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The use of fluorite geochemistry and machine learning to identify critical mineral systems

Fluorite (CaF 2 ) is a potential pathfinder to critical mineral and rare earth element (REE) deposits but its application has been limited to a narrow range of mineralization types. I show that fluorite is a robust recorder of mineralization fertility by applying statistical and machine-learning methods to a new global fluorite geochemical database. Distinct median rare earth and trace element patterns are observed among deposit types and genetic environments. Fluorite associated with carbonatites and REE deposits are relatively enriched in Sr and have minimal Eu anomalies. These characteristics define new bivariate discrimination diagrams that correctly identify 78% of carbonatite-related fluorite and 88% of fluorite from REE deposits. Random forest classifiers were developed for a wide range of mineralization types and genetic settings. Trained solely on rare earth element patterns, these models achieve accuracies of 77–79%. Higher classification accuracies (up to 88–96%) are obtained when including elements such as Sr, highlighting the significance of trace elements for optimal fluorite classification. The recognition of diagnostic fluorite compositional fingerprints, particularly in REE-fertile systems, underscores its potential as a pathfinder and indicator for critical mineral exploration in F-bearing environments.

Mineralium Deposita

Extracting data from maps: Lessons learned from the artificial intelligence for critical mineral assessment competition

The U.S. Geological Survey (USGS), Defense Advanced Projects Research Agency (DARPA), NASA Jet Propulsion Laboratory (JPL), and MITRE ran a 12-week machine learning competition aimed at accelerating development of AI tools for critical mineral assessments. The Artificial Intelligence for Critical Mineral Assessment Competition solicited innovative solutions for two challenges: 1) automated georeferencing of historical maps, and 2) automated feature extraction from historical maps. Competitors used a new dataset of historical map images to train, validate, and evaluate their models. Automated georeferencing pipelines attained a median root-mean square error of 1.1 km. Prompt-based extraction (i.e., with user input) of polygons, polylines, and points from geologic maps yielded median F1-scores of 0.77, 0.56, 0.35, respectively. Geologic maps pose numerous challenges for AI workflows because they vary significantly. However, despite its short duration, the competition yielded promising results that have since spurred further innovation in this area and led to the development of new AI tools to semi-automate key, time-consuming parts of the assessment workflow.

Applied Computing and Geosciences

The Europa Imaging System (EIS) investigation

The Europa Imaging System (EIS) consists of a Narrow-Angle Camera (NAC) and a Wide-Angle Camera (WAC) that are designed to work together to address high-priority science objectives regarding Europa’s geology, composition, and the nature of its ice shell. EIS accommodates variable geometry and illumination during rapid, low-altitude flybys with both framing and pushbroom imaging capability using rapid-readout, 8-megapixel (4k × 2k) detectors. Color observations are acquired using pushbroom imaging with up to six broadband filters. The data processing units (DPUs) perform digital time delay integration (TDI) to enhance signal-to-noise ratios and use readout strategies to measure and correct spacecraft jitter. The NAC has a 2.3° × 1.2° field of view (FOV) with a 10-μrad instantaneous FOV (IFOV), thus achieving 0.5-m pixel scale over a swath that is 2 km wide and several km long from a range of 50 km. The NAC is mounted on a 2-axis gimbal, ±30° cross- and along-track, that enables independent targeting and near-global (≥90%) mapping of Europa at ≤100-m pixel scale (to date, only ∼15% of Europa has been imaged at ≤900 m/pixel), as well as stereo imaging from as close as 50-km altitude to generate digital terrain models (DTMs) with ≤4-m ground sample distance (GSD) and ≤0.5-m vertical precision. The NAC will also perform observations at long range to search for potential erupting plumes, achieving 10-km pixel scale at a distance of one million kilometers. The WAC has a 48° × 24° FOV with a 218-μrad IFOV, achieving 11-m pixel scale at the center of a 44-km-wide swath from a range of 50 km, and generating DTMs with 32-m GSD and ≤4-m vertical precision. The WAC is designed to acquire three-line pushbroom stereo and color swaths along flyby ground-tracks.

