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At least 613 records · Page 34Linked to original sources

USGS2014

Air-sea interactions during strong winter extratropical storms

A high-resolution, regional coupled atmosphere–ocean model is used to investigate strong air–sea interactions during a rapidly developing extratropical cyclone (ETC) off the east coast of the USA. In this two-way coupled system, surface momentum and heat fluxes derived from the Weather Research and Forecasting model and sea surface temperature (SST) from the Regional Ocean Modeling System are exchanged via the Model Coupling Toolkit. Comparisons are made between the modeled and observed wind velocity, sea level pressure, 10 m air temperature, and sea surface temperature time series, as well as a comparison between the model and one glider transect. Vertical profiles of modeled air temperature and winds in the marine atmospheric boundary layer and temperature variations in the upper ocean during a 3-day storm period are examined at various cross-shelf transects along the eastern seaboard. It is found that the air–sea interactions near the Gulf Stream are important for generating and sustaining the ETC. In particular, locally enhanced winds over a warm sea (relative to the land temperature) induce large surface heat fluxes which cool the upper ocean by up to 2 °C, mainly during the cold air outbreak period after the storm passage. Detailed heat budget analyses show the ocean-to-atmosphere heat flux dominates the upper ocean heat content variations. Results clearly show that dynamic air–sea interactions affecting momentum and buoyancy flux exchanges in ETCs need to be resolved accurately in a coupled atmosphere–ocean modeling framework.

Ocean Dynamics↗

USGS2023

Initial comparison of pollen counting methods using precipitation and ambient air samples and automated artificial intelligence to support national monitoring objectives

Given the endemic nature of pollen throughout the environment, the impact upon human health, and the need for more extensive and better measurements of pollen in the USA, a preliminary project within the National Atmospheric Deposition Program’s (NADP) National Trends Network (NTN) was developed. Pollen was measured in ambient air by several methods and in precipitation wet deposition samples at three monitoring sites in the NTN. A method for counting pollen on filters was developed and provided pollen counts for NADP atmospheric wet-deposition samples and high-volume ambient air samplers (HVAS) for comparison with co-located traditional National Allergy Bureau microscopy samples and a commercially available pollen sensor (PS) counting method during the 2021 pollen season. The goals of this project were to test the potential of available air-monitoring infrastructures to obtain improved spatial measurements of aeroallergens, compare pollen counting results from the various methods, and to determine the suitability of using wet deposition samples for pollen collection. The onset and senescence of pollen seasons for general categories of genera compared favorably for each method at each site, indicating that pollen monitoring using wet-deposition and ambient air sampling filters could provide useful information to inform scientific studies, but not likely for public health objectives. Pollen counts were log transformed for Pearson product moment correlation. Tree pollen counts were correlated at all sites for daily PS data and traditional counting data ( R = 0.69–0.84), but statistical correlations between methods for grass and weed pollen were weak (0.40 < R < 0.60) or considered not correlated ( R < 0.40). Total pollen counts in NADP precipitation samples were correlated with traditional and PS counts at only one of three sites. Pollen counts for the weekly HVAS filter samples were correlated with PS counts for trees ( R = 0.62) and with NAB counts for trees ( R = 0.68) and weeds ( R = 0.72). Correlations in the data between methods suggest that, given further methods development, a variety of techniques could be integrated to expand and enhance existing pollen monitoring networks. Improved ambient air and atmospheric deposition sampling methods specifically targeted for pollen capture and analysis could support the collection of accurate and efficient meaningful aeroallergen data from existing atmospheric monitoring networks.

