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Focus areas for data acquisition for potential domestic resources of 11 critical minerals in the conterminous United States, Hawaii, and Puerto Rico—Aluminum, cobalt, graphite, lithium, niobium, platinum-group elements, rare earth elements, tantalum, tin, titanium, and tungsten

In response to a need for information on potential domestic sources of critical minerals, the Earth Mapping Resources Initiative (Earth MRI) was established to identify and prioritize areas for acquisition of new geologic mapping, geophysical data, and elevation data to improve our knowledge of the geologic framework of the United States. Phase 1 of Earth MRI concentrated on those geologic terranes favorable for hosting the rare earth elements (REEs). Phase 2 continued to address the REEs and also identified focus areas for potential domestic sources of 10 more of the 35 critical minerals on the U.S. critical minerals list (aluminum, cobalt, graphite, lithium, niobium, platinum-group elements, tantalum, tin, titanium, tungsten). This report describes the methodology, data sources, and summary results for mineral systems that host these 11 critical minerals in the conterminous United States, Hawaii, and Puerto Rico; Alaska is covered in a separate report. The mineral systems framework adopted for this study links critical mineral commodities to families of genetically related mineral deposit types. The mineral systems approach is an efficient approach, providing a simultaneous evaluation of geologic terranes through aggregation of genetically related mineral deposit types that are much larger than individual ore deposits. Geologic, geochemical, topographic, and geophysical mapping provided by Earth MRI will document geologic features that reflect the extent of individual mineral systems and provide information about critical mineral deposits that may not have been recognized previously. Each critical mineral commodity is discussed in terms of importance to the Nation’s economy, modes of occurrence, mineral systems, and deposit types along with maps and tables listing examples of focus areas for each critical mineral. Important mineral systems for these critical minerals include chemical weathering systems for aluminum (bauxite); placer systems for titanium and REEs; metamorphic systems for graphite; mafic magmatic systems for platinum-group elements and cobalt; lacustrine evaporite and porphyry tin systems for lithium; and copper-molybdenum-gold (Cu-Mo-Au) systems for tungsten. REEs occur in many different mineral systems. Focus areas were developed by scientists from the U.S. Geological Survey in collaboration with scientists from State geological surveys and other institutions. This first national-scale compilation of focus areas represents an initial step in addressing the Nation’s critical mineral needs by screening areas for acquisition of new data to provide the geologic framework necessary for identifying domestic sources of critical minerals.

Open-File Report↗

Alaska: A twenty-first-century petroleum province

Alaska, the least explored of all United States regions, is estimated to contain approximately 40% of total U.S. undiscovered, technically recoverable oil and natural-gas resources, based on the most recent U.S. Department of the Interior (U.S. Geological Survey and Minerals Management Service) estimates. Northern Alaska, including the North Slope and adjacent Beaufort and Chukchi continental shelves, holds the lion's share of the total Alaskan endowment of more than 30 billion barrels (4.8 billion m 3 ) of oil and natural-gas liquids plus nearly 200 trillion cubic feet (5.7 trillion m 3 ) of natural gas. This geologically complex region includes prospective strata within passive-margin, rift, and foreland-basin sequences. Multiple source-rock zones have charged several regionally extensive petroleum systems. Extensional and compressional structures provide ample structural objectives. In addition, recent emphasis on stratigraphic traps has demonstrated significant resource potential in shelf and turbidite systems in Jurassic to Tertiary strata. Despite robust potential, northern Alaska remains a risky exploration frontier - a nexus of geologic complexity, harsh economic conditions, and volatile policy issues. Its role as a major petroleum province in this century will depend on continued technological innovations, not only in exploration and drilling operations, but also in development of huge, currently unmarketable natural-gas resources. Ultimately, policy decisions will determine whether exploration of arctic Alaska will proceed.

Alaska↗

Geologic map of the Kechumstuk fault zone in the Mount Veta area, Fortymile mining district, east-central Alaska

This map was developed by the U.S. Geological Survey Mineral Resources Program to depict the fundamental geologic features for the western part of the Fortymile mining district of east-central Alaska, and to delineate the location of known bedrock mineral prospects and their relationship to rock types and structural features. This geospatial map database presents a 1:63,360-scale geologic map for the Kechumstuk fault zone and surrounding area, which lies 55 km northwest of Chicken, Alaska. The Kechumstuk fault zone is a northeast-trending zone of faults that transects the crystalline basement rocks of the Yukon-Tanana Upland of the western part of the Fortymile mining district. The crystalline basement rocks include Paleozoic metasedimentary and metaigneous rocks as well as granitoid intrusions of Triassic, Jurassic, and Cretaceous age. The geologic units represented by polygons in this dataset are based on new geologic mapping and geochronological data coupled with an interpretation of regional and new geophysical data collected by the Alaska Department of Natural Resources, Division of Geological and Geophysical Surveys. The geochronological data are reported in the accompanying geologic map text and represent new U-Pb dates on zircons collected from the igneous and metaigneous units within the map area.

