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At least 613 records · Page 34Linked to original sources

Geology of the Ralston Buttes district, Jefferson County, Colorado: a preliminary report

The Ralston Buttes district in Jefferson County is one of the most significant new uranium districts located east of the Continental Divide in Colorado. The district is east of the Colorado Front Range mineral belt, along the east front of the range. From November 1953 through October 1956, about 10,000 tons of uranium ore, much of which was high-grade pitchblende-bearing vein material, was shipped from the district. The ore occurs in deposits that range in size from bodies containing less than 50 tons to ore shoots containing over 1,000 tons. The only other mining activity in the area has been a sporadic production of beryl, feldspar, and scrap mica from Precambrian pegmatites, and quarrying of dimension stone, limestone, and clay from sedimentary rocks. Most of the Ralston Buttes district consists of complexly folded Precambrian metamorphic and igneous rocks - gneiss, schist, quartzite, amphibolite, and granodiorite. Paleozoic and Mesozoic sedimentary rocks crop out in the northeastern part of the district. These rocks are cut by northwesterly-trending fault systems of Laramide age and by small bodies of intrusive rocks that are Tertiary in age. The typical uranium deposits in the district are hydrothermal veins occupying openings in Laramide fault breccias or related fractures that cut the Precambrian rocks. Pitchblende and lesser amounts of secondary uranium minerals are associated with sparse base-mental sulfides in a gangue of carbonate minerals, potash feldspar, and, more rarely, quartz. Less common types of deposits consist of pitchblende and secondary uranium minerals that occupy fractures cutting pegmatites and quartz veins. The uranium deposits are concentrated in two areas, the Ralston Creek area and the Golden Gate Canyon area. The deposits in the Ralston Creek area are located along the Rogers fault system, and the deposits in the Golden Gate Canyon area are along the Hurricane Hill fault system. Two geologic factors were important to the localization of the uranium deposits: (1) favorable structural environment and (2) favorable host rocks. The deposits in each of the two major areas are located where a northwesterly-trending Laramide fault system splits into a complex network of faults. Also, most of the deposits appear to be localized where the faults cut Precambrian rocks rich in hornblende, biotite, or garnet and biotite. The ore controls recognized in this relatively new uranium district may have wider application in areas of similar geology elsewhere in the Front Range.

Colorado↗

The formation, transport, and breakup of submerged oil-particle aggregates in Great Lakes riverine environments

The formation, transport, and resuspension of oil-particle aggregates (OPA) in freshwater environments are of much interest to oil spill responders and scientists, especially as transportation of light and heavy crude oils has substantially increased across river corridors and coasts in the Great Lakes Basin. The persistent sheening from accumulated OPA along 60 km of the Kalamazoo River in Michigan’s lower peninsula resulted in a lengthy and expensive cleanup for the 2010 Enbridge Line 6B pipeline rupture. The interaction of oil with river mineral sediment and organic matter and its long-term fate depend on the physical properties of the oil and particles as well as the environmental setting of river, its climate, morphology, currents and mixing opportunities. This research brief describes the expanded work conducted for the cleanup for the 2010 Enbridge Line 6B pipeline rupture and includes laboratory experiments of aggregate characteristics with Cold Lake Blend and a range of sediment particle sizes, addition of an OPA formation algorithm to an existing sediment contaminant transport model, and development of a simplified, particle-tracking based rapid response model of OPA formation, transport, and deposition. A description of formulas developed for mixing energy in rivers in terms of river properties is also included.

