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Organochlorine pesticide residues in bed sediments of the San Joaquin River and its tributary streams, California

The distribution and concentrations of organochlorine pesticide residues in bed sediments were assessed from samples collected at 24 sites in the San Joaquin River and its tributaries in the San Joaquin Valley, California. Sampling was designed to collect the finest grained bed sediments present in the vicinity of each site. One or more of the 14 pesticides analyzed were detected at every site. Pesticides detected at one or more sites were chlordane, DDD, DDE, DDT, dieldrin, endosulfan, mirex, and toxaphene. Pesticides not detected were endrin, heptachlor, heptachlor epoxide, lindane, methoxychlor, and perthane. The most frequently detected pesticides were DDD (83% of sites), DDE (all sites), DDT (33% of sites), and dieldrin (58% of sites). Maximum concentrations of these pesticides, which were correlated with each other and with the amount of organic carbon in the sample, were DDD, 260 micrograms/kg; DDE, 430 micrograms/kg; DDT, 420 micrograms/kg; and dieldrin, 8.9 micrograms/kg. Six small tributary streams that drain agricultural areas west of the San Joaquin River had the highest concentrations. Water concentrations and loads were estimated for each pesticide from its concentration in bed sediments, the concentration of suspended sediment, and streamflow. Estimated loadings of DDD, DDE, DDT, and dieldrin from tributaries to the San Joaquin River indicate that most of the loading to the river at the time of the study was probably from the westside tributaries. Estimated water concentrations exceeded the aquatic life criterion for the sum of DDD, DDE, and DDt of 0.001 microgram/L at nine of the 24 sites sampled. Five of the nine sites are westside tributaries and one is the San Joaquin River near Vernalis. (Author 's abstract)

California↗

Surface-water and ground-water quality in the Yucaipa area, San Bernardino and Riverside Counties, California, 1996-98

The quality of surface water and ground water in the Yucaipa area was evaluated to determine general chemical characteristics and to identify areas of recent ground-water recharge. Water samples, collected from 8 sites on 3 creeks and from 25 wells, were analyzed for general chemistry, nutrients, tritium, and stable isotopes of hydrogen and oxygen. At one production well (1S/2W-25R4), water samples were collected at discrete depths during pumping and a continuous profile of the vertical flow rate inside the well casing was recorded. In addition to general-chemistry samples, tritium and carbon-14 samples were collected at this well to interpret the age of water at different depths.Results indicate that most water in the Yucaipa area is a calcium-bicarbonate type. The general chemical composition of surface water resembles that of ground water, although the concentration of most constituents is higher in ground water. The chemical composition of most ground-water samples is similar. Elevated concentrations of nitrate in some ground-water samples may indicate recharge from agricultural areas.In surface water that recharges ground water tritium activity ranged from 7 to 18 picocuries per liter. The range of tritium activity found in ground water indicates different times since recharge and possible mixing along ground-water flow paths. The oldest ground-water sample had a tritium activity less than 0.3 picocuries per liter, indicating more than 50 years since recharge. Water samples that had tritium activity greater than 0.3 picocuries per liter indicate that some of the water was recharged since 1952. The youngest ground water (greater than 7 picocuries per liter) was found near the hills and mountains surrounding the Yucaipa area; the oldest ground water (less than 0.3 picocuries per liter) was found in the Western Heights subbasin. Testing of the vertical contribution of ground water to well 1S/2W-25R4 showed that more than one-half of the water flowed into the well between depths of about 450 and 600 feet below land surface; the rest of the water flowed into the well between 600 and about 850 feet below land surface. At a discharge rate of 750 gallons per minute, virtually no water was contributed to the well below a depth of about 850 feet. The water samples collected at this well ranged in age from less than 50 to less than 400 years before present.

