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USGS2013

Historical methane hydrate project review

In 1995, U.S. Geological Survey made the first systematic assessment of the volume of natural gas stored in the hydrate accumulations of the United States. That study, along with numerous other studies, has shown that the amount of gas stored as methane hydrates in the world greatly exceeds the volume of known conventional gas resources. However, gas hydrates represent both a scientific and technical challenge and much remains to be learned about their characteristics and occurrence in nature. Methane hydrate research in recent years has mostly focused on: (1) documenting the geologic parameters that control the occurrence and stability of gas hydrates in nature, (2) assessing the volume of natural gas stored within various gas hydrate accumulations, (3) analyzing the production response and characteristics of methane hydrates, (4) identifying and predicting natural and induced environmental and climate impacts of natural gas hydrates, and (5) analyzing the effects of methane hydrate on drilling safety. Methane hydrates are naturally occurring crystalline substances composed of water and gas, in which a solid water-‐lattice holds gas molecules in a cage-‐like structure. The gas and water becomes a solid under specific temperature and pressure conditions within the Earth, called the hydrate stability zone. Other factors that control the presence of methane hydrate in nature include the source of the gas included within the hydrates, the physical and chemical controls on the migration of gas with a sedimentary basin containing methane hydrates, the availability of the water also included in the hydrate structure, and the presence of a suitable host sediment or “reservoir”. The geologic controls on the occurrence of gas hydrates have become collectively known as the “methane hydrate petroleum system”, which has become the focus of numerous hydrate research programs. Recognizing the importance of methane hydrate research and the need for a coordinated effort, the U.S. Congress enacted Public Law 106-‐193, the Methane Hydrate Research and Development Act of 2000. This Act called for the Secretary of Energy to begin a methane hydrate research and development program in consultation with other U.S. federal agencies. At the same time a new methane hydrate research program had been launched in Japan by the Ministry of International Trade and Industry to develop plans for a methane hydrate exploratory drilling project in the Nankai Trough. Since this early start we have seen other countries including India, China, Canada, and the Republic of Korea establish large gas hydrate research and development programs. These national led efforts have also included the investment in a long list of important scientific research drilling expeditions and production test studies that have provided a wealth of information on the occurrence of methane hydrate in nature. The most notable expeditions and projects have including the following: -‐Ocean Drilling Program Leg 164 (1995) -‐Japan Nankai Trough Project (1999-‐2000) -‐Ocean Drilling Program Leg 204 (2004) -‐Japan Tokai-‐oki to Kumano-‐nada Project (2004) -‐Gulf of Mexico JIP Leg I (2005) -‐Integrated Ocean Drilling Program Expedition 311 (2005) -‐Malaysia Gumusut-‐Kakap Project (2006) -‐India NGHP Expedition 01 (2006) -‐China GMGS Expedition 01 (2007) -‐Republic of Korea UBGH Expedition 01 (2007) -‐Gulf of Mexico JIP Leg II (2009) -‐Republic of Korea UBGH Expedition 02 (2010) -‐MH-‐21 Nankai Trough Pre-‐Production Expedition (2012-‐2013) -‐Mallik Gas Hydrate Testing Projects (1998/2002/2007-‐2008) -‐Alaska Mount Elbert Stratigraphic Test Well (2007) -‐Alaska Iġnik Sikumi Methane Hydrate Production Test Well (2011-‐2012) Research coring and seismic programs carried out by the Ocean Drilling Program (ODP) and Integrated Ocean Drilling Program (IODP), starting with the ODP Leg 164 drilling of the Blake Ridge in the Atlantic Ocean in 1995, have also contributed greatly to our understanding of the geologic controls on the formation, occurrence, and stability of gas hydrates in marine environments. For the most part methane hydrate research expeditions carried out by the ODP and IODP provided the foundation for our scientific understanding of gas hydrates. The methane hydrate research efforts under ODP-‐IODP have mostly dealt with the assessment of the geologic controls on the occurrence of gas hydrate, with a specific goal to study the role methane hydrates may play in the global carbon cycle. Over the last 10 years, national led methane hydrate research programs, along with industry interest have led to the development and execution of major methane hydrate production field test programs. Two of the most important production field testing programs have been conducted at the Mallik site in the Mackenzie River Delta of Canada and in the Eileen methane hydrate accumulation on the North Slope of Alaska. Most recently we have also seen the completion of the world’s first marine methane hydrate production test in the Nankai Trough in the offshore of Japan. Industry interest in gas hydrates has also included important projects that have dealt with the assessment of geologic hazards associated with the presence of hydrates. The scientific drilling and associated coring, logging, and borehole monitoring technologies developed in the long list of methane hydrate related field studies are one of the most important developments and contributions associated with methane hydrate research and development activities. Methane hydrate drilling has been conducted from advanced scientific drilling platforms like the JOIDES Resolution and the D/V Chikyu, which feature highly advanced integrated core laboratories and borehole logging capabilities. Hydrate research drilling has also included the use of a wide array of industry, geotechnical and multi-‐service ships. All of which have been effectively used to collect invaluable geologic and engineering data on the occurrence of methane hydrates throughout the world. Technologies designed specifically for the collection and analysis of undisturbed methane hydrate samples have included the development of a host of pressure core systems and associated specialty laboratory apparatus. The study and use of both wireline conveyed and logging-‐while-‐drilling technologies have also contributed greatly to our understanding of the in-‐situ nature of hydrate-‐bearing sediments. Recent developments in borehole instrumentation specifically designed to monitor changes associated with hydrates in nature through time or to evaluate the response of hydrate accumulations to production have also contributed greatly to our understanding of the complex nature and evolution of methane hydrate systems. Our understanding of how methane hydrates occur and behave in nature is still growing and evolving – we do not yet know if methane hydrates can be economically produced, nor do we know fully the role of hydrates as an agent of climate change or as a geologic hazard. But it is known for certain that scientific drilling has contributed greatly to our understanding of hydrates in nature and will continue to be a critical source of the information to advance our understanding of methane hydrates.