Space Science Reviews

Methodology for inclusion of produced and stored carbon dioxide in the U.S. Geological Survey Federal lands greenhouse gas inventory

The U.S. Geological Survey (USGS) has developed two new carbon dioxide (CO2) emissions and sequestration accounting methods for use in future reports. The first method is a Federal lease-produced CO2 emissions calculation for an update of the report, “Federal Lands Greenhouse Gas Emissions and Sequestration in the United States.” The methodology to incorporate Federal lease CO2 production emissions into the updated report relies on CO2 sales royalty data from the Office of Natural Resources Revenue (ONRR). The end usage points for the gas include enhanced oil recovery with CO2 (CO2-EOR), food and beverage, and chemical production. CO2-EOR is the main end point for natural CO2 production in the United States; it accounted for 94% of usage in 2022 [1]. Federal lands emissions from this sector are estimated at 460 metric tons of CO2 in 2022, a very small amount relative to most other Federal lands emissions sector estimates. The second new method, planned for a separate report, is a calculation of the geologic storage of CO2 on Federal lands. The second method estimates the CO2 stored under Federal surface lands and documents Federal climate change mitigation efforts. Currently, there is no storage of CO2 at an industrial level on Federal lands, however multiple proposals and projects are planned. This method was developed on non-Federal lands datasets in an effort to prepare for when these activities on Federal lands will require accounting. National estimates for CO2 geologic storage using this method, but without a Federal lands filtering step, totaled 8.0 million metric tons (Mt) in 2022. The two methods described here are new benchmark methods in a collection of accounting procedures to document the current state of greenhouse gas emissions and their storage on Federal lands. These benchmarks can then be used to measure any subsequent changes in emissions from or carbon storage beneath Federal lands. While the magnitude of the values is currently non-existent to small, emissions mitigation goals established by decision makers indicate that these values will grow, and their documentation will take on greater value and use.

continental United States

Exploration for blind geothermal systems in the eastern Great Basin of Utah: An update on the “Lund North” INGENIOUS detailed study site

Existing geothermal production in Utah is commonly collocated with surficial expressions of geothermal heat including active hot springs and hot spring deposits. However, geothermal potential across the Great Basin region is thought to be much higher for hidden or blind geothermal systems. Accordingly, exploration techniques that can locate geothermal resources that lack surface thermal features could support future development of these systems. The goal of the INGENIOUS project is to reduce exploration risk and discover new, economically viable hidden geothermal systems in the Great Basin region. This paper summarizes the efforts and preliminary results of blind geothermal resource prospecting in Utah as part of the larger INGENIOUS project. The Lund North site in the Basin and Range province of southwest Utah was designated as the fourth detailed study site for the project. The site was initially identified from the preliminary Play Fairway Analysis (PFA) geothermal favorability map, which is based on various data elements, and the identification of favorable structural settings across Utah. This site contains existing legacy data including a thermal gradient borehole with a heat-flow value exceeding 220 mW/m 2 . New data collected at this site include terrestrial gravity, magnetotellurics, transient electromagnetics, fluid geochemistry, geologic mapping, UAV-based lidar, paleomagnetism, aeromagnetic surveys, and a shallow temperature survey. Preliminary data and model interpretations corroborate the presence of a large, east-dipping, northeast-southwest-trending normal fault on the edge of a typical Basin and Range graben. Quaternary fault mapping refined by high-resolution lidar surveys suggests a complex step over fault geometry. Utilizing multi-disciplinary datasets for further site assessment at Lund North will facilitate the development of a local-scale PFA and geothermal conceptual model. This new data will be used to site successive thermal gradient drilling to verify heat flow with temperatures at depth at the Lund North site and further investigate the existence of a local geothermal system.

Utah

Stratigraphic notes—Volume 1, 2022

This is the first volume in the U.S. Geological Survey (USGS) series of reports on stratigraphy entitled “Stratigraphic Notes,” which consists of short papers that highlight stratigraphic studies, changes in stratigraphic nomenclature, and explanations of stratigraphic names and concepts used on published geologic maps. “Stratigraphic Notes” is a long-term (multiyear), multivolume publication containing articles that address updates or revisions to stratigraphic nomenclature (and whose content ultimately will be incorporated by National Geologic Map Database personnel into Geolex, https://ngmdb.usgs.gov/Geolex/ ). We welcome papers for the “Stratigraphic Notes” series from geoscientists of the USGS, of State Geological Surveys, and from academicians. Papers can be submitted for publication in “Stratigraphic Notes” by contacting the USGS Geologic Names Committee ( gnc@usgs.gov ). As new “Stratigraphic Notes” volumes are published, links to the volumes will be posted at https://doi.org/10.3133/pp1879 . This first volume ("Stratigraphic notes—Volume 1, 2022") includes articles that provide guidance for those who wish to submit papers to “Stratigraphic Notes,” as well as information on how to make your manuscripts compliant for geologic names reviews and how to organize your paper’s content to facilitate inclusion of new or revised names in Geolex. This volume also includes some specific guidance on conducting geologic names reviews of geologic and hydrogeologic reports.

