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At least 541 records · Page 30Linked to original sources

Greenhouse gas balances in coastal ecosystems: Current challenges in “blue carbon” estimation and significance to national greenhouse gas inventories

Coastal wetlands are defined herein as inundated, vegetated ecosystems with hydrology, and biogeochemistry influenced by sea levels, at timescales of tides to millennia. Coastal wetlands are necessary components of global greenhouse gas estimation and scenario modeling, both for continental and oceanic mass balances. The carbon pools and fluxes on coastal lands, especially those influenced by tidal drivers and sea level rise, are distinct in their magnitude, rates, and uncertainties. We describe herein the pathways taken for a US scale estimation of blue carbon based on annual timesteps and bottom-up modeling, as appropriate for the first effort to include coastal wetlands in the Intergovernmental Panel on Climate Change (IPCC) guidelines for a National Greenhouse Gas Inventory (NGGI). As such, we summarize multiple efforts to reconcile mapping, modeling, and measurement issues and we report the assumptions we made based on data availability. Provided as requested feedback to the IPCC. Subsidiary Body for Scientific and Technological Advice (SBSTA) evaluation of guidance criteria, these analyses synergistically point scientists, practitioners, and policy makers toward the greatest uncertainties to address in future assessments: coastal wetland methane emissions and carbon dioxide emissions associated with the fate of eroded soil. This is a story of what was learned in the 2014–2018 NASA Carbon Monitoring System project (https://carbon.nasa.gov/cgi-bin/cms_projects.pl), how it informs “good practice” (IPCC 2006) in reporting coastal wetland emissions and removals, and where it points scientifically toward data needs at different temporal and spatial scales.

Book chapter↗

Does geomorphology determine vulnerability of mangrove coasts to sea-level rise?

The greatest climate-based threat to coastlines worldwide is sea-level rise. We tested the hypothesis that tropical coasts fringed by mangroves and receiving high inputs of terrigenous sediment are less vulnerable to sea-level rise than biogenic systems dependent upon peat formation for vertical land development. An analysis of published data spanning a range of geomorphic settings showed that mineral accretion was a poor predictor of vulnerability to rising sea level. We additionally compared two oceanic island systems representing two extremes along this sediment gradient to further examine controls on elevation dynamics in minerogenic versus biogenic mangrove systems. Minerogenic systems characterized by intermediate to high rates of mineral sedimentation (Pacific high islands in Micronesia) were not better buffered against sea-level rise because of high subsidence rates. Peat-forming systems (Caribbean low islands in Belize) kept pace with relative sea-level rise (combined ocean and land movements) because of subsurface expansion driven by root matter accumulation. The data were not consistent with the paradigm that tropical coastlines characterized by peat-forming mangroves are generally more vulnerable to sea-level rise compared to minerogenic systems; however, they are not necessarily equally sensitive to the same external and internal forces controlling soil elevations. Our findings demonstrate that reliance on surface accretion data alone can lead to an inaccurate evaluation of coastal vulnerability and why all surface and subsurface land movements must be considered in relation to local sea-level trends to assess risk of submergence. Recognition of such differences is essential to proper management of tropical coastlines to ensure their resilience in the face of future sea-level rise.

Book chapter↗

Standing crop and aboveground biomass partitioning of a dwarf mangrove forest in Taylor River Slough, Florida

