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USGS2024

Dissolved arsenic concentrations in surface waters within the upper portions of the Klamath River Basin, Oregon and California

Arsenic toxicity is an environmental health problem. Levels of arsenic in surface waters at some locations in the Klamath River Basin in southern Oregon and northern California can exceed the U.S. Environmental Protection Agency (EPA) standard for drinking water. There are both anthropogenic and natural sources of arsenic. The Klamath River Basin consists primarily of volcanic deposits and contains an underground geothermal system with hot springs and warm water wells, all known natural sources of arsenic. Anthropogenic sources of arsenic are related to the agricultural use of herbicides, fungicides, and insecticides. Surface water arsenic levels can also be affected by fertilizer amendments, evaporative concentration, oxygen-level depletion, and various geochemical transformations that can increase arsenic mobilization. In this study by the U.S. Geological Survey and the Bureau of Reclamation, dissolved concentrations of arsenic, copper, and lead were measured in surface waters at 39 unique sites within the upper portions of the Klamath River Basin between 2018 and 2022. In every year, except 2022, sites were sampled four times between April and November. Surface-water arsenic concentrations varied up to four-orders of magnitude among sites. Median arsenic concentration was lowest at Cherry Creek (0.03 micrograms per liter [μg/L]) and highest at Wood Kimball Spring (36.7 μg/L), two sites located north of Upper Klamath Lake. The highest arsenic concentrations (17.4±4.9 μg/L, n =3) were found in drain sites (defined here as a waterbody returning used irrigation water) while the lowest arsenic concentrations were found in an artesian well (0.8 μg/L, n =1). The elevated arsenic concentrations of the drain sites suggest that arsenic might be concentrated or mobilized by agricultural activities, water re-use practices, and (or) by geochemical processes occurring around water stored in drains (that is, in the water column and across sediment water boundaries). A source of arsenic in drain water in the Klamath Strait Drain area includes water used for irrigation originating from Ady Canal. Other potential sources include groundwater, geothermal water, and local soils and sediments. Seasonal differences in surface-water arsenic concentrations were detected at 13 sites, 10 of which had higher arsenic concentrations in summer than in either spring or fall. The sites sampled around Upper Klamath Lake, the impounded rivers, one of the two canal sites, and 5 of the 14 river sites had higher surface-water arsenic concentrations in the summer than in either spring or fall. Surface-water arsenic concentrations from groundwater sources (that is, springs and in the artesian well) did not vary significantly among seasons (p-values greater than 0.1). Median surface-water concentrations of copper and lead ranged from 0.03 to 3.7 μg/L, and from 0.013 to 0.175 μg/L ( n =2–18), respectively. Dissolved concentrations of both metals were below acute toxicity endpoints reported by the EPA for freshwater animals. Surface-water arsenic concentrations varied independently from corresponding changes in surface-water lead or copper concentrations. However, arsenic concentrations measured in bed-sediment samples collected from a subset of sites located north of Upper Klamath Lake correlated strongly and significantly with the corresponding sedimentary lead concentrations ( p =0.015). Aqueous arsenic speciation measured in a subset of sites in 2019 and 2022 showed that all the arsenic existed as arsenic (V), the most oxidized arsenic species, and presumably, the least toxic. The highest proportions of arsenite (As(III)), the presumably most toxic arsenic species, relative to total arsenic concentrations were found at drain sites. Our assessment of dissolved arsenic concentrations in various surface-water bodies in the Upper Klamath River Basin reveals geographical areas of consistently low (below 2.1 μg/L), moderate (below 10 μg/L) and high (above 10 μg/L) surface-water arsenic concentrations. South of Upper Klamath Lake, surface-water arsenic concentrations were consistently higher than 20 μg/L at two drain sites located in an area of predominant agricultural land use with extensive water re-use practices. North of Upper Klamath Lake, surface-water arsenic concentrations greater than 20 μg/L were consistently measured at sites with limited nearby agricultural activities, suggesting a geogenic source. The consistently high arsenic levels from the Wood River at Jackson F. Kimball State Park, Fort Creek, and Crooked Creek, which are sites located at or near headwater spring sources, suggest a natural background source of arsenic. Water flowing downstream from this area could be a potential source of arsenic to Upper Klamath Lake and the Upper Klamath River.

California, Oregon↗
USGS1990

Effects of storm-water runoff on local ground-water quality, Clarksville, Tennessee

Storm-related water-quality data were collected at a drainage-well site and at a spring site in Clarksville, Tennessee, to define the effects of storm-water runoff on the quality of ground water in the area. A dye-trace test verified the direct hydraulic connection between the drainage well and Mobley Spring. Samples of storm run off and spring flow were collected at these sites for nine storms during the period February to October 1988. Water samples were collected also from Mobley Spring and two other springs and two observation wells in the area during dry-weather conditions to assess the general quality of ground water in an urban karst terrain. Evaluation of the effect of storm-water runoff on the quality of local ground water is complicated by the presence of other sources of contaminants in the area Concentrations and load for most major constituents were much smaller in storm-water runoff at the drainage well than in the discharge of Mobley Spring, indicating that much of the chemical constituent load discharged from the spring comes from sources other than the drainage well. However, for some of the minor constituents associated with roadway runoff (arsenic, copper, lead, organic carbon, and oil and grease), the drainage well contributed relatively large amounts of these constituents to local ground water during storms. The close correlation between concentrations of total organic carbon and concentrations of most trace metals at the drainage-well and Mobley Spring sites indicates that these constituents are transported together. Many trace metals were flushed early during each runoff event. Mean storm loads for copper, lead, zinc, and four nutrient species (total nitrogen, ammonia nitrogen, total phosphorus, and orthophosphorus) in storm-water runoff at the drainage-well site were lower than mean storm load predicted from an existing regression model. The overprediction by the model may be a result of the small size of the drainage area relative to the range of drainage areas used in the development of the models, or to the below-normal amounts of rainfall during the period of sampling for this investigation. Loads& in storm-water runoff for 22 constituents were extrapolated from sampled storms to total loads for the period February to October 1988. Calculated loads for trace metals for the period ranged from 0.030pound.s for cadmium to 12pound.s for strontium. Loads of the primary nutrients ranged from 0.97pounds for nitrite as nitrogen to 34pounds of organic nitrogen. Storm-water quality at the drainage-well and Mobley Spring sites was compared to background water quality of the local aquifer; as characterized by dry-weather samples from three springs and two observation wells in the Clarksville area. Concentrations of total-recoverable cadmium, chromium, copper, lead, and nickel were higher in many stormwater samples from both the drainage-well and Mobley Spring sites than in samples from any other site. In addition, concentrations of total organic carbon, methylene blue active substances, and total-recoverable oil and grease were generally higher in storm-water samples from the drainage-well site than in any ground-water sample. Densities of fecal coliform and fecal streptococcus bacteria and concentrations of total recoverable iron, manganese, and methylene blue active substances in storm samples from the drainage-well site exceeded the maximum contaminant levels listed in Tennessee’s drinking-water standards (1988) by as much as 2,500 and 5,500 colonies per 100 milliliters, and 2.7, 0.29, and 0.05 milligrams per liter, respectively. Densities of fecal coliform and fecal streptococcus bacteria and concentrations of total-recoverable iron, manganese, and lead in storm samples from Mobley Spring exceeded the maximum contaminant levels by as much as 500 and 4,500 colonies per 100 milliliters, and 18.7,0.65, and 0.02 milligrams per liter, respectively. For iron, manganese, and bacteria, these undesirable levels are not necessarily attributable to storm-water recharge, because concentrations of these constituents also exceeded drinking-water standards in one or more of the dry-weather samples from selected springs and observation wells in the area.