Michigan↗

Climate-driven sulfate export in alpine watersheds may stimulate methylmercury production

Climate change is increasing sulfate export and changing wetland extent in mountain regions. These changes may increase microbially mediated production of the neurotoxic substance methylmercury due to enhanced sulfate metabolism in mountain environments. Here, we assess methylmercury concentrations and formation rates across high-elevation wetlands in the Colorado Rocky Mountains. We also investigate sulfate controls on methylmercury production within subalpine peatlands by amending soils with sulfate to mimic increased stream export of sulfate from the alpine zone and measuring methylmercury formation rates for different sulfate treatments. We found that subalpine peatlands have statistically significant higher methylmercury concentrations and formation rates compared to alpine, mineral-soil wetlands. Methylmercury production in subalpine peatlands also increased significantly ( p < 0.05) following sulfate additions; the highest rates occurred in sediments with intermediate extractable sulfate concentrations (∼0.60–1.4 mg sulfate g −1 dry soil). Our study is the first to identify soil sulfate-related thresholds for methylmercury production and sulfate-limitation of methylmercury production in subalpine peatlands. These findings highlight important linkages between climate-driven mineral weathering and mercury cycling in mountain regions globally.

Colorado↗

Stratigraphic sections, depositional environments, and metal content of the upper part of the Middle Pennsylvanian Minturn Formation, Northern Sangre De Cristo Range, Custer and Saguache counties, Colorado

The calcareous upper part of the 2,000-meter-thick Middle Pennsylvanian Minturn Formation (Lindsey and others, 1985) in the northern Sangre de Cristo Range is a key stratigraphic interval for correlating rocks and mapping the structure of the range. The stratigraphy of this complex and heretofore poorly known interval is reported here in order to provide a basis for correlation among the structural blocks in the range. Inferred depositional environments of the upper part of the Minturn Formation are described briefly. The upper part of the Minturn contains numerous occurrences of stratiform uranium and copper that were examined and sampled in order to document the concentration and distribution of metals within the established stratigraphic framework. The occurrences studied are classified according to the inferred depositional setting of the host rock in order to assess the extent of paleogeographic and paleohydrologic control of mineralized horizons.

Colorado↗

U.S. Geological survey program on toxic waste--ground-water contamination; proceedings of the Second technical meeting, Cape Cod, Massachusetts, October 21-25, 1985

This study characterizes the clay minerals in sediments associated with a plume of creosote-contaminated groundwater. The plume of contaminated groundwater near Pensacola, FL, is in shallow, permeable, Miocene to Holocene quartz sand and flows southward toward Pensacola Bay. Clay-size fractions were separated from 41 cores, chiefly split-spoon samples at 13 drill sites. The most striking feature of the chemical analyses of the clay fractions from uncontaminated site 2 and contaminated sites 4,5,6, and 7 is the variability of iron oxide (species in some samples as Fe2O3); total iron oxide abundance is lowest (2.5%) in uncontaminated sample 2-40, but is > 4.5% (4.5 to 8.5%) in the remaining assemblages. One feature suggesting interaction between the indigenous clays and the waste plume is the presence of nontronite-rich smectite. Nontronite commonly has been identified as the product of hydrothermal alteration and deep-sea weathering of submarine basalts; it is not a common constituent of Cenozoic Gulf Coast sediments. At the Pensacola site, relatively abundant nontronitic smectite is confined to contaminated sands or associated muds; it is least abundant or absent in sands and muds peripheral to the waste plume. The geochemistry of the waste plume, its substantial dissolved, (chiefly ferrous iron), mildly acidic (pH 5-6), and low redox composition, provides an environment similar to that previously determined for the low-temperature synthesis of nontronite. Data from clay-size fractions confirm conclusions that neoformed pyrite in some grain coatings occurs in an assemblage with excess iron over that required in the pyrite. Continuing studies to evaluate these tentative conclusions include: (1) chemical analysis of clay fractions from remaining sites to further examine the apparent relation between iron content and abundance of nontronitic smectite; (2) clay separation and analysis, and pore fluid extraction (squeezing or ultracentrifugation) and analysis from a continuous core through the mud lens to determine pore fluid composition (presence or absence of waste fluid), and character of associated clay minerals; and (3) clay separation and analysis in both permeable sands and the intervening mud lens that are clearly outside the limits of the waste plume to further document the effects of the plume. (See also W90-00022) (Lantz-PTT)

