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The Breccia Museo formation, Campi Flegrei, southern Italy: Geochronology, chemostratigraphy and relationship with the Campanian Ignimbrite eruption

The Breccia Museo is one of the most debated volcanic formations of the Campi Flegrei volcanic district. The deposit, made up of six distinctive stratigraphic units, has been interpreted by some as the proximal facies of the major caldera-forming Campanian Ignimbrite eruption, and by others as the product of several, more recent, independent and localized events. New geochemical and chemostratigraphical data and Ar–Ar age determinations for several units of the Breccia Museo deposits (~39 ka), correlate well with the Campanian Ignimbrite-forming eruption. The chemical zoning of the Breccia Museo deposits is interpreted here to be a consequence of a three-stage event that tapped a vertically zoned trachytic magma chamber.

Bulletin of Volcanology↗

Geochemistry and the understanding of ground-water systems

Geochemistry has contributed significantly to the understanding of ground-water systems over the last 50 years. Historic advances include development of the hydrochemical facies concept, application of equilibrium theory, investigation of redox processes, and radiocarbon dating. Other hydrochemical concepts, tools, and techniques have helped elucidate mechanisms of flow and transport in ground-water systems, and have helped unlock an archive of paleoenvironmental information. Hydrochemical and isotopic information can be used to interpret the origin and mode of ground-water recharge, refine estimates of time scales of recharge and ground-water flow, decipher reactive processes, provide paleohydrological information, and calibrate ground-water flow models. Progress needs to be made in obtaining representative samples. Improvements are needed in the interpretation of the information obtained, and in the construction and interpretation of numerical models utilizing hydrochemical data. The best approach will ensure an optimized iterative process between field data collection and analysis, interpretation, and the application of forward, inverse, and statistical modeling tools. Advances are anticipated from microbiological investigations, the characterization of natural organics, isotopic fingerprinting, applications of dissolved gas measurements, and the fields of reaction kinetics and coupled processes. A thermodynamic perspective is offered that could facilitate the comparison and understanding of the multiple physical, chemical, and biological processes affecting ground-water systems.

Hydrogeology Journal↗

The application of satellite differential SAR interferometry-derived ground displacements in hydrogeology

The application of satellite differential synthetic aperture radar (SAR) interferometry, principally coherent (InSAR) and to a lesser extent, persistent-scatterer (PSI) techniques to hydrogeologic studies has improved capabilities to map, monitor, analyze, and simulate groundwater flow, aquifer-system compaction and land subsidence. A number of investigations over the previous decade show how the spatially detailed images of ground displacements measured with InSAR have advanced hydrogeologic understanding, especially when a time series of images is used in conjunction with histories of changes in water levels and management practices. Important advances include: (1) identifying structural or lithostratigraphic boundaries (e.g. faults or transitional facies) of groundwater flow and deformation; (2) defining the material and hydraulic heterogeneity of deforming aquifer-systems; (3) estimating system properties (e.g. storage coefficients and hydraulic conductivities); and (4) constraining numerical models of groundwater flow, aquifer-system compaction, and land subsidence. As a component of an integrated approach to hydrogeologic monitoring and characterization of unconsolidated alluvial groundwater basins differential SAR interferometry contributes unique information that can facilitate improved management of groundwater resources. Future satellite SAR missions specifically designed for differential interferometry will enhance these contributions. ?? Springer-Verlag 2006.

Hydrogeology Journal↗

Groundwater salinity mapping using geophysical log analysis within the Fruitvale and Rosedale Ranch oil fields, Kern County, California, USA

