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Regional evaluation of evapotranspiration in the Everglades

Nine sites in the Florida Everglades were selected and instrumented for collection of data necessary for evapotranspiration-determination using the Bowen-ratio energy-budget method. The sites were selected to represent the sawgrass or cattail marshes, wet prairie, and open-water areas that constitute most of the natural Everglades system. At each site, measurements necessary for evapotranspiration (ET) calculation and modeling were automatically made and stored on-site at 15- or 30-minute intervals. Data collected included air temperature and humidity at two heights, wind speed and direction, incoming solar radiation, net solar radiation, water level and temperature, soil moisture content, soil temperature, soil heat flux, and rainfall. Data summarized in this report were collected from January 1996 through December 1997, and the development of site-specific and regional models of ET for this period is described. Latent heat flux is the energy flux density equivalent of the ET rate. Modified Priestley-Taylor models of latent heat flux as a function of selected independent variables were developed at each site. These models were used to fill in periods of missing latent heat flux measurement, and to develop regional models of the entire Everglades region. The regional models may be used to estimate ET in wet prairie, sawgrass or cattail marsh, and open-water portions of the natural Everglades system. The models are not applicable to forested areas or to the brackish areas adjacent to Florida Bay. Two types of regional models were developed. One type of model uses measurements of available energy at a site, together with incoming solar energy and water depth, to estimate hourly ET. This available-energy model requires site data for net radiation, water heat storage, and soil heat flux, as well as data for incoming solar radiation and water depth. The other type of model requires only incoming solar energy, air temperature, and water depth data to provide estimates of hourly ET. The second model thus uses data that are more readily available than the data required for the available-energy model. Computed ET mean annual totals for all nine sites for the 1996-97 period ranged from 42.4 inches per year at a site where the water level is below land surface for several months each year to 57.4 inches per year at an open-water site with no emergent vegetation. Although the density of photosynthetically-active plant leaves has been shown to relate directly to ET in some studies, it does not appear to relate directly to ET in the Everglades, based on comparison of annual ET data with leaf-area index, defined as the Normalized Difference Vegetation Index (NDVI), data from satellite imagery. NDVI and ET appear to be inversely related in the Everglades. The greatest ET rates occurred at open-water sites where the NDVI data indicated the lowest leaf-area index. Among the remaining vegetated sites, there is no clear relation between ET and NDVI, though the highest ET rate corresponded to the lowest NDVI and one of the lowest ET rates corresponded to the highest NDVI value. The variation in ET follows a seasonal pattern, with lowest monthly ET totals occurring in December through February, and highest ET occurring in May through August. The greatest range in monthly ET among all nine sites for the 2-year period occurred at site 3: from 1.81 inches in December 1997 to 6.84 inches in July 1996. A study to compare the Bowen-ratio/energy balance method of ET measurement with the eddy-correlation method was done at one site from June 22, 1998, through September 28, 1998. This comparison indicated that both methods gave comparable values of the Bowen ratio, but there was a considerable difference in available energy measured by the two methods. The mean of all 30-minute measured turbulent heat fluxes from the eddy-correlation apparatus for June 22 through September 29, 1998, was 137.4 watts per square meter, and the mean of the corresponding measured energy was 163.6 watts per square meter, or about 20 percent greater. The disagreement in mean energy fluxes measured by the two methods is problematical and is not fully understood. Although the difference seems to be related to friction velocity, and is practically non-existent at values of friction velocity greater than 0.3 meter per second, the "correctness" of either method cannot be determined with the data available.

Florida

Global geologic map of Europa

Discovered by Galileo Galilei more than 400 years ago and imaged in detail by the Voyager 2 Galileo spacecraft, Jupiter’s icy moon Europa has been a source of intrigue. A range of science investigations indicate that it contains the key ingredients for habitability, notably energy, chemistry, and liquid water. Europa’s surface is geologically complex and, based on the dearth of impact craters, interpreted to be as young as ~60 Ma. The array of geologic features that characterize the surface include extensive ridged plains, regions of broad disruption termed chaotic terrain, long, quasi-linear ridges that span thousands of kilometers, and bands as much as 60 kilometers wide and that extend 100s of kilometers. These features, along with other geophysical measurements, indicate the presence of a global briny liquid water ocean beneath the ice shell. It was not until the arrival of the Galileo spacecraft in 1995 that the true nature and level of complexity of the surface was revealed. Although image data returned by Galileo provided insight into the structure of a variety of regions, the entire satellite has yet to be observed at a regional scale (less than 250 meters per pixel) and the detailed geologic nature of much of its surface remains a mystery. Establishing the global context of the distribution and timing of Europan geologic units forms a basis to understand regional and local scale processes, serves as a tool for the planning of future missions, and most of all is essential to gaining insight into the potential habitability of this icy world.