Report↗

USGS2012

Contributions of Arctic PRISM to monitoring western hemispheric shorebirds

Long-term monitoring of populations is of paramount importance to understanding responses oforganisms to global environmental change and to evaluating whether conservation practices are yielding intended results through time (Wiens 2009). The population status of many shorebird species, the focus of this volume, remain poorly known. Long-distance migrant shorebirds have proven particularly difficult to monitor, in part because of their highly migratory nature and ranges that extend into highly inaccessible regions. As migrant shorebirds travel the length of the hemisphere, they congregate and disperse in ways that vary among species, locations, and years, presenting serious challenges to designing and implementing monitoring programs. Rigorous field and quantitative methods that estimate population size and monitor trends are vitally needed to direct and evaluate effective conservation measures. Many management efforts depend on unbiased population size estimates; for example, the shorebird conservation plans for both Canada and the United States seek to restore populations to levels calculated for the 1970s based on the best information available from existing surveys. Further, federal wildlife agencies within the United States and Canada have mandates to understand the state of their nations' resources under various conventions for the protection of migratory birds. Accurate estimates of population size are vital statistics for a variety of conservation activities, such as prioritizing species for conservation action and setting management targets. Areas of essential habitat, such as those designated under the Western Hemisphere Shorebird Reserve Network, the Important Bird Areas program of BirdLife International and the National Audubon Society, or Canada's National Wildlife Areas program, are all evaluated on the basis ofproportions of species' populations which they contain. The size, and trends in size, ofa species' population are considered key information for assessing its vulnerability and subsequent listing under the U.S. Endangered Species Act and the Canadian Species at Risk Act. To meet the need for information on population size and trends, shorebird biologists from Canada and the United States proposed a shared blueprint for shorebird monitoring across the Western Hemisphere in the late 1990s; this effort was undertaken in concert with the development of the Canadian and U.S. Shorebird Conservation Plans (Donaldson et al. 2000, Brown et aL 2001). Soon thereafter, partners in the monitoring effort adopted the name "Program for Regional and International Shorebird Monitoring" (PRISM). Among the primary objectives of PRISM were to estimate the population sizes and trends of breeding North American shorebirds and describe their distributions (Bart et al. 2002). PRISM members evaluated ongoing and potential monitoring approaches to address 74 taxa (including subspecies) and proposed a combination of arctic andboreal breeding surveys, temperate breeding and non-breeding surveys, and neotropical surveys.

Book chapter↗

USGS1997

Nitrate and pesticides in surficial aquifers and trophic state and phosphorus sources for selected lakes, eastern Otter Tail County, west-central Minnesota, 1993-96

Nitrate concentrations (as nitrogen) were analyzed in water from 73 wells completed in surficial aquifers. Water from about one-third of the wells had concentrations greater than 10 mg/L (milligrams per liter), the regulatory limit for drinking water established by the U.S. Environmental Protection Agency. Nitrate concentrations: (1) were greater in water from wells in agricultural settings than in nonagricultural settings; (2) were not greater in water from shallow wells (25 feet deep or less) in settings with rapid soil permeability than with moderate soil permeability, probably because the effects of permeability were offset by the effects of land use and well depth; and (3) were greater in water from shallow wells (25 feet deep or less) than from deep wells (greater than 25 feet deep). Triazine herbicides were detected in water from 23 of the 73 sampled wells by immunoassay tests. Most of these wells are in agricultural settings. Ten pesticides, which included seven triazine herbicide compounds, were detected in water from 19 of 25 wells analyzed by gas chromatography/mass spectrometry. Atrazine and deethylatrazine, a degradation product of atrazine, were detected in water from 18 and 16 wells, respectively. None of the detected pesticides had concentrations that exceeded their respective regulatory limits for drinking water established by the U.S. Environmental Protection Agency. Four lakes in the Otter Tail River Basin, which in downstream order are Little Pine, Big Pine, Rush, and Otter Tail Lakes, ranged in trophic state from upper oligotrophic to lower eutrophic. The Secchi disk transparencies were 4.0 to 7.4 feet, chlorophyll a concentrations (epilimnetic) were 4.4 to 28 micrograms per liter, and total phosphorus concentrations (epilimnetic) were less than 0.010 to 0.022 mg/L (except one concentration of 0.060 mg/L). The trophic state of these lakes may have become less eutrophic from upstream to downstream lakes. Major external sources of phosphorus to Big Pine Lake were the Otter Tail and Toad Rivers. The phosphorus load from these two streams during March 16, 1995, to March 15, 1996 was 10,400 pounds. The phosphorus load from the Toad River (5,730 pounds) was greater than from the Otter Tail River (4,670 pounds) even though streamflow from the Toad River was about 70 percent less than the Otter Tail River. Phosphorus removal from Big Pine Lake through the Otter Tail River outlet during the 1-year period was 8,460 pounds. The total annual accumulation of phosphorus, which includes an estimated 700 pounds from ground-water discharge, was 2,640 pounds. The accumulated phosphorus probably was utilized by phytoplankton or was absorbed by nonliving particulate matter that eventually settled into bottom sediments. Bottom sediments were an internal source of phosphorus to Little Pine and Big Pine Lakes. Increased total phosphorus concentrations (hypolimnetic) of 0.037 to 0.120 mg/L at depth during August 9-10, 1995, indicated phosphorus release from bottom sediments. The increased phosphorus probably was associated with anoxic conditions in the hypolimnion during summer stratification. Phosphorus at depth in Little Pine and Big Pine Lakes was mostly orthophosphate. During the fall turnover of the lakes, this orthophosphate may have circulated to near the lake surface and became an available nutrient for phytoplankton during the following growing season. The internal phosphorus load to Little Pine Lake may have been important because about three-fourths of the lake probably became stratified and anoxic in the hypolimnion. The internal phosphorus load to Big Pine Lake may not have been important because only a small portion of the lake became stratified and anoxic at depth.

