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At least 577 records · Page 32Linked to original sources
USGS2009

Evaluating remediation alternatives for mine drainage, Little Cottonwood Creek, Utah, USA

The vast occurrence of mine drainage worldwide, documented in descriptive studies, presents a staggering challenge for remediation. Any tool that can move beyond descriptive study and helps to evaluate options for remediation in a way that maximizes improvements to the water quality of streams and minimizes cost of remediation could save valuable resources and time. A reactive solute transport model, calibrated from two detailed mass-loading studies in Little Cottonwood Creek (LCC), Utah, provides a tool to evaluate remediation options. Metal loading to LCC is dominated by discharge from two mine drainage tunnels. Discharge from an upstream tunnel has been treated by a fen to reduce metal loading. Discharge from the downstream tunnel (WDT) can be controlled because of a bulkhead that creates a mine pool. Simulations of remedial options for three compliance locations suggest that the water-quality standards for Cu and Zn at upstream and downstream compliance locations are met using various combinations of fen treatment and WDT regulation, but the complete compliance at the middle compliance location requires the highest level of fen treatment and the greatest regulation of WDT discharge. Reactive transport modeling is an useful tool for the evaluation of remedial alternatives in complex natural systems, where multiple hydrologic and geochemical processes determine metal fate.

Utah↗
USGS2003

Mercury Speciation by X-ray Absorption Fine Structure Spectroscopy and Sequential Chemical Extractions: A Comparison of Speciation Methods

Determining the chemical speciation of mercury in contaminated mining and industrial environments is essential for predicting its solubility, transport behavior, and potential bioavailability as well as for designing effective remediation strategies. In this study, two techniques for determining Hg speciation-X-ray absorption fine structure (XAFS) spectroscopy and sequential chemical extractions (SCE)-are independently applied to a set of samples with Hg concentrations ranging from 132 to 7539 mg/kg to determine if the two techniques provide comparable Hg speciation results. Generally, the proportions of insoluble HgS (cinnabar, metacinnabar) and HgSe identified by XAFS correlate well with the proportion of Hg removed in the aqua regia extraction demonstrated to remove HgS and HgSe. Statistically significant (> 10%) differences are observed however in samples containing more soluble Hg-containing phases (HgCl2, HgO, Hg3S2O 4). Such differences may be related to matrix, particle size, or crystallinity effects, which could affect the apparent solubility of Hg phases present. In more highly concentrated samples, microscopy techniques can help characterize the Hg-bearing species in complex multiphase natural samples.

Environmental Science & Technology↗
USGS2020

Observations of an extreme atmospheric river storm with a diverse sensor network

Observational networks enhance real‐time situational awareness for emergency and water resource management during extreme weather events. We present examples of how a diverse, multitiered observational network in California provided insights into hydrometeorological processes and impacts during a 3‐day atmospheric river storm centered on 14 February 2019. This network, which has been developed over the past two decades, aims to improve understanding and mitigation of effects from extreme storms influencing water resources and natural hazards. We combine atmospheric reanalysis output and additional observations to show how the network allows: (1) the validation of record cool season precipitable water observations over southern California; (2) the identification of phenomena that produce natural hazards and present difficulties for short‐term weather forecast models, such as extreme precipitation amounts and snow level variability; (3) the use of soil moisture data to improve hydrologic model forecast skill in northern California's Russian River basin; and (4) the combination of meteorological data with seismic observations to identify when a large avalanche occurred on Mount Shasta. This case study highlights the value of investments in diverse observational assets and the importance of continued support and synthesis of these networks to characterize climatological context and advance understanding of processes modulating extreme weather.