Aerobiologia↗

USGS2010

Comparisons of watershed sulfur budgets in southeast Canada and northeast US: New approaches and implications

Most of eastern North America receives elevated levels of atmospheric deposition of sulfur (S) that result from anthropogenic SO 2 emissions from fossil fuel combustion. Atmospheric S deposition has acidified sensitive terrestrial and aquatic ecosystems in this region; however, deposition has been declining since the 1970s, resulting in some recovery in previously acidified aquatic ecosystems. Accurate watershed S mass balances help to evaluate the extent to which atmospheric S deposition is retained within ecosystems, and whether internal cycling sources and biogeochemical processes may be affecting the rate of recovery from decreasing S atmospheric loads. This study evaluated S mass balances for 15 sites with watersheds in southeastern Canada and northeastern US for the period 1985 to 2002. These 15 sites included nine in Canada (Turkey Lakes, ON; Harp Lake, ON; Plastic Lake, ON; Hermine, QC; Lake Laflamme, QC; Lake Clair, QC; Lake Tirasse, QC; Mersey, NS; Moosepit, NS) and six in the US (Arbutus Lake, NY; Biscuit Brook, NY; Sleepers River, VT; Hubbard Brook Experimental Forest, NH; Cone Pond, NH; Bear Brook Watershed, ME). Annual S wet deposition inputs were derived from measured bulk or wet-only deposition and stream export was obtained by combining drainage water fluxes with SO 4 2− concentrations. Dry deposition has the greatest uncertainty of any of the mass flux calculations necessary to develop accurate watershed balances, and here we developed a new method to calculate this quantity. We utilized historical information from both the US National Emissions Inventory and the US (CASTNET) and the Canadian (CAPMoN) dry deposition networks to develop a formulation that predicted SO 2 concentrations as a function of SO 2 emissions, latitude and longitude. The SO 2 concentrations were used to predict dry deposition using relationships between concentrations and deposition flux derived from the CASTNET or CAPMoN networks. For the year 2002, we compared the SO 2 concentrations and deposition predictions with the predictions of two continental-scale air quality models, the Community Multiscale Air Quality (CMAQ) model and A Unified Regional Air-quality Modeling System (AURAMS) that utilize complete inventories of emissions and chemical budgets. The results of this comparison indicated that the predictive relationship provides an accurate representation of SO 2 concentrations and S deposition for the region that is generally consistent with these models, and thus provides confidence that our approach could be used to develop accurate watershed S budgets for these 15 sites. Most watersheds showed large net losses of SO 4 2− on an annual basis, and the watershed mass balances were grouped into five categories based on the relative value of mean annual net losses or net gains. The net annual fluxes of SO 4 2− showed a strong relationship with hydrology; the largest net annual negative fluxes were associated with years of greatest precipitation amount and highest discharge. The important role of catchment hydrology on S budgets suggests implications for future predicted climate change as it affects patterns of precipitation and drought. The sensitivity of S budgets is likely to be greatest in watersheds with the greatest wetland area, which are particularly sensitive to drying and wetting cycles. A small number of the watersheds in this analysis were shown to have substantial S sources from mineral weathering, but most showed evidence of an internal source of SO 4 2− , which is likely from the mineralization of organic S stored from decades of increased S deposition. Mobilization of this internal S appears to contribute about 1–6 kg S ha −1 year −1 to stream fluxes at these sites and is affecting the rate and extent of recovery from acidification as S deposition rates have declined in recent years. This internal S source should be considered when developing critical deposition loads that will promote ecosystem recovery from acidification and the depletion of nutrient cations in the northeastern US and southeastern Canada.

Connecticut, Maine, New Hampshire, New Jersey, New↗

USGS2005

Estimation and mapping of wet and dry mercury deposition across northeastern North America