Minnesota↗

USGS2014

Dissolved-solids sources, loads, yields, and concentrations in streams of the conterminous United States

Recent studies have shown that excessive dissolved-solids concentrations in water can have adverse effects on the environment and on agricultural, domestic, municipal, and industrial water users. Such effects motivated the U.S. Geological Survey’s National Water Quality Assessment Program to develop a SPAtially-Referenced Regression on Watershed Attributes (SPARROW) model that has improved the understanding of sources, loads, yields, and concentrations of dissolved solids in streams of the conterminous United States. Using the SPARROW model, long-term mean annual dissolved-solids loads from 2,560 water-quality monitoring stations were statistically related to several spatial datasets that are surrogates for dissolved-solids sources and land-to-water delivery processes. Specifically, sources in the model included variables representing geologic materials, road deicers, urban lands, cultivated lands, and pasture lands. Transport of dissolved solids from these sources was modulated by land-to-water delivery variables that represent precipitation, streamflow, soil, vegetation, terrain, population, irrigation, and artificial drainage characteristics. Where appropriate, the load estimates, source variables, and transport variables were statistically adjusted to represent conditions for the base year 2000. The nonlinear least-squares estimated SPARROW model was used to predict long-term mean annual conditions for dissolved-solids sources, loads, yields, and concentrations in a digital hydrologic network representing nearly 66,000 stream reaches and their corresponding incremental catchments that drain the Nation. Nationwide, the predominant source of dissolved solids yielded from incremental catchments and delivered to local streams is geologic materials in 89 percent of the catchments, road deicers in 5 percent of the catchments, pasture lands in 3 percent of the catchments, urban lands in 2 percent of the catchments, and cultivated lands in 1 percent of the catchments. Whereas incremental catchments with dissolved solids that originated predominantly from geologic sources or from urban lands are found across much of the Nation, incremental catchments with dissolved solids yields that originated predominantly from road deicers are largely found in the Northeast, and incremental catchments with dissolved solids that originated predominantly from cultivated or pasture lands are largely found in the West. The total amount of dissolved solids delivered to the Nation’s streams is 271.9 million metric tons (Mt) annually, of which 194.2 million Mt (71.4%) come from geologic sources, 37.7 million Mt (13.9%) come from road deicers, 18.2 million Mt (6.7%) come from pasture lands, 13.9 million Mt (5.1%) come from urban lands, and 7.9 million Mt (2.9%) come from cultivated lands. Nationwide, the median incremental-catchment yield delivered to local streams is 26 metric tons per year per square kilometer [(Mt/yr)/km 2 ]. Ten percent of the incremental catchments yield less than 4 (Mt/yr)/km 2 , and 10 percent yield more than 90 (Mt/yr)/km 2 . Incremental-catchment yields greater than 50 (Mt/yr)/km 2 mostly occur along the northern part of the West Coast and in a crescent shaped band south of the Great Lakes. For example, the median incremental-catchment yield is 81 (Mt/yr)/km 2 for the Great Lakes, 78 (Mt/yr)/km 2 for the Ohio, and 74 (Mt/yr)/km 2 for the Upper Mississippi water-resources regions. Incremental-catchment yields less than 10 (Mt/yr)/km 2 mostly occur in a wide band across the arid lowland of the interior West that excludes areas along the coast and the extensive, higher mountain ranges. For example, the median incremental-catchment yield is 3 (Mt/yr)/km 2 for the Lower Colorado, 5 (Mt/yr)/km 2 for the Rio Grande, and 8 (Mt/yr)/km 2 for the Great Basin water-resources regions. Predicted incremental loads were cascaded down through the reach network, with loads accumulating from reach to reach. For most stream reaches, the entire incremental load of dissolved solids delivered to the reach was transported to either the ocean or to one of the large streams flowing along the U.S. international boundary without losses occurring along the way. The exceptions to this include streams in the southwestern part of the country, such as the Colorado River, Rio Grande, and streams of internally drained drainages in the Great Basin, where dissolved-solids loads decreased through streamflow diversion for off-stream use, or by infiltration through the streambed. Long-term mean annual flow-weighted concentrations were derived from the predicted accumulated-load and stream-discharge data. Widespread low concentrations, generally less than 100 milligrams per liter (mg/L), occur in many reaches of the New England, South Atlantic-Gulf, and Pacific Northwest water-resources regions as a result of moderate dissolved-solids yields and high runoff rates. Widespread moderate concentrations, generally between 100 and 500 mg/L, occur in many reaches of the Great Lakes, Ohio, and Upper Mississippi River water-resources regions. Whereas dissolved-solids yields are generally high in these regions, runoff rates are also high, which helps moderate concentrations in these regions. Widespread higher concentrations, generally greater than 500 mg/L, occur across a belt of reaches that extends almost continuously from Canada to Mexico in the Midwest, cutting through the Souris-Red-Rainy, Missouri, Arkansas-White-Red, Texas-Gulf, and Rio Grande water-resources regions. Although dissolved-solids yields are moderate to low in these areas, low runoff rates result in the high concentrations for these areas. In 12.6 percent of the Nation’s stream reaches, predicted concentrations of dissolved solids exceed 500 mg/L, the U.S. Environmental Protection Agency’s secondary, nonenforceable drinking water standard. While this standard provides a metric for evaluating predicted concentrations in the context of drinking-water supplies, it should be noted that it only applies to drinking water actually served to customers by water utilities, and it does not apply to all stream reaches in the Nation nor does it apply during times when water is not being withdrawn for use. Exceedance of 500 mg/L is more pronounced in certain water-resources regions than others. For example, about half of the reaches in the Souris-Red-Rainy region have concentrations predicted to exceed 500 mg/L, and between 25 and 37 percent of the reaches in the Missouri, Arkansas-White-Red, Texas-Gulf, Rio Grande, and Lower Colorado regions are predicted to exceed 500 mg/L. Development of stream-load data for use in the SPARROW model also provided long-term temporal trend information in dissolved-solids concentrations at the monitoring stations for their period of record, which was constrained between 1980 and 2009. For the 2,560 monitoring stations used in this study, long-term trends in flow-adjusted dissolved-solids concentrations increased over time at 23 percent of the stations, decreased at 18 percent of the stations, and did not change over time at 59 percent of the stations. Long-term trends show a strong regional spatial pattern where from the western parts of the Great Plains to the West Coast, concentrations mostly either did not change or decreased over time, and from the eastern parts of the Great Plains to the East Coast, concentrations mostly either did not change or increased over time. Results from the trend analysis and from the SPARROW model indicate that, compared to monitoring stations with no trends or decreasing trends, stations with increasing trends are associated with a smaller percentage of the predicted dissolved-solids load originating from geologic sources, and a larger percentage originating from urban lands and road deicers. Conversely, compared to stations with increasing trends or no trends, stations with decreasing trends have a larger percentage of the predicted dissolved-solids load originating from geologic sources and a smaller percentage originating from urban lands and road deicers. Stations with decreasing trends also have larger percentages of predicted dissolved-solids load originating from cultivated lands and pasture lands, compared to stations with increasing trends or no trends.

