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At least 613 records · Page 34Linked to original sources

An assessment of plant species differences on cellulose oxygen isotopes from two Kenai Peninsula, Alaska peatlands: Implications for hydroclimatic reconstructions

Peat cores are valuable archives of past environmental change because they accumulate plant organic matter over millennia. While studies have primarily focused on physical, ecological, and some biogeochemical proxies, cores from peatlands have increasingly been used to interpret hydroclimatic change using stable isotope analyses of cellulose preserved in plant remains. Previous studies indicate that the stable oxygen isotope compositions (δ 18 O) preserved in alpha cellulose extracted from specific plant macrofossils reflect the δ 18 O values of past peatland water and thereby provide information on long-term changes in hydrology in response to climate. Oxygen isotope analyses of peat cellulose (δ 18 O cellulose ) have been successfully developed from peat cores that accumulate the same species for millennia. However, to fully exploit the potential of this proxy in species-diverse fens, studies are needed that account for the isotopic variations caused by changes in dominant species composition. This study assesses variation in δ 18 O values among peatland plant species and how they relate to environmental waters in two fens informally named Horse Trail and Goldfin, located on the leeward (dry) and windward (wet) side, respectively, of the climatic gradient across the Kenai Peninsula, Alaska. Environmental water δ 18 O values at both fens reflect unmodified δ 18 O values of mean annual precipitation, although at Goldfin standing pools were slightly influenced by evaporation. Modern plant [mosses and Carex spp. (sedges)] δ 18 O cellulose values indicate that all Carex spp. are higher (~2.5‰) than those of mosses, likely driven by their vascular structure and ecophysiological difference from non-vascular mosses. Moss δ 18 O cellulose values within each peatland are similar among the species, and differences appear related to evaporation effects on environmental waters within hummocks and hollows. The plant taxa-environmental water δ 18 O differences are applied to the previously determined Horse Trail Fen untreated bulk δ 18 O record. Results include significant changes to inferred millennial-to-centennial scale hydroclimatic trends where dominant taxa shift from moss to Carex spp., indicating that modern calibration datasets are necessary for interpreting stable isotopes from fens, containing a mix of vascular and nonvascular plants. Accounting for isotopic offsets through macrofossil analysis and modern plant-water isotope measurements opens new opportunities for hydroclimatic reconstructions from fen peatlands.

Alaska↗

Continental climate response to orbital forcing from biogenic silica records in Lake Baikal

CHANGES in insolation caused by periodic changes in the Earth's orbital parameters provide the primary forcing for global ice ages1-6. But it is not clear to what extent the climates in continental interiors are controlled directly by regional variations in insolation and to what extent they are driven instead by the highly nonlinear response of the oceans and ice sheets. Here we investigate this question using the record of biogenic silica in Lake Baikal as a proxy for climate change in this high-latitude mid-continental region. We find a good correlation between this record and that of marine oxygen isotopes4. Over the past 250 kyr the Baikal record exhibits both a strongly nonlinear component (manifested in a 100-kyr periodicity) and weaker direct-insolation components (manifested in the 41-kyr (obliquity) and 23- and 19-kyr (precession) orbital cycles). These results show that even though extreme continental climates such as this are influenced directly by insolation variations, they are dominated by the nonlinear rhythm of the oceans and ice sheets.

Lake Baikal↗

Forest legacies, climate change, altered disturbance regimes, invasive species and water

The factors that must be considered in seeking to predict changes in water availability has been examined. These factors are the following: forest legacies including logging, mining, agriculture, grazing, elimination of large carnivores, human-caused wildfire, and pollution; climate change and stream flow; altered disturbances such as frequency intensity and pattern of wildfires and insect outbreaks as well as flood control; lastly, invasive species like forest pests and pathogens. An integrated approach quantifying the current and past condition trends can be combined with spatial and temporal modeling to develop future change in forest structures and water supply. The key is a combination of geographic information system technologies with climate and land use scenarios, while preventing and minimizing the effects of harmful invasive species.

Unasylva↗

Temporal variability in the hydrologic regimes of the United States

Discharge records where flows have not been subject to overt anthropogenic controls have been identified for over 1500 streamflow gauging stations throughout the United States in the US Geological Survey Hydro-Climatic Data Network. These stations fall within all 21 water resources regions of the United States. Analysis of runoff in 20 regions, where long-term daily records are available, shows an increasing trend in 16 regions. Further analysis using a stratified subset of 65 sites shows an increase in baseflow at approximately 90% of the sites during the past 50 years, regardless of the size of the drainage area. Because anthropogenic alterations of watershed characteristics cannot explain these hydrologic changes, then meteorological or climatic forces are implicated.

