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At least 613 records · Page 34Linked to original sources
USGS2025

Analysis of trends in terrestrial vegetation at Mediterranean Coast Network Parks: Channel Islands National Park

The five islands comprising Channel Islands National Park (CHIS) experience natural gradients in temperature and moisture driven by ocean currents. Additionally, the islands were used as ranchlands and military land before becoming a national park, resulting in widespread erosion and vegetation change. As a result, CHIS spans gradients in climate as well as ranching duration and time since animal removal. Vegetation monitoring was initiated in 1984 on three islands (Anacapa, Santa Barbara, San Miguel), in 1990 on Santa Rosa Island, and in 1998 on Santa Cruz Island, with the goal of documenting the long-term response of island vegetation to ranch animal removal and climate fluctuations. Since that time, monitoring has documented the range of natural fluctuation in island environments over decades and provided insights into vegetation change in ecosystems unencumbered by ongoing development. Long-term vegetation monitoring at CHIS is therefore a rare example of an ecosystem experiment that demonstrates the results of management actions and serves as a baseline for land managers and scientists worldwide. Terrestrial vegetation data collected between 1984 and 2018 were modeled to estimate trends over time and to characterize relationships with covariates related to site characteristics, nonnative mammal removal programs, and water balance metrics. Data were analyzed for trends in vegetation cover, woody plant density, and plant community diversity grouped by life form and nativity across all islands and within individual islands, as well as for several individual species that dominate plant communities or present challenges to native plant recovery. In all, a total of 162 trend and covariate models were tested in this study, the details of which are provided in this report. Briefly, results reflect a decline in nonnative annual disturbance-thriving species with the reduction in animal grazing and trampling. Increasing trends were observed in native shrub density and native shrub recruitment density, as well as native shrub cover across all islands averaged together and on Santa Cruz Island. However, opposite trends were seen on the smaller islands of Santa Barbara and Anacapa, where increasing seabird activity may be damaging vegetation. Further results indicate the importance of soil moisture, relative humidity, fog, precipitation, site exposure, and solar radiation for vegetation patterns and trends. In many instances, there are apparent interacting effects of environmental variables with trends related to nonnative mammal removal and site location. Vegetation patterns in space and time emerge in the dataset as nuanced responses to interacting drivers.

Calfornia↗
USGS2007

Influence of soil chemistry on metal and bioessential element concentrations in nymphal and adult periodical cicadas (Magicicada spp.)

Metal and bioessential element concentrations were measured in three species of 17-year periodical cicadas (Magicicada spp.) to determine how cicada tissue chemistry is affected by soil chemistry, measure the bioavailability of metals from both uncontaminated and lead-arsenate-pesticide contaminated soils, and assess the potential risks of observed metal contamination for wildlife. Periodical cicada nymphs feed on root xylem fluids for 13 or 17??years of underground development. The nymphs then emerge synchronously at high densities, before leaving their nymphal keratin exoskeleton and molting into their adult form. Cicadas are an important food source for birds and animals during emergence events, and influence nutrient cycles in woodland ecosystems. Nymphal exoskeletons and whole adult cicadas were sampled in Clarke and Frederick Counties, Virginia and Berkeley and Jefferson Counties, West Virginia during the Brood X emergence in May and June, 2004. Elements, such as Al, Fe, and Pb, are strongly enriched in the nymphal exoskeleton relative to the adult body; Cu and Zn are enriched in bodies. Concentrations of Fe and Pb, when normalized to relatively inert soil constituents such as Al and Ce, are similar in both the molt exoskeleton and their host soil, implying that passive assimilation through prolonged soil contact (adhesion or adsorption) might control these metal concentrations. Normalized concentrations of bioessential elements, such as S, P, K, Ca, Mn, Cu, Zn, and Mo, and chalcophile (sulfur-loving) elements, such as As, Se, and Au, indicate strong enrichment in cicada tissues relative to soil, implying selective absorption and retention by xylem fluids, the cicada nymphs themselves, or both. Element enrichment patterns in cicada tissues are similar to enrichment patterns observed in xylem fluids from tree roots. Chalcophile elements and heavy metals accumulate in keratin-rich tissues and may bind to sulfhydryl groups. Metal concentrations in the nymphal exoskeleton show a positive correlation with soil metal concentrations, with Au exhibiting particularly strong enrichment in the exoskeleton relative to soil concentrations. Metal concentrations in adult bodies do not correlate with soil chemistry. Bioessential elements S, Ca, Mn, Fe, and Zn differed by sex in adults, whereas Na, Mg, K, Ca, Mn, Fe, Zn, and As differed by species. Body concentrations of Ca differed by site conditions (orchard or reference setting). The high Pb contents of orchard soils contaminated by arsenical pesticide residues might inhibit Ca uptake by cicada nymphs. The adult cicadas contain concentrations of metals similar to, or less than, other invertebrates, such as earthworms. There does not appear to be a dietary threat to birds or other consumers of adult cicadas based on Maximum Tolerable Dietary Level (MTDL) Guidelines developed for agricultural animals.

