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Hydrogeologic setting and simulation of pesticide fate and transport in the unsaturated zone of a regolith-mantled, carbonate-rock terrain near Newville, Pennsylvania

Physical and chemical data were collected from May 1991 through April 1993 at a 4.5 hectare field site in Cumberland County, Pa., about 5 kilometers southeast of Newville. These data were used to define the hydrogeologic setting of a field site representative of the intensively farmed carbonate valleys of southeastern and south-central Pennsylvania. The environmental processing of commonly used pesticides (herbicides, fungicides, and insecticides) in the unsaturated zone was simulated with a process- oriented digital model to evaluate the environmental fate and transport of pesticides to ground water. Site data and modelling results provide a basis for a discussion of water-quality implications of agricultural best-management practices. The carbonate valleys of Pennsylvania comprise regolith-mantled carbonate-rock terrains that consist of broad undulating upland areas dissected by mostly dry valleys and widely spaced spring-fed creeks. The upland areas are farmed and exhibit possess a doline karst topography with many closed depressions, sinkholes, and bedrock outcrops. Unsaturated materials at the field site consist of an almost continuous soil cover composed of fine-grained residuum underlain by an intermediate vadose zone composed of karstified limestone. Soils are absent on scattered bedrock outcrops and are more than 12 meters thick in other areas of the site. The soil profile stores appreciable quantities of water with a volumetric average of about 36 percent water at field capacity. Organic carbon content of soil materials is about 1.7 percent in the Ap-horizon and from 0.1 to 0.3 percent throughout the full thickness of the B- and C-horizons. Atrazine, metolachlor, simazine, and the atrazine soil metabolites deethylatrazine and deisopropylatrazine were detected at concentrations above 0.05 mg/L in just the upper 0.6 meters of soil materials. However, detectable concentrations of atrazine, simazine, and atrazine soil metabolites were measured in water samples from lysimeters installed in soil materials at depths of 1.2, 2.1, and 3.7 meters and from monitor wells completed in the saturated zone to depths of 122 meters. Data collected from the field site were used to configure a pesticide screening model based on the pesticide version of the leaching estimation and chemistry model (LEACHP) developed by Wagenet and Hutson (1987). Model simulations show that most field-applied pesticides volatilize to the atmosphere, accumulate in soils, degrade in the subsurface environment, or leach to ground water. Model results were used to rank the leaching potentials of 66 pesticides. Eighteen of 32 herbicides, 4 of 9 fungicides, and 10 of 25 insecticides have moderate to large potential for leaching to ground water. A review of available pesticide monitoring data suggests that many compounds given moderate or high leaching potentials have not been tested for in ground water and the presence of pesticides in Pennsylvania's ground water may be underreported. Monitoring data do not exist for more than two-thirds of the pesticide compounds currently used in agricultural, carbonate areas of Pennsylvania. Knowledge of processes that govern fate and transport of pesticides is needed to facilitate development of effective pesticide best-management practices. In addition to comprehensive monitoring for pesticides and pesticide degradation products in ground water downgradient of areas of pesticide use, improved (1) characterization of unsaturated flow and transport through regolith mantled carbonate rocks, (2) estimates of pesticide degradation rates, (3) understanding of soil-property controls on pesticide movement, and (4) management models developed from process-oriented research would aid in understanding the processes.

Water-Resources Investigations Report↗

Ground-water levels, predevelopment ground-water flow, and stream-aquifer relations in the vicinity of the Savannah River Site, Georgia and South Carolina

Ground-water levels, predevelopment ground-water flow, and stream-aquifer relations in the vicinity of the U.S. Department of Energy Savannah River Site, Georgia and South Carolina, were evaluated as part of a cooperative study between the U.S. Geological Survey, U.S. Department of Energy, and Georgia Department of Natural Resources. As part of this evaluation: (1) ground-water-level fluctuations and trends in three aquifer systems in sediment of Cretaceous and Tertiary age were described and related to patterns of ground-water use and precipitations; (2) a conceptual model ofthe stream-aquifer flow system was developed; (3) the predevelopment ground-water flow system, configuration of potentiometric surfaces, trans-river flow, and recharge-discharge relations were described; and (4) stream-aquifer relations and the influence of river incision on ground-water flow and stream-aquifer relations were described. The 5,147-square mile study area is located in the northern part of the Coastal Plain physiographic province of Georgia and South Carolina. Coastal Plain sediments comprise three aquifer systems consisting of seven aquifers that are separated hydraulically by confining units. The aquifer systems are, in descending order: (1) the Floridan aquifer system—consisting of the Upper Three Runs and Gordon aquifers in sediments of Eocene age; (2) the Dublin aquifer system—consisting of the Millers Pond, upper Dublin, and lower Dublin aquifers in sediments of Paleocene-Late Cretaceous age; and (3) the Midville aquifer system—consisting of the upper Midville and lower Midville aquifers in sediments of Late Cretaceous age. The Upper Three Runs aquifer is the shallowest aquifer and is unconfined to semi-confined throughout most of the study area. Ground-water levels in the Upper Three Runs aquifer respond to a local flow system and are affected mostly by topography and climate. Ground-water flow in the deeper, Gordon aquifer and Dublin and Midville aquifer systems is characterized by local flow near outcrop areas to the north, changing to intermediate flow and then regional flow downdip (southeastward) as the aquifers become more deeply buried. Water levels in these deeper aquifers show a pronounced response to topography and climate in the vicinity of outcrops, and diminish southeastward where the aquifer is more deeply buried. Stream stage and pumpage affect ground-water levels in these deeper aquifers to varying degrees throughout the study area. The geologic characteristics of the Savannah River alluvial valley substantially control the configuration of potentiometric surfaces, ground-water-flow directions, and stream-aquifer relations. Data from 18 shallow borings indicate incision into each aquifer by the paleo Savannah River channel and subsequent infill of permeable alluvium, allowing for direct hydraulic connection between aquifers and the Savannah River along parts of its reach. This hydraulic connection may be the cause of large ground-water discharge to the river near Jackson, S.C., where the Gordon aquifer is in contact with Savannah River alluvium, and also the cause of lows or depressions formed in the potentiometric surfaces of confined aquifers that are in contact with the alluvium. Ground water in these aquifers flows toward the depressions. The influence of the river is diminished downstream where the aquifers are deeply buried, and upstream and downstream ground-water flow is possibly separated by a water divide or "saddle". Water-level data indicate that saddle features probably exist in the Gordon aquifer and Dublin aquifer system, and also might be present in the Midville aquifer system. Ground-water levels respond seasonally or in long term to changes in precipitation, evapotranspiration, pumpage, and river stage. Continuous water-level data and water-levels measured in a network of 271 wells during the Spring (May) and Fall (October) in 1992, indicate that seasonal water-level changes generally are less than 4 feet, and that larger changes occur near supply wells. Long-term data (more than 10 years of record) from 283 wells indicate that water levels in most aquifers declined during some period prior to 1993. Although most declines were less than 15 feet and were limited to scattered areas influenced by supply wells, widespread declines of as much as 59 feet occurred in the lower Midville aquifer in Richmond County, Georgia. Water-level data at well-cluster sites indicate that in the vicinity of major ground-water divides, head decreases with depth; and in the vicinity of a regional drain, such as the Savannah River, head increases with depth. Although this vertical head distribution holds true over much of the study area, water-level data indicate that the Gordon, Millers Pond, and lower Dublin aquifers are apparent hydrologic "sinks" in parts of the study area, indicating a potential for vertical leakage from both above and below. Reasons for anomalously low heads in these three aquifers are unclear, but probably are related to: (1) subsurface pinchout of the aquifer, that influences flow patterns in the ground-water flow system, (2) hydraulic connection of the aquifer to river alluvium and associated large ground-water discharge, or (3) water-level declines as a result of pumpage. Estimated average ground-water discharge to the Savannah River based on data from 1941, 1942, and 1949, was 1,220 cubic feet per second; of which 46 percent was from the local flow system, 41 percent was from the intermediate flow system, and 13 percent was from the regional flow system. Estimated ground-water discharge during the 1954 and 1986 droughts indicates that the contribution from the intermediate flow system decreased in a downstream direction, and that most ground-water discharge was from the local flow system. The decreased contribution from the intermediate flow system in downstream reaches may be related to a downdip (downstream) thickening of confining units underlying the stream, that reduces upward leakage of water. Flow lines based on contours of the estimated predevelopment potentiometric surface of the confined Dublin and Midville aquifer systems, suggest ground-water flow beneath the floodplain of the Savannah River from one side of the river to the other side. This phenomenon, termed trans-river flow, is assumed to occur for a short distance into Georgia prior to discharge into the Savannah River alluvial valley. Trans-river flow is influenced by changes in hydraulic gradient (ground-water levels) near the river. Trans-river flow cannot be inferred from contours of the potentiometric surface of the Gordon or Upper Three Runs aquifers.