Whereas many ecosystem characteristics and processes influence mercury accumulation in higher trophic-level organisms, the mercury flux from the atmosphere to a lake and its watershed is a likely factor in potential risk to biota. Atmospheric deposition clearly affects mercury accumulation in soils and lake sediments. Thus, knowledge of spatial patterns in atmospheric deposition may provide information for assessing the relative risk for ecosystems to exhibit excessive biotic mercury contamination. Atmospheric mercury concentrations in aerosol, vapor, and liquid phases from four observation networks were used to estimate regional surface concentration fields. Statistical models were developed to relate sparsely measured mercury vapor and aerosol concentrations to the more commonly measured mercury concentration in precipitation. High spatial resolution deposition velocities for different phases (precipitation, cloud droplets, aerosols, and reactive gaseous mercury (RGM)) were computed using inferential models. An empirical model was developed to estimate gaseous elemental mercury (GEM) deposition. Spatial patterns of estimated total mercury deposition were complex. Generally, deposition was higher in the southwest and lower in the northeast. Elevation, land cover, and proximity to urban areas modified the general pattern. The estimated net GEM and RGM fluxes were each greater than or equal to wet deposition in many areas. Mercury assimilation by plant foliage may provide a substantial input of methyl-mercury (MeHg) to ecosystems. ?? 2005 Springer Science+Business Media, Inc.

Ecotoxicology↗

USGS2012

Assessment of environments for Mars Science Laboratory entry, descent, and surface operations

The Mars Science Laboratory mission aims to land a car-sized rover on Mars' surface and operate it for at least one Mars year in order to assess whether its field area was ever capable of supporting microbial life. Here we describe the approach used to identify, characterize, and assess environmental risks to the landing and rover surface operations. Novel entry, descent, and landing approaches will be used to accurately deliver the 900-kg rover, including the ability to sense and "fly out" deviations from a best-estimate atmospheric state. A joint engineering and science team developed methods to estimate the range of potential atmospheric states at the time of arrival and to quantitatively assess the spacecraft's performance and risk given its particular sensitivities to atmospheric conditions. Numerical models are used to calculate the atmospheric parameters, with observations used to define model cases, tune model parameters, and validate results. This joint program has resulted in a spacecraft capable of accessing, with minimal risk, the four finalist sites chosen for their scientific merit. The capability to operate the landed rover over the latitude range of candidate landing sites, and for all seasons, was verified against an analysis of surface environmental conditions described here. These results, from orbital and model data sets, also drive engineering simulations of the rover's thermal state that are used to plan surface operations.

Space Science Reviews↗

USGS1983

Stability of streams and lakes on Mars

Under present climatic conditions streams and lakes on Mars will freeze. Freezing is slow and would have a negligible effect in impeding flow of the large floods that are believed to have eroded the outflow channels. Valley networks are more difficult to form under current climatic conditions since they appear to have formed by slow erosion by streams of modest discharges. Freezing of small Martian streams was modeled for a variety of climatic conditions on the supposition that the Martian atmosphere may have been considerably thicker in the past when the valley networks formed. The modeling involves examination of the energy balance at the upper and lower surfaces of ice on streams to determine the rate at which the ice thickens with time. The results indicate that freezing rates are not strongly dependent on atmospheric pressure. With no wind, increasing the pressure by a factor of 10 cuts the time taken to freeze solid only by about a factor of about 2. Under windy conditions dependence on atmospheric pressure is even weaker. The distance that water could travel in a stream before flow is arrested by freezing is also calculated. The distances depend on the initial temperature of the stream and when icings develop, but in general, if a stream deeper than 2 m can be initiated and sustained, the water within it can survive long enough to cut most of the valley networks observed. The main problem with forming the valley is initiating the flow. Groundwater seepage alone appears inadequate because of the difficulty of recharging the groundwater system. Melting of ice precipitated onto the surface following injection of water into the atmosphere by large impacts is a possible source of water, but the climatic conditions under which the ice could melt and the water be collected into streams that can survive long enough to cut the valley is uncertain.

Icarus↗

USGS1984

Heating rates in furnace atomic absorption using the L'vov platform

Heating rate profiles for the furnace tube wall, the furnace atmosphere, and a L'vov platform were established for a range of conditions in a cyclically heated graphite atomizer. The tube wall profile was made by direct observation with a recording optical pyrometer. The sodium line reversal method was used to establish the heating rate of the furnace atmosphere, and appearance temperatures for a series metals of differing volatility was used to establish platform profiles. The tube wall heating rate was nearly linear at 2240°C s − until the desired temperature was reached after which the temperature remained constant. The furnace atmosphere reached a given temperature 0.2–0.4 s later than the tube wall through most of the atomize cycle. The platform lagged the tube wall 0.5–0.8 s. Under typical operating conditions the furnace atmosphere was 100–200°C cooler than the tube wall and at nearly constant temperature when the analyte vaporized from the platform. The L'vov platform causes the cyclically heated commercial furnace to approximate the behavior of a constant temperature furnace during atomization.

