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A review of distributed parameter groundwater management modeling methods

Models which solve the governing groundwater flow or solute transport equations in conjunction with optimization techniques, such as linear and quadratic programing, are powerful aquifer management tools. Groundwater management models fall in two general categories: hydraulics or policy evaluation and water allocation. Groundwater hydraulic management models enable the determination of optimal locations and pumping rates of numerous wells under a variety of restrictions placed upon local drawdown, hydraulic gradients, and water production targets. Groundwater policy evaluation and allocation models can be used to study the influence upon regional groundwater use of institutional policies such as taxes and quotas. Furthermore, fairly complex groundwater-surface water allocation problems can be handled using system decomposition and multilevel optimization. Experience from the few real world applications of groundwater optimization-management techniques is summarized. Classified separately are methods for groundwater quality management aimed at optimal waste disposal in the subsurface. This classification is composed of steady state and transient management models that determine disposal patterns in such a way that water quality is protected at supply locations. Classes of research missing from the literature are groundwater quality management models involving nonlinear constraints, models which join groundwater hydraulic and quality simulations with political-economic management considerations, and management models that include parameter uncertainty.

Water Resources Research↗

Ground-water levels in the alluvial aquifer in eastern Arkansas, 1987

Groundwater level measurements of 516 wells that tap the alluvial aquifer in the Quaternary deposits of the Mississippi Alluvial Plain were made by U.S. Geological Survey and district Soil Conservation Service personnel during 1987. The shallowest prepumping water levels occurred in Ashley, Clay, Crittenden, Greene, Mississippi, Phillips, and Randolph Counties where water levels averaged less than 20 ft below the land surface. The deepest water levels occurred in Arkansas, Lonoke, Poinsett, and Prairie Counties where water levels of more than 100 ft below land surface were measured. Water levels in the postpumping season averaged about 3.3 ft lower than during the prepumping season. (USGS)

Open-File Report↗

Groundwater response to the 2014 pulse flow in the Colorado River Delta

During the March-May 2014 Colorado River Delta pulse flow, approximately 102 × 10 6 m 3 (82,000 acre-feet) of water was released into the channel at Morelos Dam, with additional releases further downstream. The majority of pulse flow water infiltrated and recharged the regional aquifer. Using groundwater-level and microgravity data we mapped the spatial and temporal distribution of changes in aquifer storage associated with pulse flow. Surface-water losses to infiltration were greatest around the Southerly International Boundary, where a lowered groundwater level owing to nearby pumping created increased storage potential as compared to other areas with shallower groundwater. Groundwater levels were elevated for several months after the pulse flow but had largely returned to pre-pulse levels by fall 2014. Elevated groundwater levels in the limitrophe (border) reach extended about 2 km to the east around the midway point between the Northerly and Southerly International Boundaries, and about 4 km to the east at the southern end. In the southern part of the delta, although total streamflow in the channel was less due to upstream infiltration, augmented deliveries through irrigation canals and possible irrigation return flows created sustained increases in groundwater levels during summer 2014. Results show that elevated groundwater levels and increases in groundwater storage were relatively short lived (confined to calendar year 2014), and that depressed water levels associated with groundwater pumping around San Luis, Arizona and San Luis Rio Colorado, Sonora cause large, unavoidable infiltration losses of in-channel water to groundwater in the vicinity.

Colorado River Basin↗

Occurrence of nitrous oxide in the central High Plains aquifer, 1999

Nitrogen-enriched groundwater has been proposed as an important anthropogenic source of atmospheric nitrous oxide (N2O), yet few measurements of N2O in large aquifer systems have been made. Concentrations of N2O in water samples collected from the 124 000 km2 central High Plains aquifer in 1999 ranged from < 1 to 940 nM, with a median concentration of 29 nM (n = 123). Eighty percent of the N20 concentrations exceeded the aqueous concentration expected from equilibration with atmospheric N2O. Measurements of N2O, NO3-, and 3H in unsaturated-zone sediments, recently recharged groundwater, and older groundwater indicate that concentrations of N2O in groundwater increased over time and will likely continue to increase in the future as N-enriched water recharges the aquifer. Large concentrations of O2 and NO3- and small concentrations of NH4+ and dissolved organic carbon in the aquifer indicate that N2O in the central High Plains aquifer was produced primarily by nitrification. Calculations indicate that the flux of N2O from the central High Plains aquifer to the atmosphere from well pumping and groundwater discharge to streams was not a significant source of atmospheric N2O.Nitrogen-enriched groundwater has been proposed as an important anthropogenic source of atmospheric nitrous oxide (N2O), yet few measurements of N2O in large aquifer systems have been made. Concentrations of N2O in water samples collected from the 124000 km2 central High Plains aquifer in 1999 ranged from < 1 to 940 nM, with a median concentration of 29 nM (n = 123). Eighty percent of the N2O concentrations exceeded the aqueous concentration expected from equilibration with atmospheric N2O. Measurements of N2O, NO3-, and 3H in unsaturated-zone sediments, recently recharged groundwater, and older groundwater indicate that concentrations of N2O in groundwater increased over time and will likely continue to increase in the future as N-enriched water recharges the aquifer. Large concentrations of O2 and NO3- and small concentrations of NH4+ and dissolved organic carbon in the aquifer indicate that N2O in the central High Plains aquifer was produced primarily by nitrification. Calculations indicate that the flux of N2O from the central High Plains aquifer to the atmosphere from well pumping and groundwater discharge to streams was not a significant source of atmospheric N2O.Water samples were collected from 92 domestic wells, 16 monitoring wells and 15 public-supply wells in the High Plains Aquifer in 1999, and concentrations of nitrous oxide were measured. The groundwater concentrations ranged from less than 1 to 940 nM. Concentrations expressed as a percent of saturation in water ranged from less than 10 to 9690%. A significant decrease was noted in N2O concentrations with increasing depth of the well screen below the water table, and a significant positive correlation was found between the concentrations of N2O and nitrate. The small area-averaged N2O emission rate for the aquifer indicated that it was not an important component of the atmospheric N2O budget, but the importance could increase as groundwater N2O concentrations increase.