Alaska↗

Surface-water, ground-water, and sediment geochemistry of epizonal and shear-hosted mineral deposits in the Tintina Gold Province--arsenic and antimony distribution and mobility: Chapter G in Recent U.S. Geological Survey studies in the Tintina Gold Province, Alaska, United States, and Yukon, Canada--results of a 5-year project

Epigenetic mineral deposits in the Tintina Gold Province are generally characterized by high concentrations of arsenic and antimony in their mineral assemblage. A total of 347 samples (ground water, surface water, and stream sediment) were collected to investigate the distribution and mobility of arsenic and antimony in the environment near known mineral deposits. Samples were collected from east to west at Keno Hill and Brewery Creek, Yukon, Canada; and Cleary Hill, True North, Scrafford Mine, Fairbanks, Ryan Lode, Stampede Creek, Slate Creek, and Donlin Creek, all in Alaska. Surface- and ground-water samples are all slightly acidic to near-neutral in pH (5-8), have a wide range in specific conductance (surface water 17-2,980 microsiemens per centimeter and ground water 170-2,940 microsiemens per centimeter), and show elevated dissolved arsenic and antimony concentrations (arsenic in surface water is less than 1 to 380 micrograms per liter and in ground water is less than 1 micrograms per liter to 1.5 milligrams per liter; antimony in surface water is less than 2 to 660 micrograms per liter and in ground water is less than 2 to 60 micrograms per liter). Stream sediments downstream from these deposits have high concentrations of arsenic and antimony (arsenic median is 1,670 parts per million, maximum is 10,000 parts per million; antimony median is 192 parts per million, maximum is 7,200 parts per million). The mobility of arsenic and antimony is controlled by the local redox environment, with arsenic being less mobile in oxidized surface waters relative to antimony, and arsenic more mobile in reduced ground water. These factors suggest that both antimony and arsenic may be useful pathfinder elements in water and sediment for targeting similar style deposits elsewhere in the Tintina Gold Province.

Alaska;Yukon↗

Detrital zircon geochronology of Cretaceous and Paleogene strata across the south-central Alaskan convergent margin

Ages of detrital zircons are reported from ten samples of Lower Cretaceous to Paleogene metasandstones and sandstones from the Chugach Mountains, Talkeetna Mountains, and western Alaska Range of south-central Alaska. Zircon ages are also reported from three igneous clasts from two conglomerates. The results bear on the regional geology, stratigraphy, tectonics, and mineral resource potential of the southern Alaska convergent margin. Chugach Mountains - The first detrital zircon data are reported here from the two main components of the Chugach accretionary complex - the inboard McHugh Complex and the outboard Valdez Group. Detrital zircons from sandstone and two conglomerate clasts of diorite were dated from the McHugh Complex near Anchorage. This now stands as the youngest known part of the McHugh Complex, with an inferred Turonian (Late Cretaceous) depositional age no older than 91-93 Ma. The zircon population has probability density peaks at 93 and 104 Ma and a smattering of Early Cretaceous and Jurassic grains, with nothing older than 191 Ma. The two diorite clasts yielded Jurassic U-Pb zircon ages of 179 and 181 Ma. Together, these findings suggest a Mesozoic arc as primary zircon source, the closest and most likely candidate being the Wrangellia composite terrane. The detrital zircon sample from the Valdez Group contains zircons as young as 69 and 77 Ma, consistent with the previously assigned Maastrichtian to Campanian (Late Cretaceous) depositional age. The zircon population has peaks at 78, 91, 148, and 163 Ma, minor peaks at 129, 177, 330, and 352 Ma, and no concordant zircons older than Devonian. A granite clast from a Valdez Group conglomerate yielded a Triassic U-Pb zircon age of 221 Ma. Like the McHugh Complex, the Valdez Group appears to have been derived almost entirely from Mesozoic arc sources, but a few Precambrian zircons are also present. Talkeetna Mountains - Detrital zircons ages were obtained from southernmost metasedimentary rocks of the Talkeetna Mountains (schist of Hatcher Pass) and, immediately to the south, the northernmost sedimentary sequence of the Matanuska forearc basin (Arkose Ridge Formation). Detrital zircons from the Paleogene Arkose Ridge Formation are as young as 61 and 70 Ma; the population is dominated by a single Late Cretaceous peak at 76 Ma; the oldest zircon is 181 Ma. Sedimentological evidence clearly shows that the conglomeratic Arkose Ridge Formation was derived from the Talkeetna Mountains; our detrital zircon data support this inference. Zircons dated at ca. 90 Ma in the Arkose Ridge sample suggest that buried or unmapped plutons of this age may exist in the Talkeetnas. This is a particularly interesting age as it corresponds to the age of the supergiant Pebble gold-molybdenum-copper porphyry prospect near Iliamna and suggests a new area of prospectivity for Pebble-type deposits. The schist of Hatcher Pass, which was previously assigned a Jurassic depositional age, yielded surprisingly young Late Cretaceous detrital zircons, the youngest at 75 Ma. The probability density curve has four Cretaceous peaks from 76 to 102 Ma, a pair of Late Jurassic peaks at 155 and 166 Ma, three Early Jurassic to Late Triassic peaks at 186, 197, and 213 Ma, minor Carboniferous peaks at 303 and 346 Ma, and a minor Paleoproterozoic peak at 1828 Ma. The schist of Hatcher Pass was largely derived from Mesozoic arc sources, most likely the Wrangellia composite terrane, with some contribution from one or more older, inboard sources, probably including the Yukon-Tanana terrane. We postulate that the schist of Hatcher Pass represents metamorphosed rocks of the Valdez Group that were subducted and then exhumed along the Chugach terrane's 'backstop' during Paleogene transtension. Western Alaska Range - Six detrital zircon samples were collected from a little studied belt of turbidites in Tyonek quadrangle on strike with the Kahiltna assemblage of the central Alaska Range.