Science of the Total Environment↗
USGS2021

A chemical and bio‐herbicide mixture increased exotic invaders, both targeted and non‐targeted, across a diversely invaded landscape after fire

Questions Invasive‐plant treatments often target a single or few species, but many landscapes are diversely invaded. Exotic annual grasses (EAGs) increase wildfires and degrade native perennial plant communities in cold‐desert rangelands, and herbicides are thus sprayed to inhibit EAG germination and establishment. We asked how EAG target and non‐target species responded to an herbicide mixture sprayed over a large, topographically diverse landscape after wildfire. We focused on how whole‐community and natural EAG‐pathogen treatment responses varied over years and physical properties of sites. Location Sagebrush steppe of southwest Idaho, USA. Methods We monitored plant cover and diversity in 41 pairs of plots located inside or outside areas (486 ha total) treated with a combined aerial broadcast spray of pre‐emergent herbicide (imazapic) and weed‐suppressive bacteria ( Pseudomonas fluorescens , “MB906”) to target EAGs after wildfires. Results EAG cover and exotic species richness were initially less in treated plots but increased to levels similar to or greater than those of untreated plots by the third post‐treatment year. The EAG pathogen Ustilago bullata was not directly affected by the treatment. The treatment increased exotic perennial forb cover in all plots and exotic annual forb cover in cooler/wetter plots but reduced exotic annual forb cover in warmer/drier plots. Cover of the invasive biennial grass Poa bulbosa decreased more across study years in untreated than treated plots. Among natives, the treatment reduced perennial grass cover and annual forb presence but led to marginal increases in perennial forb cover and, on soils with less gravel, increased shrub presence. Conclusions A treatment targeting a single plant functional group did not achieve lasting success in these diversely invaded communities. Spraying alone did not release native perennials sufficiently to counteract the simultaneous release of secondary invaders and the return of target invaders. Planting or seeding may also be needed to achieve management goals.

Idaho↗
USGS2018

Applying recreation ecology science to sustainably manage camping impacts: A classification of camping management strategies

Wilderness and other protected natural areas such as national forests, parks, and refuges are managed to provide high-quality recreational opportunities while preserving natural resource conditions. In managing recreation visitation, land managers could allow visitors to create their own infrastructure of trails and campsites, or they could choose to apply an impact management strategy to provide an infrastructure that includes sustainably designed trails and campsites. Recreation ecology studies have repeatedly demonstrated that informal “visitor-created” trails and campsites are generally not sustainably designed or located (Cole 1981, 1982a, 2013; Marion 2016; Wimpey and Marion 2011). For example, informal trails frequently occur in flat terrain where trail widening and muddiness can be chronic problems, or are fall-aligned (perpendicular to contour lines) in sloping terrain, where they are considerably more vulnerable to soil loss and widening (Marion et al. 2016; Marion and Wimpey 2017). Similarly, visitors are highly attracted to flat terrain near water for camping, where they frequently create substantial numbers of large and unnecessary campsites at densities that threaten visitor solitude, experiential qualities, and natural resources.

