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USGS2017

Fluorine

Fluorine compounds are essential in numerous chemical and manufacturing processes. Fluorspar is the commercial name for fluorite (isometric CaF 2 ), which is the only fluorine mineral that is mined on a large scale. Fluorspar is used directly as a fluxing material and as an additive in different manufacturing processes. It is the source of fluorine in the production of hydrogen fluoride or hydrofluoric acid, which is used as the feedstock for numerous organic and inorganic chemical compounds. The United States was the world’s leading producer of fluorspar until the mid-1950s. In the mid-1970s, the U.S. fluorspar mining industry began to decline because of foreign competition. By 1982, there was essentially only a single U.S. producer left, and that company ceased mining in 1996. Consumption of fluorspar in the United States peaked in the early 1970s, which was also the peak period of U.S. steel production. Since then, U.S. fluorspar consumption has decreased substantially; the United States has nonetheless increased its imports of downstream fluorine compounds, such as, in order of tonnage imported, hydrofluoric acid, aluminum fluoride, and cryolite. This combination of no U.S. production (until recently) and high levels of consumption has made the United States the world’s leading fluorspar-importing country, in all its various forms. The number of fluorspar-exporting countries has decreased substantially in recent decades, and, as a result, the United States has become dependent on just a few countries to supply its needs. In 2013, the United States imported the majority of its fluorspar from three countries, which were, in descending order of the amount imported, Mexico, China, and South Africa. Geologically, in igneous systems, fluorine is one of a number of elements that are “incompatible.” These incompatible elements become concentrated in the residual magma while the common silicates crystallize upon magma ascent and cooling, leading to relatively high fluorine concentrations in the more evolved or differentiated igneous rocks and in hydrothermal deposits associated with those evolved igneous rocks. In sedimentary rocks, fluorine’s highest concentrations are found in phosphorites because fluorine substitutes for hydroxyl ions in apatite, which leads to fluorine concentrations of, typically, from 2 to 4 weight percent in phosphorites. Because of the presence of fluorine, phosphate fertilizer manufacturers can produce a fluorosilicic acid byproduct. Most deposits mined for fluorine are hydrothermal, however, and consist of fluorine minerals that precipitated from hot water. Magmatic brines and brines from deep within sedimentary basins that have high concentrations of dissolved fluoride are the mineralizing fluids for various types of hydrothermal fluorspar deposits. Relatively dilute hydrothermal fluids that formed in some volcanic rocks can also transport sufficient fluoride to form a high-grade fluorspar deposit. Fluorite has low solubility in a common range of hydrothermal temperatures, particularly from about 160 degrees Celsius (°C) down to 60 °C. The increasing fluorite solubility below 60 °C partly explains why some water with exceptionally high levels of dissolved fluorine are found even at ambient temperatures in evaporitic lake basins in some East African Rift valleys in Kenya and Tanzania. The geologic conditions that led to the high concentrations there are known to exist in a number of other places in the world as well, including, perhaps, places in the Basin and Range province of the United States. Eight minerals or mineral groups have sufficient fluorine in their structures to be considered as possible ores of the element; they are bastnaesite (also spelled bastnäsite; and other fluorocarbonates), cryolite, sellaite, villiaumite, fluorite, fluorapatite (in phosphorites), various phyllosilicates, and topaz. Fluorite is currently the only mineral that is mined for fluorine, and nomineral except fluorite is likely to become a source of commercially produced fluorine as a primary product as long as supplies from relatively thick and high-grade fluorite deposits continue to be available. At least seven classes (which include one subclass) of hydrothermal fluorite deposits are recognized; they are classified according to their tectonic and (or) magmatic settings, as follows: (1) carbonatite-related fluorspar deposits; (2) alkaline-intrusion-related fluorspar deposits; (3) alkaline-volcanic-related epithermal fluorspar deposits; (4) Mississippi Valley-type fluorspar deposits (and a subclass of salt-related carbonate-hosted fluorspar deposits); (5) fluorspar deposits related to strongly differentiated granites; (6) subalkaline-volcanic-related epithermal fluospar deposits; and (7) fluorspar deposits that appear to be conformable within tuffaceous limy lacustrine sediments. An eighth class (not hydrothermal) is that of fluorspar deposits concentrated in soils and weathered zones; that is, residual fluorspar deposits. Generally, fluorspar deposits related to strongly differentiated granites have larger tonnages and lower grades than carbonatite-related fluorspar deposits, which, in turn, have larger tonnages and lower grades than fluorspar vein deposits from various other classes. The United States has a few identified resources of fluorspar, most notably the Klondike II property in the Illinois- Kentucky fluorspar district located about 8 kilometers southwest of Salem, Kentucky, which has a large vein that contains at least 1.6 million metric tons at a grade of 60 percent CaF 2 (Feytis, 2009). Additional fluorspar resources of lower grade but larger tonnage have been identified at Hicks Dome in the Illinois-Kentucky fluorspar district and at Lost River near the western tip of the Seward Peninsula in Alaska, along with a couple of dozen smaller, higher grade resources. Internationally, new mines that either opened before the beginning of 2013 or were scheduled to open soon after that time include the Nui Phao tungsten-fluorspar-bismuth-copper-gold deposit in northern Vietnam; the St. Lawrence project in Newfoundland, Canada, which is located in a well-known fluorspar district; the Bamianshan deposit, which is related to a strongly differentiated granite in northwestern Zhejiang Province, China, near some of that Province’s large, subalkaline-volcanic-related epithermal veins; and the Nokeng project in South Africa, which is also related to a strongly differentiated granite. Other deposits in northwestern Australia, Nevada (United States), Norway, South Africa, and Sweden have been identified and could be put into production within just a few years. Among undiscovered resources, an interesting possibility might be to produce a fluorine product from evaporitic, high-fluorine, high-pH sodium-carbonate brines like Lake Magadi (Kenya) and Lake Natron (Tanzania) in Africa’s Eastern Rift Valley. In addition, apparently conformable fluorspar deposits in tuffaceous limy lacustrine sediments, such as those in Italy, are likely to occur in similar young alkalic volcanic settings elsewhere in the world. Modern geophysical and geochemical exploration techniques have typically not been brought to bear in exploration for new fluorspar deposits, although such techniques are likely to be used in future exploration. The tendency for fluorine to dissolve in significant concentrations in water at low temperature allows both surface water and groundwater to be used as sampling media in geochemical exploration. Evolved granite-related fluorspar deposits may be particularly susceptible to geophysical exploration methods because crystalline rocks that form a basement to sedimentary sections can be approximately defined with gravity and magnetic methods, and magnetite-bearing skarns can be directly detected with magnetic surveys. Environmental considerations of fluorine mining focus especially on drinking water, where high fluorine concentrations can lead to tooth decay; dental and skeletal fluorosis; and bone and cartilage conditions, including genu valgum, which is the crippling bone deformity more commonly known as knock knee. Trace amounts of other elements in fluorspar ores are a concern at some deposits; for example, high beryllium concentrations in alkaline-volcanic-related epithermal deposits or high cadmium concentrations associated with Mississippi Valley-type and salt-related carbonate-hosted fluorspar deposits. Future research might include testing whether fluorine can be extracted economically from high-pH, sodium-carbonate brines and exploring for new occurrences of apparently conformable fluorspar deposits in tuffaceous limy lacustrine sediments outside of the Latium Region of Italy. Other promising new areas of research could be studies of fluorspar deposit fluid inclusion compositions by quadrupole mass spectrometry, by noble gas mass spectrometry on irradiated fluid inclusions, or by chlorine isotopes, while also measuring the chemistry of the same fluid inclusions either by bulk crush-and-leach methods or by laser ablation-inductively coupled plasma mass spectrometry. Advanced studies of fluid inclusion chemistry could be applied beneficially to some of the enigmatic large epithermal fluorspar veins at various places in the world, where they might determine those deposits’ possible relationships to igneous intrusions, or to dissolved salt, or to heated meteoric water in volcanic sections, or perhaps to all three. This knowledge could help focus new exploration.

