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USGS2020

Water balance as an indicator of natural resource condition: Case studies from Great Sand Dunes National Park and Preserve

Managing climate impacts to natural resources in protected areas can be hampered by lack of monitoring data, poor understanding of natural resource responses to climate, or lack of timely condition assessments that can inform management actions. Here we demonstrate the utility of water balance as a tool for understanding natural resource responses to climate by developing case studies focused on stream flow, vegetation production, and wildfire ignition at Great Sand Dunes National Park and Preserve (GSDNP), U.S.A. The efficacy of water balance to predict these responses stems from the explicit integration of climate with site conditions that modify the effects of climate. This in turn results in estimates of water availability, water use, and water need that are proximal drivers of aquatic and terrestrial natural resource conditions. The water balance model successfully forecasted stream flow (r 2 = 0.69, P < 0.001); determined the critical water needs for maintaining annual vegetation production in different vegetation types spanning a large environmental gradient (r 2 = 0.18–0.71); and predicted proportion of historic wildfire ignitions in forest (r 2 = 0.96–0.99) and non-forest (r 2 = 0.96–0.97) vegetation types. Collectively, these case studies demonstrate practical approaches to translate climate data into assessments of natural resource condition that inform long-term planning and near-term strategic actions needed for conservation of protected areas.

Great Sand Dunes National Park and Preserve↗

USGS2016

Groundwater quality, age, and susceptibility and vulnerability to nitrate contamination with linkages to land use and groundwater flow, Upper Black Squirrel Creek Basin, Colorado, 2013