Scientific Investigations Map

Potentiometric surface maps and groundwater-level hydrographs for confined aquifers of the New Jersey Coastal Plain, 2018

The U.S. Geological Survey, in cooperation with the New Jersey Department of Environmental Protection (NJDEP), prepared potentiometric surface maps for 10 confined aquifers of the New Jersey Coastal Plain physiographic province based on water-level measurements collected during late 2018 and early 2019 from 951 wells in New Jersey and parts of Pennsylvania and Delaware. Maps were prepared for the confined Cohansey aquifer, Rio Grande water-bearing zone, Atlantic City 800-foot sand, Piney Point aquifer, Vincentown aquifer, Wenonah-Mount Laurel aquifer, Englishtown aquifer system, and the upper, middle, and lower aquifers of the Potomac-Raritan-Magothy aquifer system. Potentiometric surface maps indicate regional cones of depression in the following aquifers and the counties in which they are centered: Atlantic City 800-foot sand in Atlantic County, the Piney Point aquifer in Cumberland County, the Wenonah-Mount Laurel aquifer and Englishtown aquifer system in Monmouth and Ocean Counties, the Wenonah-Mount Laurel aquifer in Camden and Gloucester County, the upper aquifer of the Potomac-Raritan-Magothy aquifer system in Ocean County, and the upper, middle, and lower aquifers of the Potomac-Raritan-Magothy aquifer system in Camden County. Cones of depression with smaller areal extents were in the confined Cohansey aquifer, the Rio Grande water-bearing zone, the Atlantic City 800-foot sand centered in Cape May County, the Piney Point aquifer centered in Ocean County, the Wenonah-Mount Laurel aquifer in Salem and Burlington Counties, the Englishtown aquifer system in Camden County, the upper aquifer of the Potomac-Raritan-Magothy aquifer system in Monmouth County, and the middle aquifer of the Potomac-Raritan-Magothy aquifer system in Monmouth, Ocean, and Salem Counties. No cone of depression was interpreted in the Vincentown aquifer. Long-term hydrographs are presented for 75 wells spanning each of the 10 confined aquifers, and contain a mix of discrete water-level measurements and daily mean water levels based on continuously recorded 15-minute data. Changes of water levels during 2014–19, as indicated by the hydrographs, were compared with those of previous periods to assess any departures from historical data. During 2014–19, water levels were stable and fluctuated within similar ranges as previous periods in the following aquifers and locations: all wells in the confined Cohansey aquifer, the Rio Grande water-bearing zone, the Vincentown aquifer, the Englishtown aquifer system, the Piney Point aquifer wells in Burlington and Ocean Counties, six of eight wells in the Wenonah-Mount Laurel aquifer, all wells in the upper and lower aquifers of the Potomac-Raritan-Magothy aquifer system outside NJDEP Critical Areas, and all wells in the middle aquifer of the Potomac-Raritan-Magothy aquifer system except those within NJDEP Critical Area II. Increasing water levels in 2014–19, ongoing since historical periods, were indicated in the following aquifers and locations: Atlantic County wells in the Piney Point aquifer, all wells in the upper and lower aquifers of the Potomac-Raritan-Magothy aquifer system outside NJDEP Critical Areas, and all wells in the middle aquifer of the Potomac-Raritan-Magothy aquifer system within NJDEP Critical Area II. Water levels in the Atlantic City 800-foot sand also increased during 2014–19 in wells in Atlantic County and northern Cape May County closer to the center of the cone of depression in that aquifer, which is a response unique to this period and absent from previous periods. During 2013–19, continued decreasing water levels, ongoing since previous periods, were indicated by hydrographs of Atlantic City 800-foot sand wells in southern Cape May County, Piney Point aquifer wells in Cumberland County where the regional cone of depression is located, and two wells in the Wenonah-Mount Laurel aquifer—070478, which in 2014–19 departed from previous periods, and 330020, which continued a gradual decrease throughout its period of record.

New Jersey

Plan to coordinate post-earthquake investigations supported by the National Earthquake Hazards Reduction Program (NEHRP)

Introduction This report presents a plan supported by the National Earthquake Hazards Reduction Program (NEHRP) to coordinate domestic and international post-earthquake investigations (herein called “the Plan”). Post-earthquake scientific and engineering investigations are undertaken to capture critical information to understand the causes and impacts of the event, lessons from which can substantially improve the Nation’s resilience after future earthquakes. NEHRP is the Federal Government’s coordinated nationwide program to reduce risks to life and property from earthquakes. The Plan describes the activation and coordination of the four designated NEHRP Agencies in the Federal Government: Federal Emergency Management Agency, National Institute of Standards and Technology, U.S. National Science Foundation, and U.S. Geological Survey (USGS). The Plan also describes coordination between NEHRP Agencies and other organizations that may participate in pre-event and post-earthquake investigations, including non-NEHRP Federal agencies; State, regional, local, Tribal, and territorial agencies; domestic nongovernmental organizations; academic institutions and affiliated organizations; private companies; foreign governmental agencies and nongovernmental organizations; and international organizations. The Plan delineates the coordination of NEHRP post-earthquake scientific and engineering investigations to document the direct, indirect, and cascading physical and societal impacts from fault rupture and ground shaking hazards and from secondary hazards such as landslides, liquefaction, and tsunamis. In addition, the Plan identifies pre-event activities necessary to ensure that post-earthquake investigations are executed effectively. The USGS is the lead NEHRP Agency for activating and coordinating NEHRP post-earthquake investigations and for implementing this Plan. The USGS also leads coordination of the NEHRP Agencies in completing the pre-event activities identified in the Plan. The Plan has new information and supersedes USGS Circular 1242, “The Plan to Coordinate NEHRP Post-Earthquake Investigations,” which was published in 2003. This second-generation Plan was developed with the assistance of the Applied Technology Council (ATC) of Redwood City, California, under USGS contract 140G0121P0309, ATC-155. A 17-member Project Review Panel provided guidance on plan development, and input was solicited from subject matter experts representing key stakeholder groups and from participants at a public workshop.