Tennessee↗
USGS2026

Tephra from Kīlauea’s 2008–2018 lava lake eruption—Proximal deposits and dispersal characteristics

A network of ten buckets was established early in the 2008–2018 summit eruption at Kīlauea to collect proximal tephra ejected from the new, informally named the “Overlook crater”; the buckets were emptied on most days of the eruption thereafter. This report summarizes the results of more than 2,400 different sampling intervals (most 1–3 days long) during the eruption, focusing on the physical and dispersal characteristics of the tephra deposits. The network was within about 300 meters south of the vent to capture tephra dispersed by the dominant northeast trade wind. The juvenile tephra mainly reflected spattering at the southeast (SE) sink, a downwelling area in the southeastern part of the lava lake in the Overlook crater that remained in the same area throughout the eruption, with admixtures of solid rock and secondary minerals derived from the wall of the crater. The proportion of juvenile material to lithic material ranged widely early in the eruption but was generally greater than 90 percent for the last 6 years of the eruption as lake level rose and the crater walls decreased in height and became more stable. The accumulation rate of tephra at each bucket was strongly dependent on the location of the bucket and reflects the interplay between lava lake level and wind direction and speed. The mass per unit area (m/a) of collected tephra was a maximum of about 97 kilograms per square meter for the entire eruption, equivalent to a thickness of about 75 millimeters. Thirty-two explosive events with a volcanic explosivity index of −2 to −4 deposited much of the tephra in the network. Fifteen of these rock-fall-induced events occurred within 6 days of one another. Pele’s hair, a volcanic glass predominantly associated with quieter activity at the vent in the final half of the eruption, was dispersed more than 60 kilometers downwind from the lava lake and formed a nearly continuous deposit near the Overlook crater. This eruption was probably the most frequently sampled long-lasting eruption in history, but most of the deposits are ephemeral. The collected samples, although generally of small mass, are retained by the Hawaiian Volcano Observatory and are available for detailed study.

Hawaii↗
USGS2000

Monthly variability and possible sources of nitrate in ground water beneath mixed agricultural land use, Suwannee and Lafayette Counties, Florida

In an area of mixed agricultural land use in Suwannee and Lafayette Counties of northern Florida, water samples were collected monthly from 14 wells tapping the Upper Floridan aquifer during July 1998 through June 1999 to assess hydrologic and land-use factors affecting the variability in nitrate concentrations in ground water. Unusually high amounts of rainfall in September and October 1998 (43.5 centimeters total for both months) resulted in an increase in water levels in all wells in October 1998. This was followed by unusually low amounts of rainfall during November 1998 through May 1999, when rainfall was 40.7 centimeters below 30-year mean monthly values. The presence of karst features (sinkholes, springs, solution conduits) and the highly permeable sands that overlie the Upper Floridan aquifer provide for rapid movement of water containing elevated nitrate concentrations to the aquifer. Nitrate was the dominant form of nitrogen in ground water collected at all sites and nitrate concentrations ranged from less than 0.02 to 22 milligrams per liter (mg/L), as nitrogen. Water samples from most wells showed substantial monthly or seasonal fluctuations in nitrate concentrations. Generally, water samples from wells with nitrate concentrations higher than 10 mg/L showed the greatest amount of monthly fluctuation. For example, water samples from six of eight wells had monthly nitrate concentrations that varied by at least 5 mg/L during the study period. Water from most wells with lower nitrate concentrations (less than 6 mg/L) also showed large monthly fluctuations. For instance, nitrate concentrations in water from four sites showed monthly variations of more than 50 percent. Large fluctuations in nitrate concentrations likely result from seasonal agricultural practices (fertilizer application and animal waste spreading) at a particular site. For example, an increase in nitrate concentrations observed in water samples from seven sites in February or March 1999 most likely results from application of synthetic fertilizers during the late winter months. Lower nitrate concentrations were detected in water samples from five of eight wells sampled during high-flow conditions for the Suwannee River in March 1998 compared to low-flow conditions in November 1998. Evidence for reduction of nitrate due to denitrification reactions was observed at one site (AC-1), as indicated by elevated concentrations of nitrogen gas and a corresponding increase in nitrogen isotope (d15N-NO3) values with a decrease in nitrate concentrations. Denitrification is unlikely at other sites based on the presence of dissolved oxygen concentrations greater than 2 mg/L in ground water and no observed trend between nitrate concentrations and values d15N-NO3 values. Nitrate was the dominant nitrogen species in most monthly rainfall samples; however, ammonium concentrations were similar or greater than nitrate during November and December 1998. During February through May 1999, both nitrate and ammonium concentrations were substantially higher in monthly rainfall samples collected at the study area compared to mean monthly concentrations at the Bradford Forest site located east of the study area, which is part of the National Atmospheric Deposition Program/National Trends Network. Also, higher nitrogen deposition rates in the study area compared to those at Bradford Forest could indicate that substantial amounts of ammonia are volatilized from fertilizers and animal wastes, released to the atmosphere, and incorporated as nitrate and ammonium in rainfall deposited in the middle Suwannee River Basin. Ground-water samples from most sites had d15N-NO3 values that indicated a mixture of inorganic and organic sources of nitrogen, which corresponded to multiple land uses where both synthetic fertilizers and manure are used on fields near these sites. Distinct d15N-NO3 signatures, however, were observed at some sites. For example, water samples from areas of row-crop farming as the dominant land use had d15N-NO3 values less than 4 per mil, indicating an inorganic nitrogen source such as synthetic fertilizer. In contrast, d15N-NO3 values greater than 9 per mil were found in water samples from three sites where manure from dairy and or poultry operations is spread on fields throughout the year.