A method is presented for deriving a volume model of groundwater total dissolved solids (TDS) from borehole geophysical and aqueous geochemical measurements. While previous TDS mapping techniques have proved useful in the hydrogeologic setting in which they were developed, they may yield poor results in settings with lithological heterogeneity, complex water chemistry, or limited data. Problems arise because of assumed values for empirical constants in Archie’s Equation, unrealistic porosity and temperature gradients, or bicarbonate-rich groundwater. These issues become critical in complex geologic settings such as the San Joaquin Valley of California, USA. To address this, a method to map TDS in three dimensions is applied to the Fruitvale and Rosedale Ranch oil fields near Bakersfield, California. Borehole resistivity, porosity, and temperature data are used to derive TDS using Archie’s Equation, and are then kriged to interpolate TDS. Archie’s a and m (tortuosity factor and cementation exponent, respectively) are found by comparing model predictions, after kriging, to TDS measurements, and minimizing the differences via mathematical optimization. Contributions of abundant bicarbonate ions to TDS were corrected using an empirical model. This work was motivated by federal and state law requirements to monitor and protect underground sources of drinking water. Modeling shows the legally significant boundary of 10,000 ppm TDS is at ~1,067 m below sea level in Rosedale Ranch, and deepens into Fruitvale to ~1,341 m. Mapping groundwater TDS at this resolution reveals that TDS is primarily controlled by depth, recharge, stratigraphy, and in some places, by faulting and facies changes.

California↗

Limnogeology in Brazil's "forgotten wilderness": A synthesis from the large floodplain lakes of the Pantanal

Sediment records from floodplain lakes have a large and commonly untapped potential for inferring wetland response to global change. The Brazilian Pantanal is a vast, seasonally inundated savanna floodplain system controlled by the flood pulse of the Upper Paraguay River. Little is known, however, about how floodplain lakes within the Pantanal act as sedimentary basins, or what influence hydroclimatic variables exert on limnogeological processes. This knowledge gap was addressed through an actualistic analysis of three large, shallow (<5 m) floodplain lakes in the western Pantanal: Lagoa Gaíva, Lagoa Mandioré and Baia Vermelha. The lakes are dilute (CO3 2- > Si 4+ > Ca 2+ ), mildly alkaline, freshwater systems, the chemistries and morphometrics of which evolve with seasonal flooding. Lake sills are bathymetric shoals marked by siliciclastic fans and marsh vegetation. Flows at the sills likely undergo seasonal reversals with the changing stage of the Upper Paraguay River. Deposition in deeper waters, typically encountered in proximity to margin-coincident topography, is dominated by reduced silty-clays with abundant siliceous microfossils and organic matter. Stable isotopes of carbon and nitrogen, plus hydrogen index measured on bulk organic matter, suggest that contributions from algae (including cyanobacteria) and other C3-vegetation dominate in these environments. The presence of lotic sponge spicules, together with patterns of terrigenous sand deposition and geochemical indicators of productivity, points to the importance of the flood pulse for sediment and nutrient delivery to the lakes. Flood-pulse plumes, waves and bioturbation likewise affect the continuity of sedimentation. Short-lived radioisotopes indicate rates of 0.11-0.24 cm year -1 at sites of uninterrupted deposition. A conceptual facies model, developed from insights gained from modern seasonal processes, can be used to predict limnogeological change when the lakes become isolated on the floodplain or during intervals associated with a strengthened flood pulse. Amplification of the seasonal cycle over longer time scales suggests carbonate, sandy lowstand fan and terrestrial organic matter deposition during arid periods, whereas deposition of lotic sponges, mixed aquatic organic matter, and highstand deltas characterizes wet intervals. The results hold substantial value for interpreting paleolimnological records from floodplain lakes linked to large tropical rivers with annual flooding cycles.

Bahia Vermelha, Brazilian Pantanal, Lagoa Gaiva, L↗

Programed oil generation of the Zubair Formation, Southern Iraq oil fields: Results from Petromod software modeling and geochemical analysis