Spectrochimica Acta Part B: Atomic Spectroscopy↗

USGS2020

A new sampler for the collection and retrieval of dry dust deposition

Atmospheric dust can influence biogeochemical cycles, accelerate snowmelt, and affect air, water quality, and human health. Yet, the bulk of atmospherically transported material remains poorly quantified in terms of total mass fluxes and composition. This lack of information stems in part from the challenges associated with measuring dust deposition. Here we report on the design and efficacy of a new dry deposition sampler (Dry Deposition Sampling Unit (DSU)) and method that quantifies the gravitational flux of dust particles. The sampler can be used alone or within existing networks such as those employed by the National Atmospheric Deposition Program (NADP). Because the samplers are deployed sterile and the use of water to remove trapped dust is not required, this method allows for the recovery of unaltered dry material suitable for subsequent chemical and microbiological analyses. The samplers were tested in the laboratory and at 15 field sites in the western United States. With respect to material retention, sampler performance far exceeded commonly used methods. Retrieval efficiency was >97% in all trials and the sampler effectively preserved grain size distributions during wind exposure experiments. Field tests indicated favorable comparisons to dust-on-snow measurement across sites ( r 2 0.70, p < 0.05) and within sites to co-located aerosol data ( r 2 0.57–0.99, p < 0.05). The inclusion of dust deposition and composition monitoring into existing networks increases spatial and temporal understanding of the atmospheric transport on materials and substantively furthers knowledge of the effects of dust on terrestrial ecosystems and human exposure to dust and associated deleterious compounds.

Arizona, California, Colorado, Idaho, Nevada, Utah↗

USGS2015

The fate of cyanide in leach wastes at gold mines: an environmental perspective

This paper reviews the basic chemistry of cyanide, methods by which cyanide can be analyzed, and aspects of cyanide behavior that are most relevant to environmental considerations at mineral processing operations associated with gold mines. The emphasis is on research results reported since 1999 and on data gathered for a series of U.S. Geological Survey studies that began in the late 1990s. Cyanide is added to process solutions as the CN − anion, but ore leaching produces numerous other cyanide-containing and cyanide-related species in addition to the desired cyanocomplex of gold. These can include hydrogen cyanide (HCN); cyanometallic complexes of iron, copper, zinc, nickel, and many other metals; cyanate (CNO − ); and thiocyanate (SCN − ). The fate of these species in solid wastes and residual process solutions that remain once gold recovery activities are terminated and in any water that moves beyond the ore processing facility dictates the degree to which cyanide poses a risk to aquatic organisms and aquatic-dependent organisms in the local environment. Cyanide-containing and cyanide-related species are subject to attenuation mechanisms that lead to dispersal to the atmosphere, chemical transformation to other carbon and nitrogen species, or sequestration as cyanometallic precipitates or adsorbed species on mineral surfaces. Dispersal to the atmosphere and chemical transformation amount to permanent elimination of cyanide, whereas sequestration amounts to storage of cyanide in locations from which it can potentially be remobilized by infiltrating waters if conditions change. From an environmental perspective, the most significant cyanide releases from gold leach operations involve catastrophic spills of process solutions or leakage of effluent to the unsaturated or saturated zones. These release pathways are unfavorable for two important cyanide attenuation mechanisms that tend to occur naturally: dispersal of free cyanide to the atmosphere and sunlight-catalyzed dissociation of strong cyanometallic complexes, which produces free cyanide that can then disperse to the atmosphere. The widest margins of environmental safety will be achieved where mineral processing operations are designed so that time for offgassing, aeration, and sunlight exposure are maximized in the event that cyanide-bearing solutions are released inadvertently.

