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At least 541 records · Page 30Linked to original sources

The severity of the 2014–2015 snow drought in the Oregon Cascades in a multicentury context

The western United States (US) is a hotspot for snow drought. The Oregon Cascade Range is highly sensitive to warming and as a result has experienced the largest mountain snowpack losses in the western US since the mid-20th century, including a record-breaking snow drought in 2014–2015 that culminated in a state of emergency. While Oregon Cascade snowpacks serve as the state's primary water supply, short instrumental records limit water managers' ability to fully constrain long-term natural snowpack variability prior to the influence of ongoing and projected anthropogenic climate change. Here, we use annually-resolved tree-ring records to develop the first multi-century reconstruction of Oregon Cascade April 1st Snow Water Equivalent (SWE). The model explains 58% of observed snowpack variability and extends back to 1688 AD, nearly quintupling the length of the existing snowpack record. Our reconstruction suggests that only one other multiyear event in the last three centuries was as severe as the 2014–2015 snow drought. The 2015 event alone was more severe than nearly any other year in over three centuries. Extreme low-to-high snowpack “whiplash” transitions are a consistent feature throughout the reconstructed record. Multi-decadal intervals of persistent below-the-mean peak SWE are prominent features of pre-instrumental snowpack variability, but are generally absent from the instrumental period and likely not fully accounted for in modern water management. In the face of projected snow drought intensification and warming, our findings motivate adaptive management strategies that address declining snowpack and increasingly variable precipitation regimes.

Oregon↗

Seasonal and species-level water-use strategies and groundwater dependence in dryland riparian woodlands during extreme drought

Drought-induced groundwater decline and warming associated with climate change are primary threats to dryland riparian woodlands. We used the extreme 2012–2019 drought in southern California as a natural experiment to assess how differences in water-use strategies and groundwater dependence may influence the drought susceptibility of dryland riparian tree species with overlapping distributions. We analyzed tree-ring stable carbon and oxygen isotopes collected from two cottonwood species ( Populus trichocarpa and P . fremontii ) along the semi-arid Santa Clara River. We also modeled tree source water δ 18 O composition to compare with observed source water δ 18 O within the floodplain to infer patterns of groundwater reliance. Our results suggest that both species functioned as facultative phreatophytes that used shallow soil moisture when available but ultimately relied on groundwater to maintain physiological function during drought. We also observed apparent species differences in water-use strategies and groundwater dependence related to their regional distributions. P . fremontii was constrained to more arid river segments and ostensibly used a greater proportion of groundwater to satisfy higher evaporative demand. P . fremontii maintained ∆ 13 C at pre-drought levels up until the peak of the drought, when trees experienced a precipitous decline in ∆ 13 C. This response pattern suggests that trees prioritized maintaining photosynthetic processes over hydraulic safety, until a critical point. In contrast, P . trichocarpa showed a more gradual and sustained reduction in ∆ 13 C, indicating that drought conditions induced stomatal closure and higher water use efficiency. This strategy may confer drought avoidance for P . trichocarpa while increasing its susceptibility to anticipated climate warming.

California↗

Interplanetary electric fields for extreme magnetic storms

Using a list of sudden-commencement storms, the ring-current index, and 1-h near-Earth solar-wind measurements from solar cycles 20–25, we develop extreme-value statistical models relating storm intensity 𝐷 =max⁡{−𝐷⁢𝑠⁢𝑡} to the storm main-phase maximum duskward interplanetary electric field 𝐸 . The conditional relationship 𝐷|𝐸 is demonstrably sublinear—linear models are confidently rejected—indicating saturation of magnetospheric response under extreme solar-wind forcing. An event like that of July 2012 ( 𝐸 =69.6 mV/m), if Earth-directed, would be associated with a median storm intensity of 𝐷 =49⁢5 648 378 nT. Storms comparable to March 1989 ( 𝐷 =594 nT) correspond to electric fields of 𝐸 =5⁢4 76 39 mV/m, while Carrington-class storms ( 𝐷 =964 nT) correspond to 𝐸 =9⁢5 133 68 mV/m—substantially lower than several previous estimates. These results indicate that solar-wind conditions capable of driving extremely intense magnetic storms are less exceptional, and potentially more frequent, than previously thought.