IAHS-AISH Publication↗

Influences of geomorphology and geology on alpine treeline in the American West - More important than climatic influences?

The spatial distribution and pattern of alpine treeline in the American West reflect the overarching influences of geological history, lithology and structure, and geomorphic processes and landforms, and geologic and geomorphic factors—both forms and processes—can control the spatiotemporal response of the ecotone to climate change. These influences occur at spatial scales ranging from the continental scale to fine scale processes and landforms at the slope scale. Past geomorphic influences, particularly Pleistocene glaciation, have also left their impact on treeline, and treelines across the west are still adjusting to post-Pleistocene conditions within Pleistocene-created landforms. Current fine scale processes include solifluction and changes on relict solifluction and digging by animals. These processes should be examined in detail in future studies to facilitate a better understanding of where individual tree seedlings become established as a primary response of the ecotone to climate change.

The Rocky Mountains↗

Paleolimnology of Lake Tanganyika, East Africa, over the past 100 k yr

New sediment core data from a unique slow-sedimentation rate site in Lake Tanganyika contain a much longer and continuous record of limnological response to climate change than have been previously observed in equatorial regions of central Africa. The new core site was first located through an extensive seismic reflection survey over the Kavala Island Ridge (KIR), a sedimented basement high that separates the Kigoma and Kalemie Basins in Lake Tanganyika. Proxy analyses of paleoclimate response carried out on core T97-52V include paleomagnetic and index properties, TOC and isotopic analyses of organic carbon, and diatom and biogenic silica analyses. A robust age model based on 11 radiocarbon (AMS) dates indicates a linear, continuous sedimentation rate nearly an order of magnitude slower here compared to other core sites around the lake. This age model indicates continuous sedimentation over the past 79 k yr, and a basal age in excess of 100 k yr. The results of the proxy analyses for the past ??? 20 k yr are comparable to previous studies focused on that interval in Lake Tanganyika, and show that the lake was about 350 m lower than present at the Last Glacial Maximum (LGM). Repetitive peaks in TOC and corresponding drops in ??13C over the past 79 k yr indicate periods of high productivity and mixing above the T97-52V core site, probably due to cooler and perhaps windier conditions. From ??? 80 through ??? 58 k yr the ??13C values are relatively negative (-26 to -28???) suggesting predominance of algal contributions to bottom sediments at this site during this time. Following this interval there is a shift to higher values of ??13C, indicating a possible shift to C-4 pathway-dominated grassland-type vegetation in the catchment, and indicating cooler, dryer conditions from ??? 55 k yr through the LGM. Two seismic sequence boundaries are observed at shallow stratigraphic levels in the seismic reflection data, and the upper boundary correlates to a major discontinuity near the base of T97-52V. We interpret these discontinuities to reflect major, prolonged drops in lake level below the core site (393 m), with the lower boundary correlating to marine oxygen isotope Stage 6. This suggests that the previous glacial period was considerably cooler and more arid in the equatorial tropics than was the last glacial period.

Conference Paper↗

Regional acidification trends in Florida shellfish estuaries: A 20+ year look at pH, oxygen, temperature, and salinity

Increasing global CO 2 and local land use changes coupled with increased nutrient pollution are threatening estuaries worldwide. Local changes of estuarine chemistry have been documented, but regional associations and trends comparing multiple estuaries latitudinally have not been evaluated. Rapid climate change has impacted the annual and decadal chemical trends in estuaries, with local ecosystem processes enhancing or mitigating the responses. Here, we compare pH, dissolved oxygen, temperature, and salinity data from 10 Florida shellfish estuaries and hundreds of shellfish bed stations. Over 80,000 measurements, spanning from 1980 to 2008, taken on Atlantic Ocean and West Florida coast showed significant regional trends of consistent pH decreases in 8 out of the 10 estuaries, with an average rate of decrease on the Gulf of Mexico side estuaries of Florida of 7.3 × 10 −4 pH units year −1 , and average decrease on the Atlantic Coast estuaries of 5.0 × 10 −4 pH units year −1 . The rates are approximately 2–3.4 times slower than observed in pH decreases associated with ocean acidification in the Atlantic and Pacific. Other significant trends observed include decreasing dissolved oxygen in 9 out of the 10 estuaries, increasing salinity in 6 out of the 10, and temperature increases in 3 out of the 10 estuaries. The data provide a synoptic regional view of Florida estuary trends which reflect the complexity of changing climate and coastal ocean acidification superimposed on local conditions. These data provide context for understanding, and interpreting the past and predicting future of regional water quality health of shellfish and other organisms of commercial and ecological significance along Florida’s coasts.