Florida↗
USGS2024

Mapping Arundo donax (Arundo cane) with multispectral imagery before, during, and after herbicide treatment along the Rio Grande in Webb County, Texas, 2020–21

Arundo donax , commonly called Arundo cane, giant reed, or Carrizo cane, is an invasive bamboo-like perennial grass common in riparian areas throughout the southwestern United States. In Texas, not only does it negatively affect riparian ecosystems, but it has also become a problem for border security because it reduces visibility along the Rio Grande. To address these problems, in 2015 the Texas State Soil and Water Conservation Board was authorized by the Texas State Legislature to develop a program to eradicate Arundo cane along the Rio Grande. In 2020, the Texas State Soil and Water Conservation Board applied imazapyr and glyphosate herbicides along a 19.3-kilometer reach of the Rio Grande, northwest of Laredo, Texas. The U.S. Geological Survey, in cooperation with the Texas State Soil and Water Conservation Board and the Webb Soil and Water Conservation District, used WorldView-3 Standard high-resolution satellite imagery to map Arundo cane extent along the reach before , during , and after the herbicide-treatment period on June 30, 2020, September 26, 2020, and May 7, 2021, respectively. A maximum likelihood supervised classification analysis was computed on the images to map the spatial extent and estimate the area covered by Arundo cane. The estimated area covered by Arundo cane in the before classification was 1,282,000 square meters, in the during classification was 1,064,000 square meters, and in the after classification was 1,108,000 square meters. The qualitative comparison of the three images shows that there was an overall decrease in vegetation classified as Arundo cane throughout the study area.

Texas↗
USGS2024

Monitoring marine eruptions

Introduction Submarine volcanoes produce much of the same seismicity and eruptive activity as subaerial volcanoes and can pose hazards to society. Although they can be monitored with similar techniques and methods as described in other chapters of this volume, their submerged location brings unique challenges. This chapter addresses these challenges and provides recommendations for monitoring volcanoes fully or partly in marine environments to meet the capabilities described in other chapters of this volume. The United States and its territories host dozens of submarine volcanoes with most (around 60) in the Commonwealth of the Northern Mariana Islands. Approximately 20 of the Northern Mariana Islands submarine volcanoes are known to be hydrothermally active, and 10 have confirmed eruptions since the 1950s (for example, Baker and others, 2008; Tepp and others, 2019a). Nine of those volcanoes were considered by the National Volcanic Threat Assessment (Ewert and others, 2018) to have a combination of eruptive type and summit depth that poses a higher risk of hazardous eruptions, although only one was listed as a moderate (level 3) threat. Other notable submarine volcanoes of interest to the United States that have historically erupted are Axial Seamount off the Washington State coast, Kamaʻehuakanaloa in Hawaiʻi, and Vailuluʻu seamount in American Samoa. All of these, however, have a low risk of hazards because of their depth (greater than 600 meters below sea level) and eruptive type and so are not included in the National Volcanic Threat Assessment. In addition to submarine volcanoes, the submerged flanks of island volcanoes can also be a source of hazardous submarine eruptions—for example, the 1877 eruption of Mauna Loa, Hawai‘i, in Kealakekua Bay (Wanless and others, 2006). The most notable submarine eruption in recent times was the 2022 eruption of Hunga Tonga–Hunga Haʻapai in Tonga, which was one of the largest eruptions on Earth in the past 100 years. It created a massive volcanic plume, unprecedented shock waves, and far-reaching tsunami (Lynett and others, 2022). Other recent submarine eruptions in the Pacific Ocean Basin have produced subaerial plumes that reached aircraft heights (Carey and others, 2014) and large pumice rafts that can affect marine traffic and harbors (for example, Jutzeler and others, 2014; Kornei, 2019). These examples illustrate the potential hazards of major submarine eruptions. Yet, submarine volcanoes are largely unmonitored, and many eruptions occur that are unnoticed or only identified hours or days afterward. Within U.S. territory, submarine volcanoes in the Northern Mariana Islands have been known to produce eruptive activity that can affect society. Reports from fishermen and other marine vessels in the Northern Mariana Islands have noted underwater explosions, sea-surface discoloration, and bubbling water, all of which are known to be signs of submarine volcanic activity. South Sarigan seamount, located about 160 kilometers (km) north of Saipan, erupted in 2010 from greater than 150 meters below the sea surface, resulting in a gas and ash plume that reached more than 11.9 km into the atmosphere (for example, Searcy, 2013; Embley and others, 2014), high enough to affect international air traffic. Precursory and co-eruptive seismicity was detected on the regional Northern Mariana Islands seismic network (Searcy, 2013) and on global monitoring instruments (Green and others, 2013). Monitoring of submarine volcanoes is best accomplished with marine-based instrumentation, which is also useful for monitoring small island volcanoes that may not have the land area necessary for comprehensive subaerial monitoring. The primary marine-based instrumentation used for submarine volcanoes includes ocean-bottom pressure sensors to assess sea-floor deformation, ocean-bottom seismometers (OBSs) to detect seismicity, and both moored and ocean-bottom hydrophones to detect submarine explosions. Other sensors offer important monitoring data, such as turbidity, temperature, and chemistry of hydrothermal emissions. Marine-based instruments are typically deployed in campaign-style networks with no real-time telemetry owing to cost considerations and technical limitations. However, when necessary, marine instruments can be operated in real time using cables to transmit data to land-based facilities; other technologies for this purpose are in use or in development, such as acoustic transmission from the instrument to a moored buoy (Matsumoto and others, 2016) and a winch-based system with a satellite antenna that is part of the instrument mooring (Matsumoto and others, 2019). Emerging technologies for marine-based monitoring may be considered as part of a future monitoring plan. These technologies include ocean gliders and floats with on-board hydrophones that have been used to record earthquakes and submarine eruptions (for example, Matsumoto and others, 2013; Sukhovich and others, 2015) and fiber-optic cables that have been used as strainmeters to detect earthquakes (for example, Marra and others, 2018; Lindsey and others, 2019). Land-based instruments and satellites can also provide some capability for monitoring submarine volcanoes, but they provide more limited observations than marine-based instrumentation.

