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Hydrologic response of groundwater and streamflow to natural and anthropogenic drivers of change in headwaters of the upper Colorado River basin during recent wet (1982–1999) and drought (2000–2022) conditions

Study region: Headwaters of the upper Colorado River basin (UCOL), USA Study focus: Surface-water and groundwater numerical models incorporating water-use information were used to investigate changes in climate, water use, and simulated hydrologic responses of snow processes, evapotranspiration, groundwater, and streamflow during recent wet (1982–1999) and drought (2000–2022) periods in the headwater subregions of the upper Colorado River basin. New hydrologic insights for the region: Decreases in average streamflow between wet and drought periods ranged from 20 % in the Colorado River headwaters subregion to 23 % in the Gunnison River headwaters subregion. Like streamflow, average surface runoff was statistically less during the drought than the wet period, with decreases from 24–31 % in the headwaters. On a volume basis, runoff decreases were greater than streamflow decreases in both the Colorado River and Gunnison River headwaters. Although the amount of water-year groundwater discharge to streams remained nearly the same between the wet and drought periods, groundwater as a percentage of streamflow increased between the wet and drought periods, highlighting the importance of groundwater in sustaining streamflow during drought conditions. Multiple linear regression analyses revealed that snowmelt-only models were better than the best precipitation and temperature models at explaining streamflow variability from all headwater subregions for both the wet and drought periods.

Arizona, Colorado, New Mexico, Utah, Wyoming

Toward a new framework to evaluate process-based model configurations and quantify data worth prior to calibration

Model criticism, discrimination, and selection methods often rely on calibrated model outputs. Because calibration can be computationally expensive, model criticism can first be undertaken by assessing model outputs obtained from limited prior parameter ensembles. However, such prior-based methods are often heuristic and do not formalize the notion of balancing model consistency with data and model complexity (i.e., model adequacy). We present a new framework to discriminate among candidate models prior to calibration that formalizes prior-to-calibration model adequacy into a metric to implicitly balance prior model output data coverage with model complexity represented by prior output (co)variance. The prior model adequacy metric “Mahalanobis distance deviation” quantifies the deviation of (a) the set of squared Mahalanobis distances of data from a prior model output distribution from (b) the set of squared Mahalanobis distances of data from their own distribution. A new data worth metric “discernment value” is also presented which quantifies the value of data for screening less-adequate models prior to calibration. Discernment value is calculated from the change in variance of a weighted average of prior model outputs from all candidate models due to less-adequate model outputs receiving lower weight. The framework is demonstrated using a one-dimensional groundwater flow model with eight possible configurations. A synthetic data network is used to test the framework. Results show the framework identifies the candidate models most similar to the true model used to create the synthetic data. Discernment values show variation in the value of different data types and locations for screening less-adequate models.

Water Resources Research

Concentrations and distribution of manmade organic compounds in the Lake Tahoe Basin, Nevada and California, 1997-99