Professional Paper

SlideDetect: Spatio-temporal landslide detection using a three-dimensional convolutional neural network

Landslides pose a serious and ongoing threat to both human lives and infrastructure worldwide; therefore, it is of interest to predict where and when landslides are likely to occur. Advances in machine learning techniques have spurred numerous studies aimed at estimating relative landslide propensity, but are limited to spatial (as opposed to temporal) prediction due to the sparsity of landslide timing data. We address this data gap by training SlideDetect, a 3-dimensional convolutional neural network (3D CNN), to identify landslides based on their spatial and temporal occurrence within multitemporal image stacks. We use an inventory of landsides triggered by the 2018 Hokkaido earthquake and two years of monthly composite optical imagery spanning this event. The model can identify not only landslide location but also landslide date with an area under the precision-recall curve (PR-AUC) of 0.84. We further present a new standard for presenting PR curve results that explicitly compares model performance at different confidence thresholds, allowing for clearer model evaluation and comparison. Our new approach to constraining landslide timing paired with this more consistent and objective method for evaluating model performance shows considerable promise, and with further application and testing, SlideDetect could enhance the data availability and tools needed to advance landslide hazard and risk assessments.

JGR Machine Learning and Computation

A method to obtain remotely sensed grain size distributions from nonplanar granular deposits

Constraining the grain size distribution of granular deposits with complex surfaces is difficult with existing approaches. Field and laboratory techniques are time consuming and limited by the maximum grain size that laboratories can accommodate. In this study, we present a new method to identify the coarse fraction of the grain size distribution at a debris-flow fan deposit surveyed with terrestrial laser scanning (TLS) in Glenwood Canyon, Colorado, USA. This method is a novel grain segmentation algorithm developed for application to point cloud data of deposits with complex surfaces and angular grains ranging in size from centimeters to a meter. This approach combines an existing random forest machine learning method with a novel iterative clustering algorithm. We compared the grain size distribution from our algorithm with a Wolman pebble count conducted in the field, and found a root mean squared error of less than 2 cm from the 5th to 95th percentile of the grain size distribution of grains ranging from cobble to boulder sized (6.3–78 cm in our application). Finally, we compared our new algorithm with an existing open-source grain segregation algorithm, and our method outperformed the selected alternative when applied to the debris-flow deposit point cloud.

Colorado

Unlocking ecological insights from sub-seasonal visible-to-shortwave infrared imaging spectroscopy: The SHIFT campaign

We stand at the threshold of a transformative era in Earth observation, marked by space-borne visible-to-shortwave infrared (VSWIR) imaging spectrometers that promise consistent global observations of ecosystem function, phenology, and inter- and intra-annual change. However, the full value of repeat spectroscopy, the information embedded within different temporal scales, and the reliability of existing algorithms across diverse ecosystem types and vegetation phenophases have remained elusive due to the absence of suitable sub-seasonal spectroscopy data. In response, the Surface Biology and Geology (SBG) High-Frequency Time Series (SHIFT) campaign was initiated during late February 2022 in Santa Barbara County, California. SHIFT, designed to support NASA's SBG mission, addressed mission scoping, scientific advancement, applications development, and community building. This ambitious endeavor included weekly Airborne Visible InfraRed Imaging Spectrometer-Next Generation (AVIRIS-NG) imagery acquisitions for 13 weeks (spanning February 24 to May 29, 2022), accompanied by coordinated terrestrial vegetation and coastal aquatic data collection. We describe the rich datasets collected and illustrate how the complex sub-seasonal patterns of change can be linked to biological science and applications, surpassing insights from multispectral observations. Leveraging open-source processing methods and cloud-based analysis tools, the SHIFT campaign showcases the readiness of the scientific community to harness ecological insights from remotely sensed hyperspectral time series. We provide an overview of SHIFT's goals, data collections, preliminary results, and the collaborative efforts of early career scientists committed to unlocking the transformative potential of high-frequency time series data from space-borne VSWIR imaging spectrometers.