Applied Geochemistry↗

USGS2011

Calibration of Nu-Instruments Noblesse multicollector mass spectrometers for argon isotopic measurements using a newly developed reference gas

The greatest challenge limiting 40 Ar/ 39 Ar multicollection measurements is the availability of appropriate standard gasses to intercalibrate detectors. In particular, use of zoom lens ion-optics to steer and focus ion beams into a fixed detector array (i.e., Nu Instruments Noblesse) makes intercalibration of multiple detectors challenging because different ion-optic tuning conditions are required for optimal peak shape and sensitivity at different mass stations. We have found that detector efficiency and mass discrimination are affected by changes in ion-optic tuning parameters. Reliance upon an atmospheric Ar standard to calibrate the Noblesse is problematic because there is no straightforward way to relate atmospheric 40 Ar and 36 Ar to measurements of 40 Ar and 39 Ar if they are measured on separate detectors. After exploring alternative calibration approaches, we have concluded that calibration of the Noblesse is best performed using exactly the same source, detector, and ion-optic tuning settings as those used in routine 40 Ar/ 39 Ar analysis. To accomplish this, we have developed synthetic reference gasses containing 40 Ar, 39 Ar and 38 Ar produced by mixing gasses derived from neutron-irradiated sanidine with an enriched 38 Ar spike. We present a new method for calibrating the Noblesse based on use of both atmospheric Ar and the synthetic reference gasses. By combining atmospheric Ar and synthetic reference gas in different ways, we can directly measure 40 Ar/ 39 Ar, 38 Ar/ 39 Ar, and 36 Ar/ 39 Ar correction factors over ratios that vary from 0.5 to 460. These correction factors are reproducible to better than ± 0.5‰ (2σ standard error) over intervals spanning ~ 24 h but can vary systematically by ~ 4% over 2 weeks of continuous use when electron multiplier settings are held constant. Monitoring this variation requires daily calibration of the instrument. Application of the calibration method to 40 Ar/ 39 Ar multicollection measurements of widely used sanidine reference materials ACs-2, FCs-2, and TCs-2 demonstrate that calculated 40 Ar*/ 39 Ar K can be accurately corrected to yield model 40 Ar/ 39 Ar ages consistent with those reported by Earthtime 40 Ar/ 39 Ar laboratories. Replicate analyses of 8–12 single-crystal sanidine ages are reproduced to within 1–2‰ (2σ standard error) under optimal analytical conditions. This calibration technique is applicable over a wide range of isotopic ratios and signal sizes. Finally, the reference gas has the added advantage of facilitating straightforward characterization of electron multiplier dead time over a wide dynamic range.

Chemical Geology↗

USGS2004

Mars chronology: Assessing techniques for quantifying surficial processes

Currently, the absolute chronology of Martian rocks, deposits and events is based mainly on crater counting and remains highly imprecise with epoch boundary uncertainties in excess of 2 billion years. Answers to key questions concerning the comparative origin and evolution of Mars and Earth will not be forthcoming without a rigid Martian chronology, enabling the construction of a time scale comparable to Earth's. Priorities for exploration include calibration of the cratering rate, dating major volcanic and fluvial events and establishing chronology of the polar layered deposits. If extinct and/or extant life is discovered, the chronology of the biosphere will be of paramount importance. Many radiometric and cosmogenic techniques applicable on Earth and the Moon will apply to Mars after certain baselines (e.g. composition of the atmosphere, trace species, chemical and physical characteristics of Martian dust) are established. The high radiation regime may pose a problem for dosimetry-based techniques (e.g. luminescence). The unique isotopic composition of nitrogen in the Martian atmosphere may permit a Mars-specific chronometer for tracing the time-evolution of the atmosphere and of lithic phases with trapped atmospheric gases. Other Mars-specific chronometers include measurement of gas fluxes and accumulation of platinum group elements (PGE) in the regolith. Putting collected samples into geologic context is deemed essential, as is using multiple techniques on multiple samples. If in situ measurements are restricted to a single technique it must be shown to give consistent results on multiple samples, but in all cases, using two or more techniques (e.g. on the same lander) will reduce error. While there is no question that returned samples will yield the best ages, in situ techniques have the potential to be flown on multiple missions providing a larger data set and broader context in which to place the more accurate dates. ?? 2004 Elsevier B.V. All rights reserved.