California↗
USGS2000

Sediment distribution and transport along a rocky, embayed coast: Monterey Peninsula and Carmel Bay, California

Field measurements of beach morphology and sedimentology were made along the Monterey Peninsula and Carmel Bay, California, in the spring and summer of 1997. These data were combined with low-altitude aerial imagery, high-resolution bathymetry, and local geology to understand how coastal geomorphology, lithology, and tectonics influence the distribution and transport of littoral sediment in the nearshore and inner shelf along a rocky shoreline over the course of decades. Three primary modes of sediment distribution in the nearshore and on the inner shelf off the Monterey Peninsula and in Carmel Bay were observed. Along stretches of the study area that were exposed to the dominant wave direction, sediment has accumulated in shore-normal bathymetric lows interpreted to be paleo-stream channels. Where the coastline is oriented parallel to the dominant wave direction and streams channels trend perpendicular to the coast, sediment-filled paleo-stream channels occur in the nearshore as well, but here they are connected to one another by shore-parallel ribbons of sediment at depths between 2 and 6 m. Where the coastline is oriented parallel to the dominant wave direction and onshore stream channels are not present, only shore-parallel patches of sediment at depths greater than 15 m are present. We interpret the distribution and interaction or transport of littoral sediment between pocket beaches along this coastline to be primarily controlled by the northwest-trending structure of the region and the dominant oceanographic regime. Because of the structural barriers to littoral transport, peaks in wave energy appear to be the dominant factor controlling the timing and magnitude of sediment transport between pocket beaches, more so than along long linear coasts. Accordingly, the magnitude and timing of sediment transport is dictated by the episodic nature of storm activity. (C) 2000 Elsevier Science B.V.

Marine Geology↗
USGS2011

Large shift in source of fine sediment in the upper Mississippi River

Although sediment is a natural constituent of rivers, excess loading to rivers and streams is a leading cause of impairment and biodiversity loss. Remedial actions require identification of the sources and mechanisms of sediment supply. This task is complicated by the scale and complexity of large watersheds as well as changes in climate and land use that alter the drivers of sediment supply. Previous studies in Lake Pepin, a natural lake on the Mississippi River, indicate that sediment supply to the lake has increased 10-fold over the past 150 years. Herein we combine geochemical fingerprinting and a suite of geomorphic change detection techniques with a sediment mass balance for a tributary watershed to demonstrate that, although the sediment loading remains very large, the dominant source of sediment has shifted from agricultural soil erosion to accelerated erosion of stream banks and bluffs, driven by increased river discharge. Such hydrologic amplification of natural erosion processes calls for a new approach to watershed sediment modeling that explicitly accounts for channel and floodplain dynamics that amplify or dampen landscape processes. Further, this finding illustrates a new challenge in remediating nonpoint sediment pollution and indicates that management efforts must expand from soil erosion to factors contributing to increased water runoff.

Environmental Science & Technology↗
USGS2001

Determination of the sources of nitrate contamination in karst springs using isotopic and chemical indicators

The sources of nitrate (NO-3) in groundwater of the shallow karst aquifer in southwestern Illinois' sinkhole plain were investigated using chemical and isotopic techniques. The groundwater in this aquifer is an important source of potable water for about half of the residents of the sinkhole plain area. Previous work has shown that groundwater from approximately 18% of the wells in the sinkhole plain has NO-3 concentrations in excess of the USEPA's drinking water standard of 10 mg N/1. Relative to background levels, the NO-3 concentrations in water from 52% of the wells, and probably all of the springs in the study area, are anomalously high, suggesting that sources other than naturally occurring soil organic matter have contributed additional NO-3 to groundwater in the shallow karst aquifer. This information, and the dominance of agriculture in the study area, suggest that agrichemical contributions may be significant. To test this hypothesis, water samples from 10 relatively large karst springs were collected during four different seasons and analyzed for inorganic constituents, dissolved organic carbon, atrazine, and ??15N and ??18O of the NO-3 ions. The isotopic data were most definitive and suggested that the sources of NO-3 in spring water are dominated by N-fertilizer with some possible influence of atmospheric NO-3 and, to a much lesser extent, human and/or animal waste. Differences in the isotopic composition of NO-3 and some of the chemical characteristics were observed during the four consecutive seasons in which spring water samples were collected. Isotopic values for ??15N and ??18O of the NO-3 ranged from 3.2??? to 19.1??? and from 7.2??? to 18.7???, respectively. The trend of ??15N and ??18O data for NO-3 also indicated that a significant degree of denitrification is occurring in the shallow karst hydrologic system (within the soil zone, the epikarst and the shallow karst aquifer) prior to discharging to springs. ?? 2001 Elsevier Science B.V. All rights reserved.

