, as in temperate climate. A dependence of m values on coastal sediment grain size is seen, and m decreases with increasing grain size. With constant m = 0.67, parameter A obtains a dimension unit m1/3. But A equals the water depth in meters 1 m from the water edge. This fact and the variability of parameter m testify that the Bruun/Dean equation is essentially an empirical formula. There is no need to give any measurement unit to parameter A. But the International System of Units (SI) has to be used in applying the Bruun/Dean equation for shoreface profiles. A comparison of the shape of Arctic shoreface profiles with those of temperate environments shows surprising similarity. Therefore, the conclusions reached in this Arctic paper seem to apply also to temperate environments.

Journal of Coastal Research↗

Quality-assurance data for routine water quality analyses by the U. S. Geological Survey laboratory in Troy, New York; July 1993 through June 1995

A laboratory for analysis of low-ionic strength water has been developed at the U.S. Geological Survey (USGS) office in Troy, N.Y., to analyze samples collected by USGS projects in the Northeast. The laboratory's quality-assurance program is based on internal and interlaboratory quality-assurance samples and quality-control procedures developed to ensure proper sample collection, processing, and analysis. The quality-assurance/quality-control data are stored in the laboratory's SAS data-management system, which provides efficient review, compilation, and plotting of quality-assurance/quality-control data. This report presents and discusses samples analyzed from July 1993 through June 1995. Quality-control results for 18 analytical procedures were evaluated for bias and precision. Control charts show that data from seven of the analytical procedures were biased throughout the analysis period for either high-concentration or low-concentration samples but were within control limits; these procedures were: acid-neutralizing capacity, dissolved inorganic carbon, dissolved organic carbon (soil expulsions), chloride, magnesium, nitrate (colorimetric method), and pH. Three of the analytical procedures were occasionally biased but were within control limits; they were: calcium (high for high-concentration samples for May 1995), dissolved organic carbon (high for highconcentration samples from January through September 1994), and fluoride (high in samples for April and June 1994). No quality-control sample has been developed for the organic monomeric aluminum procedure. Results from the filter-blank and analytical-blank analyses indicate that all analytical procedures in which blanks were run were within control limits, although values for a few blanks were outside the control limits. Blanks were not analyzed for acid-neutralizing capacity, dissolved inorganic carbon, fluoride, nitrate (colorimetric method), or pH. Sampling and analysis precision are evaluated herein in terms of the coefficient of variation obtained for triplicate samples in 14 of the 18 procedures. Data-quality objectives were met by more than 90 percent of the samples analyzed in all procedures except total monomeric aluminum (85 percent of samples met objectives), total aluminum (70 percent of samples met objectives), and dissolved organic carbon (85 percent of samples met objectives). Triplicate samples were not analyzed for ammonium, fluoride, dissolved inorganic carbon, or nitrate (colorimetric method). Results of the USGS interlaboratory Standard Reference Sample Program indicated high data quality with a median result of 3.6 of a possible 4.0. Environment Canada's LRTAP interlaboratory study results indicated that more than 85 percent of the samples met data-quality objectives in 6 of the 12 analyses; exceptions were calcium, dissolved organic carbon, chloride, pH, potassium, and sodium. Data-quality objectives were not met for calcium samples in one LRTAP study, but 94 percent of samples analyzed were within control limits for the remaining studies. Data-quality objectives were not met by 35 percent of samples analyzed for dissolved organic carbon, but 94 percent of sample values were within 20 percent of the most probable value. Data-quality objectives were not met for 30 percent of samples analyzed for chloride, but 90 percent of sample values were within 20 percent of the most probable value. Measurements of samples with a pH above 6.0 were biased high in 54 percent of the samples, although 85 percent of the samples met data-quality objectives for pH measurements below 6.0. Data-quality objectives for potassium and sodium were not met in one study (only 33 percent of the samples analyzed met the objectives), although 85 percent of the sample values were within control limits for the other studies. Measured sodium values were above the upper control limit in all studies. Results from blind reference-sample analyses indicated that data

Open-File Report↗

Tectonically controlled fan delta and submarine fan sedimentation of late Miocene age, southern Temblor Range, California

