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At least 595 records · Page 33Linked to original sources

Nitrogen isotopes as indicators of NOx source contributions to atmospheric nitrate deposition across the midwestern and northeastern United States

Global inputs of NO x are dominated by fossil fuel combustion from both stationary and vehicular sources and far exceed natural NO x sources. However, elucidating NO x sources to any given location remains a difficult challenge, despite the need for this information to develop sound regulatory and mitigation strategies. We present results from a regional-scale study of nitrogen isotopes (δ 15 N) in wet nitrate deposition across 33 sites in the midwestern and northeastern U.S. We demonstrate that spatial variations in δ 15 N are strongly correlated with NO x emissions from surrounding stationary sources and additionally that δ 15 N is more strongly correlated with surrounding stationary source NO x emissions than pH, SO 4 2- , or NO 3 - concentrations. Although emission inventories indicate that vehicle emissions are the dominant NO x source in the eastern U.S., our results suggest that wet NO 3 - deposition at sites in this study is strongly associated with NO x emissions from stationary sources. This suggests that large areas of the landscape potentially receive atmospheric NO y deposition inputs in excess of what one would infer from existing monitoring data alone. Moreover, we determined that spatial patterns in δ 15 N values are a robust indicator of stationary NO x contributions to wet NO 3 - deposition and hence a valuable complement to existing tools for assessing relationships between NO 3 - deposition, regional emission inventories, and for evaluating progress toward NO x reduction goals.

Connecticut, Maine, Massachusetts, New Hampshire, ↗

Nitrate in the Mississippi River and its tributaries, 1980 to 2008: Are we making progress?

Changes in nitrate concentration and flux between 1980 and 2008 at eight sites in the Mississippi River basin were determined using a new statistical method that accommodates evolving nitrate behavior over time and produces flow-normalized estimates of nitrate concentration and flux that are independent of random variations in streamflow. The results show that little consistent progress has been made in reducing riverine nitrate since 1980, and that flow-normalized concentration and flux are increasing in some areas. Flow-normalized nitrate concentration and flux increased between 9 and 76% at four sites on the Mississippi River and a tributary site on the Missouri River, but changed very little at tributary sites on the Ohio, Iowa, and Illinois Rivers. Increases in flow-normalized concentration and flux at the Mississippi River at Clinton and Missouri River at Hermann were more than three times larger than at any other site. The increases at these two sites contributed much of the 9% increase in flow-normalized nitrate flux leaving the Mississippi River basin. At most sites, concentrations increased more at low and moderate streamflows than at high streamflows, suggesting that increasing groundwater concentrations are having an effect on river concentrations.

Illinois, Iowa, Louisiana, Missouri↗

The ecology of arsenic

Arsenic is a metalloid whose name conjures up images of murder. Nonetheless, certain prokaryotes use arsenic oxyanions for energy generation, either by oxidizing arsenite or by respiring arsenate. These microbes are phylogenetically diverse and occur in a wide range of habitats. Arsenic cycling may take place in the absence of oxygen and can contribute to organic matter oxidation. In aquifers, these microbial reactions may mobilize arsenic from the solid to the aqueous phase, resulting in contaminated drinking water. Here we review what is known about arsenic-metabolizing bacteria and their potential impact on speciation and mobilization of arsenic in nature.

Science↗

Editorial: From cold seeps to hydrothermal vents: Geology, chemistry, microbiology, and ecology in marine and coastal environments