Professional Paper↗

USGS2023

Ambient seismic noise tomography of the Kingdom of Saudi Arabia

Harrat Rahat is a Cenozoic volcanic field in the west-central part of the Kingdom of Saudi Arabia, 150 kilometers east of the Red Sea, and is the site of the most recent eruption in the country (1256 C.E.; 654 in the year of the Hijra). The city of Al Madīnah lies at the north end of Harrat Rahat, and its volcanic and seismic risks are frequently reassessed. In 2009 C.E. an earthquake swarm at Harrat Lunayyir, 200 km west-northwest of Al Madīnah, produced significant shaking and some building damage in nearby communities, which prompted a revision of seismic hazard models for the region. A network of seismic stations on this volcanically active western side of the Arabia Plate was installed, and stations were also added in the tectonically active northern part of the country. Although regional earthquakes may be used to determine the crustal structure of the western Arabia Plate, such crustal models are hindered by insufficient numbers of earthquakes in the stable plate interior. Tomography studies can be used to infer material properties of the subsurface, such as presence of partial melt, and are beneficial for volcanic hazard assessments. We use ambient seismic noise to compute Rayleigh and Love surface-wave dispersion maps between 5 and 12 second periods for a subset of seismic stations within and near northern Harrat Rahat. The surface-wave maps are inverted to produce shear-wave velocities using a neighborhood algorithm and interpolated into a pseudo three-dimensional model. The distributions of surface-wave and shear-wave velocities are heterogenous, varying from ±3–8 percent. However, low velocities are not restricted to Harrat Rahat. We observed a difference between Rayleigh- and Love-wave velocities that extends north of the site of the 1256 C.E. eruption and coincides with a low gravity anomaly. We obtain a shear-wave velocity increase of 10–15 percent between 15- and 25-kilometers depth, which is consistent with the presence of a transition between the felsic upper crust and the mafic lower crust of the Arabian Shield. The average shear-wave velocities of the upper and lower crust are estimated to be 3.64 and 3.95 kilometers per second using Rayleigh waves and 3.53 and 4.16 kilometers per second using Love waves, which are in good agreement with the results of other geophysical surveys in this area. The modest magnitude of the low-velocity anomalies within the crust and their locations extending well beyond the limits of Harrat Rahat indicate that they are not caused by a crustal magma chamber. If magma chambers exist, they are smaller than can be imaged with our seismological method (resolution corresponds to a 15-kilometer wavelength), deeper than 30 kilometers, or shallower than 5 kilometers with a small velocity contrast. The last possibility is discounted by weak-to-absent surface geothermal activity and by a lack of shallow seismicity that characterizes other areas with known shallow magmas, such as Hawaiʻi. We then expanded our work to the entire Arabian Shield with principally the same methodology to look at large-scale regional patterns. We found modest shear-wave velocity deviations on the order of only ±3 percent, which are within expected ranges for lithological variation.