Scientific Investigations Report↗

USGS2025

Spatiotemporal drivers of water quality and phytoplankton communities in a cyanobacteria-dominated reservoir provide management insights

Reservoirs serve critical roles providing drinking water, irrigation, flood control, hydropower, recreation, fisheries, and aquatic habitat. Yet their physical position, complex shape, and large watersheds make reservoirs especially susceptible to eutrophication and harmful algal bloom (HAB) production. Boysen Reservoir, WY, is a high priority for proactive nutrient management because it is an important source for drinking water and recreation, and has a history of toxic cyanobacterial blooms. We combined four years of comprehensive monitoring efforts by state and federal agencies to characterize the spatiotemporal patterns of nutrient inflow, internal water quality dynamics, and phytoplankton community shifts in Boysen Reservoir. We found nutrient inflow was hydrologically driven, with snowmelt runoff transporting high nutrient loads. Our findings suggest physicochemical and nutrient conditions of the reservoir were strongly different between the furthest reaches of the reservoir, but less variable among the intermediate sites. Space did not play a role in phytoplankton community dynamics, but time was an important factor. Cyanobacteria dominated phytoplankton communities by mid-summer across the reservoir and were driven mainly by temporal physicochemical conditions, like stratification and water temperature. The two most dominant phytoplankton taxa across the four years of sampling were N-fixing, toxin producing cyanobacteria. Extensive monitoring efforts and data analyses can illuminate strategies to safeguard water resources via understanding the drivers of water quality changes and HAB production.

Wyoming↗

USGS2010

Saving our shared birds: Partners in Flight tri-national vision for landbird conservation

Landbirds are the most abundant and diverse group of birds in North America, with nearly 900 species distributed across every major terrestrial habitat. Birds are indicators of environmental health; their populations track changes in habitat, water, disease, and climate. They are providers of invaluable ecosystem services, such as pest control, seed dispersal, and pollination. As the focus of bird watching, they help generate billions of dollars for national economies. Yet, we are in danger of losing this spectacular and irreplaceable bird diversity: landbirds are experiencing significant declines, ominous threats, and shrinking habitats across a continent with growing human populations, increasing resource consumption, and changing climate. Saving Our Shared Birds presents for the first time a comprehensive conservation assessment of landbirds in Canada, Mexico, and the continental United States. This new tri-national vision encompasses the complete range of many migratory species and highlights the vital links among migrants and highly threatened resident species in Mexico. It points to a set of continent-scale actions necessary to maintain the landbird diversity and abundance that are our shared responsibility. This collaborative effort of Partners in Flight (PIF) is the next step in linking the countries of the Western Hemisphere to help species at risk and keep common birds common through voluntary partnerships—our mission since 1990. Saving Our Shared Birds builds upon PIF’s 2004 North American Landbird Conservation Plan, which presented science-based priorities for the conservation of 448 landbird species in Canada and the United States. Our three nations have expressed their commitment to cooperative conservation through numerous international treaties, agreements, and programs, including formation of the North American Bird Conservation Initiative (NABCI) a decade ago. The NABCI partnership recognizes that effective conservation requires a concerted effort within each country, as well as a tri-national strategy to address issues throughout the full life cycles of our birds. Today more than ever, it is urgent for the people of Canada, Mexico, and the United States to work together to keep common birds common, prevent extinction of our bird species at greatest risk, and ensure the diversity and abundance of birdlife across North America and throughout the hemisphere, far into the future. Saving Our Shared Birds shows the way forward.