The Upper Black Squirrel Creek Basin is located about 25 kilometers east of Colorado Springs, Colorado. The primary aquifer is a productive section of unconsolidated deposits that overlies bedrock units of the Denver Basin and is a critical resource for local water needs, including irrigation, domestic, and commercial use. The primary aquifer also serves an important regional role by the export of water to nearby communities in the Colorado Springs area. Changes in land use and development over the last decade, which includes substantial growth of subdivisions in the Upper Black Squirrel Creek Basin, have led to uncertainty regarding the potential effects to water quality throughout the basin. In response, the U.S. Geological Survey, in cooperation with Cherokee Metropolitan District, El Paso County, Meridian Service Metropolitan District, Mountain View Electric Association, Upper Black Squirrel Creek Groundwater Management District, Woodmen Hills Metropolitan District, Colorado State Land Board, and Colorado Water Conservation Board, and the stakeholders represented in the Groundwater Quality Study Committee of El Paso County conducted an assessment of groundwater quality and groundwater age with an emphasis on characterizing nitrate in the groundwater. Groundwater-quality samples were collected from 50 randomly selected wells between May and June 2013. The samples were analyzed for major ions, nutrients, dissolved gases, tritium ( 3 H), chlorofluorocarbons (CFC-11, CFC-12, and CFC-113), and fuel products (such as benzene, toluene, ethylbenzene, and xylenes). None of the groundwater samples exceeded the U.S. Environmental Protection Agency (EPA) National Primary Drinking Water Regulations for primary maximum contaminant levels (MCL) for major ions. Secondary maximum contaminant levels, which are not health concerns and affect mainly taste, color, or odor of the water, were observed in rare instances for pH (2 samples), chloride (1 sample), iron (3 samples), and manganese (8 samples). The secondary maximum contaminant level for total dissolved solids was also exceeded for two samples. Nitrate (nitrite plus nitrate as nitrogen in groundwater) was elevated above the estimated background concentration of natural recharge waters of 1 milligram per liter (mg/L) in 44 of the 50 wells sampled and showed a median concentration of 5.4 mg/L. Nitrate concentrations were above the MCL of 10 mg/L in 5 of the 50 wells sampled and above half of the EPA MCL (5 mg/L) in 27 of the 50 wells sampled, which included samples above the MCL. Dissolved-oxygen concentrations exceeded 0.5 mg/L in 95 percent of reported values (40 of 42 samples) and exceeded 2.0 mg/L in 90 percent of reported values (38 of 42 samples). The oxidized conditions observed in most areas indicate that nitrate from fertilizers and animal or human waste was geochemically stable and could persist in the groundwater for decades or perhaps longer. A historical analysis of median nitrate concentrations over nearly three decades showed an increase in nitrate of approximately 1 mg/L from 4.3 to 5.4 mg/L, although the increase was not determined to be significantly different using nonparametric statistical methods. Major-ion data indicate that groundwater representative of the primary aquifer was classified as calcium-sodium bicarbonate type water. Other water samples from wells located mainly along the periphery of the primary aquifer had cation-anion compositions consistent with distinct water sources, including groundwater contributions from the underlying bedrock aquifers. The areas with differentiable water sources were located mainly where alluvial deposits were thin and geologic contacts to the underlying bedrock aquifers were relatively shallow. Nitrate concentrations in the groundwater were evaluated for relations to land use. An agricultural region was defined using a sequence of land satellite imagery. Groundwater flow directions interpreted from median water-table elevations measured from 2000 to 2013 were used in conjunction with cropland locations to define the agricultural region boundaries by encompassing potential pathways of nitrate transport in the groundwater from nitrogen-based fertilizers. A statistically significant higher median nitrate concentration was observed for areas inside the agricultural region (6.7 mg/L) compared to areas outside the agricultural region (2.3 mg/L), although median concentrations in both areas were below the MCL (10 mg/L). Median nitrate concentration was also significantly greater in land parcels with septic use (4.9 mg/L) compared to nonseptic parcels (1.7 mg/L). In general, agriculture or septic use was identified as the primary source of nitrate, depending on location, while commercial, county, grazing, and residential land uses were generally secondary sources of nitrate. Apparent groundwater ages were estimated from chlorofluorocarbons (CFC-11, CFC-12, and CFC-113) and tritium ( 3 H) data using models that assumed piston flow and binary mixing (dilution of a young component with old, tracer-free water). The mean and median groundwater ages were about 30 years and the standard deviation was 6 years, indicating that most groundwater in the primary aquifer was “young” water that had recharged to the aquifer over the last few decades (post-1950s). The median fraction of young water was about 71 percent, and the standard deviation was 29 percent. The remaining water predated the 1950s, which may have originated from deeper geologic formations or may represent slow moving groundwater within the primary aquifer. Some of the oldest groundwater ages (older than 30 years) were observed in the upper reaches of the aquifer to the northwest where the primary aquifer is thin and intersects bedrock, supporting the hypothesis of geochemically distinct groundwater entering the primary aquifer from below. Groundwater that had reached the central part of the aquifer from upgradient areas of the basin was variable in age because of differences in flow paths and travel velocities. The groundwater age analysis showed that current (2013) land-use practices could affect water quality over decades to come, and that responses to remedial actions could be slow, especially for constituents, such as nitrate, that are stable under oxidized conditions. Fuel products (including acetone, benzene, diisopropyl ether, ethylbenzene, methyl acetate, methyl tertiary butyl ether (MTBE), methyl tert-pentyl ether, m- + p-xylene, o-xylene, tert-amyl alcohol, tert-butyl alcohol, tert-butyl ethyl ether, and toluene) were analyzed in groundwater from 49 of the 50 wells. Water from seven sites had detections for fuel compounds; all concentrations were below MCL. The results provided assurance of water quality and a valuable baseline to evaluate future trends of fuel constituents as the region is further developed. Probability maps were developed from logistic regression models to examine the likelihood that nitrate concentrations in groundwater exceeded specified levels. Susceptibility analysis examined relations between mid-level (5.0 mg/L) nitrate concentrations and climatic, hydrologic, and geologic variables; the significant variables were identified as depth to groundwater, soil organic matter, and soil water storage to 25-centimeter (cm) depth. The vulnerability assessments included natural factors driving susceptibility but also human factors related to land use and septic use. Vulnerability to low-level (2.5 mg/L) nitrate was related to depth to groundwater, septic zoning, and soil organic matter. The results highlighted that septic zoning affected low-level nitrate concentrations. Vulnerability to mid-level (5.0 mg/L) nitrate was examined using all 50 samples and also with two data outliers removed, which showed relatively high nitrate concentrations but also anomalous water chemistry or were located beyond the primary study area. Vulnerability to mid-level (5.0 mg/L) nitrate using all 50 samples was related to depth to groundwater, land use, septic use within a 500-meter (m) radius, soil water storage to a 25-cm depth, soil organic matter, and whether a location was within the agricultural region. The mid-level (5.0 mg/L) vulnerability model using 48 samples (two outliers removed) produced the best overall fit and was related to the same variables as when using all samples except septic use. The results for mid-level vulnerability provided additional support that septic use was associated with low levels of nitrate in the groundwater. Soil properties and land use were identified as the main drivers of moderate nitrate concentrations. Probabilities of exceeding low-level nitrate concentrations were high in most areas with the lowest probabilities usually to the northwest along thin geologic deposits in the upper part of the basin. The results of this investigation offer the foundational information needed for developing best management practices to mitigate nitrate contamination, basic concepts on water quality to aid public education, and information to guide regulatory measures if policy makers determine this is warranted. Science-based decision making will require continued monitoring and analysis of water quality in the future.