The structure and standing crop biomass of a dwarf mangrove forest, located in the salinity transition zone ofTaylor River Slough in the Everglades National Park, were studied. Although the four mangrove species reported for Florida occurred at the study site, dwarf Rhizophora mangle trees dominated the forest. The structural characteristics of the mangrove forest were relatively simple: tree height varied from 0.9 to 1.2 meters, and tree density ranged from 7062 to 23 778 stems haa??1. An allometric relationship was developed to estimate leaf, branch, prop root, and total aboveground biomass of dwarf Rhizophora mangle trees. Total aboveground biomass and their components were best estimated as a power function of the crown area times number of prop roots as an independent variable (Y = B ?? Xa??0.5083). The allometric equation for each tree component was highly significant (p<0.0001), with all r2 values greater than 0.90. The allometric relationship was used to estimate total aboveground biomass that ranged from 7.9 to 23.2 ton haa??1. Rhizophora mangle contributed 85% of total standing crop biomass. Conocarpus erectus, Laguncularia racemosa, and Avicennia germinans contributed the remaining biomass. Average aboveground biomass allocation was 69% for prop roots, 25% for stem and branches, and 6% for leaves. This aboveground biomass partitioning pattern, which gives a major role to prop roots that have the potential to produce an extensive root system, may be an important biological strategy in response to low phosphorus availability and relatively reduced soils that characterize mangrove forests in South Florida.

Florida↗

Hydrologic investigations of green infrastructure by the Central Midwest Water Science Center

The water management system within developed communities includes stormwater, wastewater, and drinking-water sources and sinks. Each water management system component provides critical services that support public health in these areas. Stormwater can be quite variable and difficult to manage in developed communities because the amount of stormwater that must be routed through a developed area depends on changing land cover and variable precipitation. In addition to flooding concerns, stormwater also is a major cause of water contamination in developed communities because it carries contaminants such as trash, bacteria, heavy metals, and sediments to local waterways. Historically, communities have managed stormwater with gray infrastructure such as street gutters, culverts, sewer systems, and tunnels. Although these structures efficiently capture and route stormwater to a local waterway or treatment plant, they do not filter any contaminants. Furthermore, many older communities have combined storm sewer and sanitary sewer systems. These combined systems result in an excessive amount of wastewater to be treated before being released into receiving water or the untreated waters are released directly to receiving waters during storms. Many communities are now incorporating green infrastructure stormwater mitigating solutions—pervious surfaces (allows water through), grassed swales, bioretention basins, and rain gardens—into their stormwater-management systems. Green infrastructure can absorb and filter stormwater where it falls by taking advantage of natural soil and plant storage and filtration capabilities. Thus, green infrastructure projects can potentially reduce the amount of stormwater and the concentration and transport of contaminants. Increasing green infrastructure in a developed community may reduce the requirements for new storm sewer infrastructure, improve the water quality of nearby waterways, and enhance aesthetics. The U.S. Geological Survey has partnered with several cooperators to quantify the effects of green infrastructure projects in several developed communities throughout the central Midwest. As part of these green infrastructure projects, the U.S. Geological Survey Central Midwest Water Science Center and cooperators installed, calibrated, and monitored equipment to measure hydrologic responses (including flooding and water movement) and selected water-quality constituents in developed communities.

Fact Sheet↗

Surficial Geologic Map of Mesa Verde National Park, Montezuma County, Colorado

Mesa Verde National Park in southwestern Colorado was established in 1906 to preserve and protect the artifacts and dwelling sites, including the famous cliff dwellings, of the Ancestral Puebloan people who lived in the area from about A.D. 550 to A.D. 1300. In 1978, the United Nations designated the park as a World Heritage Site. The geology of the park played a key role in the lives of these ancient people. For example, the numerous (approximately 600) cliff dwellings are closely associated with the Cliff House Sandstone of Late Cretaceous age, which weathers to form deep alcoves. In addition, the ancient people farmed the thick, red loess (wind-blown dust) deposits on the mesa tops, which because of its particle size distribution has good moisture retention properties. The soil in this loess cover and the seasonal rains allowed these people to grow their crops (corn, beans, and squash) on the broad mesa tops. Today, geology is still an important concern in the Mesa Verde area because the landscape is susceptible to various forms of mass movement (landslides, debris flows, rockfalls), swelling soils, and flash floods that affect the park's archeological sites and its infrastructure (roads, septic systems, utilities, and building sites). The map, which encompasses an area of about 100 mi 2 (260 km 2 ), includes all of Mesa Verde National Park, a small part of the Ute Mountain Indian Reservation that borders the park on its southern and western sides, and some Bureau of Land Management and privately owned land to the north and east. Surficial deposits depicted on the map include: artificial fills, alluvium of small ephemeral streams, alluvium deposited by the Mancos River, residual gravel on high mesas, a combination of alluvial and colluvial deposits, fan deposits, colluvial deposits derived from the Menefee Formation, colluvial deposits derived from the Mancos Shale, rockfall deposits, debris flow deposits, earthflow deposits, translational and rotational landslide deposits, rock rubble deposits, and loess. Bedrock units depicted on the map include the Cliff House Sandstone, Menefee Formation, Point Lookout Sandstone, and Mancos Shale all of Late Cretaceous age. In addition, minette dikes, of Oligocene age, found at several locations in the park are depicted on the map. Descriptions, including associated hazards and resources as used by the Ancestral Puebloans, are given for all map units.