Scientific Investigations Report↗
USGS2024

Volcanic gas monitoring

Introduction As magma rises through the crust, decreasing pressure conditions allow volatiles to exsolve from the magma. These volatiles then migrate upward through the crust, where they can be stored at shallower levels or escape to the atmosphere. Rising magma also heats rock masses beneath volcanic centers, causing water in shallow aquifers and hydrothermal systems to boil and release additional gases and steam (see chapter F , this volume; Ingebritsen and Hurwitz, 2024). The chemistry and quantity of gases that reach the surface during periods of quiescence or volcanic unrest can reveal that gas-rich magma is ascending, crystallizing, or alternatively stalling, with important implications for volcanic hazard (for example, Sutton and others, 1992; Aiuppa and others, 2007, 2021; Werner and others, 2009, 2011, 2012; Moretti and others, 2013; de Moor and others, 2016; Lewicki and others, 2019; Edmonds and others, 2022; Kern and others, 2022; Kunrat and others, 2022). Most volcanoes in Alaska and the western United States are characterized by weak degassing, with one or more low-temperature fumaroles (typically near the local boiling temperature of water) and connect to a deeper and sometimes extensive hydrothermal system (for example, McGee and others, 2001; Symonds and others, 2003a, b). Hydrothermal systems will affect the chemistry of rising gases exsolved from deeper magma (Symonds and others, 2001), including sulfur dioxide (SO 2 ), hydrogen chloride (HCl), and water vapor (for example, Doukas and Gerlach, 1995; Gerlach and others, 1998, 2008; Symonds and others, 2001; Werner and others, 2013). As an example, depending on factors such as temperature, pressure, and oxidation state, rising SO 2 will react with groundwater to form hydrogen sulfide (H 2 S) gas, dissolved sulfate (SO 4 2− ), or elemental sulfur (Christenson, 2000; Symonds and others, 2001; Werner and others, 2008). The reaction and dissolution of SO 2 into shallow groundwater is commonly referred to as scrubbing, and can reduce the likelihood that ascending, degassing magma can be detected. Carbon dioxide, however, in addition to exsolving from magma early in the ascent process, is not easily removed by hydrothermal fluids (Lowenstern, 2001). As scrubbing and other processes take place, the SO 2 /H 2 S, CO 2 /SO 2 , and CO 2 /H 2 S ratios may change. High rates of SO 2 emission indicate that magma has moved to relatively shallow levels in the volcano and that the system has heated up enough to establish dry pathways from depth to the surface. Monitoring multiple gas species and the total output of those species is thereby useful for volcano monitoring during both periods of quiescence, to establish background degassing conditions, and during unrest, when gas geochemistry and emission rates can provide information on changing conditions, such as magma ascent. To provide context for multidisciplinary volcano forecasts, we focus on the following two key required capabilities: (1) characterizing baseline geochemistry and gas discharge from volcanoes and volcanic regions and (2) monitoring changes in gas geochemistry and discharge to inform forecasts of volcanic eruptions and their effects. Sufficient baseline data must be collected to identify and interpret anomalous degassing associated with volcanic unrest (for example, Sorey and others, 1998; Rouwet and others, 2014). Differences in volcano type, baseline degassing rates, local hydrology, and geography (for example, high versus low latitude) will result in a different baseline for each volcano. Volcanoes of any threat level that exhibit one or more degassing phenomena would ideally be monitored by techniques needed to establish baseline degassing data, with the sampling frequency of baseline data dictated by the threat level (table E1). Additional monitoring techniques become necessary during periods of unrest. In general, three of the most important techniques for gas monitoring are (1) direct sampling of fumarole, spring, and soil gases for laboratory geochemical measurements, (2) measurements of the chemical composition of the volcanic plume and emission rates of major gas species (for example, H 2 O, CO 2 , SO 2 , and H 2 S) by satellite, airborne, or ground-based techniques, and (3) measurements of diffuse emissions of CO 2 and other gases through soils. Various methods and instruments may be useful both for baseline studies and during unrest.

Scientific Investigations Report↗
USGS2023

Hydrogeology, karst, and groundwater availability of Monroe County, West Virginia

Monroe County is in southeastern West Virginia, encompassing an area of 474 square miles. The area consists of karst and siliciclastic aquifers of Ordovician, Silurian, Devonian, and Mississippian age and is in parts of two physiographic provinces: the Valley and Ridge Province to the east of Peters Mountain, and the Appalachian Plateau Province to the west of Peters Mountain. This study was developed in response to inquiries from the Monroe County Commission requesting assessment of the water resources of the county to better understand the quantity of the county’s groundwater resources, for both current [2023] and future demand, and to provide information to support protection and management of the county’s valuable groundwater resources. Various products were developed for this study that provide knowledge with respect to water availability and contamination susceptibility of the karst aquifers within the county. U.S. Geological Survey (USGS) geologists conducted extensive geologic mapping in support of the project, producing (1) a countywide bedrock geologic map, (2) a countywide hydrogeologic map, and (3) a light detection and ranging (lidar)-derived countywide digital elevation model and associated sinkhole map. A significant part of this work was to map in detail the Greenbrier Group at the formation level, which prior to this study had only partially been completed. The report also includes (4) a description of the lithologic units identified as part of the geologic mapping process. U.S. Geological Survey hydrologists completed several additional products for the hydrology part of the effort, including development of (1) a countywide potentiometric surface (water-table) map, (2) a countywide base-flow stream assessment, (3) countywide water-budget estimates, (4) well log surveys for 15 wells to better understand subsurface controls on groundwater flow within the study area, (5) two groundwater tracer tests to better refine the groundwater divide from the northern and southern parts of the karst aquifer in Monroe County; and finally, based on all available data collected for the study including the potentiometric surface map, geologic map, current [2023] and legacy fluorometric groundwater tracer tests, and base-flow stream assessments, (6) groundwater-basin delineations were reassessed for principal groundwater basins within the Greenbrier aquifer. In Monroe County, four principal hydrogeologic settings produce large yields of water for residential, agricultural, and other uses. The most relied upon water-bearing zone with respect to current [2023] public water supply is from springs along Peters Mountain. These springs are derived from intervals of fractured sandstone and resultant alluvial deposits. Groundwater flows downslope through these permeable alluvial deposits and discharges at the contact with less permeable strata, such as the Reedsville Shale. The second most relied upon water-bearing zone in Monroe County is within the karstic Greenbrier Group aquifer, in which the basal Hillsdale Limestone overlies the less permeable Maccrady Shale. This geologic contact between the Hillsdale Limestone and Maccrady Shale is not only targeted as a source of water for agricultural supply but also is targeted as a source of water for residential supply. The third most relied upon water-bearing zone is composed of shallow perched aquifers within the Greenbrier Group. The discontinuous nature of these perched aquifers makes mapping their extent impossible, but they are related to permeable geologic strata, such as karstified limestones with solutionally enhanced permeability that overlies less permeable shale or chert bedrock. During geologic mapping of the county, several of these perched aquifers were documented in the Pickaway, Union, and Alderson Limestones. A fourth zone consists of springs from Ordovician carbonates at the base of Peters Mountain, which are influenced by sinking streams as well as upwelling along faults. In terms of water quantity, the most sustainable springs are those having deeper-sourced flows. Public supplies are a principal source of water used for residential and commercial supply in the region, accounting for 0.49 million gallons per day (Mgal/d) of fresh-water withdrawals (0.14 Mgal/d of groundwater and 0.35 Mgal/d of surface water) for residential and commercial use and serving 6,645 individuals (49.2 percent of the population). An estimated 6,861 people, (50.8 percent of the population) primarily rely on private wells or other unregulated sources, such as springs, and withdraw 0.55 Mgal/d of groundwater for their residential use. Public water supply in the region is primarily (71.4 percent) derived from springs and augmented by stream withdrawals (backup sources mainly during low-flow periods), with the remaining portion (28.6 percent) derived from groundwater withdrawals from wells. For rural residents, however, 100 percent of their withdrawals are derived from groundwater (wells or springs).