Colorado↗

USGS2005

Factors controlling tungsten concentrations in ground water, Carson Desert, Nevada

n investigation of a childhood leukemia cluster by US Centers for Disease Control and Prevention revealed that residents of the Carson Desert, Nevada, are exposed to high levels of W and this prompted an investigation of W in aquifers used as drinking water sources. Tungsten concentrations in 100 ground water samples from all aquifers used as drinking water sources in the area ranged from 0.27 to 742 μg/l. Ground water in which W concentrations exceed 50 μg/l principally occurs SE of Fallon in a geothermal area. The principal sources of W in ground water are natural and include erosion of W-bearing mineral deposits in the Carson River watershed upstream of Fallon, and, possibly, upwelling geothermal waters. Ground water in the Fallon area is strongly reducing and reductive dissolution of Fe and Mn oxyhydroxides may be releasing W; however, direct evidence that the metal oxides contain W is not available. Although W and Cl concentrations in the Carson River, a lake, and water from many wells, appear to be controlled by evaporative concentration, evaporation alone cannot explain the elevated W concentrations found in water from some of the wells. Concentrations of W exceeding 50 μg/l are exclusively associated with Na – HCO 3 "> Na–HCO3 and Na–Cl water types and pH > 8.0; in these waters, geochemical modeling indicates that W exhibits <10% adsorption. Tungsten concentrations are strongly and positively correlated with As, B, F, and P, indicating either common sources or common processes controlling their concentrations. Geochemical modeling indicates W concentrations are consistent with pH-controlled adsorption of W. The geochemical model PHREEQC was used to calculate IAP values, which were compared with published Ksp values for primary W minerals. FeWO 4 , MnWO 4 , Na 2 WO 4 , and MgWO 4 were undersaturated and CaWO 4 and SrWO 4 were approaching saturation. These conclusions are tentative because of uncertainty in the thermodynamic data. The similar behavior of As and W observed in this study suggests ground water in areas where elevated As concentrations are present also may contain elevated W concentrations, particularly if there is a mineral or geothermal source of W and reducing conditions develop in the aquifer.