Colorado↗

Geohydrology, simulation of regional groundwater flow, and assessment of water-management strategies, Twentynine Palms area, California

The Marine Corps Air Ground Combat Center (MCAGCC) Twentynine Palms, California, overlies the Surprise Spring, Deadman, Mesquite, and Mainside subbasins of the Morongo groundwater basin in the southern Mojave Desert. Historically, the MCAGCC has relied on groundwater pumped from the Surprise Spring subbasin to provide all of its potable water supply. Groundwater pumpage in the Surprise Spring subbasin has caused groundwater levels in the subbasin to decline by as much as 190 feet (ft) from 1953 through 2007. Groundwater from the other subbasins contains relatively high concentrations of fluoride, arsenic, and (or) dissolved solids, making it unsuitable for potable uses without treatment. The potable groundwater supply in Surprise Spring subbasin is diminishing because of pumping-induced overdraft and because of more restrictive Federal drinking-water standards on arsenic concentrations. The U.S. Geological Survey, in cooperation with the MCAGCC, completed this study to better understand groundwater resources in the area and to help establish a long-term strategy for regional water-resource development. The Surprise Spring, Deadman, Mesquite, and Mainside subbasins are filled with sedimentary deposits of Tertiary age, alluvial fan deposits of Quaternary-Tertiary age, and younger alluvial and playa deposits of Quaternary age. Combined, this sedimentary sequence reaches a maximum thickness of more than 16,000 ft in the Deadman and Mesquite subbasins. The sedimentary deposits of Tertiary age yield a small amount of water to wells, and this water commonly contains high concentrations of fluoride, arsenic, and dissolved solids. The alluvial fan deposits form the principal water-bearing unit in the study area and have a combined thickness of 250 to more than 1,000 ft. The younger alluvial and playa deposits are unsaturated throughout most of the study area. Lithologic and downhole geophysical logs were used to divide the Quaternary/ Tertiary alluvial fan deposits into two aquifers (referred to as the upper and the middle aquifers) and the Tertiary sedimentary deposits into a single aquifer (referred to as the lower aquifer). In general, wells perforated in the upper aquifer yield more water than wells perforated in the middle and lower aquifers. The study area is dominated by extensive faulting and moderate to intense folding that has displaced or deformed the pre-Tertiary basement complex as well as the overlying Tertiary and Quaternary deposits. Many of these faults act as barriers to the lateral movement of groundwater flow and form many of the boundaries of the groundwater subbasins. The principal recharge to the study area is groundwater underflow across the western and southern boundaries that originates as runoff in the surrounding mountains. Groundwater discharges naturally from the study area as spring flow, as groundwater underflow to downstream basins, and as water vapor to the atmosphere by transpiration of phreatophytes and direct evaporation from moist soil. The annual volume of water that naturally recharged to or discharged from the groundwater flow system in the study area during predevelopment conditions was estimated to be 1,010 acre-feet per year (acre-ft/yr). About 90 percent of this recharge originated as runoff from the Little San Bernardino and the Pinto Mountains to the south, and the remainder originated as runoff from the San Bernardino Mountains to the west. Evapotranspiration by phreatophytes near Mesquite Lake (dry) was the primary form of predevelopment groundwater discharge. From 1953 through 2007, approximately 139,400 acre-feet (acre-ft) of groundwater was pumped by the MCAGCC from the Surprise Spring subbasin. A regional-scale numerical groundwater flow model was developed using MODFLOW-2000 for the Surprise Spring, Deadman, Mesquite, and Mainside subbasins. The aquifer system was simulated by using three model layers representing the upper, middle, and lower aquifers. Measured groundwater levels