Water-Resources Investigations Report↗

Reconnaissance investigation of water quality, bottom sediment, and biota associated with irrigation drainage in the lower-Colorado River valley, Arizona, California, and Nevada, 1986-87

The Lower Colorado River Valley Irrigation Drainage Project area included the Colorado River and its environs from Davis Dam to just above Imperial Dam. Water, bottom sediment, and biota were sampled at selected locations within the study area and analyzed for selected inorganic and synthetic organic constituents that are likely to be present at toxic concentrations. With the exceptions of selenium and DDE, this study found sampling locations to be relatively free of large concentrations of toxic constituents that could be a threat to humans, fish, and wildlife. Selenium was the only inorganic constituent to exceed any existing standard, criterion, or guideline for protection of fish and wildlife resources. Concentrations of DDE in double-crested cormorants, however, exceeded the criterion of 1.0 microgram per gram established by the National Academy of Sciences and the National Academy of Engineering for DDT and its metabolites for protection of wildlife. Dissolved-selenium concentrations in water from the lower Colorado River appear to be derived from sources above Davis Dam. At this time, therefore , agricultural practices in the lower Colorado River valley do not appear to exacerbate selenium concentrations. This fact, however, does not mean that the aquatic organisms and their predators are not in jeopardy. Continued selenium loading to the lower Colorado environment could severely affect important components of the ecosystem. (Author 's abstract)

Arizona, California, Nevada↗

Groundwater development leads to decreasing arsenic concentrations in the San Joaquin Valley, California

In the San Joaquin Valley (SJV), California, about 10% of drinking water wells since 2010 had arsenic concentrations above the US maximum contaminant level of 10 μg/L. High concentrations of arsenic are often associated with high pH (greater than 7.8) or reduced geochemical conditions. Although most wells have low arsenic (<3 μg/L) and do not have changing arsenic concentrations, this study found that most wells with concentrations above 10 μg/L had arsenic trends. Overall, about 24% of wells had time-series trends since 2010 and 59% had paired-sample trends since 2000. Most wells had decreasing arsenic trends, even in wells with higher arsenic concentrations. These wells often had co-detections of increasing nitrate and sulfate trends that reflect oxic groundwater likely derived from agricultural recharge. Wells with increasing arsenic trends were deeper or located in the valley trough where aquifer materials are more fine-grained and where reducing conditions favor arsenic mobility. Wells with arsenic trends also tend to be clustered near areas of higher well density. Groundwater pumping in these areas has likely increased the contribution of younger, more oxic groundwater in wells with declining arsenic or, less frequently, increased the contribution of higher pH or reduced groundwater in wells with rising arsenic. Projections of arsenic trends indicate that 37 wells with high arsenic presently will be below 10 μg/L in ten years. Unfortunately, these improvements will be largely offset by 31 wells that are expected to increase above 10 μg/L in addition to expected rises in nitrate in wells where arsenic decreased. This study shows how human-altered flow systems can impact the natural geochemical character of water in both beneficial and deleterious ways.

California↗

Predevelopment water levels, groundwater recharge, and selected hydrologic properties of aquifer materials, Hinkley and Water Valleys, California

