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578 records · Page 33Linked to original sources
USGS1993

Ground-water-quality assessment of the Central Oklahoma Aquifer, Oklahoma: Geochemical and geohydrologic investigations

The National Water-Quality Assessment pilot project for the Central Oklahoma aquifer examined the chemical and isotopic composition of ground water, the abundances and textures of minerals in core samples, and water levels and hydraulic properties in the flow system to identify geochemical reactions occurring in the aquifer and rates and directions of ground-water flow. The aquifer underlies 3,000 square miles of central Oklahoma and consists of Permian red beds, including parts of the Permian Garber Sandstone, Wellington Formation, and Chase, Council Grove, and Admire Groups, and Quaternary alluvium and terrace deposits. In the part of the Garber Sandstone and Wellington Formation that is not confined by the Permian Hennessey Group, calcium, magnesium, and bicarbonate are the dominant ions in ground water; in the confined part of the Garber Sandstone and Wellington Formation and in the Chase, Council Grove, and Admire Groups, sodium and bicarbonate are the dominant ions in ground water. Nearly all of the Central Oklahoma aquifer has an oxic or post-oxic environment as indicated by the large dissolved concentrations of oxygen, nitrate, arsenic(V), chromium(VI), selenium(VI), vanadium, and uranium. Sulfidic and methanic environments are virtually absent. Petrographic textures indicate dolomite, calcite, sodic plagioclase, potassium feldspars, chlorite, rock fragments, and micas are dissolving, and iron oxides, manganese oxides, kaolinite, and quartz are precipitating. Variations in the quantity of exchangeable sodium in clays indicate that cation exchange is occurring within the aquifer. Gypsum may dissolve locally within the aquifer, as indicated by ground water with large concentra-tions of sulfate, but gypsum was not observed in core samples. Rainwater is not a major source for most elements in ground water, but evapotranspiration could cause rainwater to be a significant source of potassium, sulfate, phosphate and nitrogen species. Brines derived from seawater are the most likely source of bromide and chloride in the aquifer. The dominant reaction in recharge is the uptake of carbon dioxide gas from the unsaturated zone (about 2.0 to 4.0 millimoles per liter) and the dissolution of dolomite (about 0.3 to 1.0 millimoles per liter). This reaction generates calcium, magnesium, and bicarbonate water composition. If dolomite does not dissolve to equilibrium, pH values range from 6.0 to 7.3; if dolomite dissolves to equilibrium, pH values are about 7.5. By the time recharge enters the deeper flow system, all ground water is saturated or supersaturated with dolomite and calcite. After carbonate-mineral equilibration has occurred, cation exchange of calcium and magnesium for sodium is the dominant geochemical reaction, which occurs to a substantial extent only in parts of the aquifer. Mass transfers of cation exchange greater than 2.0 millimoles per liter occur in the confined part of the Garber Sandstone and Wellington Formation and in parts of the Chase, Council Grove, and Admire Groups. Associated with cation exchange is dissolution of small quantities of dolomite, calcite, biotite, chlorite, plagioclase, or potassium feldspar, which produces pH values that range from 8.6 to 9.1. Large tritium concentrations indicate ground-water ages of less than about 40 years for most samples of recharge. Carbon-14 ages for samples from the unconfined aquifer generally are less than 10,000 years. Carbon-14 ages of ground water in the confined part of the aquifer range from about 10,000 to 30,000 years or older. These ages produce a time trend in deuterium values that qualitatively is consistent with the timing of the transition from the last glacial maximum to the present interglacial period. The most transmissive geologic units in the Central Oklahoma aquifer are the Garber Sandstone and Wellington Formation and the alluvium and terrace deposits; the Chase, Council Grove, and Admire Groups are less transmissive on the basis of available specific-capacity data. The transmissivities of the Permian geologic units depend largely on the percentage