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Geochemical disequilibrium at the brittle-ductile transition

We investigate the microtextural, microchemical, and isotopic effects of late-stage ductile deformation in quartzite mylonites and kyanite–muscovite–quartz veins from the Raft River shear zone (Utah). Quartz microstructures record pervasive disequilibrium, expressed by unannealed features including undulatory extinction, deformation lamellae, and poorly defined fabrics, typical of waning deformation in shear zones. Microchemical disequilibrium is best preserved in kyanite quartzites, where CL-zoned kyanite records repeated fractures, overgrowth, and mineral precipitation, and in muscovite from muscovite-poor quartzite mylonites that shows minor-element zoning consistent with syn-deformational overgrowth on detrital cores. In contrast, muscovite from muscovite-rich kyanite quartzites exhibits minimal chemical zoning. These microchemical variations correlate with 40 Ar/ 39 Ar age systematics. Chemically zoned muscovite preserves variable single-step ages, including ∼150 Ma ages, reflecting retention of detrital cores. In contrast, syndeformational muscovite consistently yields Miocene ages, indicating recrystallization and new growth below argon closure temperatures that reset inherited isotopic signatures. Similar trends are observed in quartzite mylonites, where increasing quartz recrystallization and stronger crystallographic preferred orientations occur toward deeper structural levels. Together, these observations indicate increasing retrograde deformation and recrystallization with depth in the Raft River shear zone and demonstrate that strain-driven recrystallization exerts a first-order control on muscovite ages. We suggest that apparent thermochronologic gradients in retrograde shear zones may reflect recrystallization gradients rather than temperature gradients. Where cooling limits the thermal driving force for recrystallization, isotopic relics are preserved, and local deformation and fluid availability control re-equilibration. Consequently, isotopic disequilibrium—particularly in the 40 Ar/ 39 Ar system—may be the rule rather than the exception of retrograde tectonic environments.

Idaho, Utah

Using subducting plate motion to constrain Cascadia slab geometry and interface strength

Subduction zones are home to multiple geohazards driven by the evolution of the regional tectonics, including earthquakes, volcanic eruptions and landslides. Past evolution builds the present-day structure of the margin, while the present-day configuration of the system determines the state-of-stress in which individual hazardous events manifest. Regional simulations of subduction zones provide a tool to synthesize the tectonic history of a region and investigate how geologic features lead to variations in the state of stress across the subduction system. However, it is challenging to design regional models that provide a force-balance that is consistent with the large-scale motion of surrounding tectonic plates while also not over-constraining the solution. Here, we present new models for the Cascadia subduction zone that meet these criteria and demonstrate how the motion of the subducting Juan de Fuca plate can be used to determine the along-strike variations in the viscous (long-term) coupling across the plate boundary. All successful models require lower viscous coupling in the northern section of the trench compared to the central and southern sections. However, due to uncertainties in the geometry of the Cascadia slab, we find that there is a trade-off between along-strike variation in viscous coupling and slab shape. Better constraints on the slab shape, and/or use of other observations are needed to resolve this trade-off. The approach presented here provides a framework for further exploring how geologic features in the overriding plate and the properties of the plate boundary region affect the state-of-stress across this and other subduction zones.

Cascadia subduction zone

Enhanced microplastic fragmentation along human built structures in an urban waterway

Plastic pollution and microplastic (MP, 1 µm to 5 mm) generation are growing problems affecting the global community and a wide range of natural and disturbed environments. Urban and suburban waterways are directly impacted by plastic pollution due to their proximity to population centers and many different types single use plastic waste sources. In this study, plastic waste accumulation and fragmentation was investigated along the Cooper River in Camden County, NJ. Polymer composition was identified for individual plastic waste particles collected along the Cooper River using Fourier transform infrared (FTIR) spectrometry. Multiple human-built structures (Wallworth Lake, Evans Pond and Hopkins Pond dams) along the Cooper River were found to accumulate different types of plastic waste. The accumulation of plastic waste along these structures resulted in the initial stages of plastic fragmentation and the identification of large MP particles (1 to 5 mm). Quantitative analysis revealed that fragmented polystyrene (PS) particles constituted 82.8% of the total plastic fragments identified, most of which were identified at the Wallworth Lake dam. Many other types of fragmented plastic litter, including polyethylene and polypropylene, were identified at the Wallworth Lake dam, as well. This research demonstrates that engineered structures within urban and suburban aquatic ecosystems serve as significant aggregators of plastic debris, thereby catalyzing its breakdown into microplastics. Considering the escalating ecological and human health ramifications of microplastic proliferation, the fragmentation of plastic waste in an urban and suburban waterway observed in this study can also result in potentially toxic smaller MP particles, and increased exposure to aquatic organisms and humans.