Hydrologic and geophysical data were collected to support updates to an existing groundwater-flow model of Hinkley Valley, California, in the Mojave Desert about 80 miles northeast of Los Angeles, California. These data provide information on predevelopment (pre-1930) water levels, groundwater recharge, and selected hydrologic properties of aquifer materials. A predevelopment groundwater-level map, drawn using water-level measurements from 48 wells collected as early as 1918, showed groundwater movement from recharge areas along the Mojave River to evaporative discharge areas near the margin of Harper (dry) Lake in Water Valley. During predevelopment conditions, depth to water ranged from near land surface along the Mojave River to above land surface near Harper (dry) Lake, consistent with flowing wells in Water Valley at that time. Depths to water in much of Hinkley Valley downgradient from the Lockhart fault were less than 20 feet below land surface. By 2017, water-level declines as a result of agricultural pumping, were as much as 60 feet near the Hinkley compressor station. Areal recharge from infiltration of precipitation on the valley floor is negligible. Average annual recharge as infiltration of runoff from upland drainages to Hinkley and Water Valleys averages 64.7 acre-feet per year. In most years recharge does not occur; in years when it occurs, recharge to Hinkley Valley is typically about 296 acre-feet. In contrast, average recharge as infiltration of streamflow from the Mojave River from 1931 to 2015 was between 13,400 and 17,100 acre-feet per year; in some years recharge from the Mojave River exceeded 100,000 acre-ft. Estimates of predevelopment groundwater movement through Hinkley Gap and groundwater discharge to Harper (dry) Lake ranged from 570 to 1,900 and 820 to 2,460 acre-feet per year, respectively; at the time of this study in 2017, groundwater movement through Hinkley Gap was estimated to be about 83 acre-feet per year. Hydraulic-conductivity values estimated from slug-test data for 95 monitoring wells ranged from less than 0.1 to 680 feet per day (ft/d); values generally decreased with depth. Median hydraulic-conductivity values calculated from nuclear magnetic resonance (NMR) data for Mojave River alluvium and near-shore lake deposits were 73 and 11 ft/d, respectively; median hydraulic-conductivity values for locally derived alluvium and weathered bedrock were 6 and 2 ft/d, respectively. Hydraulic-conductivity values, estimated from NMR data for formerly saturated deposits overlying the 2017 water table, were as high as 300 ft/d near the Hinkley compressor station. Downgradient from the Hinkley compressor station, formerly saturated deposits had hydraulic-conductivity values of about 150 ft/d, which were higher than values in saturated material. Coarse-textured, permeable material in formerly saturated deposits above the 2017 water table may have allowed groundwater, released from the Hinkley compressor station that may have contained Cr(VI), to move rapidly downgradient. The Lockhart fault is an impediment to groundwater flow within Hinkley Valley. Groundwater-flow directions from horizontal point-velocity probe data were deflected to the west on the upgradient side of the fault compared to the nominal direction of groundwater flow estimated from water-level data. Younger groundwater was present on the upgradient and downgradient sides of the fault, and older groundwater with unadjusted carbon-14 ages as old as 5,650 years before present was in water from wells within splays of the Lockhart fault, consistent with limited groundwater movement across the fault. As a result, groundwater and Cr(VI) released from the Hinkley compressor station moved to the northwest along the downgradient side of the fault. Coupled well-bore flow and depth-dependent water-quality data show water from wells C-01 and IW-03 within the Q4 2015 (October–December 2015) regulatory Cr(VI) plume was yielded from thin layers within the aquifer that are composed of well-sorted lake-margin (beach) deposits that likely have high lateral and longitudinal connectivity. Collectively, data show highly permeable deposits above the regional water table and thin permeable deposits within saturated portions of the upper aquifer that may have conducted groundwater and Cr(VI) downgradient when releases from the Hinkley compressor station first occurred.

California↗

Waterbird habitat in California's Central Valley basins under climate, urbanization, and water management scenarios

California's Central Valley provides critical, but threatened habitat and food resources for migrating and wintering waterfowl, shorebirds, and other waterbirds. The Central Valley is comprised of nine basins that were defined by the Central Valley Joint Venture (CVJV) to assist in conservation planning. Basins vary in composition and extent of habitats, which primarily include croplands and wetlands that rely on water supplies shared with other competing human and environmental uses. Changes in climate, urban development, and water supply management are uncertain and could reduce future availability of water supplies supporting waterbird habitats and limit effectiveness of wetland restoration planned by the CVJV to support wintering waterbirds. We modeled 17 plausible scenarios including combinations of three climate projections, three urbanization rates, and five water supply management options to promote agricultural and urban water uses, with and without wetland restoration. Our research examines the reduction in quantity and quality of habitats during the fall migration-wintering period by basin under each scenario, and the efficacy of planned wetland restoration to compensate reductions in flooded areas of wetland habitats. Scenario combinations of projected climate, urbanization, and water supply management options reduced availability of flooded cropland and wetland habitats during fall-winter and degraded the quality of seasonal wetlands (i.e., summer-irrigation for improved forage production), though the extent and frequency of impacts varied by basin. Planned wetland restoration may substantially compensate for scenario-related effects on wetland habitats in each basin. However, results indicate that Colusa, Butte, Sutter, San Joaquin, and Tulare Basins may require additional conservation to support summer-irrigation of seasonal wetlands and winter-flooding of cropland habitats. Still further conservation may be required to provide sufficient areas of flooded seasonal and semi-permanent wetlands in San Joaquin and Tulare Basins during fall-winter. The main objective of this research is to provide decision-support for achieving waterbird conservation goals in the valley and to inform CVJV's regional conservation planning.

