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1,658 records · Page 34Linked to original sources
USGS2025

Evidence of mineral alteration in a salt marsh subterranean estuary: Implications for carbon and trace element cycling

Subterranean estuaries (STE) in salt marshes are biogeochemically active zones where interactions between terrestrial groundwater and seawater drive complex cycling of carbon and trace elements, influenced by mineral dissolution. These systems, characterized by fine-grained organic-rich peat overlying permeable coastal aquifers, play a crucial role as a blue carbon sink, yet their geochemical dynamics remain poorly understood. We investigated dissolved trace elements, carbon, silica, and radium isotopes in a salt marsh STE (Sage Lot Pond, Waquoit Bay, MA) over seasonal and annual cycles. Our results reveal that groundwater and estuarine water circulation through marsh peat and aquifer sediments leads to enrichments of dissolved organic and inorganic carbon (DOC and DIC), Si, Ba, and Mn, with variable source/sink behavior of Fe and net removal of U. Submarine groundwater discharge dominated Ba fluxes, whereas pore water drainage from marsh peat acted as the main sink for U and source of Si. Fe cycling was variable, with terrestrial Fe largely removed as groundwater passed through the STE, consistent with Fe-sulfide and amorphous phase formation. Radium isotope ratios identified two distinct subsurface flow pathways, influenced by metal-oxide cycling and organic matter breakdown. Si production was decoupled from DIC, suggesting Si originates from mineral alteration, whereas DIC results from both mineral weathering and microbial respiration. Silicate mineral alteration, coupled with marsh pore water drainage, accounts for up to 16% of annual DIC exports (66 g C m −2 y −1 ), highlighting the importance of STEs in coastal carbon and trace element cycling, especially as marshes face environmental change.

Massachusetts↗
USGS2024

Are the horizontal-to-vertical spectral ratios of earthquakes and microtremors the same?

We consider the similarities and differences between earthquake and microtremor horizontal‐to‐vertical spectral ratios (eHVSR and mHVSR, respectively) using a dataset of 161 sites in southern California. Quantitative comparisons are made in terms of the eHVSR and mHVSR lognormal median curves, as well as the frequencies and amplitudes associated with the fundamental‐ and higher‐mode resonances where present. The results show only 58% of the eHVSR–mHVSR pairs agree in terms of their median curve and only 25% of the eHVSR–mHVSR pairs agree in terms of shared resonances, which increases to 68% if flat HVSRs are considered equivalent. Furthermore, while the shared resonances match very well in terms of frequency (root mean square error, RMSE, <0.11 Hz), the amplitudes of those resonances do not agree (RMSE >1.6). These findings demonstrate that while eHVSR and mHVSR agree at some sites, they are not equivalent at all sites. To investigate if the agreement between eHVSR and mHVSR could be related to features of the microtremor data, earthquake recordings, and/or the site conditions, three machine learning (ML) models at varying levels of interpretability are presented. The ML models—which include multivariate logistic regression, gradient‐boosted trees, and support vector machines—show only partial success at using site‐specific data to predict whether eHVSR and mHVSR will likely agree in terms of their median curve (accuracy of 78%) and number of resonances (accuracy of 84%). Therefore, we conclude that while eHVSR and mHVSR can be quite similar in terms of resonant frequencies at some sites, they are not identical at all sites. Furthermore, preliminary evidence shows that the agreement of eHVSR and mHVSR can be predicted a priori given features of the microtremor measurements, earthquake recordings, and site conditions, although a larger dataset will be necessary for developing a robust predictive model.

