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2018 update to the U.S. Geological Survey national volcanic threat assessment

When erupting, all volcanoes pose a degree of risk to people and infrastructure, however, the risks are not equivalent from one volcano to another because of differences in eruptive style and geographic location. Assessing the relative threats posed by U.S. volcanoes identifies which volcanoes warrant the greatest risk-mitigation efforts by the U.S. Geological Survey and its partners. This update of the volcano threat assessment of Ewert and others (2005) considers new research in order to determine which volcanic systems should be added or removed from the list of potentially active volcanoes, updates the scoring of active volcanoes, and updates the 24-factor hazard and exposure matrix used to create the threat ranking. The threat assessment places volcanoes into five threat categories: very low, low, moderate, high, and very high. Within all five threat categories there are changes in relative rankings of volcanoes, and in a few cases, volcanoes moved between categories owing to changes in our understanding of their hazard, unrest, and exposure factors. Scorings of hazard factors were updated for some volcanoes where new research has identified Holocene eruptive activity or clarified our understanding of Holocene eruptive history and the occurrence of particular hazards such as tephra fall or pyroclastic density currents. The most numerous scoring changes made in the threat matrix since 2005 have been made among the hazard factors, particularly those accounting for observed eruptive activity or unrest. The very low threat category underwent the greatest amount of change, dropping from 32 to 21 volcanoes, owing to better knowledge of the eruptive histories of those volcanoes. The list of 18 very high threat volcanoes determined by Ewert and others (2005) remains the same; 11 of the 18 volcanoes are located in Washington, Oregon, or California, where explosive and often snow- and ice-covered edifices can project hazards long distances to densely populated and highly developed areas. Five of the 18 very high threat volcanoes are in Alaska near important population centers, economic infrastructure, or below busy air traffic corridors. The remaining two very high threat volcanoes are on the Island of Hawaiʻi, where densely populated and highly developed areas now exist on the flanks of highly active volcanoes. The high- and moderate-threat categories are dominated by Alaskan volcanoes. In these categories the generally more active and more explosive volcanoes in Alaska can have a substantial effect on national and international aviation, and large eruptions from any of the moderate- to very-high-threat volcanoes could cause regional or national-scale disasters. This revised threat assessment includes 18 very high threat, 39 high threat, 49 moderate threat, 34 low threat, and 21 very low threat volcanoes. The total of 161 volcanoes is a decrease of 8 from the total reported by Ewert and others (2005).

Scientific Investigations Report↗

Analyses of meteorological and hydrological records support Tribal members’ accounts of changing climate on the Fort Apache Reservation, east–central Arizona