Estuaries and Coasts↗

Fish bioenergetics modeling

A bioenergetics model for a fish is defined as a quantitative description of the fish's energy budget. Bioenergetics modeling can be applied to free-ranging fish in rivers, lakes, and oceans to estimate annual food consumption by fish populations; such applications have proven useful in managing fisheries. In addition, bioenergetics models have been used to better understand fish growth and consumption in ecosystems, to guide conservation management of endangered or threatened fish populations, to determine the importance of the role of fish in cycling nutrients within ecosystems, to predict fish growth and consumption under climate change , and to identify the important factors regulating contaminant accumulation in free-ranging fish. Over the past 60 years, fish bioenergetics modeling has led to significant advancements in both aquatic ecology, especially fish ecology, and fisheries management.

Book chapter↗

Temperature as a potent driver of regional forest drought stress and tree mortality

s the climate changes, drought may reduce tree productivity and survival across many forest ecosystems; however, the relative influence of specific climate parameters on forest decline is poorly understood. We derive a forest drought-stress index (FDSI) for the southwestern United States using a comprehensive tree-ring data set representing AD 1000-2007. The FDSI is approximately equally influenced by the warm-season vapour-pressure deficit (largely controlled by temperature) and cold-season precipitation, together explaining 82% of the FDSI variability. Correspondence between the FDSI and measures of forest productivity, mortality, bark-beetle outbreak and wildfire validate the FDSI as a holistic forest-vigour indicator. If the vapour-pressure deficit continues increasing as projected by climate models, the mean forest drought-stress by the 2050s will exceed that of the most severe droughts in the past 1,000 years. Collectively, the results foreshadow twenty-first-century changes in forest structures and compositions, with transition of forests in the southwestern United States, and perhaps water-limited forests globally, towards distributions unfamiliar to modern civilization.

Nature Climate Change↗

Effects of chronic and acute stressors on transplanted black mangrove (Avicennia germinans) seedlings along an eroding Louisiana shoreline

Coastal wetland restoration can be used to offset past wetland losses and/or reduce future losses due to land-use changes, rising sea levels, and accelerating climate change. However, there is a need for information regarding the restoration-relevant performance of foundation species like mangrove and marsh plants, including their responses to acute and chronic stressors that can affect restoration outcomes. Mangrove encroachment and poleward range expansion into marsh, facilitated by warming winters, has provided restoration practitioners in the northern Gulf of Mexico with a new foundation plant species to consider using during restoration. To evaluate the performance of transplanted mangroves and characterize restoration-relevant marsh–mangrove interactions, we planted nursery-raised black mangrove ( Avicennia germinans ) seedlings within different marsh cover treatments along an eroding marsh-dominated shoreline in Louisiana. Mangrove seedling survival increased with greater densities of marsh cover, indicating that marsh grass ( Spartina alterniflora ) may facilitate mangrove establishment. However, only 35% of transplanted mangrove seedlings established after 10 weeks, suggesting a low return on resources expended in raising seedlings for 1–3 years in greenhouse conditions. Moreover, a 2018 freeze event killed 100% of transplanted mangrove seedlings, while nearby naturally established mangroves suffered minor damage. Our results, along with those in the mangrove restoration literature, indicate that planting mangroves in the northern Gulf of Mexico may not be the most efficient use of limited resources. Rather, restoration efforts may benefit from focusing initially on the restoration of abiotic conditions (e.g. elevation and hydrologic regimes), followed by using marsh plants (rather than transplanted mangroves) to jump-start ecosystem development.