Circular

Altitude of the potentiometric surface and depth to water in the Mississippi River Valley alluvial aquifer, spring 2022

Potentiometric-surface and depth-to-water maps for spring 2022 were created for the Mississippi River Valley alluvial aquifer (MRVA) using groundwater-altitude data from 1,136 wells completed in the MRVA and from the altitude of the top of the water surface in area rivers from 160 streamgages. The potentiometric-surface and depth-to-water maps for 2022 were created to support investigations to characterize the MRVA as part of the U.S. Geological Survey Water Availability and Use Science Program. Sufficient data were available to map the potentiometric surface and depth to water of the MRVA for spring 2022 for about 83 percent of the aquifer area. The potentiometric contours ranged from 0 to 340 feet (ft) above the North American Vertical Datum of 1988. The regional direction of groundwater gradient was generally to the south-southwest, except in areas of groundwater-altitude depressions, where the groundwater gradient was into the depression, and near rivers, where the groundwater gradient can be from aquifer to the river or from the river into the aquifer. There are large depressions in the potentiometric-surface map in the lower one-half of the Cache region and in much of the Grand Prairie and Delta regions. Depth to water in the MRVA, spring 2022, by well ranged from 5.00 ft above land surface to 145.66 ft below land surface.

Mississippi River Valley alluvial aquifer

Groundwater, surface-water, and water-chemistry data, Black Mesa area, northeastern Arizona—2019–2021

The Navajo (N) aquifer is an extensive aquifer and the primary source of groundwater in the 5,400-square-mile Black Mesa area in northeastern Arizona. Water availability is an important issue in the Black Mesa area because of the arid climate, past industrial water use, and continued water requirements for municipal use by a growing population. Precipitation in the area typically ranges from less than 6 to more than 16 inches per year, depending on location. The U.S. Geological Survey water-monitoring program in the Black Mesa area began in 1971 and provides information about the long-term effects of groundwater withdrawals from the N aquifer for industrial and municipal uses. This report presents the results of data collected as part of the monitoring program in the Black Mesa area from calendar years 2020–2021 and, additionally, uses streamflow statistics from November and December 2019. The monitoring program includes measurements of (1) groundwater withdrawals (pumping), (2) groundwater levels, (3) spring discharge, (4) surface-water discharge, and (5) groundwater chemistry. In calendar year 2020, total groundwater withdrawals were estimated to be 2,680 acre-feet (acre-ft), and, in 2021, total withdrawals were estimated to be 2,570 acre-ft. Total withdrawals during 2021 were about 65 percent less than total withdrawals in 2005 because the Peabody Western Coal Company discontinued its use of water to transport coal in a coal slurry pipeline after 2005 and ceased mining operations in 2019. Owing to Navajo Nation and Hopi Reservation access restrictions during the Coronavirus pandemic, water levels were not collected from municipal wells in 2020 or 2021. Water levels measured in 2021 from wells completed in the unconfined areas of the N aquifer within the Black Mesa area showed a decline in 7 of 13 wells when compared with water levels from the prestress period (prior to 1965). The changes in water levels across all 13 wells ranged from +8.4 feet (ft) to −42.4 ft, and the median change was −0.4 ft. Water levels also showed decline in 11 of 12 wells measured in the confined area of the aquifer when compared to the prestress period. The median change for the confined area of the aquifer was −25.9 ft, with changes across all 12 wells ranging from +17.3 ft to −133.7 ft. Spring flow was measured at four springs between 2020 and 2021. Flow fluctuated during the period of record for Burro Spring and Pasture Canyon Spring, but a decreasing trend was statistically significant (p<0.05) at Moenkopi School Spring and Unnamed Spring near Dennehotso, Arizona. Discharge at Burro Spring has remained relatively constant since it was first measured in the 1980s, and discharge at Pasture Canyon Spring has fluctuated for the period of record. Continuous records of surface-water discharge in the Black Mesa area were collected from streamflow-gaging stations at the following sites: Moenkopi Wash at Moenkopi 09401260 (1976–2021), Dinnebito Wash near Sand Springs 09401110 (1993–2020), Polacca Wash near Second Mesa 09400568 (1994–2020), and Pasture Canyon Springs 09401265 (2004–2021). Median winter flows (November through February) of each winter were used as an estimate of the amount of groundwater discharge at the above-named sites. For the period of record, the median winter flows have generally remained constant at Polacca Wash and Pasture Canyon Springs, whereas a decreasing trend was observed at Moenkopi Wash and Dinnebito Wash. In 2020 and 2021, water samples were collected from a total of four springs in the Black Mesa area and analyzed for selected chemical constituents. Results from the four springs were compared with previous analyses from the same springs. Dissolved solids, chloride, and sulfate concentrations increased at Moenkopi School Spring during the more than 30 years of record at that site. Concentrations of dissolved solids and sulfate at Pasture Canyon Spring have not varied significantly (p>0.05) since the early 1980s, and there is no increasing or decreasing trend in those data. However, concentrations of chloride from Pasture Canyon Spring show a diminishing trend. Concentrations of dissolved solids, chloride, and sulfate at Unnamed Spring near Dennehotso have varied for the period of record, but there is no statistical trend in the data. Concentrations of dissolved solids at Burro Spring have varied for the period of record, but there is no statistical trend in the data. However, concentrations of chloride and sulfate from Burro Spring show a trend towards lower concentrations.