The Fort Apache Reservation in east–central Arizona, home to the White Mountain Apache Tribe of the Fort Apache Reservation, Arizona, contains several climate zones because of the large variation in surface elevation within the reservation. This study was carried out in cooperation with the White Mountain Apache Tribe of the Fort Apache Reservation, Arizona, to raise awareness of how the changing climate affects the Fort Apache Reservation. This report documents the evaluation of existing multidecadal meteorological and hydrological datasets for the Fort Apache Reservation, used to evaluate the effects of a changing climate on the reservation. In this evaluation, near-surface air temperature, snow depth, snow water equivalent, precipitation, and streamflow datasets were analyzed for monotonic trends indicative of changing climatic conditions during specified periods of time. The results of these trend analyses were then compared with the Tribal community's memories of the changing climate. Trend analysis of near-surface air temperatures from a U.S. Historical Climatological Network station on the Fort Apache Reservation at Whiteriver, Arizona, indicated that mean annual air temperatures have increased by an average of 2.48 degrees Fahrenheit from 1980 to 2023. Records from the same station also indicated that average monthly maximum temperatures recorded for March increased by 5.39 degrees Fahrenheit for the same time period. Annual precipitation at the five precipitation stations used in this study decreased greatly from the 1980s to 2023. The largest total decrease was 10.07 inches, or 34.7 percent. However, only one of the two precipitation stations with longer term data available prior to 1980 had a significant negative trend when data from the entire period of record, from 1901 to 2023, were analyzed. Trend analyses show a decrease in the annual maximum snow water equivalent and an earlier disappearance of the snowpack at two Natural Resources Conservation Service snow telemetry stations in the mountainous region just east of the Fort Apache Reservation from 1981 to 2023. Based on the trend analyses, the average annual maximum snow water equivalent has decreased by more than 40 percent at both stations, and the average date when the snowpack was fully melted at the stations in the spring has moved earlier in time from late April to early April or late March. However, a statistically significant trend was not determined for the early April snow water equivalent measured at a nearby Natural Resources Conservation Service snow course across its period of record, indicating that the history of mountain snowpack in this area is not fully understood. Analysis of snowfall data from a National Oceanic and Atmospheric Administration Cooperative Observer Program network station on the Fort Apache Reservation at McNary 2N, AZ (station 025412) indicated that, on average, the measured total annual snowfall at the station decreased 42.4 percent from 1935 to 2023. Streamflow data from six U.S. Geological Survey streamgages on the Fort Apache Reservation were analyzed for trends. For most streamflow gages, statistically significant trends were not determined for tested parameters when the entire streamflow period of record was used for stations with records going back to at least the 1960s. However, when the data from 1980 to 2023 was tested, most of the streamflow parameters had statistically significant negative trends. All six streamgages showed a decrease in average annual runoff of at least 50 percent from 1980 to 2023; one streamgage showed an 81.8 percent decrease. A similar statistical finding was observed in the analysis of the annual spring snowmelt peak from one of the six streamgages used in the study and located in an area receiving measurable amounts of snowmelt runoff. When data from the entire period of record (1958–2023) was used, no trend in streamflow was determined; however, a significant negative trend was determined from 1980 to 2023, indicating a decrease in average annual springtime runoff of 62.6 percent. Statistical analysis on the timing of the annual spring snowmelt peak at the same streamgage indicated the snowmelt peak is happening on average about 12 days earlier now (2023) than it did in the past. The trend results for the timing of the annual spring snowmelt peak were the same and statistically significant for both periods tested (1958–2023 and 1980–2023). Two of the streamflow records from the Fort Apache Reservation were compared to the Palmer Hydrological Drought Index computed for Arizona Climate Division 4 (East Central) by the National Centers for Environmental Information. The comparison showed that the streamflow records generally tracked the Palmer Hydrological Drought Index. In interviews, Tribal community members living on the Fort Apache Reservation described the changes in climate that they observed during their lifetimes. Common themes reported were that air temperatures have become warmer, and the weather is less predictable with changes in seasonal patterns. Drier conditions, lower snowfall, shorter winters, and lower river levels were also reported. These community member observations align with the results of this study.

Arizona↗

Hydrology and water quality in the Nederlo Creek Basin, Wisconsin, before construction of two water-retention structures

The Nederlo Creek basin, in the "Driftless Area" of southwest Wisconsin, is geographically and hydrologically similar to other small basins in the area. Topography is rugged, with approximately 400 feet of relief between the boundary ridge tops and the valley floor. The water-retention structures (a dry floodwater- retention structure and a 43-acre reservoir) are to provide recreation and flood protection for the basin. Streamflow, springflow, precipitation, and groundwater levels were monitored at several sites to describe the hydrologic system. Streamflow is fairly constant at base flow, but rapid changes in discharge occur during periods of snowmelt or heavy rain; recession to base-flow discharge following these events is rapid. Surface runoff is a significant contributor to Streamflow only 10 percent of the time. The mean annual hydrologic budget for water years 1968-72 shows that of the 32.5 inches of precipitation on the basin, 6.4 inches left as runoff and 25.9 inches as evapotranspiration; ground-water storage increased an average of 0.2 inches per year. The water is a hard calcium magnesium bicarbonate type. Concentrations of major constituents in ground water and streams at base flow are similar, but concentrations in the stream generally decrease during periods when surface runoff contributes to Streamflow. Dissolved-oxygen concentrations in the stream are generally lowest during the summer; nighttime lows are generally between 7 and 8 milligrams per liter and daily maximums between 11 and 12.5 milligrams per liter. Diurnal water-temperature fluctuations of several degrees are common in streams during summer; daily maximum water temperatures as high as 26°C have been measured in some areas, but temperatures this high seldom persist for more than 2 hours. Estimates of mean annual total phosphorus and total nitrogen loads during 1967-74 fall within the ranges of 0.02 to 0.07 and 0.4 to 0.8 tons per square mile, respectively; 70 to 80 percent of the total phosphorus and 35 to 55 percent of the total nitrogen are transported during periods when surface runoff contributes to Streamflow. Mean annual suspended-sediment loads during 1968-74 range from 13 to 60 tons per square mile, with 74 to 86 percent of the total transported during periods when surface water contributes to streamflow. These sediment loads are at the low end of the range previously reported for streams in the "Driftless Area".