Nevada↗

USGS1972

Water resources inventory of Connecticut Part 6: Upper Housatonic River basin

The upper Housatonic River basin report area has an abundant supply of water of generally good quality, which is derived from precipitation on the area and streams entering the area. Annual precipitation has averaged about 46 inches over a 30-year period. Of this, approximately 22 inches of water is returned to the atmosphere each year by evaporation and transpiration; the remainder flows overland to streams or percolates downward to the water table and ultimately flows out of the report area in the Housatonic River or in smaller streams tributary to the Hudson River. During the autumn and winter precipitation normally is sufficient to cause a substantial increase in the amount of water stored in surface reservoirs and in aquifers, whereas in the summer, losses through evaporation and transpiration result in sharply reduced streamflow and lowered ground-water levels. Mean monthly storage of water in November is 2.8 inches more than it is in June. The amount of water that flows into, through, and out of the report area represents the total amount potentially available for use ignoring reuse. For the 30-year period 1931 through 1960, the annual runoff from precipitation has averaged 24 inches (294 billion gallons). During the same period, inflows from Massachusetts and New York have averaged 220 and 64 billion gallons per year, respectively. A total average annual runoff of 578 billion gallons is therefore available. Although runoff indicates the total amount of water potentially available, it is rarely feasible to use all of it. On the other hand, with increased development, some water may be reused several times. The water availability may be tapped as it flows through the area or is temporarily stored in streams, lakes, and aquifers. The amounts that can be developed differ from place to place and time to time, depending on the amount of precipitation, on the size of drainage area, on the thickness, transmissivity, and areal extent of aquifers, and on the variations in chemical and physical quality of water. Differences in precipitation cause differences in the amount of streamflow whereas differences in the proportion of stratified drift affect its timing. Water can be obtained from wells almost anywhere in the area, but the amount obtainable at any particular point depends on the type and water-bearing properties of the aquifers tapped. Stratified-drift aquifers are the only ones generally capable of yielding more than 100 gpm (gallons per minute) to individual wells. Drilled, screened wells tapping this unit yield from 17 to 1,400 gpm, with a median yield of 200 gpm. Till and bedrock are widespread but generally provide only small supplies of water. Till is tapped in a few places by dug wells, which can yield small supplies of only a few hundred gallons per day throughout all or most of the year. Bedrock is the chief aquifer for privately owned domestic and rural supplies; it is tapped by drilled wells, about 90 percent of which will supply at least 2 gpm. Only 1 of 10 bedrock wells, however, will supply more than 30 gpm. The amount of ground water potentially available in the report area depends upon the thickness and hydraulic properties of aquifers, the amount of salvageable natural discharge of ground water, and the quantity of water available by induced infiltration from streams and lakes. From data on transmissivity, thickness, recharge, well performance, and streamflow, preliminary estimates of ground-water availability can be made for most stratified-drift aquifers in the report area. Long-term yields estimated for eight areas of stratified drift especially favorable for development of large ground-water supplies ranged from 0.6 to 5 mgd (million gallons per day). Detailed site studies are needed to verity these estimates and to determine optimum yields, drawdowns, and spacing of individual wells before major ground-water development is undertaken in these or other areas. The chemical quality of water in the report area is generally good; carbonate-bedrock units exert considerable local influence on water quality. Samples of naturally occurring surface water collected at 24 sites during low flow averaged 90 mg/l (milligrams per liter) dissolved solids and 60 mg/l hardness. Water from wells is generally more highly mineralized than naturally occurring water from streams. About 37 percent of the wells sampled yielded water with more than 200 mg/l dissolved solids and 50 percent yielded water with more than 120 mg/l hardness. These concentrations reflect the high degree of mineralization of ground water in carbonate bedrock and unconsolidated deposits derived from this bedrock. The larger streams, which transport varying amounts of industrial and domestic effluents, averaged about 150 mg/l dissolved solids and 90 mg/l hardness. Iron and manganese concentrations in both ground water and surface water at some places exceed recommended limits for domestic and industrial use. Most wells in the report area yield water with little or no iron or manganese. In certain localities however, the probability is high of encountering water with excessive concentrations of these constituents. Schists, especially the unit in the northwestern corner of the basin, are the likely sources of water with excessive iron and manganese. Iron concentrations in naturally occurring stream water exceed 0.3 mg/l under low-flow conditions at 29 percent of the sites sampled. These excessive concentrations result from discharge of iron-bearing water from aquifers or from swamps where iron is released from decaying vegetation. Water temperature in the larger streams ranges from 0°C (degrees Celsius) to about 28°C. Ground water between 30 feet and 200 feet below the land surface has a relatively constant temperature, usually between 8°C and 11°C. The quantity of suspended sediment transported by streams under natural conditions is negligible. Even in streams affected by man, turbidity is rarely a problem. The total amount of water used in the report area for all purposes during 1967 was about 6,360 million gallons, or 140 gpd per person. Public supplies furnished the domestic needs of nearly half the population of the area. All of the 14 public supplies sampled provided water that meets the drinking water standards of the U.S. Public Health Service.

Connecticut↗

USGS2024

Deep learning for water quality

Understanding and predicting the quality of inland waters are challenging, particularly in the context of intensifying climate extremes expected in the future. These challenges arise partly due to complex processes that regulate water quality, and arduous and expensive data collection that exacerbate the issue of data scarcity. Traditional process-based and statistical models often fall short in predicting water quality. In this Review, we posit that deep learning represents an underutilized yet promising approach that can unravel intricate structures and relationships in high-dimensional data. We demonstrate that deep learning methods can help address data scarcity by filling temporal and spatial gaps and aid in formulating and testing hypotheses via identifying influential drivers of water quality. This Review highlights the strengths and limitations of deep learning methods relative to traditional approaches, and underscores its potential as an emerging and indispensable approach in overcoming challenges and discovering new knowledge in water-quality sciences.

