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At least 577 records · Page 32Linked to original sources

Hydrogeologic framework and simulation of predevelopment groundwater flow, eastern Abu Dhabi Emirate, United Arab Emirates

Groundwater in eastern Abu Dhabi in the United Arab Emirates is an important resource that is widely used for irrigation and domestic supplies in rural areas. The U.S. Geological Survey and the Environment Agency—Abu Dhabi cooperated on an investigation to integrate existing hydrogeologic information and to answer questions about regional groundwater resources in Abu Dhabi by developing a numerical groundwater flow model based on MODFLOW–2005 software. The groundwater flow model developed in this investigation provides an improved understanding of groundwater conditions in the eastern region of the Emirate of Abu Dhabi. The flow model simulates steady-state predevelopment conditions from before the rapid growth of modern pumping in the 1980s and was calibrated with 1,342 groundwater-level observations by use of automated and manual calibration techniques. The calibrated model provides good accuracy, with a mean error of 0.50 meters and a standard error of 5.92 meters for simulated groundwater levels. The results of the regional water budget simulation show that gap recharge, which is groundwater inflow through mountain-front gap alluvium, is the greatest source of water to the aquifer. In the base simulation scenario, gap recharge represents 80 percent of total inflow (119,470 of 149,403 cubic meters per day) and the greatest outflow from the aquifer is from evapotranspiration (93 percent of total outflow). Model scenario and sensitivity results reveal a need for data that more thoroughly and more accurately describe aquifer hydraulic conductivity, inflow to the aquifer from the Oman Mountains, and recharge from precipitation on the piedmont. Additional long-term aquifer pumping test observations would improve understanding of aquifer hydraulic conductivity, which would also improve model accuracy. Future studies can modify the model to understand the effect of land-use change and water use on groundwater supplies and simulate more complex groundwater flow conditions in a predictive mode.

Scientific Investigations Report↗

Groundwater quality in relation to drinking water health standards and hydrogeologic and geochemical characteristics for 47 domestic wells in Potter County, Pennsylvania, 2017

As part of a regional effort to characterize groundwater in rural areas of Pennsylvania, water samples from 47 domestic wells in Potter County were collected from May through September 2017. The sampled wells had depths ranging from 33 to 600 feet in sandstone, shale, or siltstone aquifers. Groundwater samples were analyzed for physicochemical properties that could be evaluated in relation to drinking-water health standards, geology, land use, and other environmental factors. Laboratory analyses included concentrations of major ions, nutrients, bacteria, trace elements, volatile organic compounds (VOCs), ethylene and propylene glycol, alcohols, gross-alpha/beta-particle activity, uranium, radon-222, and dissolved gases. A subset of samples was analyzed for radium isotopes (radium-226 and -228) and for the isotopic composition of methane. Results of this 2017 study show that groundwater quality generally met most drinking-water standards that apply to public water supplies. However, a percentage of samples exceeded maximum contaminant levels (MCLs) for total coliform bacteria (69.6 percent), Escherichia coli (30.4 percent), arsenic, and barium; and secondary maximum contaminant levels (SMCLs) for field pH, manganese, sodium, iron, total dissolved solids, aluminum, and chloride. All of the analyzed VOCs were below limits of detection and associated drinking water criteria. Radon-222 activities exceeded the proposed drinking-water standard of 300 picocuries per liter in 80.9 percent of the samples. The field pH of the groundwater ranged from 4.6 to 9.0. Generally, the lower pH samples had greater potential for elevated concentrations of dissolved metals, including beryllium, copper, lead, nickel, and zinc, whereas the higher pH samples had greater potential for elevated concentrations of total dissolved solids, sodium, fluoride, boron, and uranium. Near-neutral samples (pH 6.5 to 7.5) had greater hardness and alkalinity concentrations than other samples with pH values outside this range. Calcium/bicarbonate waters were the predominant hydrochemical type for the sampled aquifers, with mixed water types for many samples, including variable contributions from calcium, magnesium, and sodium combined with bicarbonate, sulfate, chloride, and nitrate. Water from 45 wells had concentrations of methane greater than the 0.0002 milligrams per liter (mg/L) detection limit. One sample had the maximum value of 11 mg/L, which exceeds the Pennsylvania action level of 7 mg/L. Additionally, three other samples had concentrations of methane greater than 4 mg/L. Outgassing of such levels of methane from the water to air within a confined space can result in a potential hazard. The elevated concentrations of methane generally were associated with suboxic groundwater (dissolved oxygen less than 0.5 mg/L) that had near-neutral to alkaline pH with relatively elevated concentrations of iron, manganese, ammonia, lithium, fluoride, and boron. Other constituents, including barium, sodium, chloride, and bromide, commonly were elevated, but not limited to, those well-water samples with elevated methane. Low levels of ethane (as much as 1.2 mg/L) were present in eight samples with the highest methane concentrations. Five samples were analyzed for methane isotopes. The isotopic and hydrocarbon compositions in these five samples suggest the methane may be of microbial origin or a mixture of thermogenic and microbial gas, but differed from the compositions reported for mud-gas logging samples collected during drilling of gas wells. The concentrations of sodium (median 8.2 mg/L), chloride (median 7.64 mg/L), and bromide (median 0.02 mg/L) for the 47 groundwater samples collected for this study ranged widely and were positively correlated with one another and with specific conductance and associated measures of ionic strength. Sixty percent of the Potter County well-water samples had chloride concentrations less than 10 mg/L. Samples with higher chloride concentrations had variable bromide concentrations and corresponding chloride/bromide ratios that are consistent with sources such as road-deicing salt and septic effluent (low bromide) or brine (high bromide). Brines are naturally present in deeper parts of the regional groundwater system and, in some cases, may be mobilized by gas drilling. It is also possible that valley wells were drilled close to or into the brine-freshwater interface, so brine signatures do not necessarily indicate contamination due to drilling. The chloride, bromide, and other constituents in road-deicing salt or brine solutions tend to be diluted by mixing with fresh groundwater in shallow aquifers used for water supply. Although 1 of 8 groundwater samples with the highest methane concentrations (greater than 0.2 mg/L) had concentrations of chloride and bromide with corresponding chloride/bromide ratios that indicated mixing with road-deicing salt, the other 7 of 8 samples with elevated methane had concentrations of chloride and bromide with corresponding chloride/bromide ratios that indicated mixing with a small amount of brine (0.02 percent or less) similar in composition to those reported for gas and oil well brines in Pennsylvania. In several eastern Pennsylvania counties where gas drilling is absent, groundwater with comparable chloride/bromide ratios and chloride concentrations have been reported. Approximately 50 percent of Potter County well-water samples, including two samples with the fourth (72.9 mg/L) and fifth (47.0 mg/L) highest chloride concentrations, have chloride/bromide ratios that indicate predominantly anthropogenic sources of chloride, such as road-deicing salt or septic effluent.