International Journal of Wilderness↗
USGS2001

Tampa Bay Integrated Science Pilot Study: wetland characterization

Coastal wetlands in Tampa Bay consist of mangrove forest and tidal salt marsh. Wetlands buffer storm surges, provide fish and wildlife habitat, and enhance water quality through the removal of water-borne nutrients and contaminants. Substantial areas of both mangrove and salt marsh have been lost to agricultural, residential and industrial development in this urban estuary. Wetlands restoration has been initiated in Tampa Bay. Baseline studies on the current condition of wetlands and historical and prehistorical information is needed for successful restoration planning and evaluation. A major objective of this component of the Tampa Bay pilot program was to characterize wetlands in Tampa Bay beginning with areas that differ in their degree of human-induced disturbance ( Fig. 1 ). The Alafia River area is urbanized, industrialized and dredged, whereas the Terra Ceia area has a history of agricultural use with associated soil berms and mosquito ditches, but has not been farmed for at least 20 years ( Fig. 2 ).

Open-File Report↗
USGS2004

Response to comment on "A reservoir of nitrate beneath desert soils"

We appreciate the comment by Jackson et al. ( 1 ), which underscores two points made in our recent paper ( 2 ): (i) that desert subsoil nitrate (NO – 3 ) inventories are spatially highly variable, and thereby warrant substantial measurement efforts to reduce uncertainty in global extrapolations, and (ii) that Chihuahuan Desert subsoil NO – 3 inventories tend to be much smaller than inventories in other western U.S. deserts.

Science↗
USGS2012

Predicting Impacts of Increased CO2 and Climate Change on the Water Cycle and Water Quality in the Semiarid James River Basin of the Midwestern USA

Emissions of greenhouse gases and aerosols from human activities continue to alter the climate and likely will have significant impacts on the terrestrial hydrological cycle and water quality, especially in arid and semiarid regions. We applied an improved Soil and Water Assessment Tool (SWAT) to evaluate impacts of increased atmospheric CO2 concentration and potential climate change on the water cycle and nitrogen loads in the semiarid James River Basin (JRB) in the Midwestern United States. We assessed responses of water yield, soil water content, groundwater recharge, and nitrate nitrogen (NO3–N) load under hypothetical climate-sensitivity scenarios in terms of CO2, precipitation, and air temperature. We extended our predictions of the dynamics of these hydrological variables into the mid-21st century with downscaled climate projections integrated across output from six General Circulation Models. Our simulation results compared against the baseline period 1980 to 2009 suggest the JRB hydrological system is highly responsive to rising levels of CO2 concentration and potential climate change. Under our scenarios, substantial decrease in precipitation and increase in air temperature by the mid-21st century could result in significant reduction in water yield, soil water content, and groundwater recharge. Our model also estimated decreased NO3–N load to streams, which could be beneficial, but a concomitant increase in NO3–N concentration due to a decrease in streamflow likely would degrade stream water and threaten aquatic ecosystems. These results highlight possible risks of drought, water supply shortage, and water quality degradation in this basin.

Science of the Total Environment↗
USGS2002

Reactivity and mobility of new and old mercury deposition in a boreal forest ecosystem during the first year of the METAALICUS study

The METAALICUS (Mercury Experiment To Assess Atmospheric Loading In Canada and the US) project is a whole ecosystem experiment designed to study the activity, mobility, and availability of atmospherically deposited mercury. To investigate the dynamics of mercury newly deposited onto a terrestrial ecosystem, an enriched stable isotope of mercury ( 202 Hg) was sprayed onto a Boreal forest subcatchment in an experiment that allowed us, for the first time, to monitor the fate of “new” mercury in deposition and to distinguish it from native mercury historically stored in the ecosystem. Newly deposited mercury was more reactive than the native mercury with respect to volatilization and methylation pathways. Mobility through runoff was very low and strongly decreased with time because of a rapid equilibration with the large native pool of “bound” mercury. Over one season, only ∼8% of the added 202 Hg volatilized to the atmosphere and less than 1% appeared in runoff. Within a few months, approximately 66% of the applied 202 Hg remained associated with above ground vegetation, with the rest being incorporated into soils. The fraction of 202 Hg bound to vegetation was much higher than seen for native Hg (<5% vegetation), suggesting that atmospherically derived mercury enters the soil pool with a time delay, after plants senesce and decompose. The initial mobility of mercury received through small rain events or dry deposition decreased markedly in a relatively short time period, suggesting that mercury levels in terrestrial runoff may respond slowly to changes in mercury deposition rates.