Professional Paper↗

USGS1976

Gravity and magnetic studies of the Geysers-Clear Lake geothermal region, California, USA

Gravity and magnetic fields in The Geysers-Clear Lake region are interpreted in relation to the known geology and other available geophysical data. New gravity data provide additional detail with the area of geothermal steam production. Computer techniques were used for removal of the regional gravity field, anomaly enhancement, and modeling subsurface structures. The gravity field was separated into three components: (1) a regional field presumed to be due to deep crustal structure related to the continental margin; (2) a residual gravity low of approximately 30 mgal centered over Mount Hannah and having an approximate diameter of 20 km, which is caused, according to our model, by a magma chamber whose top lies within 10 km of the surface; and (3) a closed residual low over the original steam production field. This low is probably related to effects within 1.5 km of the surface and was modeled as a steam-saturated reservoir structure. Local magnetic highs correlate with surface outcrops of serpentinite and relief on the volcanic rocks. Upward continuation of the aeromagnetic data suggests that the serpentinite body along the Collayomi fault may extend to a depth of more than 3 km near Boggs Mountain, but that other serpentinite bodies are probably more shallow. A long-wavelength magnetic high (centered at ~39°03'N 122°33'W) and a magnetic low (centered at ~38&deg:43'N 122°47'W) give half-width depth estimates of about 10 km. The center of the Mount Hannah gravity low lies in an area between these features and appears devoid of deep magnetic expression.

California↗

USGS1997

Permeability and porosity of the Illinois UPH 3 drillhole granite and a comparison with other deep drillhole rocks

Permeability, porosity, and volumetric strain measurements were conducted on granite cores obtained at depths of 0.7 to 1.6 km from the Illinois UPH 3 drillhole at effective confining pressures from 5 to 100 MPa. Initial permeabilities were in the range of 10-17 to 10-19 m2 and dropped rapidly with applied pressure to values between 10-20 and 10-24 m2 at 100 MPa, typical of other deep granite core samples. These values are several decades lower than equivalent weathered surface granites at comparable effective confining pressures, where weathering products in cracks and pores inhibit crack closure with applied pressure. Permeabilities of the Illinois cores were inversely related to sample depth, suggesting that stress relief and thermal microfractures induced during core retrieval dominated the fluid flow. Thus these samples provide an upper bound on in situ matrix permeability values. A comparison of core permeability from UPH 3 and other deep drillholes shows that stress relief damage can often dominate laboratory permeability measurements. We conclude that it may be difficult to make meaningful estimates of in situ permeability based on either borehole samples (possible damage during retrieval) or surface-derived analogs (altered by weathering). Volumetric strain determined from porosity measurements was compared with differential strain analysis (DSA) data reported by other investigators on samples from the same depths in the drillhole. Our strain measurements (0.002 to 0.005 at 100 MPa) were nearly twice as large as the DSA values, probably because of the crack-enhancing effects of fluids present in our samples that are absent in the dry DSA cores, as well as other time-dependent deformation effects. This difference in observed strain magnitudes between the two measurement methods may be an important consideration if strain and/or porosity data from deep core samples are used in models of stress, fluid circulation, and excess fluid pressure generation in the midcrust.

Journal of Geophysical Research B: Solid Earth↗

USGS1998

Two-way coupling between Vesuvius eruptions and southern Apennine earthquakes, Italy, by elastic stress transfer