Pennsylvania↗

Groundwater age and susceptibility of south Atlantic and Gulf Coast principal aquifers of the contiguous United States

Groundwater susceptibility to contamination was investigated by using environmental tracer-based groundwater age metrics in the south Atlantic and Gulf Coast principal aquifer systems of the Southeastern Coastal Plain, Mississippi embayment–Texas coastal uplands, and the Coastal Lowlands. Samples of dissolved gas, tritium, sulfur hexafluoride, tritiogenic helium, and carbon-14 were collected from 231 public supply wells in the 3 principal aquifer systems. Dissolved gas models were used to characterize recharge conditions and they identified recharge mechanisms that ranged from rapid, but short-lived, water table rises (possibly associated with large scale flooding), to slower diffuse recharge not associated with large water table fluctuations. Dissolved gas and geochemical correction models were used to calculate and (or) correct tracer concentrations before input to lumped parameter models of groundwater age. Lumped parameter models that were fit to tracer concentrations indicated groundwater was relatively old across the aquifer systems, with an estimated mean age of about 30,000 years. Estimates of groundwater age were related to hydrogeology, with increasing groundwater ages associated with greater depth, confinement, and distance from the recharge zone. Young groundwater with mean ages less than 2,000 years generally was in unconfined parts of the aquifer system, except for local areas of heavy groundwater extraction from unconfined aquifer units where estimated mean ages were up to 15,000 years. Lumped parameter model optimized age distributions describe the relative contribution of differing flow paths to the mean age, and a composite distribution of all samples from the three aquifer systems indicated that about 15 percent of the total sampled water had an age of less than 100 years. Various metrics of susceptibility, to land surface and geogenic contamination sources, derived from the age distributions, indicated geogenic sources as the primary threat to groundwater quality in the aquifer systems. Values of the susceptibility index (unitless) and fraction of recharge since 2,000 and 15,000 years before present are provided for assessment of individual well susceptibility. The data and interpretation methods presented here provide an additional means of investigating the susceptibility and sustainability of groundwater resources of the Southeastern Coastal Plain, Mississippi embayment–Texas coastal uplands, and the Coastal Lowlands aquifer systems.

Scientific Investigations Report↗

Assessing potential groundwater-level declines from future withdrawals in the Hualapai Valley, northwestern Arizona

A numerical groundwater flow model of the Hualapai Valley Basin in northwestern Arizona was developed to assist water-resource managers in understanding the potential effects of projected groundwater withdrawals on groundwater levels in the basin. The Hualapai Valley Hydrologic Model (HVHM) simulates the hydrologic system for the years 1935 through 2219, including future withdrawal scenarios that simulate large-scale agricultural expansion with and without enhanced groundwater recharge from potential new infiltration basin projects. HVHM is a highly parameterized model (75,586 adjustable parameters) capable of simulating grid-scale variability in aquifer properties (for example, conductivity, specific yield, and specific storage) and system stresses (for instance, natural recharge and groundwater withdrawals). Parameter estimation and uncertainty quantification were performed using an iterative ensemble smoother software (PESTPP-IES) to produce an ensemble of models fit to historical data. Results via the future withdrawal scenario from this ensemble indicate that mean groundwater level will decline at wells in the Kingman subbasin 87 to 128 feet by the year 2050 and 204 to 241 feet by the year 2080. Mean groundwater level is expected to decline at wells in the Hualapai subbasin between 44 and 210 feet by 2050 and between 107 and 350 feet by 2080. The enhanced recharge scenario results show potential for these declines to be partially mitigated in the Kingman subbasin by between 8 and 23 feet in 2050 and between 23 and 43 feet in 2080. The enhanced recharge scenario has no simulated effect on groundwater levels in the Hualapai subbasin. All planned enhanced infiltration projects are located in the Kingman subbasin, which is simulated to become hydraulically disconnected from the Hualapai subbasin owing to groundwater-level declines before 2050. Mean depth to water in the Kingman subbasin as simulated in the future withdrawal scenario will exceed 1,200 feet between the years 2155 and 2214 (median year 2171). In the future withdrawal plus enhanced recharge scenario, mean depth to water in the Kingman subbasin exceeds 1,200 feet between the years 2163 and 2207 (median year 2180), except for one model realization in which the subbasin does not reach an mean depth to water of 1,200 feet by the end of forecast simulation (year 2220). Simulated dewatering of the basin margins reduces scenario pumping rates by as much as 7 percent in 2029 and 12 percent in 2079 below specified rates. Forecasts of groundwater-level declines are based on the reduced simulated pumping rates.