New Jersey

Top-down targeted network analysis of critical mineral commodities applied to international geochemistry database

The global demand for critical mineral commodities is rapidly increasing, making domestic production an important factor in supporting the economy and national security. Large scale, publicly available geochemical databases allow for the application of data informatics methods to interrogate critical mineral commodities data for correlations in deposit formation and distribution, particularly for identifying enrichment of multiple critical mineral commodities at the same deposit. In this study, we applied network analysis to the Critical Minerals Mapping Initiative (CMMI) ore geochemistry (Critical Minerals in Ores, CMiO) database to identify the high concentration (defined as 10× bulk crustal abundance) co-occurrence of different critical mineral commodities across a mineral system hierarchy from deposit environments to individual deposits. Identifying patterns or unique outliers in enrichment in network communities will allow for the location of secondary critical mineral commodity resources from under-utilized deposits. We find trends in the enrichment of critical mineral commodities in network-communities between the elements praseodymium (Pr), neodymium (Nd), terbium (Tb), and dysprosium (Dy) across multiple CMiO database deposit environments and groups down to specific deposit types and sites. A separate trend in network community deposition is observed as well between iridium (Ir) and platinum (Pt) in deposit environments, groups, types, and sites. Network analysis focused on critical minerals in magmatic-hydrothermal deposits identified multiple deposit sites from different deposit types within the CMiO database with concentrations of Dy, Nd, Tb, Pr, Ir, and Pt that are at least ten times greater than the crustal average. This approach can be applied to any target element(s) or deposit(s) of interest, allowing broad investigation of co-enriched critical mineral commodities.

Journal of Geochemical Exploration

Site response in the Walnut Creek–Concord region of the San Francisco Bay, California: Ground motion amplification in a fault-bounded basin

Thirty‐seven portable accelerometers were deployed in the eastern San Francisco Bay communities of Walnut Creek and Concord to study site response in a fault‐bounded, urban, sedimentary basin. Local earthquakes were recorded for a period of two years from 2017 to 2019 resulting in 101 well‐recorded events. Site response is estimated by two methods: the reference site spectral ratio method and a source‐site spectral inversion method. The reference site spectral ratio method allows investigation of the variability of site amplification with source azimuth and frequency. The source‐site spectral inversion method yields the best least‐squares fit to site response for a database of ground‐motion records. Both methods show substantial amplification in the Walnut Creek–Concord basin below 2 Hz indicating strong surface‐wave development. Greater amplification is seen for sources aligned along the long axis of the basin. Inversion using close‐in sources at short distances yields lower amplification at longer periods than the entire data set due to reduced surface‐wave generation for steeper angles of incidence. Inversion of site response spectra for shallow shear‐wave velocity using a global search algorithm yields V S30 values consistent with generalized mapping results based on geology and topography but with greater variability due to local site variations. 3D finite‐element modeling shows greater amplification in the Walnut Creek–Concord basin with a basin‐edge effect likely contributing to higher ground motions. Topography is also seen to lead to increased scattering and shadowing effects.

California

Apatite and monazite geochemistry record magmatic and metasomatic processes in rare earth element mineralization at Mountain Pass, California

The largest rare earth element (REE) deposit in the United States is a carbonatite intrusion at Mountain Pass in the Mojave Desert, California. Despite a clear spatiotemporal association of alkaline silicate and carbonatite intrusions at Mountain Pass, a genetic model of their mutual formation has not been resolved. The Mountain Pass carbonatite has long been upheld as an example of a primary magmatic body, but recent work has suggested it could be fluid-derived. This study investigates the geochemistry of apatite and monazite grains from the alkaline silicate and carbonatite stocks and dikes of the Mountain Pass district, to elucidate the magmatic history of the intrusive suite and identify the role of fluids in rare earth element mineralization. Three apatite populations are identified in the alkaline silicate rocks. A primary magmatic apatite group supports intrusion of the stocks as separate pulses of magma derived from a spatially extensive metasomatized mantle source region. The second group implicates the role of a regional fluid that mobilized light rare earth elements from apatite grains. A minor group of inherited apatite cores, identified by low Sr and negative Eu anomalies, supports assimilation of crustal material in the formation of the intrusive suite. Analyses of monazite and apatite grains from the carbonatite orebody also reveal a mix of primary magmatic and metasomatic (fluid-related) minerals. Compositional similarities between primary phosphates in the carbonatite and alkaline silicate rocks support a genetic link between the intrusive suites. The presence of fluids regionally and within the carbonatite orebody indicates the Mountain Pass carbonatite should not be classified as a purely magmatic REE deposit.