West Virginia↗
USGS1999

Characterization of selected biological, chemical, and physical conditions at fixed sites in the Upper Colorado River Basin, Colorado, 1995-98

Biological community samples were collected at 15 sites in the Upper Colorado River Basin (UCOL) in Colorado as part of the National Water-Quality Assessment (NAWQA) Program. Sites sampled in two physiographic provinces, the Southern Rocky Mountains and the Colorado Plateau, represented agriculture, mining, urban and recreation, and mixed land uses and background conditions. Nine measures of water quality, which include information on nutrients, specific conductance (a surrogate for salinity), trace elements in streambed sediment, pesticides in fish tissue, fish communities, and macroinvertebrate richness and composition and stream habitat were used for comparisons among sites within the two physiographic provinces. Sampling sites from three other NAWQA study units—the Rio Grande Valley, the South Platte River Basin, and the Upper Snake River Basin study units—were categorized on the basis of land use and stream size in order to develop a larger data set for comparison to sites in the UCOL. Three categories of land use—forested (includes mining, urban and recreation, and background), agriculture, and mixed—were used for comparison to the UCOL fixed sites. Results indicated that all sites other than the Colorado River below Baker Gulch (a background site) showed some water-quality characteristics to be significantly affected. Results indicated that the concentrations of cadmium and zinc in streambed sediment at mining land-use sites in the Southern Rocky Mountains physiographic province generally were orders of magnitude higher than streambed-sediment concentrations at the background site. Streambed-sediment concentrations at mining land-use sites in the UCOL were greater than the 75 th percentile of concentrations from sites in the three other NAWQA study units. Fish communities and habitat conditions were degraded at mining land-use sites compared to the background site. Ephemeroptera, Plecoptera, and Trichoptera (EPT) richness and the percentage of EPT were lower at mining land-use sites than at the background site and were less than the 50 th percentile of those for sites from the three other NAWQA study units. Nutrient concentrations at urban and recreation sites in the Southern Rocky Mountain physiographic province generally were greater than concentrations at the background site and generally were between the 25 th and 90 th percentile of concentrations for sites from the three other NAWQA study units. Habitat conditions and fish communities at urban and recreation sites were slightly degraded compared to the background site. EPT richness and the percentage of EPT were lower at urban and recreation sites than at the background site and were between the 25 th and 75 th percentile of those for sites from the three other NAWQA study units. The percentage of Chironomidae, which may be indicative of pollutant-tolerant organisms, was higher at urban and recreation sites than at the background site. Mixed land-use sites in the Southern Rocky Mountains physiographic province had similar nutrient concentrations and similar cadmium and zinc streambed-sediment concentrations. Fish-community degradation index values were very different among the three mixed land-use sites in the Southern Rocky Mountains physiographic province. Larger percentages of omnivores and anomalies such as lesions and deformities at two mixed land-use sites resulted in higher degradation values of the fish community. Agriculture land-use sites had higher concentrations of nutrients and selenium than the background site in the Colorado Plateau physiographic province. Concentrations of p,p '-DDE in fish tissue at agriculture sites were higher than the 75 th percentile of concentrations for sites from the three other NAWQA study units. Fish communities had degradation values near the 75 th percentile for agriculture sites. The percentage of EPT was low at agriculture sites when compared to the background site. Two mixed land-use sites in the Colorado Plateau physiographic province had similar concentrations of nutrients, selenium, and p,p '-DDE, and similar EPT richness and composition. These two sites were located downstream from agricultural and urban activities. Some water-quality measures at these two sites indicated degradation compared to a mixed land-use site upstream from most of the agriculture and urban activities in the Colorado Plateau physiographic province.

Colorado↗
USGS1996

Analysis of nutrients in the surface waters of the Georgia–Florida Coastal Plain study unit, 1970–91

During the early phase of the Georgia-Florida National Water Quality Assessment study, existing information on nutrients was compiled and analyzed in order to evaluate the nutrient concentrations within the 61,545 square mile study unit. Evaluation of the nutrient concentrations collected at surface-water sites between October 1, 1970, and September 30, 1991, utilized the environmental characteristics of land resource provinces, land use, and nonpoint and point-source discharges within the study unit. Long-term trends were investigated to determine the temporal distribution of nutrient concentrations. In order to determine a level of concern for nutrient concentrations, the U.S. Environmental Protection Agency (USEPA) guidelines were used: (1) for nitrate concentrations, the maximum contaminant level in public-drinking water supplies (10 mg/L); (2) for ammonia concentrations, the chronic exposure of aquatic organisms to un-ionized ammonia (2.1 mg/L); (3) for total-phosphorus concentrations, the recommended concentration in flowing water to discourage excessive growth of aquatic plants (0.1 mg/L); and (4) for kjeldahl concentrations, however, no guidelines were available. For sites within the 10 major river basins, median nutrient concentrations were enerally below USEPA guidelines, except for total-phosphorus concentrations where 45 percent of the medians exceeded the guideline. The only median ammonia concentration that exceeded the guideline occurred at the Swift Creek site (3.4 mg/L), in the Suwannee River basin, perhaps due to wastewater discharges. For all sites within the Withlacoochee, Aucilla, and St. Marys River basins, median concentrations of nitrate, ammonia, and total phosphorus were below the USEPA guidelines. Nutrient data at each monitoring site within each major basin were aggregated for comparisons of median nutrient concentrations among major basins. The Ochlockonee and Hillsborough River basins had the highest median nutrient concentrations, the Aucilla River basin had the lowest. Median concentrations of nitrate and ammonia among all major basins were below USEPA guidelines. The median total-phosphorus concentrations for the following river basins exceeded the USEPA guideline: Hillsborough, St. Johns, Suwannee, Ochlockonee, Satilla, Altamaha, and Ogeechee. Although nutrient concentrations within the study unit were low, long-term increasing trends were found in all four nutrients. All 18 study-unit wide nitrate trends had increasing slopes ranging from less than 0.01 to 0.07 (mg/L)/yr. The range in slope for the 13 ammonia trends was -0.03 to 0.01 (mg/L)/yr with 6 increasing trends in the northern part of the study unit. Of the 17 total-phosphorus trends found in the study unit, 10 were found at sites where the median concentration exceeded the USEPA guideline. At these 10 sites, 4 sites had increasing trends with slopes ranging from less than 0.01 to 0.07 (mg/L)/yr, 5 sites had decreasing trends with slopes ranging from -0.01 to -0.24 (mg/L)/yr, and one site showed a seasonal concentration trend. Median nutrient concentrations were significantly different among the four land resource provinces: Southern Piedmont, Southern Coastal Plain, Coastal Flatwoods, and Central Florida Ridge. As a result, nutrient concentrations among basins with similar nutrient inputs but located within different land resource provinces are not expected to be the same due to differences in the combination of factors such as soil permeability, runoff rates, and stream channel slopes. This concept is an important consideration in designing a surface-water quality network within the study area. For the most part, the Coastal Flatwoods showed the lowest median nutrient concentrations and the Southern Coastal Plain had the highest median nutrient concentrations. Lower median nitrate concentrations in surface-water basins were associated with the forest/wetland land-use category and higher median concentrations of nitrate and ammonia with the urban category when land-use percentages were classified into four land-use categories (agriculture, forest/wetland, mixed, and urban). These results were reasonable based on expected high nutrient inputs from urban areas and low inputs from forested and wetland areas. However, the lack of association between high nutrient concentrations and the agricultural land-use category was not expected since high nutrient inputs are generally needed for agriculture production.