California↗

Hydrology, nutrient concentrations, and nutrient yields in nearshore areas of four lakes in northern Wisconsin, 1999-2001

The effects of shoreline development on water quality and nutrient yields in nearshore areas of four lakes in northern Wisconsin were investigated from October 1999 through September 2001. The study measured surface runoff and ground-water flows from paired developed (sites containing lawn, rooftops, sidewalks, and driveways) and undeveloped (mature and immature woods) catchments adjacent to four lakes in northern Wisconsin. Water samples from surface runoff and ground water were collected and analyzed for nutrients. Coupled with water volumes, loads and subsequent yields of selected constituents were computed for developed and undeveloped catchments. The median runoff from lawn surfaces ranged from 0.0019 to 0.059 inch over the catchment area. Median surface runoff estimates from the wooded catchments were an order of magnitude less than those from the lawn catchments. The increased water volumes from the lawn catchments resulted in greater nutrient loads and subsequent annual nutrient yields from the developed sites. Soil temperature and soil moisture were measured at two sites with mixed lawn and wooded areas. At both of these sites, the area covered with a lawn commonly was warmer than the wooded area. No consistent differences in soil moisture were found. A ground-water model was constructed to simulate the local flow systems at two of the paired catchments. Model simulations showed that much of the ground water delivered to the lake originated from distant areas that did not contribute runoff directly to the lake. Surface runoff and ground-water nutrient concentrations from the lawn and wooded catchments did not have apparent patterns. Some of the median concentrations from lawns were significantly different (at the 0.05 significance level) from those at wooded catchments. Water wells and piezometers were sampled for chemical analyses three times during the study period. Variability in the shallow ground-water chemistry over time in the lawn samples was larger than samples from the wooded areas and upgradient wells. Median nutrient yields in surface runoff from lawns always were greater than those from the wooded catchments. Runoff volumes were the most important factor in determining whether lawns or wooded catchments contribute more nutrients to the lake. The ground-water system had appreciable nutrient concentrations, and are likely an important pathway for nutrient transport to the lake. The nitrate plus nitrite nitrogen and total phosphorus yields to the ground-water system from a lawn catchment were approximately 3 to 4 times greater than those from the wooded catchment. There was no difference in the yields of dissolved inorganic phosphorus to the ground-water system from the lawn and wooded catchments. Study results demonstrate that choosing the appropriate landscape position for locating lawns in sloped areas (specifically, slopes that do not terminate at the lake or areas with intervening flat or buffer zones between lawn and lake) can help reduce the adverse effect of lawns on the shallow ground water and, ultimately, the lake. Additional information would be needed to extrapolate these results to a large drainage area of a lake.

Wisconsin↗

Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory-Determination of organochlorine pesticides and polychlorinated biphenyls in bottom and suspended sediment by gas chromatography with electron-capture detection