Environmental Science & Technology↗

Quality of groundwater used for domestic supply in the eastern Sacramento Valley and adjacent foothills, California

Summary More than 2 million Californians rely on groundwater from privately owned domestic wells for drinking-water supply. This report summarizes a water-quality survey of domestic and small-system drinking-water supply wells in the eastern Sacramento Valley and adjacent foothills where more than 25,000 residents are estimated to use privately owned domestic wells. Study results show that inorganic and organic constituents in groundwater were present above regulatory (maximum contaminant level, MCL) benchmarks for public drinking-water quality in 8 and 3 percent, respectively, of the aquifer area used for domestic drinking-water supply (herein, “domestic groundwater resources”; fig. 1). The only inorganic constituent detected above regulatory benchmarks was arsenic. The only organic constituent exceeding regulatory benchmarks was the fumigant 1,2,3-trichloropropane (1,2,3-TCP). Three additional organic constituents—the disinfection by-product chloroform, the gasoline oxygenate methyl tert -butyl ether (MTBE), and the solvent tetrachloroethene (PCE)—were detected at low concentrations below one-tenth of regulatory benchmarks in 34, 10, and 10 percent of domestic groundwater resources, respectively. Total dissolved solids (TDS), iron, and manganese exceeded non-regulatory aesthetic guidelines for drinking water in 5, 10, and 26 percent of domestic groundwater resources, respectively. Per- and polyfluoroalkyl substances (PFASs) were detected in 29 percent of domestic groundwater resources,with 5 percent exceeding the recently enacted (April 2024) U.S. Environmental Protection Agency MCLs. Total coliform and enterococci bacteria were detected in 13 and 8 percent of domestic groundwater resources, respectively. Redox sensitive constituents in this study included arsenic, manganese, nitrate, and iron. In the lower elevation portions of the eastern Sacramento Valley study area, reducing conditions in groundwater aquifers promote elevated arsenic, iron, and manganese, and conversely lower concentrations of nitrate. The presence of the volatile organic compound (VOC) 1,2,3-TCP was related to its past history in select agricultural land uses (on orchards or vineyards) in the Sacramento Valley; however, unlike in the San Joaquin Valley where orchards and vineyards are more common, its detection frequency was low (only detected in one well in this study). Chloroform was frequently detected in this study at low levels. Chloroform is a disinfection byproduct commonly found in domestic wells treated by shock chlorination. The solvent PCE is among the most frequently detected VOCs in groundwater, which is primarily related to its long history of use and its persistence in groundwater in oxic conditions. The gasoline oxygenate MTBE was a contaminant introduced to groundwater through atmospheric exchange when it was used as a fuel additive to decrease smog inducing emissions from vehicles. Its occurrence in groundwater at low levels is expected and makes it a potentially useful tracer of relatively recent recharge water being withdrawn from wells. The PFASs are anthropogenic chemicals with hundreds of uses, and they have been incorporated into many different products, processes, and applications worldwide. Like MTBE, the occurrence of PFASs in groundwater may be in part due to atmospheric exchange, but there are several other pathways that contribute PFASs to the environment.

California↗

Characterization of the hydrologic resources of San Miguel County, New Mexico, and identification of hydrologic data gaps, 2011

The U.S. Geological Survey (USGS), in cooperation with San Miguel County, New Mexico, conducted a study to assess publicly available information regarding the hydrologic resources of San Miguel County and to identify data gaps in that information and hydrologic information that could aid in the management of available water resources. The USGS operates four continuous annual streamgages in San Miguel County. Monthly discharge at these streamgages is generally bimodally distributed, with most runoff corresponding to spring runoff and to summer monsoonal rains. Data compiled since 1951 on the geology and groundwater resources of San Miguel County are generally consistent with the original characterization of depth and availability of groundwater resources and of source aquifers. Subsequent exploratory drilling identified deep available groundwater in some locations. Most current (2011) development of groundwater resources is in western San Miguel County, particularly in the vicinity of El Creston hogback, the hogback ridge just west of Las Vegas, where USGS groundwater-monitoring wells indicate that groundwater levels are declining. Regarding future studies to address identified data gaps, the ability to evaluate and quantify surface-water resources, both as runoff and as potential groundwater recharge, could be enhanced by expanding the network of streamgages and groundwater-monitoring wells throughout the county. A series of seepage surveys along the lengths of the rivers could help to determine locations of surface-water losses to and gains from the local groundwater system and could help to quantify the component of streamflow attributable to irrigation return flow; associated synoptic water-quality sampling could help to identify potential effects to water quality attributable to irrigation return flow. Effects of groundwater withdrawals on streamflow could be assessed by constructing monitoring wells along transects between production wells and stream reaches of interest to monitor decline or recovery of the water table, to quantify the timing and extent of water-table response, and to identify the spatial extent of capture zones. Assessment of groundwater potential could be aided by a county-wide distribution of water-level information and by a series of maps of groundwater potential, compiled for each individual aquifer, including saline aquifers, for which the potential for municipal use through desalination could be explored. A county-wide geographic information system hydrologic geodatabase could provide a comprehensive picture of water use in San Miguel County and could be used by San Miguel County as a decision-support tool for future management decisions.