Florida, Georgia↗
USGS2026

Lithium brine potential of North Dakota: Results from the 2025 sampling program

Lithium (Li), classified as a critical mineral and key in energy storage applications because of its high energy density, faces unprecedented demand. This has driven interest in unconventional sources of Li, especially brines from sedimentary basins. Accordingly, the spatial distribution of basinal brinehosted Li resources across North America is becoming better defined, including the Williston Basin underlying Saskatchewan, Canada. This has led to growing investment and exploration by industry throughout the 2020s; however, despite this interest, the Li potential of basinal brines of the Williston Basin in North Dakota remain underexplored. This work presents the results from the 2025 joint brine sampling campaign between the North Dakota Geological Survey, the United States Geological Survey (USGS), and The University of Texas at Austin. Twenty-seven fluid samples were collected from producing oil and water source wells from eight stratigraphic intervals across western North Dakota and analyzed for major cation and anion concentrations. Similar to southeastern Saskatchewan, the highest Li concentrations were identified in the Devonian Duperow Formation, with concentrations up to 179 mg/L being observed in a well commingled between the Duperow and Red River Formations. Some samples from the overlying Birdbear Formation exceeded 75 mg/L, whereas Li concentrations were lower in the Madison Group (33-44 mg/L) and the Three Forks (50 mg/L), Dawson Bay (43 mg/L), Winnipegosis (23 mg/L), and Red River (40.0 mg/L) Formations. This work indicates Li resource potential exists across the Williston Basin and advances our understanding of the Li distribution in basinal brines which could provide a new domestic source of this critical mineral.

North Dakota↗
USGS2024

Colored shaded relief bathymetry and acoustic backscatter of Ozette Lake, Washington

Offshore of the Pacific Northwest of the United States is the Cascadia Subduction Zone, a 1,000-kilometer-long tectonic boundary defined by a large fault, called a megathrust, that extends from the Mendocino Junction off northern California to the Nootka Fracture Zone off Vancouver Island, Canada (U.S. Geological Survey, 2023). The Juan de Fuca and Gorda oceanic plates to the west of this boundary subduct under the North America continental plate to the east. Several other smaller faults that cut through the North America plate crust also affect the region. Although their effects upon Ozette Lake are uncertain, geological evidence for past earthquakes, such as underwater landslides, may be found in Pacific Northwest lakes. Underwater landslides caused by past earthquakes should be well preserved in these relatively undisturbed lake environments. The floor of Ozette Lake, Washington, located along the Pacific coast of the United States, west of the Puget Sound region and about 140 kilometers east of the megathrust was mapped by the U.S. Geological Survey in July of 2019 to search for evidence of past earthquakes. Mapping was completed using a SWATHplus-M 234-kHz interferometric side scan sonar system pole-mounted on the U.S. Geological Survey research vessel San Lorenzo. The system collected full-coverage bathymetric and acoustic backscatter data that were processed to 2-meter spatial resolution (Dartnell and others, 2024). This two-map series displays the results of this mapping. A colored shaded relief bathymetry map (sheet 1) and an acoustic backscatter map (sheet 2) show the lake floor morphology and backscatter intensities, respectively, that can be analyzed for evidence of past earthquakes.

Washington↗
USGS2025

The 3D National Topography Model Call for Action—Part 2: The Next Generation 3D Elevation Program

The three-dimensional (3D) National Topography Model initiative to integrate elevation and hydrography data includes the next generation of hydrography data from the 3D Hydrography Program and the next generation of elevation data from the 3D Elevation Program (3DEP). The first-ever collection of light detection and ranging (lidar) data for the nation (IfSAR for Alaska) provides a critical baseline reference, and the addition of multiple repeat elevation mapping projects as part of the next generation of 3DEP would substantially expand analysis capabilities. As the U.S. Geological Survey (USGS) is closing in on our goal of complete coverage with 3DEP data available or in progress for 98.3 percent of the Nation at the end of fiscal year 2024, the USGS is already transitioning to the next generation of 3DEP. Based on the 3D Nation Study results and input from a broad range of stakeholders, the USGS National Geospatial Program has finalized a new design for 3DEP that provides increased lidar quality levels and refresh rates. The new program is designed with more flexibility to meet changing user needs and take advantage of improvements in mapping technologies. The program will aim to expand the level of interagency coordination for topobathymetric lidar acquisition for inland rivers. The next generation of 3DEP will also aim to emphasize research, including advancing program design, products, and services and engaging and leveraging the evolving 3D industry. Research goals also include becoming more flexible in meeting user needs and taking advantage of evolving remote-sensing technologies. The program also plans to move from focusing on producing standard products to producing a concept of a 3D Nation Ecosystem with a variety of inputs, products, and services.

Circular↗
USGS2026

Geologic map of pre-Middle Jurassic basement rocks beneath the Atlantic and Gulf Coastal Plains in Florida

Much of the southeastern United States, including all of Florida, is covered by flat-lying sedimentary strata of the Atlantic and Gulf Coastal Plains which have accumulated since Middle Jurassic time. The pre-Middle Jurassic rocks that underlie these coastal plains in Florida, here collectively referred to as “basement,” are known only from a relatively small number of boreholes. This scientific investigations map presents an interpretation of the basement geology in a 1:1,000,000-scale subsurface geologic map with supporting text, data, and figures. The subsurface mapping methodology integrates petrographic, geochronological, thermochronological, geochemical, and mineralogical analyses of drill cores and cuttings in the context of regional geophysical data. The pre-Middle Jurassic rocks of Florida consist of the Gondwanan (West African) Suwannee terrane which was accreted to Laurentia during the Alleghanian orogeny and subsequently intruded by Permian granites, superposed by early Mesozoic rift basins, and partially overlain by bimodal Jurassic volcanic rocks. The younger basement components, specifically the Southwest Florida volcanic province, North Florida tholeiites, early Mesozoic rift basins, and Alleghanian granitoids, have correlative and contemporaneous units throughout the Appalachian orogen. In contrast, Florida’s older basement rocks, including Paleozoic siliciclastic strata of the Suwannee basin, North Florida volcanic series, Osceola and Gaskin intrusive complexes, and the St. Lucie Metamorphic Complex, have neither surface exposures nor unequivocal correlates. Major structures include early Mesozoic normal faults and northwest-striking transfer zones such as the Jay fault. Many of these faults define the boundaries of subbasins within the South Georgia rift system. Top-of-basement structure contours show gentle arches and embayments that are also recognized in overlying coastal plain strata.

