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State shifts in the deep Critical Zone drive landscape evolution in volcanic terrains

Understanding the near-surface environment where atmospheric and solid earth processes interact, often termed the “Critical Zone,” is important for assessing resources and building resilient societies. Here, we examine a volcanic landscape in the Oregon Cascade Range, an understudied Critical Zone setting that is host to major regional water resources, pervasive silicate weathering, and significant geohazards. We leverage a bedrock age chronosequence to show that the volcanic Critical Zone undergoes a structural shift, from depth extents of >1 km to meters, over timescales of ~1 My. We map an active groundwater volume comparable to major continental lakes, stored at the Cascade Range crest. This state shift makes volcanic landscape evolution a unique probe of deep coupling between Earth systems.

PNAS

Volcanic gas monitoring

Introduction As magma rises through the crust, decreasing pressure conditions allow volatiles to exsolve from the magma. These volatiles then migrate upward through the crust, where they can be stored at shallower levels or escape to the atmosphere. Rising magma also heats rock masses beneath volcanic centers, causing water in shallow aquifers and hydrothermal systems to boil and release additional gases and steam (see chapter F , this volume; Ingebritsen and Hurwitz, 2024). The chemistry and quantity of gases that reach the surface during periods of quiescence or volcanic unrest can reveal that gas-rich magma is ascending, crystallizing, or alternatively stalling, with important implications for volcanic hazard (for example, Sutton and others, 1992; Aiuppa and others, 2007, 2021; Werner and others, 2009, 2011, 2012; Moretti and others, 2013; de Moor and others, 2016; Lewicki and others, 2019; Edmonds and others, 2022; Kern and others, 2022; Kunrat and others, 2022). Most volcanoes in Alaska and the western United States are characterized by weak degassing, with one or more low-temperature fumaroles (typically near the local boiling temperature of water) and connect to a deeper and sometimes extensive hydrothermal system (for example, McGee and others, 2001; Symonds and others, 2003a, b). Hydrothermal systems will affect the chemistry of rising gases exsolved from deeper magma (Symonds and others, 2001), including sulfur dioxide (SO 2 ), hydrogen chloride (HCl), and water vapor (for example, Doukas and Gerlach, 1995; Gerlach and others, 1998, 2008; Symonds and others, 2001; Werner and others, 2013). As an example, depending on factors such as temperature, pressure, and oxidation state, rising SO 2 will react with groundwater to form hydrogen sulfide (H 2 S) gas, dissolved sulfate (SO 4 2− ), or elemental sulfur (Christenson, 2000; Symonds and others, 2001; Werner and others, 2008). The reaction and dissolution of SO 2 into shallow groundwater is commonly referred to as scrubbing, and can reduce the likelihood that ascending, degassing magma can be detected. Carbon dioxide, however, in addition to exsolving from magma early in the ascent process, is not easily removed by hydrothermal fluids (Lowenstern, 2001). As scrubbing and other processes take place, the SO 2 /H 2 S, CO 2 /SO 2 , and CO 2 /H 2 S ratios may change. High rates of SO 2 emission indicate that magma has moved to relatively shallow levels in the volcano and that the system has heated up enough to establish dry pathways from depth to the surface. Monitoring multiple gas species and the total output of those species is thereby useful for volcano monitoring during both periods of quiescence, to establish background degassing conditions, and during unrest, when gas geochemistry and emission rates can provide information on changing conditions, such as magma ascent. To provide context for multidisciplinary volcano forecasts, we focus on the following two key required capabilities: (1) characterizing baseline geochemistry and gas discharge from volcanoes and volcanic regions and (2) monitoring changes in gas geochemistry and discharge to inform forecasts of volcanic eruptions and their effects. Sufficient baseline data must be collected to identify and interpret anomalous degassing associated with volcanic unrest (for example, Sorey and others, 1998; Rouwet and others, 2014). Differences in volcano type, baseline degassing rates, local hydrology, and geography (for example, high versus low latitude) will result in a different baseline for each volcano. Volcanoes of any threat level that exhibit one or more degassing phenomena would ideally be monitored by techniques needed to establish baseline degassing data, with the sampling frequency of baseline data dictated by the threat level (table E1). Additional monitoring techniques become necessary during periods of unrest. In general, three of the most important techniques for gas monitoring are (1) direct sampling of fumarole, spring, and soil gases for laboratory geochemical measurements, (2) measurements of the chemical composition of the volcanic plume and emission rates of major gas species (for example, H 2 O, CO 2 , SO 2 , and H 2 S) by satellite, airborne, or ground-based techniques, and (3) measurements of diffuse emissions of CO 2 and other gases through soils. Various methods and instruments may be useful both for baseline studies and during unrest.