New Mexico↗

Use of geochemical, isotopic, and age tracer data to develop models of groundwater flow for the purpose of water management, northern High Plains aquifer, USA

A prolonged drought in the High Plains of Nebraska prompted the use of groundwater for cooling at the largest coal-fired power plant in the State. Prior to the drought, groundwater was used primarily for irrigation and the power plant relied exclusively on surface water stored in a nearby reservoir for cooling. Seepage from the reservoir system during the past ∼75 a has resulted in the buildup of a large mound of water in the underlying unconfined aquifer. A well field was installed during the drought for the purpose of tapping the groundwater mound as a supplemental source of water for cooling. Concentrations of dissolved Cl − and SO 4 2 - "> SO 4 2- indicate 65–100% of shallow groundwater and 0–100% of deep groundwater (saturated thickness ∼115 m) in the immediate vicinity of the reservoir was from seepage out of the reservoir system. Hydrogen and O isotopic data indicate most surface-water seepage occurred in the late spring and early summer when reservoir stage was at its highest level. Tritium/ 3 He apparent groundwater ages imply horizontal flow velocities from the reservoir were on the order of 60–600 m/a. These diverse data provided information regarding the spatial distribution, timing, and rate of seepage from the reservoir that could not have been obtained from the available geologic, hydraulic head, and conductivity data. In particular, mixing fractions of surface water and regional groundwater in the aquifer could not have been determined using hydraulic information. Mixing fractions were of special interest in this study because of the management objective to maximize the capture of surface-water seepage in the cooling water wells. Groundwater-flow models developed as well-field management tools were calibrated using inverse modeling techniques and observations of groundwater age, surface-water flow, reservoir stage, and groundwater levels. The age data only accounted for 6 of the 2574 field observations used to calibrate the groundwater-flow models, yet they were among the most influential for refining estimates of hydraulic conductivity, recharge, and seepage from the reservoir. Results from this study demonstrate the benefits of using geochemical, isotopic, and age tracer data to develop conceptual and numerical models of groundwater flow for the purpose of water management.

Nebraska↗

Geohydrology and water quality of the stratified-drift aquifers in Upper Buttermilk Creek and Danby Creek Valleys, Town of Danby, Tompkins County, New York

In 2006, the U.S. Geological Survey, in cooperation with the Town of Danby and the Tompkins County Planning Department, began a study of the stratified-drift aquifers in the upper Buttermilk Creek and Danby Creek valleys in the Town of Danby, Tompkins County, New York. In the northern part of the north-draining upper Buttermilk Creek valley, there is only one sand and gravel aquifer, a confined basal unit that overlies bedrock. In the southern part of upper Buttermilk Creek valley, there are as many as four sand and gravel aquifers, two are unconfined and two are confined. In the south-draining Danby Creek valley, there is an unconfined aquifer consisting of outwash and kame sand and gravel (deposited by glacial meltwaters during the late Pleistocene Epoch) and alluvial silt, sand, and gravel (deposited by streams during the Holocene Epoch). In addition, throughout the study area, there are several small local unconfined aquifers where large tributaries deposited alluvial fans in the valley. The principal sources of recharge to the unconfined aquifers in the study area include direct infiltration of precipitation (rain and snowmelt) at land surface, unchanneled surface runoff from adjacent hillsides that seeps into the aquifer along the edges of the valley, groundwater inflow from adjacent till and bedrock that enters the aquifer along the sides of the valley, and seepage loss from upland-tributary streams where they flow over their alluvial fans in the valley. The percentages of all sources of recharge to the contiguous unconfined aquifer in Danby Creek valley include 16 percent from precipitation that falls directly over the aquifer, 55 percent from unchanneled surface runoff and groundwater inflow from hillsides, and 29 percent from losing tributary streams that cross the aquifer. The total annual recharge to the contiguous unconfined aquifer is 2.56 cubic feet per second (604 million gallons per year). The principal sources of recharge to the confined aquifers include precipitation that falls directly on the surficial confining unit, which then slowly flows vertically downward through the fine-grained sediments and enters the confined aquifer, and groundwater inflow from till and bedrock that borders the aquifer along adjacent hillsides and at the bottom of the valley. In addition, there is substantial amounts of recharge to the confined aquifers where the confining units are locally absent (forming windows) and where parts of the confining units consist of sediments of low to moderate permeability (forming a semiconfining layer). In the northern part of the study area (upper Buttermilk Creek valley), groundwater in the stratified-drift aquifers discharges to (1) domestic and commercial wells; (2) Buttermilk Creek in the area near the northern town border, and (3) and a small unnamed stream in a ravine in Buttermilk State Park just north of the town border. In the southern part of the study area (Danby Creek valley), groundwater discharges (1) to domestic, commercial, and farm wells; (2) to Danby Creek; (3) to a large wetland in the central parts of Danby Creek valley; and (4) as losses because of plant uptake and evaporation. About 300 people depend on groundwater from the upper Buttermilk Creek and Danby Creek stratified-drift aquifer system. An unconfined surficial aquifer about 8,000 feet (ft) long and as much as 800 ft wide, with a saturated thickness of about 20 ft, occupies the lower (southeastern most) 8,000 ft of Danby Creek valley within the Town of Danby. However, because the aquifer is thin, the volume of water stored in the aquifer is small and the potential for induced recharge from Danby Creek during summer periods of low flow is also small, an array of wells would probably be needed to provide sustainable continuous amount of water to large water users such as municipalities and industries. Additional data and a groundwater flow model would be required to estimate sustainable withdrawal from the confined aquifers in upper Buttermilk Creek valley. Well data from water-well drillers through 2012 indicate that the confined aquifers in upper Buttermilk Creek valley are thin (typically about 10 feet thick) and the reported well-yield data suggest these aquifers may not be capable of supplying sufficient water to meet the needs of municipalities and industries. However, additional geohydrologic data leading to calibration of a groundwater flow model would be needed to properly evaluate the long-term (multiple years) potential yield of the confined aquifer system in upper Buttermilk Creek valley and of the unconfined aquifer in Danby Creek valley. During 2007&ndash;10, groundwater samples were collected from 13 wells including 7 wells that are completed in the confined sand and gravel aquifers, 1 well that is completed in the unconfined aquifer, and 5 wells that are completed in the bedrock aquifers. Calcium dominates the cation composition and bicarbonate dominates the anion composition in most groundwater. Water quality in the study area generally meets state and Federal drinking-water standards but concentrations of some constituents exceeded the standards. The standards that were exceeded include sodium (3 samples), dissolved solids (1 sample), iron (3 samples), manganese (8 samples), and arsenic (1 sample).