Georgia, South Carolina↗

Potentiometric surface of the Sparta aquifer in eastern and south-central Arkansas and north-central Louisiana, and the Memphis Aquifer in east-central Arkansas, October 1996-July 1997

During the 1997 water year, the water level in the Sparta and Memphis aquifers was measured in about 274 wells in Arkansas, and the water level in the Sparta aquifer was measured in about 55 wells in Louisiana. The potentiometric surface data reveal spatial trends across the study area. In Arkansas, the altitude of the potentiometric surfaced ranged from 199 feet below sea level in Union County to 307 feet above sea level in Saline County. In Louisiana, the altitude of the potentiometric surface ranged from 224 feet below sea level in Ouachita Parish to 230 feet above sea level in Bienville Parish. The general direction of ground-water flow in the Sparta and Memphis aquifers is from the west to the Southeast. The regional direction of ground-water flow in Arkansas is from the north and west to the south and east, away from the recharge zone in the outcrop and subcrop area, except near areas affected by intense ground-water withdrawals; such areas are manifested by large cones of depression centered in Columbia, Jefferson, and Union Counties. The regional ground-water flow in the Sparta aquifer in north-central Louisiana generally is downdip in an easterly direction from the recharge zone in the outcrop and subcrop area in the west toward the Mississippi Alluvial Plain. The potentiometric surface of the Sparta aquifer in Arkansas and Louisiana exhibits cones of depression descending below sea level. Comparison of potentiometric surface maps through time shows that the cones of depression in Columbia and Union Counties are coalescing at or near the Columbia and Union County line. However, the general direction of ground-water movement indicates that heavy pumpage locally has altered or reversed the natural direction of flow in some areas. Flow in these areas is toward the cones of depression at the center of pumping. Hydrographs from wells in the Sparta and Memphis aquifers reveals that water levels have declined more than 2.0 feet per year in some wells. Long-term hydrographs of eight wells in Arkansas, during the period 1972-1997, reveal water-level declines ranging from less than 0.8 foot per year in Phillips County to more than 2.0 feet per year in Union County. Long-term hydrographs of two wells in Louisiana, during the period 1972-1997, reveal water-level declines were more than 2.0 feet per year in Lincoln and Ouachita Parishes.

Water-Resources Investigations Report↗

Potentiometric surface of the Cockfield aquifer in southeastern Arkansas and the Wilcox aquifers in southern and northeastern Arkansas, October 1996-July 1997

The Cockfield and Wilcox aquifers are secondary sources of water for local use in southern and northeastern Arkansas, where in 1995 more than 51 million gallons per day of water was withdrawn. During October 1996 to July 1997, water levels in the Cockfield and Wilcox aquifers were measured in 104 wells in Arkansas. The potentiometric surface data reveal spatial trends in both aquifers across the study areas. The regional direction of ground-water flow of the Cockfield aquifer is generally southeastward, away from the outcrop area, except where affected by intense ground-water withdrawals. The potentiometric surface indicates that heavy pumpage has altered or reversed the natural direction of flow in some areas. Flow in these areas is toward centers of pumping within cones of depression. A cone of depression caused by the pumpage near Greenville, Mississippi, extends into Chicot, Desha, and Drew Counties. This cone of depression has altered flow patternArkansas. Long-term hydrographs of six wells, during the period 1971-1996, showed water levels declined at an average rate between 0.5 and 1.0 foot per year at these locations. The regional direction of ground-water flow in the Wilcox aquifers is generally toward the east and south, away from the outcrop except where water levels are affected by intense ground-water withdrawals. The potentiometric surface indicates that heavy pumpage has altered or reversed the natural direction of ground-water flow in some areas. Flow in these areas is toward centers of pumping within cones of depression. Two cones of depression are centered in the vicinity of Paragould and West Memphis, Arkansas, where ground-water withdrawals have altered the natural direction of flow. Long-term hydrographs of seven wells, during the period 1971- 1996, show water-level declines in the Wilcox aquifer in northeastern Arkansas generally were between 0.5 and 1.0 foot per year but were more than 1.0 foot per year in two wells. The U.S. Geological Survey in cooperation with the Arkansas Soil and Water Conservation Commission and the Arkansas Geological Commission has monitored water levels in the Cockfield and Wilcox aquifers since the 1960's. During October 1996 to July 1997, 53 water-level measurements were made in wells completed in the Cockfield aquifer, 13 water-level measurements were made in wells completed in the Wilcox aquifer in southern Arkansas, and 38 water-level measurements were made in wells com- pleted in the Wilcox aquifer in northeastern Arkansas. The purpose of these measurements was to provide information to describe the recent potentiometric surfaces and long-term water-level trends in the Cockfield and Wilcox aquifers. This report presents the results as potentiometric surface maps and as long-term water-level hydrographs.