A method applicable for the determination of 19 organochlorine (OC) pesticides, including total toxaphene as a complex mixture, and 3 polychlorinated biphenyl (PCB) mixtures as Aroclor equivalents--Aroclor 1016/1242, 1254, and 1260--in soil, aquatic bottom sediment, and suspended sediment is described. Method performance data are presented. The solvent system is designed to extract simultaneously selected OC pesticides and PCBs from the same sample matrix. The compounds are extracted by conventional Soxhlet extraction with dichloromethane, followed by partial isolation using gel permeation chromatography (GPC) to remove inorganic sulfur and large naturally present molecules from the sediment extract. The aliquot of extract collected from the GPC for OCs (OC pesticides and PCBs) is split into two sample fractions by alumina/silica combined-column chromatography, followed by Florisil adsorption chromatography to remove interfering compounds in the second fraction. The OC fractions are analyzed by dual capillary-column gas chromatography with electron-capture detection (GC/ECD). This report is limited to the determination of selected OC pesticides and PCBs by GC/ECD using this method. Interim reporting levels (IRLs) have been set at 0.400 to 3.12 micrograms per kilogram for 18 individual OC pesticides, 200 micrograms per kilogram for toxaphene, and 4.04 to 4.68 micrograms per kilogram for the PCBs, based on a sample size of 25-gram equivalent dry weight. These reporting levels may change following additional determinations of method detection limits.

Water-Resources Investigations Report↗

Microwave radiometric survey of the San Joaquin nuclear project site, Kern County, California

An airborne microwave survey was made in the region of the San Joaquin nuclear project site near Bakersfield, Calif. The purpose of the study was to determine if the variability of soil emissivity due to moisture content is a valid near-surface expression of buried fault systems. The results showed the existence of linear-emissivity anomalies paralleling, and to some extent, overlying the Greeley and Pond-Poso Creek faults. The anomalies seem to be direct expressions of silt-filled, northwesterly trending channels of the Pond-Poso Creek-Tulare Lake distributary system. The location, orientation, and linearity of the distributary channels suggest an association with buried faults, but no relationship has yet been determined.

California↗

Biocrust ecology: Unifying micro- and macro-scales to confront global change

Biological soil crusts (biocrusts) are communities of microbes, lichens and bryophytes living at the soil surface in drylands (Fig. 1; Belnap et al ., 2016). Biocrusts occur on all continents and can comprise a majority of cover in some systems (Belnap et al ., 2016). While species diversity and distributions have long been a research focus, interest in controls on community composition and cover has expanded as biocrusts are increasingly recognized for their roles in ecosystem functioning (Deane-Coe and Stanton, 2017). For example, biocrust organisms can stabilize soils (Belnap et al ., 2016; Faist et al ., 2017), fix atmospheric carbon (C) (Sancho et al ., 2016), and serve as the foremost source of ‘new’ soil nitrogen (N) in drylands, via N 2 fixation (Barger et al ., 2016) These contributions to gross primary production and soil fertility could be quite large, as high-end estimates suggest biocrusts and similar communities of bryophytes and lichens might account for 10% of terrestrial C- and 50% of N-fixation globally (Elbert et al ., 2012). Yet verifying these and other biocrust roles in ecosystem functioning is complicated by limited knowledge of biocrust cover and composition across the vast dryland biome (Ferrenberg et al ., 2017). It was against this backdrop that ‘Biocrust3: the 3 rd International workshop on biological soil crusts’ was held in Moab, UT, USA, on 26-30 September 2016. The workshop brought together over 50 scientists from 21 countries and six continents, and included numerous biocrust science pioneers (Fig. 2). The meeting was notable for its cross-scale focus, discussion of novel molecular and imaging techniques, and sessions on mapping and restoring biocrusts in a changing world. Here, we synthesize a central theme that emerged from Biocrust3, namely the potential for combining cutting edge tools with studies focused on organismal traits, ecosystem functions, and global change biology to advance the frontier of biocrust ecology.

New Phytologist↗

Assessing the topographic distribution of legacy soil phosphorus in agricultural fields of the Delmarva Peninsula, Mid-Atlantic Coastal Plain, USA