California↗
USGS2025

Modeling seawater intrusion along the Alabama coastline using physical and machine learning models to evaluate the effects of multiscale natural and anthropogenic stresses

Seawater intrusion threatens groundwater resources in coastal regions, including southern Baldwin County, Alabama, where the freshwater-saltwater interface dynamics remain poorly understood. To address this gap, this study uses combined physics-based and machine-learning models to quantify seawater intrusion caused by natural (storm surges) and anthropogenic (human activities) perturbations. The long short-term memory network and wavelet analysis were used to assess vertical aquifer vulnerabilities, revealing that the shallow part of the Coastal lowlands aquifer system (CL1) in the southern Baldwin County region is more susceptible to sea level rise and groundwater extraction than deeper aquifers. Based on these findings, a cross-sectional numerical model (physics approach) for the CL1 aquifer was developed to evaluate tidal and storm surge effects, using Tropical Storm Claudette (June 2021) as a case study. Results showed that tidal fluctuations had a minimal impact on the saltwater-freshwater interface location, whereas storm surges caused substantial inland movement, with effects lasting for nine months. The steady-state version of the three-dimensional (3D) physical model predicted seawater intrusion across the entire area, and convolutional neural network-based modeling further validated the model results. The 3D physical model was also applied to a smaller area to assess human impact on the saltwater interface due to two groundwater pumping scenarios (± 50% of the baseline pumping rate). Results revealed that a 50% increase in groundwater withdrawals caused seawater to advance ~ 320 m inland, whereas a 50% reduction led to a ~ 270-meter retreat. This study highlights the vulnerability of Alabama’s shallow coastal aquifers to seawater intrusion due to storm surges and human activities, and demonstrates that combining physics-based models with machine learning approaches can improve groundwater predictions, though its accuracy depends on the availability of site-specific data.

Alabama↗
USGS2025

Estimating agricultural irrigation water consumption for the High Plains aquifer region with integrated energy- and water-balance evapotranspiration modeling approaches

Estimation of irrigation water use provides essential information for the management and conservation of agricultural water resources. Conventionally, water use data are created based on reports and surveys from water users, whereas manual records may not be complete due to lacking flow meters, measurement gaps, inconsistent methods across regions, and time- and cost-consuming data processing. Alternatively, spatially explicit estimation of irrigation water use can be conducted efficiently using remote sensing evapotranspiration (ET) modeling approaches. In this study, we created a gridded blue water evapotranspiration (BWET) dataset to estimate historical irrigation water consumption (1986 – 2020) in the croplands across the United States High Plains aquifer region. The BWET data were generated by integrating an energy-balance ET model [Operational Simplified Surface Energy Balance model (SSEBop)] and a water-balance ET model [Vegetation ET model (VegET)]. BWET in croplands indicates crop consumptive use of irrigation water extracted from surface water and groundwater resources. The BWET estimates were compared with reported irrigation water use data for all counties within the aquifer region. The results revealed high agreement between growing season (May – September) BWET and annual water withdrawal at county level. Specifically, correlation coefficients of volumetric BWET and water withdrawal were 0.90 and 0.96, respectively, for the entire aquifer region and western Kansas. The timeseries of BWET and water withdrawal showed similar temporal trends and high covariations. The BWET estimates were systematically lower than the water withdrawal measurements, which was primarily attributed to blue water losses in the irrigation system. The irrigation efficiency, calculated as the ratio of BWET to water withdrawal depth, was 0.57 and 0.74 for the entire aquifer region and western Kansas, respectively. This study demonstrates the capability of using satellite-based ET models (e.g., SSEBop and VegET) to efficiently estimate crop water consumption and evaluate irrigation efficiency at landscape, county, and regional scales.