Alaska↗

Soil data from fire and permafrost-thaw chronosequences in upland Picea mariana stands near Hess Creek and Tok, interior Alaska

Soils of the Northern Circumpolar Permafrost region harbor 1,672 petagrams (Pg) (1 Pg = 1,000,000,000 kilograms) of organic carbon (OC), nearly 50 percent of the global belowground OC pool (Tarnocai and others, 2009). Of that soil OC, nearly 88 percent is presently stored in perennially frozen ground. Recent climate warming at northern latitudes has resulted in warming and thawing of permafrost in many regions (Osterkamp, 2007), which might mobilize OC stocks from associated soil reservoirs via decomposition, leaching, or erosion. Warming also has increased the magnitude and severity of wildfires in the boreal region (Turetsky and others, 2011), which might exacerbate rates of permafrost degradation relative to warming alone. Given the size and vulnerability of the soil OC pool in permafrost soils, permafrost thaw will likely function as a strong positive feedback to the climate system (Koven and others, 2011; Schaefer and others, 2011). In this report, we report soil OC inventories from two upland fire chronosequences located near Hess Creek and Tok in Interior Alaska. We sampled organic and mineral soils in the top 2 meters (m) across a range of stand ages to evaluate the effects of wildfire and permafrost thaw on soil C dynamics. These data were used to parameterize a simple process-based fire-permafrost-carbon model, which is described in detail by O’Donnell and others (2011a, b). Model simulations examine long-term changes in soil OC storage in response to fire, permafrost thaw, and climate change. These data also have been used in other papers, including Harden and others (2012), which examines C recovery post-fire, and Johnson and others (2011), which synthesizes data within the Alaska Soil Carbon Database. Findings from these studies highlight the importance of climate and disturbance (wildfire, permafrost thaw) on soil C storage, and loss of soil C from high-latitude ecosystems.

Alaska↗

Regional Fluid Flow and Basin Modeling in Northern Alaska

The foothills of the Brooks Range contain an enormous accumulation of zinc (Zn) in the form of zinc sulfide and barium (Ba) in the form of barite in Carboniferous shale, chert, and mudstone. Most of the resources and reserves of Zn occur in the Red Dog deposit and others in the Red Dog district; these resources and reserves surpass those of most deposits worldwide in terms of size and grade. In addition to zinc and lead sulfides (which contain silver, Ag) and barite, correlative strata host phosphate deposits. Furthermore, prolific hydrocarbon source rocks of Carboniferous and Triassic to Early Jurassic age generated considerable amounts of petroleum that may have contributed to the world-class petroleum resources of the North Slope. Deposits of Zn-Pb-Ag or barite as large as those in the Brooks Range are very rare on a global basis and, accordingly, multiple coincident favorable factors must be invoked to explain their origins. To improve our understanding of these factors and to contribute to more effective assessments of resources in sedimentary basins of northern Alaska and throughout the world, the Mineral Resources Program and the Energy Resources Program of the U.S. Geological Survey (USGS) initiated a project that was aimed at understanding the petroleum maturation and mineralization history of parts of the Brooks Range that were previously poorly characterized. The project, titled “Regional Fluid Flow and Basin Modeling in Northern Alaska,” was undertaken in collaboration with industry, academia, and other government agencies. This Circular contains papers that describe the results of the recently completed project. The studies that are highlighted in these papers have led to a better understanding of the following: The complex sedimentary facies relationships and depositional settings and the geochemistry of the sedimentary rocks that host the deposits (sections 2 and 3). The factors responsible for formation of the barite and zinc deposits (sections 4 and 5). The geochemical indicators or exploration tools that might be used to locate other large deposits of similar character in the Red Dog district and elsewhere (section 6). The isotopic compositions of barite and sulfide deposits (sections 7 and 8) The distribution and nature of phosphate and metalliferous oil shale localities (sections 9 and 10). The architecture, kinematics, and timing of the complex thrust systems that disrupted and redistributed the Carboniferous and younger rocks; these studies are necessary in order to make a realistic palinspastic reconstruction of the basin (sections 11 and 12). The nature and extent of the petroleum system sourced from Mississippian rocks (section 13).

Circular↗