Arizona

Determination of per- and polyfluoroalkyl substances in water by direct injection of matrix-modified centrifuge supernatant and liquid chromatography/tandem mass spectrometry with isotope dilution

A direct-injection liquid chromatography/tandem mass spectrometry method was developed to determine 34 per- and polyfluoroalkyl substances (PFAS), including selected branched isomers, in centrifuge supernatant of matrix-modified (amended with approximately 50 percent methanol) water samples. The method has been validated in reagent water, surface water, groundwater, and wastewater effluent. Other water types (for example, drinking water, untreated wastewater, and landfill leachate) have been analyzed by the method but not systematically validated. Recovery of isotope-dilution standards, added to each sample, may be used to assess method performance in nonvalidated matrices on a sample-by-sample basis. Using this method, PFAS concentrations were determined in the range of 2–2,000 nanograms per liter in water samples. This range can be extended by diluting concentrated samples. At circumneutral pH, most compounds are present in the environment in their ionized form, and data are reported as such (for example, perfluorooctanoic acid is referred to as “perfluorooctanoate” [PFOA], perfluorooctane sulfonic acid is referred to as “perfluorooctane sulfonate” [PFOS]). Sample preparation procedures were designed without the use of filtration and with minimum sample handling steps to mitigate procedural losses of target compounds due to sorption to surfaces. Further, isotope-dilution quantification allowed for the correction of bias that may result from procedural losses, matrix-induced signal suppression or enhancement, and other factors. Validation experiments to characterize bias and variability, method detection level, and holding time were done in four distinct water matrices—reagent water, surface water, treated wastewater effluent, and groundwater—at multiple concentration levels. Mean PFAS recoveries met data quality objectives of bias and variability studies in all four validation matrices except for two compounds with low and variable recovery in the reagent water matrix only. Isotope-dilution standards, treated as surrogate compounds, were analyzed in more than 1,500 customer-submitted environmental samples with aggregate recovery of 102.5±6.5 percent (mean±standard deviation). Maximum holding times for all target compounds in the four validation matrices were 28 days for refrigerated samples and 90 days for frozen samples.

Techniques and Methods

Geophysical identification of potential groundwater – surface water interactions in the Bonita Peak Mining District, San Juan County, Colorado

This report includes the results and interpretation of geophysical investigations to aid in the location, identification, and conceptual site model (CSM) development of the near surface groundwater and surface water hydrology of the Upper Cement Creek and California Gulch of the Animas Rivers within the Bonita Peak Mining Districts (BPMD). Mine influenced water (MIW) from numerous mine adits within the BPMD has altered the geochemistry and ecology of these ground and surface waters. Many studies of varying scales have investigated the geology, hydrogeology, geochemistry, and aqueous chemistry of these adits and impacted areas. Field investigations using non-invasive geophysical methods were conducted in the summer of 2019 to aid in identifying potential groundwater inputs to these streams and further the CSM of the near surface within and along these streams. Two field deployments were completed in August and September of 2019. In August 2019, Phase 1 was completed using multifrequency electromagnetic induction (EMI) and thermal infrared imaging (TIR) to measure the bulk electrical conductivity, magnetic susceptibility, and the temperature response at known and suspected groundwater seeps into the Upper Cement Creek and California Gulch stretches of these alpine streams. Results and interpretation from Phase 1 were used to co-locate stretches of these streams for further detailed fiber optic distributed temperature system (FODTS) monitoring of the temperature dynamics for submeter identification of potential groundwater seeps during Phase 2. Phase 2 included additional EMI measurements, FODTS measurements, and repeated some Phase 1 measurements for improved data quality. All these data were used for the combined qualitative interpretation identifying seep locations. The data from both Phase 1 and Phase 2 are available in the USGS data release at: https://www.sciencebase.gov/catalog/item/5f18a30082cef313ed84879b. These data include detailed near-surface electrical conductivity and magnetic susceptibility mapping, discrete TIR imaging, and several kilometers of FODTS data. These data were georeferenced and used to identify potential groundwater seeps into these streams. The results indicate a complex near surface geophysical and hydrogeologic regime. Seeps are classified and spatially correlated to the EMI, TIR, and geochemical sampling results. This report is a thorough compilation of the geophysical field efforts in the summer of 2019, the data processing, and interpretations of these data. These data alone should not be used for final interpretations of the complex hydrogeology within these alpine systems. Rather, these data should be combined with other known data from various investigations to further refine the CSM and guide decisions for future investigations, watershed protective measures, and other site decisions. Geographical information system (GIS) layers of these results are available to project managers for such integration and combined interpretations.

Colorado

Eruptive history within the vicinity of Al Madīnah in northern Harrat Rahat, Kingdom of Saudi Arabia

The northernmost part of the Harrat Rahat volcanic field contains early Pleistocene to Holocene mafic eruptive products within the vicinity of the city of Al Madīnah, Kingdom of Saudi Arabia. A detailed geologic investigation into the eruptive history of a 570 square kilometer (km 2 ) area covering Al Madīnah and the surrounding area has yielded 33 mapped Quaternary volcanic units consisting of lava flows, scoria cones, and shield volcanoes. These eruptive products consist of continental, intraplate alkalic and minor transitional basalts, hawaiites, and a single mugearite that were emplaced from at least 1,014±14 thousand years ago (ka) to a single Holocene eruption in 1256 C.E. Lava flows are generally 10 to 15 kilometers (km) long (but can reach 23 km long), 1 to 3 km wide, and at least 10 meters thick. Most of the mapped units erupted episodically between 400 and 340 ka and 180 and 100 ka. Despite small individual volumes (less than 1 cubic kilometers dense rock equivalent), each unit represents eruption of a distinct magma batch that was strongly influenced by clinopyroxene, olivine, and plagioclase fractionation. Some of these units are interpreted to have undergone magma mixing pre- and (or) syneruptively. Integrating eruption ages, geochemistry, and paleomagnetic data yields evidence that some eruptions were temporally and (or) spatially clustered. Aligned scoria cones and elongate vent edifices were constructed atop fissure vent systems that reflect the local stress field, which controls dike ascent through the middle and upper crust.