Chemical Geology↗
USGS2018

“Naturalness” in designated Wilderness: Long-term changes in non-native plant dynamics on campsites, Boundary Waters, Minnesota

Wilderness areas in the United States are preserved for their untrammeled naturalness and opportunities for unconfined recreation. The Boundary Waters Canoe Area Wilderness has these qualities, but long-term recreation visitation pressures on campsites can cause significant ecological changes. This article explores changes on campsites, specifically examining non-native plant ecology over 3 decades. The research replicates a 1982 study analyzing vegetation composition and cover on campsites and environmentally paired controls. Camping activities have removed substantial tree cover on campsites, altering their ecological conditions and perceived wilderness character. Over the span of 32 years, the number of non-native plant species found on campsites has not risen, although their mean relative cover has increased significantly and they have spread to more sites. Of the 23 non-native herbs and grasses found on the campsites, only Cirsium arvense is considered a noxious weed by the state of Minnesota. Other noninvasive, non-native plants fall into a gray area in the context of "naturalness" for an area protected as Wilderness because they provide some positive ecological services even as they degrade wilderness character. Thus, wilderness managers face a difficult challenge in coping with the long-term impacts of visitor use on wilderness conditions and character.

Minnesota↗
USGS2012

Introduction to emergent wetlands: Chapter A in Emergent wetlands status and trends in the northern Gulf of Mexico: 1950-2010

Throughout the past century, emergent wetlands have been declining across the Gulf of Mexico. Emergent wetland ecosystems provide a plethora of resources including plant and wildlife habitat, commercial and recreational economic activity, water quality improvement, and natural barriers against storms. As emergent wetland losses increase, so does the need for information on the causes and effects of these losses, for emergent wetland mapping, for monitoring and restoration efforts, and for increased education. The U.S. Geological Survey (USGS) and the U.S. Environmental Protection Agency’s Gulf of Mexico Program Office (EPA GMPO) are committed to providing the best science to restore, enhance, and protect these important ecosystems. The Emergent Wetlands Status and Trends Report is a continuation of the completed Seagrass Status and Trends in the Northern Gulf of Mexico Report (Handley and others, 2007), both of which serve to update the EPA GMPO Status and Trends of Emergent and Submerged Vegetated Habitats of Gulf of Mexico Coastal Waters, USA Report (Duke and Kruczynski, 1992). The Emergent Wetlands Status and Trends Report is also part of the Gulf of Mexico Alliance Ecosystems Integration and Assessment Priority Issue Team’s work plan to provide resources that will aid in the ecological and economic enhancement of the Gulf of Mexico region. The purpose of this report is to provide scientists, managers, and citizens with valuable baseline information on the status and trends of emergent wetlands along the coast of the Gulf of Mexico. The study upon which this report is based examines the emergent wetlands of eight individual estuarine areas within the northern Gulf of Mexico region and presents statewide summaries for Texas, Louisiana, Mississippi, Alabama, and Florida. Each estuarine area is detailed in vignettes that address current status and historical trends of estuarine and palustrine emergent wetlands, emergent wetlands mapping and monitoring, causes of status change, restoration and enhancement activities, background information for the study area, and the methodology employed to analyze and document the historical trends and current status of emergent wetlands. The eight individual estuarine areas examined in this report are:  Corpus Christi/ Nueces/Aransas Bays, Tex.  Galveston Bay, Tex.  Barataria/Terrebonne Bay, La.  Mississippi Delta, La.  Mississippi Sound, Miss.  Mobile Bay, Ala.  Florida Panhandle, Fla.  Tampa Bay, Fla.