Open-File Report↗

The USGS Abandoned Mine Lands Initiative: Protecting and restoring the environment near abandoned mine lands

The Abandoned Mine Lands (AML) Initiative is part of a larger strategy of the U.S. Department of the Interior and the U.S. Department of Agriculture to clean up Federal lands contaminated by abandoned mines. Thousands of abandond hard-rock metal mines (such as gold, copper, lead, and zinc) have left a dual legacy across the Western United States. They reflect the historic development of the west, yet at the same time represent a possible threat to human health and local ecosystems. Abandoned Mine Lands (AML) are areas adjacent to or affected by abandoned mines. AML's often contain unmined mineral deposits, mine dumps (the ore and rock removed to get to the ore deposits), and tailings (the material left over from the ore processing) that contaminate the surrounding watershed and ecosystem. For example, streams near AML's can contain metals and (or) be so acidic that fish and aquatic insects cannot live in them. Many of these abandoned hard-rock mines are located on or adjacent to public lands administered by the Bureau of Land Management, National Park Service, and U.S. Forest Service. These federal land management agencies and the USGS are committed to mitigating the adverse effects that AML's can have on water quality and stream habitats. The USGS AML Initiative began in 1997 and will continue through 2001 in two pilot watersheds - the Boulder River basin in southwestern Montana and the upper Animas River basin in southwestern Colorado. The USGS is providing a wide range of scientific expertise to help land managers minimize and, where possible, eliminate the adverse environmental effects of AML's. USGS ecologists, geologists, water quality experts, hydrologists, geochemists, and mapping and digital data collection experts are collaborating to provide the scientific knowledge needed for an effective cleanup of AML's.

Arizona, California, Colorado, Idaho, Montana, New↗

The geochemist’s involvement with the pollution problem

The geochemist can contribute much information of value toward assessing the effect of environment, including inorganic pollution, on health. The average composition of rocks, soils, plants, and water and also the increments of inorganic substances that can be expected in geologic environments of high-metal content are essential for comparison with metal contents of these components of the environment in areas contaminated by various types of inorganic air and water pollution. Background levels of lead, zinc, nickel, chromium, copper, and manganese in soils and in four classes of vegetation have been estimated from collections that were made in remote areas presumed to be free from inorganic contamination. The trace-metal content of soils and plants varies widely in different geologic provinces of the United States; in those areas of high natural mineralization, additions of metals from man-made pollution may compound a possible hazard. Results of sampling in urban areas show that contamination of vegetation by gasoline lead can be expected for at least 1000 ft back from transportation lanes, and that the lead burden is increasing greatly with time. Ore-treatment plants can also be a source of air contamination for several miles downwind and several thousand feet in other directions. Soils of naturally high metal content in a mining district may be further contaminated with both major and minor elements from smelting operations. Recent studies show that volatile elements are released directly to the air from ore deposits in place. Concentrations of mercury, for instance, may be as much as 20 times background for several hundred feet in altitude over ore deposits in which mercury occurs as a relatively minor constituent. The source of inorganic pollution in surface drainage and also in ground water is commonly geologic, as rivers may be contaminated from coal and metal deposits in place and also from mining and smelting operations. More information of the type illustrated should be accumulated and made available to scientists who are working in environmental health, and, in particular, to those involved in the pollution problem. Only by these means can we provide a scientific basis for the enactment of realistic and effective legislation for pollution control.