Professional Paper

Salinas Valley integrated hydrologic and reservoir operations models, Monterey and San Luis Obispo Counties, California

The area surrounding the Salinas Valley groundwater basin in Monterey and San Luis Obispo Counties of California is a highly productive agricultural area, contributes substantially to the local economy, and provides a substantial portion of vegetables and other agricultural commodities to the Nation. This region of California provides about half of the Nation’s lettuce, celery, broccoli, and spinach each year. Thus, this agricultural area provides substantial volumes of agricultural products not just for California but for the United States. Changes in population and increased agricultural development, which includes a shift toward more water-intensive crops, and climate variability, have put increasing demand on both surface-water and groundwater resources in the valley. This situation has resulted in water management challenges in the Salinas Valley that generally relate to the distribution of the water supply throughout the basin. Where and when the water is present in the surface and subsurface does not coincide with where and when the water is needed. Historically, to deal with the distribution issue, water has been used conjunctively in the valley. Conjunctive use is a water management strategy that coordinates surface-water and groundwater use to maximize water availability. Groundwater is used throughout the Salinas Valley to meet water demands when surface-water supplies are insufficient. The availability of surface water is constrained by climate. Precipitation and streamflow vary seasonally and year to year. Although there are two reservoirs in the Salinas Valley to capture and store water during wet periods, the only conveyance of reservoir water to coastal agricultural areas is the Salinas River. Increasing demand for groundwater and surface-water resources throughout the Salinas Valley has resulted in undesirable effects from unsustainable water use, such as surface-water depletion, groundwater-level declines, storage depletion in the principal aquifers, and seawater intrusion. To address these escalating issues, local communities, water management agencies, and groundwater sustainability agencies are evaluating how to sustainably manage both their surface-water and groundwater resources. To meet water demands and reduce the undesirable effects of unsustainable water use, continued conjunctive management of surface water and groundwater would ideally incorporate strategies to deal with increases in demand and climate variability. To evaluate the challenging water management issues in the Salinas Valley, the U.S. Geological Survey, Monterey County Water Resources Agency, and the Salinas Valley Basin Groundwater Sustainability Agency developed a comprehensive suite of models that represent the Salinas Valley hydrogeologic system called the Salinas Valley System Model. The geologic framework is known as the Salinas Valley Geologic Framework and was developed to characterize the subsurface using various topographic and geologic data sources, including information on hydrogeologic units, their surfaces and extents, geologic structures, lithology, and elevations from borehole data and cross sections, as well as details on faults and existing models. The surface-water model is called the Salinas Valley Watershed Model and simulates the Salinas River watershed. Monthly surface-water inflows into the integrated hydrologic model domain were simulated using the Salinas Valley Watershed Model. The historical model uses historical climate data, water and land use data, and reservoir releases to simulate agricultural operations, including landscape water demands, diversions, and reclaimed wastewater. The operational model adds an embedded reservoir operations framework to the simulation of the historical model that allows specified operational rules to simulate reservoir releases and changes in reservoir storage. The operational model assumes current reservoir operations and constant land use, which differs from historical conditions. Thus, the operational model is a hypothetical baseline model that can be used by local water managers to evaluate and quantify potential benefits of water supply projects. Together, the geologic framework, watershed, historical, and operational models form a tool that can be used to simulate irrigated agriculture and associated reservoir operations of the integrated hydrologic system of the Salinas Valley.

California

Assessment and characterization of ephemeral stream channel stability and mechanisms affecting erosion in Grand Valley, western Colorado, 2018–21