The U.S. Geological Survey, in cooperation with the Tahoe Regional Planning Agency and the Lahontan Regional Water-Quality Control Board, sampled Lake Tahoe, major tributary streams to Lake Tahoe, and several other lakes in the Lake Tahoe Basin for manmade organic compounds during 1997-99. Gasoline components were found in all samples collected from Lake Tahoe during the summer boating season. Methyl tert -butyl ether (MTBE), benzene, toluene, ethylbenzene, and xylenes (BTEX) were the commonly detected compounds in these samples. Most samples from tributary streams and lakes with no motorized boating had no detectable concentrations of gasoline components. Motorized boating activity appears to be directly linked in space and time to the occurrence of these gasoline components. Other sources of gasoline components to Lake Tahoe, such as the atmosphere, surface runoff, and subsurface flow, are minor compared to the input by motorized boating. Water sampled from Lake Tahoe during mid-winter, when motorized boating activity is low, had no MTBE and only one sample had any detectable BTEX compounds. Soluble pesticides rarely were detected in water samples from the Lake Tahoe Basin. The only detectable concentrations of these compounds were in samples from Blackwood and Taylor Creeks collected during spring runoff. Concentrations found in these samples were low, in the 1 to 4 nanograms per liter range. Organochlorine compounds were detected in samples collected from semipermeable membrane devices (SPMD's) collected from Lake Tahoe, tributary streams, and Upper Angora Lake. In Lake Tahoe, SPMD samples collected offshore from urbanized areas contained the largest number and highest concentrations of organochlorine compounds. The most commonly detected organochlorine compounds were cis- and trans-chlordane, p , p' -DDE, and hexachlorobenzene. In tributary streams, SPMD samples collected during spring runoff generally had higher combined concentrations of organochlorine compounds than those collected during baseflow conditions. Upper Angora Lake had the fewest number of organochlorine compounds detected of all lake samples. Dioxins and furans were not detected in SPMD samples from two sites in Lake Tahoe or from two tributary streams. The number of polycyclic aromatic hydrocarbon (PAH) compounds and their combined concentrations generally were higher in samples from Lake Tahoe than those from tributary streams. Areas of high-motorized boating activity at Lake Tahoe had the largest number and highest concentrations of PAH's. PAH compounds were detected in samples from SPMD's in four of six tributary streams during spring runoff, all tributary streams during baseflow conditions, and at all lake sites. The most commonly detected PAH's in tributary streams during spring runoff were phenanthrene, fluoranthene, pyrene, and chrysene, and during baseflow conditions were phenanthrene, 1-methylphenanthrene, diethylnaphthalene, and pyrene. Upper Truckee River, which has an urban area in its drainage basin, had the largest number and highest combined concentration of PAH's of all stream samples. Bottom-sediment from Lake Tahoe had detectable concentrations of p-cresol, a phenol, in all but one sample. A sample collected near Chambers Lodge contained phenol at an estimated concentration of 4 micrograms per kilogram (µg/kg). Bottom-sediment samples from tributary streams had no detectable concentrations of organochlorine or PAH compounds. Several compounds were detected in bottom sediment from Upper Angora Lake at high concentrations. These compounds and their concentrations were p , p' -DDD (10 µg/kg), p , p' -DDE (7.4 µg/kg), 2,6-dimethylnaphthalene (estimated at 190 µg/kg), pentachlorophenol (3,000 µg/kg), and p-cresol (4,400 µg/kg).

California, Nevada

Mapping Arundo donax (Arundo cane) with multispectral imagery before, during, and after herbicide treatment along the Rio Grande in Webb County, Texas, 2020–21

Arundo donax , commonly called Arundo cane, giant reed, or Carrizo cane, is an invasive bamboo-like perennial grass common in riparian areas throughout the southwestern United States. In Texas, not only does it negatively affect riparian ecosystems, but it has also become a problem for border security because it reduces visibility along the Rio Grande. To address these problems, in 2015 the Texas State Soil and Water Conservation Board was authorized by the Texas State Legislature to develop a program to eradicate Arundo cane along the Rio Grande. In 2020, the Texas State Soil and Water Conservation Board applied imazapyr and glyphosate herbicides along a 19.3-kilometer reach of the Rio Grande, northwest of Laredo, Texas. The U.S. Geological Survey, in cooperation with the Texas State Soil and Water Conservation Board and the Webb Soil and Water Conservation District, used WorldView-3 Standard high-resolution satellite imagery to map Arundo cane extent along the reach before , during , and after the herbicide-treatment period on June 30, 2020, September 26, 2020, and May 7, 2021, respectively. A maximum likelihood supervised classification analysis was computed on the images to map the spatial extent and estimate the area covered by Arundo cane. The estimated area covered by Arundo cane in the before classification was 1,282,000 square meters, in the during classification was 1,064,000 square meters, and in the after classification was 1,108,000 square meters. The qualitative comparison of the three images shows that there was an overall decrease in vegetation classified as Arundo cane throughout the study area.

Texas

Methods for estimating the magnitude and frequency of peak discharges of rural, unregulated streams in Virginia

Methods are presented for estimating the peak discharges of rural, unregulated streams in Virginia. A Pearson Type III distribution is fitted to the logarithms of the unregulated annual peak-discharge records from 363 stream-gaging stations in Virginia to estimate the peak discharge at these stations for recurrence intervals of 2 to 500 years. Peak-discharge characteristics for 284 unregulated stations are divided into eight regions based on physiographic province, and regressed on basin characteristics, including drainage area, main channel length, main channel slope, mean basin elevation, percentage of forest cover, mean annual precipitation, and maximum rainfall intensity. Regression equations for each region are computed by use of the generalized least-squares method, which accounts for spatial and temporal correlation between nearby gaging stations. This regression technique weights the significance of each station to the regional equation based on the length of records collected at each cation, the correlation between annual peak discharges among the stations, and the standard deviation of the annual peak discharge for each station. Drainage area proved to be the only significant explanatory variable in four regions, while other regions have as many as three significant variables. Standard errors of the regression equations range from 30 to 80 percent. Alternate equations using drainage area only are provided for the five regions with more than one significant explanatory variable. Methods and sample computations are provided to estimate peak discharges at gaged and engaged sites in Virginia for recurrence intervals of 2, 5, 10, 25, 50, 100, 200, and 500 years, and to adjust the regression estimates for sites on gaged streams where nearby gaging-station records are available.

