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Anaerobic biodegradation of perfluorooctane sulfonate (PFOS) and microbial community composition in soil amended with a dechlorinating culture and chlorinated solvents

Perfluorooctane sulfonate (PFOS), one of the most frequently detected per - and polyfluoroalkyl substances (PFAS) occurring in soil, surface water, and groundwater near sites contaminated with aqueous film-forming foam (AFFF), has proven to be recalcitrant to many destructive remedies, including chemical oxidation. We investigated the potential to utilize microbially mediated reduction (bioreduction) to degrade PFOS and other PFAS through addition of a known dehalogenating culture, WBC-2, to soil obtained from an AFFF-contaminated site. A substantial decrease in total mass of PFOS (soil and water) was observed in microcosms amended with WBC-2 and chlorinated volatile organic compound (cVOC) co-contaminants — 46.4 ± 11.0 % removal of PFOS over the 45-day experiment. In contrast, perfluorooctanoate (PFOA) and 6:2 fluorotelomer sulfonate (6:2 FTS) concentrations did not decrease in the same microcosms. The low or non-detectable concentrations of potential metabolites in full PFAS analyses, including after application of the total oxidizable precursor assay, indicated that defluorination occurred to non-fluorinated compounds or ultrashort-chain PFAS. Nevertheless, additional research on the metabolites and degradation pathways is needed. Population abundances of known dehalorespirers did not change with PFOS removal during the experiment, making their association with PFOS removal unclear. An increased abundance of sulfate reducers in the genus Desulfosporosinus (Firmicutes) and Sulfurospirillum (Campilobacterota) was observed with PFOS removal, most likely linked to initiation of biodegradation by desulfonation. These results have important implications for development of in situ bioremediation methods for PFAS and advancing knowledge of natural attenuation processes.

Science of the Total Environment

Tungsten skarn quantitative mineral resource assessment and gold, rare earth elements, graphite, and uranium qualitative assessments of the Kuldjuktau and Auminzatau Ranges, in the central Kyzylkum region, Uzbekistan

A new quantitative mineral resource assessment for tungsten skarn was conducted for the Auminzatau and Kuldjuktau mountain ranges in Central Uzbekistan, along with qualitative assessments of orogenic gold, rare earth elements (REEs), amorphous graphite, and uranium. By integrating a variety of geological, geochemical, geophysical, and remote sensing data sets, estimates of undiscovered tungsten skarn deposits in permissive tracts are combined with grade and tonnage distributions of known deposits to generate probabilistic estimates of undiscovered resources. Undiscovered deposits in Auminzatau are estimated to contain median resources of 98 thousand metric tons (kt) of WO 3 with a 70 percent (%) probability of at least 28 kt and a 10% probability of at least 468 kt, of which 16 kt to 293 kt may be economic to extract. In Kuldjuktau, the undiscovered deposits are estimated to contain median resources of 27 kt of WO 3 with a 60% probability of at least 12 kt and a 10% probability of at least 208 kt, of which 5 kt to 132 kt may be economic to extract. Our results suggest that the Auminzatau–Kuldjuktau Mountains area is highly prospective for additional discovery of significant Au and U resources and has low prospectivity for discovery of significant REE and graphite resources.