This Research Topic compiles contemporary studies on cold seeps, hydrothermal vents, mud volcanoes, and related seafloor features that are associated with focused fluid emissions and the transfer of carbon, other chemical species, and sometimes heat from the geosphere to the ocean. Because these features sometimes tap fluids and gas originating kilometers below the seafloor, they provide an important window into deep processes that are otherwise inaccessible to scientists. At the shallow portion of their journey, migrating fluids nearing the seafloor contribute to a range of unique biological, physical, and chemical processes within the sediments themselves and at the sediment-water interface. Seafloor fluid emissions play a critical role in global biogeochemical cycles, ocean chemistry, and possibly even climate change. Seafloor leakage points often emit hydrocarbon gases (especially methane and CO 2 ) and are sometimes the loci for deposition of seafloor minerals that have economic value. A burgeoning area of research focuses on natural products generated at these features, seeking compounds with potential pharmaceutical or other applications. Multidisciplinary studies have become routine for characterization of seafloor fluid emission sites, attesting to the inseparability of geologic, physical, chemical, and biological processes in these settings. It is increasingly common for researchers to combine in a single research cruise: subbottom imaging and seafloor mapping; porewater and water column geochemistry and gas sampling; sediment retrieval for lithologic, biostratigraphic, and solid phase analyses; and studies of benthic and subseafloor communities at the microbial to macrofaunal scales. This multidisciplinary approach has the advantage of ensuring the spatial and temporal coincidence of surveys and samples, an important factor at highly dynamic seafloor fluid emission sites. In addition, researchers often use remotely operated vehicles (ROVs), autonomous underwater vehicles (AUVs), or human-occupied vehicles (HOVs) to record video of the seafloor, compile photomosaics, collect targeted samples, and survey with high-resolution geophysical near-seafloor systems, providing a degree of detail about seafloor fluid emission sites that is unprecedented compared to most areas of the deep ocean. While rarer, long-term cabled observatories or shorter-term deployments of portable observatories are also used at some loci for seafloor fluid flux and are particularly helpful for capturing temporal variations at these dynamic features. Here we summarize the Research Topic’s contribution to multidisciplinary seafloor emission studies in the categories of cold seeps, mud volcanoes, and hydrothermal vents. Figure 1 shows the geographic distribution of the studies in this Research Topic and key features referred to in this Introduction.

Frontiers in Earth Science↗

Loads of nitrate, phosphorus, and total suspended solids from Indiana watersheds

Transport of excess nutrients and total suspended solids (TSS) such as sediment by freshwater systems has led to degradation of aquatic ecosystems around the world. Nutrient and TSS loads from Midwestern states to the Mississippi River are a major contributor to the Gulf of Mexico Hypoxic Zone, an area of very low dissolved oxygen concentration in the Gulf of Mexico. To better understand Indiana’s contribution of nutrients and TSS to the Mississippi River, annual loads of nitrate plus nitrite as nitrogen, total phosphorus, and TSS were calculated for nine selected watersheds in Indiana using the load estimation model, S-LOADEST. Discrete water-quality samples collected monthly by the Indiana Department of Environmental Management’s Fixed Stations Monitoring Program from 2000–2010 and concurrent discharge data from the U. S. Geological Survey streamflow gages were used to create load models. Annual nutrient and TSS loads varied across Indiana by watershed and hydrologic condition. Understanding the loads from large river sites in Indiana is important for assessing contributions of nutrients and TSS to the Mississippi River Basin and in determining the effectiveness of best management practices in the state. Additionally, evaluation of loads from smaller upstream watersheds is important to characterize improvements at the local level and to identify priorities for reduction.

Proceedings of the Indiana Academy of Science↗

Environmental conditions synchronize waterbird mortality events in the Great Lakes

Since the 1960s, periodic outbreaks of avian botulism type E have contributed to large-scale die-offs of thousands of waterbirds throughout the Great Lakes of the United States. In recent years, these events have become more common and widespread. Occurring during the summer and autumn months, the prevalence of these die-offs varies across years and is often associated with years of warmer lake temperatures and lower water levels. Little information exists on how environmental conditions mediate the spatial and temporal characteristics of mortality events. In 2010, a citizen science programme, Avian Monitoring for Botulism Lakeshore Events (AMBLE), was launched to enhance surveillance efforts and detect the appearance of beached waterbird carcasses associated with avian botulism type E outbreaks in northern Lake Michigan. Using these data, our goal was to quantify the within-year characteristics of mortality events for multiple species, and to test whether the synchrony of these events corresponded to fluctuations in two environmental factors suspected to be important in the spread of avian botulism: water temperature and the prevalence of green macroalgae. During two separate events of mass waterbird mortality, we found that the detection of bird carcasses was spatially synchronized at scales of c . 40 km. Notably, the extent of this spatial synchrony in avian mortality matched that of fluctuations in lake surface water temperatures and the prevalence of green macroalgae. Synthesis and applications . Our findings are suggestive of a synchronizing effect where warmer lake temperatures and the appearance of macroalgae mediate the characteristics of avian mortality. In future years, rising lake temperatures and a higher propensity of algal masses could lead to increases in the magnitude and synchronization of avian mortality due to botulism. We advocate that citizen-based monitoring efforts are critical for identifying the potential environmental conditions associated with widespread mortality events and estimating future risk to waterbird populations.