Louisiana↗

Towards vibrant fish populations and sustainable fisheries that benefit all: Learning from the last 30 years to inform the next 30 years

A common goal among fisheries science professionals, stakeholders, and rights holders is to ensure the persistence and resilience of vibrant fish populations and sustainable, equitable fisheries in diverse aquatic ecosystems, from small headwater streams to offshore pelagic waters. Achieving this goal requires a complex intersection of science and management, and a recognition of the interconnections among people, place, and fish that govern these tightly coupled socioecological and sociotechnical systems. The World Fisheries Congress (WFC) convenes every four years and provides a unique global forum to debate and discuss threats, issues, and opportunities facing fish populations and fisheries. The 2021 WFC meeting, hosted remotely in Adelaide, Australia, marked the 30th year since the first meeting was held in Athens, Greece, and provided an opportunity to reflect on progress made in the past 30 years and provide guidance for the future. We assembled a diverse team of individuals involved with the Adelaide WFC and reflected on the major challenges that faced fish and fisheries over the past 30 years, discussed progress toward overcoming those challenges, and then used themes that emerged during the Congress to identify issues and opportunities to improve sustainability in the world's fisheries for the next 30 years. Key future needs and opportunities identified include: rethinking fisheries management systems and modelling approaches, modernizing and integrating assessment and information systems, being responsive and flexible in addressing persistent and emerging threats to fish and fisheries, mainstreaming the human dimension of fisheries, rethinking governance, policy and compliance, and achieving equity and inclusion in fisheries. We also identified a number of cross-cutting themes including better understanding the role of fish as nutrition in a hungry world, adapting to climate change, embracing transdisciplinarity, respecting Indigenous knowledge systems, thinking ahead with foresight science, and working together across scales. By reflecting on the past and thinking about the future, we aim to provide guidance for achieving our mutual goal of sustaining vibrant fish populations and sustainable fisheries that benefit all. We hope that this prospective thinking can serve as a guide to (i) assess progress towards achieving this lofty goal and (ii) refine our path with input from new and emerging voices and approaches in fisheries science, management, and stewardship.

Reviews in Fish Biology and Fisheries↗

Influences of potential oil and gas development and future climate on Sage-grouse declines and redistribution

Multiple environmental stressors impact wildlife populations, but we often know little about their cumulative and combined influences on population outcomes. We generally know more about past effects than potential future impacts, and direct influences such as changes of habitat footprints than indirect, long-term responses in behavior, distribution, or abundance. Yet, an understanding of all these components is needed to plan for future landscapes that include human activities and wildlife. We developed a case study to assess how spatially explicit individual-based modeling could be used to evaluate future population outcomes of gradual landscape change from multiple stressors. For Greater Sage-grouse in southwest Wyoming, USA, we projected oil and gas development footprints and climate-induced vegetation changes 50 years into the future. Using a time-series of planned oil and gas development and predicted climate-induced changes in vegetation, we recalculated habitat selection maps to dynamically modify future habitat quantity, quality, and configuration. We simulated long-term Sage-grouse responses to habitat change by allowing individuals to adjust to shifts in habitat availability and quality. The use of spatially explicit individual-based modeling offered a useful means of evaluating delayed indirect impacts of landscape change on wildlife population outcomes. The inclusion of movement and demographic responses to oil and gas infrastructure resulted in substantive changes in distribution and abundance when cumulated over several decades and throughout the regional population. When combined, additive development and climate-induced vegetation changes reduced abundance by up to half of the original size. In our example, the consideration of only a single population stressor the final possible population size by as much as 50%. Multiple stressors and their cumulative impacts need to be broadly considered through space and time to avoid underestimating the impacts of multiple gradual changes and overestimating the ability of populations to withstand change.

