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At least 577 records · Page 32Linked to original sources

Intensity and duration of chemical weathering: An example from soil clays of the southeastern Koolau Mountains, Oahu, Hawaii

Orographic precipitation on the southern flank of the southeastern Koolau Mountains produces a pronounced precipitation gradient. The corresponding gradient in the intensity of the chemical weathering environment provides an opportunity to address the effects of varying chemical weathering intensity on the composition of clay-size weathering products in soils developed on basalt. In addition, little-modified remnants of the constructional surface of the Koolau Volcano, isolated by stream dissection, remain as facets on the southern ends of the parallel ridges of the study area. By comparing clay mineralogy of soils developed on these older geomorphic surfaces with those developed on the younger sharp-crested ridges and steep side slopes, the effects of weathering duration on clay mineralogy can also be addressed. Soil clays in this part of the Koolau Mountains are mineralogically complex; principal phases include smectite, kaolinite, and halloysite, but pure end member phases are uncommon. Rather, most phases contain some amount of mixed layering. Smectite may contain small (<5%) amounts of randomly interstratified halloysite. Similarly, kaolinite commonly contains a small proportion of halloysite interlayers. A complex halloysitic phase shows evidence of interstratification with both smectite and kaolinite. Nonphyllosilicates found in the clay fraction include gibbsite, goethite, rare quartz, and perhaps cristobalite. The gradient in precipitation is reflected in soil clay mineralogy by varying proportions of dominantly smectitic, kaolinitic, and halloysitic phases. In regions of relatively low precipitation (<2,000 mm/yr), soils are dominated by the smectitic and halloysitic phases. With increased precipitation (as much as ∼4,000 mm/yr), kaolinitic and halloysitic phases become the dominant clay minerals, and goethite and gibbsite become increasingly abundant. Older soils developed on geomorphic surfaces representing the original constructional surface of Koolau Volcano are markedly more leached than those from younger landscapes in the same precipitation regime. Although smectite may be present, kaolinite is the dominant phase, and accumulations of Fe and Ti occur in the uppermost soil levels. Enrichment of Zr and Ti in these soils, as compared to concentrations in the original basaltic parent material, indicates that as much as 75% of the parent material has been lost. Thus weathering duration may affect soil clay composition in the same way as weathering intensity. Because smectite and halloysite are expandable clay minerals, their presence in soils may decrease slope stability and influence the nature of slope processes. Soil avalanches occur on steep slopes throughout the study area, whereas slow-moving landslides appear to be restricted to gentler slopes in drier parts of the study area where smectite is abundant. The clay mineralogy of soils thus appears to influence the nature of slope processes in the southeastern Koolau Mountains.

Special Paper of the Geological Society of America↗

The crane flies (Diptera: Tipuloidea) of Great Smoky Mountains National Park

The list of crane flies (Diptera: Ptychopteridae, Tipuloidea, Trichoceridae) known from Great Smoky Mountains National Park is updated. Sampling in association with the All Taxa Biodiversity Inventory of Great Smoky Mountains National Park resulted in the addition of 107 new Park records, bringing the current list to 250 species. This species assemblage is much richer than those of surrounding areas, although similar in composition. Total richness is estimated to be between 450 and 500 species for Great Smoky Mountains National Park.

North Carolina, Tennesse↗

Cambarus fetzneri sp. nov., a new species of burrowing crayfish (Decapoda: Cambaridae) from the Allegheny Mountains of Virginia and West Virginia, USA

The disjunct distribution of Cambarus monongalensis has led to speculation about its taxonomic status. An Appalachian Plateau population occurs in northern and central West Virginia and Southwestern Pennsylvania, and a mountain population occurs in the Allegheny Mountains and Ridge and Valley physiographic provinces of the Virginias. Herein we describe the mountain population as Cambarus fetzneri sp. nov. The two species differ genetically and morphologically, and have different color patterns. Specifically, C. fetzneri sp. nov. chelae lack extensive red coloration on the distal end of the propodus and dactyl, possess rostral margins that lack any red coloration, compared to C. monongalensis , which has extensive red coloration on the dactyl and propodus, as well as red rostral margins. Morphologically, the rostrum of C. fetzneri sp. nov. is shorter and wider than that of C. monongalensis . Also, adult C. fetzneri sp. nov. are considerably smaller in body size than those of C. monongalensis .