New York↗

Continuous resistivity profiling to delineate submarine groundwater discharge - Examples and limitations

Aquifer-ocean interaction, saline intrusion, and submarine groundwater discharge (SGD) are emerging topics in hydrology and oceanography with important implications for water-resource management and estuarine ecology. Although the threat of saltwater intrusion has long been recognized in coastal areas, SGD has, until recently, received much less attention. It is clear that SGD constitutes a major nutrient flux to coastal waters, with implications for estuarine ecology, eutrophication, and loss of coral reefs; however, fundamental questions regarding SGD remain unanswered: What are the spatial and temporal distributions of SGD offshore? How do seasonal and storm-related variations in aquifer recharge affect SGD flux and nutrient loading? What controls do aquifer structure and heterogeneity impose? How are SGD and saline recirculation related? Geophysical methods can provide insights to help answer these questions and improve the understanding of this intriguing and environmentally relevant hydrologic phenomenon.

Leading Edge (Tulsa, OK)↗

Groundwater-quality data in the Bear Valley and Selected Hard Rock Areas study unit, 2010: Results from the California GAMA Program

Groundwater quality in the 112-square-mile Bear Valley and Selected Hard Rock Areas (BEAR) study unit was investigated by the U.S. Geological Survey (USGS) from April to August 2010, as part of the California State Water Resources Control Board (SWRCB) Groundwater Ambient Monitoring and Assessment (GAMA) Program’s Priority Basin Project (PBP). The GAMA-PBP was developed in response to the California Groundwater Quality Monitoring Act of 2001 and is being conducted in collaboration with the SWRCB and Lawrence Livermore National Laboratory (LLNL). The BEAR study unit was the thirty-first study unit to be sampled as part of the GAMA-PBP. The GAMA Bear Valley and Selected Hard Rock Areas study was designed to provide a spatially unbiased assessment of untreated-groundwater quality in the primary aquifer system and to facilitate statistically consistent comparisons of untreated groundwater quality throughout California. The primary aquifer system is defined as the zones corresponding to the perforation intervals of wells listed in the California Department of Public Health (CDPH) database for the BEAR study unit. Groundwater quality in the primary aquifer system may differ from the quality in the shallow or deep water-bearing zones; shallow groundwater may be more vulnerable to surficial contamination. In the BEAR study unit, groundwater samples were collected from two study areas (Bear Valley and Selected Hard Rock Areas) in San Bernardino County. Of the 38 sampling sites, 27 were selected by using a spatially distributed, randomized grid-based method to provide statistical representation of the primary aquifer system in the study unit (grid sites), and the remaining 11 sites were selected to aid in the understanding of the potential groundwater-quality issues associated with septic tank use and with ski areas in the study unit (understanding sites). The groundwater samples were analyzed for organic constituents (volatile organic compounds [VOCs], pesticides and pesticide degradates, pharmaceutical compounds, and wastewater indicator compounds [WICs]), constituents of special interest (perchlorate, N-nitrosodimethylamine [NDMA], and 1,2,3-trichloropropane [1,2,3-TCP]), and inorganic constituents (trace elements, nutrients, dissolved organic carbon [DOC], major and minor ions, silica, total dissolved solids [TDS], alkalinity, and arsenic and iron species), and uranium and other radioactive constituents (radon-222 and activities of tritium and carbon-14). Isotopic tracers (of hydrogen and oxygen in water, of nitrogen and oxygen in dissolved nitrate, of dissolved boron, isotopic ratios of strontium in water, and of carbon in dissolved inorganic carbon) and dissolved noble gases (argon, helium-4, krypton, neon, and xenon) were measured to help identify the sources and ages of sampled groundwater. In total, groundwater samples were analyzed for 289 unique constituents and 8 water-quality indicators in the BEAR study unit. Quality-control samples (blanks, replicate pairs, or matrix spikes) were collected at 13 percent of the sites in the BEAR study unit, and the results for these samples were used to evaluate the quality of the data from the groundwater samples. Blank samples rarely contained detectable concentrations of any constituent, indicating that contamination from sample collection or analysis was not a significant source of bias in the data for the groundwater samples. Replicate pair samples all were within acceptable limits of variability. Matrix-spike sample recoveries were within the acceptable range (70 to 130 percent) for approximately 84 percent of the compounds. This study did not evaluate the quality of water delivered to consumers. After withdrawal, groundwater typically is treated, disinfected, and (or) blended with other waters to maintain water quality. Regulatory benchmarks apply to water that is delivered to the consumer, not to untreated groundwater. However, to provide some context for the results, concentrations of constituents measured in the untreated groundwater were compared with regulatory and non-regulatory health-based benchmarks established by the U.S. Environmental Protection Agency (USEPA) and CDPH, and to non-health-based benchmarks established for aesthetic concerns by CDPH. Comparisons between data collected for this study and benchmarks for drinking water are for illustrative purposes only and are not indicative of compliance or non-compliance with those benchmarks. All concentrations of organic and special-interest constituents from grid sites sampled in the BEAR study unit were less than health-based benchmarks. In total, VOCs were detected in 17 of the 27 grid sites sampled (approximately 63 percent), pesticides and pesticide degradates were detected in 4 grid sites (approximately 15 percent), and perchlorate was detected in 21 grid sites (approximately 78 percent). Inorganic constituents (trace elements, major and minor ions, nutrients, and uranium and other radioactive constituents) were sampled for at 27 grid sites; most concentrations were less than health-based benchmarks. Exceptions include one detection of arsenic greater than the USEPA maximum contaminant level (MCL-US) of 10 micrograms per liter (μg/L), three detections of uranium greater than the MCL-US of 30 μg/L, nine detections of radon-222 greater than the proposed MCL-US of 4,000 picocuries per liter (pCi/L), and one detection of fluoride greater than the CDPH maximum contaminant level (MCL-CA) of 2 milligrams per liter. Concentrations of inorganic constituents with non-health-based benchmarks (iron, manganese, chloride, and TDS) were less than the CDPH secondary maximum contaminant level (SMCL-CA) in most grid sites. Exceptions include two detections of iron greater than the SMCL-CA of 300 μg/L and one detection of manganese greater than the SMCL-CA of 50 μg/L.