Geophysical Research Letters↗

Galileo observations of Post-Imbrium lunar craters during the first Earth-Moon flyby

Copernican‐age craters are among the most conspicuous features seen on the far side and western limb of the Moon in the Galileo multispectral images acquired in December 1990. Among the new morphologic observations of far‐side craters are bright rays, continuous ejecta deposits, and dark rings associated with probable impact‐melt veneers. These observations suggest that the mapped age assignments of several large far‐side craters (Ohm, Robertson, and possibly Lowell and Lenz) need revision. New crater size‐frequency measurements on Lunar Orbiter images suggest the following age reassignments: Hausen (170 km diameter), Pythagoras (120 km), and Bullialdus (61 km) from Eratosthenian to Upper Imbrian, and Carpenter (60 km) and Harpalus (39 km) from Copernican to Eratosthenian. Colors and albedos of craters (away from impact‐melt veneers) are correlated with their geologic emplacement ages as determined from counts of superposed craters; these age‐color relations are used to estimate the emplacement age (time since impact event) for other Copernican‐age craters. These age‐color relations indicate a probable Copernican age for 27 far‐side or western limb craters larger than 10 km diameter that were not previously mapped as Copernican. The apparent deficiency of Copernican craters on the far side compared with the near side in published geologic maps is not present in our data. Age‐color trends differ between mare and highland regions and between the interiors and continuous ejecta of the craters. Similar trends are established for color and albedo versus soil‐maturity indices for the returned lunar samples, with distinct trends for mare and highland soils. However, the mare versus highland offsets are reversed in the two comparisons. These relations can be explained by variations in regolith thicknesses and rates of mixing with relatively fresh, crystalline ejecta. Therefore, the soil‐maturity trends represent longer geologic time periods in regions with thinner regoliths, such as the maria.

Journal of Geophysical Research E: Planets↗

Petrology and geochronology of metamorphosed volcanic rocks and a middle Cretaceous volcanic neck in the east-central Sierra Nevada, California

Metamorphosed Mesozoic volcanic rocks from the east-central Sierra Nevada range in composition from basalt to rhyolite and have ages, based on whole rock Rb-Sr and U-Pb zircon dating, of about 237–224, 185, 163, 134, and 100 m.y. The major plutons of the batholith in this area are of Triassic (215–200 m.y.) and Cretaceous (94–80 m.y.) ages. Initial 87 Sr/ 86 Sr values for the metamorphosed volcanic rocks of the area are in the range from 0.7042 to 0.7058 and are generally different from the values for the surrounding batholithic rocks (0.7056–0.7066). A circular, zoned granitic pluton, with an outcrop area of 2.5 km 2 , similar in appearance to a ring dike complex, was apparently a conduit for some or possibly all of the middle-Cretaceous metamorphosed volcanic rocks exposed about 5 km to the south in the western part of the Ritter Range. Samples from the metamorphosed volcanic rocks and the pluton yield a Rb-Sr whole rock isochron age of 99.9 ± 2.2 m.y. with an initial 87 Sr/ 86 Sr of 0.7048 ± 0.0001. Major element variation diagrams of the pluton and volcanic rocks define coincident compositional trends. The pluton, intruded into Early Jurassic metamorphosed volcanic rocks (Rb-Sr whole rock isochron age of 185 ± 6 m.y., initial 87 / 86 Sr = 0.70474 ± 0.00009), is composed of a central body of granite that is intruded into and almost completely surrounded by a crescent-shaped outer rim of quartz monzodiorite. Contact relations between the granitic rocks, intrusive in some places and completely gradational at other places, indicate that the quartz monzodiorite was not completely crystallized prior to the intrusion of the granite. Modal minerology within the pluton is also consistent with this inferred crystallization history. The granitic rock textures are cataclastic, characterized by a groundmass of feldspar and quartz that surrounds larger grains of feldspar, hornblende, and biotite. Widely spaced aplite dikes from the granite intrude the quartz monzodiorite along the contact between the granitic rocks. The aplite dikes and interstitial alkali feldspar associated with myrmekite in the pluton, being undeformed, indicate crystallization of a small amount of silicate liquid after cataclasis. Aplite compositions suggest a minimum crystallization pressure of 0.5 kb (1–2 km); this depth is consistent with crystallization near the base of a large stratovolcano. The pluton is characterized by steep, linear features, defined by mineral clots and inclusions, that probably formed during the upward movement of the nearly crystallized magma in the volcanic conduit. The ages of volcanic events relative to the ages of the major intrusive epochs and the major element and isotopic compositions of the volcanic rocks relative to the major plutons indicate that the volcanic rocks are not simply or directly related to the major plutons in the Sierra Nevada.