Phosphorus (P) management remains a challenge in agricultural watersheds. The Choptank River Conservation Effects Assessment Project watershed, located in Maryland and Delaware and draining to the Chesapeake Bay, contains legacy soil P from historical dairy and poultry manure applications. These practices elevated soil P beyond crop needs, contributing to persistent P export to aquatic ecosystems. We assessed spatial P distribution and analyzed GIS (Geographic Information Systems)-derived landscape features driving legacy P movement on a farm (47 ha). We hypothesized that P accumulates in drained lowlands and depressional areas due to gravity-driven processes that accelerate P-enriched water to receiving waters via overland flow. In collaboration with the US Department of Agriculture Legacy P project, we collected 105 soil samples (0- to 5-cm and 5- to 15-cm depths) and 14 ditch sediment samples across five topographic openness classes from a farm with >100 years of dairy manure application. Average Mehlich-III P concentrations were 218 and 179 mg kg −1 at 0- to 5-cm and 5- to 15-cm depths, respectively, with legacy areas defined by P content > 100 mg kg −1 . Soil P and clay particle size were positively correlated ( r = 0.42, p < 0.05), increased as landscape openness decreased, and were negatively correlated with topographic openness (ranging from −0.2 to −0.4, p < 0.05), indicating accumulation of P and clay in low-lying areas. These patterns suggest that historical field-level managements have primarily shaped P distribution, while hydrologic and landscape properties further influence its redistribution via transport pathways and drainage. These findings support the development of landscape models to map critical source areas in low-relief watersheds and guide targeted mitigation in high-risk P export zones.

Maryland↗

Dissolved organic matter compositional change and biolability during two storm runoff events in a small sgricultural watershed

Agricultural watersheds are globally pervasive, supporting fundamentally different organic matter source, composition, and concentration profiles in comparison to natural systems. Similar to natural systems, agricultural storm runoff exports large amounts of organic carbon from agricultural land into waterways. But intense management of upper soil layers, waterway channelization, wetland and riparian habitat removal, and postharvest vegetation removal promise to uniquely drive organic matter release to waterways. During a winter first flush and a subsequent storm event, this study investigated the influence of a small agricultural watershed on dissolved organic matter (DOM) source, composition, and biolability. Storm water discharge released strongly terrestrial yet biolabile (23 to 32%) dissolved organic carbon (DOC). Following a 21 day bioassay, a parallel factor analysis identified an 80% reduction in a protein-like (phenylpropyl) component (C2) that was previously correlated to lignin phenol concentration, and a 10% reduction in a humic-like, terrestrially sourced component (C4). Storm-driven releases tripled DOC concentration (from 2.8 to 8.7 mg L −1 ) during the first flush event in comparison to base flow and were terrestrially sourced, with an eightfold increase in vascular plant derived lignin phenols (23.0 to 185 μg L −1 ). As inferred from system hydrology, lignin composition, and nitrate as a groundwater tracer, an initial pulse of dilute water from the upstream watershed caused a counterclockwise DOC hysteresis loop. DOC concentrations peaked after 3.5 days, with the delay between peak discharge and peak DOC attributed to storm water hydrology and a period of initial water repellency of agricultural soils, which delayed DOM leaching.

California↗

Lake phosphorus loading from septic systems by seasonally perched ground water, Puget Sound region, Washington

In a previous study, estimated phosphorus (P) loadings from septic systems to lakes in the Puget Sound region were found to be correlated with the presence of old homes around the lakes. In the present study, we assessed the movement of septic-effluent P in seasonally perched ground water near Pine Lake, a typical glacial-till lake in the region. This ground water occurs in soils overlying less permeable glacial till, which is prevalent around Pine Lake and many other lakes in the area. Water samples were taken from 15 shallow (<1.5 meters) wells installed 10-50 meters downgradient from seven septic systems 20 to 40 years old. The equivalent volumetric fraction of each sample consisting of undiluted effluent was estimated from chloride concentration. Using Monte Carlo analysis to account for the various sources of uncertainty, we found that, though movement of diluted septic effluent to the lake was common, transport of more than 1% of effluent P through the soil was probable (p > or = 0.5) for only 4 of 26 samples, was transport of more than 10% of effluent P probable. The highest probabilities of P movement were associated with two samples from a well that was downgradient from a drainfield located at the base of a hillslope depression where perched ground water concentrates and remains for extended periods. All evidence considered, most P loading to Pine Lake from septic systems appears to come from only a few older systems located in areas where perched ground-water flow and associated saturated soil conditions predominate for extended periods during the winter season. (USGS)