Report↗

USGS2016

Seasonal flows of international British Columbia-Alaska rivers: The nonlinear influence of ocean-atmosphere circulation patterns

The northern portion of the Pacific coastal temperate rainforest (PCTR) is one of the least anthropogenically modified regions on earth and remains in many respects a frontier area to science. Rivers crossing the northern PCTR, which is also an international boundary region between British Columbia, Canada and Alaska, USA, deliver large freshwater and biogeochemical fluxes to the Gulf of Alaska and establish linkages between coastal and continental ecosystems. We evaluate interannual flow variability in three transboundary PCTR watersheds in response to El Niño-Southern Oscillation (ENSO), Pacific Decadal Oscillation (PDO), Arctic Oscillation (AO), and North Pacific Gyre Oscillation (NPGO). Historical hydroclimatic datasets from both Canada and the USA are analyzed using an up-to-date methodological suite accommodating both seasonally transient and highly nonlinear teleconnections. We find that streamflow teleconnections occur over particular seasonal windows reflecting the intersection of specific atmospheric and terrestrial hydrologic processes. The strongest signal is a snowmelt-driven flow timing shift resulting from ENSO- and PDO-associated temperature anomalies. Autumn rainfall runoff is also modulated by these climate modes, and a glacier-mediated teleconnection contributes to a late-summer ENSO-flow association. Teleconnections between AO and freshet flows reflect corresponding temperature and precipitation anomalies. A coherent NPGO signal is not clearly evident in streamflow. Linear and monotonically nonlinear teleconnections were widely identified, with less evidence for the parabolic effects that can play an important role elsewhere. The streamflow teleconnections did not vary greatly between hydrometric stations, presumably reflecting broad similarities in watershed characteristics. These results establish a regional foundation for both transboundary water management and studies of long-term hydroclimatic and environmental change.

Alaska, British Columbia↗

USGS2009

Metal exposure and effects in voles and small birds near a mining haul road in Cape Krusenstern National Monument, Alaska

Voles and small passerine birds were live-captured near the Delong Mountain Regional Transportation System (DMTS) haul road in Cape Krusenstern National Monument in northwest Alaska to assess metals exposure and sub-lethal biological effects. Similar numbers of animals were captured from a reference site in southern Cape Krusenstern National Monument for comparison. Histopathological examination of selected organs, and analysis of cadmium, lead, and zinc concentrations in liver and blood samples were performed. Voles and small birds captured from near the haul road had about 20 times greater blood and liver lead concentrations and about three times greater cadmium concentrations when compared to those from the reference site, but there were no differences in zinc tissue concentrations. One vole had moderate metastatic mineralization of kidney tissue, otherwise we observed no abnormalities in internal organs or DNA damage in the blood of any of the animals. The affected vole also had the greatest liver and blood Cd concentration, indicating that the lesion might have been caused by Cd exposure. Blood and liver lead concentrations in animals captured near the haul road were below concentrations that have been associated with adverse biological effects in other studies; however, subtle effects resulting from lead exposure, such as the suppression of the activity of certain enzymes, cannot be ruled out for some individual animals. Results from our 2006 reconnaissance-level study indicate that overall, voles and small birds obtained from near the DMTS road in Cape Krusenstern National Monument were not adversely affected by metals exposure; however, because of the small sample size and other uncertainties, continued monitoring of lead and cadmium in terrestrial habitats near the DMTS road is advised.

Alaska↗

USGS2001

Detection of pesticides and pesticide metabolites using the cross reactivity of enzyme immunoassays

Enzyme immunoassay is an important environmental analysis method that may be used to identify many pesticide analytes in water samples. Because of similarities in chemical structure between various members of a pesticide class, there often may be an unwanted response that is characterized by a percentage of cross reactivity. Also, there may be cross reactivity caused by degradation products of the target analyte that may be present in the sample. In this paper, the concept of cross reactivity caused by degradation products or by nontarget analytes is explored as a tool for identification of metabolites or structurally similar compounds not previously known to be present in water samples. Two examples are examined in this paper from various water quality studies. They are alachlor and its metabolite, alachlor ethane sulfonic acid, and atrazine and its class members, prometryn and propazine. A method for using cross reactivity for the detection of these compounds is explained in this paper.