Journal of Geophysical Research Solid Earth↗

Strangways Crater, Northern Territory, Australia: Siderophile element enrichment and lithophile element fractionation

The Strangways Crater, Northern Territory, Australia (15°12′S, 133°35′ E ), has a central core, about 10 km in diameter, of shocked granitic gneiss and amphibolite, and some remnants of a melt rock sheet, surrounded by outer rings of quartzite and siltstone to a diameter of 20–25 km. Seven samples of melt rock (six granitic melts, one shale melt clast) and four samples of country rock (granitic gneiss, amphibolite, shale, quartzite) were analyzed by neutron-activation analysis: for Sc, Cr, Fe, Co, Zn, Rb, Zr, Sb, Cs, Ba, rare earth elements, Hf, Ta, Th, and U, the samples were analyzed instrumentally; and for Ni, Se, Pd, Ag, Cd, Re, Os, Ir, and Au, they were analyzed radiochemically. Siderophile elements are significantly enriched in the granitic melt rocks relative to country rocks; for example, the Ir enrichments range from 0.6 to 2.8 ppb. The low Ir/Ni ratio (∼0.16 relative to C1 chondrites) excludes a chondritic impacting body, and Cr enrichment argues against impact by an iron meteorite. The Strangways Crater may have been formed by the impact of an olivine-rich achondrite and melt rocks appear to contain about 3 wt.% of projectile material. The composition of the granitic melt rocks cannot be reproduced by any simple mixture of analyzed country rock types and chemical fractionation by selective shock melting appears to have taken place.

Journal of Geophysical Research Solid Earth↗

Active tectonic and magmatic processes beneath Long Valley Caldera, eastern California: An overview

Geological, chronological, and structural studies of the Long Valley-Mono/Inyo Craters area document a long history of related volcanic eruptions and earthquakes controlled by regional extensional tectonics of the Basin and Range province. This activity has persisted for hundreds of thousands of years and is likely to continue. The Long Valley magma chamber had a volume approaching 3000 km 3 prior to its climatic caldera-forming eruption 0.7 m.y. ago but has been reduced to less than a third of this volume by cooling, eruption, and crystallization. Seismic evidence indicates that the main mass of the present Long Valley magma chamber is about 10 km in diameter and that its roof is 8–10 km deep with smaller cupolas as shallow as 4–5 km. Although a chamber of this size is probably capable of producing an eruption approaching 30 km 3 of lava, the record over the past 0.5 m.y. suggests that eruptions of 1 km 3 or less are far more likely. Models proposed for the current ground uplift and seismicity within the caldera require inflation of 0.1–0.2 km 3 by additional magma since mid-1979, and some models suggest that inflation was accompanied by injection of a thin dike or dikes (probably of silicic magma) into the ring fracture zone beneath the south moat. Several of the M 5.8–6.2 earthquakes that occurred in the region beginning in 1978 had non-double-couple focal mechanisms. Whether these unusual mechanisms indicate injection of mafic (low-viscosity) magma at midcrustal depths in the Sierra Nevada block south of the caldera remains debatable. Studies of calderas of various ages throughout the world indicate that episodes of unrest are relatively common and do not invariably culminate in eruptions. Although current unrest is concentrated in the south moat of Long Valley caldera, the Inyo/Mono Craters probably hold a greater potential for producing an eruption in the foreseeable future. The Inyo/Mono Craters have erupted at 500-year intervals over the past 2000–3000 years, whereas the Long Valley magma chamber has erupted at about 200,000-year intervals over the past 700,000 years. In either case, a major earthquake near the caldera could strongly influence the course of volcanic activity.