Earth-Science Reviews↗

USGS2025

Elevated CO2 enables brackish marsh transgression into freshwater forested wetlands while stimulating CH4 emissions

Wetlands are significant carbon (C) sinks and are expected to promote greater C assimilation as atmospheric CO 2 concentrations rise. However, the fate of C with environmental change along fresh-to-oligohaline wetland transitions is not well understood. We established an ex-situ mesocosm experiment to mimic future elevated atmospheric CO 2 concentrations ( e CO 2 , 720 ppm) versus current (380 ppm), and we exposed four co-occurring coastal wetland communities that naturally transgress (i.e., freshwater forest, mixed forest and marsh, marsh, mudflat) to these concentrations for two years. Overall, wetland communities with marsh plants in monoculture and mixed culture maintained high ecosystem C uptake with e CO 2 versus freshwater forested wetlands or mudflats, likely from superior plant species photosynthetic adjustment versus leaf area increases. e CO 2 promoted greater CO 2 uptake by leaves in all communities except mudflats, while promoting CH 4 efflux from whole ecosystems only when marsh plants were present. e CO 2 is projected to stimulate C gain 2.2-fold for forested wetlands and oligohaline marsh and 2.9-fold for forest-marsh mixture through greater CO 2 uptake. However, this comes at a cost of stimulated CH 4 flux by 1.4-to-1.7-fold in mixed and marsh communities versus reduced CH 4 fluxes with e CO 2 by forest and mudflat communities, perhaps through different oxidation pathways. Freshwater forested wetlands limited greenhouse gas emissions compared with transitional habitats, oligohaline marshes, and mudflats as atmospheric CO 2 concentrations increased. Stimulated C uptake in marshes may not offset higher methane emissions from these systems, potentially facilitating greater warming in a future with elevated atmospheric CO 2 .

Estuarine, Coastal and Shelf Science↗

USGS2004

Cassini observations of Io's visible aurorae

More than 500 images of Io in eclipse were acquired by the Cassini spacecraft in late 2000 and early 2001 as it passed through the jovian system en route to Saturn (Porco et al., 2003, Science 299, 1541-1547). Io's bright equatorial glows were detected in Cassini's near-ultraviolet filters, supporting the interpretation that the visible emissions are predominantly due to molecular SO2. Detailed comparisons of laboratory SO2 spectra with the Cassini observations indicate that a mixture of gases contribute to the equatorial emissions. Potassium is suggested by new detections of the equatorial glows at near-infrared wavelengths from 730 to 800 nm. Neutral atomic oxygen and sodium are required to explain the brightness of the glows at visible wavelengths. The molecule S2 is postulated to emit most of the glow intensity in the wavelength interval from 390 to 500 nm. The locations of the visible emissions vary in response to the changing orientation of the external magnetic field, tracking the tangent points of the jovian magnetic field lines. Limb glows distinct from the equatorial emissions were observed at visible to near-infrared wavelengths from 500 to 850 nm, indicating that atomic O, Na, and K are distributed across Io's surface. Stratification of the atmosphere is demonstrated by differences in the altitudes of emissions at various wavelengths: SO2 emissions are confined to a region close to Io's surface, whereas neutral oxygen emissions are seen at altitudes that reach up to 900 km, or half the radius of the satellite. Pre-egress brightening demonstrates that light scattered into Jupiter's shadow by gases or aerosols in the giant planet's upper atmosphere contaminates images of Io taken within 13 minutes of entry into or emergence from Jupiter's umbra. Although partial atmospheric collapse is suggested by the longer timescale for post-ingress dimming than pre-egress brightening, Io's atmosphere must be substantially supported by volcanism to retain auroral emissions throughout the duration of eclipse. ?? 2004 Elsevier Inc. All rights reserved.