Arizona, California, Nevada

The influence of postfire root strength decay on shallow landslide susceptibility in western Oregon

Severe wildfires can increase the potential for postfire landslides, partly due to the loss of vegetation and root reinforcement. This study investigates the multi-year dynamics of root strength following wildfire in coniferous forests of western Oregon and evaluates implications for postfire slope stability. Root tensile strength was measured through laboratory testing of 969 roots collected from 26 test pits over four postfire timeframes: unburned conditions, 4–12 months postfire (Cedar Creek, 2022), 24–35 months postfire (Holiday Farm, 2020), and 59–67 months postfire (Eagle Creek, 2017). Variables analyzed include root diameter, tensile thread strength, stiffness, progressive tensile strength with displacement, time-dependent strength and ductility, root area ratio, and cohesion. Results indicate a 50% reduction in root strength after wildfire, with the lowest values occurring around 4 years postfire. Projections indicate it could take 10–22 years following fire for root strength to recover to 70% and 90% of the prefire original root strength, respectively. This timeline indicates a multi-year window of vulnerability for shallow landslides that reaches a maximum approximately 4 years following fire. Brittle failure behavior was observed in burned root systems compared to unburned root systems, signaling a more abrupt loss of strength at yield. Simple slope stability analyses show that reduced root strength can lead to instability on more gentle slopes and under less saturation in comparison to unburned conditions. These findings highlight the critical role of root reinforcement in postfire slope stability and the long-term implications of wildfire disturbance on landslide susceptibility.

Oregon

Widespread landslide activity in an extreme wet season and implications for regional sediment management, eastern San Francisco Bay area, California

Watershed sediment production is expected to increase in a warmer future with more extreme rain, with cascading effects throughout drainage and sediment-transport networks. This study investigated landscape-scale sediment movement in the eastern San Francisco Bay area, California, USA, during the extreme 2016–2017 wet season that brought major rainfall, landslides, and flooding. Mapping 8,928 landslides across a 1,050-km 2 study area revealed new sediment yield of 510–956 t/km 2 , equivalent to denudation of 193–361 mm/ky. These results correspond closely to long-term denudation rates in the northern and central California Coast Ranges, indicating that mass wasting in very wet years dominates long-term sediment mobilization. However, due to long residence times in drainage networks, the 2017 landslides contributed at most ∼1%–2% of the estimated locally derived fluvial sediment transport to San Francisco Bay. Although the amount of sediment mobilized did not threaten municipal water supplies, small rangeland impoundments in this mixed-use landscape lost storage capacity to new sedimentation. Considering regional sediment supply and demand, even the exceptionally large sediment delivery in an extreme wet year cannot meet the need for sediment to accrete tidal wetlands in the bay. To keep pace with rising sea levels, this abnormally high terrestrial sediment input would need to occur in 50 of the next 75 years, an unlikely occurrence due to the prevalence of recent drought years. Shoreline protection and restoration in the bay would need additional sources of sediment, such as through management of dredged sediment through beneficial-reuse programs.

California

An orbital comparison of a late mantling unit on Aeolis Mons with other erosion-resistant strata explored by MSL in Gale crater, Mars

Previous investigations along Curiosity 's traverse in Gale crater have explored the relationship between orbital and in situ observations. This work aims to better understand the geologic environment of units only observable from orbit and compare them to the properties of units examined by Curiosity . Here, we map an erosion-resistant dark-toned mantling unit that overlies the modern topography of Aeolis Mons (informally known as Mt. Sharp) and compare this unit to two other previously mapped dark-toned resistant units, the marker band and the mound skirting unit (MSU), that have been inferred to represent different geologic environments (lacustrine and aeolian, respectively). Visible to short wave infrared spectra from the Compact Reconnaissance Imaging Spectrometer for Mars and visual images from the High Resolution Imaging Science Experiment and Context Cameras aboard the Mars Reconnaissance Orbiter are used for this comparison. Spectral data suggest a mafic composition with minor alteration, although the composition varies more with location around Mt. Sharp rather than between units. Morphologically, the mantling unit has strong similarities to the marker band based on their consistent low-albedo, erosion-resistance, and smooth appearance, contrasting with the highly variable surface texture of the MSU. We hypothesize that all three units had a similar sediment source but experienced aqueous alteration at different times: early ubiquitous cementation in a surface aqueous environment in the mantling unit and marker band versus patchy late diagenesis in the MSU. If true, these results suggest that water activity continued within the Gale crater long after the erosion of Mt. Sharp.