Arizona↗

Status and understanding of groundwater quality in the Redding–Red Bluff shallow aquifer study unit, 2019—California GAMA priority basin project

Groundwater quality in the north Sacramento Valley (NSV) was studied in the Redding–Red Bluff shallow aquifer study unit (referred to as the NSV shallow aquifer or NSV-SA) as part of the Priority Basin Project (PBP) of the California Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is in Shasta and Tehama Counties and included two physiographic study areas: (1) the Redding area to the north and (2) the Red Bluff area to the south. The study was focused on groundwater resources used for domestic drinking-water supply, which are mostly drawn from shallower parts of aquifer systems than those of groundwater resources used for public drinking-water supply in the same area. This assessment characterized the quality of ambient groundwater in the aquifer before filtration or treatment, rather than the quality of drinking water delivered to the tap. The water-quality evaluation in this study has three components: (1) a status assessment, which characterized the quality of the groundwater resources used for domestic supply for 2018–19, in reference to state and national benchmarks; (2) an understanding assessment, which evaluated the natural and human factors potentially affecting water quality in those resources; and (3) a comparison between the groundwater resources used for domestic supply and those used for public supply in the region. The status assessment was based on data collected from 50 sites sampled by the U.S. Geological Survey for the GAMA-PBP in 2018–19. To provide context for the measured concentrations of groundwater constituents compared to U.S. Environmental Protection Agency and California State Water Resources Control Board Division of Drinking Water regulatory and non-regulatory benchmarks for drinking-water quality, relative concentrations (RCs) of groundwater constituents were calculated as the concentration in a sample divided by the respective benchmark. Health-based benchmarks include regulatory and non-regulatory human-health benchmarks such as a maximum contaminant level, notification level, or health-based screening level. Aesthetic-based benchmarks are regulatory or non-regulatory non-health-based benchmarks that can affect the color or taste of water. A grid-based method was used to estimate the proportions of the groundwater resources used for domestic drinking wells that have water-quality constituents below (low), approaching (moderate, greater than half the benchmark), or above (high) benchmark concentrations. This method provides statistically unbiased results at the study-area scale and permits comparisons to other GAMA-PBP study areas.

California↗

Comparing domestic and public-supply groundwater quality in the northern San Joaquin Valley, 2019—California GAMA Priority Basin Project