Virginia, West Virginia↗

Climatic controls on the snowmelt hydrology of the northern Rocky Mountains

The northern Rocky Mountains (NRMs) are a critical headwaters region with the majority of water resources originating from mountain snowpack. Observations showing declines in western U.S. snowpack have implications for water resources and biophysical processes in high-mountain environments. This study investigates oceanic and atmospheric controls underlying changes in timing, variability, and trends documented across the entire hydroclimatic-monitoring system within critical NRM watersheds. Analyses were conducted using records from 25 snow telemetry (SNOTEL) stations, 148 1 April snow course records, stream gauge records from 14 relatively unimpaired rivers, and 37 valley meteorological stations. Over the past four decades, midelevation SNOTEL records show a tendency toward decreased snowpack with peak snow water equivalent (SWE) arriving and melting out earlier. Temperature records show significant seasonal and annual decreases in the number of frost days (days ≤0°C) and changes in spring minimum temperatures that correspond with atmospheric circulation changes and surface–albedo feedbacks in March and April. Warmer spring temperatures coupled with increases in mean and variance of spring precipitation correspond strongly to earlier snowmeltout, an increased number of snow-free days, and observed changes in streamflow timing and discharge. The majority of the variability in peak and total annual snowpack and streamflow, however, is explained by season-dependent interannual-to-interdecadal changes in atmospheric circulation associated with Pacific Ocean sea surface temperatures. Over recent decades, increased spring precipitation appears to be buffering NRM total annual streamflow from what would otherwise be greater snow-related declines in hydrologic yield. Results have important implications for ecosystems, water resources, and long-lead-forecasting capabilities.

Idaho, Montana↗

New mapping near Iron Creek, Talkeetna Mountains, indicates presence of Nikolai greenstone

Detailed geologic mapping in the Iron Creek area, Talkeetna Mountains B-5 Quadrangle, has documented several intrusive bodies and rock units not previously recognized and has extended the geologic history of the area through the Mesozoic and into the Tertiary era. Greenschist-facies metabasalt and metagabbro previously thought to be Paleozoic are intruded by Late Cretaceous to Paleocene dioritic to granitic plutons. The metabasalts are massive to amygdaloidal, commonly contain abundant magnetite, and large areas are patchily altered to epidote ± quartz. They host numerous copper oxide–copper sulfide–quartz–hematite veins and amygdule fillings. These lithologic features, recognized in the field, suggested a correlation of the metamafic rocks with the Late Triassic Nikolai Greenstone, which had not previously been mapped in the Iron Creek area. Thin, discontinuous metalimestones that overlie the metabasalt sequence had previously been assigned a Pennsylvanian(?) and Early Permian age on the basis of correlation with marbles to the north, which yielded Late Paleozoic or Permian macrofossils, or both. Three new samples from the metalimestones near Iron Creek yielded Late Triassic conodonts, which confirms the correlation of the underlying metamafic rocks with Nikolai Greenstone. These new data extend the occurrence of Nikolai Greenstone about 70 km southwest of its previously mapped extent. Five to 10 km north of the conodont sample localities, numerous microgabbro and diabase sills intrude siliceous and locally calcareous metasedimentary rocks of uncertain age. These sills probably represent feeder zones to the Nikolai Greenstone. In the Mt. Hayes quadrangle 150 km to the northeast, large sill-form mafic and ultramafic feeders (for example, the Fish Lake complex) to the Nikolai Greenstone in the Amphitheatre Mountains host magmatic sulfide nickel–copper–platinum-group-element (PGE) mineralization. This new recognition of Nikolai Greenstone and possible magmatic feeders in the Iron Creek area suggests a much greater potential for large PGE, copper, or nickel deposits in the Talkeetna Mountains than previous mineral resource appraisals of the area have suggested, and requires reevaluation of large-scale tectonic models for the area.