Book chapter↗

Geochemical controls of vanadium accumulation in fossil fuels

High vanadium contents in petroleum and other fossil fuels have been attributed to organic-matter type, organisms, volcanic emanations, diffusion of sea water, and epigenetic enrichment. However, these factors are inadequate to account for the high abundance of vanadium in some fossil fuels and the paucity in others. By examining vanadium deposits in sedimentary rocks with sparse organic matter, constraints are placed on processes controlling vanadium accumulation in organic-rich sediments. Vanadium, as vanadate (V(V)), entered some depositional basins in oxidizing waters from dry, subaerial environments. Upon contact with organic matter in anoxic waters, V(V) is reduced to vanadyl (V(IV)), which can be removed from the water column by adsorption. H2S reduces V(IV) to V(III), which hydrolyzes and precipitates. The lack of V(III) in petroleum suggests that reduction of V(IV) to V(III) is inhibited by organic complexes. In the absence of strong complexing agents, V(III) forms and is incorporated in clay minerals.

Conference Paper↗

Nitrogen biogeochemistry in a boreal headwater stream network in interior Alaska

High latitude, boreal watersheds are nitrogen (N)-limited ecosystems that export large amounts of organic carbon (C). Key controls on C cycling in these environments are the biogeochemical processes affecting the N cycle. A study was conducted in Nome Creek, an upland headwater tributary of the Yukon River, and two first-order tributaries to Nome Creek, to examine the relation between seasonal and transport-associated changes in C and N pools and N-cycling processes across varying hydrologic gradients using laboratory bioassays of water and sediment samples and in-stream tracer tests. DON exceeded dissolved inorganic nitrogen (DIN) in Nome Creek except late in the summer season, with little variation in organic C:N ratios with time or transport distance. DIN was dominant in the 1st order tributaries. Rates of organic N mineralization and denitrification in laboratory incubations were related to sediment organic C content, while nitrification rates differed greatly between two 1st order tributaries with similar drainages. Additions of DIN or urea did not stimulate microbial activity. In-stream tracer tests with nitrate and urea indicated that uptake rates were slow relative to transport rates; simulated rates of uptake in stream storage zones were higher than rates assessed in the laboratory bioassays. In general, N-cycle processes were more active and had a greater overall impact in the 1st order tributaries and were minimized in Nome Creek, the larger, higher velocity, transport-dominated stream. Understanding key controls on N-cycling processes in these watersheds has important implications for DIN speciation and down-stream impacts of potential increased N loads in response to climate warming.

Alaska↗

Simulation of nitrous oxide and nitric oxide emissions from tropical primary forests in the Costa Rican Atlantic Zone

Nitrous oxide (N 2 O) and nitric oxide (NO) are important atmospheric trace gases participating in the regulation of global climate and environment. Predictive models on the emissions of N 2 O and NO emissions from soil into the atmosphere are required. We modified the CENTURY model (Soil Sci. Soc. Am. J., 51 (1987) 1173) to simulate the emissions of N 2 O and NO from tropical primary forests in the Atlantic Zone of Costa Rica at a monthly time step. Combined fluxes of N 2 O and NO were simulated as a function of gross N mineralization and water-filled pore space (WFPS). The coefficients for partitioning N 2 O from NO were derived from field measurements (Global Biogeochem. Cycles, 8 (1994) 399). The modified CENTURY was calibrated against observations of carbon stocks in various pools of forest ecosystems of the region, and measured WFPS and emission rates of N 2 O and NO from soil to the atmosphere. WFPS is an important factor regulating nutrient cycling and emissions of N2O and NO from soils making the accuracy of the WFPS prediction central to the modeling process. To do this, we modified the hydrologic submodel and developed a new method for the prediction of WFPS at the monthly scale from daily rainfall information. The new method is based on: (1) the relationship between monthly rainfall and the number of rainfall events, and (2) the relative cumulative frequency distribution of ranked daily rainfall events. The method is generic and should be applicable to other areas. Simulated monthly average WFPS was 0.68&plusmn;0.02 &mdash; identical with the field measurement average of 0.68&plusmn;0.02 from the annual cycle observed by Keller and Reiners (Global Biogeochem. Cycles, 8 (1994) 399). Simulated fluxes of N 2 O and NO were 52.0&plusmn;9.4 mg-N m &minus;2 month &minus;1 and 6.5&plusmn;0.7 mg-N m &minus;2 month &minus;1 , respectively, compared with measured averages of 48.2&plusmn;11.0 mg-N m &minus;2 month &minus;1 and 7.1&plusmn;1.1 mg-N m &minus;2 month &minus;1 . The simulated N 2 O/NO ratio was 11.2&plusmn;1.9 compared with the measured value of 10.9&plusmn;4.7. WFPS is the dominant determinant of the fraction of gross N mineralization that is emitted from the soil as N 2 O and NO. If WFPS were not limiting during part of the year, this fraction would be 4.2%. With some periods of lower WFPS, the realized fraction is 2.2%. Because of the strong relationships between N 2 O and NO emission rates and rainfall and its derivative, WFPS, these moisture variables can be used to scale up nitrogen trace gas fluxes from sites to larger spatial scales.