Minerals

Forecasting volcanic activity in Germany—A multi-criteria approach

Igneous activity, including shallow intrusions and volcanism, has the potential to disrupt underground critical infrastructure. Notably, future underground infrastructure projects like high-level radioactive waste repositories must be sited in areas of extremely low disruption probability by igneous activity. In Germany, according to the Repository Site Selection Act of 2017 (Standortauswahlgesetz, or StandAG), areas in which Quaternary volcanism is either present or future volcanic activity is expected within the next 1 million years (m.y.) must be excluded from the site selection process. Although the locations of regions with Quaternary volcanism are reasonably well known in Germany, forecasting potential igneous activity at intraplate volcanic fields is challenging, as many processes and their interactions control the spatial distribution of volcanic centers. Here, a semi-quantitative, multi-criteria approach is proposed for a regional evaluation of the relative potential of future igneous activity in Germany. A variety of geoscientific indicators are used, including seismic anomalies in Earth’s mantle, gravity data, tectonic activity, sutures, ground motion, earthquakes, mantle degassing centers, and geochronological data of volcanic rocks. The indicators describe the sequence of processes from potential melt generation in Earth’s mantle, through ascent and accumulation of melt within the lithosphere, to eruption at Earth’s surface. In total, 15 out of 30 proposed geoscientific indicators are selected and quantified using 20 total assigned parameters. Defined threshold values are used to spatially delimit relevant parameter properties to focus on areas with higher potential of future magmatic activity. To consider uncertainties of parameters and their underlying processes, which are usually more spatially extensive below ground, buffer zones are defined in which values of relevance decrease with increasing distance from the initial lateral shape of a parameter. Normalized parameters are combined into an index, whose spatial value distribution is used to differentiate the relative potential of future igneous activity (within the next 1 m.y.). The sensitivity of the results is shown by varying the weighting factors for the relevant parameters in country-wide index maps. Thereby, profiles illustrate the distribution of the resulting index values and respective index fractions of various parameters. Different index maps for the relative potential of future igneous activity are presented and can be used for hazard assessments.

Professional Paper

Risk implications of Poisson assumptions and declustering inferred from a fully time-dependent earthquake forecast

We use the Third Uniform California Earthquake Rupture Forecast Epidemic Type Aftershock Sequence model, which is fully time-dependent in terms of including spatiotemporal clustering, to evaluate the effects of the Poisson assumption and declustering algorithms on statewide loss exceedance curves. The model is simulation based, meaning it produces synthetic catalogs that exhibit realistic behavior with respect to aftershocks and multi-fault earthquakes. A Poisson version of the model was constructed by randomizing event times, and the influence of two declustering algorithms was examined as well. We demonstrate that the probability of one-or-more loss exceedances (occurrence exceedance probability) is greater for the Poisson model because it has fewer seismically quiet time windows. The discrepancy between dollar loss estimates with a given exceedance probability is up to a factor of 32% but varies depending on the loss threshold (the x-axis value) and the forecast duration (we examined a range between 24 h and 50 years, with the discrepancy for the latter being negligible). We discuss how the one-or-more loss exceedance metric is questionable because it ignores all but the maximum loss experienced in each timeframe. An alternative metric based on total aggregate loss in each time window (aggregate exceedance probability) was therefore also examined, for which the Poisson model again implies higher risk at intermediate losses but lower risk at higher losses (because large, triggered events now contribute to total aggregate losses for the fully time-dependent model). We also argue that declustering is not a scientifically justifiable way to deal with full time dependence, in agreement with a chorus from other recent studies. It is difficult to draw generally applicable conclusions from our study, in part because application specific details will likely be important, but our results highlight how full time dependence can be reckoned with once authoritative forecast models are made available.

California

Miocene evolution of the Humboldt Current

Diatom records from the East Pisco Basin (EPB) of southern Peru and offshore Ocean Drilling Program (ODP) Hole 682 A reveal stepwise increases in the primary productivity of the Humboldt Current during the middle and late Miocene. Although diatoms are present back through the late middle Eocene, successively enhanced diatom production occurs during the Miocene in four steps. The first step between 14.2 and 13.8 Ma marks the onset of diatom deposition in the Pisco-0 sequence. A second step at ∼12.9 Ma coincides with a major drop in global sea level during which diatom deposition ceased in the EPB but continued in ODP 682 A as well as in Chile, Ecuador, and Colombia. Beginning at 10.4 to 10.0 Ma, a major increase in diatom sedimentation rates in both the EPB and in ODP 682 A signals an abrupt intensification of the Humboldt Current productivity, which may be related to the closure of the Central American Seaway to deeper water circulation. A fourth step coincides with the transgressive deposition of the diatom-rich Pisco-2 sequence at 8.4 Ma and is enhanced by the onset of the global Late Miocene Biogenic Bloom (8.0–4.5 Ma). Between 7 and 6 Ma, common subtropical diatoms in ODP 682 A contrast with high diatom deposition rates in the EPB, suggesting variable El Niño-La Niña conditions. During this time, fossil vegetation evidence from southern Peru supports the presence of seasonal periods of enhanced rainfall typical of El Niño conditions. The Miocene trend of increasing sea mammal diversity in the EPB parallels these steps, further supporting stepwise enhancement of primary productivity in the Humboldt Current during the Miocene.