Report↗
USGS2013

Tectonic map of the Circum-Pacific region, Pacific basin sheet

Circum-Pacific Map Project : The Circum-Pacific Map Project was a cooperative international effort designed to show the relationship of known energy and mineral resources to the major geologic features of the Pacific basin and surrounding continental areas. Available geologic, mineral, and energy-resource data are being complemented by new, project-developed data sets such as magnetic lineations, seafloor mineral deposits, and seafloor sediment. Earth scientists representing some 180 organizations from more than 40 Pacific-region countries are involved in this work. Six overlapping equal-area regional maps at a scale of 1:10,000,000 form the cartographic base for the project: the four Circum-Pacific Quadrants (Northwest, Southwest, Southeast, and Northeast), and the Antarctic and Arctic Sheets. There is also a Pacific Basin Sheet at a scale of 1:17,000,000. The Base Map Series and the Geographic Series (published from 1977 to 1990), the Plate-Tectonic Series (published in 1981 and 1982), the Geodynamic Series (published in 1984 and 1985), and the Geologic Series (published from 1984 to 1989) all include six map sheets. Other thematic map series in preparation include Mineral-Resources, Energy-Resources and Tectonic Maps. Altogether, more than 50 map sheets are planned. The maps were prepared cooperatively by the Circum-Pacific Council for Energy and Mineral Resources and the U.S. Geological Survey and are available from the Branch of Distribution, U. S. Geological Survey, Box 25286, Federal Center, Denver, Colorado 80225, U.S.A. The Circum-Pacific Map Project is organized under six panels of geoscientists representing national earth-science organizations, universities, and natural-resource companies. The six panels correspond to the basic map areas. Current panel chairmen are Tomoyuki Moritani (Northwest Quadrant), R. Wally Johnson (Southwest Quadrant), Ian W.D. Dalziel (Antarctic Region), vacant. (Southeast Quadrant), Kenneth J. Drummond (Northeast Quadrant), and George W. Moore (Arctic Region). Project coordination and final cartography was being carried out through the cooperation of the Office of the Chief Geologist of the U.S. Geological Survey, under the direction of General Chairman, George Gryc of Menlo Park, California. Project headquarters were located at 345 Middlefield Road, MS 952, Menlo Park, California 94025, U.S.A. The framework for the Circum-Pacific Map Project was developed in 1973 by a specially convened group of 12 North American geoscientists meeting in California. The project was officially launched at the First Circum-Pacific Conference on Energy and Mineral Resources, which met in Honolulu, Hawaii, in August 1974. Sponsors of the conference were the AAPG, Pacific Science Association (PSA), and the Coordinating Committee for Offshore Prospecting for Mineral Resources in Offshore Asian Areas (CCOP). The Circum-Pacific Map Project operates as an activity of the Circum-Pacific Council for Energy and Mineral Resources, a nonprofit organization that promotes cooperation among Circum-Pacific countries in the study of energy and mineral resources of the Pacific basin. Founded by Michel T. Halbouty in 1972, the Council also sponsors conferences, topical symposia, workshops and the Earth Science Series books. Tectonic Map Series : The tectonic maps distinguish areas of oceanic and continental crust. Symbols in red mark active plate boundaries, and colored patterns show tectonic units (volcanic or magmatic arcs, arc-trench gaps, and interarc basins) associated with active plate margins. Well-documented inactive plate boundaries are shown by symbols in black. The tectonic development of oceanic crust is shown by episodes of seafloor spreading. These correlate with the rift and drift sequences at passive continental margins and episodes of tectonic activity at active plate margins. The recognized episodes of seafloor spreading seem to reflect major changes in plate kinematics. Oceanic plateaus and other prominences of greater than normal oceanic crustal thickness such as hotspot traces are also shown. Colored areas on the continents show the ages of deformation and metamorphism of basement rocks and the emplacement of igneous rocks. Transitional tectonic (molassic) and reactivation basins are shown by a colored boundary, and if they are deformed, a colored horizontal line pattern indicates the age of deformation. Colored bands along basin boundaries indicate age of inception, and isopachs indicate thickness of platform strata on continental crust and cover on oceanic crust. Colored patterns at separated continental margins show the age of inception of rift and drift (breakup) sequences. Symbols mark folds and faults, and special symbols show volcanoes and other structural features. Affiliations are as of compilation of the data. This map was created in quadrants and then compiled together. They are the Northwest land, Northwest Marine (different compilers), Northeast, Southwest and Southeast, and parts in plate-boundary sections.