Wisconsin↗

Planning report for the Gulf Coast Regional Aquifer-System Analysis in the Gulf of Mexico coastal plain, United States

Large quantities of water for municipal, industrial and agriculture use are supplied from the aquifers in Tertiary and younger sediments over an area of about 225,000 square miles in the Coastal Plain of Alabama, Arkansas, Florida, Illinois, Kentucky, Louisiana, Mississippi, Missouri, Tennessee, and Texas. Three regional aquifer systems, the Mississippi Embayment aquifer system, the Coastal Lowlands aquifer system, and the Texas Coastal Uplands aquifer system have been developed to varying degrees throughout the area. A variety of problems has resulted from development such as movement of the saline-freshwater interface into parts of aquifers that were previously fresh, lowering of the potentiometric surface with resulting increases in pumping lift, and land-surface subsidence due to the compaction of clays within the aquifer. Increased demand for ground water is anticipated to meet the needs of urban growth, expanded energy development, and growth of irrigated agriculture. The U. S. Geological Survey initiated an eightyear study in 1981 to define the geohydrologic framework, describe the chemistry of the ground water, and to analyze the regional ground-water flow patterns. The objectives, plan, and organization of the study are described in this report and the major tasks to be undertaken are outlined.

Water-Resources Investigations Report↗

Development of a water-use data system in Minnesota

The Minnesota State Legislature passed laws as early as 1937 to regulate use of Minnesota's ground water and surface water through a permit system. Several unsuccessful attempts were made to computerize water-use data reported to the State. The U.S. Geological Survey, through the National Water-Use Information Program, assisted the Minnesota Department of Natural Resources and the Minnesota State Planning Agency, Land Management Information Center, in developing MWUDS (Minnesota Water-Use Data System). The Minnesota Water-Use Data System stores data on the quantity of individual annual water withdrawals and discharges in relation to the water resources affected, provides descriptors for aggregation of data and trend analysis, and enables access to additional data contained in other data bases. MWUDS is stored on a computer at the Land Management Information Center, an agency associated with the State Planning Agency. Interactive menu-driven programs simplify data entry, update, and retrieval and are easy to use. Estimates of unreported water use supplement reported water use to completely describe the stress on the hydrologic system. Links or common elements developed in the MWUDS enable access to data available in other State waterrelated data bases, forming a water-resource information system. Water-use information can be improved by developing methods for increasing accuracy of reported water use and refining methods for estimating unreported water use.

Water-Resources Investigations Report↗

Hydrology and water quality of East Lake Tohopekaliga, Osceola County, Florida

East Lake Tohopekaliga, one of the major lakes in central Florida, is located in the upper Kissimmee River basin in north-east Osceola County. It is one of numerous lakes in the upper basin used for flood control, in addition to recreation and some irrigation of surrounding pasture. This report is the fourth in a series of lake reconnaissance studies in the Kissimmee River basin prepared in cooperation with the South Florida Water Management District. The purpose of the report is to provide government agencies and the public with a brief summary of the lake 's hydrology and water quality. Site information is given and includes map number, site name, location, and type of data available (specific conductivity, pH, alkalinity, turbidity, color, dissolved oxygen, hardness, dissolved chlorides, dissolved sodium, dissolved calcium, dissolved magnesium, dissolved potassium, nitrogen, ammonia, nitrates, carbon and phosphorus). The U.S. Geological Survey (USGS) maintained a lake stage gaging station on East Lake Tohopekaliga from 1942 to 1968. The South Florida Water Management District has recorded lake stage since 1963. Periodic water quality samples have been collected from the lake by the South Florida Water Management District and USGS. Water quality and discharge data have been collected for one major tributary to the lake, Boggy Creek. Although few groundwater data are available for the study area, results of previous studies of the groundwater resources of Osceola County are included in this report. To supplement the water quality data for East Lake Tohopekaliga, water samples were collected at selected sites in November 1982 (dry season) and in August 1983 (rainy season). Samples were taken at inflow points, and in the lake, and vertical profiles of dissolved oxygen and temperature were measured in the lake. A water budget from an EPA report on the lake is also included. (Lantz-PTT)