Virginia

Subsurface vertical connectivity shapes solute transport to montane streams: Insights from watershed-scale geophysics-informed modeling

Headwater catchments provide essential water and nutrients to downstream ecosystems. The timing and evolution of their transport is shaped in part by the “invisible” subsurface structure but have been largely unexplored at the watershed scale. This raises a fundamental question: how and to what extent does subsurface structure influence streamflow and solute transport in montane watersheds? Here, we test controls of three-dimensionally resolved subsurface structure on solute transport, which reflects source waters and water residence time. We integrate the geophysically mapped architecture of Coal Creek, a headwater catchment in the Colorado River Basin, into numerical flow-transport models. Our results reveal greater vertical connectivity elongates flow paths and enhances deep groundwater contributions to streams, therefore substantially influencing the timing and magnitude of solute transport. In contrast, watershed-integrated outlet discharge can be predicted without high-resolution subsurface information. These findings demonstrate incorporating subsurface architecture is critical for predicting ecosystem health and contaminant transport.

Colorado

Evaluation of solid bitumen created from marine oil shale bituminite under hydrous and anhydrous pyrolysis conditions

To test the influence of environmental conditions on aromaticity of solid bitumen generated during petroleum generation, four organic-rich (26–36 wt% total organic carbon) oil shale samples collected from the Neoproterozoic–Lower Cambrian restricted marine Salt Range Formation in the upper Indus Basin, Pakistan, were pyrolyzed under hydrous and anhydrous conditions. Experiments used closed system batch reactors at subcritical water temperatures between 300 and 370°C for 72 h. Thermal conversion of bituminite in the Salt Range oil shales created a newly formed solid bitumen, similar to previous observations from experiments on the Eocene lacustrine Green River Formation Mahogany zone oil shale. Newly formed solid bitumen in the Salt Range Formation oil shales generally has higher reflectance (R o ) in hydrous residues compared to anhydrous experiments subjected to the same time-temperature conditions, also similar to prior observations. This finding supports the hypothesis that radical disproportionation is favored in the presence of hydrogen contributed by water, promoting aromatization in the solid bitumen residue with concomitant increased expulsion of saturated hydrocarbons. Indigenous solid bitumen (and vitrinite in a comparison sample) also shows higher reflectance values in hydrous versus anhydrous residues, indicating that additional aromatization in the presence of exogenous hydrogen occurs both in newly formed organic matter and in organic matter that is present throughout the experiment. Despite similarities in their bulk rock geochemical screening parameters, R o evolution shows different trajectories amongst the four Salt Range oil shales, suggesting as-yet undetermined differences in kinetic properties which are probably related to differences in a priori chemical composition. These results have implications for the use of solid bitumen reflectance (BR o ) as a thermal proxy, suggesting BR o values and appearance could vary as a function of the concentration of water. Variation in water concentration may be present at the reservoir or formation scale, but may also be present at a much finer scale in tight oil shales where permeability is several orders of magnitude lower than conventional reservoirs. Therefore, local variations in the presence of water potentially could explain substantial variation in BR o values and appearance in closely spaced source rock samples and even within an individual microscope field.