JGR Planets

Relationship between peak and cumulative ground motions from 49 Mw 3-6 earthquakes in the San Francisco Bay Area

We examine the relationship between peak ground velocity (PGV) and cumulative absolute displacement (CAD) for 49 M w 3 – 6 earthquakes in the San Francisco Bay Area (SFBA) and gain insight into the spatiotemporal partitioning of seismic energy in ground motion records with respect to source, path, and site effects. PGV and CAD are positively correlated, but there can be large deviations from the average trend. For example, ground motion records with either very long duration resonance or short pulse-like motions will have higher or lower CAD, respectively, but could have very similar PGV. We perform principal component analysis (PCA) on PGV-CAD for >7000 records in the SFBA with the goal of investigating what influences positive or negative anomalies in cumulative motions. PCA rotates the PGV-CAD datapoints into two principal components, where the one with the larger variance, which we call the “primary intensity” represents mostly the distance-dependence of ground motion amplitudes. The other principal component, which we call the “excess motion”, represents the deviation from cumulative motions that would be typical for a ground motion record with a given PGV. The excess motion will be positive in the case of records with long duration ringing and will be negative for short duration pulse-like ground motions. We find that excess motion is generally positive at sites in sedimentary basins and in soft sediments around the SF Bay. Excess motion is generally negative in the very near field, as well as at sites on hard bedrock. We discuss the findings here in terms of implications for seismic hazard applications and other wave propagation phenomena.

California

Geochemical, mineralogical, and isotopic evidence for multi-stage genesis of the Hicks Dome REE + Y-HFSE-fluorite deposit, Illinois, USA

Hicks Dome hosts breccias enriched in rare earth elements (REE), Y, Th, F, Ba, Ti, Nb, and Be, alongside spatially associated lamprophyre dikes (ca. 271 Ma). Hicks Dome is located within the Illinois–Kentucky Fluorspar District, which hosts fluorite, Pb–Zn, and barite resources. This study investigates the genetic relationships between Hicks Dome mineralization in breccias, alkaline magmatism, and Illinois–Kentucky Fluorspar District mineralization. Lamprophyre dikes are light REE–enriched with chondrite-normalized abundances decreasing from La to Lu. The Host Breccia exhibits middle and heavy REE–enriched patterns that mirror those of the principal REE–Th host minerals, including fluorapatite, xenotime, and thorite. Textural evidence suggests recrystallization of phosphates, sulfates, and Ti–Nb oxides in the Host Breccia. U–Pb geochronology constrains multiple mineralizing events, with ages of 277 ± 18 Ma from low-Th apatite interpreted as main-stage mineralization, and 121.6 ± 9.7 Ma from high-Th apatite indicating later overprinting. O–H–C stable isotope data provide evidence for multiple stages of fluid-rock interaction and fluid mixing: (1) early magmatic fluids dissolved limestone country rock, (2) mixing between magmatic fluids and basinal brines led to main-stage mineralization in the Host Breccia, and (3) late-stage mineralization occurred following mixing of meteoric water and basinal brine. These results indicate that heavy REEs, high field strength elements, and fluorine precipitated proximal to its alkaline magmatic source because of fluid–rock interactions and fluid mixing. Subsequent fluid mixing drove late-stage recrystallization and additional fluorite formation, a process that may be similar to mineralization in the Illinois-Kentucky Fluorspar District.