Journal of Geophysical Research Solid Earth↗

Root zone of the late Proterozoic Salma caldera, northeastern Arabian Shield, Kingdom of Saudi Arabia

The eroded root of the late Proterozoic Salma caldera crops out in a striking, roughly elliptical feature, about 27 km long and 22 km wide, near the northeastern edge of the Arabian Shield. The caldera is genetically part of an elongate alkalic granitic massif (Jabal Salma) that extends 35 km from the caldera to the southwest. Comenditic ash flow tuff and lava(?) of the caldera fill, probably more than 1 km thick, are the oldest recognized rocks of the caldera complex. These rocks were erupted during caldera collapse associated with the rapid evacuation of the upper, mildly peralkalic part of a zoned magma reservoir. Within the caldera fill, a massive, lithic-rich intracaldera rhyolite, probably a lava in excess of 1 km thick, is overlain by a layered ash flow sequence. Numerous megabreccia blocks, probably derived from the caldera wall, occur in the massive rhyolite. Open folds in the layered volcanic rocks may be due to high-temperature slumping of the rocks toward the center of the caldera following collapse. Later peralkalic granite that intruded the caldera ring fracture zone occurs in an arcuate pattern outside the area of exposed caldera fill. After caldera collapse, metaluminous to peraluminous magma rose beneath the caldera at approximately 580 Ma and solidified as biotite alkali granite, rim syenogranite, and late, high-level granophyre. Rare earth element abundances indicate that the layered rhyolite tuff, peralkalic granite, and granophyre are chemically more evolved than the biotite alkali granite and rim syenogranite. The granophyre intruded the caldera fill as a dome-shaped body composed of numerous sheetlike masses. Granophyric texture resulted from rapid pressure release and quenching accompanying the intrusion of each sheet. Maximum penetration of the granophyre into overlying rocks occurred in the central region and along the west side of the caldera, where the caldera fill volcanic rocks have been removed by erosion. No apparent structural doming of the exposed volcanic rocks along the east side of the caldera took place; the layered ash flows commonly dip steeply toward the center of the caldera. Postemplacement deformation and metamorphism of the caldera are minimal. Small-displacement strike-slip faults cut the complex, which is tilted to the northeast by no more than about 2°.

Journal of Geophysical Research Solid Earth↗

Stable isotope compositions of gases and vegetation near naturally burning coal

Our measurements of stable isotope compositions of CO2 issuing from vents produced by naturally burning coal indicate that the coal is oxidized through a kinetic process in which groundwater is the oxidizing agent. The CO2 produced by the oxidation of the coal is extremely depleted in 13C relative to normal atmospheric CO2. The change in the ??13C value of atmospheric CO2 near the vents resulting from the burning coal was not recorded in tree rings from red cedars, but the ??13C values of some C3 and C4 type plants collected from within the area were greatly affected. Our results indicate that the ??13C values of some species of plants may be sensitive indicators of changes in the carbon isotopic composition of atmospheric CO2. ?? 1984 Nature Publishing Group.