Humboldt Current

(Re)discovering the seismicity of Antarctica: A new seismic catalog for the southernmost continent

We apply a machine learning (ML) earthquake detection technique on over 21 yr of seismic data from on‐continent temporary and long‐term networks to obtain the most complete catalog of seismicity in Antarctica to date. The new catalog contains 60,006 seismic events within the Antarctic continent for 1 January 2000–1 January 2021, with estimated moment magnitudes (⁠Mw ⁠) between −1.0 and 4.5. Most detected seismicity occurs near Ross Island, large ice shelves, ice streams, ice‐covered volcanoes, or in distinct and isolated areas within the continental interior. The event locations and waveform characteristics indicate volcanic, tectonic, and cryospheric sources. The catalog shows that Antarctica is more seismically active than prior catalogs would indicate, examples include new tectonic events in East Antarctica, seismic events near and around the vicinity of David Glacier, and many thousands of events in the Mount Erebus region. This catalog provides a resource for more specific studies using other detection and analysis methods such as template matching or transfer learning to further discriminate source types and investigate diverse seismogenic processes across the continent.

Seismological Research Letters

A temporal look at the influence of topographic amplification on earthquake-triggered landslides in 3D seismic simulations

Earthquakes are a primary trigger for landslides, often leading to catastrophic consequences. While numerous studies have explored the spatial distribution of earthquake-triggered landslides, understanding the interaction between seismic waves and topography remains a critical challenge. Topographic irregularities can cause seismic wave amplification, altering ground shaking, and can trigger landslides that are challenging for predictive models to anticipate. This study investigates the spatial and temporal evolution of topographically amplified landslides, focusing on coseismic landslides triggered by the Mw 7.5 mainshock of the 2018 Papua New Guinea earthquake and post-seismic landslides associated with its four aftershocks, each exceeding Mw 6.0. We employ low-frequency, three-dimensional numerical ground shaking simulations and data-driven multivariate analyses to examine how landslides evolved from the coseismic to post-seismic periods. Our findings reveal a spatial shift in landslide distribution, in which the mainshock triggered slope failures predominantly on steep hillslopes, and the aftershocks triggered landslides on gentler slopes, often near geologic boundaries. We attribute this transition partly to the earthquake legacy effect of the mainshock, where the mainshock caused weakening of these hillslopes, making them more prone to failure when aftershocks occur. Additionally, the concentration of failures along geologic contacts in the post-seismic phase suggests that site amplification, stemming from contrasts in subsurface materials, exerts a key influence on landslide occurrence. Although not explicitly captured in our current numerical simulations, this mechanism warrants further investigation for more accurate hazard modeling.

JGR Solid Earth

Colored shaded-relief bathymetric and acoustic-backscatter maps of Jenkinson Lake with orthomosaic of the Sly Park Creek and Hazel Creek area, California

The Caldor Fire was ignited on August 14, 2021, and burned almost 222,000 acres (898 square kilometers) in forested terrain of the central and western Sierra Nevada, California. During the subsequent two months, the fire burned nearly all of Sly Park Creek watershed in El Dorado County. The El Dorado Irrigation District manages the water supply for the area using storage in Jenkinson Lake, a 1.6-kilometer- (1.0-mile-) wide and 3.6-kilometer- (2.2-mile-) long reservoir, located south of the town of Pollock Pines. Several weeks after the fire, the U.S. Geological Survey began investigations into post-fire landscape responses, including sediment yield, by measuring new sediment deposition in Jenkinson Lake. This study focused on the collection and processing of bathymetric and acoustic-backscatter data, as well as onshore aerial imagery in and around Jenkinson Lake, to support wildfire science after the Caldor Fire. A colored shaded-relief bathymetric map (sheet 1) and an acoustic backscatter map (sheet 2) show the lake floor morphology and backscatter intensities.