Arkansas↗

Hydrogeology of, water withdrawal from, and water levels and chloride concentrations in the major Coastal Plain aquifers of Gloucester and Salem Counties, New Jersey

Eight aquifers underlying Gloucester and Salem Counties in the southwestern Coastal Plain of New Jersey provide nearly all the drinking water for the 295,000 people who live in the area. Ground-water withdrawals in the two-county area and adjoining counties have affected water levels in several of these aquifers. Ground-water withdrawals in the two-county area also have affected the quality of water, increasing the chloride concentration in several of the aquifers as a result of saltwater intrusion. This report contains hydrologic data from the two-county area, including geometry and extent of hydrogeologic units, thickness and altitude of each aquifer, withdrawals from and water levels in major aquifers, and chloride concentrations in water from each aquifer. Reported ground-water withdrawals in Gloucester and Salem Counties during 1975-95 averaged 7,800 Mgal/yr (million gallons per year) for public supply, 4,900 Mgal/yr for industrial use, 700 Mgal/yr for irrigation, 500 Mgal/yr for power plants, 50 Mgal/yr for commercial use, and about 40 Mgal/yr for mining. Withdrawals for domestic self-supply in 1994 are estimated to be about 2,600 Mgal/yr, but only about 20 percent (520 Mgal/yr) is thought to be consumptive use; the remainder is returned to the aquifer through septic systems. The most heavily used aquifer in Salem and Gloucester Counties is the Upper Potomac-Raritan-Magothy aquifer, followed by, in decreasing order of use, the Middle Potomac-Raritan-Magothy aquifer, the Lower Potomac-Raritan-Magothy aquifer, the Kirkwood-Cohansey aquifer system, and the Wenonah-Mount Laurel aquifer. Reported withdrawals from these aquifers during 1975-95 averaged 5,000, 3,700, 3,200, and 330 Mgal/yr, respectively. Withdrawals from the Wenonah-Mount Laurel aquifer in Gloucester County increased during 1993-96 because of New Jersey Department of Environmental Protection restrictions on new withdrawals from the deeper Potomac-Raritan-Magothy aquifer system. Because of the increased rate of withdrawal, water-level altitudes in the Wenonah-Mount Laurel aquifer in some parts of the two counties in 1996 were from 5 to 40 ft lower than water levels measured in 1993 and previous years, reaching a low of almost 40 ft below sea level in Washington Township, Gloucester County. Ground water in the Upper, Middle, and Lower Potomac-Raritan-Magothy aquifers in the study area is withdrawn from the outcrop areas near the Delaware River downdip to the Glassboro vicinity. Water-level altitudes in 1993 in the three aquifers were near sea level in the outcrop areas near the Delaware River, but were as low as 80 ft below sea level in parts of Gloucester County that were affected by withdrawals in Camden County and were 20 to 60 ft below sea level near major withdrawal centers in the study area. Chloride concentrations in water samples from selected wells in seven aquifers throughout Gloucester and Salem Counties have been monitored since 1949. These aquifers include the Kirkwood-Cohansey aquifer system, the Vincentown and Wenonah-Mount Laurel aquifers, the Englishtown aquifer system, and the Upper, Middle, and Lower Potomac-Raritan-Magothy aquifers. The results of chloride analyses of 4,221 samples from 496 wells indicate the extent and magnitude of saltwater intrusion in these aquifers, six of which have been affected to varying degrees by saltwater intrusion. The confined Piney Point aquifer and the unconfined Kirkwood-Cohansey aquifer system show no measurable effects of saltwater intrusion in the study area. Chloride concentrations in water from selected public-supply wells screened in the Upper, Middle, and Lower Potomac-Raritan-Magothy aquifers have increased over time in communities along the Delaware River and further inland in both Gloucester and Salem Counties. Elevated chloride concentrations in the Potomac-Raritan-Magothy aquifer system are widespread in this area but rarely exceed the drinking-water standard of 250 milligrams per liter.

Water-Resources Investigations Report↗

Simulation of ground-water flow and movement of the freshwater-saltwater interface in the New Jersey coastal plain

The confined aquifers of the New Jersey Coastal Plain are sands that range in thickness from 50 to 600 feet and are separated by confining units. The confining units are composed of silts and clays that range in thickness from 500 to 1,000 feet. The aquifers are recharged by precipitation on their outcrop areas. This water then flows laterally downdip and vertically to the deeper confined aquifers. The confined aquifers ultimately discharge to the Raritan and Delaware Bays and to the Atlantic Ocean. In 1988, ground-water withdrawals from confined and unconfined New Jersey Coastal Plain aquifers were approximately 345 million gallons per day, more than 75 percent of which was pumped from the confined aquifers. These withdrawals have created large cones of depression in several Coastal Plain aquifers near populated areas, particularly in Camden and Monmouth Counties. The continued decline of water levels in confined aquifers can cause saltwater intrusion, reduce stream discharge near the outcrop areas, and threaten the quality of the ground-water supply. SHARP, a quasi-three-dimensional finite-difference computer model that can simulate freshwater and saltwater flow, was used to simulate the ground-water flow system in the New Jersey Coastal Plain, including the location and movement of the freshwater-saltwater interface in nine aquifers and eight intervening confining units. The freshwater-saltwater interface is defined as the hypothetical line seaward of which the chloride concentration is equal to or greater than 10,000 milligrams per liter. Model simulations were used to estimate the location and movement of the freshwater-saltwater interface resulting from (1) eustatic sea-level changes over the past 84,000 years, (2) ground-water withdrawals from 1896 through 1988, (3) and future ground-water withdrawals from 1988 to 2040 from Coastal Plain aquifers. Simultion results showed that the location and movement of the freshwater-saltwater interface are more dependent on the historical sea level than on the stresses imposed on the flow system by ground-water withdrawals from the Coastal Plain aquifers from 1896 to 1988. Results of a predictive simulation in which pumpage from existing wells was increased by 30 percent indicate that additional withdrawals from each of the eight confined aquifers in the Coastal Plain would broaden and deepen the existing cones of depression and result in significant drawdowns from the 1988 potentiometric surfaces. Drawdowns of 30 feet were simulated at the center of the cone of depression in the Upper, Middle, and Lower Potomac-Raritan-Magothy aquifers in Camden and Ocean Counties. Simulated drawdowns exceeded 80 feet at the center of the cone of depression in the Wenonah-Mount Laurel and Englishtown aquifers in Monmouth County. Drawdowns of 30 feet were simulated in the lower Kirkwood-Cohansey and confined Kirkwood aquifers in Cape May County. Simulation results showed that the increase in ground-water withdrawals would result in only minimal movement of the freshwater-saltwater interface by 2040, despite large drawdowns.