Open-File Report↗

Microbial reduction of iodate

The different oxidation species of iodine have markedly different sorption properties. Hence, changes in iodine redox states can greatly affect the mobility of iodine in the environment. Although a major microbial role has been suggested in the past to account for these redox changes, little has been done to elucidate the responsible microorganisms or the mechanisms involved. In the work presented here, direct microbial reduction of iodate was demonstrated with anaerobic cell suspensions of the sulfate reducing bacterium Desulfovibrio desulfuricans which reduced 96% of an initial 100 ??M iodate to iodide at pH 7 in 30 mM NaHCO3 buffer, whereas anaerobic cell suspensions of the dissimilatory Fe(III)-reducing bacterium Shewanella putrefaciens were unable to reduce iodate in 30 mM NaHCO3 buffer (pH 7). Both D. desulfuricans and S. putrefaciens were able to reduce iodate at pH 7 in 10 mM HEPES buffer. Both soluble ferrous iron and sulfide, as well as iron monosulfide (FeS) were shown to abiologically reduce iodate to iodide. These results indicate that ferric iron and/or sulfate reducing bacteria are capable of mediating both direct, enzymatic, as well as abiotic reduction of iodate in natural anaerobic environments. These microbially mediated reactions may be important factors in the fate and transport of 129I in natural systems.

Water, Air, & Soil Pollution↗

Probability of detecting atrazine/desethyl-atrazine and elevated concentrations of nitrate (NO2+NO3-N) in ground water in the Idaho part of the upper Snake River basin

Draft Federal regulations may require that each State develop a State Pesticide Management Plan for the herbicides atrazine, alachlor, cyanazine, metolachlor, and simazine. This study developed maps that the Idaho State Department of Agriculture might use to predict the probability of detecting atrazine and desethyl-atrazine (a breakdown product of atrazine) in ground water in the Idaho part of the upper Snake River Basin. These maps can be incorporated in the State Pesticide Management Plan and help provide a sound hydrogeologic basis for atrazine management in the study area. Maps showing the probability of detecting atrazine/desethyl-atrazine in ground water were developed as follows: (1) Ground-water monitoring data were overlaid with hydrogeologic and anthropogenic data using a geographic information system to produce a data set in which each well had corresponding data on atrazine use, depth to ground water, geology, land use, precipitation, soils, and well depth. These data then were downloaded to a statistical software package for analysis by logistic regression. (2) Individual (univariate) relations between atrazine/desethyl-atrazine in ground water and atrazine use, depth to ground water, geology, land use, precipitation, soils, and well depth data were evaluated to identify those independent variables significantly related to atrazine/ desethyl-atrazine detections. (3) Several preliminary multivariate models with various combinations of independent variables were constructed. (4) The multivariate models which best predicted the presence of atrazine/desethyl-atrazine in ground water were selected. (5) The multivariate models were entered into the geographic information system and the probability maps were constructed. Two models which best predicted the presence of atrazine/desethyl-atrazine in ground water were selected; one with and one without atrazine use. Correlations of the predicted probabilities of atrazine/desethyl-atrazine in ground water with the percent of actual detections were good; r-squared values were 0.91 and 0.96, respectively. Models were verified using a second set of groundwater quality data. Verification showed that wells with water containing atrazine/desethyl-atrazine had significantly higher probability ratings than wells with water containing no atrazine/desethylatrazine (p <0.002). Logistic regression also was used to develop a preliminary model to predict the probability of nitrite plus nitrate as nitrogen concentrations greater than background levels of 2 milligrams per liter. A direct comparison between the atrazine/ desethyl-atrazine and nitrite plus nitrate as nitrogen probability maps was possible because the same ground-water monitoring, hydrogeologic, and anthropogenic data were used to develop both maps. Land use, precipitation, soil hydrologic group, and well depth were significantly related with atrazine/desethyl-atrazine detections. Depth to water, land use, and soil drainage were signifi- cantly related with elevated nitrite plus nitrate as nitrogen concentrations. The differences between atrazine/desethyl-atrazine and nitrite plus nitrate as nitrogen relations were attributed to differences in chemical behavior of these compounds in the environment and possibly to differences in the extent of use and rates of their application.