Nature Water↗

USGS2004

Potentiometric surface of the upper Floridan aquifer in the St. Johns River Water Management District and vicinity, Florida, May 2004

This map depicts the potentiometric surface of the Upper Floridan aquifer in the St. Johns River Water Management District and vicinity in May 2001. Potentiometric contours are based on water-level measurements collected at 684 wells during the period May 2 - 30, near the end of the dry season. The shapes of some contours have been inferred from previous potentiometric-surface maps with larger well networks. The potentiometric surface of the carbonate Upper Floridan aquifer responds mainly to rainfall, and more locally, to ground-water withdrawals. Potentiometric-surface highs generally correspond to topographic highs where the aquifer is recharged. Springs and areas of diffuse upward leakage naturally discharge water from the aquifer and are most prevalent along the St. Johns River. Areas of discharge are reflected by depressions in the potentiometric surface. Ground-water withdrawals locally have lowered the potentiometric surface. Ground water in the Upper Floridan aquifer generally flows from potentiometric highs to potentiometric lows in a direction perpendicular to the contours.

Florida↗

USGS2005

Potentiometric surface of the upper Floridan aquifer in the St. Johns River Water Management District and vicinity, Florida, September 2004

Introduction: This map depicts the potentiometric surface of the Upper Floridan aquifer in the St. Johns River Water Management District and vicinity in September 2004. Potentiometric contours are based on water-level measurements collected at 608 wells during the period September 14-October 1, near the end of the wet season. The shapes of some contours have been inferred from previous potentiometric-surface maps with larger well networks. The potentiometric surface of the carbonate Upper Floridan aquifer responds mainly to rainfall, and more locally, to ground-water withdrawals. Potentiometric-surface highs generally correspond to topographic highs where the aquifer is recharged. Springs and areas of diffuse upward leakage naturally discharge water from the aquifer and are most prevalent along the St. Johns River. Areas of discharge are reflected by depressions in the potentiometric surface. Ground-water withdrawals locally have lowered the potentiometric surface. Ground water in the Upper Floridan aquifer generally flows from potentiometric highs to potentiometric lows in a direction perpendicular to the contours.

Florida↗

USGS2006

Potentiometric Surface of the Upper Floridan Aquifer in the St. Johns River Water Management District and Vicinity, Florida, May 2005

INTRODUCTION This map depicts the potentiometric surface of the upper Floridan aquifer in the St. Johns River Water Management District and vicinity for May 2005. Potentiometric contours are based on water level measurements collected at 598 wens during the period May 5 - 31, near the end of the dry season. Some contours are inferred from previous potentiometric-surface maps with larger well networks. The potentiometric surface of the carbonate upper Floridan aquifer responds mainly to rainfall, and more locally, to ground water withdrawals. Potentiometric-surface highs generally correspond to topographic highs where the aquifer is recharged. Springs and areas of diffuse upward leakage naturally discharge water from the aquifer and are most prevalent along the St. Johns River. Areas of discharge are reflected by depressions in the potentiometric surface. Ground water withdrawals locally have lowered the potentiometric surface. Ground water in the upper Floridan aquifer generally flows from potentiometric highs to potentiometric lows in a direction perpendicular to the contours.

Open-File Report↗

USGS1985

Effects of artificial recharge on the Ogallala aquifer, Texas

Four recharge tests were conducted by injecting water from playa lakes through wells into the Ogallala Formation. Injection was by gravity flow and by pumping under pressure. At one site, 34-acre feet of water was injected by gravity and produced a significant increase in yield of the well. At a second site, gravity injection of only 0.58 acre-foot caused a significant decrease in permeability due to plugging by suspended sediment. At two other sites, injection by pumping 6 and 14 acre-feet respectively, resulted in discharge of water at the surface and in perching of water above the water table. Differences in success of recharge were largely due to aquifer lithology and, therefore, the type of permeability; the concentration of suspended solids in the recharge water; and the injection technique. The injection technique can be controlled and the concentration of suspended solids can be minimized by treatment, but the site for well recharge will accept water most rapidly if it is selected on the basis of a favorable geohydrologic environment. Geophysical logs were used to study the effect of aquifer lithology on recharge and to understand the movement of injected water. Temperature logs were particularly useful in tracing the movement of recharged water. Natural-gamma, gamma-gamma, and neutron logs provided important data on lithology and porosity in the aquifer and changes in porosity and water distribution resulting from recharge. Effective recharge of the Ogallala Formation, using water from playa lakes, is possible where geohydrologic conditions are favorable and the recharge system is properly constructed.