Journal of Analytical and Applied Pyrolysis

Simulated hydrologic responses to proposed wastewater-returnflow scenarios in Falmouth, Massachusetts

The Cape Cod aquifer is the sole source of drinking water for communities on Cape Cod, Massachusetts, including the Town of Falmouth, where the aquifer is currently threatened by contamination from septic-system-derived nitrogen. To address this problem, the Town is proposing to sewer areas of Falmouth, treat the wastewater at the Town’s Main Wastewater Treatment Facility (a nitrogen removing/tertiary treatment facility), and discharge the treated wastewater to an ocean outfall pipe in Nantucket Sound. The U.S. Geological Survey, in cooperation with the Town of Falmouth, updated a three-dimensional steady-state groundwater flow model to represent current (defined as 2019–23) average hydrologic conditions and to simulate the long-term average freshwater hydrologic response to two wastewater-return-flow scenarios. Scenario 1 involves the sewering of all properties south of Route 28 in Falmouth, which approximates the Town’s possible sewer expansion over the next 20–30 years. Scenario 2 involves sewering of all properties in Falmouth to demonstrate the maximum potential effect of sewering on the aquifer. Overall, the simulated hydrologic response of water-table altitudes and streamflow in both scenarios was relatively small compared to fluctuations from natural recharge. In scenario 1, the water-table altitude decreased by about 0.1 feet south of Route 28, where the conversion to municipal sewers removed wastewater-return flow from onsite septic systems. The water-table altitude decreased by about 0.1–0.2 feet over a larger area in Falmouth under town-wide sewering in scenario 2. The greatest decrease in water-table altitude in both scenarios occurred near the Main Wastewater Treatment Facility, with a decrease of about 1.1 feet in scenario 1 and about 1.3 feet in scenario 2. Simulated decreases in streamflow also were estimated for six selected streams in Falmouth and Mashpee. In both scenarios, the largest simulated decreases in streamflow were at the Coonamessett River, which is the closest stream to the Main Wastewater Treatment Facility. In scenario 1, the average annual decrease in flow at the Coonamessett River was 0.1 cubic feet per second, a 1.1 percent decrease from current (2019–23) conditions. In scenario 2, streamflow at the Coonamessett River decreased by 0.6 cubic feet per second, a 5.4 percent decrease from current (2019–23) conditions.

Massachusetts

Satellite tracking of Galapagos Petrel Pterodroma phaeopygia reveals distribution and movements during chick rearing

We tracked 19 adult Galapagos Petrels Pterodroma phaeopygia during the chick-rearing seasons in 2009 and 2010 (Santa Cruz Island [ n = 16] and Floreana Island [ n = 3]) in the Galápagos Islands, Ecuador. Eight petrels performed 27 complete foraging trips lasting 0.6 to 18.8 days. Short trips (3.2 ± 2.1 days; 785 km; max displacement 671 km) and long trips (10.8 ± 3.9 days; 2,856 km; max displacement 1,034 km) resulted in concentrated use of waters off southern and western Isabela Island and within the Galápagos Marine Reserve (GMR). Less concentrated time extended farther southwest and eastward, in that case toward mainland Ecuador. Total distance covered among all completed trips, independent of duration, was strongly correlated with trip duration ( R ² = 0.92), indicating a strategy favoring active searching and foraging over commuting. Petrels ranged across Ecuador's exclusive economic zone (EEZ), as well as other countries' (Colombia, Costa Rica, Perú), and waters beyond; they spent 46%, 27%, and 34% of their time in the GMR during short, long, and apparent (incomplete) trips, respectively. However, overlap with EEZs or marine protected areas (MPAs) does not necessarily confer protection, because commercial tuna fishing, including legal fishing historically permitted inside the GMR, occurs within these waters. Including all complete and incomplete trips, petrels spent 37% of their time in high-seas waters without formal protection, outside both MPAs and EEZs. While some hot spots overlapped Galápagos MPAs, the far-ranging nature of chick-provisioning petrels underscores the importance for this species of also having coordinated, multinational protection of the high seas.

Floreana Island, Galápagos Islands, Santa Cruz Isl

Statewide cumulative human health risk assessment of inorganics-contaminated groundwater wells, Montana, USA