Journal of AOAC International↗

USGS2010

Environmental tolerance of an invasive riparian tree and its potential for continued spread in the southwestern US

Questions: Exotic plant invasion may be aided by facilitation and broad tolerance of environmental conditions, yet these processes are poorly understood in species-rich ecosystems such as riparian zones. In the southwestern United States (US) two plant species have invaded riparian zones: tamarisk (Tamarix ramosissima, T. chinensis, and their hybrids) and Russian olive (Elaeagnus angustifolia). We addressed the following questions: (1) is Russian olive able to tolerate drier and shadier conditions than cottonwood and tamarisk? (2) Can tamarisk and cottonwood facilitate Russian olive invasion? Location: Arid riparian zones, southwestern US. Methods: We analyzed riparian tree seedling requirements in a controlled experiment, performed empirical field studies, and analyzed stable oxygen isotopes to determine the water sources used by Russian olive. Results: Russian olive survival was significantly higher in dense shade and low moisture conditions than tamarisk and cottonwood. Field observations indicated Russian olive established where flooding cannot occur, and under dense canopies of tamarisk, cottonwood, and Russian olive. Tamarisk and native riparian plant species seedlings cannot establish in these dry, shaded habitats. Russian olive can rely on upper soil water until 15 years of age, before utilizing groundwater. Conclusions: We demonstrate that even though there is little evidence of facilitation by cottonwood and tamarisk, Russian olive is able to tolerate dense shade and low moisture conditions better than tamarisk and cottonwood. There is great potential for continued spread of Russian olive throughout the southwestern US because large areas of suitable habitat exist that are not yet inhabited by this species. ?? 2010 International Association for Vegetation Science.

Journal of Vegetation Science↗

USGS2012

Interactions of tissue and fertilizer nitrogen on decomposition dynamics of lignin-rich conifer litter

High tissue nitrogen (N) accelerates decomposition of high-quality leaf litter in the early phases of mass loss, but the influence of initial tissue N variation on the decomposition of lignin-rich litter is less resolved. Because environmental changes such as atmospheric N deposition and elevated CO 2 can alter tissue N levels within species more rapidly than they alter the species composition of ecosystems, it is important to consider how within-species variation in tissue N may shape litter decomposition and associated N dynamics. Douglas-fir (Pseudotsuga menziesii ) is a widespread lignin-rich conifer that dominates forests of high carbon (C) storage across western North America, and displays wide variation in tissue and litter N that reflects landscape variation in soil N. We collected eight unique Douglas-fir litter sources that spanned a two-fold range in initial N concentrations (0.67–1.31%) with a narrow range of lignin (29–35%), and examined relationships between initial litter chemistry, decomposition, and N dynamics in both ambient and N fertilized plots at four sites over 3 yr. High initial litter N slowed decomposition rates in both early (0.67 yr) and late (3 yr) stages in unfertilized plots. Applications of N fertilizer to litters accelerated early-stage decomposition, but slowed late-stage decomposition, and most strongly affected low-N litters, which equalized decomposition rates across litters regardless of initial N concentrations. Decomposition of N-fertilized litters correlated positively with initial litter manganese (Mn) concentrations, with litter Mn variation reflecting faster turnover of canopy foliage in high N sites, producing younger litterfall with high N and low Mn. Although both internal and external N inhibited decomposition at 3 yr, most litters exhibited net N immobilization, with strongest immobilization in low-N litter and in N-fertilized plots. Our observation for lignin-rich litter that high initial N can slow decomposition yet accelerate N release differs from findings where litter quality variation across species promotes coupled C and N release during decomposition. We suggest reevaluation of ecosystem models and projected global change effects to account for a potential decoupling of ecosystem C and N feedbacks through litter decomposition in lignin-rich conifer forests.

Ecosphere↗

USGS2016

Maternal transfer of contaminants in birds: Mercury and selenium concentrations in parents and their eggs

We conducted a detailed assessment of the maternal transfer of mercury and selenium to eggs in three bird species ( n = 107 parents and n = 339 eggs), and developed predictive equations linking contaminant concentrations in eggs to those in six tissues of the mother (blood, muscle, liver, kidney, breast feathers, and head feathers). Mercury concentrations in eggs were positively correlated with mercury concentrations in each of the mother's internal tissues ( R 2 ≥ 0.95), but generally not with feathers. For each species, the proportion of mercury transferred to eggs decreased as mercury concentrations in the mother increased. At the same maternal mercury concentration, the proportion of mercury transferred to eggs differed among species, such that Forster's tern ( Sterna forsteri ) and black-necked stilt ( Himantopus mexicanus ) females transferred more methylmercury to their eggs than American avocet ( Recurvirostra americana ) females. Selenium concentrations in eggs also were correlated with selenium concentrations in the mother's liver ( R 2 = 0.87). Furthermore, mercury and selenium concentrations in tern eggs were positively correlated with those in the father ( R 2 = 0.84). Incubating male terns had 21% higher mercury concentrations in blood compared to incubating females at the same egg mercury concentration. We provide equations to predict contaminant concentrations in eggs from each of the commonly sampled bird tissues.

Environmental Pollution↗

USGS2018

Monitoring algal blooms in drinking water reservoirs using the Landsat-8 Operational Land Imager

In this study, we demonstrated that the Landsat-8 Operational Land Imager (OLI) sensor is a powerful tool that can provide periodic and system-wide information on the condition of drinking water reservoirs. The OLI is a multispectral radiometer (30 m spatial resolution) that allows ecosystem observations at spatial and temporal scales that allow the environmental community and water managers another means to monitor changes in water quality not feasible with field-based monitoring. Using the provisional Land Surface Reflectance product and field-collected chlorophyll- a (chl- a ) concentrations from drinking water monitoring programs in North Carolina and Rhode Island, we compared five established approaches for estimating chl- a concentrations using spectral data. We found that using the three band reflectance approach with a combination of OLI spectral bands 1, 3, and 5 produced the most promising results for accurately estimating chl- a concentrations in lakes ( R 2 value of 0.66; root mean square error value of 8.9 µg l −1 ). Using this model, we forecast the spatial and temporal variability of chl- a for Jordan Lake, a recreational and drinking water source in piedmont North Carolina and several small ponds that supply drinking water in southeastern Rhode Island.