Alaska↗

Mountain treelines: A roadmap for research orientation

For over 100 years, mountain treelines have been the subject of varied research endeavors and remain a strong area of investigation. The purpose of this paper is to examine aspects of the epistemology of mountain treeline research-that is, to investigate how knowledge on treelines has been acquired and the changes in knowledge acquisition over time, through a review of fundamental questions and approaches. The questions treeline researchers have raised and continue to raise have undoubtedly directed the current state of knowledge. A continuing, fundamental emphasis has centered on seeking the general cause of mountain treelines, thus seeking an answer to the question, "What causes treeline?" with a primary emphasis on searching for ecophysiological mechanisms of low-temperature limitation for tree growth and regeneration. However, treeline research today also includes a rich literature that seeks local, landscape-scale causes of treelines and reasons why treelines vary so widely in three-dimensional patterns from one location to the next, and this approach and some of its consequences are elaborated here. In recent years, both lines of research have been motivated greatly by global climate change. Given the current state of knowledge, we propose that future research directions focused on a spatial approach should specifically address cross-scale hypotheses using statistics and simulations designed for nested hierarchies; these analyses will benefit from geographic extension of treeline research.

Arctic, Antarctic, and Alpine Research↗

Holocene and latest Pleistocene oblique dextral faulting on the southern Inyo Mountains fault, Owens Lake basin, California

The Inyo Mountains fault (IMF) is a more or less continuous range-front fault system, with discontinuous late Quaternary activity, at the western base of the Inyo Mountains in Owens Valley, California. The southern section of the IMF trends ???N20??-40?? W for at least 12 km at the base of and within the range front near Keeler in Owens Lake basin. The southern IMF cuts across a relict early Pliocene alluvial fan complex, which has formed shutter ridges and northeast-facing scarps, and which has dextrally offset, well-developed drainages indicating long-term activity. Numerous fault scarps along the mapped trace are northeast-facing, mountain-side down, and developed in both bedrock and younger alluvium, indicating latest Quaternary activity. Latest Quaternary multiple- and single-event scarps that cut alluvium range in height from 0.5 to 3.0 m. The penultimate event on the southern IMF is bracketed between 13,310 and 10,590 cal years B.P., based on radiocarbon dates from faulted alluvium and fissure-fill stratigraphy exposed in a natural wash cut. Evidence of the most recent event is found at many sites along the mapped fault, and, in particular, is seen in an ???0.5-m northeast-facing scarp and several right-stepping en echelon ???0.5-m-deep depressions that pond fine sediment on a younger than 13,310 cal years B.P. alluvial fan. A channel that crosses transverse to this scarp is dextrally offset 2.3 ?? 0.8 m, providing a poorly constrained oblique slip rate of 0.1-0. 3 m/ k.y. The identified tectonic geomorphology and sense of displacement demonstrate that the southern IMF accommodates predominately dextral slip and should be integrated into kinematic fault models of strain distribution in Owens Valley.

Bulletin of the Seismological Society of America↗

Holocene earthquakes of magnitude 7 during westward escape of the Olympic Mountains, Washington