The Grand Valley in western Colorado is in the semiarid Southwest United States. The north side of the Grand Valley has many ungaged ephemeral streams, which are of particular interest because (1) the underlying bedrock geology, Late Cretaceous Mancos Shale, is a sedimentary rock deposit identified as a major salinity contributor to the Colorado River and (2) despite infrequent streamflows of short duration, monsoon-derived floods in these ephemeral streams can carry substantial amounts of sediment downstream, affecting upstream and downstream banks and channel cross sections. The study area is of interest, because salinity, or the total dissolved solids concentration, in the Colorado River causes an estimated $300 million to $400 million per year in economic damages in the United States, and it is estimated 62 percent of the Upper Colorado River Basin’s total dissolved solid loads originate from geologic sources. In an effort to minimize salt contributions to the Colorado River from public lands administered by the Bureau of Land Management, a comprehensive salinity control approach is typically used to reduce nonpoint sources of salinity through land management techniques and practices. In 2018, the U.S. Geological Survey, in cooperation with the Bureau of Land Management, began an assessment of ephemeral streams located on the north side of the Grand Valley, western Colorado, to characterize stream channel stability and identify mechanisms affecting erosion. The U.S. Geological Survey developed a method for automatically extracting channel cross-section geometry from existing remotely sensed terrain models. Based on estimated flood stage and surrogate streamflows, hydraulic characteristics were calculated. Furthermore, the channel geometries and hydraulic characteristics were used to estimate channel stability using a statistical model. Cross-section stabilities were determined from a stream channel stability assessment for a subset of 1,406 visited (field observed) locations out of 13,415 cross sections, which were delineated from remotely sensed terrain models. The application of Manning’s resistance equation in combination with multiple logistic regression models demonstrated channel stability can be estimated with a 0.845 goodness of fit for a validation dataset when using a combination of drainage area, width-to-depth ratio, sinuosity, and shear stress as the explanatory variables. Stream channel stability was extrapolated for 13,415 unvisited (not field observed) cross sections using the multiple logistic regression model and defined explanatory variables. Mapping of the ephemeral streams and their associated stabilities may be used by the Bureau of Land Management to prioritize areas for remediation or changes in management strategies to reduce sediment and salinity loading to the Colorado River. The study found channel stability within the ephemeral streams to be spatially variable, longitudinally discontinuous, and dictated by changes in channel bed slope. The stable ephemeral streams were relatively wide and shallow and often had smaller drainage areas with less potential for producing shear stresses capable of overcoming channel adhesion. A change in channel bed slope can provide the means necessary to generate shear stresses appropriate to initiate erosion and a subsequent stability transition to incising channels. Channel widening happens when either or both banks of an incising channel reach a critical height for mass wasting, or when channel curvature causes higher sidewall stress. Regardless, widening channels can promote increases in sinuosity and subsequently reduce steep channel bed slopes. Consequently, stable and widening channels can have comparable bed slopes, making channel bed slope a poor explanatory variable to predict channel stability overall, despite its function to initiate channel instability. The results were based on a surrogate 0.10 annual exceedance probability (AEP; return period equal to the 10-year flood) interval streamflow, although it was recognized fluctuations in streamflow would also affect channel stability. Past and current changes within the study area affect streamflow; therefore, mechanisms affecting erosion include land use disturbances, soil compaction, loss of vegetation cover, drought, less frequent and more extreme precipitation, and fires—which all intensify the potential runoff and erosion within the study area.

Colorado

Dissolved arsenic concentrations in surface waters within the upper portions of the Klamath River Basin, Oregon and California

Arsenic toxicity is an environmental health problem. Levels of arsenic in surface waters at some locations in the Klamath River Basin in southern Oregon and northern California can exceed the U.S. Environmental Protection Agency (EPA) standard for drinking water. There are both anthropogenic and natural sources of arsenic. The Klamath River Basin consists primarily of volcanic deposits and contains an underground geothermal system with hot springs and warm water wells, all known natural sources of arsenic. Anthropogenic sources of arsenic are related to the agricultural use of herbicides, fungicides, and insecticides. Surface water arsenic levels can also be affected by fertilizer amendments, evaporative concentration, oxygen-level depletion, and various geochemical transformations that can increase arsenic mobilization. In this study by the U.S. Geological Survey and the Bureau of Reclamation, dissolved concentrations of arsenic, copper, and lead were measured in surface waters at 39 unique sites within the upper portions of the Klamath River Basin between 2018 and 2022. In every year, except 2022, sites were sampled four times between April and November. Surface-water arsenic concentrations varied up to four-orders of magnitude among sites. Median arsenic concentration was lowest at Cherry Creek (0.03 micrograms per liter [μg/L]) and highest at Wood Kimball Spring (36.7 μg/L), two sites located north of Upper Klamath Lake. The highest arsenic concentrations (17.4±4.9 μg/L, n =3) were found in drain sites (defined here as a waterbody returning used irrigation water) while the lowest arsenic concentrations were found in an artesian well (0.8 μg/L, n =1). The elevated arsenic concentrations of the drain sites suggest that arsenic might be concentrated or mobilized by agricultural activities, water re-use practices, and (or) by geochemical processes occurring around water stored in drains (that is, in the water column and across sediment water boundaries). A source of arsenic in drain water in the Klamath Strait Drain area includes water used for irrigation originating from Ady Canal. Other potential sources include groundwater, geothermal water, and local soils and sediments. Seasonal differences in surface-water arsenic concentrations were detected at 13 sites, 10 of which had higher arsenic concentrations in summer than in either spring or fall. The sites sampled around Upper Klamath Lake, the impounded rivers, one of the two canal sites, and 5 of the 14 river sites had higher surface-water arsenic concentrations in the summer than in either spring or fall. Surface-water arsenic concentrations from groundwater sources (that is, springs and in the artesian well) did not vary significantly among seasons (p-values greater than 0.1). Median surface-water concentrations of copper and lead ranged from 0.03 to 3.7 μg/L, and from 0.013 to 0.175 μg/L ( n =2–18), respectively. Dissolved concentrations of both metals were below acute toxicity endpoints reported by the EPA for freshwater animals. Surface-water arsenic concentrations varied independently from corresponding changes in surface-water lead or copper concentrations. However, arsenic concentrations measured in bed-sediment samples collected from a subset of sites located north of Upper Klamath Lake correlated strongly and significantly with the corresponding sedimentary lead concentrations ( p =0.015). Aqueous arsenic speciation measured in a subset of sites in 2019 and 2022 showed that all the arsenic existed as arsenic (V), the most oxidized arsenic species, and presumably, the least toxic. The highest proportions of arsenite (As(III)), the presumably most toxic arsenic species, relative to total arsenic concentrations were found at drain sites. Our assessment of dissolved arsenic concentrations in various surface-water bodies in the Upper Klamath River Basin reveals geographical areas of consistently low (below 2.1 μg/L), moderate (below 10 μg/L) and high (above 10 μg/L) surface-water arsenic concentrations. South of Upper Klamath Lake, surface-water arsenic concentrations were consistently higher than 20 μg/L at two drain sites located in an area of predominant agricultural land use with extensive water re-use practices. North of Upper Klamath Lake, surface-water arsenic concentrations greater than 20 μg/L were consistently measured at sites with limited nearby agricultural activities, suggesting a geogenic source. The consistently high arsenic levels from the Wood River at Jackson F. Kimball State Park, Fort Creek, and Crooked Creek, which are sites located at or near headwater spring sources, suggest a natural background source of arsenic. Water flowing downstream from this area could be a potential source of arsenic to Upper Klamath Lake and the Upper Klamath River.