of sandstone; the percentage is greatest in the central part of the aquifer and decreases in all directions from this central part. Because of large mudstone and siltstone contents, the Hennessey Group and the Vanoss Formation are assumed to be confining units above and below the aquifer. The Cimarron and Canadian Rivers are defined to be the northern and southern extent of the aquifer because of decreases in transmissivity beyond the rivers and because there is no indication of ground-water underflow at these rivers. The eastern boundary of the aquifer is the limit of the outcrop of the Chase, Council Grove, and Admire Groups. The presence of brines in the western part of the study unit and below the aquifer indicate the extent of the freshwater flow system in these directions. Regional ground-water flow is west to east; the Deep Fork is a major discharge area for the regional flow system. Local flow systems are present within the unconfined part of the study unit. Most streams are gaining streams, and very few losing streams are evident. Median values of aquifer properties were estimated as follows: recharge to the saturated zone, 1.6 inches per year; evapotranspiration of water that never reaches the saturated zone, 25 to 30 inches per year; porosity, 0.22; storage coefficient, 0.0002; transmissivity, 260 to 450 feet squared per day; horizontal hydraulic conductivity, 4.5 feet per day; and the ratio of horizontal to vertical hydraulic conductivity, 10,000. Reported ground-water withdrawals peaked in 1985 at 13,900 million gallons but had decreased to 7,860 million gallons by 1989. Unreported domestic withdrawals were estimated to be 1,685 million gallons in 1980. The flow system in the aquifer can be considered to have three major components: (1) A shallow, local flow system in the unconfined part of the aquifer, (2) a deep, regional flow system in the unconfined part of the aquifer, and (3) a deep, regional flow system in the confined part of the aquifer. In the shallow, local flow system, water flows relatively quickly along short flowlines from the point of recharge to the point of discharge at the nearest stream. Many water samples from shallow wells contain large concentrations of tritium, which indicate ground-water ages of less than 40 years. In the deep, regional flow system in the unconfined part of the aquifer, water takes more time to flow along longer flowlines than in the shallow, local flow system. Much of the water in this flow system is recharged along ridges that correspond to ground-water divides between drainage basins. Transit times for water recharging the aquifer along ridges is greater than 5,000 years, computed using a numerical flow model in conjunction with a particle-tracking model. The deep, regional flow system in the confined part of the Garber Sandstone and Wellington Formation is recharged from a small part of the outcrop area of the Garber Sandstone. From the recharge area, water flows west under the confining unit to discharge to streams as far away as the Cimarron River. Flowpaths are relatively long, as much as 50 miles. The transit times in this flow system range from thousands to tens of thousands of years. The long-term hydrogeochemical process occurring in the Central Oklahoma aquifer is removal of unstable minerals, including dolomite, calcite, biotite, chlorite, and feldspars, and the replacement of exchangeable sodium on clays with calcium and magnesium. Over geologic time, the flux of water through the rapidly moving, local flow system has been sufficient to remove most of the dolomite, calcite, and exchangeable sodium. In places, chlorite and feldspars have been removed. In the deep, regional flow system of the unconfined part of the Garber Sandstone and Wellington Formation, the flux of water has been sufficient to remove most of the exchangeable sodium, but carbonate minerals remain sufficiently abundant to maintain dolomite and calcite equilibrium. In the confined part of the Garber Sandstone and Wellington Formation and in the less transmissive parts of the unconfined aquifer, including the Chase, Council Grove, and Admire Groups, ground-water flow is slowest, and the flux of water and extent of reaction have been insufficient to remove either the carbonate minerals or the exchangeable sodium on clays.