The Lake Creek–Boundary Creek fault, previously mapped in Miocene bedrock as an oblique thrust on the north flank of the Olympic Mountains, poses a significant earthquake hazard. Mapping using 2015 light detection and ranging (lidar) confirms 2004 lidar mapping of postglacial ( &lt; 13 &#x2009;&#x2009; ka "> < 13 ka ) and Holocene fault scarps along the 22‐km‐long eastern section of the fault and documents Holocene scarps that extend &#x2265; 14 &#x2009;&#x2009; km "> ≥ 14 km along a splay fault, the Sadie Creek fault, west of Lake Crescent. Scarp morphology suggests repeated earthquake ruptures along the eastern section of the Lake Creek–Boundary Creek fault and the Sadie Creek fault since &#x223C; 13 &#x2009;&#x2009; ka "> ∼ 13 ka . Right‐lateral ( &#x223C; 11 &#x2013; 28 &#x2009;&#x2009; m "> ∼ 11 – 28 m ) and vertical (1–2 m) cumulative fault offsets suggest slip rates of &#x223C; 1 &#x2013; 2 &#x2009;&#x2009; mm / yr "> ∼ 1 – 2 mm / yr Stratigraphic and age‐model data from five trenches perpendicular to scarps at four sites on the eastern section of the fault show evidence of 3–5 surface‐rupturing earthquakes. Near‐vertical fault dips and upward‐branching fault patterns in trenches, abrupt changes in the thickness of stratigraphic units across faults, and variations in vertical displacement of successive stratigraphic units along fault traces also suggest a large lateral component of slip. Age models suggest two earthquakes date from 1.3 &#xB1; 0.8 "> 1.3 ± 0.8 and 2.9 &#xB1; 0.6 &#x2009;&#x2009; ka "> 2.9 ± 0.6 ka ; evidence and ages for 2–3 earlier earthquakes are less certain. Assuming 3–5 postglacial earthquakes, lateral and vertical cumulative fault offsets yield average slip per earthquake of &#x223C; 4.6 &#x2009;&#x2009; m "> ∼ 4.6 m , a lateral‐to‐vertical slip ratio of &#x223C; 10 : 1 "> ∼ 10 : 1 , and a recurrence interval of 3.5 &#xB1; 1.0 &#x2009;&#x2009; ka "> 3.5 ± 1.0 ka . Empirical relations yield moment magnitude estimates of M 7.2–7.5 (slip per earthquake) and 7.1–7.3 (56 km maximum rupture length). An apparent left‐lateral Miocene to right‐lateral Holocene slip reversal on the faults is probably related to overprinting of east‐directed, accretion‐dominated deformation in the eastern core of the Olympic Mountains by north‐directed, margin‐parallel shortening and westward escape of the mountains.

Washington↗

Nest success of mountain plovers relative to anthropogenic edges in eastern Colorado

We monitored nest success of mountain plovers (Charadrius montanus) relative to distance from the nearest anthropogenic edges, such as fence lines, roads, and perimeters of crop fields, in 2003 and 2004. We located and observed 163 mountain plover nests in eastern Colorado (USA). At least one egg hatched in 81 of 163 nests. Successful nests occurred at a mean distance of 93.94 m ?? 8.87 SE, whereas unsuccessful nests were located 84.39 m ?? 8.95 SE from the nearest edge. Based on our model selection criteria (AIC c), nests farther from edges were not necessarily more successful than those closer to edges. The logistic regression coefficient for edge effects (0.13 ?? 0.12 SE) suggests that nests farther from edges are more successful. However, the standard error for the edge coefficient was large and the 95% confidence interval (-0.08, 0.35) encompassed zero, suggesting nest success was independent of distance from an anthropomorphic edge. We conclude that phenomena determining nest success of mountain plovers cannot be attributed to the single factor of anthropogenic edges in this fragmented landscape.

Southwestern Naturalist↗

Cordilleran subduction initiation: Retro-arc timing and basinal response in the Inyo Mountains, eastern California

Subduction zones drive plate tectonics on Earth, yet subduction initiation and the related upper plate depositional and structural kinematics remain poorly understood because upper plate records are rare and often strongly overprinted by magmatism and deformation. During the late Paleozoic time, Laurentia’s western margin was truncated by a sinistral strike-slip fault that transformed into a subduction zone. Thick Permian strata in the Inyo Mountains of central-eastern California record this transition. Two basins that were separated by a transpressional antiform contain sedimentary lithofacies that record distinct patterns of shoaling and deepening conditions before and during tectonism associated with subduction initiation. Sandstone petrography and lithofacies analysis show that rocks in a southeastern basin are dominated by carbonate grains derived from adjacent carbonate shelves, whereas sandstones in a northwestern basin are predominantly quartzose with likely derivation from distant ergs or underlying strata. Detrital zircon spectra from all but the youngest strata in both basins are typical of Laurentian continent spectra with prominent peaks that indicate ultimate sources in Appalachia, Grenville, Yavapai/Mazatzal, and the Wyoming or Superior cratons. The first Cordilleran arc-derived detrital zircon grains appear in the uppermost strata of the northwestern basin and record Late Permian (ca. 260 Ma) Cordilleran arc magmatism at this approximate latitude, and a possible source area is suggested by geochemical similarities between these detrital zircons and broadly coeval magmatic zircons in the El Paso Mountains to the southwest. Deformation responsible for basin partitioning is consistent with sinistrally oblique contraction in the earliest Permian time. The data presented from the Inyo Mountains shed more light on the nature of Cordilleran subduction initiation and the upper-crustal response to this transition.