Icarus↗

USGS2026

Mars as one system: Insights from the 8th international conference on Mars polar science and exploration

The 8th International Conference on Mars Polar Science and Exploration (ICMPSE) provided new insights into the complex interplay between Martian ice, climate, and atmospheric dynamics. The conference emphasized a holistic view of Mars as a system, where surface processes, subsurface ice, atmospheric dynamics, and historical climate shifts are interconnected. Research updates spanned cutting-edge remote sensing techniques and observations, terrestrial analog studies, and theoretical modeling, providing a multidimensional view of Mars' dynamic history and present-day activity. Numerous presentations highlighted the importance of understanding Mars as an integrated and dynamic system where surface and atmospheric processes interact over various timescales. This paper synthesizes unresolved questions and the major themes discussed, including mid-latitude glaciation, the evolution of the polar layered deposits (PLDs), terrestrial analog studies, climate modeling, and future mission planning. The findings contributed to refining models of Martian climate history, assessing the potential for extant life, and planning future human exploration. We also discuss the historical perspective of Mars Polar Science and new findings since the 7th conference in this series and anticipate the next four to 20 years of science on Mars related to ice, climate, and the atmosphere.

Icarus↗

USGS2009

Methane sources in gas hydrate-bearing cold seeps: Evidence from radiocarbon and stable isotopes

Fossil methane from the large and dynamic marine gas hydrate reservoir has the potential to influence oceanic and atmospheric carbon pools. However, natural radiocarbon ( 14 C) measurements of gas hydrate methane have been extremely limited, and their use as a source and process indicator has not yet been systematically established. In this study, gas hydrate-bound and dissolved methane recovered from six geologically and geographically distinct high-gas-flux cold seeps was found to be 98 to 100% fossil based on its 14 C content. Given this prevalence of fossil methane and the small contribution of gas hydrate (??? 1%) to the present-day atmospheric methane flux, non-fossil contributions of gas hydrate methane to the atmosphere are not likely to be quantitatively significant. This conclusion is consistent with contemporary atmospheric methane budget calculations. In combination with ?? 13 C- and ??D-methane measurements, we also determine the extent to which the low, but detectable, amounts of 14 C (~ 1-2% modern carbon, pMC) in methane from two cold seeps might reflect in situ production from near-seafloor sediment organic carbon (SOC). A 14 C mass balance approach using fossil methane and 14 C-enriched SOC suggests that as much as 8 to 29% of hydrate-associated methane carbon may originate from SOC contained within the upper 6??m of sediment. These findings validate the assumption of a predominantly fossil carbon source for marine gas hydrate, but also indicate that structural gas hydrate from at least certain cold seeps contains a component of methane produced during decomposition of non-fossil organic matter in near-surface sediment.

Marine Chemistry↗

USGS2022

Decadal trends of mercury cycling and bioaccumulation within Everglades National Park

Mercury (Hg) contamination has been a persistent concern in the Florida Everglades for over three decades due to elevated atmospheric deposition and the system's propensity for methylation and rapid bioaccumulation. Given declines in atmospheric Hg concentrations in the conterminous United States and efforts to mitigate nutrient release to the greater Everglades ecosystem, it was vital to assess how Hg dynamics responded on temporal and spatial scales. This study used a multimedia approach (water and biota) to examine Hg and methylmercury (MeHg) dynamics across a 76-site network within the southernmost portion of the region, Everglades National Park (ENP), from 2008 to 2018. Atmospheric Hg deposition was evaluated over time using a long-term monitoring station. Hg concentrations across matrices showed that air, water, and biota from the system were inextricably linked. Temporal patterns across matrices were driven primarily by hydrologic and climatic changes in the park and no evidence of a decline in atmospheric Hg deposition from 2008 to 2018 was observed, unlike other regions of the United States. In the Shark River Slough (SRS), excess dissolved organic carbon and sulfate were also consistently delivered from upgradient canals and showed no evidence of decline over the study period. Within the SRS a strong positive correlation was observed between MeHg concentrations in surface water and resident fish. Within distinct geographic regions of ENP (SRS, Marsh, Coastal), the geochemical controls on MeHg dynamics differed and highlighted regions susceptible to higher MeHg bioaccumulation, particularly in the SRS and Coastal regions. This study demonstrates the strong influence that dissolved organic carbon and sulfate loads have on spatial and temporal distributions of MeHg across the ENP. Importantly, improved water quality and flow rates are two key restoration targets of the nearly 30-year Everglades restoration program, which if achieved, this study suggests would lead to reduced MeHg production and exposure.