California, Oregon

Effects of storm-water runoff on local ground-water quality, Clarksville, Tennessee

Storm-related water-quality data were collected at a drainage-well site and at a spring site in Clarksville, Tennessee, to define the effects of storm-water runoff on the quality of ground water in the area. A dye-trace test verified the direct hydraulic connection between the drainage well and Mobley Spring. Samples of storm run off and spring flow were collected at these sites for nine storms during the period February to October 1988. Water samples were collected also from Mobley Spring and two other springs and two observation wells in the area during dry-weather conditions to assess the general quality of ground water in an urban karst terrain. Evaluation of the effect of storm-water runoff on the quality of local ground water is complicated by the presence of other sources of contaminants in the area Concentrations and load for most major constituents were much smaller in storm-water runoff at the drainage well than in the discharge of Mobley Spring, indicating that much of the chemical constituent load discharged from the spring comes from sources other than the drainage well. However, for some of the minor constituents associated with roadway runoff (arsenic, copper, lead, organic carbon, and oil and grease), the drainage well contributed relatively large amounts of these constituents to local ground water during storms. The close correlation between concentrations of total organic carbon and concentrations of most trace metals at the drainage-well and Mobley Spring sites indicates that these constituents are transported together. Many trace metals were flushed early during each runoff event. Mean storm loads for copper, lead, zinc, and four nutrient species (total nitrogen, ammonia nitrogen, total phosphorus, and orthophosphorus) in storm-water runoff at the drainage-well site were lower than mean storm load predicted from an existing regression model. The overprediction by the model may be a result of the small size of the drainage area relative to the range of drainage areas used in the development of the models, or to the below-normal amounts of rainfall during the period of sampling for this investigation. Loads& in storm-water runoff for 22 constituents were extrapolated from sampled storms to total loads for the period February to October 1988. Calculated loads for trace metals for the period ranged from 0.030pound.s for cadmium to 12pound.s for strontium. Loads of the primary nutrients ranged from 0.97pounds for nitrite as nitrogen to 34pounds of organic nitrogen. Storm-water quality at the drainage-well and Mobley Spring sites was compared to background water quality of the local aquifer; as characterized by dry-weather samples from three springs and two observation wells in the Clarksville area. Concentrations of total-recoverable cadmium, chromium, copper, lead, and nickel were higher in many stormwater samples from both the drainage-well and Mobley Spring sites than in samples from any other site. In addition, concentrations of total organic carbon, methylene blue active substances, and total-recoverable oil and grease were generally higher in storm-water samples from the drainage-well site than in any ground-water sample. Densities of fecal coliform and fecal streptococcus bacteria and concentrations of total recoverable iron, manganese, and methylene blue active substances in storm samples from the drainage-well site exceeded the maximum contaminant levels listed in Tennessee’s drinking-water standards (1988) by as much as 2,500 and 5,500 colonies per 100 milliliters, and 2.7, 0.29, and 0.05 milligrams per liter, respectively. Densities of fecal coliform and fecal streptococcus bacteria and concentrations of total-recoverable iron, manganese, and lead in storm samples from Mobley Spring exceeded the maximum contaminant levels by as much as 500 and 4,500 colonies per 100 milliliters, and 18.7,0.65, and 0.02 milligrams per liter, respectively. For iron, manganese, and bacteria, these undesirable levels are not necessarily attributable to storm-water recharge, because concentrations of these constituents also exceeded drinking-water standards in one or more of the dry-weather samples from selected springs and observation wells in the area.

Tennessee

Tephra from Kīlauea’s 2008–2018 lava lake eruption—Proximal deposits and dispersal characteristics

A network of ten buckets was established early in the 2008–2018 summit eruption at Kīlauea to collect proximal tephra ejected from the new, informally named the “Overlook crater”; the buckets were emptied on most days of the eruption thereafter. This report summarizes the results of more than 2,400 different sampling intervals (most 1–3 days long) during the eruption, focusing on the physical and dispersal characteristics of the tephra deposits. The network was within about 300 meters south of the vent to capture tephra dispersed by the dominant northeast trade wind. The juvenile tephra mainly reflected spattering at the southeast (SE) sink, a downwelling area in the southeastern part of the lava lake in the Overlook crater that remained in the same area throughout the eruption, with admixtures of solid rock and secondary minerals derived from the wall of the crater. The proportion of juvenile material to lithic material ranged widely early in the eruption but was generally greater than 90 percent for the last 6 years of the eruption as lake level rose and the crater walls decreased in height and became more stable. The accumulation rate of tephra at each bucket was strongly dependent on the location of the bucket and reflects the interplay between lava lake level and wind direction and speed. The mass per unit area (m/a) of collected tephra was a maximum of about 97 kilograms per square meter for the entire eruption, equivalent to a thickness of about 75 millimeters. Thirty-two explosive events with a volcanic explosivity index of −2 to −4 deposited much of the tephra in the network. Fifteen of these rock-fall-induced events occurred within 6 days of one another. Pele’s hair, a volcanic glass predominantly associated with quieter activity at the vent in the final half of the eruption, was dispersed more than 60 kilometers downwind from the lava lake and formed a nearly continuous deposit near the Overlook crater. This eruption was probably the most frequently sampled long-lasting eruption in history, but most of the deposits are ephemeral. The collected samples, although generally of small mass, are retained by the Hawaiian Volcano Observatory and are available for detailed study.