California↗

Evidence for large-magnitude, post-Eocene extension in the northern Shoshone Range, Nevada, and its implications for Carlin-type gold deposits in the lower plate of the Roberts Mountains allochthon

The northern Shoshone and Toiyabe Ranges in north-central Nevada expose numerous areas of mineralized Paleozoic rock, including major Carlin-type gold deposits at Pipeline and Cortez. Paleozoic rocks in these areas were previously interpreted to have undergone negligible postmineralization extension and tilting, but here we present new data that suggest major post-Eocene extension along west-dipping normal faults. Tertiary rocks in the northern Shoshone Range crop out in two W-NW–trending belts that locally overlie and intrude highly deformed Lower Paleozoic rocks of the Roberts Mountains allochthon. Tertiary exposures in the more extensive, northern belt were interpreted as subvertical breccia pipes (intrusions), but new field data indicate that these “pipes” consist of a 35.8 Ma densely welded dacitic ash flow tuff (informally named the tuff of Mount Lewis) interbedded with sandstones and coarse volcaniclastic deposits. Both tuff and sedimentary rocks strike N-S and dip 30° to 70° E; the steeply dipping compaction foliation in the tuffs was interpreted as subvertical flow foliation in breccia pipes. The southern belt along Mill Creek, previously mapped as undivided welded tuff, includes the tuff of Cove mine (34.4 Ma) and unit B of the Bates Mountain Tuff (30.6 Ma). These tuffs dip 30° to 50° east, suggesting that their west-dipping contacts with underlying Paleozoic rocks (previously mapped as depositional) are normal faults. Tertiary rocks in both belts were deposited on Paleozoic basement and none appear to be breccia pipes. We infer that their present east tilt is due to extension on west-dipping normal faults. Some of these faults may be the northern strands of middle Miocene (ca. 16 Ma) faults that cut and tilted the 34.0 Ma Caetano caldera ~40° east in the central Shoshone Range (<5 km south of Mill Creek), but further mapping is necessary to trace the faults through the highly deformed Paleozoic rocks that surround the isolated Tertiary outcrops. Significant post-Eocene extensional faulting in the northern Shoshone Range may have important implications for both the structure of the Roberts Mountains allochthon and the exposure of potentially mineralized rocks in its lower plate, both of which were likely east-tilted and repeated by west-dipping faults together with overlying Tertiary rocks.

Nevada↗

Regional geologic and petrologic framework for iron oxide ± apatite ± rare earth element and iron oxide copper-gold deposits of the Mesoproterozoic St. Francois Mountains terrane, southeast Missouri, USA

This paper provides an overview on the genesis of Mesoproterozoic igneous rocks and associated iron oxide ± apatite (IOA) ± rare earth element, iron oxide-copper-gold (IOCG), and iron-rich sedimentary deposits in the St. Francois Mountains terrane of southeast Missouri, USA. The St. Francois Mountains terrane lies along the southeastern margin of Laurentia as part of the eastern granite-rhyolite province. The province formed during two major pulses of igneous activity: (1) an older early Mesoproterozoic (ca. 1.50–1.44 Ga) episode of volcanism and granite plutonism, and (2) a younger middle Mesoproterozoic (ca. 1.33–1.30 Ga) episode of bimodal gabbro and granite plutonism. The volcanic rocks are predominantly high-silica rhyolite pyroclastic flows, volcanogenic breccias, and associated volcanogenic sediments with lesser amounts of basaltic to andesitic volcanic and associated subvolcanic intrusive rocks. The iron oxide deposits are all hosted in the early Mesoproterozoic volcanic and volcaniclastic sequences. Previous studies have characterized the St. Francois Mountains terrane as a classic, A-type within-plate granitic terrane. However, our new whole-rock geochemical data indicate that the felsic volcanic rocks are effusive derivatives from multicomponent source types, having compositional similarities to A-type within-plate granites as well as to S- and I-type granites generated in an arc setting. In addition, the volcanic-hosted IOA and IOCG deposits occur within bimodal volcanic sequences, some of which have volcanic arc geochemical affinities, suggesting an extensional tectonic setting during volcanism prior to emplacement of the ore-forming systems.