Florida↗
USGS2024

Simulated mean monthly groundwater-transported nitrogen loads in watersheds on the north shore of Long Island Sound, 1993–2022

Elevated nitrogen loads are pervasive in the Long Island Sound, an estuary that receives freshwater and nutrients from both surface-water and groundwater discharge. Surface-water nitrogen loads to the Long Island Sound are relatively well characterized, but less is known about groundwater-transported nitrogen loads. Prior work on the northern shore of Long Island Sound (Connecticut and areas of New York and Rhode Island) suggested that groundwater travel times are relatively short (median less than 2 years) and that decade-long nutrient legacies are not widespread. Because the travel times are short, groundwater flow and nutrient loads likely vary substantially between months. In the current study, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency’s Long Island Sound Study and the Connecticut Department of Energy and Environmental Protection, developed a set of models to better characterize spatial and temporal patterns of groundwater-transported nitrogen loading from atmospheric deposition, septic systems, and fertilizers within the study area. The models provide an estimate, with uncertainty, of groundwater-transported nitrogen loads in the study area, filling a key gap in the nitrogen budget for Long Island Sound. The models also highlight the spatial and temporal variation in nitrogen loading throughout the study area. The modeling workflow involved four models. (1) A soil-water-balance model was developed by using the Soil-Water-Balance software to simulate groundwater recharge across the study area for water years 2005 through 2022. The simulated mean monthly recharge from the soil-water-balance model was used as input into a groundwater-flow model. (2) The groundwater-flow model was developed by using the MODFLOW 6 software and data for water years 1993 through 2022 and simulates average monthly hydrologic conditions. The groundwater-flow model was calibrated by using the Iterative Ensemble Smoother method within the PEST++ software. The Iterative Ensemble Smoother method generates an ensemble of sets of parameter values, with each set producing reasonable simulated hydrologic parameter values. (3) An ensemble of MODPATH particle-tracking simulations were run to generate particle flow paths and travel times, with each simulation using a different set of the flow model parameters. (4) A nitrogen load model uses the MODPATH simulation outputs to track nitrogen from the land surface through multiple attenuation zones until it discharges into fresh or saline surface water. As with the groundwater-flow model, the nitrogen model simulated average monthly groundwater-transported nitrogen loads for water years 1993 through 2022. One novel aspect of the nitrogen load model is that the nitrogen attenuation parameters were calibrated to observed nitrogen loads. Across the ensemble of simulated nitrogen loads, the median study-area-wide monthly simulated nitrogen loads from the aquifer to Long Island Sound throughout the year ranged from 900 to 18,600 kilograms of nitrogen per day, with a median load of 5,100 kilograms of nitrogen per day. The simulated loads were based on average monthly conditions for water years 1993 through 2022. Loads were highest during the winter and early spring and lowest during the late summer. However, simulated travel times for groundwater and nitrogen loads discharged to Long Island Sound during summer were longer than travel times for groundwater and loads discharged during the winter, indicating that, on average, groundwater discharged during summer traveled along different, and longer, flow paths, than groundwater discharged during winter. This indicates that summer loads would respond more slowly to changes in nitrogen inputs at the water table than winter loads. Over the entire study area, approximately 15 percent of the simulated load is from atmospheric deposition sources, 30 to 40 percent is from fertilizer, and 50 to 60 percent is from septic systems. The final analysis of the study involved simulating the change in groundwater-transported nitrogen load in response to upgrading septic systems or reducing fertilizing inputs to areas of turf grass. Both management interventions reduced the groundwater-transported nitrogen load, and reductions were greater in areas with greater loads from septic systems or turf-grass fertilizers. The delay between management actions and substantial reductions in groundwater-transported nitrogen loads varied seasonally; loads during the late summer months remained elevated longer than the winter loads.

Connecticut, Rhode Island↗
USGS2023

Prediction of the probability of elevated nitrate concentrations at groundwater depths used for drinking-water supply in the Puget Sound basin, Washington, 2004–19

The Puget Sound basin encompasses the 13,700-square-mile area that drains to the Puget Sound and the adjacent marine waters of Washington State. Well more than 4 million people live within the basin, with numbers continuing to increase, who rely on the basin’s natural resources including groundwater. The Puget Sound Partnership was created by a Washington State statute to implement a science-based recovery of the Puget Sound to help address impacts to these resources. As part of the recovery, the partnership developed the Puget Sound Vital Signs as measures of ecosystem health that guide the assessment of progress toward Puget Sound recovery goals. The Puget Sound Partnership Leadership Council adopted a Drinking Water Vital Sign associated with human health and quality of life, recognizing certain indicators as integral to the sustainability of Puget Sound recovery efforts. One such Vital Sign indicator was the vulnerability of groundwater throughout the aquifers of the Puget Sound basin to elevated nitrate concentrations as defined by the probability of exceeding 2 milligrams/liter (mg/L) at a specific location and well depth. The U.S. Geological Survey (USGS) led the effort to characterize groundwater vulnerability. For this study, groundwater vulnerability refers to a probability with which a contaminant applied at or near the land surface can migrate to the aquifer of interest for a given set of land-use practices. Nitrate concentration data were selected for evaluation because elevated nitrate concentrations are typically caused by anthropogenic activities and have been associated with deleterious impacts on human health. To identify groundwater vulnerability to elevated nitrate concentrations, logistic regression was used to relate anthropogenic (human associated) and natural variables to the occurrence of elevated nitrate concentrations in untreated groundwater from large public water supply system wells found within the Washington State Department of Health Sentry database. Variables that were analyzed included well depth, soil hydraulic conductivity, precipitation, population density, fertilizer application amounts, and land-use types. Statistically significant models that predicted the probabilities of groundwater nitrate concentrations greater than 2 mg/L based on the predictor variables were created for the time periods 2000–04, 2005–09, 2010–14, and 2015–19. For all time periods, well depth and a measure of the abundance of urban and agricultural land over or near the well consistently helped explain the vulnerability of the well to elevated nitrate concentrations defined as a probability of exceeding 2 mg/L of nitrate. Precipitation and (or) soil hydraulic conductivity were also important predictor variables in the models. The models for each time period were used to create maps of groundwater vulnerability at 150- and 300-foot depths throughout the Puget Sound basin. As expected, the most vulnerable locations were associated with shallower well depths and increased agriculture and urban land cover. Across all four time periods, groundwater vulnerability throughout the Puget Sound was low, with probabilities of exceeding 2 mg/L concentrations of nitrate at depths at 150 and 300 feet typically less than 50 percent. Results also found a slight decrease in probabilities of elevated nitrate concentrations throughout the basin over time. More specifically, additional statistical tests found that groundwater with probabilities of less than about 60 percent declined from 2000 to 2019 and represented more than 75 percent of the modeled Puget Sound basin aquifer. Wells with greater than 60 percent probability increased over the same time period but represented only about 25 percent of the aquifer. The maps and statistical analysis presented in the study provide valuable and informative evaluation of the vulnerability of groundwater in the Puget Sound basin to elevated nitrate concentrations. The probability maps do not represent measured nitrate concentrations in groundwater, but rather they present the probability that nitrate concentrations exceed 2 mg/L. The models and predictions from this study are a viable indicator for the Puget Sound Partnership’s Healthy Human Population—Drinking Water Vital Sign. The logistic regression modeling approach presented here benefits water managers by allowing them to assess temporal trends in a range of probabilities, explore vulnerability changes as new regional land cover and anthropogenic data are generated, and distinguish vulnerabilities at different depths within the aquifer.