Scientific Investigations Report

Hydrogeologic mapping and three-dimensional geologic modeling of glacial deposits in a multicounty area of southeastern Michigan, northeastern Indiana, and northwestern Ohio

The glacial deposits underlying southeastern Michigan, northeastern Indiana, and northwestern Ohio are a substantial source of water to communities, agriculture, and industry in the region. Previous efforts to characterize aquifer materials in the area cited a need for additional information about the underlying hydrogeologic characteristics and related groundwater availability as well as improved mapping of the extent and properties of the glacial deposits. Recent U.S. Geological Survey multi-State compilations of water-well drilling records have greatly increased access to high-resolution geologic data, particularly in glacial depositional environments. This study by the U.S. Geological Survey, in cooperation with the Ohio Environmental Protection Agency, uses processed data from the State-managed collections of well records to characterize the glacial deposits in the study area using two methods. The first method creates two-dimensional maps of basic hydrogeologic information commonly required for assessments of groundwater availability, including (1) total thickness of glacial deposits, (2) total thickness of coarse-grained deposits, (3) specific-capacity-based transmissivity and hydraulic conductivity, and (4) texture-based estimated equivalent horizontal and vertical hydraulic conductivity and transmissivity. The second method builds a hydrogeologic framework of the complex glacial aquifer through construction of a volumetric geologic model by using three-dimensional kriging. Results of the volumetric model indicate that aquifer materials are primarily concentrated in the western parts of the study area near the Indiana-Ohio border. Coarse-grained sediments are also present as surficial deposits in the north of the study area where intermixing glacial advances created complex distributions of unconsolidated deposits. Two-dimensional maps of hydrogeologic properties support the volumetric model, showing thicknesses of coarse-grained deposits that reach up to 250 feet in the western sections of the study area and progressively thin to near absence in the east. Visualization of the aquifer materials with a volumetric model generally shows a highly discontinuous distribution of coarse- and fine-grained materials, with no clearly defined boundaries to delineate the extent of the aquifer. Comparisons of cross sections derived from the volumetric model with existing published maps support previous near-surface hydrogeologic interpretations while filling gaps where data are sparse, particularly in deeper parts of the aquifer. Both the two-dimensional maps and the volumetric model provide data that can directly inform assessments of groundwater availability, in addition to having future applications to studies of groundwater flow and transport.

Indiana, Michigan, Ohio

The 3D Elevation Program—Supporting Ohio's economy

Introduction High-quality elevation data are proving to be a resource of great economic value in dealing with many important issues in Ohio. Current and accurate high-resolution elevation data support flood risk management, water quantity and quality assessment, precision farming, conservation planning, impervious-surface modeling, forest and other natural resources management, abandoned mine and geologic hazard assessment, karst mapping, and siting of wellhead pads for horizontal drilling. These data also support coastal zone management, traffic safety and preliminary engineering site-selection studies for transportation infrastructure, solar potential and other renewable energy planning, aviation safety, and identification of features of interest or concern such as archaeological sites and orphan oil and gas wells. Critical applications that meet the State’s management needs depend on light detection and ranging (lidar) data that provide a highly detailed three-dimensional (3D) model of the Earth’s surface and aboveground features.

Ohio

Editorial: From cold seeps to hydrothermal vents: Geology, chemistry, microbiology, and ecology in marine and coastal environments