New Jersey↗

Sources, instream transport, and trends of nitrogen, phosphorus, and sediment in the lower Tennessee River basin, 1980-96

In 1997, the U.S. Geological Survey (USGS) began an assessment of the lower Tennessee River Basin as part of the National Water-Quality Assessment Program. Existing nutrient and sediment data from 1980 to 1996 were compiled, screened, and interpreted to estimate watershed inputs from nutrient sources, provide a general description of the distribution and transport of nutrients and sediments in surface water, and evaluate trends in nutrient and sediment concentrations in the lower Tennessee (LTEN) River Basin. Nitrogen inputs from major sources varied widely among tributary basins in the LTEN River Basin. Point source wastewater discharges contributed between 0 and 0.61 tons per square mile per year [(tons/mi 2 )/yr]. Of the nonpoint sources of nitrogen for which inputs were estimated (atmospheric deposition, nitrogen fixation, fertilizer application, and livestock waste) livestock waste contributed the largest input in about two-thirds (7 out of 11) of the tributary basins, and fertilizer application contributed the largest input in the remaining 4 basins. Nitrogen input from fertilizer application was the most variable spatially among the nonpoint sources of nitrogen, ranging from 1.5 to 23 (tons/mi 2 )/yr. Atmospheric deposition estimates varied the least from basin to basin, ranging from 1.6 to 2.0 (tons/mi 2 )/yr. Estimates of nitrogen input from livestock waste ranged between 2.0 to 13 (tons/mi 2 )/yr. The percentage of the input from each of these nonpoint sources that entered the surface-water system is not known. Wastewater discharge contributed between 0 and 0.14 (ton/mi 2 )/yr of phosphorus to tributary basins. Livestock waste contributed most of the input in 8 out of the 11 basins, and fertilizer application contributed the most in the remaining 3 basins. Estimates of phosphorus input for fertilizer application ranged from 0.35 to 5.1 (tons/mi 2 )/yr and from 0.62 to 4.3 (tons/mi 2 )/yr from livestock waste. Reservoirs on the main stem of the Tennessee River and on the Duck and Elk Rivers affect nutrient transport because hydrodynamic conditions in the reservoirs promote assimilation by aquatic plants and deposition of particulate matter. Observed decreases in total nitrite plus nitrate and dissolved-orthophosphorus concentrations in reservoirs or at sites downstream of reservoirs during summer months were probably related to seasonality of plant growth. Nutrient and sediment data used to estimate annual instream loads and yields were compiled from various water-quality monitoring programs and represent the best available data in the LTEN River Basin, but these data have several characteristics that limit accuracy of load estimates. Many of the monitoring programs were not designed with the objective of annual load estimation, and data representing storm transport are, therefore, sparse; sampling and analytical methods varied through time and among the monitoring programs, hampering spatial and temporal comparisons. The load estimates computed from these data are useful for evaluating broad spatial patterns of instream load, and comparisons of instream load to inputs, but may not be sufficiently accurate for local-scale evaluations of water quality. Estimates of the mean annual instream load of total nitrogen entering (Chattanooga, Tenn.) and leaving (Paducah, Ky.) the LTEN River Basin were 29,000 and 60,000 tons per year (tons/yr), respectively. These estimates represent a gain of 31,000 tons/yr, on average, across the area (18,930 mi 2 ) between these inlet and outlet sites. The sum of the mean annual instream load from gaged tributaries to the main stem within the study unit was 14,000 tons/yr; however, this number cannot be directly compared with the gain between the inlet and outlet sites because (1) the gaged area represents only 30 percent of the total area and (2) the period of record at many tributary sites did not correspond with the period of record at the inlet or outlet sites. Estimates of mean annual instream load of total phosphorus at the inlet and outlet sites of the LTEN River Basin were 1,300 and 5,000 tons/yr, respectively, representing a gain of 3,700 tons/yr, on average, across the study unit. The sum of the gaged tributary load, representing only 28 percent of the area contributing to the main stem, was 4,300 tons/yr. Although this number cannot be closely compared with the gain throughout the study unit, for the same reasons given for total nitrogen, a general comparison suggests that the main stem of the Tennessee River and the tributary embayments along the main stem function as a sink for total phosphorus, removing a substantial amount from the water column through deposition or assimilation. The estimates of inputs can be compared and correlated with yields (area-normalized instream loads); significant correlations between estimates of inputs and yields might be useful as predictive tools for instream water quality where monitoring data are not available. Yields of nitrogen correlated moderately well with inputs from nonpoint sources, based on 1992 estimates. Nitrogen yield was highest [3.5 (tons/mi 2 )/yr] for Town Creek, for which the balance of nonpoint-source inputs to agricultural lands (fertilizer application plus nitrogen fixation plus livestock waste minus harvest) was also the highest [15 (tons/mi 2 )/yr]. Nitrogen yield was low [1.0 (tons/mi 2 )/yr] for the Buffalo River, for which the balance of agricultural nonpoint-source input was correspondingly low [3.2 (tons/mi 2 )/yr, the second lowest]. Correlation of wastewater discharge with yield was poor, and contrasted with the significant correlation between wastewater discharge and median nitrogen concentration during low streamflow. The poor correlation between wastewater discharge and annual yield was expected, however, as wastewater discharge is a small fraction compared with annual yield. In contrast with nitrogen, phosphorus yield did not correlate well with any estimated inputs or land-use types for the tributary basins. Phosphorus yield was highest [1.1 and 0.93 (tons/mi 2 )/yr] at two sites along the Duck River and at Elk River near Prospect [0.89 (ton/mi 2 )/yr]; however, estimates of inputs at these sites were in the middle of their respective ranges. The influence of the outcrop of phosphatic limestone formations of the brown-phosphate districts in the lower Duck and lower Elk River Basins might be responsible for the poor correlation between estimated inputs and yields of phosphorus. The outcrop pattern of these phosphatic limestones are an important factor to consider as regional boundaries are established for attainable, region-specific water-quality criteria for total phosphorus. Estimates of sediment input from cropland soil erosion in 1992 ranged from 51 to 540 (tons/mi 2 )/yr among the major hydrologic units in the LTEN River Basin. Information was not available to estimate this input for individual tributaries. Sediment yield estimates ranged from 65 to 263 (tons/mi 2 )/yr for the three tributary monitoring basins for which instream data were available, and from 17 to 26 (tons/mi 2 )/yr for the Tennessee River at South Pittsburg and at Pickwick Landing Dam, respectively. Lower sediment yields for the main stem sites compared with the tributary sites is probably due to sediment deposition in the main stem of the Tennessee River and tributary embayments along the main stem. Most of the significant trends in nutrient concentrations from about 1985 to about 1995 were decreasing trends, except for total nitrite plus nitrate, which increased at one site on the Elk River. The spatial distribution of decreasing trends of total nitrogen and total ammonia corresponds with the spatial variation among basins in wastewater loading rate. The time period of observed trends corresponds to the period of improvements in municipal treatment, thus decreases in wastewater effluent concentrations of nitrogen might be responsible for the decreasing trend in instream concentrations at these sites. Concentrations of total phosphorus did not decrease during this period at these sites, as might have been expected considering the reductions in wastewater input of phosphorus during this period.