Journal of Applied Ecology↗

Tree Cover Mapping Tool—Documentation and user manual

The Tree Cover Mapping (TCM) tool was developed by scientists at the U.S. Geological Survey Earth Resources Observation and Science Center to allow a user to quickly map tree cover density over large areas using visual interpretation of high resolution imagery within a geographic information system interface. The TCM tool uses a systematic sample grid to produce maps of tree cover. The TCM tool allows the user to define sampling parameters to estimate tree cover within each sample unit. This mapping method generated the first on-farm tree cover maps of vast regions of Niger and Burkina Faso. The approach contributes to implementing integrated landscape management to scale up re-greening and restore degraded land in the drylands of Africa. The TCM tool is easy to operate, practical, and can be adapted to many other applications such as crop mapping, settlements mapping, or other features. This user manual provides step-by-step instructions for installing and using the tool, and creating tree cover maps. Familiarity with ArcMap tools and concepts is helpful for using the tool.

Open-File Report↗

Coastal loading and transport of Escherichia coli at an embayed beach in Lake Michigan

A Chicago beach in southwest Lake Michigan was revisited to determine the influence of nearshore hydrodynamic effects on the variability of Escherichia coli (E. coli) concentration in both knee-deep and offshore waters. Explanatory variables that could be used for identifying potential bacteria loading mechanisms, such as bed shear stress due to a combined wave-current boundary layer and wave runup on the beach surface, were derived from an existing wave and current database. The derived hydrodynamic variables, along with the actual observed E. coli concentrations in the submerged and foreshore sands, were expected to reveal bacteria loading through nearshore sediment resuspension and swash on the beach surface, respectively. Based on the observation that onshore waves tend to result in a more active hydrodynamic system at this embayed beach, multiple linear regression analysis of onshore-wave cases further indicated the significance of sediment resuspension and the interaction of swash with gull-droppings in explaining the variability of E. coli concentration in the knee-deep water. For cases with longshore currents, numerical simulations using the Princeton Ocean Model revealed current circulation patterns inside the embayment, which can effectively entrain bacteria from the swash zone into the central area of the embayed beach water and eventually release them out of the embayment. The embayed circulation patterns are consistent with the statistical results that identified that 1) the submerged sediment was an additional net source of E. coli to the offshore water and 2) variability of E. coli concentration in the knee-deep water contributed adversely to that in the offshore water for longshore-current cases. The embayed beach setting and the statistical and numerical methods used in the present study have wide applicability for analyzing recreational water quality at similar marine and freshwater sites. ?? 2010 American Chemical Society.

Environmental Science & Technology↗

Family size and effective population size in a hatchery stock of coho salmon ( Oncorhynchus kisutch )

Means and variances of family size measured in five year-classes of wire-tagged coho salmon ( Oncorhynchus kisutch ) were linearly related. Population effective size was calculated by using estimated means and variances of family size in a 25-yr data set. Although numbers of age 3 adults returning to the hatchery appeared to be large enough to avoid inbreeding problems (the 25-yr mean exceeded 4500), the numbers actually contributing to the hatchery production may be too low. Several strategies are proposed to correct the problem perceived. Argument is given to support the contention that the problem of effective size is fairly general and is not confined to the present study population.

Canadian Journal of Fisheries and Aquatic Sciences↗

Notes on status and ecology of the endangered Hawaiian annual Awiwi, Centaurium sebaeoides (Gentianaceae)

The annual, endemic, coastal herb Centaurium sebaeoides is the only native Hawaiian species in the gentian family. The U.S. Fish and Wildlife Service listed it as Endangered under the Endangered Species Act on 29 October 1991. Before surveys reported here, the total population of this species statewide was estimated at 80-110 individuals in eight populations. During counts made in April and May 1997, following ample winter rains, 12 populations of C. sebaeoides with a total of 6300-6600 plants were noted on five islands (Kaua'i, O'ahu, Lana'i, Moloka'i, and Maui). Five populations were mapped with a global positioning system and counted; in the remaining seven populations, the numbers of individuals were estimated. More recent surveys in 1998-1999 estimated a total of only 60-80 individuals at all sites. Such dramatic population fluctuations are believed to be related to the sporadic occurrence of winter rains. Threats that further contribute to the rarity of the species include (1) displacement and overtopping by salt-tolerant nonnative woody species, especially Casuarina spp ., (2) trampling and erosion of habitat by ungulates, and (3) damage caused by off-road vehicles.