California↗

Measuring and interpreting multilayer aquifer-system compactions for a sustainable groundwater-system development

Ever decreasing water resources and climate change have driven the increasing use of groundwater causing land subsidence in many countries. Geodetic sensors such as InSAR, GPS and leveling can detect surface deformation but cannot measure subsurface deformation. A single‐well, single‐depth extensometer can be used to measure subsurface deformation, but it cannot delineate the depths of major compaction and provide insight about the deformation mechanism throughout a complex aquifer system, unless man extensometers at different depths are used. We present a multilayer compaction well (MLCW), installed in a borehole, that uses magnetic rings to detect stratum compaction at 25 depths as deep as 300 m below land surface. Our laboratory and field assessments indicate 1 mm precision and accuracy for one single‐depth magnetic reading. We tested the performance of MLCW by measuring aquifer‐system compaction over the proximal, middle, and distal fans of the Choushui River Alluvial Fan (CRAF) that has long experienced severe land subsidence. The MLCW measurements were used to create time‐depth diagrams of compaction, showing different compaction rates at different layers of aquifers and aquitards to identify the depths of major compactions. The elastic (reversible) and inelastic (irreversible) compactions from MLCW were used in stress‐strain analyses to estimate skeletal specific storages and the safe groundwater levels, below which groundwater extractions have caused irreversible compactions. The hydrogeological parameters derived from MLCW measurements can help governmental agencies to determine effective land‐use and water‐use policies, and ascertain the best strategy for utilizing artificial recharge to prevent land subsidence and achieve sustainable groundwater management.

Water Resources Research↗

Spatially distributed groundwater recharge for 2010 land cover estimated using a water-budget model for the Island of O‘ahu, Hawai‘i

Owing mainly to projected population growth, demand for freshwater on the Island of Oʻahu is expected to increase by about 26 percent between 2010 and 2030, according to the City and County of Honolulu. Estimates of groundwater recharge are needed to evaluate the availability of fresh groundwater. For this study, a water-budget model with a daily computation interval was developed and used to estimate the spatial distribution of recharge on Oʻahu for average climate conditions (1978–2007 rainfall and 2010 land cover) and for drought conditions (1998–2002 rainfall and 2010 land cover). For average climate conditions, mean annual recharge for Oʻahu is about 660 million gallons per day, or about 36 percent of precipitation (rainfall and fog interception). Recharge for average climate conditions is about 34 percent of total water inflow, which consists of precipitation, irrigation, septic leachate, water-main leakage, and seepage from reservoirs and cesspools. Recharge is high along the crest of the Koʻolau Range, reaching as much as about 180 inches per year in the north-central part of the range. Recharge is much lower outside of the mountainous areas of the island, commonly less than 5 inches per year in unirrigated areas. The island-wide estimate of groundwater recharge for average climate conditions from this study is within 1 percent of the recharge estimate used in the 2008 State of Hawaiʻi Water Resource Protection Plan, which divides the Island of Oʻahu into 23 aquifer systems for groundwater management purposes. To facilitate direct comparisons with this study, these 23 aquifer systems were consolidated into 21 aquifer systems. Recharge estimates from this study are higher for 12 of the aquifer-system areas and lower for 9. Differences in mean rainfall distribution and the inclusion of irrigation in this study are the primary reasons for discrepancies in recharge estimates between this study and the 2008 Hawaiʻi Water Resources Protection Plan. For drought conditions, mean annual recharge for Oʻahu is about 417 million gallons per day, which is about 37 percent less than recharge for average climate conditions. For individual aquifer-system areas, recharge for drought conditions is about 25 to 70 percent less than recharge for average climate conditions.

Hawai'i↗

Apparent chlorofluorocarbon age of ground water of the shallow aquifer system, Naval Weapons Station Yorktown, Yorktown, Virginia