Alabama, Georgia, Kentucky, Mississippi, Tennessee↗

Status of Water Levels in Aquifers in the Nacatoch Sand of Southwestern and Northeastern Arkansas and the Tokio Formation of Southwestern Arkansas, 1999

Nacatoch Sand and Tokio Formation aquifers in southwestern Arkansas and the Nacatoch Sand aquifer in northeastern Arkansas are a source of water for industrial, public supply, domestic, and agricultural uses. Potentiometric-surface maps were constructed from water-level measurements made in 59 wells completed in the Nacatoch Sand and 45 wells completed in the Tokio Formation from April through May 1999. The direction of ground-water flow in the aquifer in the Nacatoch Sand in northeastern Arkansas generally is towards the southeast. The potentiometric high is located along the north and northwestern boundaries. The direction of ground-water flow in the aquifer in the Nacatoch Sand in southwestern Arkansas is towards the south-southeast in Little River, Miller, and Hempstead Counties and to the east-southeast in Nevada and Clark Counties. The potentiometric high is located within the outcrop area in north-central Hempstead County. A cone of depression exists in the aquifer in the Nacatoch Sand at Hope in southeastern Hempstead County. The direction of ground-water flow in the aquifer in the Yokio Formation in southwestern Arkansas generally is towards the southeast. The potentiometric high is within the outcrop area. An area of artesian flow exists in southeastern Pike, northeastern Hempstead, and northwestern Nevada Counties. One apparent cone of depression might exist northwest of Hope in Hempstead County. In northeastern Arkansas, withdrawals from the Nacatoch Sand increased by 736 percent from 1965 to 1995. In southwestern Arkansas withdrawals from aquifers in the Nacatoch Sand and Yokio Formation increased by 125 percent and 201 percent, respectively, from 1965 to 1980 and decreased by 78 percent and 63 percent, respectively, from 1980 to 1995. Long-term hydrographs were prepared for 13 wells in the study area. Changes in water levels in some wells may be associated with changes in withdrawals from the respective aquifers.

Water-Resources Investigations Report↗

Geology and ground-water resources of southeastern New Hampshire

The continued growth and development of southeastern New Hampshire, an area of about 390 square miles adjacent to the Atlantic Ocean, will depend partly on effectively satisfying the demand for water, which has increased rapidly since World War II. The report identifies and describes the principal geologic units with respect to the occurrence of ground water. These units include bedrock and the various unconsolidated deposits that mantle the bedrock surface discontinuously throughout the area. The bedrock formations, consisting of igneous and metamorphic rocks, chiefly of Paleozoic age, form a single water-bearing unit. Ground water is in joints and fractures. The fractures are small and scattered and therefore impart only a low permeability to the rocks. Wells in the bedrock commonly produce small but reliable supplies of ground water at depths of less than 150 feet. The yields of about 80 wells inventoried for this report ranged from 1? to 100 gpm (gallons per minute) and the median was 912 gpm. Depths ranged from 45 to 600 feet. The unconsolidated deposits consist of glacial drift of Pleistocene age; swamp deposits, alluvium, and beach deposits of Recent age; and eolian deposits of Pleistocene -and Recent age. For this report the glacial drift is divided into till, ice-contact deposits, marine deposits, and outwash and shore deposits. Glacial till forms a discontinuous blanket, commonly less than 15 but in some hills (drumlins) as much as about 200 feet thick. It has a low permeability but, because of its widespread outcrop area, it has been utilized as a source of water for numerous domestic supplies. Because most wells in till are shallow, many fail to meet modern demands during dry summers. Ice-contact deposits locally form kames, kame terraces, kame plains, and ice-channel fillings throughout the area. They overlie bedrock and till and range in thickness from less than 1 foot to as much as 190 feet. In general, the ice-contact deposits are coarse textured and permeable, but variations in- the physical and hydrologic properties of a single deposit and from deposit to deposit are common. Ice-contact deposits are the source of the larger ground-water supplies in southeastern New Hampshire. Marine deposits underlie lowlands and valleys to a distance of about 20 miles inland from the present coastline. They commonly overlie bedrock and till and at places overlie or are interbedded with ice-contact deposits. Marine deposits range in thickness from less than 1 foot to possibly 75 feet. They are fine textured and impermeable; they do not yield water to wells in southeastern New Hampshire but generally act as a barrier to ground-water movement. Outwash and shore deposits form broad sand plains or gently sloping terraces of small extent. At most places the outwash and shore deposits, which range in thickness from less than 1 foot to about 50 feet, overlie marine deposits, but at some places they overlie bedrock, till, or ice-contact deposits. The outwash and shore deposits are fine textured and moderately permeable. They commonly yield enough ground water to meet the needs of farms, homes, and small industries. Alluvium underlies the flood plains and channels of the principal streams and overlies bedrock and older unconsolidated deposits wherever streams cross the older units. The alluvium generally is not tapped by wells. Beach deposits occupy areas along the Atlantic Ocean between promontories of bedrock or till. In general beach deposits are permeable and are a source of water supplies for domestic use. Yields of wells are limited, however, by the danger of drawing in salty water. Recharge in southeastern New Hampshire is derived principally from precipitation on outcrop areas of ice-contact deposits and outwash and shore deposits during the nongrowing season. Ground water is discharged naturally by springs, by effluent seepage to streams and other bodies of surface water, and by evapotranspiration. It

Water Supply Paper↗

Aquifers in the Sokoto basin, northwestern Nigeria, with a description of the general hydrogeology of the region

The Sokoto Basin of northwestern Nigeria lies in the sub-Saharan Sudan belt of west Africa in a zone of savannah-type vegetation. Rainfall, averaging about 30 inches annually in much of the basin, occurs chiefly in a wet season which lasts from May to October. A prolonged dry season extending from October to April is dominated by dusty harmattan winds from the northeast. April and May are the hottest months, when temperatures occasionally reach 105?F. Flow in streams of the Sokoto Basin is mostly overland runoff. Only in a few reaches, fed by ground-water discharge from the sedimentary rocks, are streams perennial. In the River Zamfara basin, ground-water discharge contributes almost 1 inch of the average 3.33 inches of total annual runoff. In the vicinity of Sokoto, the River Rima flows throughout the year sustained by spring discharge from perched ground water in limestone of the Kalambaina Formation. On the crystalline terrane where most of the streams rise, total annual runoff may exceed 5 inches, very little of which is ground-water discharge. The sedimentary rocks of the basin range in age from Cretaceous to Tertiary and are composed mostly of interbedded sand, clay, and some limestone; the beds dip gently toward the northwest. Alluvium of Quaternary age underlies the lowlands of the River Sokoto (now Sokoto) and its principal tributaries. These rocks contain three important artesian aquifers, in addition to regional unconfined ground-water bodies in all the principal outcron areas, and a perched water body in the outcrop of the Kalambaina Formation. Artesian aquifers occur at depth in the Gundumi Formation, the Rima Group, and the Gwandu Formation and are separated from one another by clay beds in the lower part of the Rima Group and the Dange Formation. In outcrop, clay in the Dange Formation also supports the perched water of the Kalambaina Formation. The Gundumi Formation, resting on the basement complex, is composed of varicolored clay, sand, and gravel and attains a thickness of 800 to 1,000 feet in its downdip extensions. Most of the formation is thin bedded and clayey and therefore does not yield large quantities of water to boreholes; the average yield is 2,700 gph (gallons per hour). (All gallons are imperial gallons.) Nevertheless, the upper part of the formation is sandy and more permeable and forms a regional artesian aquifer from which yields of as much as 6,600 gph are obtained from single boreholes. Clay in the lower part of the Rima Group confines the Gundumi aquifer downdip, so that at Rabah and Sokoto, for example, in the River Sokoto fadama (valley floor), artesian flow is found in boreholes screened in the Gundumi. Aquifer tests indicate low transmissivities, ranging from 300 to 5,000 gpd per ft (gallons per day per foot) in the lower part of the Gundumi Formation; but in the upper sandy zone the transmissivities are much higher, reaching 66,000 gpd per ft. In the western part of the Sokoto Basin, more productive aquifers with higher heads usually lie above the Gundumi aquifer so that it is not attractive for development, except in the River Sokoto fadama where artesian flow is possible. The Illo Group, which is in part contemporaneous with the Gundumi Formation, includes interbedded varicolored clay and grit in the southern part of the Sokoto Basin. The upper part of the Illo is known to be water-bearing; however, except for the test borehole at Mungadi, little is known of its subsurface extent and water-yielding potential. Overlying the Gundumi Formation in the central and northern part of the Sokoto Basin are interbedded fine gray sand and dark gray clay of the Wurno and Taloka Formations, separated in the extreme north by clay shale of the Dukamaje Formation. Collectively known as the Rima Group, these sediments attain a thickness of more than 1,000 feet near the Niger border. At depth and downdip the clayey beds practically disappear; the sandy beds become thicker and coar