California

An environmental assessment of impacts of coal development on the water resources of the Yampa River basin, Colorado and Wyoming; Phase I work plan

Coal resources of the western United States are being developed at ever-increasing rates, causing concerns of the effects of mining and associated activities on the environment. The Yampa River basin in northwestern Colorado and south-central Wyoming is undergoing economic development of its coal, oil and gas, and uranium resources. The Yampa River basin assessment is a 21-year program of the U.S. Geological Survey. It is designed primarily to assess the availability and quality of the basin's water resources. The basin assessment also will evaluate potential environmental and selected socioeconomic impacts of energy-resource development plans proposed by mining and power companies. This report serves as a project work plan for the basin assessment's first-phase work activities. Economic development in the Yampa River basin will result in higher levels of residuals (noneconomic byproducts) being discharged into the environment. Residuals-management encompasses the technological and economic interrelationships that should be considered in order to comply with Federal and State environmental-control regulations regarding air quality, water quality, and disposal of solid wastes. The basin assessment, the first phase that is described by this report, is designed to provide Federal, State, and local decision-makers with the basic environmental information needed to formulate and to evaluate policies for the development of energy resources. The techniques applied and conclusions reached in the Yampa River basin assessment should aid similar studies of other energy-rich basins in the western United States.

Colorado, Wyoming

A comprehensive fault system inversion approach: Methods and application to NSHM23

We present updated inversion‐based fault‐system solutions for the 2023 update to the National Seismic Hazard Model (NSHM23), standardizing earthquake rate model calculations on crustal faults across the western United States. We build upon the inversion methodology used in the Third Uniform California Earthquake Rupture Forecast (UCERF3) to solve for time‐independent rates of earthquakes in an interconnected fault system. The updated model explicitly maps out a wide range of fault recurrence and segmentation behavior (epistemic uncertainty), more completely exploring the solution space of viable models beyond those of UCERF3. We also improve the simulated annealing implementation, greatly increasing computational efficiency (and thus inversion convergence), and introduce an adaptive constraint weight calculation algorithm that helps to mediate between competing constraints. Hazard calculations show that ingredient changes (especially fault and deformation models) are the primary driver of hazard changes between NSHM23 and UCERF3. Updates to the inversion methodology are also consequential near faults in which the slip rate in UCERF3 was poorly fit or was satisfied primarily using large multifault ruptures that are now restricted by explicit b ‐value and segmentation constraints.

Bulletin of the Seismological Society of America

Earthquake rupture arrest from depth‐dependent frictional stability on the Pütürge segment of the East Anatolian Fault Zone, Türkiye (Turkey)

Determining why earthquake ruptures stop is a central challenge in earthquake science and seismic hazard assessment. The Pütürge segment of the East Anatolian Fault Zone, Türkiye, exhibits shallow creep (<∼3 km depth) yet hosts M > 6.5 earthquake ruptures at greater depth. Here, we evaluate whether variations in frictional stability along this segment aided arrest of the 2020 M 6.7 Elaziğ and 2023 M 7.8 Pazarcık earthquake ruptures. Analysis of Sentinel‐1 Synthetic Aperture Radar imagery indicates the 2023 M 7.8 rupture propagated laterally into a metamorphic massif within the Pütürge segment, where slip rapidly decayed below detection limits. Creepmeters along this segment recorded no significant surface afterslip (<3 mm) in the following year. To investigate this fault‐slip behavior, we conducted triaxial friction experiments on Pütürge fault gouge sampled from an outcrop exposure. The gouge, composed primarily of muscovite, quartz, and calcite, is velocity strengthening at conditions approximating 0–2.5 km depth and velocity weakening at 4–5 km depth. This transition to velocity‐weakening friction is associated with enhanced comminution and shear localization observed microstructurally. Our results suggest that depth‐dependent frictional stability of the Pütürge fault segment facilitates rupture nucleation and propagation at depth while maintaining rupture‐arresting behavior near Earth’s surface.