Colorado, Kansas, Nebraska, New Mexico, Oklahoma, ↗
USGS2024

A conceptual framework to assess post-wildfire water quality: State of the science and knowledge gaps

Wildfire substantially alters aquatic ecosystems by inducing moderate to catastrophic physical and chemical changes. However, the relations of environmental and watershed variables that drive those effects are complex. We present a Driver-Factor-Stressor-Effect (DFSE) conceptual framework to assess the current state of the science related to post-wildfire water-quality. We reviewed 64 peer-reviewed papers using the DFSE framework to identify drivers, factors, stressors, and effects associated with each study. A total of five drivers were identified and ranked according to their frequency of occurrence in the literature: atmospheric processes > fire characteristics > ecologic processes and characteristics > land surface characteristics > soil characteristics. Commonly reported stressors include increased nutrients, runoff, and sediment transport. Furthermore, although several different factors have been used at least once to explain water-quality effects, relatively few factors outside of precipitation and fire characteristics are frequently studied. We identified several gaps indicating the need for long-term monitoring, multi-factor studies, consideration of organic contaminants, consideration of groundwater, and inclusion of soil characteristics. This assessment expands on other reviews and meta-analyses by exploring causal linkages between influential variables and overall effects in post-wildfire watersheds. Information gathered from our assessment and the framework itself can be used to inform future monitoring plans and as a guide for modeling efforts focused on better understanding specific processes or to mitigate potential risks of post-wildfire water quality.

Water Resources Research↗
USGS2026

Stream sediment sources in Medicine Creek, northern Missouri and southern Iowa

This report presents the results of a cooperative study by the U.S. Geological Survey and Missouri Department of Natural Resources to quantify sediment transport source contributions in the Medicine Creek drainage basin. Understanding relative source contributions provides valuable information for selecting the conservation practices that may be most effective in reducing sediment and sediment-associated nutrient transport in the Medicine Creek drainage basin and similar areas of the Lower Grand River drainage basin. Sediment samples were collected from potential contributing areas (source samples) and from fluvial-transported samples (target samples). Source sample types included streambanks, row crop fields, and a combined pastures and forests category. Samples were analyzed for particle size and quantity of carbon, nitrogen, stable isotopes of carbon and nitrogen, and 49 mineral elements as potential tracers. Results for the carbon stable isotope ratio of carbon-13/carbon-12 (δ 13 C) and concentrations of total carbon, total nitrogen, calcium, potassium, and copper were selected by discriminant function analysis as the best combination of multiple tracers to differentiate each source type. The discriminant function analysis poorly differentiated pastures and forests, so these source types were combined. The sources defined by the discriminant function analysis were then used in an unmixing model to apportion sources for each target sample. In the study area, transported sediment was predominantly bank sediment, with an overall average of 86.9 percent of suspended-sediment samples and depositional streambed samples attributed to bank material. Suspended-sediment samples from the mainstem of Medicine Creek were dominated by bank sediments (average of 95.8 percent), and depositional streambed samples from throughout the drainage basin had more variable source contributions with an average of 71.1 percent attributed to bank material. The relative importance of upland sources (row crop fields and the combined pastures and forests category) varied seasonally and with streamflow but was not related to land use or drainage basin size. Relative contributions from upland sources were greater in the summer through winter rather than spring and during lower streamflow, though this may be driven by the seasonality of streamflow. These results indicate management practices that reduce bank erosion could be effective strategies for managing the dominant source of sediment and sediment-associated phosphorus.

Iowa, Missouri↗
USGS2024

Substrate Enhancement Pilot Project—Monitoring summary and evaluation, Kootenai River, Idaho, 2012–22

To assess changes in substrate conditions and the efficacy of artificially placed substrates at select sites on the Kootenai River near Bonners Ferry, Idaho, the U.S. Geological Survey, in cooperation with the Kootenai Tribe of Idaho, completed repeat bathymetric, velocimetric, and underwater videography surveys. Collectively, three project sites throughout the Kootenai River make up the Substrate Enhancement Pilot Project (SEPP), an effort intended to improve spawning and egg incubation viability at locations identified to be aquatic habitat limited for the endangered Kootenai River white sturgeon (Acipenser transmontanus). Following the placement of coarse substrates at each site, bathymetric, velocimetric, and underwater videography data were collected from 2012 to 2022 to assess the role of deposition and erosion on maintaining suitable white sturgeon spawning and incubation substrates. Minimal erosion and deposition occurred at all Substrate Enhancement Pilot Project sites, according to interannual and intra-annual net volumetric changes between bathymetric surveys. Depending on the timing of bathymetric surveys relative to the annual peak streamflow conditions, isolated locations of deposition or erosion were observed at each site and the potential for deposition or erosion was supported by measured mean depth-averaged velocities. This study concluded that variability of deposition and scour were common at each site throughout the monitoring period and may be attributed to fluctuations in streamflow. Repeat bathymetric, underwater videography, and velocity mapping surveys were used to verify the interstitial spaces and surfaces of substrates at each SEPP site remained free of fine sediments for intervals longer than a year but were susceptible to deposition between high streamflow events.