Water Supply Paper↗

Ground-water resources and geology of northern and central Johnson County, Wyoming

Northern and central Johnson County, Wyo., is an area of about 2,600 square miles that lies principally in the western part of the Powder River structural basin but also includes the east flank of the Bighorn Mountains. Sedimentary rocks exposed range in age from Cambrian to Recent and have an average total thickness of about 16,000 feet. Igneous and metamorphic rocks of Precambrian age crop out in the Bighorn Mountains. Rocks of pre-Tertiary age, exposed on the flanks and in the foothills of the Bighorns, dip steeply eastward and lie at great depth in the Powder River basin. The rest of the project area is underlain by a thick sequence of interbedded sandstone, siltstone, and shale of Paleocene and Eocene age. Owing to the regional structure, most aquifers in Johnson County contain water under artesian pressure. The Madison Limestone had not been tapped for water in Johnson County at the time of the present investigation (1963), but several wells in eastern Big Horn and Washakie Counties, on the west flank of the Bighorn Mountains, reportedly have flows ranging from 1,100 to 2,800 gallons per minute. Comparable yields can probably be obtained from the Madison in Johnson County in those areas where the limestone is fractured or cavernous. The Tensleep Sandstone reportedly yields 600 gallons per minute to a pumped irrigation well near its outcrop in the southwestern part of the project area. Several flowing wells tap the formation on the west flank of the Bighorn Mountains. The Madison Limestone and the Tensleep Sandstone have limited potential as sources of water because they can be developed economically only in a narrow band paralleling the Bighorn Mountain front in the southwestern part of the project area. Overlying the Tensleep Sandstone is about 6,000 feet of shale, siltstone, and fine-grained sandstone that, with a few exceptions, normally yields only small quantities of water to wells. The Cloverly Formation and the Newcastle Sandstone may yield moderate quantities of water to wells; but, in some areas, properly constructed wells tapping both formations might yield large quantities of water. The Shannon Sandstone Member of the Cody Shale will probably yield only small quantities of water to Wells, but it is the best potential source of ground water in the stratigraphic interval between the Newcastle and Parkman Sandstones. The Parkman Sandstone and the Lance Formation yield water to relatively shallow wells principally in the southwestern part of the project area. The Fort Union Formation yields adequate supplies of water for stock and domestic use from relatively shallow wells near its outcrop almost everywhere in the county. A few deep wells tap the Fort Union along the Powder River valley in the northeastern part of Johnson County. Some of these wells flow, but their flows rarely exceed 10 gallons per minute; larger yields could be undoubtedly be obtained by pumping. The Wasatch Formation is the principal source of ground water in Johnson County. It yields adequate supplies to many relatively shallow stock and domestic wells, some of which flow, but much larger yields probably would require pumping lifts that are prohibitive for most purposes. The Kingsbury Conglomerate and Moncrief Members of the Wasatch Formation, though, may yield moderate quantities of water in some places. Alluvial deposits underlying the valleys of the Powder River and Crazy Woman, Clear, and Piney Creeks are potential sources of moderate to large supplies of water in the Powder River drainage basin. The permeability of these deposits decreases with distance from the Bighorn Mountain front, so that largest yields can probably be obtained along the upper reaches of these streams. Most ground water utilized in the project area is for domestic and stock supplies and is obtained from drilled wells and from springs. Water for irrigation is obtained almost entirely by diverting flows of perennial streams. The discharge of wel

Water Supply Paper↗

Ground-water resources of Sheridan County, Wyoming

Sheridan County is in the north-central part of Wyoming and is an area of about 2,500 square miles. The western part of the county is in the Bighorn Mountains, and the eastern part is in the Powder River structural basin. Principal streams are the Powder and Tongue Rivers, which are part of the Yellowstone River system. The climate is semiarid, and the mean annual precipitation at Sheridan is about 16 inches. Rocks of Precambrian age are exposed in the central part of the Bighorn Mountains, and successively younger rocks are exposed eastward. Rocks of Tertiary age, which are the most widespread, are exposed throughout a large part of the Powder River structural basin. Deposits of Quaternary age underlie the flood plains and terraces along the larger streams, particularly in the western part of the basin. Aquifers of pre-Tertiary age are exposed in the western part of the county, but they dip steeply and are deeply buried just a few miles east of their outcrop. Aquifers that might yield large supplies of water include the Bighorn Dolomite, Madison Limestone, Amsden Formation, and Tensleep Sandstone. The Flathead Sandstone, Sundance Formation, Morrison Formation, Cloverly Formation,. Newcastle Sandstone, Frontier Formation, Parkman Sandstone, Bearpaw Shale, .and Lance Formation may yield small or, under favorable conditions, moderate supplies of water. Few wells tap aquifers of pre-Tertiary age, and these are restricted to the outcrop area. The meager data available indicate that the water from the Lance Formation, Bearpaw Shale, Parkman Sandstone, Tensleep Sandstone and Amsden Formation, and Flathead Standstone is of suitable quality for domestic or stock purposes, and that water from the Tensleep Sandstone and Amsden Formation and the Flathead Sandstone is of good quality for irrigation. Samples could not be obtained from other aquifers of pre-Tertiary age; so the quality of water in these aquifers could not be determined. Adequate supplies of ground water for stock or domestic use can be developed throughout much of the report area from the Fort Union and Wasatch Formations of Tertiary age; larger supplies might be obtained from the coarse-grained sandstone facies of the Wasatch Formation near Moncreiffe Ridge. Four aquifer tests were made at wells tapping formations of Tertiary age, and the coefficients of permeability determined ranged from 2.5 to 7.9 gallons per day per square foot. The depths to which wells must be drilled to penetrate an aquifer differ within relatively short distances because of the lenticularity of the aquifers. Water in aquifers of Tertiary age may occur under water-table, artesian, or a combination of artesian and gas-lift conditions. Water from the Fort Union is usable for domestic purposes, but the iron and dissolved-solids content impair the quality at some localities. Water from the Fort Union Formation is not recommended for irrigation because of sodium and bicarbonate content. The water is regarded as good to fair for stock use. Water from the Wasatch Formation generally contains dissolved solids in excess of the suggested domestic standards, but this water is usable in the absence of other supplies. The development of irrigation supplies from the Wasatch Formation may be possible in some areas, but the water quality should be carefully checked. Water of good to very poor quality for stock supplies is obtained, depending upon the location. Hydrogen sulfide, commonly present in water of the Fort Union and Wasatch Formations, becomes an objectionable characteristic when the water is used for human consumption. Deposits of Quaternary age generally yield small to moderate supplies of water to wells. Two pumping tests were conducted, and the coefficients of permeability of the aquifers tested were 380 and 1,100 gallons per day per square foot. Usable supplies of ground water can be developed from the deposits of Quaternary age, principally along the valleys of perennial strea