Environmental Modelling and Software↗

The Gas Hills uranium district and some probable controls for ore deposition

Uranium deposits occur in the upper coarse-grained facies of the Wind River formation of Eocene age in the Gas Hills district of the southern part of the Wind River Basin. Some of the principal deposits lie below the water table in the unoxidized zone and consist of uraninite and coffinite occurring as interstitial fillings in irregular blanket-like bodies. In the near-surface deposits that lie above the water table, the common yellow uranium minerals consist of uranium phosphates, silicates, and hydrous oxides. The black unoxidized uraninite -coffinite ores show enrichment of molybdenum, arsenic, and selenium when compared to the barren sandstone. Probable geologic controls for ore deposits include: 1) permeable sediments that allowed passage of ore-bearing solutions; 2) numerous faults that acted as impermeable barriers impounding the ore -bearing solutions; 3) locally abundant pyrite, carbonaceous material, and natuial gas containing hydrogen sulfide that might provide a favorable environment for precipitation of uranium. Field and laboratory evidence indicate that the uranium deposits in the Gas Hills district are very young and related to the post-Miocene to Pleistocene regional tilting to the south associated with the collapse of the Granite Mountains fault block. This may have stopped or reversed ground water movement from a northward (basinward) direction and alkaline ground water rich in carbonate could have carried the uranium into the favorable environment that induced precipitation.

Trace Elements Memorandum↗

Occurrence and transport of total mercury and methyl mercury in the Sacramento River Basin, California