Nature↗

Temperature as a potent driver of regional forest drought stress and tree mortality

s the climate changes, drought may reduce tree productivity and survival across many forest ecosystems; however, the relative influence of specific climate parameters on forest decline is poorly understood. We derive a forest drought-stress index (FDSI) for the southwestern United States using a comprehensive tree-ring data set representing AD 1000-2007. The FDSI is approximately equally influenced by the warm-season vapour-pressure deficit (largely controlled by temperature) and cold-season precipitation, together explaining 82% of the FDSI variability. Correspondence between the FDSI and measures of forest productivity, mortality, bark-beetle outbreak and wildfire validate the FDSI as a holistic forest-vigour indicator. If the vapour-pressure deficit continues increasing as projected by climate models, the mean forest drought-stress by the 2050s will exceed that of the most severe droughts in the past 1,000 years. Collectively, the results foreshadow twenty-first-century changes in forest structures and compositions, with transition of forests in the southwestern United States, and perhaps water-limited forests globally, towards distributions unfamiliar to modern civilization.

Nature Climate Change↗

A fire deficit persists across diverse North American forests despite recent increases in area burned

Rapid increases in wildfire area burned across North American forests pose novel challenges for managers and society. Increasing area burned raises questions about whether, and to what degree, contemporary fire regimes (1984–2022) are still departed from historical fire regimes (pre-1880). We use the North American tree-ring fire-scar network (NAFSN), a multi-century record comprising >1800 fire-scar sites spanning diverse forest types, and contemporary fire perimeters to ask whether there is a contemporary fire surplus or fire deficit, and whether recent fire years are unprecedented relative to historical fire regimes. Our results indicate, despite increasing area burned in recent decades, that a widespread fire deficit persists across a range of forest types and recent years with exceptionally high area burned are not unprecedented when considering the multi-century perspective offered by fire-scarred trees. For example, ‘record’ contemporary fire years such as 2020 burned 6% of NAFSN sites—the historical average—well below the historical maximum of 29% sites that burned in 1748. Although contemporary fire extent is not unprecedented across many North American forests, there is abundant evidence that unprecedented contemporary fire severity is driving forest loss in many ecosystems and adversely impacting human lives, infrastructure, and water supplies.

Nature Communications↗

Rising atmospheric CO2 reduces nitrogen availability in boreal forests

Anthropogenic nitrogen (N) pollution has been emphasized as a cause of eutrophication globally. However, several recent datasets have suggested widespread oligotrophication may be occurring in some ecosystems, which is suggested to be a response to rising atmospheric carbon dioxide (eCO 2 ). Plant δ 15 N chronologies have served as primary evidence for oligotrophication, however, there has been wide disagreement whether eCO 2 or temporal changes in N deposition explain these patterns. We constructed δ 15 N tree ring chronologies across Sweden’s 23.5 million hectare productive forest area from the 1950s to 2010s. The study area spans a 1500 km latitudinal distance where N deposition varies four-fold, but where eCO 2 is spatially uniform. Our data revealed negative δ 15 N chronologies throughout Sweden, including forests in the far north where atmospheric N deposition rates are very low. Linear mixed effects models showed that eCO 2 was by far the strongest predictor of δ 15 N values, whereas N deposition variables, temperature, and forest basal area had much lower explanatory power. Our results clarify debates on the interpretation of previous δ 15 N chronologies, and provide clear evidence that eCO 2 is causing oligotrophication in boreal forests, which has implications for predicting their future role as sinks in the global carbon cycle.