Ecosphere

The damability function: A probabilistic approach to regional landslide dam susceptibility analysis applied to the Oregon Coast Range, USA

Landslides can dam rivers and require rapid response to mitigate catastrophic outburst floods. Here, we present a workflow to map landslide dam formation susceptibility at a regional scale. We define a probabilistic function that combines river valley width and landslide volume to efficiently determine the likelihood of a landslide dam or “damability”. We combine damability values with landslide susceptibility to estimate landslide dam susceptibility. The valley width measurements are automated using a new elevation threshold-based algorithm. Landslide volume is represented as a statistical distribution from mapped landslides. We validate and apply our approach to the Oregon Coast Range, USA and find that 36 % of river stretches exceed a dam potential threshold; these are in river headwaters and steeper terrain, which in this case correlate with more resistant lithologies. We also estimate volumes of the potential dammed lakes and find that most rivers with high dam susceptibility are less likely to impound large lakes because they have low drainage areas. However, widespread susceptibility, and the potential impacts from exceptionally large landslides, suggest that this hazard should be considered in the Pacific Northwest. The damability function workflow can ingest new data and be applied more broadly to assess future landslide dam hazards.

Oregon

Prospectivity mapping for geologic hydrogen

Geologic, or naturally occurring, hydrogen has the potential to become a new, low-carbon, primary energy resource. Often referred to as “white” or “gold” hydrogen, this gas occurs naturally in the Earth’s subsurface, similar to petroleum resources. However, unlike petroleum, which releases carbon dioxide when burned, burning hydrogen only produces water as a byproduct. Exploration for geologic hydrogen remains in an early stage and discoveries of high concentrations of subsurface hydrogen are still relatively rare. To facilitate research and exploration for this potential resource, this report presents the first publicly available prospectivity map of geologic hydrogen accumulations in the conterminous United States. Prospective regions are those regions in which all major components necessary for a hydrogen accumulation likely are present—a source of sufficient hydrogen generation, porous reservoirs for storage, and seals to prevent leakage. The midcontinent region of the United States and the central California coast are revealed as having high prospectivity. This analysis also identifies previously unrecognized prospective regions that may be favorable due to long distance lateral migration of subsurface hydrogen, such as the offshore eastern seaboard of the United States, and can provide a linkage between surface observations of hydrogen degassing and far-field source regions. The methodology developed to create this map is expandable and flexible and may be adapted to incorporate new concepts in the hydrogen system and for application to other regions of the world.

conterminous United States

Environmental setting and water-quality issues in the lower Tennessee River basin

The goals of the National Water-Quality Assessment Program are to describe current water-quality conditions for a large part of the Nation's water resources, identify water-quality changes over time, and identify the primary natural and human factors that affect water quality. The lower Tennessee River Basin is one of 59 river basins selected for study. The water-quality assessment of the lower Tennessee River Basin study unit began in 1997. The lower Tennessee River Basin study unit encompasses an area of about 19,500 square miles and extends from Chattanooga, Tennessee, to Paducah, Kentucky. The study unit had a population of about 1.5 million people in 1995. The study unit was subdivided into subunits with relatively homogeneous geology and physiography. Subdivision of the study unit creates a framework to assess the effects of natural and cultural settings on water quality. Nine subunits were delineated in the study unit; their boundaries generally coincide with level III and level IV ecoregion boundaries. The nine subunits are the Coastal Plain, Transition, Western Highland Rim, Outer Nashville Basin, Inner Nashville Basin, Eastern Highland Rim, Plateau Escarpment and Valleys, Cumberland Plateau, and Valley and Ridge.The lower Tennessee River Basin consists of predominantly forest (51 percent) and agricultural land (40 percent). Activities related to agricultural land use, therefore, are the primary cultural factors likely to have a widespread effect on surface- and ground-water quality in the study unit. Inputs of total nitrogen and phosphorus from agricultural activities in 1992 were about 161,000 and 37,900 tons, respectively. About 3.7 million pounds (active ingredient) of pesticides was applied to crops in the lower Tennessee River Basin in 1992. State water-quality agencies identified nutrient enrichment and pathogens as water-quality issues affecting both surface and ground water in the lower Tennessee River Basin. Water-quality data collected by State and Federal agencies between 1980 and 1996 were summarized to characterize surface- and ground-water quality of the subunits with respect to these issues. Median concentrations of nitrogen species generally were less than 1 milligram per liter in surface and ground water in all subunits, and were highest throughout the subunits that had the largest percentages of agricultural land use. Median phosphorus concentrations also were less than 1 milligram per liter in all subunits. Phosphatic limestones present in two subunits had a larger effect on phosphorus concentrations in surface and ground water than did the amount of agricultural land use in these subunits. Median counts of fecal coliform were higher in surface water than in ground water in all subunits. The highest median counts in surface water were in the Valley and Ridge (7,500 colonies per 100 milliliters) and the Outer Nashville Basin subunits (5,000 colonies per 100 milliliters). Highest median counts in ground water were in the Inner and Outer Nashville Basin subunit. Natural setting likely has an important effect with respect to fecal contamination of surface and ground water in the lower Tennessee River Basin.