Wyoming↗

Monitoring and conservation of Japanese Murrelets and related seabirds in Japan

Of the 24 species in the Auk (or Alcidae) family of seabirds living in the northern hemisphere, 22 reside within the North Pacific Ocean. These “penguins of the north” use their small wings to “fly” underwater, some to more than 200 meters, where they catch and eat a variety of small fish and invertebrates. In terms of sheer numbers (>65 million) and food consumption, the Auks dominate seabird communities on our continental shelves and they serve as indicators of the health of our ocean. If Auk populations are not all thriving, then we should be concerned about the status of the oceans, plankton and fish that normally sustain them. A few Auk “tribes” genera) are abundant and widespread (such as Uria murres and Aethia auklets), and some are rare and isolated such as Synthliboramphus murrelets, including the Japanese “Crested” Murrelet). Only 8 species of Auk breed in Japan, including species that have either widespread or isolated populations in the North Pacific. During the past century, most of these Auks have declined dramatically in Japan from many causes, including the introduction of predatory rats and cats to breeding islands, bycatch in fishing nets, alteration of food supplies by fishing and climate change, oil spills, and destruction of seabird nesting habitats. Widespread species such as the Common Murre and Tufted Puffin were once common in Japan but now breed in low numbers at only a few locations. Probably common in the past, small numbers of the widespread Ancient Murrelet were recently re-discovered breeding at Teuri Island, which is also home to the world’s largest colony of Rhinoceros Auklet, another widespread species. Though common throughout the North Pacific, Pigeon Guillemots, breed only in the southern Kuril Islands. Their population status is unknown, but they were never considered common in Japan. In contrast, Spectacled Guillemots are an example of an uncommon and isolated population of Auk. They nest along coasts of the Sea of Okhotsk and Sea of Japan, and populations have declined in recent decades. The Long-billed Murrelet has a similar distribution to Spectacled Guillemot, and once bred in Hokkaido, but populations appear to have been extirpated. The Japanese Murrelet has a very small world population, and breeds at only a few locations in southern Japan and the Republic of Korea. The international community of research and conservation biologists is greatly concerned about the ability of this species—probably the rarest of all Auks in the world— to maintain its population size. Owing to its small size and high metabolic demand, this species is especially vulnerable to any stress that increases its food requirements such as changing fish stocks, disturbance on feeding or wintering grounds, or changing ocean climate. Immediate management actions are needed to preserve Japanese Murrelets and other Auks in Japan, by such means as eradicating rats and cats on breeding islands, altering fishing gear to minimize bycatch, and reducing human disturbance to nesting habitats. More research and monitoring of Auk populations in Japan is needed to track population trends, and further identify factors responsible for declines. Interaction between governments and biologists at regional and international levels will be mutually beneficial as we all strive to conserve precious resources and biodiversity in the northwest Pacific, and particularly the Japanese islands.

Conference Paper↗

Riparian vegetation response amid variable climate conditions across the Upper Gila River watershed: Informing Tribal restoration priorities

Riparian systems across the Southwest United States are extremely valuable for the human and ecological communities that engage with them. However, they have experienced substantial changes and stresses over the past century, including non-native vegetation expansion, vegetation die-offs, and increased fire activity. Vegetation management approaches, such as ecological restoration, may address some of these stressors as well as reduce the risk of future impacts. We apply remote sensing to inform restoration priorities along the upper Gila River within the San Carlos Apache Reservation and Upper Gila River watershed. First, we develop a spatially and temporally explicit trend analysis across three observed climate periods (1985–1993, 1993–2014, 2014–2021) using the Landsat-derived indices to quantify changes in riparian vegetation conditions. These maps can be used to identify areas potentially more at risk for degradation. Second, we analyze changes in riparian vegetation within a climate framework to better understand trends and the potential effect of climate change. Vegetation greenness has largely increased throughout the watershed despite intensifying drought conditions across our study period, though areas within the lower watershed have shown increased stress and higher rates of wildfire and other disturbances over the past 5-years. Nevertheless, small-scale restoration activities appear to show improving vegetation conditions, suggesting efficacy of these restoration activities. Results from this study may be integrated with restoration objectives to develop a restoration plan that will help riparian vegetation communities adapt to change.

Arizona↗

Mast hindcasts reveal pervasive effects of extreme drought on a foundational conifer species

Predicting seed production is challenging because many plants produce highly variable crops among years (i.e. masting), but doing so can inform forest management, conservation, and our understanding of ecosystem trajectories in a changing climate. We evaluated the ability of an existing model to forecast masting in an ecologically and culturally important tree species in the southwestern United States, Pinus edulis . Annual seed cone production was predicted using cross-validation techniques on two unique out-of-sample datasets, representing different collection methods and spatial scales (cone scars and cone counts). We then hindcasted this model into the historical past to evaluate whether seed production has declined with the onset of extreme drought conditions in western North America. The evaluated model had fair skill, with root-mean-squared error of 6%. The model had better skill predicting the interannual variability within a site than among sites (i.e. within years). Hindcast analyses indicated recent (2000–2024) mean annual cone production was 30.6% lower than in the past century (1900–1999). Mast forecasts are within reach, but much room remains for improvement. Forecasts may be a powerful tool to anticipate the effects of climate change on forests and woodlands.