Oklahoma↗
USGS1969

Recent surface movements in the Baldwin Hills, Los Angeles County, California

The Baldwin Hills are located in the northwest part of the densely populated Los Angeles basin. They comprise one of several groups of isolated hills that extend along the northwest-trending Newport-Inglewood zone of folds and faults, a structural lineament identified with a series of very productive oil fields. In addition to being the site of the Inglewood oil field, these hills are the site of surface deformation that has been monitored for over 35 years. This record of deformation, which includes differential subsidence, horizontal displacements, and surface rupturing, forms one of the best documented examples of oilfield-associated surface deformation yet recognized. The deformation is described in detail, analyzed as to cause(s), and finally attributed largely or essentially entirely to the exploitation of the spatially-associated Inglewood oil field. The Baldwin Hills are underlain by gently to moderately arched and conspicuously faulted Cenozoic sedimentary and volcanic rocks that overlie crystalline basement rocks at a depth of more than 10,000 feet. The Inglewood fault, a part of the northwest-trending Newport-Inglewood zone, diagonally transects the hills. Right-lateral displacements of 3,000-4,000 feet since middle or late Pliocene time and 1,500-2,000 feet during Quaternary time are indicated by offset structural and physio-graphic features; indications of vertical separations of up to about 200 feet during late Quaternary time occur locally. Evidence of continuing deformation includes recognized seismicity and regional elevation changes. The M5-5 1/2 Inglewood earthquake of 1920, the largest local earthquake of record, is believed to have originated immediately southeast of the Baldwin Hills; it was apparently unassociated with surficial fault displacements. Leveling in and around the west and central Los Angeles basin has shown that lowland stations have been consistently subsiding, whereas foothill stations commonly have been rising. Several seemingly persistent basins of differential subsidence and a zone of positive movement, roughly coincident with the Newport-Inglewood zone, have also been identified in the northwest part of the basin. A prominent, elliptically-shaped, northwest-trending subsidence bowl encompassing the northwest part of the Baldwin Hills, has been defined by repeated level circuits. Partial reconstruction of selected level circuits with respect to a common, relatively stable control point (Hollywood E-11), located on the edge of the subsidence bowl, has permitted evaluation of the subsidence since 1910 and 1911 at two points near the center of the bowl. Thus bench mark PBM 67 is estimated to have subsided approximately 4.324 feet between June 1910 and February 1963; and bench mark PBM 68 (the only bench mark within the subsidence bowl that was leveled prior to 1926 and has been repeatedly leveled since) subsided 3.846 feet between November 1911 and June 1962. Analysis of the available data indicates little if any elevation change at PBM 68 (or elsewhere throughout the Baldwin Hills-Inglewood area) associated with the Inglewood earthquake of 1920. Maximum subsidence of PBM 122 (which has remained very close to the center of subsidence since at . least 1950) between 1911 and 1963 is calculated to have been 5.67 feet. Horizontal displacements (with respect to a north-south base line about 3 miles east of the hills) of six triangulation points within the subsidence bowl have been measured for various periods between 1934 and 1963. Displacements have been generally toward the center of subsidence and almost precisely perpendicular to the immediately adjacent isobases of equal elevation change. Maximum movement has been recorded at triangulation point Baldwin Aux, which was displaced 2.21 feet between 1934 and 1961; horizontal displacements of three additional points ranged from 0.95 foot to 1.85 feet between 1936 and 1961. Displacements of 0.10-0.29 foot were recorded at all six monuments during the period 1961-1963. "Earth cracks" and surficial fault displacements were recognized in the Baldwin Hills at least as early as 1957. The cracks are relatively straight, generally continuous fractures confined to the structural block east of the Inglewood fault; they are concentrated in two areas centering on (1) the Baldwin Hills Reservoir and (2) the Stocker Street-LaBrea Avenue-Overhill Drive intersection. The cracks trend north to north-northeast and are nearly everywhere parallel to or coincident with minor faults and joints, and are generally orthogonal to radii emanating from the center of subsidence. Differential movement along the cracks has been almost entirely dip slip along steep to nearly vertical surfaces, and generally down-dropped toward the center of subsidence. Cumulative displacements have been as much as 6 or 7 inches. Rates of displacement have ranged widely, and the movement has generally occurred as creep or very small discrete jumps. A probable exception is the several inches of differential movement that is believed to have occurred along a crack through the floor of the Baldwin Hills Reservoir on or about December 14, 1963. The contemporary surface movements are attributable to one or more of the following phenomena: (1). exploitation of the Inglewood oil field; (2) changes in the ground-water regimen; (3) compaction of sedimentary materials in response to surface loading; (4) tectonic activity. The following considerations indicate that the differential subsidence is attributable