Nature↗

Climate drivers of large magnitude snow avalanche years in the U.S. northern Rocky Mountains

Large magnitude snow avalanches pose a hazard to humans and infrastructure worldwide. Analyzing the spatiotemporal behavior of avalanches and the contributory climate factors is important for understanding historical variability in climate-avalanche relationships as well as improving avalanche forecasting. We used established dendrochronological methods to develop a long-term (1867–2019) regional avalanche chronology for the Rocky Mountains of northwest Montana using tree-rings from 647 trees exhibiting 2134 avalanche-related growth disturbances. We then used principal component analysis and a generalized linear autoregressive moving average model to examine avalanche-climate relationships. Historically, large magnitude regional avalanche years were characterized by stormy winters with positive snowpack anomalies, with avalanche years over recent decades increasingly influenced by warmer temperatures and a shallow snowpack. The amount of snowpack across the region, represented by the first principal component, is shown to be directly related to avalanche probability. Coincident with warming and regional snowpack reductions, a decline of ~ 14% (~ 2% per decade) in overall large magnitude avalanche probability is apparent through the period 1950–2017. As continued climate warming drives further regional snowpack reductions in the study region our results suggest a decreased probability of regional large magnitude avalanche frequency associated with winters characterized by large snowpacks and a potential increase in large magnitude events driven by warming temperatures and spring precipitation.

Montana↗

Contemporary fires are less frequent but more severe in dry conifer forests of the southwestern United States

Wildfires in the southwestern United States are increasingly frequent and severe, but whether these trends exceed historical norms remains contested. Here we combine dendroecological records, satellite-derived burn severity, and field measured tree mortality to compare historical (1700-1880) and contemporary (1985-2020) fire regimes at tree-ring fire-scar sites in Arizona and New Mexico. We found that contemporary fire frequency, including recent, record fire years, is still <20% of historical levels. Since 1985, the fire return interval averages 58.8 years, compared to 11.4 years before 1880. Fire severity, however, has increased. At sites where trees historically survived many fires over centuries, 42% of recent fires resulted in high tree mortality. Suppressed wildfires tended to burn more severely than prescribed burns and wildfires managed for resource benefit. These findings suggest that expanded use of low-severity prescribed and managed fire would help restore forest resilience and historical fire regimes in dry conifer forests.

Arizona, New Mexico↗

Effects of fat reserves on annual apparent survival of blackbirds Turdus merula

1. Fat reserves are stored energy that may help birds survive periods of harsh winter weather. This hypothesis predicts that annual apparent survival is higher for birds with large fat reserves than for birds with few or no fat reserves in winter. 2. Blackbirds ( Turdus merula Linnaeus) were ringed in central Italy from 16 November to 20 February during 1990-2001. Fat scores were recorded for each bird. We used these capture-mark-recapture data for 1703 blackbirds to estimate the effect of large fat reserves on annual apparent survival , while controlling for transients, using computer programs SURVIV and MARK. Probability of birds retaining large fat reserves , or retaining few fat reserves , over 2 successive years was also estimated. 3. Birds with large fat reserves did not have higher estimated annual apparent survival than birds with few fat reserves (φ̂ large = φ̂ few = 0.595, SE = 0.043), inconsistent with our prediction. No effects of age, sex or year were detected on annual apparent survival . Birds with few fat reserves in any given year tended to have few fat reserves the following year (ψ̂ few→large = 0.332, SE = 0.052). Birds with large fat reserves in any given year were unlikely to have large fat reserves the next year (ψ̂ large→few = 0.585, SE = 0.080). 4. Large fat reserves may not increase annual survival of blackbirds wintering in central Italy. Winter weather in our study area may be too mild to effect survival . Alternatively, increased predation risk associated with large fat reserves may counteract any benefits of reduced starvation risk.