Environmental Science & Technology↗
USGS2013

Application of the Precipitation-Runoff Modeling System (PRMS) in the Apalachicola-Chattahoochee-Flint River Basin in the southeastern United States

A hydrologic model of the Apalachicola–Chattahoochee–Flint River Basin (ACFB) has been developed as part of a U.S. Geological Survey (USGS) National Climate Change and Wildlife Science Center effort to provide integrated science that helps resource managers understand the effect of climate change on a range of ecosystem responses. The hydrologic model was developed as part of the Southeast Regional Assessment Project using the Precipitation Runoff Modeling System (PRMS), a deterministic, distributed-parameter, process-based system that simulates the effects of precipitation, temperature, and land use on basin hydrology. The ACFB PRMS model simulates streamflow throughout the approximately 50,700 square-kilometer basin on a daily time step for the period 1950–99 using gridded climate forcings of air temperature and precipitation, and parameters derived from spatial data layers of altitude, land cover, soils, surficial geology, depression storage (small water bodies), and data from 56 USGS streamgages. Measured streamflow data from 35 of the 56 USGS streamgages were used to calibrate and evaluate simulated basin streamflow; the remaining gage locations were used for model delineation only. The model matched measured daily streamflow at 31 of the 35 calibration gages with Nash-Sutcliffe Model Efficiency Index (NS) greater than 0.6. Streamflow data for some calibration gages were augmented for regulation and water use effects to represent more natural flow volumes. Time-static parameters describing land cover limited the ability of the simulation to match historical runoff in the more developed subbasins. Overall, the PRMS simulation of the ACFB provides a good representation of basin hydrology on annual and monthly time steps. Calibration subbasins were analyzed by separating the 35 subbasins into five classes based on physiography, land use, and stream type (tributary or mainstem). The lowest NS values were rarely below 0.6, whereas the median NS for all five classes was within 0.74 to 0.96 for annual mean streamflow, 0.89 to 0.98 for mean monthly streamflow, and 0.82 to 0.98 for monthly mean streamflow. The median bias for all five classes was within –4.3 to 0.8 percent for annual mean streamflow, –6.3 to 0.5 percent for mean monthly streamflow, and –9.3 to 1.3 percent for monthly mean streamflow. The NS results combined with the percent bias results indicated a good to very good streamflow volume simulation for all subbasins. This simulation of the ACFB provides a foundation for future modeling and interpretive studies. Streamflow and other components of the hydrologic cycle simulated by PRMS can be used to inform other types of simulations; water-temperature, hydrodynamic, and ecosystem-dynamics simulations are three examples. In addition, possible future hydrologic conditions could be studied using this model in combination with land cover projections and downscaled general circulation model results.

Alabama, Florida, Georgia↗
USGS2016

Contamination with bacterial zoonotic pathogen genes in U.S. streams influenced by varying types of animal agriculture