Idaho↗
USGS1999

Concentrations and distribution of manmade organic compounds in the Lake Tahoe Basin, Nevada and California, 1997-99

The U.S. Geological Survey, in cooperation with the Tahoe Regional Planning Agency and the Lahontan Regional Water-Quality Control Board, sampled Lake Tahoe, major tributary streams to Lake Tahoe, and several other lakes in the Lake Tahoe Basin for manmade organic compounds during 1997-99. Gasoline components were found in all samples collected from Lake Tahoe during the summer boating season. Methyl tert -butyl ether (MTBE), benzene, toluene, ethylbenzene, and xylenes (BTEX) were the commonly detected compounds in these samples. Most samples from tributary streams and lakes with no motorized boating had no detectable concentrations of gasoline components. Motorized boating activity appears to be directly linked in space and time to the occurrence of these gasoline components. Other sources of gasoline components to Lake Tahoe, such as the atmosphere, surface runoff, and subsurface flow, are minor compared to the input by motorized boating. Water sampled from Lake Tahoe during mid-winter, when motorized boating activity is low, had no MTBE and only one sample had any detectable BTEX compounds. Soluble pesticides rarely were detected in water samples from the Lake Tahoe Basin. The only detectable concentrations of these compounds were in samples from Blackwood and Taylor Creeks collected during spring runoff. Concentrations found in these samples were low, in the 1 to 4 nanograms per liter range. Organochlorine compounds were detected in samples collected from semipermeable membrane devices (SPMD's) collected from Lake Tahoe, tributary streams, and Upper Angora Lake. In Lake Tahoe, SPMD samples collected offshore from urbanized areas contained the largest number and highest concentrations of organochlorine compounds. The most commonly detected organochlorine compounds were cis- and trans-chlordane, p , p' -DDE, and hexachlorobenzene. In tributary streams, SPMD samples collected during spring runoff generally had higher combined concentrations of organochlorine compounds than those collected during baseflow conditions. Upper Angora Lake had the fewest number of organochlorine compounds detected of all lake samples. Dioxins and furans were not detected in SPMD samples from two sites in Lake Tahoe or from two tributary streams. The number of polycyclic aromatic hydrocarbon (PAH) compounds and their combined concentrations generally were higher in samples from Lake Tahoe than those from tributary streams. Areas of high-motorized boating activity at Lake Tahoe had the largest number and highest concentrations of PAH's. PAH compounds were detected in samples from SPMD's in four of six tributary streams during spring runoff, all tributary streams during baseflow conditions, and at all lake sites. The most commonly detected PAH's in tributary streams during spring runoff were phenanthrene, fluoranthene, pyrene, and chrysene, and during baseflow conditions were phenanthrene, 1-methylphenanthrene, diethylnaphthalene, and pyrene. Upper Truckee River, which has an urban area in its drainage basin, had the largest number and highest combined concentration of PAH's of all stream samples. Bottom-sediment from Lake Tahoe had detectable concentrations of p-cresol, a phenol, in all but one sample. A sample collected near Chambers Lodge contained phenol at an estimated concentration of 4 micrograms per kilogram (µg/kg). Bottom-sediment samples from tributary streams had no detectable concentrations of organochlorine or PAH compounds. Several compounds were detected in bottom sediment from Upper Angora Lake at high concentrations. These compounds and their concentrations were p , p' -DDD (10 µg/kg), p , p' -DDE (7.4 µg/kg), 2,6-dimethylnaphthalene (estimated at 190 µg/kg), pentachlorophenol (3,000 µg/kg), and p-cresol (4,400 µg/kg).