Mercury poses a water-quality problem for California's Sacramento River, a large river with a mean annual discharge of over 650 m3/s. This river discharges into the San Francisco Bay, and numerous fish species of the bay and river contain mercury levels high enough to affect human health if consumed. Two possible sources of mercury are the mercury mines in the Coast Ranges and the gold mines in the Sierra Nevada. Mercury was once mined in the Coast Ranges, west of the Sacramento River, and used to process gold in the Sierra Nevada, east of the river. The mineralogy of the Coast Ranges mercury deposits is mainly cinnabar (HgS), but elemental mercury was used to process gold in the Sierra Nevada. Residual mercury from mineral processing in the Sierra Nevada is mainly in elemental form or in association with oxide particles or organic matter and is biologically available. Recent bed-sediment sampling, at sites below large reservoirs, showed elevated levels of total mercury (median concentration 0.28 ??g/g) in every large river (the Feather, Yuba, Bear, and American rivers) draining the Sierra Nevada gold region. Monthly sampling for mercury in unfiltered water shows relatively low concentrations during the nonrainy season in samples collected throughout the Sacramento River Basin, but significantly higher concentrations following storm-water runoff. Measured concentrations, following storm-water runoff, frequently exceeded the state of California standards for the protection of aquatic life. Results from the first year of a 2-year program of sampling for methyl mercury in unfiltered water showed similar median concentrations (0.1 ng/l) at all sampling locations, but with apparent high seasonal concentrations measured during autumn and winter. Methyl mercury concentrations were not significantly higher in rice field runoff water, even though rice production involves the creation of seasonal wetlands: higher rates of methylation are known to occur in stagnant wetland environments that have high dissolved carbon.Mercury poses a water-quality problem for California's Sacramento River, a large river with a mean annual discharge of over 650 m3/s. This river discharges into the San Francisco Bay, and numerous fish species of the bay and river contain mercury levels high enough to affect human health if consumed. Two possible sources of mercury are the mercury mines in the Coast Ranges and the gold mines in the Sierra Nevada. Mercury was once mined in the Coast Ranges, west of the Sacramento River, and used to process gold in the Sierra Nevada east of the river. The mineralogy of the Coast Ranges mercury deposits is mainly cinnabar (HgS), but elemental mercury was used to process gold in the Sierra Nevada. Residual mercury from mineral processing in the Sierra Nevada is mainly in elemental form or in association with oxide particles or organic matter and is biologically available. Recent bed-sediment sampling, at sites below large reservoirs, showed elevated levels of total mercury (median concentration 0.28 ??g/g) in every large river (the Feather, Yuba, Bear, and American rivers) draining the Sierra Nevada gold region. Monthly sampling for mercury in unfiltered water shows relatively low concentrations during the nonrainy season in samples collected throughout the Sacramento River Basin, but significantly higher concentrations following storm-water runoff. Measured concentrations, following storm-water runoff, frequently exceeded the state of California standards for the protection of aquatic life. Results from the first year of a 2-year program of sampling for methyl mercury in unfiltered water showed similar median concentrations (0.1 ng/l) at all sampling locations, but with apparent high seasonal concentrations measured during autumn and winter. Methyl mercury concentrations were not significantly higher in rice field runoff water, even though rice production involves the creation of seasonal wetlands: higher rates of methylation a

Journal of Geochemical Exploration↗

Influence of Pb on microbial activity in Pb-contaminated soils

Investigations of the influence of Pb on soil microbial communities have focused on Pb concentrations of 1 g kg-’ or less (Barkay et al., 1985; Capone et al., 1983; Chang and Broadbent, 1981; Doelman and Haanstra, 1979; Trevors et al., 1985). However, a number of environments exist in which Pb concentrations exceed 1 g kg-’ dry soil (Davenport and Peryea, 1991; Davis et al., 1992; Bisessar, 1982). Bisessar (1982) reported an inverse correlation between Pb concentration and the bacterial population size in soil near a secondary lead smelter. However, similar trends in the concentrations of Pb, As, Cd, and Cu at the site make it difficult to attribute the reductions in population size to Pb alone. Although the effects on microbial carbon mineralization of Pb concentrations as high as 20,000 g kg-’ dry soil were investigated by Debosz et a/. (1985), differences in pH between Pb treatments and the lack of controls for abiotic CO, evolution make the results of the study equivocal. Our purpose was to examine the effects of g kg-’ Pb concentrations on the growth and productivity of soil microbial communities.