Alabama, Georgia, Kentucky, Mississippi, Tennessee

Parsimonious high-resolution landslide susceptibility modeling at continental scales

Landslide susceptibility maps are fundamental tools for risk reduction, but the coarse resolution of current continental-scale models is insufficient for local application. Complex relations between topographic and environmental attributes characterizing landslide susceptibility at local scales are not transferrable across areas without landslide data. Existing maps with multiple susceptibility classifications under-represent landslide potential in moderate and gently sloping terrain. We leverage an extensive landslide database ( N = 613,724), a high-resolution digital elevation model (10-m), and high-performance computing resources, to develop a new nationwide susceptibility map for the contiguous United States, Hawaii, Alaska, and Puerto Rico. We calculate four alternative linear and nonlinear thresholds of topographic slope and relief using an objective split-sample calibration. We down-sample our results to a 90-m grid to account for uncertainty in the digital elevation model and landslide position, and evaluate these thresholds' ability to differentiate areas of greater susceptibility. The less conservative nonlinear model optimally balances our priorities of capturing observed landslides (99%) while minimizing area covered by susceptible terrain (43%). Independent evaluation with four statewide landslide inventories ( N = 172,367) reinforces our model selection but highlights spatially variable performance. Therefore, we propose a novel approach to susceptibility classification using the concentration of landslide-prone terrain within each down-sampled grid. While landslides are possible within any cells containing susceptible terrain, those with the highest concentration capture the majority of observed landslides. Our new map characterizes landside susceptibility more consistently than prior models; our transparent classification approach also provides flexibility for accommodating different tolerances in risk reduction measures.

AGU Advances

Widespread landslide activity in an extreme wet season and implications for regional sediment management, eastern San Francisco Bay area, California

Watershed sediment production is expected to increase in a warmer future with more extreme rain, with cascading effects throughout drainage and sediment-transport networks. This study investigated landscape-scale sediment movement in the eastern San Francisco Bay area, California, USA, during the extreme 2016–2017 wet season that brought major rainfall, landslides, and flooding. Mapping 8,928 landslides across a 1,050-km 2 study area revealed new sediment yield of 510–956 t/km 2 , equivalent to denudation of 193–361 mm/ky. These results correspond closely to long-term denudation rates in the northern and central California Coast Ranges, indicating that mass wasting in very wet years dominates long-term sediment mobilization. However, due to long residence times in drainage networks, the 2017 landslides contributed at most ∼1%–2% of the estimated locally derived fluvial sediment transport to San Francisco Bay. Although the amount of sediment mobilized did not threaten municipal water supplies, small rangeland impoundments in this mixed-use landscape lost storage capacity to new sedimentation. Considering regional sediment supply and demand, even the exceptionally large sediment delivery in an extreme wet year cannot meet the need for sediment to accrete tidal wetlands in the bay. To keep pace with rising sea levels, this abnormally high terrestrial sediment input would need to occur in 50 of the next 75 years, an unlikely occurrence due to the prevalence of recent drought years. Shoreline protection and restoration in the bay would need additional sources of sediment, such as through management of dredged sediment through beneficial-reuse programs.