1D petroleum system modeling was performed on wells in each of four oil fields in South Iraq, Zubair (well Zb-47), Nahr Umr (well NR-9), West Qurna (well WQ-15 and 23), and Majnoon (well Mj-8). In each of these fields, deposition of the Zubair Formation was followed by continuous burial, reaching maximum temperatures of 100°C (equivalent to 0.70%Ro) at depths of 3,344–3,750 m of well Zb-47 and 3,081.5–3,420 m of well WQ-15, 120°C (equivalent to 0.78%Ro) at depths of 3,353–3,645 m of well NR-9, and 3,391–3,691.5 m of well Mj-8. Generation of petroleum in the Zubair Formation began in the late Tertiary, 10 million years ago. At present day, modeled transformation ratios (TR) indicate that 65% TR of its generation potential has been reached in well Zb-47, 75% TR in well NR-9 and 55-85% TR in West Qurna oil field (wells WQ-15 and WQ-23) and up to 95% TR in well Mj-8, In contrast, younger source rocks are immature to early mature (<20% TR), whereas older source rocks are mature to overmature (100% TR). Comparison of these basin modeling results, in Basrah region, are performed with Kifle oil field in Hilla region of western Euphrates River whereas the Zubair Formation is immature within temperature range of 65–70°C (0.50%Ro equivalent) with up to 12% (TR = 12%) hydrocarbon generation efficiency and hence poor generation could be assessed in this last location. The Zubair Formation was deposited in a deltaic environment and consists of interbedded shales and porous and permeable sandstones. In Basrah region, the shales have total organic carbon of 0.5–7.0 wt%, Tmax 430–470°C and hydrogen indices of up to 466 with S2 = 0.4–9.4 of kerogen type II & III and petroleum potential of 0.4–9.98 of good hydrocarbon generation, which is consistent with 55–95% hydrocarbon efficiency. These generated hydrocarbons had charged (in part) the Cretaceous and Tertiary reservoirs, especially the Zubair Formation itself, in the traps formed by Alpine collision that closed the Tethys Ocean between Arabian and Euracian Plates and developed folds in Mesopotamian Basin 15–10 million years ago. These traps are mainly stratigraphic facies of sandstones with the shale that formed during the deposition of the Zubair Formation in transgression and regression phases within the main structural folds of the Zubair, Nahr Umr, West Qurna and Majnoon Oil fields. Oil biomarkers of the Zubair Formation Reservoirs are showing source affinity with mixed oil from the Upper Jurassic and Lower Cretaceous strata, including Zubair Formation organic matters, based on presentation of GC and GC-MS results on diagrams of global petroleum systems.

Arabian Journal of Geosciences↗

Geologic controls on groundwater salinity reversal in North Coles Levee Oil Field, southern San Joaquin Valley, California, USA

This paper documents a reversal in the groundwater salinity depth gradient in the North Coles Levee Oil Field in the San Joaquin Valley, California. Salinity, measured in mg/L, was mapped with water quality data from groundwater and oil and gas wells and salinity estimated from oil and gas well borehole geophysical logs using Archie's equation. The resulting three-dimensional salinity volume shows groundwater salinity increasing with depth through the Tulare and San Joaquin Formations to about 50,000 mg/L at 1100 m depth, then decreasing to 10,000–31,000 mg/L in the Etchegoin Formation at 1400 m depth. The high salinity zone occurs near the base of the San Joaquin Formation in sand lenses in shales that have been interpreted as representing a mudflat environment. The groundwater and produced water geochemistry show formation waters lie on the seawater dilution line, indicating the salinity structure is largely the result of dilution or evaporation of seawater and not due to water–rock interactions. Instead, changing depositional environments linked to decreasing sea level may be responsible for variably saline water at or near the time of deposition, leading to a salinity reversal preserved in connate waters. The steepness of the salinity reversal varies laterally, possibly due to post-depositional freshwater recharge allowed by thick sands, alternatively, by a change in connate water composition due to a lateral facies change present at the time of deposition. These results illustrate geologic and paleogeographic processes that drive the vertical salinity structure of groundwater in shallow alluvial basins.

California↗

Geochemistry and hydrodynamics of the Paradox Basin region, Utah, Colorado and New Mexico