Washington↗
USGS2026

Design and function of the Autonomous Benthic Imaging and Surveying System (ABISS) for remote sensing of lake and seabed environments

Lake and seabed environments are home to fisheries and other biota that are important to ecosystems and economies, yet these environments and the species that use them are difficult to accurately assess and monitor. Traditional benthic survey techniques, like bottom trawling used by the U.S. Geological Survey, are limited by substrate constraints, poor spatial resolution and precision, and operational depth limits, hindering accurate assessment of benthic species and habitats. In response to these limitations, the U.S. Geological Survey developed the Autonomous Benthic Imaging and Surveying System, a camera system integrated into underwater vehicles, to capture high-resolution images of the lakebed. The system uses color and stereo cameras to collect imagery, which can be analyzed using computational methods to detect organisms and (or) characterize habitat features, such as geologic substrate types. The system has been integrated into autonomous underwater vehicles and into an underwater housing used by self-contained underwater breathing apparatus (SCUBA) divers. Although the engineering of the system was motivated by the need for data collection in the Great Lakes, it has potential to collect high quality data in any aqueous setting with sufficient water clarity and safe operating conditions. The Autonomous Benthic Imaging and Surveying System can operate across diverse depths and light conditions to map and quantify ecological patterns that were difficult or impossible to assess using traditional methods. The Autonomous Benthic Imaging and Surveying System offers the potential for accurate and precise monitoring and assessment of native benthic biota, invasive species, and habitat, potentially providing natural resource managers with improved information to support decision making about benthic resource management.

Great Lakes↗
USGS1998

Assessment of the hydraulic connection between ground water and the Peace River, west-central Florida

The hydraulic connection between the Peace River and the underlying aquifers along the length of the Peace River from Bartow to Arcadia was assessed to evaluate flow exchanges between these hydrologic systems. Methods included an evaluation of hydrologic and geologic records and seismic-reflection profiles, seepage investigations, and thermal infrared imagery interpretation. Along the upper Peace River, a progressive long-term decline in streamflow has occurred since 1931 due to a lowering of the potentiometric surface of the Upper Floridan aquifer by as much as 60 feet because of intensive ground-water withdrawals for phosphate mining and agriculture. Another effect from lowering the potentiometric surface has been the cessation of flow at several springs located near and within the Peace River channel, including Kissengen Spring, that once averaged a flow of about 19 million gallons a day. The lowering of ground-water head resulted in flow reversals at locations where streamflow enters sinkholes along the streambed and floodplain. Hydrogeologic conditions along the Peace River vary from Bartow to Arcadia. Three distinctive hydrogeologic areas along the Peace River were delineated: (1) the upper Peace River near Bartow, where ground-water recharge occurs; (2) the middle Peace River near Bowling Green, where reversals of hydraulic gradients occur; and (3) the lower Peace River near Arcadia, where ground-water discharge occurs. Seismic-reflection data were used to identify geologic features that could serve as potential conduits for surface-water and ground-water exchange. Depending on the hydrologic regime, this exchange could be recharge of surface water into the aquifer system or discharge of ground water into the stream channel. Geologic features that would provide pathways for water movement were identified in the seismic record; they varied from buried irregular surfaces to large-scale subsidence flexures and vertical fractures or enlarged solution conduits. Generally, the upper Peace River is characterized by a shallow, buried irregular top of rock, numerous observed sinkholes, and subsidence depressions. The downward head gradient provides potential for the Peace River to lose water to the ground-water system. Along the middle Peace River area, head gradients alternate between downward and upward, creating both recharging and discharging ground-water conditions. Seismic records show that buried, laterally continuous reflectors in the lower Peace River pinch out in the middle Peace River streambed. Small springs have been observed along the streambed where these units pinch out. This area corresponds to the region where highest ground-water seepage volumes were measured during this study. Further south, along the lower Peace River, upward head gradients provide conditions for ground-water discharge into the Peace River. Generally, confinement between the surficial aquifer and the confined ground-water systems in this area is better than to the north. However, localized avenues for surface-water and ground-water interactions may exist along discontinuities observed in seismic reflectors associated with large-scale flexures or subsidence features. Ground-water seepage gains or losses along the Peace River were quantified by making three seepage runs during periods of: (1) low base flow, (2) high base flow, and (3) high flow. Low and high base-flow seepage runs were performed along a 74-mile length of the Peace River, between Bartow and Nocatee. Maximum losses of 17.3 cubic feet per second (11.2 million gallons per day) were measured along a 3.2-mile reach of the upper Peace River. The high-flow seepage run was conducted to quantify losses in the Peace River channel and floodplain between Bartow and Fort Meade. Seepage losses calculated during high-flow along a 7.2-mile reach of the Peace River, from the Clear Springs Mine bridge to the Mobil Mine bridge, were approximately 10 percent of the river flow, or 118 cubic feet per second. Calculated seepages along the Peace River in Hardee and De Soto Counties were inconclusive, because most seepages were within the range of discharge measurement error. Two continuous aerial thermal infrared imagery surveys were conducted to locate sites of ground-water discharge along the Peace River. Although temperature and hydrologic conditions were ideal to observe spring flow using thermal infrared imaging techniques, no sources of ground-water discharge were identified using this method. Diffuse ground-water seepage may, however, provide significant ground-water discharge.

Florida↗