During the past 1000 years, eruptions of Vesuvius have often been accompanied by large earthquakes in the Apennines 50–60 km to the northeast. Statistical investigations had shown that earthquakes often preceded eruptions, typically by less than a decade, but did not provide a physical explanation for the correlation. Here, we explore elastic stress interaction between earthquakes and eruptions under the hypothesis that small stress changes can promote events when the Apennine normal faults and the Vesuvius magma body are close to failure. We show that earthquakes can promote eruptions by compressing the magma body at depth and opening suitably oriented near-surface conduits. Voiding the magma body in turns brings these same normal faults closer to Coulomb failure, promoting earthquakes. Such a coupling is strongest if the magma reservoir is a dike oriented normal to the regional extension axis, parallel to the Apennines, and the near-surface conduits and fissures are oriented normal to the Apennines. This preferred orientation suggests that the eruptions issuing from such fissures should be most closely linked in time to Apennine earthquakes. Large Apennine earthquakes since 1400 are calculated to have transferred more stress to Vesuvius than all but the largest eruptions have transferred to Apennine faults, which may explain why earthquakes more commonly lead than follow eruptions. A two-way coupling may thus link earthquakes and Vesuvius eruptions along a 100-km-long set of faults. We test the statistical significance of the earthquake-eruption correlation in the two-way coupling zone, and find a correlation significant at the 95% confidence level.

Journal of Geophysical Research B: Solid Earth↗

USGS2012

Test drilling and data collection in the Calaveras County portion of the Eastern San Joaquin Groundwater Subbasin, California, December 2009-June 2011

Two multiple-well monitoring sites were drilled in the Calaveras County portion of the Eastern San Joaquin Groundwater Subbasin, about 100 miles east of San Francisco, California, during December 2009 and January 2010. Site 3N/9E-12G1-4 was drilled to a depth of 503 feet below land surface (bls), and four wells were installed. Site 4N/9E-36A1-3 was drilled to a depth of 400 feet bls, and three wells were installed. Lithologic and geophysical data collected during test drilling indicated the presence of volcanic sands interspersed with lahar deposits that are characteristic of the Mehrten Formation to about 420 feet bls at site 12G1-4, and the presence of volcanic sands interspersed with clay that are characteristic of the Valley Springs Formation at site 36A1-3. In January 2010, water levels at site 12G1-4 ranged from 120 to 127 feet bls (the shallowest well at the site, 12G4, screened from 90 to 110 feet bls, was dry). Between May and November 2010, water levels declined as much as 22 feet in wells 12G1 and 12G2, the deepest wells at this site, and declined about 6 feet in shallower well 12G3. During this same period, water-levels declined less than 8 feet in the three wells at site 36A1-3. Water levels in all monitoring wells recovered to near-May-2010 levels by mid-spring 2011. Dissolved solids in the six sampled monitoring wells (residue on evaporation) ranged from 154 to 239 milligrams per liter (mg/L); arsenic concentrations ranged from 1.8 to 13 micrograms per liter (μg/L), and were greater than the U.S. Environmental Protection Agency Maximum Contaminant Level (MCL) for arsenic of 10 μg/L in well 36A2. The oxygen-18 (δ 18 O) and deuterium (δD) stable-isotopic composition of water from the six monitoring wells and from nine domestic and public-supply wells sampled as part of this study ranged from -6.7 to -8.2 per mil (δ 18 O), and -50 to -60 per mil (δD), and was consistent with values expected for water recharged in the lower altitudes of the Sierra Nevada. Well 36A3, the shallowest well at site 36A1-3, was the only well that contained measurable tritium - indicative of water recharged after 1952. Carbon-14 activities from the six monitoring wells ranged from 76.0 to 18.9 percent modern carbon, and groundwater ages (time since recharge), not corrected for chemical reactions, ranged from 2,200 to 13,400 years before present.

California↗

USGS2018

Geohydrology, geochemistry, and numerical simulation of groundwater flow and land subsidence in the Bicycle Basin, Fort Irwin National Training Center, California