Groundwater quality in the Northern San Joaquin Valley region of California was studied as part of California State Water Resources Control Board (SWRCB) Groundwater Ambient Monitoring and Assessment Program-Priority Basin Project (GAMA-PBP). The GAMA-PBP made a spatially unbiased assessment of the aquifer system used for domestic drinking-water supply in the study region and compared the results to the aquifer system used for public drinking-water supply. These assessments characterized the quality of raw groundwater to evaluate ambient conditions in regional aquifers and not the quality of treated drinking water. The study included two components: (1) a status assessment presenting study results summarizing the status of groundwater quality used for domestic supply in the Northern San Joaquin Valley and (2) a comparative assessment of groundwater resources used for domestic and public drinking-water supply in the study region. The status assessment was based on data collected by the GAMA-PBP from 45 sites in the Northern San Joaquin Valley domestic-supply aquifer assessment study unit during 2019. To contextualize water-quality results, concentrations of water-quality constituents in ambient groundwater were compared to regulatory and non-regulatory benchmarks used by the State of California and Federal agencies as health-based or aesthetic standards for public drinking water. A grid-based method to estimate aquifer-scale proportions of groundwater resources with concentrations approaching or exceeding benchmark thresholds was used in the status assessment. This method provides spatially unbiased results and allows inter-comparability with similar groundwater-quality assessments. A spatially weighted method was used to calculate aquifer-scale proportions for public-supply wells within the domestic assessment grid network using contemporaneous regulatory compliance monitoring data. Differences among aquifer-scale proportions for constituents exceeding regulatory and non-regulatory benchmarks in domestic- and public-supply aquifers were quantitatively evaluated. Factors influencing the vertical and lateral distribution of key contaminants of concern (nitrate, fumigants, and arsenic) across overlapping aquifer systems used for domestic and public drinking-water supply were also evaluated. Status assessment results indicated inorganic and organic constituents with health-based benchmarks were present at high relative concentrations (RCs), meaning they exceeded a benchmark threshold, in 20 and 9 percent of the domestic-supply aquifer system in the Northern San Joaquin Valley, respectively. Inorganic constituents with health-based benchmarks present at high RCs included nitrate and arsenic. The only organic constituents with health-based benchmarks present at high RCs were the fumigants 1,2-dibromo-3-chloropropane (DBCP) and 1,2,3-trichloropropane (1,2,3-TCP). Inorganic constituents with aesthetic-based benchmarks were present at high RCs in 13 percent of the domestic-supply aquifer system in the Northern San Joaquin Valley and included iron and manganese. Microbial indicators (total coliform bacteria and Enterococci) were present in 18 and 2 percent of the domestic-supply aquifer system in the Northern San Joaquin Valley, respectively. Comparative assessment results indicated inorganic and organic constituents with health-based benchmarks were present at high RCs in 13 and 6 percent of the public-supply aquifer system in the Northern San Joaquin Valley, respectively. Inorganic constituents with aesthetic-based benchmarks were present at high RCs in 22 percent of the public-supply aquifer system in the Northern San Joaquin Valley. There were no significant differences among high RC proportions for individual water-quality constituents, except for nitrate, which was greater in the domestic- compared to public-supply aquifer system in the Northern San Joaquin Valley. The most prevalent constituents with health-based benchmarks contributing to high RC proportions in the public-supply aquifer system were arsenic and fumigants, including DBCP and 1,2,3-TCP. Analysis of construction data for wells included in the comparative assessment indicated that, although depth to top of perforations are comparable for domestic and public-supply wells in the Northern San Joaquin Valley (median depth about 60 meters [m]), public-supply wells have longer perforation intervals and extend to deeper parts of the aquifer system than domestic wells that typically draw exclusively from the shallower aquifer system in the upper 80 m of unconsolidated sediments. Analysis of the vertical and lateral distribution of constituents of interest (nitrate, fumigants, and arsenic) across domestic- and public-supply aquifers indicated that nitrate is prevalent in shallow aquifers throughout the Northern San Joaquin Valley but is potentially diluted by mixing with deeper, older groundwater at long-screened public-supply wells. Fumigants were prevalent in areas of urban and agricultural land use in the western part of the Northern San Joaquin Valley, particularly in areas near Lodi, California, but 1,2,3-TCP was more widespread than DBCP and was detected in shallow and deeper parts of the aquifer system, potentially because of its recalcitrance in groundwater and ability to be detected at low concentrations. Arsenic was most prevalent in the western part of the Northern San Joaquin Valley with proximity to deltaic sediments and was detected at high RCs in wells tapping shallow and deep parts of the aquifer system.

California↗

Hydrogeology and simulated groundwater availability in reaches 3 and 4 of the Washita River aquifer, southern Oklahoma, 1980–2017

The 1973 Oklahoma Groundwater Law (Oklahoma Statutes §82–1020.5) requires that the Oklahoma Water Resources Board conduct hydrologic investigations of the State’s aquifers to determine the maximum annual yield for each groundwater basin. Because more than 20 years have elapsed since the final order was issued, the U.S. Geological Survey, in cooperation with the Oklahoma Water Resources Board, conducted an updated hydrologic investigation and evaluated the effects of potential groundwater withdrawals on groundwater flow and availability in reaches 3 and 4 of the Washita River aquifer in southern Oklahoma for a study period spanning 1980–2017. A hydrogeologic framework and conceptual model were developed to guide the construction and calibration of a numerical model of the Washita River aquifer. The numerical model was calibrated to water-table-altitude observations at selected wells, base-flow observations at selected U.S. Geological Survey streamgages, and the conceptual-model recharge. Three types of groundwater-availability scenarios were run using the calibrated numerical model. These scenarios were used to (1) estimate equal-proportionate-share pumping rates, (2) quantify the potential effects of projected well withdrawals on groundwater storage over a 50-year period, and (3) simulate the potential effects of a hypothetical 10-year drought. With Washita River main-stem inflows, the 20-, 40-, and 50-year equal-proportionate-share pumping rates under normal recharge conditions were about 3.08 acre-feet per acre per year for reach 3 and about 3.80 acre-feet per acre per year for reach 4. Projected 50-year pumping scenarios were used to simulate the effects of modified well withdrawal rates. Because well withdrawals were less than 1 percent of the calibrated numerical-model water budget, changes to the well pumping rates had little effect on Washita River base flows and groundwater storage in the Washita River aquifer. A hypothetical 10-year drought scenario was used to simulate the potential effects of a prolonged period of reduced recharge on groundwater storage. Groundwater storage at the end of the drought period was 4.6 percent less than the groundwater storage of the calibrated numerical model at the end of the drought period.