North Carolina↗

USGS2007

Vision for a worldwide fluvial-sediment information network

The nations of the world suffer both from the deleterious effects of some natural and human-altered fluxes of fluvial sediment and a lack of consistent and reliable information on the temporal and spatial occurrence of fluvial sediments. Decades ago, this difficulty was unavoidable due to a lack of understanding of the magnitude and scope of environmental influences exerted by fluvial sediment coupled with a dearth of tools for monitoring and studying the data. Such is no longer the case. Fluvial sediment has a broad influence on the environment and humanity. Data needs that were once limited primarily to reservoir and channel maintenance now include issues associated with public water supply; contaminated sediment management; productivity of agricultural lands; stream restoration and watershed health; in-stream biotic stability; post-wildfire channel morphology; dam decommissioning, rehabilitation, or removal; and legal requirements for sediment management (Gray and Glysson, 2005). The adverse effects of poorly managed or unmanaged sediment movement related to these and other issues are well-known qualitatively, and in some cases quantitatively. For example, physical, chemical, and biological damages attributable to fluvial sediment in North America alone are now estimated to range between $20 billion and $50 billion annually (Pimental and others, 1995; Osterkamp and others, 1998; 2004). Capabilities for monitoring, analyzing, storing, and sharing fluvial-sediment data have been developed and, in many cases, are sufficiently mature for consideration for global utilization. Hence, there is not only a strong and expanding need for a global effort to gauge and understand fluvial-sediment characteristics and processes better, but the knowledge and tools to achieve these ends are largely available and ready for their applicability to be evaluated. Given the increasing importance of erosion and sediment processes for water-resources management, an International Sedimentation Initiative (ISI, 2007a), under the United Nations Educational, Scientific, and Cultural Organization’s International Hydrologic Programme (IHP, 2007) was adopted in 2004. The ISI, the focus of which is on sustainable water-resources management on the global scale, features six major activities and projects, which are listed as part of the section entitled, “Relation of the WoFSIN concept to the thrusts of the International Sedimentation Initiative,” that precedes the “Conclusions” section of this paper. Based on the need for more, and more consistent and reliable fluvial-sediment information and on the existence of the ISI and other international and national sediment programs, we envision the need for a Worldwide Fluvial Sediment-Information Network (WoFSIN) with a focus on data acquisition, storage, and dissemination globally. Envisioned components of a WoFSIN, administered largely via the Internet and relying mostly on the benefits derived from existing resources and programs, follow that summary. The goal of the WoFSIN is to maximize the availability and usefulness of the world’s historical and current fluvial-sediment and ancillary data through collaboration with existing programs so as to require few additional resources in the long-term. Thus, the WoFSIN concept was developed recognizing that informed resource management is predicated on the availability of adequate and reliable information. The WoFSIN is described in the ensuing sections in stand-alone fashion, followed by a section that describes the complementary aspects of the WoFSIN and the International Sediment Initiative. Thus, our first objective is to describe the fundamental components of a WoFSIN. Our second objective is to identify overlap or gaps between the WoFSIN and ISI concepts that might be useful in refining the ISI’s ability to meet its global mission to develop decision support for sediment management at the global scale more fully, cost-effectively, and (or) with enhanced quality.

Conference Paper↗

USGS1998

A policy model to initiate environmental negotiations: Three hydropower workshops

How do I get started in natural resource negotiations? Natural resource managers often face difficult negotiations when they implement laws and policies regulating such resources as water, wildlife, wetlands, endangered species, and recreation. As a result of these negotiations, managers must establish rules, grant permits, or create management plans. The Legal‐Institutional Analysis Model (LIAM) was designed to assist managers in systematically analyzing the parties in natural resource negotiations and using that analysis to prepare for bargaining. The LIAM relies on the theory that organizations consistently employ behavioral roles. The model uses those roles to predict likely negotiation behavior. One practical use of the LIAM is when all parties to a negotiation conduct a workshop as a way to open the bargaining on a note of trust and mutual understanding. The process and results of three LIAM workshops designed to guide hydroelectric power licensing negotiations are presented. Our experience with these workshops led us to conclude that the LIAM can be an effective tool to begin a negotiation and that trust built through the workshops can help create a successful result.