California↗

Relations of hydrogeologic factors, groundwater reduction-oxidation conditions, and temporal and spatial distributions of nitrate, Central-Eastside San Joaquin Valley, California, USA

In a 2,700-km 2 area in the eastern San Joaquin Valley, California (USA), data from multiple sources were used to determine interrelations among hydrogeologic factors, reduction-oxidation (redox) conditions , and temporal and spatial distributions of nitrate (NO 3 ), a widely detected groundwater contaminant. Groundwater is predominantly modern, or mixtures of modern water, with detectable NO 3 and oxic redox conditions , but some zones have anoxic or mixed redox conditions . Anoxic conditions were associated with long residence times that occurred near the valley trough and in areas of historical groundwater discharge with shallow depth to water. Anoxic conditions also were associated with interactions of shallow, modern groundwater with soils. NO 3 concentrations were significantly lower in anoxic than oxic or mixed redox groundwater , primarily because residence times of anoxic waters exceed the duration of increased pumping and fertilizer use associated with modern agriculture. Effects of redox reactions on NO 3 concentrations were relatively minor. Dissolved N 2 gas data indicated that denitrification has eliminated gt;5 mg/L NO 3 -N in about 10% of 39 wells. Increasing NO 3 concentrations over time were slightly less prevalent in anoxic than oxic or mixed redox groundwater . Spatial and temporal trends of NO 3 are primarily controlled by water and NO 3 fluxes of modern land use.

California↗

Identifying areas of degrading and improving groundwater-quality conditions in the State of California, USA, 1974-2014

Areas of improving and degrading groundwater-quality conditions in the State of California were assessed using spatial weighting of a new metric for scoring wells based on constituent concentrations and the direction and magnitude of a trend slope (Sen). Individual well scores were aggregated across 2135 equal-area grid cells covering the entire groundwater resource used for public supply in the state. Spatial weighting allows results to be aggregated locally (well or grid cell), regionally (groundwater basin), provincially, or statewide. Results differentiate degrading (increasing concentration trends) areas with low to moderate concentrations (unimpaired) from degrading areas with moderate to high concentrations (impaired). Results also differentiate improving areas (decreasing concentration trends) in the same manner. Multi-year to decadal groundwater-quality trends were computed from periodic, inorganic water-quality data for 38 constituents collected between 1974 and 2014 for compliance monitoring of nearly 13,000 public-supply wells (PSWs) in the State of California. Mann-Kendall (MK) rank correlations and Sen’s slope estimator were used to detect statistically significant trends for the entire period of recorded data (long-term trend), for the period since 2000 (recent trend), for different pumping seasons (seasonal trend), and for reversals of trends. Statewide, the most frequently detected trends since 2000 were for nitrate (36%), gross alpha/uranium (10%), arsenic (14%), total dissolved solids (TDS) (23%), and the major ions that contribute to TDS (19–28%). The Transverse and Selected Peninsular Ranges (TSPR) and the San Joaquin Valley (SJV) hydrogeologic provinces had the largest percentage of areas with moderate to high nitrate concentrations and groundwater quality trends. Improving nitrate concentrations in parts of the TSPR is associated with long-term managed aquifer recharge that has replaced historical, agriculturally affected groundwater with low-nitrate recharge in parts of the TSPR. This example suggests that application of dilute, excess surface water to agricultural fields during the winter could improve groundwater-quality in the SJV over the long term.

California↗

Nevada and Landsat

Nevada’s geography is colorful—and contradictory. As one of the most mountainous States, Nevada shares the country’s second-deepest lake, Lake Tahoe, with neighboring California. It is also the driest State and largely covered by desert. Northern Nevada has long, cold winters, whereas the south has long, hot summers. It is the seventh-largest State, but it ranks in the bottom one-half of States for population. More than 72 percent of its 3.1 million residents live in the Las Vegas area. In Nevada, the desert is not dull. An extraordinary variety of wildflowers bloom in the spring, and other plants include mesquite, cacti, creosote, and yucca such as Joshua trees ( Yucca brevifolia ). Sagebrush ( Artemisia tridentata ) is more than the State flower; it is a hardy, enduring shrub foundational to a vast ecosystem in the Great Basin that feeds and shelters hundreds of wildlife species. The Silver State has a strong mining tradition, and agriculture centers around livestock ranching and irrigated crops. Although mining and agriculture once formed the base of Nevada’s economy, tourism now leads the way, mostly from gambling and entertainment in Las Vegas, Reno, and other cities. Water is a critical resource for supporting residents, visitors, and industries, and Lake Mead behind Hoover Dam on the Colorado River supplies most of it for southern Nevada. Nevada has significant natural resources, but they face threats—especially in a warming climate. Here are a few ways Landsat benefits Nevada.