Water Supply Paper↗

USGS1972

Vegetation of prairie potholes, North Dakota, in relation to quality of water and other environmental factors

Measurements of specific conductance provide an adequate indication of the average salinity of surface waters in natural ponds and lakes of the northern .prairie region. Yearly and seasonal variations in specific conductance were much greater in brackish and subsaline wetlands than in fresh-water areas. The principal vegetational types. Land-use practices of varying brackish to saline wetlands were sulfates and chlorides of sodium and magnesium. In less saline waters, carbonate and bicarbonate salts of calcium and potassium were of greater importance, but as salinity increased, the proportion of these compounds decreased rapidly. A major environmental factor controlling the establishment of marsh and aquatic vegetation is the permanence of surface water. Permanence is a measure of the extent to which surface water persists at a given site. Varying degrees of water permanence during the growing season led to the establishment of distinct vegetational types, which were differentiated primarily on the 'basis of community structure or life form of the dominant vegetation. Salinity of surface waters was closely correlated with differences in species composition of plant communities found in the principal vegetational types. Land-use practices of varying degrees of intensity also had a secondary influence on species composition. Since an unstable water chemistry is characteristic of most prairie ponds and lakes, it is more reliable to use the plant communities as indicators of average salinity than to use single measurements of specific conductance. Characteristic species of wetland vegetational types occupied the central deeper parts of pond and lake basins or occurred as concentric peripheral bands. The wetland vegetational types are wetland low-prairie, wet-meadow, shallow-marsh emergent, deep-marsh emergent, fen emergent, submerged and floating, natural drawdown, cropland drawdown, and cropland tillage vegetation. Combinations of species (plant associations) within these vegetational types were placed in one of six salinity categories designated as fresh, slightly brackish, moderately brackish, brackish, subsaline, and saline. Salt tolerance apparently varied greatly among the various marsh and aquatic plants since the num'ber of species represented in moderately brackish to saline communities decreased markedly with increased salinity of the surface water environment.

Professional Paper↗

USGS1961

Aqua de Ney, California, a spring of unique chemical character

The chemistry of water of Aqua de Ney, a cold spring of unusual character located in Siskiyou County, Calif., has been re-examined as part of a study of the relation of water chemistry to rock environment. The water has a pH of 11·6 and a silica content of 4000 parts per million (p.p.m.), the highest values known to occur in natural ground waters. The rocks exposed nearby consist of two volcanic sequences, one predominantly basaltic in composition, the other highly siliceous. Neither these rocks nor the sedimentary and igneous rocks presumed to underlie the area at depth seem to offer explanation of the unusual mineralization which includes 240 p.p.m. of boron, 1000 p.p.m. of sulphide (as H 2 S), and 148 p.p.m. of ammonia nitrogen (as NH 4 ) in a water that is predominantly sodium chloride and sodium carbonate in character. By analogy, it is assumed that water from Aqua de Ney is the product of an initial mixture of connate sea water with a calcium magnesium sulphate water. It is postulated that ion exchange has increased the content of sodium and reduced that of calcium and magnesium, and that sulphate reduction has brought about the high alkalinity, high pH, and high content of sulphide. The large silica value is explained as the result of solution of silica by water having the high pH observed.

California↗

USGS1979

Environmental features, general hydrology, and external sources of nutrients affecting Wilderness Lake, King County, Washington

A water budget prepared for Wilderness Lake, a candidate for lake-quality restoration, indicates that of the 530 acre-feet of water that enters the lake each year, 170 acre-feet is from precipitation and 360 acre-feet is from groundwater inflow. An equal amount leaves the lake, and of this, 380 acre-feet is by surface runoff, 8 acre-feet is by groundwater seepage, and 140 acre-feet is by evaporation. Based on these amounts of inflow and outflow, the theoretical water-renewal time of the lake is calculated to be 2.6 years. The annual contributions of nitrogen and phosphorus to the lake from precipitation, natural ground water, and septic-tank leachate are about 920 kilograms nitrogen and 38 kilograms phosphorus. Nitrogen and phosphorus contributions from other sources were not assessed but could be significant. (Woodard-USGS)

Washington↗

USGS1995

Numerical Simulation of Regional Changes in Ground-Water Levels and in the Freshwater-Saltwater Interface Induced by Increased Pumpage at Barbers Point Shaft, Oahu, Hawaii