Apparent ages of ground water are useful in the analysis of various components of flow systems, and results of this analysis can be incorporated into investigations of potential pathways of contaminant transport. This report presents the results of a study in 1997 by the U.S. Geological Survey (USGS), in cooperation with the Naval Weapons Station Yorktown, Base Civil Engineer, Environmental Directorate, to describe the apparent age of ground water of the shallow aquifer system at the Station. Chlorofluorocarbons (CFCs), tritium ( 3 H), dissolved gases, stable isotopes, and water-quality field properties were measured in samples from 14 wells and 16 springs on the Station in March 1997. Nitrogen-argon recharge temperatures range from 5.9°C to 17.3°C with a median temperature of 10.9°C, which indicates that ground-water recharge predominantly occurs in the cold months of the year. Concentrations of excess air vary depending upon geohydrologic setting (recharge and discharge areas). Apparent ground-water ages using a CFC-based dating technique range from 1 to 48 years with a median age of 10 years. The oldest apparent CFC ages occur in the upper parts of the Yorktown-Eastover aquifer, whereas the youngest apparent ages occur in the Columbia aquifer and the upper parts of the discharge area setting, especially springs. The vertical distribution of apparent CFC ages indicates that groundwater movement between aquifers is somewhat retarded by the leaky confining units, but the elapsed time is relatively short (generally less than 35 years), as evidenced by the presence of CFCs at depth. The identification of binary mixtures by CFC-based dating indicates that convergence of flow lines occurs not only at the actual point of discharge, but also in the subsurface. The CFC-based recharge dates are consistent with expected 3 H concentrations measured in the water samples from the Station. The concentration of 3H in ground water ranges from below the USGS laboratory minimum reporting limit of 0.3 to 15.9 tritium units (TU) with a median value of 10.8 TU. Water-quality field properties are highly variable for ground water with apparent CFC ages less than 15 years because of geochemical processes within local flow systems. Ground water with apparent CFC ages greater than 15 years represents more stable conditions in subregional flow systems. The range of apparent CFC ages is slightly greater than the ranges in time of travel of ground water calculated for shallow wells (less than 60- feet deep) from flow-path analysis. Calculated travel times to springs can be up to two orders of magnitude greater than the CFC-based apparent ages. Reasonable assumptions of values for hydraulic parameters can result in substantial overestimates for time of travel to springs. Recharge rates computed from apparent CFC ages range from 0.29 to 0.89 feet per year (ft/ yr) with an average value of 0.54 ft/yr. The analysis of apparent CFC ages in conjunction with geohydrologic data indicates that young water (less than 50 years) is present at depth (nearly 120 feet) and that both local and subregional flow systems occur in the shallow aquifer system at the Station. The addition of the dimension of time to the three-dimensional framework of Brockman and others (1997) will benefit current (2001) and future remediation activities by providing estimates of advective transport rates and how these rates vary depending upon geohydrologic setting and position within the ground-water-flow system. Estimated ground-water apparent ages and recharge rates can be used as calibration criteria in simulations of ground-water flow on the Station to refine and constrain future ground-water-flow models of the shallow aquifer system.

Virginia↗

Preliminary assessment of water quality in the alluvial aquifer of the Puerco River basin, Northeastern Arizona

The quality of groundwater in the alluvial aquifer of the Puerco River basin, northeastern Arizona, was evaluated in order to assess potential contamination from uranium mining and milling operations in New Mexico. A total of 14 wells and 1 spring were sampled to determine if a contaminant plume of radionuclides or trace elements is present. The water is characterized by high dissolved solids with a median of 698 mg/l and high concentrations of alkalinity, sodium, and sulfate. Except for iron, manganese, and strontium, the concentrations of trace elements generally are below the applicable EPA and State of Arizona maximum contaminant levels. Gross alpha activity has a median of 27 picocuries/l and ranges from 4 to 42 picocuries/l. Uranium, which accounts for most of the gross alpha activity, has a median concentration of 19 micrograms/l and ranges from 1 to 38 micrograms/l. Twenty percent to 84% of the gross alpha activity was derived from other undetermined radionuclides. Other radionuclides, including radium-226 and radium-228, generally are not present in activities > 5 picocuries/l in the water. Statistical analysis of the water quality data suggest that no contaminant plume can be defined on the basis of samples from existing wells. The contamination in the alluvial aquifer apparently does not change in the downstream direction along the Puerco River. The geochemistry of radionuclides indicates that most radionuclides from the uranium-decay series are immobile or only slightly mobile, whereas uranium will not precipitate out of solution but may be removed by sorption in the alluvial aquifer. (Author 's abstract)

Water-Resources Investigations Report↗

Hydrologic and water-quality conditions in the lower Apalachicola-Chattahoochee-Flint and parts of the Aucilla-Suwannee-Ochlockonee River basins in Georgia and adjacent parts of Florida and Alabama during drought conditions, July 2011

As part of the U.S. Department of the Interior sustainable water strategy, WaterSMART, the U.S. Geological Survey documented hydrologic and water-quality conditions in the lower Apalachicola-Chattahoochee-Flint and western and central Aucilla-Suwannee-Ochlockonee River basins in Alabama, Florida, and Georgia during low-flow conditions in July 2011. Moderate-drought conditions prevailed in this area during early 2011 and worsened to exceptional by June, with cumulative rainfall departures from the 1981-2010 climate normals registering deficits ranging from 17 to 27 inches. As a result, groundwater levels and stream discharges measured below median daily levels throughout most of 2011. Water-quality field properties including temperature, dissolved oxygen, specific conductance, and pH were measured at selected surface-water sites. Record-low groundwater levels measured in 12 of 43 surficial aquifer wells and 128 of 312 Upper Floridan aquifer wells during July 2011 underscored the severity of drought conditions in the study area. Most wells recorded groundwater levels below the median daily statistic, and 7 surficial aquifer wells were dry. Groundwater-level measurements taken in July 2011 were used to determine the potentiometric surface of the Upper Floridan aquifer. Groundwater generally flows to the south and toward streams except in reaches where streams discharge to the aquifer. The degree of connection between the Upper Floridan aquifer and streams decreases east of the Flint River where thick overburden hydraulically separates the aquifer from stream interaction. Hydraulic separation of the Upper Floridan aquifer from streams located east of the Flint River is shown by stream-stage altitudes that differ from groundwater levels measured in close proximity to streams. Most streams located in the study area during 2011 exhibited below normal flows (streamflows less than the 25th percentile), substantiating the severity of drought conditions that year. Streamflow and springflow measured at 202 sites along 2,122 stream miles during July 20-24, 2011, identified about 286 miles of losing streams, about 1,230 miles of gaining streams, and about 606 miles of streams with no flow. Water-quality field properties measured at 123 stream and 5 spring sites during July 2011 yielded water temperatures ranging from 20.6 to 31.6 degrees Celsius, dissolved oxygen ranging from 0.47 to 9.98 milligrams per liter, specific conductance ranging from 13 to 834 microsiemens per centimeter at 25 degrees Celsius, and pH ranging from 3.6 to 8.03.