Hawaii↗

Don Swanson: A field volcanology career worth celebrating

Don Swanson has profoundly influenced generations of volcanologists and has made major contributions to our understanding of both silicic and basaltic volcanic systems. He provides an exceptional example of how a gifted scientist can develop entirely new paradigms related to large-scale problems on the basis of decades of study, as exemplified by his work on the emplacement of flood basalts, monitoring and forecasting volcanic eruptions, the development of lava flows and domes, and the explosive nature of Kīlauea Volcano. Don has maintained exceptional productivity even while playing major leadership and management roles in science, and his research is intrinsically geological and rooted in painstaking fieldwork that is both collaborative and interdisciplinary. This volume recognizes Don’s career accomplishments by emphasizing his careful approach to volcanology and highlighting meticulous field observations as the basis for better understanding how volcanoes work.

Special Papers of the Geological Society of Americ↗

Field volcanology: A tribute to the distinguished career of Don Swanson

Don Swanson has profoundly influenced generations of volcanologists and has made major contributions to our understanding of both silicic and basaltic volcanic systems. He provides an exceptional example of how a gifted scientist can develop entirely new paradigms related to large-scale problems on the basis of decades of study, as exemplified by his work on the emplacement of flood basalts, monitoring and forecasting volcanic eruptions, the development of lava flows and domes, and the explosive nature of Kīlauea Volcano. Don has maintained exceptional productivity even while playing major leadership and management roles in science, and his research is intrinsically geological and rooted in painstaking fieldwork that is both collaborative and interdisciplinary. This volume recognizes Don’s career accomplishments by emphasizing his careful approach to volcanology and highlighting meticulous field observations as the basis for better understanding how volcanoes work.

Special Papers of the Geological Society of Americ↗

Amphibian and reptile conservation in the United States of America

Wildlife stewardship is of utmost importance in the United States, where management for sustainable natural resources is extended to native species including amphibians and reptiles. The U.S. wildlife conservation framework is a nested system of authorities regulating species and habitats, science-based management and policy decisions, and adaptive management as new knowledge is applied to improve outcomes of population- and habitat-management actions. Yet the approach has evolved through time, from single-species management of game species to the conservation of entire ecosystems and the biodiversity they support. Today, the mismatch of conservation ideals with conservation capacity puts nongame species like amphibians and reptiles in the crosshairs for losses due to insufficient resources to address growing numbers of threats. Despite these challenges, optimism prevails, as the management and conservation of U.S. herpetofauna is an increasing priority of the public, with considerable investment into habitat restoration, species-specific threat mitigation, research, public outreach, and education. Herein, we outline key elements of U.S. herpetological conservation efficacy: (1) a web of legal authorities governing the management of U.S. herpetofauna and their habitats; (2) a network of people and organizations that work toward filling priority knowledge gaps by conducting scientific research and that are actively engaged in the science-management interface for species-to-ecosystem level conservation decision-making, and (3) a learning framework of adaptive management within the legal landscape (“lawscape”) and for improving effectiveness of conservation actions. Lastly, the human dimension of species conservation in the U.S. is emerging, where bottom-up local efforts are having success in addition to state- and regional-scale approaches. We propose U.S. herpetological conservation priorities under three themes: threats, research, and human dimensions (people). Together these multifaceted efforts are contributing to advances in the maintenance of U.S. amphibian and reptile diversity. The success of these efforts is notable and could be viewed as a model system, where lessons learned may apply elsewhere.

Book chapter↗

OpenCLC: An open-source software tool for similarity assessment of linear hydrographic features

The National Hydrography Dataset (NHD) is a foundational geospatial data source in the United States that enables extensive and diverse environmental research and supports decision-making in numerous contexts. However, the NHD requires regular validation and update given possible inconsistent initial collection and hydrographic changes. Furthermore, systems or tools that use NHD data must manage regular updates that occur within the high-resolution version of the NHD (NHD HR). This research contributes to filling this gap by establishing an open-source software tool named OpenCLC, which automatically identifies matching and mismatching line features between two sets of hydrographic flowlines. Aside from identifying differences among two version of NHD lines, results can be applied to improve the quality of NHD HR content. OpenCLC significantly outperforms the best available commercial off-the-shelf software in computational scalability, and it is made widely available as part of the CyberGIS Toolkit to benefit broad environmental and geospatial science communities.