The Paradox Basin region is approximately bounded by the south flank of the Uinta Basin to the north, the Uncompahgre uplift and San Juan Mountains to the east, the Four Corners structural platform to the southeast, the north rim of the Black Mesa Basin and the Grand Canyon to the south and southwest, and the Wasatch Plateau and Hurricane fault system to the west. Some of these geologic features are areas of ground-water recharge or discharge whereas others such as the Four Corners platform do not directly influence fluid movement. The aquifer systems studied were: (1) Mississippian rocks; (2) Pinkerton Trail Limestone of Wengerd and Strickland, 1954; (3) Paradox Member of the Hermosa Formation; (4) Honaker Trail Formation of Wengerd and Matheny, 1958; (5) Permian rocks. Recharge in the Paradox Basin occurs on the west flank of the San Juan Mountains and along the west side of the Uncompahgre uplift. The direction of ground-water movement in each analyzed unit is principally southwest-ward toward the topographically low outcrop areas along the Colorado River in Arizona. However, at any point in the basin, flow may be in some other direction owing to the influence of intrabasin recharge areas or local obstructions to flow, such as faults or dikes. A series of potentiometric surface maps was prepared for the five systems studied. Material used in construction of the maps included outcrop altitudes of springs and streams, drill-stem tests, water-well records, and an electric analog model of the entire basin. Many structurally and topographically high areas within the basin are above the regional potentiometric surface; recharge in these areas will drain rapidly off the high areas and adjust to the regional water level. With a few exceptions, most wells in formations above the Pennsylvanian contain fresh (< 1,000 mg/l T.D.S. 2 ) to moderately saline (< 10,000 mg/l T.D.S.) water. In only a few cases are true brines (> 35,000 mg/l T.D.S.) reported. Most water samples from strata below the Permian are brines of the sodium chloride type but with large amounts of calcium sulfate or calcium chloride type water commonly occurring. Because evaporite facies occur in the Paradox Member, this unit has brines with as much as 400,000 mg/l dissolved solids content. Previous analysis of the San Juan Basin has indicated the presence of an osmotic membrane system. The highly permeable Jurassic formations were postulated to be the outflow side of the membrane. It is also possible that the Upper Paleozoic units with known brines and with an otherwise inexplicably high potentiometric surface in the Four Corners area of New Mexico could be the outflow receptors of the San Juan membrane system.

Colorado, New Mexico, Utah↗

Mineral-water reactions in metamorphism and volcanism

Low-temperature (120??C and less) metamorphism of graywacke, granite and andesite yields zeolites and precursor gels by reaction with fresh water but low-greenschist facies by reaction with salt (sea)water. ?? 1985.

Chemical Geology↗

Chemical fluxes and origin of a manganese carbonate-oxide-silicate deposit in bedded chert

Lens-like rhodochrosite-rich bodies within interbedded chert and shale are associated with basalt and/or graywacke in ophiolitic and orogenic zones. The Buckeye manganese mine in the Franciscan Complex of the California Coast Ranges is associated with metagraywacke. Despite blueschist-facies metamorphism, this deposit preserves the compositions and some textural features of its sedimentary protoliths. For this reason, it is a suitable deposit with which to compare more intensely altered deposits, or deposits originating in different paleoenvironments. Six Mn-rich and three Mn-poor minerals form monomineralic layers and mixtures: rhodochrosite, gageite, Mn-oxides (hausmannite, braunite), divalent Mn-silicates (caryopilite, taneyamalite), chlorite, quartz (metachert) and aegirine-augite. The Mn-rich protoliths have high Mn/Fe combined with relatively low concentrations of Ca, Al, Ti, Co, Ni, Cu, Th and REE. REE patterns of various protoliths are distinct. Rhodochrosite and gageite layers are depleted (seawater ?? 5 ?? 104) and flat, whereas patterns of metachert and the Mn-silicate-rich layers mimic the patterns of metashale and metagraywacke (seawater ?? 106). Hausmannite layers have flat patterns (seawater ?? 7 ?? 104) whereas braunite-rich layers are more enriched (seawater ?? 2 ?? 105) and show a distinct positive Ce anomaly. Factor analysis reveals components and fluxes attributed to sub-seafloor fluids (Ni, As, Zn, Sb, W, Mn), seawater (Mg, Au, V, Mo), detritus and veins (Ca, Ba, Sr). Silica is negatively correlated with the sub-seafloor factor. The observed variances indicate that water from the sediment column mixed with seawater, that deposition occurred near the sediment-seawater interface before mixtures of subsurface fluid and seawater homogenized, and that the system was not entirely closed during metamorphism. The variations in REE enrichment can be related to kinetics of deposition: rhodochrosite and gageite were precipitated most rapidly, and therefore were the protoliths that most effectively diluted the REE-rich background resulting from fine clastic material (derived from distal turbidites). The variation of the Ce anomaly and U/Th among diverse lithologies and the differences in Mn oxidation states are consistent with progressive dilution of reduced subsurface fluids with oxidized seawater. By this scheme, rhodochrosite, gageite and hausmannite were deposited from the most reduced fluids, braunite from intermediate mixtures, and Mn-silicates from the sub-seafloor fluids most diluted with fresh seawater. Comparison of the Buckeye with other lens-like and sheet-like deposits having high Mn/Fe and containing Mn3+ and/or Mn2+ suggests that each had three essential fluxes: a sub-seafloor source of Mn, a local source of very soluble silica and a source of relatively fresh, oxygenated water. Additional fluxes, such as clastics, appear to be more characteristic of the paleoenvironment than the three essential fluxes. ?? 1992.