The Santa Margarita Formation in the southern Temblor Range, composed of conglomerate and subordinate sandstone, evolved as a large complex of fan deltas and submarine fans in late Miocene time. An 80 to 90-m.y.-old granitic basement of the Salinian block and an accompanying 23.5-m.y.-old volcanic field now located in the northern Gabilan Range and the Pinnacles area, respectively, were the primary source terranes. In general, the fan deltas crop out along the west side of the southern Temblor Range, whereas the proximal parts of the submarine fans crop out along the east side of the range. The fan deltas consist of subaerial topset beds and low-angle basinward-dipping subaqueous foreset beds. Strata interpreted to be topset beds are composed largely of conglomerate with thick to very thick horizontal beds and matrix-supported clasts. Most of the thick to very thick conglomerate beds are internally massive and disorganized. Strata interpreted as foreset beds are composed of thick-bedded, large-scale, low-angle, cross-stratified conglomerate and sandstone units which commonly are internally massive. Abundant molluskan macrofossils such as Ostrea and Pecten are present in the subaqueous foreset beds; many have been displaced downslope from their original site of deposition. Conglomerate- and sandstone-filled submarine canyons, through which coarse-grained detritus was transported to the adjacent submarine fans, locally have cut into the foreset beds of the fan deltas. These submarine canyon deposits are generally better stratified than adjacent foreset-bed deposits, and they consist of thick horizontal beds, internally massive or normally graded, arranged in fining- and thinning-upward sequences. Isolated and composite conglomerate- and sandstone-filled channels, which crop out on the east flank of the southern Temblor Range, are interpreted as proximal submarine-fan channel deposits. These channel-form conglomerate and sandstone deposits are characterized by thick, horizontal beds which are internally massive or normally graded containing division T a , and locally T b , of the Bouma sequence. Sparse calcareous foraminifers collected from diatomaceous interbeds suggest that these fan channels were deposited in upper bathyal water depths. Subaerial and regenerated subaqueous debris flows probably formed the bulk of the Santa Margarita fan delta and submarine fan system. Santa Margarita debris flows ranged from the mudflow variety to the cataclysmic debris-avalanche variety. The cogenetic Republic and Williams sandstones of local usage, located on the east side of the southern Temblor Range, are slightly older and finer grained than the Santa Margarita Formation. These units, containing well-graded sandstones, fining- and thinning-upward and coarsening- and thickening-upward sandstone sequences, thick-bedded tabular and channel-shaped sandstones, a mixture of shallow- and deep-water foraminifers, and a fan-shaped geometry in the subsurface, are interpreted as submarine fan deposits. Sedimentation associated with the Santa Margarita Formation was intimately related to the growing southern Temblor Range anticlinorium and the right-laterally shifting Salinian block along the San Andreas fault. Examples of control exerted on Santa Margarita sedimentation by the southern Temblor Range anticlinorium include the preferential accumulation of sediments along the flanks of the anticlinorium, thickening of strata on the downthrown side of the Recruit Pass fault and on flanks of selected anticlines, intraformational unconformities, and possible partial blockage of the eastward-prograding fan deltas by the Recruit Pass fault. East of the growing southern Temblor Range anticlinorium, the distal ends of the Santa Margarita submarine fans were deflected northwestward by the growing Buena Vista Hills anticline. Several examples of well-defined diachronous sedimentation, where conglomerates and sandstones of the Santa Margarita Formation occupy progressively higher stratigraphic levels in a northwest direction subparallel to the trace of the San Andreas fault, strongly imply that the Salinian basement terrane was shifting in a right-lateral sense during Santa Margarita sedimentation. Regional factors of importance in focusing conglomerate sedimentation on the southern Temblor Range locale for a 2- to 3-m.y. period in the late Mohnian were right-lateral oblique slip on the San Andreas fault, formation of the "big bend" in the San Andreas fault by left-lateral slip along the Garlock and White Wolf faults, and the partial overlap of the Salinian and Franciscan assemblage basement rocks.