Animal waste, stream water, and streambed sediment from 19 small (< 32 km 2 ) watersheds in 12 U.S. states having either no major animal agriculture (control, n = 4), or predominantly beef ( n = 4), dairy ( n = 3), swine ( n = 5), or poultry ( n = 3) were tested for: 1) cholesterol, coprostanol, estrone, and fecal indicator bacteria (FIB) concentrations, and 2) shiga-toxin producing and enterotoxigenic Escherichia coli , Salmonella , Campylobacter , and pathogenic and vancomycin-resistant enterococci by polymerase chain reaction (PCR) on enrichments, and/or direct quantitative PCR. Pathogen genes were most frequently detected in dairy wastes, followed by beef, swine and poultry wastes in that order; there was only one detection of an animal-source-specific pathogen gene ( stx1 ) in any water or sediment sample in any control watershed. Post-rainfall pathogen gene numbers in stream water were significantly correlated with FIB, cholesterol and coprostanol concentrations, and were most highly correlated in dairy watershed samples collected from 3 different states. Although collected across multiple states and ecoregions, animal-waste gene profiles were distinctive via discriminant analysis. Stream water gene profiles could also be discriminated by the watershed animal type. Although pathogen genes were not abundant in stream water or streambed samples, PCR on enrichments indicated that many genes were from viable organisms, including several (shiga-toxin producing or enterotoxigenic E. coli , Salmonella , vancomycin-resistant enterococci) that could potentially affect either human or animal health. Pathogen gene numbers and types in stream water samples were influenced most by animal type, by local factors such as whether animals had stream access, and by the amount of local rainfall, and not by studied watershed soil or physical characteristics. Our results indicated that stream water in small agricultural U.S. watersheds was susceptible to pathogen gene inputs under typical agricultural practices and environmental conditions. Pathogen gene profiles may offer the potential to address both source of, and risks associated with, fecal pollution.

Arizona, Indiana, Iowa, Kentucky, Maryland, Michig↗
USGS2001

Formation and transport of the sulfonic acid metabolites of alachlor and metolachlor in soil

Alachlor and metolachlor are dechlorinated and transformed into their corresponding ethane sulfonic acid (ESA) metabolites in soil. In a field-disappearance study, it was shown that alachlor ESA was formed at a faster rate and at concentrations 2−4 times higher than metolachlor ESA, conforming with the observed longer disappearance half-life of metolachlor (15.5 d) in the field as compared to alachlor (8 d). Runoff data also showed higher concentrations of alachlor ESA as compared to metolachlor ESA, even though they were applied at the same levels. Data from soil cores showed transport of the ESA compounds in soil to as far down as 75−90 cm below the surface, at concentrations ranging from less than 0.5 μg/L to about 50 μg/L. In contrast, no parent herbicide was detected at these depths. This observation correlates with the higher log K oc values for alachlor (3.33) and metolachlor (3.01) relative to their corresponding ESA metabolites, alachlor ESA (2.26), and metolachlor ESA (2.29).

Environmental Science & Technology↗
USGS2012

Reducing Vulnerability of Ports and Harbors to Earthquake and Tsunami Hazards

Recent scientific research suggests the Pacific Northwest could experience catastrophic earthquakes in the near future, both from distant and local sources, posing a significant threat to coastal communities. Damage could result from numerous earthquake-related hazards, such as severe ground shaking, soil liquefaction, landslides, land subsidence/uplift, and tsunami inundation. Because of their geographic location, ports and harbors are especially vulnerable to these hazards. Ports and harbors, however, are important components of many coastal communities, supporting numerous activities critical to the local and regional economy and possibly serving as vital post-event, response-recovery transportation links. A collaborative, multi-year initiative is underway to increase the resiliency of Pacific Northwest ports and harbors to earthquake and tsunami hazards, involving Oregon Sea Grant (OSG), Washington Sea Grant (WSG), the National Oceanic and Atmospheric Administration Coastal Services Center (CSC), and the U.S. Geological Survey Center for Science Policy (CSP). Specific products of this research, planning, and outreach initiative include a regional stakeholder issues and needs assessment, a community-based mitigation planning process, a Geographic Information System (GIS) — based vulnerability assessment methodology, an educational web-site and a regional data archive. This paper summarizes these efforts, including results of two pilot port-harbor community projects, one in Yaquina Bay, Oregon and the other in Sinclair Inlet, Washington. Finally, plans are outlined for outreach to other port and harbor communities in the Pacific Northwest and beyond, using "getting started" workshops and a web-based tutorial.