Chemical Geology↗

13C 12C exchange between calcite and graphite: A possible thermometer in Grenville marbles

The fractionation of 13 C between calcite and graphite, Δ(Cc-Gr). is consistently small (2.6–4.8 permil) in 34 assemblages from upper amphibolite- and granulite-facies marbles of the Grenville Province. In 25 samples from the Adirondack Mountains, New York, it decreases regularly with increasing metamorphic temperature. The fractionations are independent of absolute δ 13 C values of calcite (−2.9 to +5.0). For T = 600–800° C , the Adirondack data are described by Δ ( Cc - Gr ) = −0.00748 T (° C ) + 8.68. This good correlation between Δ and T suggests that carbon isotope equilibrium was attained in these high-grade marbles and that the theoretical calculations of this fractionation by Bottinga are approximately 2 permil too large in this temperature range. Because of the relatively high temperature sensitivity suggested by these results and by Bottinga's calculations, and the pressure independence of isotope fractionation, Δ(Cc-Gr) may provide a very good thermometer for high-grade marbles. Comparison of this field calibration for Δ(Cc-Gr) vs temperature with results from other terranes supports the utility of Δ(Cc-Gr) for geothermometry and suggests that graphite is much more sluggish to exchange than calcite, that exchange between calcite and graphite occurs at temperatures as low as 300°C, and that equilibrium may normally be attained only when peak metamorphic temperatures are greater than 500–600°C. Because 13 C exchange is an unavoidable metamorphic process at temperatures above 300°C, high values of δ 13 C(Gr) in moderate- to high-grade carbonate-bearing rocks do not provide a sufficient criterion to infer an abiogenic origin for the graphite.

Geochimica et Cosmochimica Acta↗

Extraction of whole versus ground source rocks: Fundamental petroleum geochemical implications including oil-source rock correlation

In petroleum geochemistry, extractable hydrocarbons (HCs) in source rocks have typically been studied by grinding the rock to a fine powder (≤100 mesh) and then extracting the HCs from the rock with a solvent. This procedure carries the implicit assumption that the HCs are homogeneously distributed throughout the rock. However, sequential Soxhlet extractions of whole (unpowdered) source rocks have shown that progressive extracts from the same rock can be quite different and may not even correlate with each other. A crude oil-like material clearly has been fractionated from indigenous bitumen in these rocks, has moved to cracks and parting laminae in the rocks, is ready for expulsion from the rocks, and is thus most accessible to the first extracting solvents. This process, which we believe is largely due to HC gases and carbon dioxide generated over all maturation ranks in source rocks, carries petroleum geochemical implications of a fundamental nature for oil-source rock correlations and gives insight into primary migration mechanisms, origin of oil deposits, and use of maturity and organic-facies indices.

Geochimica et Cosmochimica Acta↗

Clastic metasediments of the Early Proterozoic Broken Hill Group, New South Wales, Australia: Geochemistry, provenance, and metallogenic significance