Groundwater pumping from Bicycle Groundwater Basin (referred to as Bicycle Basin) in the Fort Irwin National Training Center, California, began in 1967. From 1967 to December 2010, about 46,000 acre-feet of water had been pumped from the basin and transported to the Irwin Basin. During this time, not only did water levels in the basin decline by as much as 100 feet, the quality of the groundwater pumped from the basin also deteriorated in some wells. The U.S. Geological Survey collected geohydrologic data from existing wells, test holes, and 16 additional monitoring wells installed at 6 sites in Bicycle Basin during 1992–2011 to determine the quantity and quality of groundwater available in the basin. Geophysical surveys, including electrical, gravity, and seismic refraction surveys, were completed to help determine the geometry of the structural basin, delineate depths to the interface between Quaternary and Tertiary rocks, map the depth to the water table, and used to develop a geohydrologic framework and groundwater-flow model for Bicycle Basin. Water samples were used to determine the groundwater quality in the basin and to delineate potential sources of poor-quality groundwater. Analysis of stable isotopes of oxygen and hydrogen in groundwater indicated that presentday precipitation is not a major source of recharge to the basin. Tritium and carbon-14 data indicated that most of the groundwater in the basin was recharged prior to 1952 and had an apparent age of 15,625–39,350 years. Natural recharge to the basin was not sufficient to replenish the groundwater pumped from the basin. Interferograms from synthetic aperture radar data (InSAR), analyzed to evaluate land-surface subsidence between 1993 and 2010, showed 0.23 to 1.1 feet of subsidence during this period near one production well north of Bicycle Lake (dry) playa. A groundwater-flow model of Bicycle Basin was developed and calibrated using groundwater levels for 1964– 2010, and a subsidence model using land-surface deformation data for 1993–2010. Between January 1967 and December 2010, the simulated total recharge from precipitation runoff and underflow from adjacent basins was about 5,100 acre-feet and pumpage from the Bicycle Basin was about 47,000 acrefeet of water. Total outflows exceeded natural recharge during this period, resulting in a net loss of about 42,100 acre-feet of groundwater storage in the basin. The Fort Irwin National Training Center is considering various groundwater-management options in the Bicycle Basin. The groundwater-flow model was used to (1) evaluate changes in groundwater levels and subsidence with the addition of capture and recharge of simulated runoff in retention basins (scenario 1) for predevelopment through 2010; (2) simulate a base case (scenario 2) for reference; and (3) compare projections of alternative future pumping strategies for 2011–60 (scenarios 3–5). Model results from the runoff-capture simulation (scenario 1) indicated that total recharge, including runoff captured using retention basins, locally increased water levels, which partially offset, but did not mitigate, groundwater depletion associated with pumping. Groundwater-storage depletion in scenario 1 was about 14 percent less than without runoff capture. Simulated-drawdown results in model layer 1 in the eastern part of the basin indicated that, because of the captured runoff, simulated heads were as much as 100 feet higher in December 2010 than prior to the onset of development in 1967. In contrast, simulated drawdown for model without runoff capture indicated that, without captured runoff, simulated heads for December 2010 in this area were 80–90 feet lower than during the predevelopment period. Subsidence was mitigated slightly in scenario 1 compared to without runoff capture; the largest decrease in subsidence at observation sites was about 0.07 feet.

California↗

USGS1986

Field comparison of shallow seismic sources

Choosing a seismic source for a shallow reflection survey can be the most pivotal decision for the engineering geophysicist. The intent of this paper is to present data that will assist in selection of a shallow seismic source best meeting the goals within the constraints of specific projects, particularly in areas where the water table is near the surface. The data were collected (and displayed as seismograms and amplitude spectra) for 15 different shallow seismic sources in October, 1985, at a single site in New Jersey; they show the different characteristics of each source. Considering the almost three orders of magnitude difference in total source energy between the largest and smallest source, we chose a display format that presented the data as objectively as possible, while still allowing direct source‐to‐source comparisons. Two strong reflections at about 100 and 130 ms probably mark the top and bottom of a clay unit 80 m below the surface at this site. Our previous work and that of our colleagues suggests that, given a specific set of site characteristics, any source could dominate the comparison categories addressed here.

New Jersey↗

USGS1998

Effects of topography on the interpretation of the deformation field of prominent volcanoes - Application to Etna

We have investigated the effects of topography on the surface-deformation field of volcanoes. Our study provides limits to the use of classical half-space models. Considering axisymmetrical volcanoes, we show that interpreting ground-surface displacements with half-space models can lead to erroneous estimations of the shape of the deformation source. When the average slope of the flanks of a volcano exceeds 20°, tilting in the summit area is reversed to that expected for a flat surface. Thus, neglecting topography may lead to misinterpreting an inflation of the source as a deflation. Comparisons of Mogi's model with a three-dimensional model shows that ignoring topography may lead to an overestimate of the source-volume change by as much as 50% for a slope of 30°. This comparison also shows that the depths calculated by using Mogi's solution for prominent volcanoes should be considered as depths from the summit of the edifices. Finally, we illustrate these topographic effects by analyzing the deformation field measured by radar interferometry at Mount Etna during its 1991–1993 eruption. A three-dimensional modeling calculation shows that the flattening of the deflation field near the volcano's summit is probably a topographic effect.

Geophysical Research Letters↗

USGS2003

Hydrological response to earthquakes in the Haibara well, central Japan - II. Possible mechanism inferred from time-varying hydraulic properties

28 coseismic groundwater level decreases have been observed at the Haibara well, Shizuoka prefecture, central Japan, from 1981 to 1997. These groundwater level changes cannot be explained as the poroelastic response to coseismic static strain. We use the atmospheric pressure and tidal responses of the well, rock properties measured on core samples from the same formation and pumping test results to characterize the hydraulic and mechanical properties of the aquifer. The responses of the Haibara well to the M2 Earth tide constituent and to atmospheric pressure have varied over time. In particular, increasing amplitude and decreasing phase lags were observed after the 1993 pumping test, as well as after earthquakes that caused coseismic water level changes. The tidal response, together with the surface load efficiency derived from the atmospheric pressure response, is used to estimate the mechanical properties of the aquifer. The largest amplitude of the M2 constituent, 2.2 mm, is small enough to imply that pore fluid in this system is approximately twice as compressible as water, possibly due to the presence of a small amount of exsolved gas. Diffusion of a coseismic pressure drop near the well could account for the observed time histories of the water level changes. The time histories of the water level drops are well matched by the decay of a coseismic pressure drop at least 80 m away from the well. Removal of a small amount of gas from the formation in that location might in turn explain the coseismic pressure drops.