Arizona, Colorado, New Mexico, Utah↗

Sea level history in Beringia during the past 250,000 years

This paper attempts to relate current knowledge of sea-level history in Beringia to the Broecker-van Donk “Termination” concept of climatic and sea-level history. The Einahnuhtan transgression is thought to represent Termination III, which according to Broecker and van Donk, took place about 225,000 y.a. The Kotzebuan transgression is thought to represent a positive fluctuation that modulated the generally falling sea level during the ensuing 100,000 yr. Sea level probably fell to about −135 m in the Bering Sea area during the maximum phase of the penultimate glaciation. The two Pelukian shorelines probably represent Termination II (about 125,000 yr BP in the Broecker-van Donk chronology) and one of the two positive fluctuations that modulated the generally falling sea level of early Wisconsinan time, about 105,000 and 80,000 y.a. according to Broecker and van Donk. Another positive modulation brought sea level to at least −20 m, about 30,000 y.a. Sea level evidently fell to between −90 and −100 m during the late Wisconsinan regression, but a substantial part of the outer Bering shelf remained submerged. Submerged shoreline features at −38m, −30 m, −24 to −20 m, and −12 to −10 m represent stillstands or slight regressions that modulated Termination I, the late Wisconsinan, and early Holocene recovery of sea level.

Alaska↗

Mid-Wisconsin to Holocene permafrost and landscape dynamics based on a drained lake basin core from the northern Seward Peninsula, northwest Alaska

Permafrost-related processes drive regional landscape dynamics in the Arctic terrestrial system. A better understanding of past periods indicative of permafrost degradation and aggradation is important for predicting the future response of Arctic landscapes to climate change. Here, we used a multi-proxy approach to analyse a ~ 4 m long sediment core from a drained thermokarst lake basin on the northern Seward Peninsula in western Arctic Alaska (USA). Sedimentological, biogeochemical, geochronological, micropalaeontological (ostracoda, testate amoebae) and tephra analyses were used to determine the long-term environmental Early-Wisconsin to Holocene history preserved in our core for central Beringia. Yedoma accumulation dominated throughout the Early to Late-Wisconsin but was interrupted by wetland formation from 44.5 to 41.5 ka BP. The latter was terminated by the deposition of 1 m of volcanic tephra, most likely originating from the South Killeak Maar eruption at about 42 ka BP. Yedoma deposition continued until 22.5 ka BP and was followed by a depositional hiatus in the sediment core between 22.5 and 0.23 ka BP. We interpret this hiatus as due to intense thermokarst activity in the areas surrounding the site, which served as a sediment source during the Late-Wisconsin to Holocene climate transition. The lake forming the modern basin on the upland initiated around 0.23 ka BP and drained catastrophically in spring 2005. The present study emphasises that Arctic lake systems and periglacial landscapes are highly dynamic and that permafrost formation as well as degradation in central Beringia was controlled by regional to global climate patterns as well as by local disturbances.

Alaska↗

A reactive transport approach to modeling cave seepage water chemistry II: Elemental signatures

Karst systems are useful for examining spatial and temporal variability in Critical Zone processes because they provide a window into the subsurface where waters have interacted with vegetation, soils, regolith, and bedrock across a range of length and timescales. These hydrologic pathways frequently include the precipitation of speleothems, which provide long-term archives of climate and environmental change. Trace element ratios in speleothems (Mg/Ca, Sr/Ca, Ba/Ca) have the potential to provide information about past changes in rainfall and infiltration, but controls on them can be complex and their interpretation must be based on an understanding of the modern cave system. Here we integrate observations of surface conditions, bedrock, soil, and drip water chemistry of Blue Spring Cave in Tennessee, USA with the reactive transport model CrunchTope, which we have calibrated for karst systems to investigate the primary controls on trace element variations in cave seepage waters. We find that measured drip water Mg/Ca and Sr/Ca are captured within the model through variable amounts of limestone dissolution followed by precipitation of secondary calcite that happens within the cave rather than the host limestone. However, strong spatial controls on drip water Mg/Ca and Sr/Ca likely reflect seepage water interactions with variable amounts of diagenetic phases in the host rock. In contrast, Ba/Ca values are consistent across the cave and vary with effective rainfall, suggesting that this parameter may be the most consistent metric for limestone dissolution and prior calcite precipitation and can act as a proxy for rainfall and infiltration in this cave system. Our findings emphasize the importance of evaluating spatial heterogeneity in cave drip waters and outline a novel modeling approach for determining the dominant controls on drip water chemistry in support of the interpretations of paleoclimate records.

Geochimica et Cosmochimica Acta↗