Whole-rock analyses of samples of pelite, psammite, and psammopelite from the Early Proterozoic Broken Hill Group (Willyama Supergroup) in the Broken Hill Block, New South Wales, Australia, reveal distinctive geochemical signatures. Major-element data show high Al 2 O 3 and K 2 O, low MgO and Na 2 O, and relatively high Fe 2 O 3 T MgO "> Fe2O3TMgO ratios, compared to average Early Proterozoic clastic metasediments. High field strength elements (HFSE) are especially abundant, including Nb (most 15–27 ppm), Ta (most 1.0–2.2 ppm), Th (17–36 ppm), Hf (4–15 ppm), and Zr (most 170–400 ppm); Y (33–74 ppm) is also high. Concentrations of ferromagnesian elements are generally low ( Sc = < 20 ppm, Ni = ≤ 62 ppm, Co = <26 ppm; Cr = most < 100 ppm). Data for rare earth elements (REEs) show high abundances of light REEs ( La CN = 116–250 × chondrite; La CN = 437 in one sample), high La CN Yb CN "> LaCNYbCN ratios (5.6–13.9), and large negative Eu anomalies ( Eu Eu &#x2217; = 0.32&#x2013;0.57 "> EuEu∗= 0.32–0.57 ). The geochemical data indicate derivation of the metasedimentary rocks of the Broken Hill Group by the erosion mainly of felsic igneous (or meta-igneous) rocks. High concentrations of HFSE, Y, and REEs in the metasediments suggest a provenance dominanted by anorogenic granites and(or) rhyolites, including those with A-type chemistry. Likely sources of the metasediments were the rhyolitic to rhyodacitic protoliths of local quartz + feldspar ± biotite ± garnet gneisses (e.g., Potosi-type gneiss) that occur within the lower part of the Willyama Supergroup, or chemically similar basement rocks in the region; alternative sources may have included Early Proterozoic anorogenic granites and(or) rhyolites in the Mount Isa and(or) Pine Creek Blocks of northern Australia, or in the Gawler craton of South Australia. Metallogenic considerations suggest that the metasediments of the Broken Hill Block formed enriched source rocks during the generation of pegmatite-hosted deposits and concentrations of La, Ce, Nb, Ta, Th, and Sn in the region. Li, Be, B, W, and U in pegmatite minerals of the district may have been acquired during granulite-facies metamorphism of the local metasediments.

New South Wales↗

Modeling and analysis of direct-current electrical resistivity in the Durham Triassic basin, North Carolina

Sixty-two Schlumberger electrical soundings were made in the Durham Triassic basin in an effort to determine basin structural geometry, depth of the sedimentary layers, and spatial distribution of individual rock facies. A digital computer program was used to invert the sounding curves of apparent resistivity versus distance to apparent resistivity versus depth. The apparent-resistivity-versus-depth data from the computer-modeling program were used to construct a geoelectric model of the basin that is believed to accurately represent the subsurface geology of the basin. The largest depth to basement in the basin along a resistivity profile (geoelectric section) was determined to be 1,800 m. A resistivity decrease was observed on certain soundings from depths of 100 to 1,000 m; below a 1,000-m depth, apparent resistivity increased to the bottom of the basin. Resistivity values for basement rocks were greater than 1,000 ohm-m and less than 350 ohm-m for the sedimentary layers in the basin. The data suggest that the basin contains a system of step faults near its eastern boundary.

North Carolina↗

Seismic stratigraphy of the Mississippi-Alabama shelf and upper continental slope

The Mississippi-Alabama shelf and upper continental slope contain relatively thin Upper Pleistocene and Holocene deposits. Five stages of shelf evolution can be identified from the early Wisconsinan to present. The stages were controlled by glacioeustatic or relative sea-level changes and are defined by the stratigraphic position of depositional and erosional episodes. The stratigraphy was identified on seismic profiles by means of geomorphic pattern, high-angle clinoform progradational deposits, buried stream entrenchments, planar conformities, and erosional unconformities. The oldest stage (stage 1) of evolution occurred during the early Wisconsinan lowstand; the subaerially exposed shelf was eroded to a smooth seaward-sloping surface. This paleosurface is overlain by a thin (< 10 m) drape of transgressive deposits (stage 2). Stage 3 occurred in three phases as the late Wisconsinan sea retreated: (1) fluvial channel systems eroded across the shelf, (2) deposited a thick (90 m) shelf-margin delta, and (3) contemporaneously deposited sediments on the upper slope. Stage 4 included the rapid Holocene sea-level rise that deposited a relatively thin transgressive facies over parts of the shelf. The last major depositional episode (stage 5) was the progradation of the St. Bernard delta over the northwestern and central parts of the area. A depositional hiatus has occurred since the St. Bernard progradation. These Upper Quaternary shelf and slope deposits provide models for analogous deposits in the geologic record. Primarily, they are examples of cyclic sedimentation caused by changes in sea level and may be useful in describing short-term, sandy depositional episodes in prograding shelf and slope sequences.