Nevada↗

From data to interpretable models: Machine learning for soil moisture forecasting

Soil moisture is critical to agricultural business, ecosystem health, and certain hydrologically driven natural disasters. Monitoring data, though, is prone to instrumental noise, wide ranging extrema, and nonstationary response to rainfall where ground conditions change. Furthermore, existing soil moisture models generally forecast poorly for time periods greater than a few hours. To improve such forecasts, we introduce two data-driven models, the Naive Accumulative Representation (NAR) and the Additive Exponential Accumulative Representation (AEAR). Both of these models are rooted in deterministic, physically based hydrology, and we study their capabilities in forecasting soilmoisture over time periods longer than a fewhours. Learned model parameters represent the physically based unsaturated hydrological redistribution processes of gravity and suction. We validate our models using soil moisture and rainfall time series data collected from a steep gradient, post-wildfire site in southern California. Data analysis is complicated by rapid landscape change observed in steep, burned hillslopes in response to even small to moderate rain events. The proposed NAR and AEAR models are, in forecasting experiments, shown to be competitive with several established and state-of-the-art baselines. The AEAR model fits the data well for three distinct soil textures at variable depths below the ground surface (5, 15, and 30 cm). Similar robust results are demonstrated in controlled, laboratory-based experiments. Our AEAR model includes readily interpretable hydrologic parameters and provides more accurate forecasts than existing models for time horizons of 10–24 h. Such extended periods of warning for natural disasters, such as floods and landslides, provide actionable knowledge to reduce loss of life and property.

International Journal of Data Science and Analytic↗

Life zone investigations in Wyoming

Wyoming is among the foremost of our States in its wealth of natural scenery, culminating in the grandeur of Yellowstone National Park, one of the wonders of the world. In addition to this distinction it posseses vast open plains and lofty mountains whence flow the headwaters of mighty river systems emptying far away to the west into the Pacific Ocean, to the southeast into the Gulf of Mexico, and to the southwest into the Gulf of California. The various slope exposures of its mountain ranges, the fertility of its intervening valleys or basins, and the aridity of its desert spaces present a study of geographic and vertical distribution of wild life that is in many particulars unique. The study of geographic and vertical distribution of life with the governing factors and attendant problems is valuable as a matter of scientific research and in the attainment of practical knowledge. The Biological Survey has been making detailed investigations of the transcontinental life belts, or zones, of North America for some years, and this work has been carried on with special reference to their practical value. It has become increasingly evident that life zones furnish a fairly accurate index to average climatic conditions and, therefore, are useful as marking the limits of agricultural possibilities, so far as these are dependent upon climate. The knowledge thus gained has been published and made available as the investigations have progressed and the life zones have been mapped. 1

North American Fauna↗

A bibliometric profile of the Remote Sensing Open Access Journal published by MDPI between 2009 and 2018