Water Supply Paper↗

Geology and ground water of the Savannah River Plant and vicinity, South Carolina

The area described in this report covers approximately 2,600 square miles in west-central South Carolina and includes the site of the Savannah River Plant, a major production facility of the U.S. Atomic Energy Commission. The climate, surface drainage, and land forms of the study area are typical of the southern part of the Atlantic Coastal Plain. Precipitation is normally abundant and fairly evenly distributed throughout the year, and the mean annual temperature is moderately warm (64?F). The major streams that drain the area (the Savannah, Salkehatchie, and Edisto Rivers) have low gradients and flow in a southeasterly direction toward the Atlantic Ocean. Surface features of the area include narrow, flat-bottomed, steep-sided valleys and broad gently rolling interfluvial areas. Those parts of the Coastal Plain included within the report area can be subdivided into the Aiken Plateau, the Congaree Sandhills, and the Coastal Terraces. The area is underlain by a sequence of unconsolidated and partly consolidated sediments of Late Cretaceous, Tertiary, and Quaternary age. The unconsolidated sediments were deposited unconformably on a basement of igneous and metamorphic rocks of Precambrian and Paleozoic age and sedimentary rocks of Triassic age. The basement rocks are similar to the granite-diorite complex of the Charlotte Belt, the metamorphosed rocks of the Carolina Slate Belt, and the consolidated sediments of the Newark Group. The unconsolidated sediments strike about N. 60 ? E. and dip 6-20 feet per mile to the southeast. They form a wedge-shaped mass that increases in thickness toward the southeast to slightly more than 1,200 feet in the vicinity of Allendale, S.C., on the southeast or downdip side of the study area. The oldest or lowermost unconsolidated sedimentary unit, the Tuscaloosa Formation of Late Cretaceous age, is overlain in the subsurface by beds that are also probably Late Cretaceous in age and that herein are named the Ellenton Formation. The Upper Cretaceous deposits are, in turn, overlain by the, McBean Formation and the Congaree(?) Formation of middle Eocene age, the Barnwell Formation of late Eocene age, the Hawthorn Formation of early and middle Miocene age, and by fluvial and marine(?) terrace deposits of Pliocene(?), Pleistocene, and Recent age. In the mapped area, the Congaree(?) Formation includes undifferentiated rocks (mostly Congaree and Barnwell Formations and some Mcbean outliers). (See map explanation.) Structurally, the Upper Cretaceous sediments are overlapped to the northwest by Tertiary deposits. A preliminary geologic map of the general area is included in the report. The principal aquifer in the area is composed of the beds of medium to coarse sand and gravel contained in the Tuscaloosa and Ellenton Formations. Subordinate aquifers include deposits of sand and limestone of Tertiary and Quaternary age. The ground water in the principal aquifer occurs under water-table conditions in the outcrop area of the Tuscaloosa Formation in the northern and western parts of the study area, but it is under artesian pressure downdip in the southern and eastern parts of the study area. Contours drawn on the piezometric surface of the water in the principal aquifer indicate that water is recharged to the aquifer mainly by leakage through the overlying Tertiary formations. Likewise, the piezometric contours show that the outcrop area of the Tuscaloosa Formation functions chiefly as an area of discharge. Doubtless, water is also discharged from the aquifer by moving downdip to areas near the coast where the prevailing hydraulic gradient may favor the upward leakage of water through the upper confining beds. The hydraulic properties of the principal aquifer were determined by a series of pumping tests. The results indicate that the aquifer is highly productive and could supply 15 million gallons per day in the vicinity of the Savannah River Plant without exceeding the available drawdown.

South Carolina↗

Ground-water resources of Natrona County, Wyoming

Natrona County covers an area of 5.369 square miles in central Wyoming. The climate is arid except in the mountainous areas. The county includes parts of the Great Plains, Middle Rocky Mountains, Wyoming Basin, and Southern Rocky Mountains physiographic provinces. There is wide variation of topography. More than 30 geologic formations are exposed in the county, 28 of which are known to yield water to wells and springs. The formations range in age from Precambrian to Holocene. Ground water in approximately 40 percent of the county contains more than 1.000 mg/l (milligrams per liter) of dissolved solids. Water chemically suitable for livestock can be developed at depths of less than 1,000 feet throughout most of the area. Many of the geologic formations were deposited under similar conditions and have similar water-bearing properties; also. water from these rocks deposited under similar conditions tends to have similar chemical characteristics. For this report, the stratigraphic section has been arbitrarily divided into six rock units based on similarity of deposition. The igneous and metamorphic rock unit includes rocks of Precambrian age and igneous intrusives and extrusives of Tertiary age. These rocks probably would not yield more than about 5 gpm (gallons per minute) to wells. The water is usually calcium bicarbonate type and contains less than 500 mg/l of dissolved solids. The marine rock unit includes formations of Cambrian, Mississippian, and Pennsylvanian and Permian age, having a maximum total thickness of about 1,900 feet. The Madison Limestone of Mississippian age and the Tensleep Sandstone and the Casper Formation of Pennsylvanian and Permian age supply the largest yields to wells and springs in the county. In the northeastern part of the county, flow from each of three wells in the Madison reportedly is more than 4.000 gpm. Each of three wells in the Tensleep in the same area flows more than 400 gpm. Yields of springs in the Casper Formation near Casper Mountain range from about 1.0 to 17 cubic feet per second. Ground water from near the outcrop of all these formations usually contains less than 500 rag/l of dissolved solids. The dissolved-solids content increases with distance from the outcrop and in places is more than 3.200 mg/l. Several types of water were found in this unit including sodium sulfate, calcium sodium sulfate, calcium sulfate, sodium calcium sulfate, sodium chloride, and calcium bicarbonate.