Pütürge segment of the East Anatolian Fault Zone

Microbial ecology of permafrost soils: Populations, processes, and perspectives

Permafrost microbial research has flourished in the past decades, due in part to improvements in sampling and molecular techniques, but also the increased focus on the permafrost greenhouse gas feedback to climate change and other ecological processes in high latitude and alpine permafrost soils. Permafrost microorganisms are adapted to these extreme environments and remain active at low temperatures and when resources are limited. They are also an important component of global elemental cycles as they regulate organic matter turnover and greenhouse gas production, particularly as permafrost thaws. Here we review the permafrost microbiology literature coupled with an exploration of its historical aspects, with a particular focus on a new understanding advanced by molecular biology techniques. We further identify knowledge gaps and ways forward to improve our understanding of microbial contributions to ecosystem biogeochemistry of permafrost-affected systems.

Permafrost and Periglacial Processes

Precariously balanced rocks in northern New York and Vermont, U.S.A.: Ground-motion constraints and implications for fault sources

Precariously balanced rocks (PBRs) and other fragile geologic features have the potential to constrain the maximum intensity of earthquake ground shaking over millennia. Such constraints may be particularly useful in the eastern United States (U.S.), where few earthquake‐source faults are reliably identified, and moderate earthquakes can be felt at great distances due to low seismic attenuation. We describe five PBRs in northern New York and Vermont—a region of elevated seismic hazard associated with historical seismicity. These boulders appear to be among the most fragile PBRs in the region, based on reports from hobbyists. The PBRs are glacial erratics, best evidenced by glacial striations on bedrock pedestals. The pedestals themselves are locally high knobs, often situated on regionally high topography; this setting limits soil development and indicates that any outwash deposits were likely ephemeral. As a result, PBR ages can be reliably established by the retreat of the last continental ice sheet, ∼15–13 ka. To quantify the fragility of the PBRs, we surveyed them with ground‐based light detection and ranging and calculated geometric parameters from the point clouds, field observations, and seismic responses. Preliminary validation of the 2023 time‐independent U.S. National Seismic Hazard Model (NSHM) shows that the existence of PBRs is generally consistent with the median site‐specific hazard curves. Only the Blue Ridge Road site suggests a modest reduction in hazard. To visualize the ensemble of data, we mapped the minimum permissible distance to potential source faults around each PBR site as a function of source magnitude by using the ground‐motion models from the 2023 NSHM. Viewed in this manner, our data are consistent with potential M ∼6.5 earthquake‐source faults in many parts of the Lake Champlain Valley and northern Adirondack Mountains. Our work illustrates a potential pathway for better constraining earthquake‐source faults in regions of cryptic faults.