Remote Sensing Open Access Journal (RS OAJ) is an international leading journal in the field of remote sensing science and technology. It was first published in the year 2009 and is currently celebrating tenth year of publications. In this research, a bibliometric analysis of RS OAJ was conducted based on 5588 articles published during the 10-year (2009–2018) time-period. The bibliometric analysis includes a comprehensive set of indicators such as dynamics and trends of publications, journal impact factor, total cites, eigenfactor score, normalized eigenfactor, CiteScore, h-index, h-classic publications, most productive countries (or territories) and institutions, co-authorship collaboration about countries (territories), research themes, citation impact of co-occurrences keywords, intellectual structure, and knowledge commutation. We found that publications of RS OAJ presented an exponential growth in the past ten years. From 2010 to 2017 (for which complete years data were available), the h-index of RS OAJ is 67. From 2009–2018, RS OAJ includes publications from 129 countries (or territories) and 3826 institutions. The leading nations contributing articles, based on 2009–2018 data, and listed based on ranking were: China, United States, Germany, Italy, France, Spain, Canada, England, Australia, Netherlands, Japan, Switzerland and Austria. The leading institutions, also for the same period and listed based on ranking were: Chinese Academy of Sciences, Wuhan University, University of Chinese Academy of Sciences, Beijing Normal University, The university of Maryland, National Aeronautics and Space Administration, National Oceanic and Atmospheric Administration, China University of Geosciences, United States Geological Survey, German Aerospace Centre, University of Twente, and California Institute of Technology. For the year 2017, RS OAJ had an impressive journal impact factor of 3.4060, a CiteScore of 4.03, eigenfactor score of 0.0342, and normalized eigenfactor score of 3.99. In addition, based on 2009–2018, data co-word analysis determined that “remote sensing”, “MODIS”, “Landsat”, “LiDAR” and “NDVI” are the high-frequency of author keywords co-occurrence in RS OAJ. The main themes of RS OAJ are multi-spectral and hyperspectral remote sensing, LiDAR scanning and forestry remote sensing monitoring, MODIS and LAI data applications, Remote sensing applications and Synthetic Aperture Radar (SAR). Through author keywords citation impact analysis, we find the most influential keyword is Unmanned Aerial Vehicle (UAV), followed, forestry, Normalized Difference Vegetation Index (NDVI), terrestrial laser scanning, airborne laser scanning, forestry inventory, urban heat island, monitoring, agriculture, and laser scanning. By analyzing the intellectual structure of RS OAJ, we identify the main reference publications and find that the themes are about Random Forests, MODIS vegetation indices and image analysis, etc. RS OAJ ranks first in cited journals and third in citing, this indicates that RS OAJ has the internal knowledge flow. Our results will bring more benefits to scholars, researchers and graduate students, who hopes to get a quick overview of the RS OAJ. And this article will also be the starting point for communication between scholars and practitioners. Finally, this paper proposed a nuanced h-index (nh-index) to measure productivity and intellectual contribution of authors by considering h-index based on whether the one is first, second, third, or nth author. This nuanced approach to determining h-index of authors is powerful indicator of an academician’s productivity and intellectual contribution.

Remote Sensing↗

Fallow-land Algorithm based on Neighborhood and TemporalAnomalies (FANTA) to map planted versus fallowed croplands usingMODIS data to assist in drought studies leading to water and foodsecurity assessments

An important metric to monitor for optimizing water use in agricultural areas is the amount of cropland left fallowed, or unplanted. Fallowed croplands are difficult to model because they have many expressions; for example, they can be managed and remain free of vegetation or be abandoned and become weedy if the climate for that season permits. We used 250 m, 8-day composite Moderate Resolution Imaging Spectroradiometer normalized difference vegetation index data to develop an algorithm that can routinely map cropland status (planted or fallowed) with over 75% user’s and producer’s accuracies. The Fallow-land Algorithm based on Neighborhood and Temporal Anomalies (FANTA) compares the current greenness of a cultivated pixel to its historical greenness and to the greenness of all cultivated pixels within a defined spatial neighborhood, and is therefore transportable across space and through time. This article introduces FANTA and applies it to California from 2001 to 2015 as a case study for use in data-poor places and for use in historical modeling. Timely and accurate knowledge of the extent of fallowing can provide decision makers with insights and knowledge to mitigate the impacts of drought and provide a scientific basis for effective management response. This study is part of the WaterSMART (Sustain and Manage America’s Resources for Tomorrow) project, an interdisciplinary and collaborative research effort focused on improving water conservation and optimizing water use.