California

The 3D National Topography Model Call for Action—Part 2: The Next Generation 3D Elevation Program

The three-dimensional (3D) National Topography Model initiative to integrate elevation and hydrography data includes the next generation of hydrography data from the 3D Hydrography Program and the next generation of elevation data from the 3D Elevation Program (3DEP). The first-ever collection of light detection and ranging (lidar) data for the nation (IfSAR for Alaska) provides a critical baseline reference, and the addition of multiple repeat elevation mapping projects as part of the next generation of 3DEP would substantially expand analysis capabilities. As the U.S. Geological Survey (USGS) is closing in on our goal of complete coverage with 3DEP data available or in progress for 98.3 percent of the Nation at the end of fiscal year 2024, the USGS is already transitioning to the next generation of 3DEP. Based on the 3D Nation Study results and input from a broad range of stakeholders, the USGS National Geospatial Program has finalized a new design for 3DEP that provides increased lidar quality levels and refresh rates. The new program is designed with more flexibility to meet changing user needs and take advantage of improvements in mapping technologies. The program will aim to expand the level of interagency coordination for topobathymetric lidar acquisition for inland rivers. The next generation of 3DEP will also aim to emphasize research, including advancing program design, products, and services and engaging and leveraging the evolving 3D industry. Research goals also include becoming more flexible in meeting user needs and taking advantage of evolving remote-sensing technologies. The program also plans to move from focusing on producing standard products to producing a concept of a 3D Nation Ecosystem with a variety of inputs, products, and services.

Circular

Monazite and xenotime U-Pb geochronology and thermometry of the Blue Ridge and Inner Piedmont of North Carolina: Implications for the thermal-metamorphic evolution of the southern Appalachian metamorphic “core”

The southern Appalachian orogen preserves a complex distribution of metamorphism and deformation varying in timing, magnitude, and spatial extent. These complexities give rise to disparate interpretations for southern Appalachian tectonic evolution, which complicates the testing and interpretation of tectonic models in this system. New monazite (Mnz) and xenotime (Xtm) laser ablation split stream (LASS) analyses alongside Mnz-Xtm thermometry in the orogenic core in the eastern Blue Ridge (EBR), western Inner Piedmont (WIP), and Cat Square terranes (CST) of North Carolina yield new constraints that define distinct pro- and retrograde metamorphic events. The EBR preserves two prograde thermal events: the Taconic (∼470-440 Ma, >660°C) and Neoacadian (∼380-340 Ma, 600–700°C), separated by a period of cooling (exhumation?) and followed by garnet breakdown from 339 to 329 Ma. Evidence of pervasive Neoacadian ductile deformation in the EBR is largely limited to the Brevard fault zone (BFZ), indicating that a major rheological gradient existed across the BFZ during the Neoacadian and early Alleghanian. Southeast of the BFZ, in the WIP and CST, monazite data define a protracted Neoacadian evolution from early mineral growth at ∼405 Ma at ∼450–600°C to >700°C at ∼360 Ma, followed by early Alleghanian retrograde metamorphism and deformation (<345 Ma, 350–500°C). These constraints, together with previously reported thermobarometric data, define a P-T-t evolution for the WIP and CST consistent with Neoacadian crustal flow, while the coeval presence of a thermal-rheological boundary along the BFZ further supports a model of Neoacadian crustal “escape” flow within the orogen.

North Carolina

Completion summary for monitor wells NRF-17 and NRF-18 at the Naval Reactors Facility, Idaho National Laboratory, Idaho