Oregon, Washington↗
USGS2007

Multi-scale responses of vegetation to removal of horse grazing from Great Basin (USA) mountain ranges

Although free-roaming equids occur on all of the world's continents except Antarctica, very few studies (and none in the Great Basin, USA) have either investigated their grazing effects on vegetation at more than one spatial scale or compared characteristics of areas from which grazing has been removed to those of currently grazed areas. We compared characteristics of vegetation at 19 sites in nine mountain ranges of the western Great Basin; sites were either grazed by feral horses (Equus caballus) or had had horses removed for the last 10-14 years. We selected horse-occupied and horse-removed sites with similar aspect, slope, fire history, grazing pressure by cattle (minimal to none), and dominant vegetation (Artemisia tridentata). During 1997 and 1998, line-intercept transects randomly located within sites revealed that horse-removed sites exhibited 1.1-1.9 times greater shrub cover, 1.2-1.5 times greater total plant cover, 2-12 species greater plant species richness, and 1.9-2.9 times greater cover and 1.1-2.4 times greater frequency of native grasses than did horse-occupied sites. In contrast, sites with horses tended to have more grazing-resistant forbs and exotic plants. Direction and magnitude of landscape-scale results were corroborated by smaller-scale comparisons within horse-occupied sites of horse-trail transects and (randomly located) transects that characterized overall site conditions. Information-theoretic analyses that incorporated various subsets of abiotic variables suggested that presence of horses was generally a strong determinant of those vegetation-related variables that differed significantly between treatments, especially frequency and cover of grasses, but also species richness and shrub cover and frequency. In contrast, abiotic variables such as precipitation, site elevation, and soil erodibility best predicted characteristics such as forb cover, shrub frequency, and continuity of the shrub canopy. We found species richness of plants monotonically decreased across sites as grazing disturbance increased, suggesting that either the bell-shaped diversity-disturbance curve of the intermediate-disturbance hypothesis does not apply in this system or that most sites are already all on the greater-disturbance slope of the curve. In our study, numerous vegetation properties of less-grazed areas and sites differed notably from horse-grazed sites at local and landscape scales during a wetter and an average-precipitation year. ?? 2007 Springer Science+Business Media B.V.

Plant Ecology↗
USGS2019

New and interesting species of the genus Muelleria (Bacillariophyta) from the Antarctic region and South Africa

During a survey of the terrestrial diatom flora of some sub-Antarctic islands in the southern Indian and Atlantic Oceans and of the Antarctic continent, more than 15 taxa belonging to the genus Muelleria were observed. Nine of these taxa are described as new species using light and scanning electron microscopy. Comments are made on their systematic position and how they are distinguished from other species in the genus. Additionally, two previously unrecognized taxa within the genus were discovered in samples from South Africa. One of these, Muelleria taylorii Van de Vijver & Cocquyt sp. nov., is new to science; the other, Muelleria vandermerwei (Cholnoky) Van de Vijver & Cocquyt nov. comb., had been included in the genus Diploneis. The large number of new Muelleria taxa on the (sub)-Antarctic locations is not surprising. Species in Muelleria occur rarely in collections; in many habitats, it is unusual to find more than 1-2 valves in any slide preparation. As a result, records are scarce. The practice of "force-fitting" (shoehorning) specimens into descriptions from common taxonomic keys (and species drift) results in European species, such as M. gibbula and M. linearis, being applied to Antarctic forms in ecological studies. Finally, the typical terrestrial habitats of soils, mosses and ephemeral water bodies of most of these taxa have been poorly studied in the past.

Phycologia↗
USGS1999

Land subsidence in the United States

This report explores the role of science in defining and understanding subsidence problems, and shows that the optimal use of our land and water resources may depend on improved scientific understanding to minimize subsidence. More than 80 percent of the identified land subsidence in the Nation is a consequence of human impact on subsurface water, and is an often overlooked environmental consequence of our land- and water-use practices. Nine illustrative case studies demonstrate the role of subsurface water in human-induced land subsidence. These studies represent three distinct processes that account for most of the water-related subsidence--compaction of aquifer systems, drainage and subsequent oxidation of organic soils, and dissolution and collapse of susceptible rocks. The compaction of alluvial aquifer systems that can accompany excessive ground-water pumping and resulting ground-water level declines is, by far, the single largest cause of subsidence.