California↗

Water management, agriculture, and ground-water supplies

Encyclopedic data on world geography strikingly illustrate the drastic inequity in the distribution of the world's water supply. About 97 percent of the total volume of water is in the world's oceans. The area of continents and islands not under icecaps, glaciers, lakes, and inland seas is about 57.5 million square miles, of which 18 million (36 percent) is arid to semiarid. The total world supply of water is about 326.5 million cubic miles, of which about 317 million is in the oceans and about 9.4 million is in the land areas. Atmospheric moisture is equivalent to only about 3,100 cubic miles of water. The available and accessible supply of ground water in the United States is somewhat more than 53,000 cubic miles (about 180 billion acre ft). The amount of fresh water on the land areas of the world at any one time is roughly 30,300 cubic miles and more than a fourth of this is in large fresh-water lakes on the North American Continent. Annual recharge of ground water in the United States may average somewhat more than 1 billion acre-feet yearly, but the total volume of ground water in storage is equivalent to all the recharge in about the last 160 years. This accumulation of ground water is the nation's only reserve water resource, but already it is being withdrawn or mined on a large scale in a few areas. The principal withdrawals of water in the United States are for agriculture and industry. Only 7.4 percent of agricultural land is irrigated, however; so natural soil moisture is the principal source of agricultural water, and on that basis agriculture is incomparably the largest water user. In view of current forecasts of population and industrial expansion, new commitments of water for agriculture should be scrutinized very closely, and thorough justification should be required. The 17 Western States no longer contain all the large irrigation developments. Nearly 10 percent of the irrigated area is in States east of the western bloc, chiefly in several Southeastern States. Ground water is not completely 'self-renewing' because, where it is being mined, the reserve is being diminished and the reserve would be renewed only if pumping were stopped. Water is being mined at the rate of 5 million acre-feet per year in Arizona and 6 million in the High Plains of Texas. In contrast, water has been going into storage in the Snake River Plain of Idaho, where deep percolation from surface-water irrigation has added about 10 million acre-feet of storage since irrigation began. Situations in California illustrate problems of land subsidence resulting from pumping and use of water, and deterioration of ground-water reservoirs due to sea-water invasion. Much water development in the United States has been haphazard and rarely has there been integrated development of ground water and surface water. Competition is sharpening and new codes of water law are in the making. New laws, however, will not prevent the consequences of bad management. An important task for water management is to recognize the contingencies that may arise in the future and to prepare for them. The three most important tasks at hand are to make more efficient use of water, to develop improved quantitative evaluations of water supplies arid their quality, and to develop management practices which are based on scientific hydrology.

Circular↗

Linking selenium sources to ecosystems: San Francisco Bay-Delta Model

Marine sedimentary rocks of the Coast Ranges contribute selenium to soil, surface water, and ground water in the western San Joaquin Valley, California. Irrigation funnels selenium into a network of subsurface drains and canals. Proposals to build a master drain (i.e., San Luis Drain) to discharge into the San Francisco Bay-Delta Estuary remain as controversial today as they were in the 1950s, when drainage outside the San Joaquin Valley was first considered. An existing 85-mile portion of the San Luis Drain was closed in 1986 after fish mortality and deformities in ducks, grebes and coots were discovered at Kesterson National Wildlife Refuge, the temporary terminus of the drain. A 28-mile portion of the drain now conveys drainage from 100,000 acres into the San Joaquin River and eventually into the Bay-Delta. If the San Luis Drain is extended directly to the Bay-Delta, as is now being proposed as an alternative to sustain agriculture, it could receive drainage from an estimated one-million acres of farmland affected by rising water tables and increasing salinity. In addition to agricultural sources, oil refineries also discharge selenium to the Bay-Delta, although those discharges have declined in recent years. To understand the effects of changing selenium inputs, scientists have developed the Bay-Delta Selenium Model.

California↗

Development and application of downscaled hydroclimatic predictor variables for use in climate vulnerability and assessment studies

This paper outlines the production of 270-meter grid-scale maps for 14 climate and derivative hydrologic variables for a region that encompasses the State of California and all the streams that flow into it. The paper describes the Basin Characterization Model (BCM), a map-based, mechanistic model used to process the hydrological variables. Three historic and three future time periods of 30 years (1911&ndash;1940, 1941&ndash;1970, 1971&ndash;2000, 2010&ndash;2039, 2040&ndash;2069, and 2070&ndash;2099) were developed that summarize 180 years of monthly historic and future climate values. These comprise a standardized set of fine-scale climate data that were shared with 14 research groups, including the U.S. National Park Service and several University of California groups as part of this project. We present three analyses done with the outputs from the Basin Characterization Model: trends in hydrologic variables over baseline, the most recent 30-year period; a calibration and validation effort that uses measured discharge values from 139 streamgages and compares those to Basin Characterization Model-derived projections of discharge for the same basins; and an assessment of the trends of specific hydrological variables that links historical trend to projected future change under four future climate projections. Overall, increases in potential evapotranspiration dominate other influences in future hydrologic cycles. Increased potential evapotranspiration drives decreasing runoff even under forecasts with increased precipitation, and drives increased climatic water deficit, which may lead to conversion of dominant vegetation types across large parts of the study region as well as have implications for rain-fed agriculture. The potential evapotranspiration is driven by air temperatures, and the Basin Characterization Model permits it to be integrated with a water balance model that can be derived for landscapes and summarized by watershed. These results show the utility of using a process-based model with modules representing different hydrological pathways that can be inter-linked.