California↗

Hydrologic evaluation of salinity control and reclamation projects in the Indus Plain, Pakistan--A summary

This report summarizes the observations and findings of a team of four specialists from the U.S. Geological Survey assigned to Pakistan under the auspices of the U.S. Agency for International Development during May to August 1972 for a hydrologic evaluation of Salinity Control and Reclamation Projects in the Indus Plain Individual members of the team undertook comprehensive studies related to climatology, surface-water hydrology, and the canal system; streamflow and sediment yields of the rivers; computer applications to hydrologic data; aquifer characteristics; hydrologic evaluation of Salinity Control and Reclamation Projects (SCARPs); tubewell performance; hydrology of shallow versus deep tubewells; well and well-screen design in the Indus Plain; evaluation of observed and anticipated trends in both private and public tubewell development; evaluation of water-quality programs, data analysis, and records, and computer coding of special water-quality data; and evaluation of water-level data, well discharge and specific-capacity tests and aquifer tests. The reclamation program, by pumping from tubewells, has been notably successful in lowering the water table, in providing supplemental water for irrigation and for leaching of salinized soils, and in improving crop production. Some changes in water quality have been observed in SCARP-I and the Mona Scheme of SCARP-II, but these have not as yet (1972) significantly affected the utility of the water for irrigation. Problems associated with reclamation include control of deterioration in performance of tubewells and their rehabilitation, local brackish or saline-water encroachment, and maintenance of a favorable salt balance in the ground-water system. Rapid and as yet (1972) unregulated growth of shallow private tubewell development in the past decade has introduced complicating factors to the reclamation planning of the early 1960's which had emphasized public tubewell development through the SCARP program. In comparing shallow (0-200 feet) with deep (200-400 feet} tubewell development, it is concluded that long-term response of the water table is the same, whether many shallow wells of small capacity or fewer deeper wells of large capacity pump the same total volume of water in the same area. Moreover, it is concluded that there is no definite advantage for either type of pumping regime with respect to water quality. Utilization of the Punjab aquifer could be greatly enhanced by recharge of high-quality water diverted from the Chenab and Jhelum Rivers to the Ravi and Sutlej Rivers by way of the link and irrigation canals during periods of surplus flow. Recharge to the aquifer could also be improved by diversion of high-quality water from the Chenab and the Jhelum to natural nalas and other surface drainageways during periods of surplus flow. Such recharge would be of much better quality than water leaching downward from irrigated fields. Continued monitoring of the hydrologic system and research on problems engendered by reclamation are essential to the viability of the SCARP program and related water-resources development in the Indus River Basin.

Water Supply Paper↗

An intercomparison of oceanic methane and nitrous oxide measurements

Large-scale climatic forcing is impacting oceanic biogeochemical cycles and is expected to influence the water-column distribution of trace gases, including methane and nitrous oxide. Our ability as a scientific community to evaluate changes in the water-column inventories of methane and nitrous oxide depends largely on our capacity to obtain robust and accurate concentration measurements that can be validated across different laboratory groups. This study represents the first formal international intercomparison of oceanic methane and nitrous oxide measurements whereby participating laboratories received batches of seawater samples from the subtropical Pacific Ocean and the Baltic Sea. Additionally, compressed gas standards from the same calibration scale were distributed to the majority of participating laboratories to improve the analytical accuracy of the gas measurements. The computations used by each laboratory to derive the dissolved gas concentrations were also evaluated for inconsistencies (e.g., pressure and temperature corrections, solubility constants). The results from the intercomparison and intercalibration provided invaluable insights into methane and nitrous oxide measurements. It was observed that analyses of seawater samples with the lowest concentrations of methane and nitrous oxide had the lowest precisions. In comparison, while the analytical precision for samples with the highest concentrations of trace gases was better, the variability between the different laboratories was higher: 36 % for methane and 27 % for nitrous oxide. In addition, the comparison of different batches of seawater samples with methane and nitrous oxide concentrations that ranged over an order of magnitude revealed the ramifications of different calibration procedures for each trace gas. Finally, this study builds upon the intercomparison results to develop recommendations for improving oceanic methane and nitrous oxide measurements, with the aim of precluding future analytical discrepancies between laboratories.

Biogeosciences↗