Oklahoma↗

Potentiometric surfaces (2013, 2015), groundwater quality (2010–15), and water-level changes (2011–13, 2013–15) in the Sparta-Memphis aquifer in Arkansas

The Sparta-Memphis aquifer, present across much of eastern Arkansas, is the second most used groundwater resource in the State, with the Mississippi River Valley alluvial aquifer being the primary groundwater resource. The U.S. Geological Survey, in cooperation with Arkansas Department of Agriculture-Natural Resources Division, Arkansas Geological Survey, Natural Resources Conservation Service, Union County Water Conservation Board, and the Union County Conservation District, collects groundwater data across the Sparta-Memphis aquifer extent in Arkansas. This report presents water-level data for measurements conducted during two time periods, January–May 2013 and January–June 2015, and discusses water-level altitude changes for the 2011–13 and 2013–15 periods in the Sparta-Memphis aquifer. Accompanying water-level data in this report include groundwater-quality data for the period 2010–15 in the Sparta-Memphis aquifer. Groundwater data can guide ongoing and future groundwater-monitoring efforts and inform management of the aquifers in Arkansas. Water levels measured at 306 wells from January to May 2013 and 273 wells from January to June 2015 are graphically presented as potentiometric-surface maps. Measurements from 2011, 2013, and 2015 were used in the construction of 2011–13 and 2013–15 water-level change maps. Select long-term hydrographs are included in the report to illustrate water-level changes at the local scale. Water-level data show the influence of climate, pumping, and conservation and management efforts on groundwater levels. With respect to climate, the study area experienced extreme drought conditions between January 2011 and December 2012. The proximate effects of drought—increased evapotranspiration, decreased recharge, and increased irrigation needs—resulted in water-level declines that were particularly notable in the northern and central portions of the study area. Groundwater sampled in 2010–15 from 148 wells completed in the Sparta-Memphis aquifer was analyzed for specific conductance, pH, chloride (Cl) concentration, and bromide (Br) concentration. In 2015, groundwater-quality data from 103 wells completed in the Sparta-Memphis aquifer had a median specific conductance of 356 microsiemens per centimeter at 25 degrees Celsius and a median Cl concentration of 9.5 milligrams per liter (mg/L). The data show two areas of higher Cl (greater than 10 mg/L) and higher Br (greater than 0.5 mg/L) concentrations in Union, Calhoun, and Bradley Counties in southern Arkansas and Monroe and Phillips Counties in eastern-central Arkansas. A Cl and Br mixing model indicates the two regions of wells may have different sources of higher salinity. In the greater Union County area, water in most wells may be a mixture of recharge or precipitation and higher salinity groundwater from the Nacatoch aquifer. Water in wells in eastern-central Arkansas may be sourced from aquifers having a higher Cl concentration (and thus, also a higher Cl-to-Br ratio).

Arkansas↗

Assessment of fresh groundwater discharge and saline surface-water intrusion at Operable Unit 2, North Chevalier Field Disposal Area (Site 11), Naval Air Station Pensacola, Florida, 2018–22

Site 11 is a former landfill at North Chevalier Field Disposal Area in Operable Unit 2 at Naval Air Station Pensacola, in northwest Florida. Site 11 is adjacent to Bayou Grande, a shallow, tidally influenced, saline estuary of the Pensacola Bay watershed. Federal and Florida regulators have expressed concern that contaminants detected in groundwater beneath the inland parts of Site 11 may discharge to Bayou Grande. In 2017, the Department of Defense, U.S. Navy, Naval Facilities Engineering Systems Command Southeast asked the U.S. Geological Survey to assess the occurrence of fresh groundwater discharge to Bayou Grande at Site 11 and to delineate to the extent practicable the location of groundwater discharge. Between 2018 and 2022, the U.S. Geological Survey used a multiple-lines-of-evidence approach that included a visual method and three physical methods based on the temperature difference between groundwater and surface water to assess groundwater discharge. One of the physically based methods also used the difference in specific conductance between fresh groundwater and brackish to saline surface water. Combined, the data indicate that fresh groundwater from across Site 11 discharges primarily along the shoreline of the northern and northeastern part of Site 11. The data also indicate that saline surface water from Bayou Grande intrudes tens of feet into the shallow aquifer beneath Site 11. The combined data indicate that the interface between fresh groundwater and saline surface water changes over space and time. Any new monitoring wells proposed for installation near the shoreline of Site 11 should include approaches to monitor the changes in the location of the freshwater/saltwater interface. Care would need to be taken to collect any groundwater samples at the correct season and tidal period to provide the highest probability of collecting a representative sample of Site 11 groundwater unaffected by saltwater.

Florida↗

Modeled groundwater and surface-water interactions surrounding Mobile Bay, Alabama, 2008–15

The U.S. Geological Survey, in cooperation with the Gulf Coast Ecosystem Restoration Council, has used MODFLOW 6 to develop a groundwater-flow model to simulate groundwater and surface-water interactions in the Mobile Bay, Alabama, area. The model results indicated that, on average, groundwater discharge near the coastline is equal to 2.5 percent of the surface water that flows into the bay. The model was also used to determine how changes in recharge, sea level, and groundwater pumping affect groundwater levels and discharge rates. The results indicate that more groundwater discharge occurred in the winter and spring when recharge was higher, sea level was lower, and groundwater pumping was lower than during the summer and fall. Additionally, the amount of emergent groundwater was closely related to sea level; when sea level was higher, there was more area with emergent groundwater. Furthermore, the depth of nonemergent groundwater was related to trends in recharge and pumping. During periods of increased recharge and reduced pumping, a significant portion of the model area exhibited a depth to the water table of less than 1 meter below the land surface. Conversely, during periods of decreased recharge and heightened pumping, much of the model area showed a depth to the water table ranging from 1 to 5 meters.