Human Dimensions of Wildlife: An International Jou↗

USGS2003

Nonylphenol ethoxylates and other additives in aircraft deicers, antiicers, and waters receiving airport runoff

Samples of nine different formulations of aircraft deicer and antiicer fluids (ADAF) were screened for the presence of selected surfactants. Nonylphenol ethoxylates (NPnEO) were identified in three ADAF formulations, octylphenol ethoxylates were identified in two formulations, and six formulations contained alcohol ethoxylates. A preliminary field study was conducted at General Mitchell International Airport, Milwaukee, WI, to quantify NPnEO (n = 1-15) and one of its byproducts, nonylphenol (NP), in airport runoff. Samples were collected from two airport outfalls, from the receiving stream, and from an upstream reference site during intensive ADAF application events. NPnEO was measured at concentrations up to 1190microg/L in airport outfall samples, up to 77 ug/L in samples from the receiving stream and less than 5.0 microg/L from the upstream reference. Concentrations of glycol and other ADAF-related constituents, including NPnEO, were reduced by approximately 1 order of magnitude between the outfall sites and the receiving stream site; however, concentrations of NP in the receiving stream remained similar to those from the outfalls (< 0.04 microg/L at the upstream reference, 0.98 and 7.67 microg/L at outfalls, and 3.89 microg/L in the receiving stream). The field data suggest that NP is generated through degradation of NPnEO from airport runoff.

Wisconsin↗

USGS2006

The National Assessment of Shoreline Change: A GIS compilation of vector shorelines and associated shoreline change data for the sandy shorelines of the California coast

Introduction The Coastal and Marine Geology Program of the U.S. Geological Survey has generated a comprehensive data clearinghouse of digital vector shorelines and shoreline change rates for the sandy shoreline along the California open coast. These data, which are presented herein, were compiled as part of the U.S. Geological Survey's National Assessment of Shoreline Change Project. Beach erosion is a chronic problem along many open-ocean shores of the United States. As coastal populations continue to grow and community infrastructures are threatened by erosion, there is increased demand for accurate information including rates and trends of shoreline migration. There is also a critical need for shoreline change data that is consistent from one coastal region to another. One purpose of this work is to develop standard, repeatable methods for mapping and analyzing shoreline movement so that periodic, systematic, and internally consistent updates of shorelines and shoreline change rates can be made at a National Scale. This data compilation for open-ocean, sandy shorelines of the California coast is one in a series that already includes the Gulf of Mexico and the Southeast Atlantic Coast (Morton et al., 2004; Morton et al., 2005) and will eventually cover Washington, Oregon, and parts of Hawaii and Alaska. Short- and long-term shoreline change evaluations are determined by comparing the positions of three historical shorelines digitized from maps, with a modern shoreline derived from LIDAR (light detection and ranging) topographic surveys. Historical shorelines generally represent the following time-periods: 1850s-1880s, 1920s-1930s, and late 1940s-1970s. The most recent shoreline is from data collected between 1997 and 2002. Long-term rates of change are calculated by linear regression using all four shorelines. Short-term rates of change are end-point rate calculations using the two most recent shorelines. Please refer to our full report on shoreline change of the California coastline at http://pubs.usgs.gov/of/2006/1219/ for additional information regarding methods and results (Hapke et al., 2006). Data in this report are organized into downloadable layers by region (Northern, Central and Southern California) and are provided as vector datasets with metadata. Vector shorelines may represent a compilation of data from one or more sources and these sources are included in the dataset metadata. This project employs the Environmental Systems Research Institute's (ESRI) ArcGIS as it's GIS mapping tool and contains several data layers (shapefiles) that are used to create a geographic view of the California Coast. These vector data form a basemap comprised of polygon and line themes that include a U.S. coastline (1:80,000), U.S. cities, and state boundaries.

California↗

USGS2021

Estimation of dissolved-solids concentrations using continuous water-quality monitoring and regression models at four sites in the Yuma area, Arizona and California, January 2017 through March 2019

Multiple linear regression models were developed to estimate dissolved-solids concentrations in water at four sites in the Yuma area between Imperial Dam, Arizona and California and the southerly international boundary with Mexico at San Luis, Arizona. Continuous and discrete water-quality data were collected at gaging stations in the Colorado River upstream from Imperial Dam, Arizona-California, the Colorado River below Cooper wasteway near Yuma, Arizona, the Yuma Main Drain above Arizona–Sonora, Mexico boundary, and the 242 lateral above Main Drain at the Arizona–Sonora boundary. Continuous specific conductance and water temperature data were collected at each site between January 2017 and March 2019. Bi-weekly to monthly dissolved-solids water samples were collected during the same period. Continuous specific conductance data collected at the Colorado River below Cooper wasteway were affected by poorly mixed streamflow during periods when the Pilot Knob Hydro-electric Plant was releasing water to the river. The continuous specific conductance data for the site downstream from Cooper wasteway were corrected using mean specific conductance values computed from cross-section measurements collected during site visits. Continuous specific conductance data were affected by sensor fouling issues at the 242 lateral site, and continued operation at the site would require more frequent visits for cleaning and service to ensure data quality. During the study, instream specific conductance readings ranged from 966 to 3,030 microsiemens per centimeter (μS/cm) at 25 degrees Celsius. Computed dissolved-solids concentrations from discrete samples ranged from 690 to 2,580 milligrams per liter (mg/L). Dissolved-solids concentrations were estimated from regression models using the optimal relation between dissolved solids and environmental factors, such as specific conductance, water temperature, dissolved oxygen, streamflow, and seasonality. Specific conductance was the primary factor at all four sites and explained 87.6 to 94 percent of variation in dissolved solids. Water temperature, as an indicator of seasonality, was determined to be a statistically significant secondary factor at both the Colorado River above Imperial Dam and Colorado River below Cooper wasteway sites explaining an additional 6.9 and 2.1 percent of variation in dissolved solids, respectively. Regression models explained 87.6 to 96.9 percent of the variation in dissolved solids; the root mean square error in the modeled data ranged between about 6 and 27 mg/L.

Arizona, California↗