Circum-Pacific Map↗
USGS2016

The Water-Quality Partnership for National Parks—U.S. Geological Survey and National Park Service, 1998–2016

The U.S. Geological Survey (USGS) and the National Park Service (NPS) work together through the USGS–NPS Water-Quality Partnership to support a broad range of policy and management needs related to high-priority water-quality issues in national parks. The program was initiated in 1998 as part of the Clean Water Action Plan, a Presidential initiative to commemorate the 25th anniversary of the Clean Water Act. Partnership projects are developed jointly by the USGS and the NPS. Studies are conducted by the USGS and findings are used by the NPS to guide policy and management actions aimed at protecting and improving water quality. The National Park Service manages many of our Nation’s most highly valued aquatic systems across the country, including portions of the Great Lakes, ocean and coastal zones, historic canals, reservoirs, large rivers, high-elevation lakes and streams, geysers, springs, and wetlands. So far, the Water-Quality Partnership has undertaken 217 projects in 119 national parks. In each project, USGS studies and assessments ( http://water.usgs.gov/nps_partnership/pubs.php ) have supported science-based management by the NPS to protect and improve water quality in parks. Some of the current projects are highlighted in the NPS Call to Action Centennial initiative, Crystal Clear, which celebrates national park water-resource efforts to ensure clean water for the next century of park management ( http://www.nature.nps.gov/water/crystalclear/ ). New projects are proposed each year by USGS scientists working in collaboration with NPS staff in specific parks. Project selection is highly competitive, with an average of only eight new projects funded each year out of approximately 75 proposals that are submitted. Since the beginning of the Partnership in 1998, 189 publications detailing project findings have been completed. The 217 studies have been conducted in 119 NPS-administered lands, extending from Denali National Park and Preserve in Alaska to Everglades National Park in Florida, and from Acadia National Park in the Northeast to park lands in Hawaii and Pacific Island territories in the West. Project goals range from periodic stream monitoring, to determining the occurrence and concentrations of contaminants and the potential for them to exceed human health or aquatic life criteria, to conducting interpretive studies to evaluate the effect(s) on or vulnerability of national park resources to visitor usage and other natural and anthropogenic activities.

Fact Sheet↗
USGS1997

Episodic nature of earthquake activity in stable continental regions revealed by palaeoseismicity studies of Australian and North American Quaternary faults

Palaeoseismic investigations of recent faulting in stable continental regions of Australia, North America and India show that these faults typically have a long-term behaviour characterised by episodes of activity separated by quiescent intervals of at least 10 000 and commonly 100 000 years or more. Long recurrence intervals such as these are well documented by detailed studies of the faults that ruptured during the 1986 Marryat Creek, South Australia and 1988 Tennant Creek, Northern Territory earthquakes. Thus, neotectonic features associated with stable continental region faults such as scarps and grabens commonly have subtle geomorphic expression and may be poorly preserved. Many potentially hazardous faults in stable continental regions are aseismic, which is one reason why the inventory of these faults is incomplete. Although they may be currently aseismic, faults in stable continental regions that are favourably oriented for movement in the current stress field could produce damaging earthquakes, often in unexpected places. Comprehensive palaeoseismic investigations of modern and prehistoric faulting events in stable continental regions are needed to understand the long-term behaviour of these faults, and thereby, improve seismic-hazard assessments.