Marine Geology↗

The Ebro margin study, northwestern Mediterranean Sea - an introduction

The Ebro continental margin from the coast to the deep sea off northeastern Spain was selected for a multidisciplinary project because of the abundant Ebro River sediment supply, Pliocene and Quaternary progradation, and margin development in a restricted basin where a variety of controlling factors could be evaluated. The nature of this young passive margin for the last 5 m.y. was investigated with particular emphasis on marine circulation, sediment dynamics, sediment geochemistry, depositional facies, seismic stratigraphy, geotechnical properties, geological hazards and human influences. These studies show the importance of marine circulation, variation in sediment supply, sea-level oscillation and tectonic setting for the understanding of modern and ancient margin depositional processes and growth patterns.

Marine Geology↗

Sedimentary evolution of the Pliocene and Pleistocene Ebro margin, northeastern Spain

The Pliocene and Pleistocene deposits of the Spanish Ebro margin overlie a regional unconformity and contain a major disconformity. These unconformities, named Reflector M and Reflector G, mark the bases of two seismic sequences. Except for close to the upper boundary where a few small channel deposits are recognized, the lower sequence lacks channels. The upper sequence contains nine channel-levee complexes as well as base-of-slope aprons that represent the proximal part of the Valencia turbidite system. Diverse geometries and variations in seismic units distinguish shelf, slope, base-of-slope and basin-floor facies. Four events characterize the late Miocene to Pleistocene evolution of the Ebro margin: (a) formation of a paleodrainage system and an extensive erosion-to-depositional surface during the latest Miocene (Messinian), (b) deposition of hemipelagic units during the early Pliocene, (c) development of canyons during the late Pliocene to early Pleistocene, and (d) deposition of slope wedges, channel-levee complexes, and base-of-slope aprons alternating with hemipelagic deposition during the Pleistocene. Sea-level fluctuations influenced the evolution of the sedimentary sequences of the Ebro margin, but the major control was the sediment supply from the Ebro River.

Marine Geology↗

Neogene paleoceanographic events recorded in an active-margin setting: Humboldt basin, California

Recognition of North Pacific paleoceanographic events in the marginal Humboldt (Eel River) basin of northern California enables correlation of stratigraphic sections and development of a chronostratigraphy. Paleoclimatically related coiling shifts in Neogloboquadrina pachyderma (Ehrenberg) and benthic foraminiferal datums form the basis of the chronostratigraphy. Benthic foraminiferal datums are defined by the occurrence of selected benthic species and abundance maxima of benthic biofacies. The compiled chronostratigraphy is used to refine reconstructions of the depositional history of Humboldt basin. Paleoceanographic events, recognized by the distribution of benthic foraminiferal biofacies, are used to infer paleoceanographic history along the northeastern Pacific margin. The similarity in coiling curves of N. pachyderma from the marine sequence at DSDP Site 173 and the coastal Centerville Beach section of Humboldt basin and at other independently dated sites along the northeastern Pacific margin demonstrates that matching records of climatic oscillations is a reliable method of correlating marine sequences. Benthic fauna from the Centerville Beach section vary in phase with climatically related coiling shifts in N. pachyderma . In particular these data show an increase in displaced neritic fauna during inferred warm intervals and resurgence of deeper bathyal fauna during inferred cool events. Similar data are observed from the inland Eel River section, demonstrating that benthic foraminiferal trends recognized at Centerville Beach can be identified elsewhere in Humboldt basin. This in-phase benthic response to climatic fluctuations probably results from changes in vertical depth range of many benthic species in response to paleoclimatically related vertical changes in water-mass position. Depositional histories reconstructed for two key sites in southern Humboldt basin indicate low rates of sediment accumulation during early basin filling with hemipelagic sediments. Initiation of turbidite sedimentation in the early Pliocene resulted in a sharp increase in rate of sediment accumulation. This increase in rate of sediment accumulation is partially a response to tectonic uplift in the northern Coast Ranges and may be an effect of realignment of motion between the Pacific and North American plates at about this time. The inland site shoaled more rapidly during turbidite sedimentation as a result of a higher rate of sediment accumulation. The rate of sediment accumulation increased again at this site in the late Pliocene during deposition of shelf and nearshore facies. The Eel River region subsided concurrent with deposition of these shallow-water deposits.

Palaeogeography, Palaeoclimatology, Palaeoecology↗