Alabama, Florida, Georgia↗

Water resources of Rockland County, New York, 2005-07, with emphasis on the Newark Basin Bedrock Aquifer

Concerns over the state of water resources in Rockland County, NY, prompted an assessment of current (2005-07) conditions. The investigation included a review of all water resources but centered on the Newark basin aquifer, a fractured-bedrock aquifer over which nearly 300,000 people reside. Most concern has been focused on this aquifer because of (1) high summer pumping rates, with occasional entrained-air problems and an unexplained water-level decline at a monitoring well, (2) annual withdrawals that have approached or even exceeded previous estimates of aquifer recharge, and (3) numerous contamination problems that have caused temporary or long-term shutdown of production wells. Public water supply in Rockland County uses three sources of water in roughly equal parts: (1) the Newark basin sedimentary bedrock aquifer, (2) alluvial aquifers along the Ramapo and Mahwah Rivers, and (3) surface waters from Lake DeForest Reservoir and a smaller, new reservoir supply in the Highlands part of the county. Water withdrawals from the alluvial aquifer in the Ramapo River valley and the Lake DeForest Reservoir are subject to water-supply application permits that stipulate minimum flows that must be maintained downstream into New Jersey. There is a need, therefore, at a minimum, to prevent any loss of the bedrock-aquifer resource--to maintain it in terms of both sustainable use and water-quality protection. The framework of the Newark basin bedrock aquifer included characterization of (1) the structure and fracture occurrence associated with the Newark basin strata, (2) the texture and thickness of overlying glacial and alluvial deposits, (3) the presence of the Palisades sill and associated basaltic units on or within the Newark basin strata, and (4) the streams that drain the aquifer system. The greatest concern regarding sustainability of groundwater resources is the aquifer response to the seasonal increase in pumping rates from May through October (an average increase of 25 percent in 2005). In most cases, pump rates would have to be reduced as aquifer yield declines. This analysis underlines the fragility of the aquifer given the fact that recent years (2003-06) have been relatively wet. Impervious surfaces increase the amount of stormflow and decrease the amount of base flow in streams. Analysis of stormflows in watersheds with 11.9 and 17 percent impervious surface area increased the percentage of rainfall that becomes stormflow in streams by 7 to 8 percent and by 12.5 to 16.5 percent, respectively. Recharge was estimated from streamflow data and from groundwater-level data. Estimates from across the county in 1961 ranged from 24.8 inches in the northwest (New York Highlands area) to 14.7 inches in the southeast. Water budgets were generated for three basins with streamflow data. During 1959-94 and in 2006, groundwater pumpage for public supply accounted for 12 to 24 percent of recharge within the Mahwah River near Suffern, NY, watershed. Public-supply pumpage as a percentage of recharge in 2006 at the two other currently gaged watersheds (Pascack Brook and Saddle River) was 18 and 21 percent, respectively. About 12.9 billion gallons of water was used in Rockland County in 2005. The majority (63 percent) was for base-line domestic supply (non-growing season rates of use); of this amount, about 6 percent was from domestic wells and 94 percent was from production wells and reservoirs. Commercial, industrial, and institutional users made up 10 percent of total water use, and growing-season increases accounted for 18 percent. Sanitary sewers serve much of Rockland County and the majority of treated wastewater is discharged to the Hudson River, which is an estuary with brackish water adjacent to Rockland County. Inflow of stormwater and infiltration of groundwater constitute a significant additional contribution of water to the sanitary sewer system.

Scientific Investigations Report↗

Hydrogeologic Framework, Groundwater Movement, and Water Budget in Tributary Subbasins and Vicinity, Lower Skagit River Basin, Skagit and Snohomish Counties, Washington

A study to characterize the groundwater-flow system in four tributary subbasins and vicinity of the lower Skagit River basin was conducted by the U.S. Geological Survey to assist Skagit County and the Washington State Department of Ecology in evaluating the effects of potential groundwater withdrawals and consumptive use on tributary streamflows. This report presents information used to characterize the groundwater and surface-water flow system in the subbasins, and includes descriptions of the geology and hydrogeologic framework of the subbasins; groundwater recharge and discharge; groundwater levels and flow directions; seasonal groundwater-level fluctuations; interactions between aquifers and the surface-water system; and a water budget for the subbasins. The study area covers about 247 mi2 along the Skagit River and its tributary subbasins (East Fork Nookachamps Creek, Nookachamps Creek, Carpenter Creek, and Fisher Creek) in southwestern Skagit County and northwestern Snohomish County, Washington. The geology of the area records a complex history of accretion along the continental margin, mountain building, deposition of terrestrial and marine sediments, igneous intrusion, and the repeated advance and retreat of continental glaciers. A simplified surficial geologic map was developed from previous mapping in the area, and geologic units were grouped into nine hydrogeologic units consisting of aquifers and confining units. A surficial hydrogeologic unit map was constructed and, with lithologic information from 296 drillers'logs, was used to produce unit extent and thickness maps and four hydrogeologic sections. Groundwater in unconsolidated aquifers generally flows towards the northwest and west in the direction of the Skagit River and Puget Sound. This generalized flow pattern is likely complicated by the presence of low-permeability confining units that separate discontinuous bodies of aquifer material and act as local groundwater-flow barriers. Groundwater-flow directions in the sedimentary aquifer likely reflect local topographic relief (radial flow from bedrock highs) and more regional westward flow from the mountains to the Puget Sound. The largest groundwater-level fluctuations observed during the monitoring period (October 2006 through September 2008) occurred in wells completed in the sedimentary aquifer, and ranged from about 3 to 27 feet. Water levels in wells completed in unconsolidated hydrogeologic units exhibited seasonal variations ranging from less than 1 to about 10 feet. Synoptic streamflow measurements made in August 2007 and June 2008 indicate a total groundwater discharge to creeks in the tributary subbasin area of about 13.15 and 129.6 cubic feet per second (9,520 and 93,830 acre-feet per year), respectively. Streamflow measurements illustrate a general pattern in which the upper reaches of creeks in the study area tended to gain flow from the groundwater system, and lower creek reaches tended to lose water. Large inflows from tributaries to major creeks in the study area suggest the presence of groundwater discharge from upland areas underlain by bedrock. The groundwater system within the subbasins received an average (September 1, 2006 to August 31, 2008) of about 92,400 acre-feet or about 18 inches of recharge from precipitation a year. Most of this recharge (65 percent) discharges to creeks, and only about 3 percent is withdrawn from wells. The remaining groundwater recharge (32 percent) leaves the subbasin groundwater system as discharge to the Skagit River and Puget Sound.