The effect on the regional ground-water system of southern Oahu from increased pumpage at Barbers Point shaft was estimated by a numerical ground-water model developed for the Oahu Regional Aquifer Systems Analysis (RASA) study. The RASA model was updated by revising pumping and ground-water recharge data. Pumpage data used in the new simulations were based on the allocated pumping rates for 1995 as set by the State Commission on Water Resource Management. On the basis of numerical simulation, Barbers Point shaft can sustain a withdrawal rate of 4.34 million gallons per day without adversely affecting wells in the Waianae aquifer. From results of numerical simulations, it is estimated that, as a result of increasing pumpage in Barbers Point shaft by 2 million gallons per day above the 1995-allocated rate of 2.337 million gallons per day, regional declines in ground-water levels will be about 0.4 to 0.7 feet throughout the Waianae aquifer and about 0.8 ft at the shaft. The corresponding rise of the freshwater-saltwater interface, as a result of declines in ground-water levels, is estimated to be about 20 to 30 feet. Numerical simulation also indicates that changes in ground-water levels greater than about 0.1 feet do not extend across either the Waianae-Koolau unconformity or the south Schofield barrier. The model-estimated position of the freshwater-saltwater interface, as a result of additional pumpage, ranges from 500 to 860 feet below sea level in the southern and northern parts of the aquifer, respectively, and about 540 feet below sea level at the shaft. On the basis of an estimate of the thickness of the transition-zone, the freshwater lens would remain about 240 feet thick below the shaft. In addition, the estimated declines in ground-water levels throughout the aquifer are small compared with the thickness of the freshwater lens and these declines would not be expected to affect the yields of other wells in terms of quantity. Chloride concentrations in the water pumped at Barbers Point shaft were about 240 milligrams per liter in 1992. The estimated background chloride concentration is 200 to 220 milligrams per liter because of low rainfall and the contamination of recharge water from natural salt accumulation in the soil. A reduction in irrigation through 1995 is expected to reduce recharge to the aquifer from irrigation-return water and chloride concentrations associated with the irrigation water throughout the Waianae aquifer. As a result of these combined effects, chloride concentrations of water pumped from the Barbers Point shaft will likely decrease, although the length of time required for this lowering is unknown.

Water-Resources Investigations Report↗

USGS2012

Resource and hazard implications of gas hydrates in the Northern Gulf of Mexico: Results of the 2009 Joint Industry Project Leg II Drilling Expedition

In the 1970's, Russian scientists were the first to suggest that gas hydrates, a crystalline solid of water and natural gas, and a historical curiosity to physical chemists, should occur in abundance in the natural environment. Since this early start, the scientific foundation has been built for the realization that gas hydrates are a global phenomenon, occurring in permafrost regions of the arctic and in deep water portions of most continental margins worldwide. Recent field testing programs in the Arctic (Dallimore et al., 2008; Yamamoto and Dallimore, 2008) have indicated that natural gas can be produced from gas hydrate accumulations, particularly when housed in sand-rich sediments, with existing conventional oil and gas production technology (Collett et al., 2008) and preparations are now being made for the first marine field production tests (Masuda et al., 2009). Beyond a future energy resource, gas hydrates in some settings may represent a geohazard. Other studies also indicate that methane released to the atmosphere from destabilized gas hydrates may have contributed to global climate change in the past.

Northern Gulf Of Mexico↗

USGS2005

Naturally Occurring Arsenic in Ground Water, Norman, Oklahoma, 2004, and Remediation Options for Produced Water

In 2000, the U.S. Environmental Protection Agency (EPA) reviewed the arsenic drinking water standard for public water supplies. Considering the available research and statistics on the health effects of arsenic ingestion, the EPA reduced the Maximum Contaminant Level (MCL) for public drinking water from 50 micrograms per liter (?g/L) to 10 ?g/L (U.S. Environmental Protection Agency, 2001a). As a result of the more stringent standard, the EPA estimates that about 3,000 public water providers across the United States must take action to meet the new standard before it becomes effective on January 23, 2006 (U.S. Environmental Protection Agency, 2001b). The City of Norman (City) is one of several Oklahoma municipalities affected by the new arsenic standard. About 20 percent of Norman?s water is supplied by wells completed in the Central Oklahoma (Garber-Wellington) aquifer; the rest is supplied by Lake Thunderbird (fig. 1) or purchased from Oklahoma City. The Norman well field is composed of 24 active wells, and water produced from about half of the wells will not be in compliance with the new MCL (figs. 2 and 3). Chemical treatment of water with elevated arsenic is possible, but it is generally cost prohibitive. Another costly solution is simply to abandon the high-arsenic wells and replace them with new wells in low-arsenic areas. In the next phase of well construction beginning in 2005, the City plans to construct as many as 30 new wells in northeast Norman (Bryan Mitchell, City of Norman, oral commun., 2005). The new wells will replace production lost to the new arsenic standard and add new production to keep pace with rapidly growing consumer demand. Well modification to exclude arsenic-bearing water from existing wells is a more cost-effective solution, but it requires a great deal of knowledge about local aquifer properties and individual well dynamics to decide which wells are good candidates for modification. With the goal of determining if well modification can be used to bring some of Norman?s high-arsenic wells into compliance with the new arsenic standard, the EPA Office of Research and Development (ORD) initiated a three-year research project in 2003 with participation from the U.S. Geological Survey (USGS), Oklahoma State University, and the City of Norman. The primary objectives of the project are to: (1) determine where naturally occurring arsenic is entering wells by collecting water samples at different depths, (2) investigate the utility of new methods for collecting water-quality data in a pumping well, (3) better understand the stratigraphy and composition of aquifer rocks, (4) assess 10 wells for the possibility of arsenic remediation by well modification, and (5) evaluate the effectiveness of well modification in bringing marginal wells into compliance with the new arsenic MCL. The purpose of this report is to describe the occurrence of arsenic in ground water near Norman, Oklahoma, and available options for reducing arsenic concentrations in produced ground water.