Geophysical Journal International↗

USGS2009

A comparison of phase inversion and traveltime tomography for processing near-surface refraction traveltimes

With phase inversion, one can estimate subsurface velocities using the phases of first-arriving waves, which are the frequency-domain equivalents of the traveltimes. Phase inversion is modified to make it suitable for processing traveltimes from near-surface refraction surveys. The modifications include parameterizing the model, correcting the observed phases, and selecting the complex frequency. This modified phase inversion is compared to traveltime tomography. For two comparisons using computer-simulated traveltimes, the difference between the estimated and correct models, the residual mean, and the residual standard deviation are smaller for the phase inversion than they are for the traveltime tomography. For a comparison using field data from an S-wave refraction survey, both methods estimate models that are consistent with the known geology. Nonetheless, the phase-inversion model includes small-scale features in the bedrock that are geologically plausible; the residual mean and the residual standard deviation are smaller for the phase inversion than they are for the traveltime tomography.

Geophysical Journal↗

USGS2007

Hydrogeologic Setting and Ground-Water Flow in the Leetown Area, West Virginia

The Leetown Science Center is a research facility operated by the U.S. Geological Survey that occupies approximately 455-acres near Kearneysville, Jefferson County, West Virginia. Aquatic and fish research conducted at the Center requires adequate supplies of high-quality, cold ground water. Three large springs and three production wells currently (in 2006) supply water to the Center. The recent construction of a second research facility (National Center for Cool and Cold Water Aquaculture) operated by the U.S. Department of Agriculture and co-located on Center property has placed additional demands on available water resources in the area. A three-dimensional steady-state finite-difference ground-water flow model was developed to simulate ground-water flow in the Leetown area and was used to assess the availability of ground water to sustain current and anticipated future demands. The model also was developed to test a conceptual model of ground-water flow in the complex karst aquifer system in the Leetown area. Due to the complexity of the karst aquifer system, a multidisciplinary research study was required to define the hydrogeologic setting. Geologic mapping, surface- and borehole-geophysical surveys, stream base-flow surveys, and aquifer tests were conducted to provide the hydrogeologic data necessary to develop and calibrate the model. It would not have been possible to develop a numerical model of the study area without the intensive data collection and methods developments components of the larger, more comprehensive hydrogeologic investigation. Results of geologic mapping and surface-geophysical surveys verified the presence of several prominent thrust faults and identified additional faults and other complex geologic structures (including overturned anticlines and synclines) in the area. These geologic structures are known to control ground-water flow in the region. Results of this study indicate that cross-strike faults and fracture zones are major avenues of ground-water flow. Prior to this investigation, the conceptual model of ground-water flow for the region focused primarily on bedding planes and strike-parallel faults and joints as controls on ground-water flow but did not recognize the importance of cross-strike faults and fracture zones that allow ground water to flow downgradient across or through less permeable geologic formations. Results of the ground-water flow simulation indicate that current operations at the Center do not substantially affect either streamflow (less than a 5-percent reduction in annual streamflow) or ground-water levels in the Leetown area under normal climatic conditions but potentially could have greater effects on streamflow during long-term drought (reduction in streamflow of approximately 14 percent). On the basis of simulation results, ground-water withdrawals based on the anticipated need for an additional 150 to 200 gal/min (gallons per minute) of water at the Center also would not seriously affect streamflow (less than 8 to 9 percent reduction in streamflow) or ground-water levels in the area during normal climatic conditions. During drought conditions, however, the effects of current ground-water withdrawals and anticipated additional withdrawals of 150 to 200 gal/min to augment existing supplies result in moderate to substantial declines in water levels of 0.5-1.2 feet (ft) in the vicinity of the Center's springs and production wells. Streamflow was predicted to be reduced locally by approximately 21 percent. Such withdrawals during a drought or prolonged period of below normal ground-water levels would result in substantial declines in the flow of the Center's springs and likely would not be sustainable for more than a few months. The drought simulated in this model was roughly equivalent to the more than 1-year drought that affected the region from November 1998 through February 2000. The potential reduction in streamflow is a result of capture of ground water tha

Scientific Investigations Report↗

USGS2012

Seismic evidence for active magmatic underplating beneath the Basin and Range Province, western United States

Near-vertical and wide-angle seismic reflection data provide evidence for the presence of a magma body at the base of the crust beneath Buena Vista Valley in northwestern Nevada. The seismic response of this hypothesized magma body is characterized by high-amplitude, near-vertical P wave reflections and a comparably strong P -to- S converted phase. The magma body, referred to here as the Buena Vista Magma Body, is probably a single sill with thickness no greater than 200 m and length no greater than 1.8 km. The melt fraction in the sill is undoubtedly greater than 20–30%, and probably exceeds 50%. Melt composition is unconstrained. Although the age of the Buena Vista Magma Body is difficult to determine precisely, it is probably no older than 500,000 years. This suggests that magmatism in the Basin and Range Province is an ongoing process, despite the relative paucity of volcanic rocks erupted at the surface during the last 6 m.y.