Scientific Investigations Report↗

Groundwater-quality data in the Klamath Mountains study unit, 2010: results from the California GAMA Program

Groundwater quality in the 8,806-square-mile Klamath Mountains (KLAM) study unit was investigated by the U.S. Geological Survey (USGS) from October to December 2010, as part of the California State Water Resources Control Board (SWRCB) Groundwater Ambient Monitoring and Assessment (GAMA) Program’s Priority Basin Project (PBP). The GAMA-PBP was developed in response to the California Groundwater Quality Monitoring Act of 2001 and is being conducted in collaboration with the SWRCB and Lawrence Livermore National Laboratory (LLNL). The KLAM study unit was the thirty-third study unit to be sampled as part of the GAMA-PBP. The GAMA Klamath Mountains study was designed to provide a spatially unbiased assessment of untreated-groundwater quality in the primary aquifer system and to facilitate statistically consistent comparisons of untreated-groundwater quality throughout California. The primary aquifer system is defined by the perforation intervals of wells listed in the California Department of Public Health (CDPH) database for the KLAM study unit. Groundwater quality in the primary aquifer system may differ from the quality in the shallower or deeper water-bearing zones; shallower groundwater may be more vulnerable to surficial contamination. In the KLAM study unit, groundwater samples were collected from sites in Del Norte, Siskiyou, Humboldt, Trinity, Tehama, and Shasta Counties, California. Of the 39 sites sampled, 38 were selected by using a spatially distributed, randomized grid-based method to provide statistical representation of the primary aquifer system in the study unit (grid sites), and the remaining site was non-randomized (understanding site). The groundwater samples were analyzed for basic field parameters, organic constituents (volatile organic compounds [VOCs] and pesticides and pesticide degradates), inorganic constituents (trace elements, nutrients, major and minor ions, total dissolved solids [TDS]), radon-222, gross alpha and gross beta radioactivity, and microbial indicators (total coliform and Escherichia coli [E. coli]). Isotopic tracers (stable isotopes of hydrogen and oxygen in water, isotopic ratios of dissolved strontium in water, and stable isotopes of carbon in dissolved inorganic carbon), dissolved noble gases, and age-dating tracers (tritium and carbon-14) were measured to help identify sources and ages of sampled groundwater. Quality-control samples (field blanks, replicate sample pairs, and matrix spikes) were collected at 13 percent of the sites in the KLAM study unit, and the results were used to evaluate the quality of the data from the groundwater samples. Field blank samples rarely contained detectable concentrations of any constituent, indicating that contamination from sample collection or analysis was not a significant source of bias in the data for the groundwater samples. More than 99 percent of the replicate pair samples were within acceptable limits of variability. Matrix-spike sample recoveries were within the acceptable range (70 to 130 percent) for approximately 91 percent of the compounds. This study did not evaluate the quality of water delivered to consumers. After withdrawal, groundwater typically is treated, disinfected, and (or) blended with other waters to maintain water quality. Regulatory benchmarks apply to water that is delivered to the consumer, not to untreated groundwater. However, to provide some context for the results, concentrations of constituents measured in the untreated groundwater were compared with regulatory and non-regulatory health-based benchmarks established by the U.S. Environmental Protection Agency (USEPA) and CDPH, and to non-health-based benchmarks established for aesthetic concerns by the CDPH. Comparisons between data collected for this study and benchmarks for drinking water are for illustrative purposes only and are not indicative of compliance or non-compliance with those benchmarks. All concentrations of organic constituents from grid sites sampled in the KLAM study unit were less than health-based benchmarks. In total, VOCs were detected in 16 of the 38 grid sites sampled (approximately 42 percent), pesticides and pesticide degradates were detected in 8 grid sites (about 21 percent), and microbial indicators were detected in 14 grid sites (approximately 37 percent). Inorganic constituents (trace elements, major and minor ions, nutrients, and uranium and other radioactive constituents) and microbial indicators were sampled for at 38 grid sites, and all concentrations were less than health-based benchmarks, with the exception of one detection of boron greater than the CDPH notification level of 1,000 micrograms per liter (μg/L). Generally, concentrations of inorganic constituents with non-health-based benchmarks (iron, manganese, chloride, and TDS) were less than the CDPH secondary maximum contaminant level (SMCL-CA). Exceptions include three detections of iron greater than the SMCL-CA of 300 μg/L, four detections of manganese greater than the SMCL-CA of 50 μg/L, one detection of chloride greater than the recommended SMCL-CA of 250 μg/L, and one detection of TDS greater than the recommended SMCL-CA of 500 μg/L.

California↗