Bulletin of the Seismological Society of America

A newly identified creeping strand of the Concord fault, San Francisco Bay Area

The Concord fault constitutes a major branch of the Pacific–North America transform plate boundary in Northern California, bridging the strike‐slip Bartlett Springs ‐ Green Valley Fault system to the north with the Greenville and Calaveras Faults to the south. Like many faults in the San Francisco Bay Area its long‐term slip is partially accommodated by aseismic slip (creep). Although creep has been recognized and monitored on the northern half of the fault for decades, the precise location of the southern half of the fault and its slip rate—whether accommodated seismically or aseismically—has remained enigmatic. How slip transfers between the Concord and Greenville or Calaveras faults to the south remains an outstanding question. New field observations presented here indicate that the active trace of the fault south of downtown Concord is not where previously interpreted and is indeed actively creeping. We report observations of shallow creep continuing >7 km farther south along the Concord fault than previously reported, along a fault strand not previously recognized for most of its length. This is evident as right‐laterally deflected concrete curbs and sidewalk slabs on both sides of every street that crosses the fault at a high angle in southeast Concord and northeast Walnut Creek. We document the magnitude and location of these deflections to estimate accumulated right‐lateral aseismic slip expressed in engineered structures. Offsets of these piercing lines range from 8 to 18 cm, over widths varying from narrow breaks along centimeter‐scale concrete joints to 10‐m‐wide zones of deflection. Significantly, this active trace is ∼400 m west of where the Quaternary active trace has previously been inferred, placing it within—rather than bounding—the built area of suburban Concord. Slip along the fault has already caused infrastructure damage. These results revise our understanding of the southern Concord fault and help constrain its seismic potential.

California

Utilization of multiple geochronology techniques to constrain the age of laterization and mineralization of the world-class Mount Weld rare earth element deposit, Western Australia

Pervasive chemical weathering on stable cratons may form thick regoliths and elemental enrichment, but constraining the age of regolith formation is challenging. In this study we utilize multiple geochronological techniques on different minerals from the world-class Mount Weld rare earth element (REE) deposit, formed by lateritic weathering of a carbonatite, to constrain the age of formation and provide insight into landscape evolution. The oldest dates, ca. 100 to 38 Ma, are from Lu-Hf dating of churchite [HREE(PO 4 )·2(H 2 O)], a heavy REE phosphate mineral. Growth bands on individual minerals show a younging outwards. 40 Ar/ 39 Ar geochronology of cryptomelane [K(Mn 4+ ,Mn 2+ )₈O₁₆] yielded dates from ca. 40 to 27 Ma. Similarly, (U-Th)/He geochronology of goethite [FeO(OH)] yielded dates ranging from ca. 45 to 19 Ma. Integrating results into regional constraints, suggests 1) churchite formed by mineral saturation in a karst-like setting below the water table from ca. 100 to 40 Ma, 2) with minor uplift and erosion, cryptomelane and goethite formed at or near the water table between ca. 45 and 19 Ma, 3) after ca. 15 to 10 Ma chemical weathering within the profile had ended. Other studies document that the region experienced minimal uplift and a wet, warm climate from ca. 100 Ma to 15 Ma. These conditions and the high carbonate content of the carbonatite promote extensive chemical weathering, a deep weathering profile, and the preservation of the weathered section. This study highlights the use of multiple geochronological techniques utilizing different minerals to provide insight into how laterites form and to constrain the timing and history of the formation of this important mineral deposit.

Western Australia

Hydrogeologic framework and conceptual groundwater-flow model of the panhandle and northwest parts of the High Plains (Ogallala) aquifer in Oklahoma, 1998–2022

This study was conducted by the U.S. Geological Survey, in cooperation with the Oklahoma Water Resources Board, to update the hydrogeologic framework and conceptual flow model for the panhandle and northwest parts of the High Plains (Ogallala) aquifer in Oklahoma, which together compose the Ogallala aquifer focus area. The study included the construction of a potentiometric surface, and available geologic and hydrologic data were used to evaluate saturated thickness of the aquifer. The water budget for the updated conceptual groundwater-​flow model was based on estimated inflows and outflows for the 1998–2022 study period. Saturated thickness of the Ogallala aquifer averaged 127 and 116 feet for the panhandle and northwest parts, respectively. Groundwater withdrawals from the Ogallala aquifer for 1998–2022 averaged 422,054 and 39,645 acre-feet per year (acre-ft/yr) for the panhandle and northwest parts, respectively. Recharge, the primary inflow, was estimated at 0.63 inch per year for the 1998–2022 study period, with the panhandle part of the Ogallala aquifer receiving 175,068 acre-ft/yr and the northwest part of the Ogallala aquifer receiving 49,376 acre-ft/yr. Additional inflows included irrigation return flows, estimated at 8,111 and 642 acre-ft/yr for the panhandle and northwest parts, respectively, of the Ogallala aquifer. Net lateral groundwater flows, considered to be aquifer outflows, were estimated to account for 31,908 acre-ft/yr for the Ogallala aquifer focus area. Streambed seepage, which was an outflow of 5,535 acre-ft/yr, was only present in the northwest part of the Ogallala aquifer. Vertical leakage and saturated-zone evapotranspiration were considered negligible outflows. These findings provide a revised conceptual groundwater-flow model water budget for the Ogallala aquifer focus area in Oklahoma.