Missouri↗

Utility of high-altitude infrared spectral data in mineral exploration: Application to Northern Patagonia Mountains, Arizona

Synoptic views of hydrothermal alteration assemblages are of considerable utility in regional-scale minerals exploration . Recent advances in data acquisition and analysis technologies have greatly enhanced the usefulness of remotely sensed imaging spectroscopy for reliable alteration mineral assemblages mapping. Using NASA's Airborne Visible Infrared Imaging Spectrometer (AVIRIS) sensor, this study mapped large areas of advanced argillic and phyllic-argillic alteration assemblages in the southeastern Santa Rita and northern Patagonia mountains , Arizona . Two concealed porphyry copper deposits have been identified during past exploration , the Red Mountain and Sunnyside deposits, and related published hydrothermal alteration zoning studies allow the comparison of the results obtained from AVIRIS data to the more traditional field mapping approaches. The AVIRIS mapping compares favorably with field-based studies. An analysis of iron-bearing oxide minerals above a concealed supergene chalcocite deposit at Red Mountain also indicates that remotely sensed data can be of value in the interpretation of leached caps above porphyry copper deposits. In conjunction with other types of geophysical data , AVIRIS mineral maps can be used to discriminate different exploration targets within a region.

Economic Geology↗

Fluorine-rich mafic lower crust in the southern Rocky Mountains: The role of pre-enrichment in generating fluorine-rich silicic magmas and porphyry Mo deposits

Fluorine-rich granites and rhyolites occur throughout the southern Rocky Mountains, but the origin of F-enrichment has remained unclear. We test if F-enrichment could be inherited from ancient mafic lower crust by: (1) measuring amphibole compositions, including F and Cl contents, of lower crustal mafic granulite xenoliths from northern Colorado to determine if they are unusually enriched in halogens; (2) analyzing whole-rock elemental and Sr, Nd, and Pb isotopic compositions for upper crustal Cretaceous to Oligocene igneous rocks in Colorado to evaluate their sources; and (3) comparing batch melting models of mafic lower crustal source rocks to melt F and Cl abundances derived from biotite data from the F-rich silicic Never Summer batholith. This approach allows us to better determine if the mafic lower crust was pre-enriched in F, if it is concentrated enough to generate F-rich anatectic melts, and if geochemical data support an ancient lower crustal origin for the F-rich rocks in the southern Rocky Mountains. Electron microprobe analyses of amphibole in lower crustal mafic granulite xenoliths show they contain 0.56–1.38 wt% F and 0.45–0.73 wt% Cl. Titanium in calcium amphibole thermometry indicates that the amphiboles equilibrated at high to ultrahigh temperature conditions (805 to 940 °C), and semiquantitative amphibole thermobarometry indicates the amphiboles equilibrated at 0.5 to 1.0 GPa prior to entrainment in magmas during the Devonian. Mass balance calculations, based on these new measurements, indicate parts of the mafic lower crust in Colorado are at least 3.5 times more enriched in F than average mafic lower crust. Intrusions coeval with the Laramide Orogeny (75 to 38 Ma) pre-date F-rich magmatism in Colorado and have Sr and Nd isotopic compositions consistent with mafic lower crust ± mantle sources, but many of these intrusions contain elevated Sr/Y ratios (>40) that suggest amphibole was a stable phase during magma generation. The F-rich igneous rocks from the Never Summer igneous complex and Colorado Mineral Belt also have Sr and Nd isotopic compositions that overlap with the lower crustal mafic granulite xenoliths, but they have lower Sr/Y, higher Nb and Y abundances, and distinctly less radiogenic 206 Pb/ 204 Pb i compositions than preceding Laramide magmatism. Batch melt modeling indicates low-degree partial melts derived from rocks similar to the mafic lower crustal xenoliths we analyzed can yield silicic melts with >2000 ppm F, similar to estimated F melt concentrations for silicic melts that are interpreted to be parental to evolved leucogranites. We suggest that F-rich silicic melts in the southern Rocky Mountains were sourced from garnet-free mafic lower crust, and that fluid-absent breakdown of amphibole in ultrahigh temperature metamorphic rocks was a key process in their generation. Based on the composition of high-F amphibole measured from lower crustal xenoliths, the temperature of amphibole breakdown and melt generation for these F-enriched source rocks is likely >100 °C higher than similar lower crust with low or average F abundances. As such, these source rocks only melted during periods of unusually high heat flow into the lower crust, such as during an influx of mantle-derived magmas related to rifting or the post-Laramide ignimbrite flare-up in the region. These data have direct implications for the genesis of porphyry Mo mineralization, because they indicate that pre-enrichment of F in the deep crust could be a necessary condition for later anatexis and generation of F-rich magmas.