Australian Journal of Earth Sciences↗
USGS2000

In situ stimulation of groundwater denitrification with formate to remediate nitrate contamination

In situ stimulation of denitrification has been proposed as a mechanism to remediate groundwater nitrate contamination. In this study, sodium formate was added to a sand and gravel aquifer on Cape Cod, MA, to test whether formate could serve as a potential electron donor for subsurface denitrification. During 16- and 10-day trials, groundwater from an anoxic nitrate-containing zone (0.5-1.5 mM) was continuously withdrawn, amended with formate and bromide, and pumped back into the aquifer. Concentrations of groundwater constituents were monitored in multilevel samplers after up to 15 m of transport by natural gradient flow. Nitrate and formate concentrations were decreased 80-100% and 60-70%, respectively, with time and subsequent travel distance, while nitrite concentrations inversely increased. The field experiment breakthrough curves were simulated with a two-dimensional site-specific model that included transport, denitrification, and microbial growth. Initial values for model parameters were obtained from laboratory incubations with aquifer core material and then refined to fit field breakthrough curves. The model and the lab results indicated that formate-enhanced nitrite reduction was nearly 4-fold slower than nitrate reduction, but in the lab, nitrite was completely consumed with sufficient exposure time. Results of this study suggest that a long-term injection of formate is necessary to test the remediation potential of this approach for nitrate contamination and that adaptation to nitrite accumulation will be a key determinative factor.In situ stimulation of denitrification has been proposed as a mechanism to remediate groundwater nitrate contamination. In this study, sodium formate was added to a sand and gravel aquifer on Cape Cod, MA, to test whether formate could serve as a potential electron donor for subsurface denitrification. During 16- and 10-day trials, groundwater from an anoxic nitrate-containing zone (0.5-1.5 mM) was continuously withdrawn, amended with formate and bromide, and pumped back into the aquifer. Concentrations of groundwater constituents were monitored in multilevel samplers after up to 15 m of transport by natural gradient flow. Nitrate and formate concentrations were decreased 80-100% and 60-70%, respectively, with time and subsequent travel distance, while nitrite concentrations inversely increased. The field experiment breakthrough curves were simulated with a two-dimensional site-specific model that included transport, denitrification, and microbial growth. Initial values for model parameters were obtained from laboratory incubations with aquifer core material and then refined to fit field breakthrough curves. The model and the lab results indicated that formate-enhanced nitrite reduction was nearly 4-fold slower than nitrate reduction, but in the lab, nitrite was completely consumed with sufficient exposure time. Results of this study suggest that a long-term injection of formate is necessary to test the remediation potential of this approach for nitrate contamination and that adaptation to nitrite accumulation will be a key determinative factor.

Environmental Science & Technology↗
USGS2015

Thermal maturity of Tasmanites microfossils from confocal laser scanning fluorescence microscopy

We report here, for the first time, spectral properties of Tasmanites microfossils determined by confocal laser scanning fluorescence microscopy (CLSM, using Ar 458 nm excitation). The Tasmanites occur in a well-characterized natural maturation sequence ( R o 0.48–0.74%) of Devonian shale ( n = 3 samples) from the Appalachian Basin. Spectral property λ max shows excellent agreement ( r 2 = 0.99) with extant spectra from interlaboratory studies which used conventional fluorescence microscopy techniques. This result suggests spectral measurements from CLSM can be used to infer thermal maturity of fluorescent organic materials in geologic samples. Spectra of regions with high fluorescence intensity at fold apices and flanks in individual Tasmanites are blue-shifted relative to less-deformed areas in the same body that have lower fluorescence intensity. This is interpreted to result from decreased quenching moiety concentration at these locations, and indicates caution is needed in the selection of measurement regions in conventional fluorescence microscopy, where it is common practice to select high intensity regions for improved signal intensity and better signal to noise ratios. This study also documents application of CLSM to microstructural characterization of Tasmanites microfossils. Finally, based on an extant empirical relation between conventional λ max values and bitumen reflectance, λ max values from CLSM of Tasmanites microfossils can be used to calculate a bitumen reflectance equivalent value. The results presented herein can be used as a basis to broaden the future application of CLSM in the geological sciences into hydrocarbon prospecting and basin analysis.