California, Nevada↗
USGS2024

Precariously balanced rocks in northern New York and Vermont, U.S.A.: Ground-motion constraints and implications for fault sources

Precariously balanced rocks (PBRs) and other fragile geologic features have the potential to constrain the maximum intensity of earthquake ground shaking over millennia. Such constraints may be particularly useful in the eastern United States (U.S.), where few earthquake‐source faults are reliably identified, and moderate earthquakes can be felt at great distances due to low seismic attenuation. We describe five PBRs in northern New York and Vermont—a region of elevated seismic hazard associated with historical seismicity. These boulders appear to be among the most fragile PBRs in the region, based on reports from hobbyists. The PBRs are glacial erratics, best evidenced by glacial striations on bedrock pedestals. The pedestals themselves are locally high knobs, often situated on regionally high topography; this setting limits soil development and indicates that any outwash deposits were likely ephemeral. As a result, PBR ages can be reliably established by the retreat of the last continental ice sheet, ∼15–13 ka. To quantify the fragility of the PBRs, we surveyed them with ground‐based light detection and ranging and calculated geometric parameters from the point clouds, field observations, and seismic responses. Preliminary validation of the 2023 time‐independent U.S. National Seismic Hazard Model (NSHM) shows that the existence of PBRs is generally consistent with the median site‐specific hazard curves. Only the Blue Ridge Road site suggests a modest reduction in hazard. To visualize the ensemble of data, we mapped the minimum permissible distance to potential source faults around each PBR site as a function of source magnitude by using the ground‐motion models from the 2023 NSHM. Viewed in this manner, our data are consistent with potential M ∼6.5 earthquake‐source faults in many parts of the Lake Champlain Valley and northern Adirondack Mountains. Our work illustrates a potential pathway for better constraining earthquake‐source faults in regions of cryptic faults.

Bulletin of the Seismological Society of America↗
USGS2023

Reconnaissance basement geology and tectonics of North Zealandia

New rock dredge samples supply key information to establish the tectonic and geological framework of the northern two-thirds of the 95% submerged Zealandia continent. The R/V Investigator voyage IN2016T01 to the Fairway Ridge, Coral Sea, obtained poorly sorted poly-lithologic pebbly to cobbly sandstones, well sorted fine grained sandstones, mudstones, bioclastic limestones, and basaltic lavas. Post-cruise analytical work comprised petrography, whole rock geochemical and Sr and Nd isotopic analyses, and U-Pb zircon, Rb-Sr, and Ar-Ar geochronology. A Fairway Ridge cobbly sandstone has a ∼95 Ma (early Late Cretaceous) depositional age; two biotite granite cobbles are 111 ± 1 and 128 ± 1 Ma in age, and some volcanic pebbles are also likely Early Cretaceous. Fairway Ridge basalts have intraplate alkaline chemistry and are of Late Eocene age (∼40–36 Ma). By analogy with South Zealandia, we interpret strong positive continental magnetic anomalies of North Zealandia to mainly result from Late Cretaceous to Cenozoic intraplate basalts, many of them rift-related lavas. A new basement geological map of North Zealandia shows the position of the Mesozoic Gondwana magmatic arc axis (Median Batholith) and other major geological units. This study completes onland and offshore reconnaissance geological mapping of the entire 5 Mkm 2 Zealandia continent.