Nevada, Idaho↗

USGS2025

Airborne geophysical analysis to decipher salinization for coastal Louisiana

Coastal Louisiana is known for saltwater intrusion that threatens wetlands, aquifers, and rivers. However, the extent of saltwater intrusion is not well understood. This study develops an innovative framework with airborne electromagnetic (AEM) data to map chloride concentration distributions for wetlands in the Mississippi River deltaic plain and Chenier plain as well as for the Mississippi River Valley alluvial aquifer (MRVA) and Chicot aquifer. Moreover, the framework maps chloride concentrations along the Mississippi River and Atchafalaya River. Key components in the framework include the establishment of resistivity-to-chloride concentration transformation, 3D resistivity architecture building through geostatistics, and the employment of a lithologic model. The transformation functions correlate AEM resistivity data with porewater salinity measurements and groundwater and river chloride samples. The results show that AEM data reliably infers soil water chloride concentrations and correlates well with the distribution of various marsh types. AEM data reveals extensive saltwater presence at depth and near the coast, originating from salt domes and the Gulf of Mexico, respectively. The saltwater upconing pattern in the Chicot aquifer is likely due to excessive groundwater withdrawals. The AEM data also confirms a distinct tongue of saltwater intruding into the Atchafalaya Basin from the Gulf. The AEM data helps to identify faults that are obscured or eroded at the surface, which appear as leaky barriers in the subsurface where dramatic changes in chloride concentration are apparent. Finally, this study uses the AEM data to infer the presence of an extensive seawater wedge in the Mississippi River and Atchafalaya River.

Louisiana↗

USGS2012

Deep magmatic degassing versus scrubbing: Elevated CO2 emissions and C/S in the lead-up to the 2009 eruption of Redoubt Volcano, Alaska

We report CO 2, SO 2 , and H 2 S emission rates and C/S ratios during the five months leading up to the 2009 eruption of Redoubt Volcano, Alaska. CO 2 emission rates up to 9018 t/d and C/S ratios ≥30 measured in the months prior to the eruption were critical for fully informed forecasting efforts. Observations of ice-melt rates, meltwater discharge, and water chemistry suggest that surface waters represented drainage from surficial, perched reservoirs of condensed magmatic steam and glacial meltwater. These fluids scrubbed only a few hundred tonnes/day of SO 2 , not the >2100 t/d SO 2 expected from degassing of magma in the mid- to upper crust (3–6.5 km), where petrologic analysis shows the final magmatic equilibration occurred. All data are consistent with upflow of a CO 2 -rich magmatic gas for at least 5 months prior to eruption, and minimal scrubbing of SO 2 by near-surface groundwater. The high C/S ratios observed could reflect bulk degassing of mid-crustal magma followed by nearly complete loss of SO 2 in a deep magmatic-hydrothermal system. Alternatively, high C/S ratios could be attributed to decompressional degassing of low silica andesitic magma that intruded into the mid-crust in the 5 months prior to eruption, thereby mobilizing the pre-existing high silica andesite magma or mush in this region. The latter scenario is supported by several lines of evidence, including deep long-period earthquakes (−28 to −32 km) prior to and during the eruption, and far-field deformation following the onset of eruptive activity.

Alaska↗

USGS1982

Environmental geology of Harrison Bay, northern Alaska

The surficial and shallow subsurface geology of Harrison Bay on the Beaufort Sea coast was mapped as part of the U.S. Geological Survey's prelease evaluation for Outer Continental Shelf (OCS) Oil and Gas Lease Sale 71. During the 1980 summer season, approximately 1600 km of multisensored, high-resolution geophysical profile data were collected along a rectangular grid with 4.8 km line spacing. Interpretation of these data is presented on five maps showing bathymetry, sea-floor microrelief, ice-gouge characteristics, Holocene sediment thickness, and geologic structure to depths of approximately 1000 m. On a broad scale, the seafloor is shallow and almost flat, although microrelief features produced by sediment transport and ice-gouge processes typically vary up to several meters in amplitude. Microrelief bedforms related to hydraulic processes are predominant in water depths less than 12 m. Microrelief caused by ice gouging generally increases with water depth, reaching a maximum of 2 m or more in water depths beyond the 20 m isobath. This intensely gouged area lies beneath the shear zone between the seasonal landfast ice and the mobile polar ice pack. The thickness of recent (Holocene) sediment increases offshore, from 2 m near the Colville River delta to 30 m or more on the outer shelf. The thin Holocene layer is underlain by a complex horizon interpreted to be the upper surface of a Pleistocene deposit similar in composition to the present Arctic Coastal Plain. The base of the inferred Pleistocene section is interpreted to be a low-angle unconformity 100 m below sea level. Beneath this Tertiary-Quaternary unconformity, strata are interpreted to be alluvial fan-delta plain deposits corresponding to the Colville Group and younger formations of Late Cretaceous to Tertiary age. Numerous high-angle faults downthrown to the north trend across the survey area. With few exceptions, these faults terminate at or below the 100 m unconformity, suggesting that most tectonism occurred before Quaternary time. Acoustic anomalies suggesting gas accumulation are rare, and where identified typically occur adjacent to faults. A laterally continuous zone of poor seismic data occurs in the nearshore area and is interpreted to be caused by subsea permafrost. This report describes these geologic conditions in Harrison Bay and discusses potential hazards that they may pose for future oil and gas operations in Sale 71 and adjacent Beaufort Sea shelf areas.