Alabama, Mississippi↗

Modeling the long-term fate of agricultural nitrate in groundwater in the San Joaquin Valley, California

Nitrate contamination of groundwater systems used for human water supplies is a major environmental problem in many parts of the world. Fertilizers containing a variety of reduced nitrogen compounds are commonly added to soils to increase agricultural yields. But the amount of nitrogen added during fertilization typically exceeds the amount of nitrogen taken up by crops. Oxidation of reduced nitrogen compounds present in residual fertilizers can produce substantial amounts of nitrate which can be transported to the underlying water table. Because nitrate concentrations exceeding 10 mg/L in drinking water can have a variety of deleterious effects for humans, agriculturally derived nitrate contamination of groundwater can be a serious public health issue. The Central Valley aquifer of California accounts for 13 percent of all the groundwater withdrawals in the United States. The Central Valley, which includes the San Joaquin Valley, is one of the most productive agricultural areas in the world and much of this groundwater is used for crop irrigation. However, rapid urbanization has led to increasing groundwater withdrawals for municipal public water supplies. That, in turn, has led to concern about how contaminants associated with agricultural practices will affect the chemical quality of groundwater in the San Joaquin Valley. Crop fertilization with various forms of nitrogen-containing compounds can greatly increase agricultural yields. However, leaching of nitrate from soils due to irrigation has led to substantial nitrate contamination of shallow groundwater. That shallow nitrate-contaminated groundwater has been moving deeper into the Central Valley aquifer since the 1960s. Denitrification can be an important process limiting the mobility of nitrate in groundwater systems. However, substantial denitrification requires adequate sources of electron donors in order to drive the process. In many cases, dissolved organic carbon (DOC) and particulate organic carbon (POC) are the primary electron donors driving active denitrification in groundwater. The purpose of this chapter is to use a numerical mass balance modeling approach to quantitatively compare sources of electron donors (DOC, POC) and electron acceptors (dissolved oxygen, nitrate, and ferric iron) in order to assess the potential for denitrification to attenuate nitrate migration in the Central Valley aquifer.

California↗

Geology, selected geophysics, and hydrogeology of the White River and parts of the Great Salt Lake Desert regional groundwater flow systems, Utah and Nevada

The east-central Great Basin near the Utah-Nevada border contains two great groundwater flow systems. The first, the White River regional groundwater flow system, consists of a string of hydraulically connected hydrographic basins in Nevada spanning about 270 miles from north to south. The northernmost basin is Long Valley and the southernmost basin is the Black Mountain area, a valley bordering the Colorado River. The general regional groundwater flow direction is north to south. The second flow system, the Great Salt Lake Desert regional groundwater flow system, consists of hydrographic basins that straddle the Utah-Nevada border, with a length of about 150 miles from north to south. The general regional groundwater flow direction is from south to north towards the Great Salt Lake Desert. For 15 years with support from the Southern Nevada Water Authority (SNWA), hydrologists, geologists, and geophysicists studied the basin connections and the groundwater resources in these and adjacent flow systems over an area of about 25,000 square miles. A major first part of the SNWA study was constructing a 3-dimensional digital hydrogeologic framework based on geologic maps and cross sections at 1:250,000 scale. This framework documents the presence of three major aquifers: (1) Paleozoic carbonate rocks, (2) Eocene to Miocene volcanic rocks, and (3) Miocene to Holocene basin-fill sediments, as well as confining units that constrain flow. We interpret that movement of most groundwater through and across basins is by fracture-dominated flow along faults/fractures, yet in most places flow is prevented or retarded across faults, so mapping structures gives a first approximation to conduits and barriers to flow. The most important structures by far are high-angle normal faults of the basin-range episode of east-west extensional deformation. This event began at about 20 Ma, although most deformation and the formation of the present topography took place between 10 Ma and present. This topography consists of north-trending basins (mostly grabens) that alternate with north- trending ranges (mostly horsts); erosion of the ranges filled the basins with clastic alluvial basin-fill deposits. Geophysics provides data on the third dimension (cross sections) of the hydrogeologic framework. Audiomagnetotelluric profiles and gravity inversion located faults and enabled us to estimate thicknesses of basin-fill deposits. To this framework, hydrologic studies addressed precipitation, surface water, and springs, as well as groundwater levels, volumes, geochemistry, water budgets, and monitoring. At nearly the same time as our study, the Utah Geological Survey (UGS) and U.S. Geological Survey (USGS) addressed the same issues in many of the same areas, and publication of the efforts by all three agencies reveals a surprising similarity of conclusions, with some critical exceptions, which therefore demonstrates the great value of many scientists independently studying the same complex scientific problem. The differences in conclusions include directions and volumes of some ground- water flow paths, such as one proposed by the USGS of unlikely groundwater flow from Steptoe Valley to southern Snake Valley, and another proposed by the UGS of unlikely significant groundwater recharge flow from the Snake Range to the Fish Springs complex.