Florida↗

USGS1999

Metal emissions from Kilauea, and a suggested revision of the estimated worldwide metal output by quiescent degassing of volcanoes

Measurements of a large suite of metals (Pb, Cd, Cu, Zn and several others) and sulfur at Kilauea volcano over an extended period of time has yielded a detailed record of the atmospheric injection of ordinarily-rare metals from this quiescently degassing volcano, representative of an important type. We have combined the Kilauea data with data of recent studies by others (emissions from volcanoes in the Indonesian arc; the large Laki eruption of two centuries ago; Etna: estimates of total volcanic emissions of sulfur) to form the basis for a new working estimate of the rate of worldwide injection of metals to the atmosphere by volcanoes. The new estimate is that volcanoes inject a substantially smaller mass of ordinarily-rare metals into the atmosphere than was stated in a widely cited previous estimate [J.O. Nriagu, A global assessment of natural sources of atmospheric trace metals, Nature 338 (1989) 47-49]. Our estimate, which is an upper limit, is an annual injection mass of about 10,000 tons of the metals considered, versus the earlier estimate of about 23,000 tons. Also, the proportions of the metals are substantially different in our new estimate.

Earth and Planetary Science Letters↗

USGS2001

Cloud characterization and clear-sky correction from Landsat-7

Landsat, with its wide swath and high resolution, fills an important mesoscale gap between atmospheric variations seen on a few kilometer scale by local surface instrumentation and the global view of coarser resolution satellites such as MODIS. In this important scale range, Landsat reveals radiative effects on the few hundred-meter scale of common photon mean-free-paths, typical of scattering in clouds at conservative (visible) wavelengths, and even shorter mean-free-paths of absorptive (near-infrared) wavelengths. Landsat also reveals shadowing effects caused by both cloud and vegetation that impact both cloudy and clear-sky radiances. As a result, Landsat has been useful in development of new cloud retrieval methods and new aerosol and surface retrievals that account for photon diffusion and shadowing effects. This paper discusses two new cloud retrieval methods: the nonlocal independent pixel approximation (NIPA) and the normalized difference nadir radiance method (NDNR). We illustrate the improvements in cloud property retrieval enabled by the new low gain settings of Landsat-7 and difficulties found at high gains. Then, we review the recently developed “path radiance” method of aerosol retrieval and clear-sky correction using data from the Department of Energy Atmospheric Radiation Measurement (ARM) site in Oklahoma. Nearby clouds change the solar radiation incident on the surface and atmosphere due to indirect illumination from cloud sides. As a result, if clouds are nearby, this extra side-illumination causes clear pixels to appear brighter, which can be mistaken for extra aerosol or higher surface albedo. Thus, cloud properties must be known in order to derive accurate aerosol and surface properties. A three-dimensional (3D) Monte Carlo (MC) radiative transfer simulation illustrates this point and suggests a method to subtract the cloud effect from aerosol and surface retrievals. The main conclusion is that cloud, aerosol, and surface retrievals are linked and must be treated as a combined system. Landsat provides the range of scales necessary to observe the 3D cloud radiative effects that influence joint surface-atmospheric retrievals.

Remote Sensing of Environment↗