Colorado, Kansas, Oklahoma, Texas

Metaproteomics and metagenomics reveal microbial pathways of organic matter degradation and methanogenesis in a marginally producing natural gas well

The expansion of natural gas production and utilization worldwide has led to the decline of many once-productive wells, eventually resulting in costly well-plugging and unused infrastructure. However, in areas like the Michigan basin, MI, where the majority of natural gas is biogenically produced, microbial communities could potentially be stimulated to generate additional methane, increasing gas supply and reducing the need to drill new wells. In this study, we performed metaproteomic, metagenomic, and geochemical analyses of Antrim Shale formation water from a marginally producing natural gas well to evaluate resident microbial community functions in the context of potential bioenergy production. Functional proteins involved in methanogenesis, degradation/catabolism (including organic matter degradation), biosynthesis, energy utilization, transmembrane transport, and stress response were among the most commonly identified groups. Three metagenome-assembled genomes (MAGs) were characterized, including Methanomicrobiaceae, Methanothrix , and Smithella . For each, the identified proteins involved in methanogenesis and the degradation of diverse organic compounds, strongly suggest their role in utilizing shale-derived organic matter. These findings provide an increased understanding of the microorganisms and their metabolisms generating natural gas in the Antrim Shale and establish a foundation for future stimulation efforts aimed at enhancing biogenic methane production in marginal gas wells.

Michigan

Global variability of the composition and temperature at the 410-km discontinuity from receiver function analysis of dense arrays

Seismic boundaries caused by phase transitions between olivine polymorphs in Earth's mantle provide thermal and compositional markers that inform mantle dynamics. Seismic studies of the mantle transition zone often use either global averaging with sparse arrays or regional sampling from a single dense array. The intermediate approach of this study utilizes many densely spaced seismic arrays distributed around the globe. We systematically compute teleseismic P-to-S receiver functions for each seismic array and invert for the 1-D seismic velocity structure of the mantle transition zone beneath each array to facilitate a comparison between densely sampled regions. We stack 3,600 receiver functions on average at 67 arrays in total. The stack is used in a probabilistic inversion to estimate the mantle transition zone interface depths and velocities beneath each array. We focus on the 410-km discontinuity (410) because it is a prominent seismic interface that is clearly linked to a single mineral phase transition between olivine and wadsleyite. The depths and velocity contrasts of the 410 are mapped to temperatures and compositions using mineral physics constraints. The depth of the 410 ranges from ∼405–440 km, which is consistent with a ∼360 K temperature range in a dry mantle and a ∼260 K temperature range in a wet mantle (2 wt. % water). The Vs contrast across the 410 ranges from ∼2.5–8 %, which is consistent with ∼20–70 vol. % olivine composition in a dry mantle and ∼25–80 vol. % in a wet mantle. The bulk composition of the upper mantle near the 410-km discontinuity is typically considered to be well-mixed because there is no thermodynamic impediment to convection at the olivine to wadsleyite phase transition. However, the wide range of inferred olivine content from our study suggests that there are large lateral variations in the bulk composition of the upper mantle near the 410-km discontinuity.

Earth and Planetary Science Letters