Open-File Report↗

USGS1997

Variation of the 3-μm absorption feature on Mars: observations over eastern Valles Marineris by the mariner 6 infrared spectrometer

A new approach for calibration of the shortest wavelength channel (1.8 to 6.0 μm) of the Mariner 6 infrared spectrometer was derived. This calibration provides a new description of the instrument response function from 1.8 to 3.7 μm and accounts for the thermal contribution to the signal at longer wavelengths. This allows the two segments from 1.8 to 6 μm to be merged into a single spectrum. The broad water of hydration absorption spans these two segments and is examined in these merged spectra using a method of band integration. Unlike previous analyses which rely on ratios at two wavelengths, the integration method can assess the band strength independently from the albedo in the near infrared. Spectra taken over the eastern end of the Valles Marineris are examined for variations of the band-integrated value, and three distinct clusters are found. Within the estimated uncertainty, two clusters (both low and high albedo) have approximately the same integrated band depth. The third cluster (medium albedo) has an integrated band depth about 10% higher. This difference cannot be systematically attributed to either surface or atmospheric parameters and suggests variation in the amount of water either chemically or physically bound in surface materials. Approximately one-half of the high integrated band depth cluster is associated with chaotic terrain at the source of outflow channels, the other half occurs over lower inertia plains adjacent to chasmata. This suggests both surface physical properties and mineralogy as well as water in exchange with the atmosphere contribute to the 3-μm bound water absorption.

Journal of Geophysical Research E: Planets↗

USGS1993

The Geysers-Clear Lake area, California: Thermal waters, mineralization, volcanism, and geothermal potential

Manifestations of a major thermal anomaly in the Geysers-Clear Lake area of northern California include the late Pliocene to Holocene Clear Lake Volcanics, The Geysers geothermal field, abundant thermal springs, and epithermal mercury and gold mineralization. The epithermal mineralization and thermal springs typically occur along high-angle faults within the broad San Andreas transform fault system that forms the western boundary of the North American plate in this area. The young volcanic rocks overlie Mesozoic marine rocks of the Great Valley sequence which have been thrust above the coeval Franciscan Complex and penecontemporaneously dropped back down along low-angle detachment faults.Many of the waters of the region are nonmeteoric as defined by their isotopic signature. One type of isotopically shifted water emerges from or near Great Valley sequence rocks and is the most chloride rich. It is interpreted to be evolved connate in origin. A second type, evolved meteoric water, has moderate chloride contents, high boron contents, and high B/Cl ratios and is found locally in Franciscan rocks, notably at the Sulphur Bank mercury mine, where it probably results from near-closed-system, repeated boiling of meteoric water in host rocks that also contribute organic components to the water. At the Sulphur Bank mine fracturing of otherwise impermeable Franciscan rocks by faulting has created a localized zone of permeability in which thermal water boils repeatedly with limited venting to the surface. Boron-rich fluids were apparently present at depth in The Geysers geothermal field when intrusion of silicic magma occurred, because the concealed intrusion of felsite is surrounded by a halo of tourmaline-bearing hornfels. The volume of this poorly dated early to middle Quaternary intrusive body probably exceeds the 100 km 3 of erupted Clear Lake Volcanics. Similar intrusions may have occurred in the eastern part of the area at Wilbur Springs and the McLaughlin mine, where gold deposition and evidence of hydrothermal phenomena suggest more magmatic activity than is indicated by the small exposed bodies of early Quaternary basaltic lava. The Clear Lake Volcanics are the present locus of volcanism in the northern Coast Ranges and progressively older volcanic centers occur to the south. Geophysical data suggest that a large silicic magma body may be centered north of The Geysers steam field, providing the heat for the geothermal field.Geothermal power production has peaked at The Geysers and pressure declines indicate significant depletion of the fluid resource. The vapor-dominated field evolved from a preexisting hydrothermal system within fractured, otherwise impermeable Franciscan metamorphic rocks. A deep water table of saline fluid has been postulated to be present under the steam field, but no chloride-rich water has been found at drillable depth. We propose that recently discovered, isotopically shifted steam in the northwest Geysers area indicates the presence not of deep connate water but xather of boiled-down, boron-rich Franciscan evolved meteoric water. This water is likely to be present in limited quantities and will not provide a significant hot water resource for geothermal power production at The Geysers field or from the main Clear Lake volcanic field.

Economic Geology↗