This Research Topic compiles contemporary studies on cold seeps, hydrothermal vents, mud volcanoes, and related seafloor features that are associated with focused fluid emissions and the transfer of carbon, other chemical species, and sometimes heat from the geosphere to the ocean. Because these features sometimes tap fluids and gas originating kilometers below the seafloor, they provide an important window into deep processes that are otherwise inaccessible to scientists. At the shallow portion of their journey, migrating fluids nearing the seafloor contribute to a range of unique biological, physical, and chemical processes within the sediments themselves and at the sediment-water interface. Seafloor fluid emissions play a critical role in global biogeochemical cycles, ocean chemistry, and possibly even climate change. Seafloor leakage points often emit hydrocarbon gases (especially methane and CO 2 ) and are sometimes the loci for deposition of seafloor minerals that have economic value. A burgeoning area of research focuses on natural products generated at these features, seeking compounds with potential pharmaceutical or other applications. Multidisciplinary studies have become routine for characterization of seafloor fluid emission sites, attesting to the inseparability of geologic, physical, chemical, and biological processes in these settings. It is increasingly common for researchers to combine in a single research cruise: subbottom imaging and seafloor mapping; porewater and water column geochemistry and gas sampling; sediment retrieval for lithologic, biostratigraphic, and solid phase analyses; and studies of benthic and subseafloor communities at the microbial to macrofaunal scales. This multidisciplinary approach has the advantage of ensuring the spatial and temporal coincidence of surveys and samples, an important factor at highly dynamic seafloor fluid emission sites. In addition, researchers often use remotely operated vehicles (ROVs), autonomous underwater vehicles (AUVs), or human-occupied vehicles (HOVs) to record video of the seafloor, compile photomosaics, collect targeted samples, and survey with high-resolution geophysical near-seafloor systems, providing a degree of detail about seafloor fluid emission sites that is unprecedented compared to most areas of the deep ocean. While rarer, long-term cabled observatories or shorter-term deployments of portable observatories are also used at some loci for seafloor fluid flux and are particularly helpful for capturing temporal variations at these dynamic features. Here we summarize the Research Topic’s contribution to multidisciplinary seafloor emission studies in the categories of cold seeps, mud volcanoes, and hydrothermal vents. Figure 1 shows the geographic distribution of the studies in this Research Topic and key features referred to in this Introduction.

Frontiers in Earth Science

Assessment of density pattern retention of generalized data for 1:100,000-scale United States topographic maps

Cartographic generalization reduces the complexity of geographic data to produce legible, smaller-scale displays that retain essential information and logical geographic patterns. Generalization is a vital process in topographic map production. An important challenge in this process is managing and evaluating consistency across scale in the density and spatial distribution of map features such as buildings, roads, streams, water bodies, and elevation contours. Density patterns in these features reflect underlying physiographic conditions, which include factors such as bedrock geology, tectonics, climate, and landforms. Assessments of an acceptable level of change in feature density patterns are critical to ensuring the readability, usability, and accuracy of generalized maps and data. Preserving realistic density patterns across mapping scales also supports sustainable development goals in cartography, by helping to prioritize and communicate the relative reliability of geospatial data at specific scales.

Conference Paper

Neutron activation analysis in hydrology

Neutron activation analysis in hydrogeochemical and related investigations is increasingly practical because of developments in radiation detectors and computerized data processing. While neutron activation is the most widely used kind of activation analysis other kinds (for example, charged particle activation) are available for special applications. Neutron activation analysis is promising because approximately 70 percent of the elements in the periodic table are detected with satisfactory sensitivity, contamination from reagents is eliminated, simultaneous determination of more than 20 elements is often possible, technique is versatile, is applicable to small samples and is non-destructive in the instrumental form. Developments in theU.S. Geological Survey include a special sampling technique for water; a comprehensive technique using carriers precipitated with sulfide to concentrate desired trace elements; a determination of mercury, silver, and gold; determination of aluminum, vanadium and nine other elements; determinations of two groups of rare earth elements; and adaptations of the analytical methods to sediment and biota.

Open-File Report

Hydrogeology of stratified drift in Farmington, Connecticut: Available data and future needs

The purpose of this report is twofold. The first is to update hydrogeologic information on the major stratified-drift deposits that underlie much of Farmington. The second is to outline data requirements for future ground-water evaluation and management. The scope of the report is limited to the stratified drift, as it is the only aquifer capable of sustaining large withdrawals for public or industrial supply. This aquifer is composed of interbedded layers of gravel, sand, silt and clay. Most of this material was deposited by glacial meltwaters, but locally the aquifer contains some unconsolidated deposits of nonglacial origin. The most extensive stratified-drift deposits are in the valleys of the Farmington and Pequabuck Rivers.(See plate B.) A few small areas of stratified drift near East Farmington Heights and Oakland Gardens are not discussed in this report as their potential for large-scale development is slight.