Water-Resources Investigations Report↗

External quality-assurance results for the National Atmospheric Deposition Program and the National Trends Network during 1986

During 1986, the U.S. Geological Survey operated three programs to provide external quality-assurance monitoring of the National Atmospheric Deposition Program and National Trends Network. An intersite-comparison program was used to assess the accuracy of onsite pH and specific-conductance determinations at quarterly intervals. The blind-audit program was used to assess the effect of routine sample handling on the precision and bias of program and network wet-deposition data. Analytical results from four laboratories, which routinely analyze wet-deposition samples, were examined to determine if differences existed between laboratory analytical results and to provide estimates of the analytical precision of each laboratory. An average of 78 and 89 percent of the site operators participating in the intersite-comparison met the network goals for pH and specific conductance. A comparison of analytical values versus actual values for samples submitted as part of the blind-audit program indicated that analytical values were slightly but significantly (a = 0.01) larger than actual values for pH, magnesium, sodium, and sulfate; analytical values for specific conductance were slightly less than actual values. The decreased precision in the analyses of blind-audit samples when compared to interlaboratory studies indicates that a large amount of uncertainty in network deposition data may be a result of routine field operations. The results of the interlaboratory comparison study indicated that the magnitude of the difference between laboratory analyses was small for all analytes. Analyses of deionized, distilled water blanks by participating laboratories indicated that the laboratories had difficulty measuring analyte concentrations near their reported detection limits. (USGS)

Water-Resources Investigations Report↗

Analysis of ground-water-quality data of the Upper Colorado River basin, water years 1972-92