Soil Biology and Biochemistry↗

Sedimentary and gravity-slide emplacement of serpentinite

Large deposits of serpentinite in alpine-type orogenic areas have been formed by sedimentary processes ranging from the detrital accumulation of bedded serpentinite sandstone and shale to the emplacement of chaotic breccias (olistostromes) and gigantic slide blocks. Known occurrences of sedimentary serpentinite are listed, and eight deposits from the circum-Pacific, Caribbean, and Mediterranean areas are described in detail. Sedimentary serpentinites range in age from early Paleozoic to Quaternary, although most are Cretaceous or Tertiary. Most were deposited in eugeosynclinal environments, early in the geosynclinal cycle. Individual deposits range in thickness from a few centimeters to nearly 3 km, and several extend laterally for tens of kilometers. Graded bedding is common, and many deposits contain marine fossils. Serpentinite is the dominant rock constituent, and clasts foreign to the alpine ultramafic assemblage are rare. Chemical analyses often detrital serpentinites show that these rocks contain slightly more silica and alumina than do nondetrital serpentinites, due to contamination by aluminosilicate minerals and quartz during deposition. This and nine other criteria are potentially useful in the recognition of sedimentary serpentinites. Several features suggest that most sedimentary serpentinites were deposited very rapidly by submarine landslides, mudflows, or turbidity currents. The sources of this serpentinite debris are postulated to be upward-migrating serpentinite protrusions which penetrate the seafloor or Earth's surface upslope from eventual depositional sites. Sedimentary serpentinites are much more abundant in alpine-type orogenic areas than is commonly thought, and many ultramafic masses presently regarded as igneous intrusions or tectonic protrusions may in fact be coeval with, instead of younger than, their enclosing sedimentary or metasedimentary rocks. In eugeosynclinal sequences such as the Franciscan Formation, some elongate bodies now regarded as serpentinite sills may be beds of ultramafic detritus whose sedimentary features have been masked by post-depositional shearing; isolated masses may be exotic slide blocks. A sedimentary origin can explain some of the most persistent and perplexing characteristics of many alpine serpentinites: their conformity with enclosing sedimentary rocks, their grossly planar shapes, and the absence of metamorphism along their contacts.

California↗

Big Soda Lake (Nevada). 2. Pelagic sulfate reduction

The epilimnion of hypersaline, alkaline, meromictic Big Soda Lake contains an average 58 mmol sulfate liter &minus;1 and 0.4 &micro; mol dissolved iron liter &minus;1 . The monimolimnion, which is permanently anoxic, has a sulfide concentration ranging seasonally from 4 to 7 mmol liter &minus;1 . Depth profiles of sulfate reduction in the monimolimnion, assayed with a 35 S tracer technique and in situ incubations, demonstrated that sulfate reduction occurs within the water column of this extreme environment. The average rate of reduction in the monimolimnion was 3 &micro; mol sulfate liter &minus;1 d &minus;1 in May compared to 0.9 in October. These values are comparable to rates of sulfate reduction reported for anoxic waters of more moderate environments. Sulfate reduction also occurred in the anoxic zone of the mixolimnion, though at significantly lower rates (0.025&ndash;0.090 &micro; mol liter &minus;1 d &minus;1 at 25 m). Additions of FeS (1.0 mmol liter &minus;1 ) doubled the endogenous rate of sulfate reduction in the monimolimnion, while MnS and kaolinite had no effect. These results suggest that sulfate reduction in Big Soda Lake is iron limited and controlled by seasonal variables other than temperature. Estimates of the organic carbon mineralized by sulfate reduction exceed measured fluxes of particulate organic carbon sinking from the mixolimnion. Thus, additional sources of electron donors (other than those derived from the sinking of pelagic autotrophs) may also fuel monimolimnetic sulfate reduction in the lake.

Nevada↗

From exploration to production: Understanding the development dynamics of lithium mining projects

Recently, there has been considerable recent controversy whether current and new lithium mines will be able to supply the rapidly growing needs of the electromobility transition. Mineral exploration projects are typically active for many years, and only some become operational mines. From exploration to production, the projects go through several stages of characterisation and evaluation. At each stage, decisions are made by companies and stakeholders to advance, continue or stop the project. This is a complex process, and even projects with very similar geological and technical characteristics may take very different trajectories, depending on external factors such as global market conditions and local regulatory environments. The present study investigates the dynamics of this process for lithium exploration projects. A global database of 397 lithium projects was compiled, covering their progression through major development stages between 2004 and 2022. Ordinal logistic regression was used for the statistical analysis of this data. Different explanatory variables were tested, including economic, geological, technical, and geographic factors, to identify the best predictors for project progress at each development stage. The results suggest an essential role for lithium carbonate prices, and a variable role for other factors at each stage. Critically, the already elapsed lead time and project economics, which are traditionally considered important for the prediction of the start-up of individual mines, do not appear to be relevant in all cases. The results provide important insights into the dynamics of lithium supply and may eventually allow more realistic forecasts to be made for future lithium market dynamics.