Across the United States, rural residents rely on unregulated and generally unmonitored private wells for drinking water, which may pose serious health risks due to unrecognized contaminants. We assessed the nature, degree, and spatial distribution of cumulative health risks from inorganic contaminants in groundwater. Our analysis included nearly 84,000 data points from 6500+ wells, across 51 of Montana's 98 watersheds, using a public groundwater database. We compared a drinking water screening level cumulative risk assessment (CRA) for inorganics based on the U.S. Environmental Protection Agency (EPA) protective health thresholds (Maximum Contaminant Level Goals, Health Advisories [MCLG-HAs]) to a CRA based on EPA public supply enforceable Maximum Contaminant Levels (MCLs). Based on median concentrations of 19 inorganics (antimony, arsenic, barium, beryllium, boron, cadmium, chromium, copper, fluoride, manganese, molybdenum, nickel, nitrate, lead, selenium, strontium, thallium, uranium, zinc), 75% of watersheds had MCLG-HA-based cumulative risk values > 1.0; arsenic and uranium contributed the most risk, followed by strontium, fluoride, manganese and boron. Hence, this screening level (Tier I) CRA indicated widespread potential for unrecognized human health risk to private well users from inorganic contaminants considering both carcinogenic and non-carcinogenic risks. Sensitivity analysis showed that benchmarks applied (MCLG-HAs versus MCLs) exerted the largest control on results. Our findings identify priority regions for Tier 2 risk assessments to elucidate local sources and distributions of geogenic versus anthropomorphic contaminants. Our study is the first statewide assessment of cumulative health risk from groundwater that we are aware of, and results support increased statewide drinking water education and testing to reduce human health risks from contaminated private well water.

Montana

Techniques for simulating flood hydrographs and estimating flood volumes for ungaged basins in east and west Tennessee

A dimensionless hydrograph developed for a variety of basin conditions in Georgia was tested for its applicability to streams in East and West Tennessee by comparing it to a similar dimensionless hydrograph developed for streams in East and West Tennessee. Hydrographs of observed discharge at 83 streams in East Tennessee and 38 in West Tennessee were used in the study. Statistical analyses were performed by comparing simulated (or computed) hydrographs, derived by application of the Georgia dimensionless hydrograph, and dimensionless hydrographs developed from Tennessee data, with the observed hydrographs at 50 and 75% of their peak-flow widths. Results of the tests indicate that the Georgia dimensionless hydrography is virtually the same as the one developed for streams in East Tennessee, but that it is different from the dimensionless hydrograph developed for streams in West Tennessee. Because of the extensive testing of the Georgia dimensionless hydrograph, it was determined to be applicable for East Tennessee, whereas the dimensionless hydrograph developed from data on streams in West Tennessee was determined to be applicable in West Tennessee. As part of the dimensionless hydrograph development, an average lagtime in hours for each study basin, and the volume in inches of flood runoff for each flood event were computed. By use of multiple-regression analysis, equations were developed that relate basin lagtime to drainage area size, basin length, and percent impervious area. Similarly, flood volumes were related to drainage area size, peak discharge, and basin lagtime. These equations, along with the appropriate dimensionless hydrograph, can be used to estimate a typical (average) flood hydrograph and volume for recurrence-intervals up to 100 years at any ungaged site draining less than 50 sq mi in East and West Tennessee.

Tennessee

Groundwater dominates snowmelt runoff and controls streamflow efficiency in the western United States

Climate change in seasonally snow-covered mountain catchments is reducing water supply and decreasing streamflow predictability. Here, we use tritium age dating to show that contrary to the common assumption that snowmelt quickly contributes to runoff, streamflow during snowmelt in western US catchments is dominated by older groundwater. The average age of streamwater during snowmelt runoff (5.7 ± 4.3 years) was intermediate to the average age of groundwater (10.4 ± 4.5 years) and recent precipitation, indicating that 58% (±34%) of snowmelt runoff was derived from groundwater. Water ages, streamflow, and groundwater storage were mediated by bedrock geology: low-permeability hard rock/shale catchments exhibited younger ages, less storage, and more efficient streamflow generation than high-permeability sandstone/clastic catchments. Our results demonstrate that snowmelt runoff is the result of multiple prior years of climate mediated by groundwater storage. Including these interactions will be crucial for predicting water resources as climate and landscape changes accelerate.

western united States

Peak-discharge frequency and potential extreme peak discharge for natural streams in the Brazos River basin, Texas