California↗

Distribution of nitrate in the unsaturated zone, Highland-East Highlands area, San Bernardino County, California

Nitrogen in the unsaturated soil zone in the Highland-East Highlands area of San Bernardino County, Calif., has been suspected as the source of nitrate in water from wells. Plans to recharge the local aquifers with imported surface water would raise the water table and intercept that nitrogen. This study was made to describe the distribution of inorganic nitrogen and other chemical constituents and nitrogen-using bacteria in the unsaturated zone, to relate nitrogen occurrences, in a general way, to present and historical land use, and to attempt to predict nitrogen concentrations in ground water after recharge. Some generalized correlations between nitrogen occurrence and land use were observed. In 11 of 13 test holes, the maximum nitrate-nitrogen (NO 3 - -N) concentrations occurred within 10 feet of the surface, suggesting that the major source of nitrogen is from the surface at these sites. Test holes were ranked according to maximum NO 3 - -N in the top 10 feet, total NO 3 - -N in the top 10 feet, and total NO 3 - -N in the top 40 feet. In all three rankings, the top seven test holes were the same--five in or near present or historical agricultural areas (primarily citrus groves), one in a feedlot, and one adjacent to an abandoned sewage-treatment plant. Two test holes in historically uninhabited areas ranked lowest. The control test hole in an uninhabited area ranked high in geometric mean of ammonium-nitrogen concentration (NH 4 + -N), suggesting that present in freshly weathered granite. The geometric means of NH 4 + -N concentrations in six of eight citrus-related test holes were significantly lower than in the control hole, suggesting that irrigation in citrus groves may have created conditions favoring nitrification of the primary NH 4 + -N. Rank correlation analyses between various measurements in test holes showed that high NO 3 - -N concentrations tend to occur with high specific conductance and chloride concentrations in soil extracts. If recharge is carried out as planned, assuming complete mixing of the recharge water and interstitial pore water in the top 20 feet of the saturated zone, NO 3 - -N concentrations in water at the top of the saturated zone may exceed 10 milligrams per liter in seven areas studied. Concentrations could reach as high as 66 milligrams per liter in the worst case projected. The highest concentrations may be found in three areas that are now, or were recently, citrus groves.

California↗

Selenium and other elements in juvenile striped bass from the San Joaquin Valley and San Francisco Estuary, California

Concentrations of selenium and other trace elements were determined in 55 whole body samples of juvenile anadromous striped bass ( Morone saxatilis ) from the San Joaquin Valley and San Francisco Estuary, California. The fish (&le;1 yr old&mdash;the predominant life stage in the San Joaquin Valley) were collected in September&ndash;December 1986 from 19 sites in the Valley and 3 sites in the Estuary, and analyzed for the following elements: aluminum (Al), arsenic (As), boron (B), barium (Ba), beryllium (Be), cadmium (Cd), chromium (Cr), copper (Cu), iron (Fe), mercury (Hg), magnesium (Mg), molybdenum (Mo), nickel (Ni), lead (Pb), selenium (Se), strontium (Sr), vanadium (V), and zinc (Zn). When compared to concentrations in whole freshwater fish measured by surveys from other waters, a few samples contained higher levels, of As, Cd, Cu, Pb, and Se. The median concentrations of Al, As, Cu, Fe, Mg, Se, and Sr also differed significantly ( P ⩽0.05) among sites. However, only Se concentrations were highest (up to 7.9 &mu;g/g dry weight) in samples from Valley sites exposed to agricultural subsurface (tile) drainwater; concentrations were lower in samples collected elsewhere. Water quality variables&mdash;especially those strongly influenced by tile drainwater (conductivity, total dissolved solids, total alkalinity, and total hardness)&mdash;were also significantly correlated ( P ⩽0.05) with Se concentrations in fish. Selenium concentrations in striped bass from the Estuary were only one-fourth to one-half the concentrations measured in the most contaminated fish from the San Joaquin River.

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