Colorado, New Mexico↗

Complex carbonate ore mineralogy in the Mountain Pass carbonatite rare earth element deposit, USA

Economic concentrations of rare earth element (REE) minerals are uncommon in the Earth’s crust, with most occurring in carbonatites. Unlike most igneous rocks composed of silicate minerals, carbonatites are dominated by carbonate minerals, some of which can incorporate significant light REEs (LREEs; La, Ce, Pr, Nd). Technological applications of REEs are numerous and they have been identified as some of the most critical mineral commodities to the global economy. The Mountain Pass carbonatite stock in the Mojave Desert of California is the most economically significant REE deposit in the USA and contains a few to tens of percent (by volume) of the carbonate REE ore mineral bastnäsite. Despite the economic significance of the Mountain Pass deposit, studies of its ore mineralogy are limited. Here we present new carbonate ore mineralogy data for a compositionally diverse suite of carbonatitic rocks from the Mountain Pass stock and related dikes. Whole-rock geochemical data are integrated with mineral-scale textural and chemical data obtained by scanning electron microscopy (SEM), electron probe microanalysis (EPMA), and microRaman spectroscopy. Our results document a complex spectrum of REE-bearing carbonate minerals and intermediate mixed-layer structures. Mineral species include bastnäsite [REE(CO 3 )F], hydroxylbastnäsite [REE(CO 3 )OH], parisite [Ca(REE) 2 (CO 3 ) 3 F 2 ], synchysite [Ca(REE)(CO 3 ) 2 F], röntgenite [Ca 2 (Ce,La) 3 (CO 3 ) 5 F 3 ], and sahamalite [(Mg,Fe 2+ )(REE) 2 (CO 3 ) 4 ]. Carbonate ore mineralogy is heterogeneous within and between samples, including at the intracrystal scale. Complexly zoned crystals exhibit as many as five to six different compositional domains and syntaxial intergrowths, commonly with the more Ca-rich varieties (parisite, synchysite) forming crystal rims that surround relict bastnäsite cores. We attribute the phenocryst variability to changes in the chemistry and temperature of primary carbonatite magmas and evolved/exsolved fluids. Cross-cutting vein textures of calcite, celestine and various REE carbonate minerals, interstitial bastnäsite crystallization, breccia blocks lined by fine-grained bastnäsite, and the presence of hydroxylbastnäsite and partially hydroxylated bastnäsite point to the role of secondary hydrothermal processes in REE mineralization. Fluorcarbonate mineral compositions demonstrate that La and Ce are more structurally abundant in bastnäsite, whereas the more Ca-rich species (parisite, synchysite) contain a greater proportion of REE heavier than Pr (Nd, Sm, Eu, Gd) and Y. Atomic ratios of Pr/(Nd + Pr) are likewise variable, with the highest average value for bastnäsite (0.25) compared to parisite (0.22) and sychysite (0.21). This finding has geometallurgical implications, given that current mining operations are focused on recovery of Nd and Pr for high field strength permanent magnets and the Nd/Pr ratios are a critical factor in ore processing and magnet manufacture.

California↗

Climatic significance of the bristlecone pine latewood frost-ring record at Almagre Mountain, Colorado, U.S.A.