Fuel↗
USGS2012

Assessment of regional change in nitrate concentrations in groundwater in the Central Valley, California, USA, 1950s-2000s

A regional assessment of multi-decadal changes in nitrate concentrations was done using historical data and a spatially stratified non-biased approach. Data were stratified into physiographic subregions on the basis of geomorphology and soils data to represent zones of historical recharge and discharge patterns in the basin. Data were also stratified by depth to represent a shallow zone generally representing domestic drinking-water supplies and a deep zone generally representing public drinking-water supplies. These stratifications were designed to characterize the regional extent of groundwater with common redox and age characteristics, two factors expected to influence changes in nitrate concentrations over time. Overall, increasing trends in nitrate concentrations and the proportion of nitrate concentrations above 5 mg/L were observed in the east fans subregion of the Central Valley. Whereas the west fans subregion has elevated nitrate concentrations, temporal trends were not detected, likely due to the heterogeneous nature of the water quality in this area and geologic sources of nitrate, combined with sparse and uneven data coverage. Generally low nitrate concentrations in the basin subregion are consistent with reduced geochemical conditions resulting from low permeability soils and higher organic content, reflecting the distal portions of alluvial fans and historical groundwater discharge areas. Very small increases in the shallow aquifer in the basin subregion may reflect downgradient movement of high nitrate groundwater from adjacent areas or overlying intensive agricultural inputs. Because of the general lack of regionally extensive long-term monitoring networks, the results from this study highlight the importance of placing studies of trends in water quality into regional context. Earlier work concluded that nitrate concentrations were steadily increasing over time in the eastern San Joaquin Valley, but clearly those trends do not apply to other physiographic subregions within the Central Valley, even where land use and climate are similar.

California↗
USGS2025

Relations of groundwater quality to long-term surface disposal of produced water near the Midway-Sunset and Buena Vista Oil Fields, California, USA

Contamination of groundwater by oil-field fluids in proximity to oil and gas development has been an issue of concern to water users and regulators given long histories of development and legacy disposal practices. A robust set of geochemical tracers including petroleum hydrocarbon compounds, thermogenic gases, inorganic ion concentrations, stable isotopes, radioactive isotopes, and noble gases were used to assess if oil-field fluids mixed with groundwater near the Midway-Sunset and Buena Vista Oil Fields in California, USA. Results show evidence of mixing of oil-field fluids with groundwater within the study area from either anthropogenic or natural processes. Produced water plumes associated with modern surface disposal facilities, used since the late 1950s, extend up to 1.5 km and currently remain within the boundaries of the oil fields. Plumes associated with earlier routing of produced water down natural drainages and in large retention structures (Midway Basin and Sunset Basin) near the Buena Vista Lake Bed are present in groundwater east of the oil fields. Based on geochemical tracer evidence, aerial imagery, and aerial electromagnetic surveys, these legacy plumes reach the western portion of the Central Valley aquifer system, an important groundwater resource for agricultural and domestic supply. The legacy plume associated with Sunset Basin may further be detected downgradient in deeper groundwater beneath the southern extent of the Buena Vista Lake Bed based on the presence of thermogenic gases and petroleum hydrocarbon compounds.

California↗
USGS2016

Regional monitoring programs in the United States: Synthesis of four case studies from Pacific, Atlantic, and Gulf Coasts

Water quality monitoring is a cornerstone of environmental protection and ambient monitoring provides managers with the critical data they need to take informed action. Unlike site-specific monitoring that is at the heart of regulatory permit compliance, regional monitoring can provide an integrated, holistic view of the environment, allowing managers to obtain a more complete picture of natural variability and cumulative impacts, and more effectively prioritize management actions. By reviewing four long-standing regional monitoring programs that cover portions of all three coasts in the United States – Chesapeake Bay, Tampa Bay, Southern California Bight, and San Francisco Bay – important insights can be gleaned about the benefits that regional monitoring provides to managers. These insights include the underlying reasons that make regional monitoring programs successful, the challenges to maintain relevance and viability in the face of ever-changing technology, competing demands and shifting management priorities. The lessons learned can help other managers achieve similar successes as they seek to establish and reinvigorate their own monitoring programs.