The 2-, 5-, 10-, 25-, 50-, and 100-year peak discharges were estimated for 186 streamflow-gaging stations with at least 8 years of data for natural streams in and near the Brazos River Basin, Texas. Multiple regression equations were developed to estimate peak-discharge frequency for the 2-, 5-, 10-, 25-, 50-, and 100-year recurrence intervals for each of three hydrologic regions that compose the Brazos River Basin. The equations for each region are a function of significant basin characteristics (explanatory variables). The significant explanatory variables among six that were tested are the contributing drainage area and stream slope for regions 1 and 2 and the contributing drainage area for region 3. For the three sets of equations, the coefficient of determination ranges from 0.59 to 0.93, and the standard error ranges from 0.184 to 0.391 log units. A larger coefficient of determination and a lower standard error generally are associated with the equations for hydrologic regions 2 and 3. Statistics from the regression analysis allow computation of the prediction interval associated with a given significance level for a peak-discharge frequency estimate. The regression equations can be used to estimate peak discharges for sites at, near, or away from sites with streamflow-gaging stations. The potential extreme peak-discharge curves as related to contributing drainage area were estimated for each of the three hydrologic regions from measured extreme peaks of record at 186 sites with streamflow-gaging stations and from measured extreme peaks at 37 sites without streamflow-gaging stations in and near the Brazos River Basin. The potential extreme peak-discharge curves generally are similar for hydrologic regions 1 and 2, and the curve for region 3 consistently is below the curves for regions 1 and 2, which indicates smaller peak discharges.

Texas

Joint pilot fish habitat framework

This story map will take you through the process of exploring and testing methods necessary for a higher resolution, seamless fish habitat assessment across both inland and estuarine waters through the lens of our joint pilot assessment Fish habitat assessments attempt to relate past, current, or future landscape conditions to the state of fish species occurrence, distribution, abundance, or community and habitat condition in streams, rivers, or estuaries. Previous fish habitat assessments, such as the National Fish Habitat Assessment, conducted separate and disconnected assessments for inland waters and estuaries. In this project, National Oceanic and Atmospheric Administration ( NOAA ) and U.S. Geological Survey ( USGS ) researchers created a seamless spatial framework to allow assessments that integrate influences on fish habitat from headwaters to the estuary. This effort began when the Chesapeake Bay Program Fish Habitat Action Team expressed interest in a Baywide fish habitat assessment spanning tidal salt, tidal fresh, warm non-tidal, and cold non-tidal waters. However, the complexity of the myriad of implementation details to consider when developing such an assessment necessitated the need for a tributary-specific pilot assessment. To conduct this pilot assessment, a NOAA/USGS joint partnership was formed with cooperation and support from the Chesapeake Bay Agreement and Chesapeake Bay Fish Habitat Action Team (FHAT).

Maryland

Groundwater flowpath characteristics drive variability in per- and polyfluoroalkyl substances (PFAS) loading across a stream-wetland system

Groundwater-dependent ecosystems in areas with industrial land use are at risk of exposure to a PFAS chemicals. We investigated one such system with several known PFAS source areas, where high and low permeability sediments (glacial) coupled with groundwater-lake and groundwater/surface-water interactions created complex ‘source to seep’ dynamics. Using heat-tracing and chemical methods, numerous preferential groundwater discharge zones were identified and sampled across the upper Quashnet River stream-wetland system in Mashpee, MA, USA, downgradient of Joint Base Cape Cod (JBCC). Surface-water and groundwater samples were analyzed for 40 PFAS compounds between March and October 2022. Samples were collected from groundwater seeps identified as preferential discharge points (PDPs), wells upgradient of the stream-wetland system, contributing flow-through kettle lakes, and along Quashnet River surface-waters. PFAS from sampled waters contained perfluorinated carboxylates (PFPea, PFHxA, PFNA), perfluorinated sulfonates (PFBS, PFPeS, PFHxS, PFOS), fluorotelomer sulfonates (6:2, 8:2 FtS), and perfluoroalkyl sulfonamides (PFOSA). Samples from PDPs and wells had measured PFAS concentrations ranging from non-detect to 4677 ng/L ng/L (mean = 418 ng/L, std. = 709 ng/L), and a range of deuterium excess values (3.2 to 15.9 per mil) indicative of varying degrees of groundwater-lake interaction prior to groundwater flowpath emergence at PDPs. Correlations ( p < 0.01) between deuterium excess, %PFAS precursors, and terminal PFAS compounds highlighted potential precursor transformations associated with lake-groundwater exchange along flowpaths sourcing PDPs. However, some seepages had higher total PFAS concentrations (>1000 ng/L) than upgradient kettle lakes despite showing lake (evaporative) isotopic signatures, indicating the potential for groundwater flowpath convergence at wetland discharge zones and the influence of lakebed PFAS precursor reactions. Results from these synoptic surveys address gaps in the existing PFAS literature by demonstrating the importance of subsurface fate and transport on PFAS compound concentrations and mass loading in preferential groundwater discharge zones.