From 1900 to 1993, latewood frost rings occurred in 1903, 1912, 1941, 1961, and 1965 in 10 to 21% of the sampled bristlecone pines at Almagre Mountain, Colorado. In early to mid September in each of those years, a severe outbreak of unseasonably cold air from higher latitudes produced a memorable or historic late-summer snowstorm in the western United States. Record subfreezing temperatures during these snowstorms probably caused the latewood frost rings, shortened (by about 1 mo in 1912) already colder than normal growing seasons, and caused crop damage in parts of the Western United States. Latewood frost rings recorded in relatively high percentages of the sampled trees (such as the 1805 event in 61% of sampled trees) were probably caused by multiple severe outbreaks of unseasonably cold air from higher latitudes that occurred from early September (possibly as early as mid- or late August) to mid-September. Analyses of 1900-1992 temperature data for two widely separated Colorado stations, Fort Collins and Colorado Springs, show that average summer (June-September) temperatures during latewood frost-ring years in this century were 1.5 and 2.0°C cooler than normal, respectively. Mountain snowpack probably persisted through these cool summers and was subsequently buried by the earlier than normal snowfall in September. Latewood frost-ring, ring-width, historical, and other data suggest that severe to cataclysmic volcanic eruptions from 1812 to 1835 triggered (1) an extended period of climatic cooling from as early as 1816 or 1817 through the early 1850s in the Southern Rocky Mountains, (2) catastrophic winters in Colorado and Wyoming in 1842-43 and 1844-45, and in the Great Salt Lake Basin in 1836-37, that caused large-scale destruction of bison and other large plains animals, and (3) Little Ice Age alpine glacial advances in about 1850-60 in the western United States.

Colorado↗

Descriptive risk assessment of the effects of acidic deposition on Rocky Mountain amphibians

We evaluated the risk of habitat acidification to the six species of amphibians that occur in the mountains of Colorado and Wyoming. Our evaluation included extrinsic environmental factors (habitat sensitivity and amount of acidic atmospheric deposition) and species-specific intrinsic factors (sensitivity to acid conditions, habitat preferences, and timing of breeding). Only one of 57 surveyed localities had both acid neutralizing capacity <200 μ eq/L and sulfate deposition >10 kg/ha/yr, extrinsic conditions with a possible risk of acidification. Amphibian breeding habitats in the Rocky Mountains do not appear to be sufficiently acidic to kill amphibian embryos. Some species breed in high-elevation vernal pools during snowmelt, and an acidic pulse during snowmelt may pose a risk to embryos of these species. However, the acidic pulse, if present, probably occurs before open water appears and before breeding begins. Although inherent variability of amphibian population size may make detection of declines from anthropogenic effects difficult, acidic deposition is unlikely to have caused the observed declines of Bufo boreas and Rana pipiens in Colorado and Wyoming. Amphibians in the Rocky Mountains are not likely to be at risk with acidification inputs at present levels.

Journal of Herpetology↗

Survey and assessment of amphibian populations in Rocky Mountain National Park

We conducted surveys in Rocky Mountain National Park, Colorado for amphibians in 1987-1994. Four species, Ambystoma tigrinum, Bufo boreas, Pseudacris maculata, and Rana sylvatica , were recorded. Pseudacris maculata was the most widely distributed and abundant species in the Park. Two populations of E maculata were estimated to contain 161 and 136 breeding males in 1988. There was no evidence of a decline of A. tigrinum or R. sylvatica , but these species were found at relatively few locations. We did not detect Rana pipiens , which had been known previously from 3 locations in the Park. We found 7 breeding populations of B. boreas , which has declined recently elsewhere in the southern Rocky Mountains, but all but 2 of these populations were small and may not reproduce annually. At least one of these small populations is thought to have been extirpated. Estimated numbers of males in the 2 large populations, which are 6.4 km apart in the same drainage, were stable or increasing slightly from 1992 to 1995, averaging 189 and 239 individuals. Current and known locations of amphibians did not differ in elevation, size, lake type, presence of shallow water or emergent vegetation on the north shore, or presence of trout. Water chemistry at amphibian breeding sites was variable, but pH decreased significantly with increasing elevation. Causes of declines of B. boreas and R. pipiens are not known. Populations of B. boreas in the North Fork of the Big Thompson River are critically important to the conservation of this species in the Rocky Mountains.

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