Fact Sheet↗

USGS2006

Potentiometric surface of the Upper Floridan aquifer in the St. Johns River water management district and vicinity, Florida, September 2005

This map depicts the potentiometric surface of the Upper Floridan aquifer in the St. Johns River Water Management District and vicinity for September 2005. Potentiometric contours are based on water-level measurements collected at 643 wells during the period September 12-28, near the end of the wet season. Some contours are inferred from previous potentiometric-surface maps with larger well networks. The potentiometric surface of the carbonate Upper Floridan aquifer responds mainly to rainfall, and more locally, to ground-water withdrawals and springflow. Potentiometric-surface highs generally correspond to topographic highs where the aquifer is recharged. Springs and areas of diffuse upward leakage naturally discharge water from the aquifer and are most prevalent along the St. Johns River. Areas of discharge are reflected by depressions in the potentiometric surface. Ground-water withdrawals locally have lowered the potentiometric surface. Ground water in the Upper Floridan aquifer generally flows from potentiometric highs to potentiometric lows in a direction perpendicular to the contours.

Open-File Report↗

USGS2006

Potentiometric Surface of the Upper Floridan Aquifer in the St. Johns River Water Management District and Vicinity, Florida, May 2006

Introduction: This map depicts the potentiometric surface of the Upper Floridan aquifer in the St. Johns River Water Management District and vicinity for May 2006. Potentiometric contours are based on water-level measurements collected at 599 wells during the period May 14-31, near the end of the dry season. Some contours are inferred from previous potentiometric-surface maps with larger well networks. The potentiometric surface of the carbonate Upper Floridan aquifer responds mainly to rainfall, and more locally, to ground-water withdrawals and springflow. Potentiometric-surface highs generally correspond to topographic highs where the aquifer is recharged. Springs and areas of diffuse upward leakage naturally discharge water from the aquifer and are most prevalent along the St. Johns River. Areas of discharge are reflected by depressions in the potentiometric surface. Ground-water withdrawals locally have lowered the potentiometric surface. Ground water in the Upper Floridan aquifer generally flows from potentiometric highs to potentiometric lows in a direction perpendicular to the contours.

Open-File Report↗

USGS2007

Potentiometric Surface of the Upper Floridan Aquifer in the St. Johns River Water Management District and Vicinity, Florida, September 2006

Introduction This map depicts the potentiometric surface of the Upper Floridan aquifer in the St. Johns River Water Management District and vicinity for September 2006. Potentiometric contours are based on water-level measurements collected at 571 wells during the period September 11-29, near the end of the wet season. Some contours are inferred from previouspotentiometric-surface maps with larger well networks. The potentiometric surface of the carbonate Upper Floridan aquifer responds mainly to rainfall, and more locally, to ground-water withdrawals and spring flow. Potentiometric-surface highs generally correspond to topographic highs where the aquifer is recharged. Springs and areas of diffuse upward leakage naturally discharge water from the aquifer and are most prevalent along the St. Johns River. Areas of discharge are reflected by depressions in the potentiometric surface. Ground-water withdrawals locally have lowered the potentiometric surface. Ground water in the Upper Floridan aquifer generally flows from potentiometric highs to potentiometric lows in a direction perpendicular to the contours.

Open-File Report↗