The U.S. Geological Survey (USGS)—in cooperation with the U.S. Department of Energy (DOE) for the Naval Reactors Laboratory Field Office that supports operations for the Naval Reactors Facility (NRF) located at the Idaho National Laboratory (INL)—drilled and constructed well NRF-17 (formerly borehole USGS 151) and well NRF-18 (formerly borehole USGS 152) for stratigraphic framework analyses and water-quality monitoring at the Idaho National Laboratory (INL) near the NRF, in southeastern Idaho. Borehole USGS 151 was continuously cored from about 48 to 1,070 feet (ft) below land surface (BLS); rotary drilled from approximately 1,070 to 1,720 ft BLS; and re-drilled to complete construction as a monitor well NRF-17, completed to 461 ft BLS. Borehole USGS 152 was continuously cored from approximately 19 to 1,259 ft BLS; rotary drilled from approximately 1,259 to 1,630 ft BLS; and re-drilled to complete construction as a monitor well NRF-18, completed to 450 ft BLS. Geophysical data were examined with photographed core material to record lithologic descriptions and to suggest zones where groundwater flow was anticipated. Basalt flows varied from highly fractured to dense, with high-to-low vesiculation. Well NRF-17 generally was constructed in mostly dense basalt (greater than 75 percent), and well NRF-18 was constructed in primarily fractured and (or) vesicular basalt. In well NRF-17, the well capacity is directly affected by the limited amount of fractured basalt, which serves as the primary pathway for groundwater. This effect was observed during the pumping test conducted after the well's final construction. Single-well aquifer tests were done at wells NRF-17 and NRF-18 to provide estimates of transmissivity and hydraulic conductivity after final well construction and initial well development. Estimated values of transmissivity and hydraulic conductivity for well NRF-17 were 8.81 feet squared per day (ft 2 /d) and 1.04×10 -2 feet per day (ft/d), respectively. Estimated values of transmissivity and hydraulic conductivity for well NRF-18 were 4.77×10 3 ft 2 /d and 5.61 ft/d, respectively. The NRF-17 pump test resulted in 19.41 ft of measured drawdown at a sustained average pumping rate of 3.3 gallons per minute (gal/min). The NRF-18 pump test resulted in 0.55 ft of measured drawdown at a sustained average pumping rate of 31.0 gal/min. Water-quality samples collected from the two wells were analyzed for cations, anions, metals, nutrients, volatile organic compounds, stable isotopes, and radionuclides. Water samples for select inorganic constituents showed concentrations consistent with signatures from tributary valley groundwater with influences from ephemeral surface-water recharge from the Big Lost River. Water-quality samples analyzed for stable isotopes of oxygen and hydrogen are consistent with signatures from tributary valley groundwater and surface-water recharge inputs to the aquifer. No measured water-quality results were greater than their respective maximum contaminant levels for public drinking-water supplies. Inorganic and nutrient water-quality results for well NRF-17 and well NRF-18 suggest the groundwater in this area is potentially affected by industrial wastewater disposal.

Idaho

Abandonment of the Upper Devonian Greenland Gap Group and Scherr Formation and revision of the Upper Devonian Brallier and Foreknobs Formations in the central Valley and Ridge Province

This study revises the lithostratigraphic framework of the Upper Devonian interval traditionally assigned to the Greenland Gap Group across the central Appalachian Valley and Ridge Province. The work aims to modernize and standardize lithostratigraphic nomenclature, establish a new reference section and demonstrate how the revised stratigraphy improves edge-matching of 1:24,000 scale geologic maps and supports compilation mapping at scales of 1:100,000 and larger. The revision eliminates the names Greenland Gap Group, Scherr Formation and the Minnehaha Springs Member of the Scherr Formation; reassigns all strata previously designated as Scherr Formation by Dennison (1970) to the upper Brallier Formation; and abandons the basal Mallow Member of the Foreknobs Formation, placing its strata within the upper Brallier as originally defined by Butts (1918). The contact between the Brallier and Foreknobs formations is placed at the base of the first mappable, ridge-forming package of fine- to coarse-grained, cross-bedded, sandstone beds, often containing rounded quartz pebbles with minor interbeds of shale and siltstone. This contact may be gradational in places but, even in absence of good exposure, can usually be distinguished topographically in recently produced lidar-derived imagery as having elevated relief due to the presence of more resistant, compositionally mature coarse-grained sandstone-rich strata. Applying this criterion for mapping the contact between the Brallier and Foreknobs formations has resulted in reconciliation of mismatches of geologic contacts along several 7.5-minute quadrangle boundaries in the states of Virginia, West Virginia, Maryland and Pennsylvania. A new reference section at Baker, West Virginia showcases the contacts between the Harrell Shale, Brallier Formation, Foreknobs Formation and Hampshire Formation. A digital outcrop model of the reference section is provided for future preservation.

Maryland, Pennsylvania, Virginia, West Virginia