As part of the U.S. Geological Survey's National Water-Quality Assessment program, an analysis of the existing ground-water-quality data in the Upper Colorado River Basin study unit is necessary to provide information on the historic water-quality conditions. Analysis of the historical data provides information on the availability or lack of data and water-quality issues. The information gathered from the historical data will be used in the design of ground-water-quality studies in the basin. This report includes an analysis of the ground-water data (well and spring data) available for the Upper Colorado River Basin study unit from water years 1972 to 1992 for major cations and anions, metals and selected trace elements, and nutrients. The data used in the analysis of the ground-water quality in the Upper Colorado River Basin study unit were predominantly from the U.S. Geological Survey National Water Information System and the Colorado Department of Public Health and Environment data bases. A total of 212 sites representing alluvial aquifers and 187 sites representing bedrock aquifers were used in the analysis. The available data were not ideal for conducting a comprehensive basinwide water-quality assessment because of lack of sufficient geographical coverage. Evaluation of the ground-water data in the Upper Colorado River Basin study unit was based on the regional environmental setting, which describes the natural and human factors that can affect the water quality. In this report, the ground-water-quality information is evaluated on the basis of aquifers or potential aquifers (alluvial, Green River Formation, Mesaverde Group, Mancos Shale, Dakota Sandstone, Morrison Formation, Entrada Sandstone, Leadville Limestone, and Precambrian) and land-use classifications for alluvial aquifers. Most of the ground-water-quality data in the study unit were for major cations and anions and dissolved-solids concentrations. The aquifer with the highest median concentrations of major ions was the Mancos Shale. The U.S. Environmental Protection Agency secondary maximum contaminant level of 500 milligrams per liter for dissolved solids in drinking water was exceeded in about 75 percent of the samples from the Mancos Shale aquifer. The guideline by the Food and Agriculture Organization of the United States for irrigation water of 2,000 milligrams per liter was also exceeded by the median concentration from the Mancos Shale aquifer. For sulfate, the U.S. Environmental Protection Agency proposed maximum contaminant level of 500 milligrams per liter for drinking water was exceeded by the median concentration for the Mancos Shale aquifer. A total of 66 percent of the sites in the Mancos Shale aquifer exceeded the proposed maximum contaminant level. Metal and selected trace-element data were available for some sites, but most of these data also were below the detection limit. The median concentrations for iron for the selected aquifers and land-use classifications were below the U.S. Environmental Protection Agency secondary maximum contaminant level of 300 micrograms per liter in drinking water. Median concentration of manganese for the Mancos Shale exceeded the U.S. Environmental Protection Agency secondary maximum contaminant level of 50 micrograms per liter in drinking water. The highest selenium concentrations were in the alluvial aquifer and were associated with rangeland. However, about 22 percent of the selenium values from the Mancos Shale exceeded the U.S. Environmental Protection Agency maximum contaminant level of 50 micrograms per liter in drinking water. Few nutrient data were available for the study unit. The only nutrient species presented in this report were nitrate-plus-nitrite as nitrogen and orthophosphate. Median concentrations for nitrate-plus-nitrite as nitrogen were below the U.S. Environmental Protection Agency maximum contaminant level of 10 milligrams per liter in drinking water except for 0.02 percent of the sites in the alluvial aquifer and 0.03 percent of the sites in the Mancos Shale. Concentrations of orthophosphate did not vary significantly among aquifers or land-use classifications. Historic water-quality data from wells and springs helped to characterize the regional distribution of ground-water quality information in the Upper Colorado River Basin study unit. The historical ground-water data summarized in this report will be used in the design of a ground-water-quality network. Because ground-water-quality issues in the study unit are related to high dissolved solids, sulfate, selenium, and nutrients, this report discusses some of the important findings related to these issues.

Colorado↗

Estimating transmissivity and storage properties from aquifer tests in the Southern Lihue Basin, Kauai, Hawaii

Three to four different analysis methods were applied to the drawdown or recovery data from five constant-rate aquifer tests of 2 to 7 days in length to estimate transmissivity of rocks in the southern Lihue basin, Kauai, Hawaii. The wells penetrate rocks of the Koloa Volcanics and the underlying Waimea Canyon Basalt. Because the wells are located far apart and in previously unexplored areas, it is difficult to accurately define the aquifer or aquifers penetrated by the wells. Therefore, the aquifer tests were analyzed using a variety of curve-matching methods and only a range of possible values of transmissivity were determined. The results of a multiple-well aquifer test are similar to a single-well aquifer test done in the same area indicating that the single-well aquifer-test results are reasonable. The results show that transmissivity in the Lihue basin ranges over several orders of magnitude, 42 to 7,900 square feet per day, but is generally lower than reported values of transmissivity of other basaltic aquifers in Hawaii. Estimates of confined-aquifer storage coefficient range from 1.3x10 -4 to 8.2x10 -2 . The hydraulic conductivity estimates obtained using an elliptical-equation method compare favorably with the results obtained from the generally more-accepted curvematching methods. No significant difference is apparent between the estimated transmissivity of the Koloa Volcanics and the Waimea Canyon Basalt in the study area. An analysis of the lithology penetrated by the wells indicates the transmissivity is probably controlled mainly by the stratigraphic position of the layers penetrated by the well. The range of transmissivity values estimated for the southern Lihue basin is lower than reported values from aquifer tests at wells penetrating postshield-stage or rejuvenation-stage lava flows on other Hawaiian islands. This range is one to four orders of magnitude lower than most reported values for dike-free basalt aquifers in Hawaii.