Tectonics↗
USGS2007

Divisions of geologic time—Major chronostratigraphic and geochronologic units

Effective communication in the geosciences requires consistent uses of stratigraphic nomenclature, especially divisions of geologic time. A geologic time scale is composed of standard stratigraphic divisions based on rock sequences and calibrated in years. Over the years, the development of new dating methods and refinement of previous ones have stimulated revisions to geologic time scales. Since the mid-1990s, geologists from the U.S. Geological Survey (USGS), State geological surveys, academia, and other organizations have sought a consistent time scale to be used in communicating ages of geologic units in the United States. Many international debates have occurred over names and boundaries of units, and various time scales have been used by the geoscience community. For consistency purposes, the USGS Geologic Names Committee and the Association of American State Geologists developed Divisions of Geologic Time .

Fact Sheet↗
USGS2024

Models no not provide proof: An example of model ambiguity and application of isotopic data in a mine pit lake

Geochemical and hydrologic models of pit lakes are commonly used in environmental regulatory decisions to predict future water quality and hydrologic conditions and to understand existing pit lakes. Models may be used to quantify sulfide oxidation, predict thermal/chemical stratification and mixing, and better understand connections between pit lakes and aquifers. One concern related to the hydrologic character of pit lakes is if they are terminal (a groundwater sink with no outflow) or flowthrough (both receiving groundwater inflow and discharging to groundwater). This question was pertinent to the Liberty pit lake, a small acidic pit lake formed in a former Cu deposit in south-central Nevada where potentiometric and geochemical data potentially indicate pit-lake outflow. Potential discharge to groundwater from the pit lake was evaluated using a water-balance model, but uncertainty in hydraulic parameters led to ambiguity in the hydrologic character. Stable isotopes of water were then sampled from the pit lake and adjacent groundwater wells, which unambiguously indicated the lack of an evaporative signature in downgradient groundwater because the groundwater did not plot on a hypothetical mixing line between evaporated pit lake water and observed meteoric recharge. This methodology provided a more effective and more data-driven approach for understanding pit-lake hydrology. Although predictive models are required to quantify reasonable bounds on future conditions, many models contain substantial uncertainty and are not well suited in some environments. Datasets that provide more clear lines of evidence could be collected from existing pit lakes whenever possible to inform water-rock interaction, limnological behavior, and connectivity to adjacent groundwater.

Nevada↗
USGS2026

Diverging mineral chemistry of iron and nickel throughout Earth’s changing redox conditions reveals foundation for their evolution as protein cofactors

Iron (Fe) and nickel (Ni) were both foundational to early metabolism, yet their biological trajectories diverged as Earth’s surface redox state changed. Here, we integrate mineral chemistry network analysis, protein metal-site coordination-sphere analysis, and curated redox comparisons to test how geochemistry and metalloprotein architecture co-evolved. Mineral network analyses show broader electronegativity variation and network diversity for Fe-bearing minerals through time relative to Ni-bearing minerals. In structural analyses of protein metal centers in a combined Fe/Ni protein structure set, it is shown that Fe- and Ni-associated environments differ in amino-acid composition, hydropathy structure, and cysteine representation. The greater chemical diversity and electronegativity variation in Fe minerals mirror the higher redox and structural versatility of Fe-binding proteins. The presence of Fe in a broader range of mineral and protein environments demonstrates the chemical adaptability of the metal, from the anoxic Archean to oxidative Earth surface conditions following the Great Oxidation Event. Iron, with its broad redox potential range in Fe-oxidoreductases, has a central role in both anaerobic and aerobic metabolisms. Nickel, by contrast, is less widespread in biology. Today, Ni is predominantly employed in deeply branching anaerobic pathways and by proteins with narrower redox potential ranges. Our results show that evolutionary processes, constrained by metal chemistry, habitually utilize Fe as a redox generalist while retaining Ni in specialized roles. The divergent paths of Ni and Fe, from rocks to proteins, demonstrate the intimate relationship between planetary geochemistry and metabolic origins on Earth and suggest that Fe/Ni geochemistry may inform habitability assessments in extraterrestrial environments when interpreted within specific planetary environmental contexts.

Life↗