SoftwareX↗

Modeling the probability of arsenic in groundwater in New England as a tool for exposure assessment

We developed a process-based model to predict the probability of arsenic exceeding 5 ??g/L in drinking water wells in New England bedrock aquifers. The model is being used for exposure assessment in an epidemiologic study of bladder cancer. One important study hypothesis that may explain increased bladder cancer risk is elevated concentrations of inorganic arsenic in drinking water. In eastern New England, 20-30% of private wells exceed the arsenic drinking water standard of 10 micrograms per liter. Our predictive model significantly improves the understanding of factors associated with arsenic contamination in New England. Specific rock types, high arsenic concentrations in stream sediments, geochemical factors related to areas of Pleistocene marine inundation and proximity to intrusive granitic plutons, and hydrologic and landscape variables relating to groundwater residence time increase the probability of arsenic occurrence in groundwater. Previous studies suggest that arsenic in bedrock groundwater may be partly from past arsenical pesticide use. Variables representing historic agricultural inputs do not improve the model, indicating that this source does not significantly contribute to current arsenic concentrations. Due to the complexity of the fractured bedrock aquifers in the region, well depth and related variables also are not significant predictors. ?? 2006 American Chemical Society.

Environmental Science & Technology↗

Acid rain effects on aluminum mobilization clarified by inclusion of strong organic acids

Assessments of acidic deposition effects on aquatic ecosystems have often been hindered by complications from naturally occurring organic acidity. Measurements of pH and ANCG, the most commonly used indicators of chemical effects, can be substantially influenced by the presence of organic acids. Relationships between pH and inorganic Al, which is toxic to many forms of aquatic biota, are also altered by organic acids. However, when inorganic Al concentrations are plotted against ANC (the sum of Ca2+, Mg 2+, Na+, and K+, minus SO42-, NO3-, and Cl-), a distinct threshold for Al mobilization becomes apparent. If the concentration of strong organic anions is included as a negative component of ANC, the threshold occurs at an ANC value of approximately zero, the value expected from theoretical charge balance constraints. This adjusted ANC is termed the base-cation surplus. The threshold relationship between the base-cation surplus and Al was shown with data from approximately 200 streams in the Adirondack region of New York, during periods with low and high dissolved organic carbon concentrations, and for an additional stream from the Catskill region of New York. These results indicate that (1) strong organic anions can contribute to the mobilization of inorganic Al in combination with SO42- and NO 3-, and (2) the presence of inorganic Al in surface waters is an unambiguous indication of acidic deposition effects. ?? 2007 American Chemical Society.

Environmental Science & Technology↗

A seascape-scale habitat model to support management of fishing impacts on benthic ecosystems

Minimizing fishing impacts on seafloor ecosystems is a growing focus of ocean management; however, few quantitative tools exist to guide seascape-scale habitat management. To meet these needs, we developed a model to assess benthic ecosystem impacts from fishing gear contact. The habitat impacts model is cast in discrete time and can accommodate overlapping fisheries as well as incorporate gear-specific contact dynamics. We implemented the model in the North Pacific using fishing data from 2003 to 2017, estimating that habitat in 3.1% of the 1.2 million km 2 study area was disturbed at the end of the simulation period. A marked decline in habitat disturbance was evident since 2010, attributable to a single regulatory gear change that lifted trawl gear components off the seafloor. Running scenarios without these gear modifications showed these policies might have contributed to a 24% reduction in habitat disturbance since their implementation. Ultimately, model outputs provide direct estimates of the spatial and temporal trends of habitat effects from fishing — a key component of regulatory policies for many of the world’s fisheries.

Canadian Journal of Fisheries and Aquatic Sciences↗

Cross-scale assessment of potential habitat shifts in a rapidly changing climate

We assessed the ability of climatic, environmental, and anthropogenic variables to predict areas of high-risk for plant invasion and consider the relative importance and contribution of these predictor variables by considering two spatial scales in a region of rapidly changing climate. We created predictive distribution models, using Maxent, for three highly invasive plant species (Canada thistle, white sweetclover, and reed canarygrass) in Alaska at both a regional scale and a local scale. Regional scale models encompassed southern coastal Alaska and were developed from topographic and climatic data at a 2 km (1.2 mi) spatial resolution. Models were applied to future climate (2030). Local scale models were spatially nested within the regional area; these models incorporated physiographic and anthropogenic variables at a 30 m (98.4 ft) resolution. Regional and local models performed well (AUC values > 0.7), with the exception of one species at each spatial scale. Regional models predict an increase in area of suitable habitat for all species by 2030 with a general shift to higher elevation areas; however, the distribution of each species was driven by different climate and topographical variables. In contrast local models indicate that distance to right-of-ways and elevation are associated with habitat suitability for all three species at this spatial level. Combining results from regional models, capturing long-term distribution, and local models, capturing near-term establishment and distribution, offers a new and effective tool for highlighting at-risk areas and provides insight on how variables acting at different scales contribute to suitability predictions. The combinations also provides easy comparison, highlighting agreement between the two scales, where long-term distribution factors predict suitability while near-term do not and vice versa.

Alaska↗