Hawai'i↗

Interpretation of dye tracing data collected November 13–December 2, 2017, at the Savoy Experimental Watershed as part of the Advanced Groundwater Field Techniques in Karst Terrains course, Savoy, Arkansas

The first course on the use of advanced groundwater field techniques for karst aquifers was conducted November 13–17, 2017, at the University of Arkansas Savoy Experimental Watershed (SEW), which is located on pastures for beef livestock research conducted by the Department of Animal Sciences at the University of Arkansas at Savoy, Arkansas. The SEW is an interdisciplinary, collaborative, long-term research site for the study of animal-waste management in a mantled karst setting. The course focused on advanced field activities appropriate for karst aquifer studies: dye tracing, groundwater/surface-water interactions, geophysical methods, and geochemistry. This report summarizes the data collected and interpreted from the dye tracing part of the November 2017 course, other USGS field courses, and past dye tracing investigations conducted by University of Arkansas students.

Arkansas↗

Geohydrology and water quality of Marine Corps Logistics Base, Nebo and Yermo annexes, near Barstow, California

Because ground water is the only dependable source of water in the Barstow area, a thorough understanding of the relationship between the geology and hydrology of this area is needed to make informed ground-water management andremediation decisions. This report summarizes geologic and hydrologic studies done during 1992-95 at the Marine Corps Logistics Base, Nebo and Yermo Annexes, near Barstow, California. The geologic investigation dealt with the stratigraphy and geologic history of the area and determined the location of faults that cross the Marine Corps Logistics Base, Nebo Annex. Two of these faultscoincide with significant ground-water barriers. Geologic and hydrologic data collected for this study were used to define two main aquifer systems in this area. The Mojave River aquifer is contained within the sand and gravel of the Mojave River alluvium, and the regional aquifer lies in the bordering alluvial-fan deposits and older alluvium. Water-level data showed that recharge occurs exten sively in the Mojave River aquifer but occurs only in small areas of the regional aquifer. Dissolved- solids concentrations showed that ground-water degradation exists in the Mojave River aquifer near the Nebo Annex and extends at least 1 mile downgradient of the Nebo golf course in the younger Mojave River alluvium. Nitrogen concentrations show that more than one source is causing the observed degradation in the Mojave River aquifer. Oxygen-18, deuterium, tritium, andcarbon-14 data indicate that the Mojave River and regional aquifers have different sources of recharge and that recent recharge occurs in the Mojave River aquifer but is more limited in the regional aquifer.

Water-Resources Investigations Report↗

Distribution of major herbicides in ground water of the United States

Information on the concentrations and spatial distributions of pesticides and their transformation products, or degradates, in the hydrologic system is essential for managing pesticide use in both agricultural and nonagricultural settings to protect water resources. This report examines the occurrence of selected herbicides and their degradates in ground water, primarily on the basis of results from two large-scale, multistate investigations by the U.S. Geological Survey&mdash;the National Water-Quality Assessment (NAWQA) Program and the Midwest Pesticide Study (MWPS). The NAWQA pesticide data were derived from 2,227 sites (wells and springs) sampled in 20 major hydrologic basins across the United States from 1993 to 1995; the MWPS data were obtained from the sampling of 303 wells in a 12-state area of the northern midcontinent from 1991 to 1994. Data are presented for seven high-use herbicides: five of current interest to the U.S. Environmental Protection Agency for designing Pesticide Management Plans (atrazine, cyanazine, simazine, alachlor and metolachlor), a largely nonagricultural herbicide (prometon), and an agricultural herbicide first registered in 1994 for use in the United States (acetochlor). Six of the herbicides (all except acetochlor) were detected by the U.S. Geological Survey studies in shallow ground water&mdash;that is, ground water recharged within the past 10 years&mdash;in a variety of agricultural and nonagricultural settings, as well as in several aquifers that are sources of drinking-water supply. Acetochlor was not detected by the MWPS in the summer of 1994, but was detected in shallow ground water during the NAWQA Program by early 1995, and during another U.S. Geological Survey study in Iowa during the summers of 1995 and 1996. The acetochlor observations suggest that, in agreement with results from previous field studies, some pesticides may be detected in shallow ground water within 1 year following their application. In accord with the results from other largescale multistate studies of pesticides in ground water, more than 98 percent of the detections during the NAWQA and MWPS investigations were at concentrations of less than 1 microgram per liter. Consequently, water quality criteria for drinking water&mdash;that is, standards established to protect human health&mdash;were exceeded at fewer than 0.1 percent of the sites sampled by NAWQA (all of these exceedances involving atrazine alone) and at none of those sampled in 1992 by the MWPS. These criteria, however, may not accurately reflect the overall health risks associated with pesticide detections in water resources because they have been established only for a relatively small number of pesticides and they do not account for the additive or synergistic effects of mixtures, impacts on the health of aquatic ecosystems, or the effects of pesticide degradates. Among the sites sampled during the NAWQA and MWPS investigations, 19.7 and 13.8 percent, respectively, had detections of two or more of the herbicides of interest. Furthermore, for most of the herbicides for which degradates were examined, detection frequencies for major degradates were typically higher than for their respective parent compounds, particularly for the herbicides that are less persistent in aerobic soil. Frequencies of detection at or above 0.01 microgram per liter in shallow ground water beneath agricultural areas during the NAWQA study were significantly correlated with agricultural use in those areas for atrazine, cyanazine, alachlor, and metolachlor (P<0.05; Spearman rank correlations), but not for simazine (P>0.05). In urban areas, overall frequencies of detection of these five herbicides in shallow ground water were positively correlated with their total nonagricultural use nationwide (P=0.026; simple linear correlation). Multivariate statistical analysis indicated that frequencies of detection in shallow ground water beneath agricultural areas were positively correlated with half-lives for transformation in aerobic soil and agricultural use of the compounds (P&le;0.0001 for both parameters). Although frequencies of detection were not significantly correlated with their subsurface mobility (K oc ; P=0.19) or the median well depths of the sampled networks (P=0.72), the range of K oc values among the five herbicides and the range of well depths were limited.