largely or entirely to exploitation of the underlying Inglewood oil field: (1) the coincidence of the centers of the oil field, the producing structure, and the subsidence bowl; (2) the general correspondence between the pattern of subsidence and the outlines of the oil field; (3) the approximate coincidence between the initiation of production and the initiation of subsidence; (4) the generally linear relations between various measures of subsidence and liquid production from both the field as a whole and the exceptionally prolific Vickers zone in particular; (5) the sharp deceleration of subsidence in the eastern block of the field coincident with the initiation of full-scale water flooding there; (6) the many examples of oil fields In which both spatial and temporal associations between production and subsidence are recognized; (7) the many similarities of the subsidence-production relations in the Inglewood field to those in the Wilmington field, where the subsidence has been authoritatively attributed to oilfield operations; (8) the theoretical relation between subsidence or a tendency toward subsidence and increased effective pressure associated with underground fluid extraction. Consideration of six possible explanations for the increasing rather than decreasing or constant rate of subsidence with respect to reservoir fluid pressure decline suggests that measured or calculated down-hole reservoir fluid pressure decline is non-representative of average or real fluid pressure decline away from producing wells. The near-linear relations between net-liquid production and subsidence are explained through analogy with a tightly confined artesian system of infinite areal extent, where production must derive from liquid expansion and/or reservoir compaction. Test data from compaction studies in two other oil fields yield estimates of ultimate compaction of the Vickers zone resulting from a total loss of fluid pressure; these estimates range over an order of magnitude. The best estimate, based on these data and considerations of late Cenozoic history in the Baldwin Hills area, is about 10 feet. The centripetally-directed horizontal movements are considered attributable to exploitation of the Inglewood oil field on the basis of: (1) their well-defined symmetrical and geometrical association with the differential subsidence; (2) the similarities between these associations and those developed in and around other subsiding oil fields; and (3) the mechanical compatibility of these movements with subsidence induced by the extraction of subsurface materials. The earth cracks and surficial fault displacements are considered largely or entirely attributable to the exploitation of the Inglewood oil field on the basis of: (1) their spatial and temporal relations to both oil-field operations and the differential subsidence; (2) the similarities of these cracks and displacements to those generated in and around other oil fields and areas of subsurface materials extraction; and (3) surface strain patterns predicted from the measured vertical and horizontal surface movements. The cracks and displacements can i)e explained by an exploitation-based, elastic-rebound model which requires elastic compression of the sedimentary section in response to compaction-induced downdrag within those blocks around the periphery of the subsidence bowl. The measured displacements have been about one-quarter to one-half those predicted for a purely elastic system. Analysis of: (1) the history of ground-water extraction within and around the Baldwin Hills; and (2) subsidence associated with water-level declines in sediments comparable with those in the Baldwin Hills, indicate that the surface movements can be no more than incidentally attributed to changes in ground-water conditions. Similarly, analysis of the history of natural and artificial changes in surface loading indicate that these movements are generally unassociated with changes in surface loading conditions. Considerations of local geologic history and various tectonic associations indicate that it is very unlikely that the differential subsidence and horizontal movements are due to tectonic downwarping. There exists a far stronger prima facie argument for tectonic involvement in the earth cracking and associated fault displacements. This argument is disputed by; (1) the spatial and temporal relations of the earth cracks to, and their mechanical compatibility with, the nontectonic differential subsidence; (2) the absence of displacements on the Inglewood fault in conjunction with those along the conjugate earth cracks; (3) the probability that purely tectonic displaceMents would be characterized by oblique or strike slip; and (4) the absence of any clear temporal relation between crack growth and local seismicity, However, because as much as 10 percent of the local isobase gradient may be unexplained' by oil-field exploitation, a small fraction of this gradient, and thus the displacements among the southern group of cracks, may be attributable to tectonic activity. This fraction should have been insignificant in the presence of the strain pattern produced by nontectonic compaction of the underlying oil measures. Because nearly all of the observed and measured surface movements can be fully explained as the products of oil-field operations, yet can be no more than incidentally attributed to changes in ground-water conditions, surface loading, or tectonic activity, we conclude that these movements are attributable largely or essentially entirely to the exploitation of the Inglewood oil field.

California↗