Water Supply Paper↗

Water in carbonate rocks of the Madison Group in southeastern Montana: A preliminary evaluation

The Madison Group of Mississippian age comprises, from oldest to youngest, the Lodgepole and Mission Canyon Limestones and the Charles Formation. The Madison crops out in the Bighorn and Pryor Mountains and in the mountains west of the study area. These rocks consist of cyclically deposited normal-marine carbonates and restricted-marine carbonates and evaporites. The Madison ranges in thickness from about 700 feet (210 metres) in the Bighorn Mountains to about 2,000 feet (610 metres) in the Williston basin. The top of the Madison ranges in depth from land surface in the mountains to about 10,000 feet (3,000 metres) below land surface along the MontanaWyoming border. The potentiometric surface of water in the Madison Group slopes northeastward from the outcrops. Potentiometric lows occur in the Cat Creek anticline-Porcupine dome area along the Bighorn River and at the north end of Powder River basin. Potentiometric highs occur in outcrop areas, on the interstream divide between the Bighorn, Tongue, and Yellowstone Rivers, and along the Cedar Creek anticline. The potentiometric surface ranges from 1,200 feet (370 metres) below land surface in the topographically high areas in the southern part of the area to 1,000 feet (300 metres) above land surface along the Yellowstone River. Yields from wells range from about 50 gallons per minute (3 litres per second) at several places to a reported 1,400 gallons per minute (88 litres per second) from a flowing well on the north side of the Porcupine dome. Yields estimated or reported from drill-stem tests range from about 1 to 157 gallons per minute {0.1 to 9.9 litres per second). Water from the Madison generally contains less than 3,000 milligrams per litre dissolved solids south of T. 1 N., and from 3,000 to 10,000 milligrams per litre in most of the remaining area; in the Williston basin the concentration increases to more than 100,000 milligrams per litre. In the southeastern and southwestern parts of the area, calcium, magnesium, and sulfate ions constitute more than 75 percent of the dissolved constituents, in milliequivalents per litre. North of about T. 8 N., sodium, potassium, and chloride ions constitute more than 50 percent of the dissolved constituents; in the Williston basin, sodium, potassium, and chloride ions constitute more than 75 percent of the total.

Montana↗

Water resources of the Edwards limestone in the San Antonio area, Texas

The water discharged from the large springs of San Antonio and most of the deep wells of the San Antonio area comes from a common reservoir in fissures and solution channels in the Edwards limestone. The water enters the limestone in a zone of outcrop along the Balcones escarpment, which crosses the northern parts of Bexar and Medina Counties and extends a long distance both to the east and west of these counties. It is estimated that the combined annual losses into the limestone from the Medina, Prio, Dry Prio, Nueces, and Sabinal Rivers and Hondo Creek may average as much as 150,000 acre-feet a year, the equivalent of a continuous flow of about 134,000,000 gallons a day. Smaller streams also contribute to the underground reservoir, and additional recharge is provided from rainfall on the outcrop of the limestone by direct penetration and by seepage from innumerable storm-water channels.

Water Supply Paper↗

Ground-water resources of Kleberg County, Texas

Abundant supplies of fresh water are obtained from deep artesian wells In all parts of Kleberg County. The water is derived from a stratum of sand, 10 to 150 feet thick, which usually has been referred to the Goliad sand but possibly may be at the base of the LIssie formation. The top of the sand Is reached at depths of around 400 feet In the western part of the county, 600 to 700 feet In the locality of Klngsville, and 1,250 to 1,450 feet In the eastern part of the county. Small supplies of fairly good water are obtained from shallow wells In very sandy areas in the eastern and southern parts of the county, but with this exception, so far as known, no good water has been obtained In the county either above or below the artesian fresh-water horizon. The fresh artesian water Is supplied by percolation from the outcrop of the water-bearing sands, which is many miles to the west In Jim Wells, Brooks, and Duval Counties. The estimated average replenishment from the outcrop to the wells of Kleberg County is 3,000,000 gallons a day. Available Information regarding most of the wells of the county Is given in the table of well records. Of the 43V wells listed 34 are not In use, and the water supplies from the others are used as follows: , Entirely for stock, 151; domestic use and stock, 241; public supply, 3; Industrial supply, 2; Irrigation, 4; railroad supply, 1; unrecorded, 1. About 80 are flowing wells In the southern and eastern parts of the county. It is concluded that the total withdrawal from those wells averages about 4,000,000 gallons a day. Some water is wasted, but the amount is not very great. There has been a general decline In the artesian head throughout the county. The largest decline has been in the western part of the county and In the vicinity of Klngsville, where the water level is now 15 to 45 feet below the surface in wells that once had a strong flow. Wells continue to flow in the southern and eastern parts of the county, but under less head than formerly. There was a small net loss in head in most parts of the county between the winters of 1932-33 and 1934-35, indicating that the decline is slowly continuing. Originally the artesian pressure In the fresh-water sands was much higher than the pressure In the overlying saltwater sands, but this relation has been reversed in the western part of the county and In the district around Klngsville, as a result of the decline in artesian head. Water obtained from the fresh-water horizon is comparatively fresh in the western and central parts of the county but contains a somewhat higher proportion of chlorides toward the Gulf. Samples obtained from about 100 wells, located for the most part in the central part of the county, showed a. higher chloride content than is normal for the freshwater beds in the area. These wells are believed in large part to be defective and to be admitting salt water. This was demonstrated and the leaks located in several wells that were tested. No evidence was found of salt-water contamination by percolation through the formations, however. The leaky wells should be repaired, If practicable, or sealed to prevent them from contaminating the fresh-water sand. The chances of leaks developing can be largely eliminated If the wells are properly drilled and provided with casing of good grade, and the casing is adequately seated.

Water Supply Paper↗

The Yorktown Formation: Improved stratigraphy, chronology and paleoclimate interpretations from the U.S. mid-Atlantic Coastal Plain

The Yorktown Formation records paleoclimate conditions along the mid-Atlantic Coastal Plain during the mid-Piacenzian Warm Period (3.264 to 3.025 Ma), a climate interval of the Pliocene in some ways analogous to near future climate projections. To gain insight into potential near future changes, we investigated Yorktown Formation outcrops and cores in southeastern Virginia, refining the stratigraphic framework. We analyzed 485 samples for alkenone-based sea surface temperature (SST) and productivity estimates from the Holland and Dory cores, an outcrop at Morgarts Beach, Virginia, and the lectostratotype of the Yorktown Formation at Rushmere, Virginia, and analyzed planktonic foraminferal assemblage data from the type section. Using the structure of the SST record, we improved the chronology of the Yorktown Formation by establishing the maximum age ranges of the Rushmere (3.3–3.2 Ma) and Morgarts Beach (3.2–3.15 Ma) Members. SST values for these members average ~26 °C, corroborating existing sclerochronological data. Increasing planktonic foraminifer abundance, productivity, and species diversity parallel increasing SST over the MIS M2/M1 transition. These records constitute the greatest temporal concentration of paleoecological estimates within the Yorktown Formation, aiding our understanding of western North Atlantic temperature patterns, seasonality and ocean circulation during this interval. We provide a chronologic framework for future studies analyzing ecological responses to profound climate change.

Virginia↗