Utah↗

Groundwater conditions in Utah, spring of 2010

This is the forty-seventh in a series of annual reports that describe groundwater conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality, provide data to enable interested parties to maintain awareness of changing groundwater conditions. This report, like the others in the series, contains information on well construction, groundwater withdrawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of groundwater. Supplementary data are included in reports of this series only for those years or areas which are important to a discussion of changing groundwater conditions and for which applicable data are available. This report includes individual discussions of selected significant areas of groundwater development in the State for calendar year 2009. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality. This report is also available online at http://www. waterrights.utah.gov/techinfo/ and http://ut.water.usgs.gov/ publications/GW2010.pdf. Groundwater conditions in Utah for calendar year 2008 are reported in Burden and others (2009) and available online at http://ut.water.usgs.gov/publications/ GW2009.pdf. Analytical results associated with water samples collected from each area of groundwater development were compared to State of Utah maximum contaminant levels (MCLs) and secondary drinking-water standards of routinely measureable substances present in water supplies. The MCLs and secondary drinking-water standards can be accessed online at http://www.rules.utah.gov/publicat/code/r309/r309-200. htm#T5. The U.S. Environmental Protection Agency (EPA) drinking-water standards can be accessed at http://www.epa. gov/safewater/mcl.html#mcls. Maximum contaminant levels and secondary drinking-water standards were developed for public water systems and do not apply to the majority of wells sampled during this study. Every 5 years, this report series includes maps depicting comparisons of 30-year changes in water levels for each of the major areas of groundwater development. The water-level change maps in this report show the difference between water levels measured in 1980 and in 2010. Water-level rises or declines occurring on shorter time scales are shown in plots of annual water-level measurements for several wells in each of the major areas of groundwater development.

Utah↗

Groundwater recharge in northern New England: Meteorological drivers and relations with low streamflow

Meteorological drivers of groundwater recharge for spring (February–June), fall (October–January), and recharge-year (October–June) recharge seasons were evaluated for northern New England and upstate New York from 1989 to 2018. Monthly groundwater recharge was computed at 21 observation wells by subtracting the water levels at the end of each month from the level of the previous month; only positive monthly values were used to compute seasonal recharge. Precipitation, temperature, sea-level pressure, 500-mb geopotential heights, and various teleconnection indices were tested as explanatory variables for the interannual variability of recharge using random forest machine learning models. Precipitation within recharge seasons was positively correlated with groundwater recharge for most wells in all seasons. In general, whilst groundwater recharge in the study area was generally highest during the months of March and April, October precipitation was an important month for explaining the interannual groundwater recharge variability. This is likely because the variability in recharge in October may be high or low for given years. Sea-level pressure and 500-mb heights were typically inversely correlated with groundwater recharge during the recharge-year and fall recharge seasons, as higher sea-level pressure and heights are usually associated with clearer skies and less precipitation. The North Atlantic Oscillation, Pacific-North American pattern, and Pacific Decadal Oscillation teleconnections affected groundwater recharge differently by well and season. The influence of groundwater recharge on minimum daily streamflows during the subsequent summer/fall was also analysed. Summer precipitation was the most important explanatory variable for study streams whilst groundwater recharge and summer air temperature were significant variables for a few streams.

Maine, New Hampshire, Vermont↗

Stable lead isotopes reveal a natural source of high lead concentrations to gasoline-contaminated groundwater

Concentrations of total lead as high as 1,600 μg/L were detected in gasoline-contaminated and uncontaminated groundwater at three gasoline-release sites in South Carolina. Total lead concentrations were highest in turbid groundwater samples from gasoline-contaminated and uncontaminated wells, whereas lower turbidity groundwater samples (collected using low-flow methods) had lower total lead concentrations. Dissolved lead concentrations in all wells sampled, however, were less than 15 μg total lead/L, the current United States Environmental Protection Agency (US EPA) maximum contaminant level (MCL). Because many total lead concentrations exceeded the MCL, the source of lead to the groundwater system at two of the three sites was investigated using a stable lead isotope ratio approach. Plots of the stable isotope ratios of lead (Pb) in groundwater as 207 Pb/ 206 Pb versus 208 Pb/ 206 Pb, and 208 Pb/ 204 Pb versus 206 Pb/ 204 Pb were similar to ratios characteristic of lead-based minerals in local rocks of the southeastern US, and were not similar to the stable lead isotopes ratios characteristic of distant lead ore deposits such as Broken Hill, Australia, used to produce tetraethyl lead in gasoline products prior to its phase-out and ban in the United States. Moreover, the isotopic composition of dissolved lead was equivalent to the isotopic composition of total lead in turbid samples collected from the same well, suggesting that the majority of the lead detected in the groundwater samples was associated with sediment particulates of indigenous aquifer material, rather than lead associated with spilled leaded gasoline. The results of this investigation indicate that (1) lead detected at some gasoline-release sites may be derived from the local aquifer material, rather than the gasoline release, and consequently may affect site-specific remediation goals; (2) non-low flow groundwater sampling methods, such as a disposable bailer, may result in turbid groundwater samples and high total lead concentrations, and; (3) stable lead isotopes can be used to clarify the source of lead detected above permissible levels in gasoline-contaminated groundwater systems.