Illinois

Postglacial ecosystem development of a hydrothermal landscape in Yellowstone National Park

The Yellowstone geo-ecosystem has been the subject of much research, but the ecological history of the Yellowstone Plateau volcanic field and its iconic geyser basins is less known. In this investigation, paleoenvironmental analyses of sediment cores from lakes in Lower Geyser Basin were compared with regional records and paleoclimate model simulations to reconstruct the vegetation, wildfire, limnology, hydrothermal dynamics, and climate drivers since deglaciation, 15,000 to 14,000 years ago. Pollen data from Lower Geyser Basin lakes reveal the strong influence of infertile rhyolitic soils on vegetation history: an initial late-glacial steppe was replaced by lodgepole pine forest from 12.8 to 11.0 ka, with little change in forest composition or cover thereafter despite changing climate. This stability contrasts with the more dynamic vegetation response on nonrhyolite substrates in the Yellowstone region where nutrient and moisture availability is greater. Highest wildfire activity and low lake nutrient levels in Lower Geyser Basin occurred from 12 to 4 ka, when summers were substantially warmer and drier and fire-inducing vapor pressure deficits were 29 to 56% higher. The hydrothermal history, inferred from sedimentary arsenic and cesium abundances, was spatially and temporally variable but lake-forming hydrothermal events align with periods of abundant moisture. Thus, long-term changes in wildfire, limnology, and, to some extent, hydrothermal activity were governed by insolation-driven climate variations, whereas the vegetation response was muted and constrained by geologic processes. These findings suggest that warmer, drier conditions in the future could result in less hydrothermal activity yet little change in forest cover across the Yellowstone Plateau volcanic field despite more wildfires.

Idaho, Montana, Wyoming

Neutron scattering reveals fractionation of natural gas mixtures in unconventional petroleum reservoir pores: Perspectives on energy resource recovery and storage

In unconventional petroleum reservoirs hydrocarbon fluids are hosted by both mineral and organic matter pores. These pores can have diameters that range from microns to less than a single nanometer and, for unconventional reservoirs, there is evidence that small pores ( <20 nm diameter) may constitute a large proportion of the available space. Understanding subsurface volumes and how fluids behave in them can be helpful for predicting hydrocarbon production and storage in the subsurface. One area with knowledge gaps regarding hydrocarbon behavior in small pores is the possibility for mixtures to fractionate (i.e., unmix) based on pore size or pore type. Mixture fractionation as a function of pore size could impact recovery of hydrocarbons, drive compositional shifts during production, and limit fluid storage within candidate reservoirs. To investigate natural gas fractionation in small geologic pores, we applied total neutron scattering to probe methane-ethane mixtures at reservoir pressures (up to ≈30 MPa) and temperature (60°C) within a sample from the Upper Cretaceous Niobrara Formation. Neutron scattering data reveal only minor fractionation occurs between methane and ethane in 20-nm diameter sample mesopores. Increased fractionation is observed for sample micropores, with up to 72% (±1% at 1-sigma) methane found in 2 nm diameter pores following injection of a 50%-50% methane-ethane mixture. These data provide rarely available direct experimental observations of hydrocarbon mixture behavior under nanoconfinement in a sample from an important unconventional petroleum reservoir. Our results are discussed in the context of evaluating hydrocarbon resources in unconventional reservoir meso- and micropores, reconciling observed gas composition changes during production, and more broadly, understanding subsurface pore volumes within an energy storage framework.

Fuel

Nodal seismic deployment on Mauna Loa volcano, Hawaii: Dataset and preliminary insights

Mauna Loa is the largest active volcano on Earth, comprising ∼51% of the Island of Hawai‘i’s landmass and posing significant risks to the island’s communities, infrastructure, and natural environment. Historical eruptions have produced lava flows that have reached the ocean in as little as 3 hr. The timing and location of such lava flows in the past 200 yr underscore how critical determination of the location and geometry of magma storage and structure is for volcanic hazard assessment and eruption forecasting. Now, after nearly 38 yr of volcanic quiescence, Mauna Loa has erupted again. On 27 November 2022, fissures initiated within the summit caldera and then migrated to the northeast rift zone, where they generated a large lava flow that threatened a major highway. To improve our understanding of the geometry of this magma system, we deployed a temporary nodal array on Mauna Loa in the summer of 2024. This increased our seismic coverage sufficiently to image this magmatic system. This nodal array consists of 33 seismometers distributed on and around the volcano and was deployed for over three months to record seismic signals. The primary objective of this project is to resolve the high‐resolution seismic velocity structure and characterize seismic features associated with magma storage and ascent pathways. In this article, we present an overview of the deployment, evaluate the quality of the data, and show example recordings to evaluate the suitability of the data set for future seismic investigations, including earthquake relocation, seismic tomography, and receiver function analysis. Comparisons with nearby permanent broadband and short‐period seismic stations demonstrate that the nodal array recorded high‐quality waveforms, making it a valuable resource for constraining the magmatic system beneath Mauna Loa at multiple scales.

Hawaii