Journal of Animal Ecology↗

On the uncertain intensity estimate of the 1859 Carrington storm

A study is made of the intensity of the Carrington magnetic storm of September 1859 as inferred from visual measurements of horizontal-component geomagnetic disturbance made at the Colaba observatory in India. Using data from modern observatories, a lognormal statistical model of storm intensity is developed, to characterize the maximum-negative value of the storm-time disturbance index (maximum – Dst) versus geomagnetic disturbance recorded at low-latitude observatories during magnetic storms. With this model and a recently published presentation of the Colaba data, the most likely maximum – Dst of the Carrington storm and its credibility interval are estimated. A related model is used to examine individual Colaba disturbance values reported for the Carrington storm. Results indicate that only about one in a million storms with maximum – Dst like the Carrington storm would result in local disturbance greater than that reported from Colaba. This indicates that either the Colaba data were affected by magnetospheric-ionospheric current systems in addition to the ring current, or there might be something wrong with the Colaba data. If the most extreme Colaba disturbance value is included in the analysis, then, of all hypothetical storms generating the hourly average disturbance recorded at Colaba during the Carrington storm, the median maximum – Dst = 964 nT, with a 68% credibility interval of [855,1087] nT. If the most extreme Colaba disturbance value is excluded from the analysis, then the median maximum – Dst = 866 nT, with a 68% credibility interval of [768,977] nT. The widths of these intervals indicate that estimates of the occurrence frequency of Carrington-class storms are very uncertain, as are related estimates of risk for modern technological systems.

Journal of Space Weather and Space Climate↗

Evaluation of mean velocity and turbulence measurements with ADCPs

To test the ability of acoustic Doppler current profilers (ADCPs) to measure turbulence, profiles measured with two pulse-to-pulse coherent ADCPs in a laboratory flume were compared to profiles measured with an acoustic Doppler velocimeter, and time series measured in the acoustic beam of the ADCPs were examined. A four-beam ADCP was used at a downstream station, while a three-beam ADCP was used at a downstream station and an upstream station. At the downstream station, where the turbulence intensity was low, both ADCPs reproduced the mean velocity profile well away from the flume boundaries; errors near the boundaries were due to transducer ringing, flow disturbance, and sidelobe interference. At the upstream station, where the turbulence intensity was higher, errors in the mean velocity were large. The four-beam ADCP measured the Reynolds stress profile accurately away from the bottom boundary, and these measurements can be used to estimate shear velocity. Estimates of Reynolds stress with a three-beam ADCP and turbulent kinetic energy with both ADCPs cannot be computed without further assumptions, and they are affected by flow inhomogeneity. Neither ADCP measured integral time scales to within 60%. ?? 2007 ASCE.

Journal of Hydraulic Engineering↗

Evaluation of multidimensional transport through a field-scale compacted soil liner

A field-scale compacted soil liner was constructed at the University of Illinois at Urbana-Champaign by the U.S. Environmental Protection Agency (USEPA) and Illinois State Geological Survey in 1988 to investigate chemical transport rates through low permeability compacted clay liners (CCLs). Four tracers (bromide and three benzoic acid tracers) were each added to one of four large ring infiltrometers (LRIs) while tritium was added to the pond water (excluding the infiltrometers). Results from the long-term transport of Br - "> Br - from the localized source zone of LRI are presented in this paper. Core samples were taken radially outward from the center of the Br - "> Br - LRI and concentration depth profiles were obtained. Transport properties were evaluated using an axially symmetric transport model. Results indicate that (1) transport was diffusion controlled; (2) transport due to advection was negligible and well within the regulatory limits of k sat &#x2A7D; 1 &#xD7; 10 - 7 cm / s ; "> k sat ⩽ 1 × 10 − 7 cm / s; (3) diffusion rates in the horizontal and vertical directions were the same; and (4) small positioning errors due to compression during soil sampling did not affect the best fit advection and diffusion values. The best-fit diffusion coefficient for bromide was equal to the molecular diffusion coefficient multiplied by a tortuosity factor of 0.27, which is within 8% of the tortuosity factor (0.25) found in a related study where tritium transport through the same liner was evaluated. This suggests that the governing mechanisms for the transport of tritium and bromide through the CCL were similar. These results are significant because they address transport through a composite liner from a localized source zone which occurs when defects or punctures in the geomembrane of a composite system are present.

Journal of Geotechnical and Geoenvironmental Engin↗