Connecticut

Anomalous shear stress variation in wet granular medium: Implications for landslide lateral faults

Landslide assessments typically focus on the mechanical properties of the basal shear zone, but lateral faults are frequently overlooked, possibly due to their lower normal stresses and variably saturated conditions. Using double-cylinder shear experiments on wet granular systems as analogs for landslide lateral faults, we observe anomalous shear stress variations with fluid volume fractions, defying an expected unimodal relationship associated with capillary cohesion. At low fluid volume fractions, shear strength weakens as the wet grain assembly experiences reduced lateral pressure and increased boundary slip. This boundary slip subsequently vanishes, with an abrupt strengthening due to the dilation of the grain assembly against fluid surface tension as saturation approaches. Strike-slip motion and confinement in this system explain the strength anomaly, highlighting a critical role of lateral faults in landslide stability, particularly in cases where dynamics cannot be adequately explained by monitored pore-water pressure or basal friction.

Geophysical Research Letters

Estimated groundwater recharge for mid-century and end-of-century climate projections, Kaua‘i, O‘ahu, Moloka‘i, Lāna‘i, Maui, and the Island of Hawai‘i

Demand for freshwater in the State of Hawaiʻi is expected to increase by roughly 13 percent from 2020 to 2035. Groundwater availability in Hawaiʻi is affected by a number of factors, including land cover, rainfall, runoff, evapotranspiration, and climate change. To evaluate the availability of fresh groundwater under projected future-climate conditions, estimates of groundwater recharge are needed. A water-budget model with a daily computation interval was used to estimate the spatial distribution of groundwater recharge for Kauaʻi, Oʻahu, Molokaʻi, Lānaʻi, Maui, and the Island of Hawaiʻi for recent climate conditions and three future-climate scenarios. Climate conditions from 1978 to 2007 were used as the reference period for recent climate conditions on each island. The three future-climate scenarios were developed using available high-resolution downscaled climate projections that include (1) a mid-century scenario using projected rainfall conditions for the Representative Concentration Pathway (RCP) scenario during 2041–71 with a total radiative forcing of 8.5 watts per square meter by the year 2100 (RCP8.5 2041–71 scenario), (2) a dry-climate scenario using projected rainfall conditions for the RCP8.5 scenario during 2071–99, and (3) a wet-climate scenario using projected rainfall conditions for the “Special Report on Emissions Scenarios” A1B scenario during 2080–99 for Maui, the RCP4.5 scenario during 2080–99 for Kauaʻi, Lānaʻi, and the Island of Hawaiʻi, and the RCP8.5 scenario during 2080–99 for Oʻahu and Molokaʻi. An additional drought scenario was added for Lānaʻi to assess the effect of extreme drought conditions during 2008–12 on groundwater recharge. All scenarios used 2020 land cover. Mean annual groundwater recharge is estimated to decrease between 5 and 55 percent on all six islands in this study for the mid-century and dry-climate scenarios relative to the reference-period recharge. Recharge is estimated to increase for Kauaʻi, Oʻahu, Molokaʻi, Lānaʻi, and Maui between 2 and 43 percent and decrease for the Island of Hawaiʻi by about 4 percent for the wet-climate scenario. Comparing the mid-century and dry-climate scenarios, all 110 aquifer systems (management areas defined by the State of Hawaiʻi Commission on Water Resource Management) from all six islands show similar direction in drying (104 aquifer systems) or wetting (6 aquifer systems) changes for recharge. However, among the three future scenarios, only 35 of 110 aquifer systems show similar direction in drying (30 aquifer systems) or wetting (5 aquifer systems) changes for recharge.