Massachusetts

Groundwater quality near the Placerita Oil Field, California, 2018

Groundwater-quality data and potential fluid-migration pathways near the Placerita Oil Field in Los Angeles County, California, were examined by the U.S. Geological Survey to determine if oil-field fluids (water and gas from oil-producing and non-producing zones) have mixed with groundwater resources. Six of the 13 new groundwater samples collected for this study contained petroleum hydrocarbons, thermogenic gas, inorganic chemical signatures, and (or) isotopic values consistent with potential mixing with fluids from hydrocarbon-bearing formations. For historical groundwater samples, benzene was the most detected petroleum hydrocarbon. The historical groundwater samples with a benzene concentration greater than 0.5 micrograms per liter were from environmental monitoring wells at industrial or commercial facilities unrelated to oil and gas development that, in many cases, have identified soil or groundwater contamination and were not typically analyzed for other constituents that could provide additional lines of evidence for potential mixing with oil-field fluids. Methane was not detected in any of the 12 historical samples with a reported measurement. Reviewing historical data revealed factors that could potentially adversely affect groundwater quality in the study area. These factors include modified hydraulic gradients caused by large volumes of water extracted from the main production area and reinjected downgradient into nonproducing zones, well-barrier failures in wells constructed in the northern part of the oil field before the 1970s, well-barrier failures in produced-water disposal wells downgradient from the main production area, and naturally occurring hydrocarbons at shallow intervals. The groundwater samples most geochemically similar to samples from hydrocarbon-bearing formations were in areas where hydrocarbons are naturally occurring at shallow intervals and where oil development is at shallow depths. Additional data for hydraulic heads, water quality, and formation temperatures at multiple depths in areas with large injection volumes and well-integrity issues are needed to evaluate whether those factors have contributed to mixing between fluids from oil-producing or injection formations and groundwater resources.

California

Beavers in the Tualatin River Basin, northwestern Oregon

Growing interest in beaver-assisted restoration in the Tualatin River Basin of northwestern Oregon motivated a series of studies by the U.S. Geological Survey to assess the capacity of the stream network to support beaver dams and to evaluate the effects of beaver dams and ponds on urban streams. This multichapter volume describes the data collection from 2016–17 and the findings of these studies, which were done in partnership with Clean Water Services. Chapter A documents the locations of beaver dams in the Tualatin River Basin and how many beaver dams the stream network could support with existing and improved riparian vegetation. Beaver dam capacity was estimated by modifying existing tools to account for the low gradient of many streams in the Tualatin River Basin. Chapter B describes the effects of beaver dams and ponds on hydrologic and hydraulic responses of storm flows. Hydrologic and hydraulic responses for two urban stream reaches were compared with and without beaver dams and ponds and for a range of streamflow conditions using two-dimensional hydraulic models. Chapter C characterizes the effects of beaver dams and ponds on the transport and deposition of suspended sediment. Continuous turbidity, discrete suspended-sediment samples, and streamflow measurements collected during storms and base-flow periods were used to assess: (1) suspended-sediment loads upstream and downstream from two beaver-affected reaches, and (2) seasonal and longitudinal turbidity patterns. Chapter D describes the effects of beaver dams and ponds on longitudinal, spatial, and seasonal water-quality patterns. Continuous and synoptic water-quality data were collected along urban stream reaches, and net ecosystem production was calculated for two beaver-affected reaches. The findings of these studies illustrate that the effects of beaver dams and ponds on hydrology, hydraulics, suspended-sediment transport and deposition, and water quality are dependent on the characteristics of a stream reach (for example, channel gradient, groundwater exchange, and riparian vegetation) and the characteristics of beaver dams and ponds along that reach. This information can be used to consider the implications of beaver-assisted restoration in the Tualatin River Basin and the effects of beaver dams and ponds in urban streams.

Oregon

Groundwater surveillance of swine pathogens from private wells supplying swine farms in Iowa

Biosecurity practices are essential for maintaining pig health and productivity. Despite these measures, pathogen spread still occurs. Water is one of the largest daily inputs on swine farms by volume and is not routinely tested or disinfected before it is consumed by the animals [1-3], making it a poorly understood biosecurity risk. Groundwater from privately-owned wells is a common water source for swine farms. Pathogens in the landscape, such as bacteria, viruses, and protozoa, can reach groundwater more rapidly through soil macropores, maintaining viability and facilitating transmission of pathogens into aquifers [3-13].

Iowa