Continental United States↗
USGS2000

Factors associated with plant species richness in a coastal tall-grass prairie

In this study we examine the factors associated with variations in species richness within a remnant tall-grass prairie in order to gain insight into the relative importance of controlling variables. The study area was a small, isolated prairie surrounded by wetlands and located within the coastal prairie region, which occurs along the northwestern Gulf of Mexico coastal plain. Samples were taken along three transects that spanned the prairie. Parameters measured included micro-elevation, soil characteristics, indications of recent disturbance, above-ground biomass (including litter), light penetration through the plant canopy, and species richness. Species richness was found to correlate with micro-elevation, certain soil parameters, and light penetration through the canopy, but not with above-ground biomass. Structural equation analysis was used to assess the direct and indirect effects of micro-elevation, soil properties, disturbance, and indicators of plant abundance on species richness. The results of this analysis showed that observed variations in species richness were primarily associated with variations in environmental effects (from soil and microtopography) and were largely unrelated to variations in measures of plant abundance (biomass and light penetration). These findings suggest that observed variations in species richness in this system primarily resulted from environmental effects on the species pool. These results fit with a growing body of information that suggests that environmental effects on species richness are of widespread importance.

Journal of Vegetation Science↗
USGS2005

Assessing the potential for re-emission of mercury deposited in precipitation from arid soils using a stable isotope

A solution containing 198 Hg in the form of HgCl 2 was added to a 4 m 2 area of desert soils in Nevada, and soil Hg fluxes were measured using three dynamic flux chambers. There was an immediate release of 198 Hg after it was applied, and then emissions decreased exponentially. Within the first 6 h after the isotope was added to the soil, ∼12 ng m - 2 of 198 Hg was emitted to the atmosphere, followed by a relatively steady flux of the isotope at 0.2 ± 0.2 ng m - 2 h - 1 for the remainder of the experiment (62 days). Over this time, ∼200 ng m - 2 or 2% of the 198 Hg isotope was emitted from the soil, and we estimate that ∼6% of the isotope would be re-emitted in a year's time. During the experiment, dry deposition of elemental Hg from the atmosphere was measured with an average deposition rate of 0.2 ± 0.1 ng m - 2 h - 1 . Emission of ambient Hg from the soil was observed after soil wetting with the isotope solution and after a storm event. However, the added moisture from the storm event did not affect 198 Hg flux. Results suggest that in this desert environment, where there is limited precipitation, Hg deposited by wet processes is not readily re-emitted and that dry deposition of elemental Hg may be an important process.

Environmental Science & Technology↗
USGS2000

Influence of a nonionic surfactant (Triton X-100) on contaminant distribution between water and several soil solids

The influence of a nonionic surfactant (Triton X-100) on the contaminant distribution coefficients in solid–water mixtures was determined for a number of relatively nonpolar compounds (contaminants) on several natural solids. The studied compounds consisted of BTEX (benzene, toluene, ethylbenzene, and p -xylene) and chlorinated pesticides (lindane, α-BHC, and heptachlor epoxide), which span several orders of magnitude in water solubility ( S w ); the solid samples comprised a bentonite, a peat, and two other soils, which cover a wide range of solid organic matter (SOM) content. The applied surfactant concentrations ( X ) ranged from below the (nominal) CMC to 2–3 times the CMC. For relatively water-soluble BTEX compounds, the distribution coefficients with surfactant ( K d *) all exceeded those without surfactant ( K d ); the K d */ K d ratios increased with increasing S w from p -xylene to benzene on each solid at a given X , with increasing X for each compound on a solid, and with decreasing solid SOM content for each compound over the range of X studied. For the less-soluble pesticides, the K d */ K d ratios exhibited a large increase with X for bentonite, a marginal change (increase or decrease) for a soil of 2.4% SOM, and a moderate-to-large decrease for two soils of 14.8% and 86.4% SOM. These unique observations were rationalized in terms of the properties of the compound, the amount of surfactant sorbed on the solid, the enhanced solubilization of the compound by surfactant in water, and the relative effects of the surfactant when adsorbed on minerals and when partitioned into SOM.

Journal of Colloid and Interface Science↗