Resources Policy↗

Geologic characteristics of sediment- and volcanic-hosted disseminated gold deposits - Search for an occurrence model

The current expansion of resource information, particularly on "disseminated" gold, and the improved technologies now available for resource investigations should place us in an enhanced position for developing a better predictive methodology for meeting one of the important responsibilities of the U.S. Geological Survey-to examine and assess the mineral resources of the geologic terranes composing the public (and privately owned) lands of the United States. The first step is systematic organization of these data. Geologic-occurrence models are an effective systematic method by which to organize large amounts of resource information into a logical sequence facilitating its use more effectively in meeting several industry and Survey objectives, which include the exploration for resources and the assessment of resource potential for land-use decisions. Such models also provide a scientific basis for metallogenesis research, which considers the observable features or attributes of ore occurrence and their "fit" into the Earth's resource puzzle. The use of models in making resource assessments/appraisals was addressed by Shawe (1981), who reported the results of a workshop on methods for resource appraisal of Wilderness and Conterminous United States Mineral Appraisal Program (CUSMAP; 1:250,000-scale quadrangles) areas. The Survey's main objective in the 1982 workshop was to evaluate the status of knowledge about disseminated or very fine grained gold deposits and, if possible, to develop an occurrence model(s). This report on the workshop proceedings has three main objectives: (1) Education through the publication of a summary review and presentation of new thinking and observations about the scientific bases for those geologic processes and environments that foster disseminated gold-ore formation; (2) systematic organization of available geologic, geochemical, and geophysical information for a range of typical disseminated gold deposits (including recognition of gaps in those data); and (3) assessment of current understanding (as presented in objective 2) toward formulating an empirical ore-occurrence model for this type of deposit. As such, this volume represents a preliminary first step at classification and provides a source of pertinent background information. Readers of this volume will soon discover, however, that full agreement has not yet been achieved in the interpretation of some of the geologic evidence. The resulting variations in tentative occurrence models for these controversial deposits ultimately will be resolved by filling the gaps in information that have already been identified. Thus, this volume does not report a U.S. Geological Survey consensus; the conclusions expressed in each chapter represent the particular interpretations of the various workshop participants.

Arizona, California, Idaho, Nevada, Utah↗

Short-term sediment dispersal on a large retreating coastal river delta via 234Th and 7Be sediment geochronology: The Mississippi River Delta Front

Many Mississippi River Delta studies have shown recent declines in fluvial sediment load from the river and associated land loss. In contrast, recent sedimentary processes on the subaqueous delta are less documented. To help address this knowledge gap, multicores were collected offshore from the three main river outlets at water depths of 25–280 m in June 2017 just after the peak river discharge period, with locations selected based on 2017 U.S. Geological Survey seabed mapping. The coring locations included the undisturbed upper foreset, mudflow lobes, gullies, and the undisturbed prodelta. Nine multicores were analyzed for Beryllium-7 activity, and four cores were analyzed for excess Thorium-234 activity via gamma spectrometry, granulometry and X-radiography. Our results indicate a general trend of declining 7 Be and 234 Th activities and inventories with increasing distance from sources and in deeper water. The core X-radiographs are graded from the predominantly physically stratified nearshore to the more bioturbated offshore, consistent with the sedimentation patterns. Sediment focusing assessed via the 7 Be and 234 Th sediment inventories shows preferential sedimentation in gully and lobe environments, whereas the upper foreset and prodelta focusing factors are relatively depleted. Overall, short-term sediment deposition from the main fluvial source remains active offshore from all three major river outlets, despite the overall declining river load.

Louisiana↗