Hawaii

Base-flow sampling to enhance understanding of the groundwater flow component of nitrogen loading in small watersheds draining into Long Island Sound

Excessive nitrogen discharge is a major concern for the Long Island Sound. Programs have been implemented to reduce point sources of nitrogen to the sound, but little is known about the nonpoint sources. This study aims to better understand the current groundwater contributions of nitrogen from nonpoint sources in the Long Island Sound watershed. During the spring and summer of 2022, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, collected water-quality samples to analyze nutrients (nitrogen and phosphorus), chloride, and bromide at 45 stations in the Long Island Sound watershed in Connecticut, New York, and Rhode Island. The stations were in small drainage watersheds (5 to 30 square kilometers) in the southern part of the Long Island Sound watershed. During two separate synoptic sampling events, water-quality samples and instantaneous streamflow measurements were collected under base-flow conditions (where the streamflow is dominated by groundwater inputs rather than overland flow or runoff flow). One sampling event was in the nongrowing season (April 24–25, 2022), and the other was in the growing season (June 30–July 1, 2022). To calculate instantaneous nitrogen loads and yields, streamflow was measured at the time of sample collection. Nitrogen concentrations, loads, and yields varied among sampling stations and by season. Total filtered nitrogen concentrations were generally lower in the nongrowing season (from less than 0.14 to 1.9 milligrams per liter) than in the growing season (from less than 0.23 to 3.0 milligrams per liter). Nitrate plus nitrite concentrations showed little variation between the nongrowing and growing seasons. Unfiltered ammonia plus organic nitrogen concentrations were generally lower in the nongrowing season (from less than 0.07 to 0.83 milligram per liter) than in the growing season (from 0.11 to 0.98 milligram per liter). In contrast, total filtered and unfiltered nitrogen loads and yields were higher in the nongrowing season than during the growing season, likely because streamflows were higher during the nongrowing season. Total unfiltered nitrogen yields during the nongrowing season ranged from less than 0.15 to 5.0 kilograms per square kilometer per day. Total unfiltered nitrogen yields during the growing season ranged from less than 0.12 to 2.5 kilograms per square kilometer per day. Total filtered nitrogen yields during the nongrowing season ranged from less than 0.13 to 5.2 kilograms per square kilometer per day. Total filtered nitrogen yields during the growing season ranged from less than 0.06 to 2.5 kilograms per square kilometer per day.

Connecticut, New York, Rhode Island

U.S. Geological Survey—Department of the Interior, Region 11, Alaska—2023–24 biennial science report

Introduction U.S. Geological Survey (USGS) Mission—The USGS national mission is to monitor, analyze, and predict the current and evolving dynamics of complex human and natural Earth-system interactions and to deliver actionable information at scales and timeframes relevant to decision makers. Consistent with the national mission, the USGS in Alaska provides timely and objective scientific information to help address issues and inform management decisions across five interconnected focus areas: Energy and Minerals; Geospatial Mapping; Natural Hazards; Water Quality, Streamflow, and Ice Dynamics; and Ecosystems. The USGS in Alaska consists of approximately 350 scientists and support staff working in 3 Alaska-based science centers. USGS science activities are also initiated by the Cooperative Research Unit and USGS centers outside Alaska. In the last 5 years, USGS research in Alaska has produced many scientific benefits resulting from more than 900 publications. Publications relevant to Alaska can be conveniently searched by keyword through the USGS Publications Warehouse at https://pubs.usgs.gov/.

Alaska

A robust quantitative method to distinguish runoff-generated debris flows from floods

Debris flows and floods generated by rainfall runoff occur in rocky mountainous landscapes and burned steeplands. Flow type is commonly identified post-event through interpretation of depositional structures, but these may be poorly preserved or misinterpreted. Prior research indicates that discharge magnitude is commonly amplified in debris flows relative to floods due to volumetric bulking and increased frictional resistance. Here, we use this flow amplification to develop a metric ( Q* ) to separate debris flows from floods based on the ratio of observed peak discharge to the theoretical maximum water discharge from rainfall runoff. We compile 642 observations of floods and debris flows and demonstrate that Q* distinguishes flow type to ∼92% accuracy. Q* allows for accurate identification of debris flows through simple channel cross-section surveys rather than through qualitative interpretation of deposits, and therefore should increase the performance of models and engineered structures that require accurate flow-type observations.

Geophysical Research Letters

The role of bedrock circulation depth and porosity in mountain streamflow response to prolonged drought

Quantitative understanding is lacking on how the depth of active groundwater circulation in bedrock affects mountain streamflow response to a multi‐year drought. We use an integrated hydrological model to explore the sensitivity of a variety of streamflow metrics to bedrock circulation depth and porosity under a plausible extreme drought scenario lasting up to 5 years. Endmember depth versus hydraulic conductivity relationships and porosity values for fractured crystalline rock are simulated. With drought, a deeper circulation system with higher drainable porosity more effectively buffers minimum flow and significantly limits perennial stream loss in comparison to a shallow circulation system. Streamflow buffering is accomplished through extensive groundwater storage loss. However, deeper circulation systems experience prolonged recovery from drought in comparison to storage‐limited shallow systems. Research highlights the importance of characterizing the deeper bedrock hydrogeology in mountainous watersheds to better understand and predict drought impacts on stream ecosystem health and water resource sustainability.