California, Delaware, Florida, Maryland, New Jerse↗
USGS2008

Bacterial succession within an ephemeral hypereutrophic mojave desert playa lake

Ephemerally wet playas are conspicuous features of arid landscapes worldwide; however, they have not been well studied as habitats for microorganisms. We tracked the geochemistry and microbial community in Silver Lake playa, California, over one flooding/desiccation cycle following the unusually wet winter of 2004-2005. Over the course of the study, total dissolved solids increased by 10-fold and pH increased by nearly one unit. As the lake contracted and temperatures increased over the summer, a moderately dense planktonic population of 1 ?????106 cells ml-1 of culturable heterotrophs was replaced by a dense population of more than 1????????109 cells ml-1, which appears to be the highest concentration of culturable planktonic heterotrophs reported in any natural aquatic ecosystem. This correlated with a dramatic depletion of nitrate as well as changes in the microbial community, as assessed by small subunit ribosomal RNA gene sequencing of bacterial isolates and uncultivated clones. Isolates from the early-phase flooded playa were primarily Actinobacteria, Firmicutes, and Bacteroidetes, yet clone libraries were dominated by Betaproteobacteria and yet uncultivated Actinobacteria. Isolates from the late-flooded phase ecosystem were predominantly Proteobacteria, particularly alkalitolerant isolates of Rhodobaca, Porphyrobacter, Hydrogenophaga, Alishwenella, and relatives of Thauera; however, clone libraries were composed almost entirely of Synechococcus (Cyanobacteria). A sample taken after the playa surface was completely desiccated contained diverse culturable Actinobacteria typically isolated from soils. In total, 205 isolates and 166 clones represented 82 and 44 species-level groups, respectively, including a wide diversity of Proteobacteria, Bacteroidetes, Actinobacteria, Firmicutes, Gemmatimonadetes, Acidobacteria, and Cyanobacteria. ?? 2008 Springer Science+Business Media, LLC.

Microbial Ecology↗
USGS2002

Helium and carbon gas geochemistry of pore fluids from the sediment-rich hydrothermal system in Escanaba Trough

Ocean Drilling Program (ODP) Leg 169, which was conducted in 1996 provided an opportunity to study the gas geochemistry in the deeper part of the sediment-rich hydrothermal system in Escanaba Trough. Gas void samples obtained from the core liner were analyzed and their results were compared with analytical data of vent fluid samples collected by a submersible dive program in 1988. The gas geochemistry of the pore fluids consisted mostly of a hydrothermal component and was basically the same as that of the vent fluids. The He isotope ratios (R/RA = 5.6-6.6) indicated a significant mantle He contribution and the C isotopic compositions of the hydrocarbons [??13C(CH4) = -43???, ??13C(C2H6) = -20???] were characterized as a thermogenic origin caused by hydrothermal activity. On the other hand, the pore fluids in sedimentary layers away from the hydrothermal fields showed profiles which reflected lateral migration of the hydrothermal hydrocarbons and abundant biogenic CH4. Helium and C isotope systematics were shown to represent a hydrothermal component and useful as indicators for their distribution beneath the seafloor. Similarities in He and hydrocarbon signatures to that of the Escanaba Trough hydrothermal system were found in some terrestrial natural gases, which suggested that seafloor hydrothermal activity in sediment-rich environments would be one of the possible petroleum hydrocarbon generation scenarios in unconventional geological settings. ?? 2002 Elsevier Science Ltd. All rights reserved.

Applied Geochemistry↗