Idaho↗

Land Use on the Island of Oahu, Hawaii, 1998

A hierarchical land-use classification system for Hawaii was developed, and land use on the island of Oahu was mapped. The land-use classification system emphasizes agriculture, developed (urban), and barren/mining uses. Areas with other land uses (conservation, forest reserve, natural areas, wetlands, water, and barren [sand, rock, or soil] regions, and unmanaged vegetation [native or exotic]) were defined as 'other.' Multiple sources of digital orthophotographs from 1998 and 1999 were used as source data. The 1998 island of Oahu land-use data are provided in digital format at http://water.usgs.gov/lookup/getspatial?oahu_lu98 for use in a Geographic Information System (GIS), at 1:24,000-scale with minimum mapping units of 2 hectares (4.9 acres) area and 30-meters (98.4 feet) feature width. In 1998, a total of 59,195 acres (15.4 percent) of the island of Oahu were classified as agricultural land use; 98,663 acres (25.7 percent) were classified as developed; 1,522 acres (0.4 percent) were classified as barren/mining; and 224,331 acres (58.5 percent) were classified as other. An accuracy assessment identified 98 percent accuracy for all land-use classes. In windward (moister) areas, dense vegetation and canopy cover along with rapid recolonization by vegetation potentially obscured land use from photo-interpretation. While in leeward (drier) areas, sparse vegetative cover and slower vegetation recolonization may have resulted in more frequent recognition of apparent land-use patterns.

Water-Resources Investigations Report↗

Hydrogeologic factors that influence ground water movement in the desert southwest United States

A project to study ground-water and surface-water interactions in the desert southwestern United States was initiated in 2001 by the Tucson, Arizona office of the Water Resources Division, U.S. Geological Survey (USGS). One of the goals of the Southwest Ground-water Resources Project was to develop a regional synthesis that includes the use of available digital geologic data, which is growing rapidly due to the increasing use of Geographic Information Systems (GIS). Included in this report are the digital maps and databases of geologic information that should have a direct impact on the studies of ground-water flow and surface-water interaction. Ground-water flow is governed by many geologic factors or elements including rock and soil permeability, stratigraphy and structural features. These elements directly influence ground-water flow, which is key to understanding the possible inter-connectivity of aquifer systems in desert basins of the southwestern United States. We derive these elements from the evaluation of regional geology and localized studies of hydrogeologic basins. These elements can then be applied to other unstudied areas throughout the desert southwest. This report presents a regional perspective of the geologic elements controlling ground-water systems in the desert southwest that may eventually lead to greater focus on smaller sub-regions and ultimately, to individual ground-water basins.

Arizona, California, Colorado, Idaho, Nevada, New ↗

Modeling water quality in watersheds: From here to the next generation

In this synthesis, we assess present research and anticipate future development needs in modeling water quality in watersheds. We first discuss areas of potential improvement in the representation of freshwater systems pertaining to water quality, including representation of environmental interfaces, in‐stream water quality and process interactions, soil health and land management, and (peri‐)urban areas. In addition, we provide insights into the contemporary challenges in the practices of watershed water quality modeling, including quality control of monitoring data, model parameterization and calibration, uncertainty management, scale mismatches, and provisioning of modeling tools. Finally, we make three recommendations to provide a path forward for improving watershed water quality modeling science, infrastructure, and practices. These include building stronger collaborations between experimentalists and modelers, bridging gaps between modelers and stakeholders, and cultivating and applying procedural knowledge to better govern and support water quality modeling processes within organizations.

Water Resources Research↗