Colorado

Hydroacoustic observations reveal drivers of mixing and salinization of a karst subterranean estuary during intense precipitation

Karst subterranean estuaries within globally ubiquitous carbonate aquifers are coastal groundwater ecosystems that provide an essential water resource for human populations. To understand the drivers of salinization within a coastal aquifer in the Yucatan Peninsula (Mexico), we employed hydroacoustics in flooded caves to observe how oceanic and atmospheric events facilitate mixing between the meteoric lens (fresh-brackish groundwater) and the saline groundwater on tidal and episodic timescales. Precipitation during Tropical Storm Carlotta increased the flow and salinity of the meteoric lens without evidence for vertical mixing across the halocline. We postulate that vertical migration of haloclines in the conduit relative to those within the rock matrix during precipitation creates lateral density gradients that drive mixing, and ultimately creates a brackish layer within the meteoric lens. These results provide a mechanistic explanation for vertical and lateral exchange in a coastal carbonate aquifer, which has implications for groundwater response to future climatic change.

Ox Bel Ha cave system, Yucatan peninsula

Bølling-Allerød productivity in the subarctic Pacific driven by seasonal upwelling

The Bølling-Allerød deglacial event is marked by high diatom productivity and opal deposition throughout the subarctic Pacific. This opal could either constitute a strengthened biological pump and thus carbon sequestration, or a weakened biological pump and release of marine-sequestered CO 2 to the atmosphere. We quantify silicic acid supply at IODP Site U1340 in the Bering Sea using biogenic opal and δ 30 Si of Coscinodiscus , a diatom genus. These records, along with diatom environmental indicators, suggest the Bølling-Allerød had high silicic acid availability related to a shift from stratification to seasonal upwelling dynamics. We thus propose the primary cause of the high productivity event was increased macronutrient supply from vertical exchange that injected old, nutrient-rich, CO 2 -rich waters into the surface. Enhanced CO 2 release from the subarctic Pacific may help explain critical intervals of CO 2 rise that occur at the onsets of the Bølling-Allerød and PreBoreal.

Geophysical Research Letters

The saline groundwater legacy of a large buried coastal paleo-estuary

Elevated groundwater salinity in coastal regions threatens the beneficial use of fresh groundwater. Coastal groundwater management typically focuses on preventing intrusion from modern sources of seawater; however, past geological processes can also leave a legacy of saline groundwater now hidden in the subsurface. Here, multiple extensive airborne electromagnetic surveys provide detailed evidence of residual salinity from a paleo-estuary filling a late Pleistocene incised valley impacting more than 10,000 km 2 that is now hidden beneath coastal Louisiana’s deltaic plain. Our results show that the three-dimensional pattern of saline groundwater beneath Louisiana mimics that of near-surface aquifers surrounding the modern Delaware Bay estuary, fingerprinting the signature of the past drowning of a large, incised valley of the Mississippi River following post-glacial sea-level rise. These findings demonstrate a new framework for understanding legacy sources of saltwater critical for managing stressed water resources along global coastlines.

Louisiana

Gulf Coast Basin CORE-CM initiative final report

The Bureau of Economic Geology at the University of Texas at Austin (UT-BEG) is leading the Gulf Coast Carbon Ore, Rare Earth, and Critical Minerals (CORE-CM) Initiative to assess the potential to produce critical minerals (CMs), including rare earth elements (REEs) from coal, coal ash, and produced water related to oil and gas production, and related materials (alumina processing waste [red mud], heavy mineral sands, graphite, and zeolite) within the Gulf Coast Basin. This project represents the first phase in a long-term program and provides reconnaissance data that will be foundational for future work by assessing resources and suggesting plans to be conducted in future work and expanding stakeholder engagement. The project includes several tasks designed to identify, characterize, and assess several necessary aspects for development of CMs and REEs in the Gulf Coast Basin.

Gulf Coast basin