Water-Resources Investigations Report↗

Field tests of nylon-screen diffusion samplers and pushpoint samplers for detection of metals in sediment pore water, Ashland and Clinton, Massachusetts, 2003

Efficient and economical screening methods are needed to detect and to determine the approximate concentrations of potentially toxic trace-element metals in shallow groundwater- discharge areas (pore water) where the metals may pose threats to aquatic organisms; such areas are likely to be near hazardous-waste sites. Pushpoint and nylon-screen diffusion samplers are two complementary options for use in such environments. The pushpoint sampler, a simple well point, is easy to insert manually and to use. Only 1 day is required to collect samples. The nylon-screen diffusion sampler is well suited for use in sediments that do not allow a pump to draw water into a pushpoint sampler. In this study, both types of devices were used in sediments suitable for the use of the pushpoint sampler. Sampling with the nylon-screen diffusion sampler requires at least two site visits: one to deploy the samplers in the sediment, and a second to retrieve the samplers and collect the samples after a predetermined equilibration period. Extensive laboratory quality-control studies, field testing, and laboratory analysis of samples collected at the Nyanza Chemical Waste Dump Superfund site along the Sudbury River in Ashland, Massachusetts, and at a Superfund site-assessment location on Rigby Brook in Clinton, Massachusetts, indicate that these two devices yield comparable results for most metals and should be effective tools for pore-water studies. The nylon-screen diffusion samplers equilibrated within 1-2 days in homogeneous, controlled conditions in the laboratory. Nylon-screen diffusion samplers that were not purged of dissolved oxygen prior to deployment yielded results similar to those that were purged. Further testing of the nylon-screen diffusion samplers in homogeneous media would help to resolve any ambiguities about the data variability from the field studies. Comparison of data from replicate samples taken in both study areas shows that even samples taken from sites within a half-meter radius of one another have distinct differences in pore-water trace-element concentrations. Sequential replicate samples collected with the pushpoint sampler yield consistent results; moving the pushpoint sampler even 5 to 10 centimeters, however, generally produces a second set of data that differs enough from the first set of data to indicate a heterogeneous environment. High concentration biases for barium and zinc in laboratory and field samples collected with nylon-screen diffusion samplers, however, may make their use inappropriate for studies of these metals. Analyzing samples with high iron concentrations required sample dilution by factors of 2 or 10. Because these dilutions caused increases in the reporting levels by the same proportion, a substantial fraction of the data was censored. The results from undiluted samples, however, indicate that both devices should be useful for sampling ground water with metal concentrations close to reporting limits.

Scientific Investigations Report↗