Environmental Geology↗

Groundwater mining of bedrock aquifers in the Denver Basin - Past, present, and future

The Denver Basin bedrock aquifer system is an important source of water for municipal and agricultural uses in the Denver and Colorado Springs metropolitan areas. The Denver area is one of the fastest growing areas in the United States with a population of 1.2 million in 1960 that has increased to over 2.4 million by 2000. This rapid population growth has produced a corresponding increase in demand for potable water. Historically, the Denver area has relied on surface water, however, in the past 10 years new housing and recreation developments have begun to rely on groundwater from the bedrock aquifers as the surface water is fully appropriated and in short supply. The Denver Basin bedrock aquifer system consists of Tertiary and Cretaceous age sedimentary rocks known as the Dawson, Denver, Arapahoe and Laramie-Fox Hills Aquifers. The number of bedrock wells has increased from 12,000 in 1985 to 33,700 in 2001 and the withdrawal of groundwater has caused water level declines of 76 m. Water level declines for the past 10 years have ranged from 3 to 12 m per year. The groundwater supplies were once thought to last 100 years but there is concern that the groundwater supplies may be essentially depleted in 10 to 15 years in areas on the west side of the basin. Extensive development of the aquifer system has occurred in the last 25 years especially near the center of the basin in Douglas and El Paso Counties where rapid urban growth continues and surface water is lacking. Groundwater is being mined from the aquifer system because the discharge by wells exceeds the rate of recharge. Concern is mounting that increased groundwater withdrawal will cause water level declines, increased costs to withdraw groundwater, reduced well yield, and reduced groundwater storage. As the long-term sustainability of the groundwater resource is in doubt, water managers believe that the life of the Denver Basin aquifers can be extended with artificial recharge, water reuse, restrictions on lawn watering, well permit restrictions and conservation measures.

Environmental Geology↗

Critical evaluation of stable isotope mixing end-members for estimating groundwater recharge sources: Case study from the South Rim of the Grand Canyon, Arizona, USA

Springs and groundwater seeps along the South Rim of the Grand Canyon serve an important function for the region’s ecosystems, residents (both human and wild animal), and economy. However, these springs and seeps are potentially vulnerable to contamination, increased groundwater extraction, or reduced recharge due to climate change. Protection of South Rim groundwater resources requires improved understanding of the regional groundwater system. In this study, statistical methods are used to investigate δ2H and δ18O in precipitation, surface water, and groundwater. A mixing model for δ18O is developed using statistically distinct seasonal end-members represented by modeled winter (Nov-Apr.) precipitation and summer (May-Oct.) surface water run-off. The calculated fraction of winter recharge (Fwin) indicates that South Rim groundwater is primarily sourced from snow-melt and winter rains with an average Fwin of 0.97 ± 0.09. Groundwater sourced from the highest elevations of the study area are more depleted than the winter end-member suggesting values of Fwin are overestimated or a meaningful portion of recharge occurs at lower elevations. Lower elevation recharge from the Coconino Plateau is supported by consistent spatial trends in δ2H and δ18O with respect to longitude, Fwin values less than 0.9 for 9 of the 50 samples, and age tracer data indicating young groundwater discharging from springs which is distinct from old groundwater observed in the regional flow system. These results suggest a new conceptual model is needed to account for recharge sources from low elevation and summer precipitation. Results imply resource managers need to reconsider current land-use and water management practices on the South Rim to protect future water quantity and quality.

Arizona↗

Hydrochemical analysis of groundwater using multivariate statistical methods - The Volta region, Ghana

Q and R-mode multivariate statistical analyses were applied to groundwater chemical data from boreholes and wells in the northern section of the Volta region Ghana. The objective was to determine the processes that affect the hydrochemistry and the variation of these processes in space among the three main geological terrains: the Buem formation, Voltaian System and the Togo series that underlie the area. The analyses revealed three zones in the groundwater flow system: recharge, intermediate and discharge regions. All three zones are clearly different with respect to all the major chemical parameters, with concentrations increasing from the perceived recharge areas through the intermediate regions to the discharge areas. R-mode HCA and factor analysis (using varimax rotation and Kaiser Criterion) were then applied to determine the significant sources of variation in the hydrochemistry. This study finds that groundwater hydrochemistry in the area is controlled by the weathering of silicate and carbonate minerals, as well as the chemistry of infiltrating precipitation. This study finds that the ??D and ?? 18 O data from the area fall along the Global Meteoric Water Line (GMWL). An equation of regression derived for the relationship between ??D and ?? 18 O bears very close semblance to the equation which describes the GMWL. On the basis of this, groundwater in the study area is probably meteoric and fresh. The apparently low salinities and sodicities of the groundwater seem to support this interpretation. The suitability of groundwater for domestic and irrigation purposes is related to its source, which determines its constitution. A plot of the sodium adsorption ratio (SAR) and salinity (EC) data on a semilog axis, suggests that groundwater serves good irrigation quality in the area. Sixty percent (60%), 20% and 20% of the 67 data points used in this study fall within the medium salinity - low sodicity (C2-S1), low salinity -low sodicity (C1-S1) and high salinity - low sodicity (C3-S1) fields, which ascribe good irrigation quality to groundwater from this area. Salinities range from 28.1 to 1956 ??S/cm, whilst SAR values fall within the range 0-3. Extremely low sodicity waters of this kind, with salinities lower than 600 ??S/cm, have the tendency to affect the dispersive properties of irrigation soils when used for irrigation. About 50% of the groundwater in the study area fall within this category and need prior treatment before usage. ?? 2009 Korean Society of Civil Engineers and Springer-Verlag Berlin Heidelberg GmbH.

KSCE Journal of Civil Engineering↗