Hawaii

Monthly variability and possible sources of nitrate in ground water beneath mixed agricultural land use, Suwannee and Lafayette Counties, Florida

In an area of mixed agricultural land use in Suwannee and Lafayette Counties of northern Florida, water samples were collected monthly from 14 wells tapping the Upper Floridan aquifer during July 1998 through June 1999 to assess hydrologic and land-use factors affecting the variability in nitrate concentrations in ground water. Unusually high amounts of rainfall in September and October 1998 (43.5 centimeters total for both months) resulted in an increase in water levels in all wells in October 1998. This was followed by unusually low amounts of rainfall during November 1998 through May 1999, when rainfall was 40.7 centimeters below 30-year mean monthly values. The presence of karst features (sinkholes, springs, solution conduits) and the highly permeable sands that overlie the Upper Floridan aquifer provide for rapid movement of water containing elevated nitrate concentrations to the aquifer. Nitrate was the dominant form of nitrogen in ground water collected at all sites and nitrate concentrations ranged from less than 0.02 to 22 milligrams per liter (mg/L), as nitrogen. Water samples from most wells showed substantial monthly or seasonal fluctuations in nitrate concentrations. Generally, water samples from wells with nitrate concentrations higher than 10 mg/L showed the greatest amount of monthly fluctuation. For example, water samples from six of eight wells had monthly nitrate concentrations that varied by at least 5 mg/L during the study period. Water from most wells with lower nitrate concentrations (less than 6 mg/L) also showed large monthly fluctuations. For instance, nitrate concentrations in water from four sites showed monthly variations of more than 50 percent. Large fluctuations in nitrate concentrations likely result from seasonal agricultural practices (fertilizer application and animal waste spreading) at a particular site. For example, an increase in nitrate concentrations observed in water samples from seven sites in February or March 1999 most likely results from application of synthetic fertilizers during the late winter months. Lower nitrate concentrations were detected in water samples from five of eight wells sampled during high-flow conditions for the Suwannee River in March 1998 compared to low-flow conditions in November 1998. Evidence for reduction of nitrate due to denitrification reactions was observed at one site (AC-1), as indicated by elevated concentrations of nitrogen gas and a corresponding increase in nitrogen isotope (d15N-NO3) values with a decrease in nitrate concentrations. Denitrification is unlikely at other sites based on the presence of dissolved oxygen concentrations greater than 2 mg/L in ground water and no observed trend between nitrate concentrations and values d15N-NO3 values. Nitrate was the dominant nitrogen species in most monthly rainfall samples; however, ammonium concentrations were similar or greater than nitrate during November and December 1998. During February through May 1999, both nitrate and ammonium concentrations were substantially higher in monthly rainfall samples collected at the study area compared to mean monthly concentrations at the Bradford Forest site located east of the study area, which is part of the National Atmospheric Deposition Program/National Trends Network. Also, higher nitrogen deposition rates in the study area compared to those at Bradford Forest could indicate that substantial amounts of ammonia are volatilized from fertilizers and animal wastes, released to the atmosphere, and incorporated as nitrate and ammonium in rainfall deposited in the middle Suwannee River Basin. Ground-water samples from most sites had d15N-NO3 values that indicated a mixture of inorganic and organic sources of nitrogen, which corresponded to multiple land uses where both synthetic fertilizers and manure are used on fields near these sites. Distinct d15N-NO3 signatures, however, were observed at some sites. For example, water samples from areas of row-crop farming as the dominant land use had d15N-NO3 values less than 4 per mil, indicating an inorganic nitrogen source such as synthetic fertilizer. In contrast, d15N-NO3 values greater than 9 per mil were found in water samples from three sites where manure from dairy and or poultry operations is spread on fields throughout the year.

Florida

Mapping Arundo donax (Arundo cane) with multispectral imagery before, during, and after herbicide treatment along the Rio Grande in Webb County, Texas, 2020–21

Arundo donax , commonly called Arundo cane, giant reed, or Carrizo cane, is an invasive bamboo-like perennial grass common in riparian areas throughout the southwestern United States. In Texas, not only does it negatively affect riparian ecosystems, but it has also become a problem for border security because it reduces visibility along the Rio Grande. To address these problems, in 2015 the Texas State Soil and Water Conservation Board was authorized by the Texas State Legislature to develop a program to eradicate Arundo cane along the Rio Grande. In 2020, the Texas State Soil and Water Conservation Board applied imazapyr and glyphosate herbicides along a 19.3-kilometer reach of the Rio Grande, northwest of Laredo, Texas. The U.S. Geological Survey, in cooperation with the Texas State Soil and Water Conservation Board and the Webb Soil and Water Conservation District, used WorldView-3 Standard high-resolution satellite imagery to map Arundo cane extent along the reach before , during , and after the herbicide-treatment period on June 30, 2020, September 26, 2020, and May 7, 2021, respectively. A maximum likelihood supervised classification analysis was computed on the images to map the spatial extent and estimate the area covered by Arundo cane. The estimated area covered by Arundo cane in the before classification was 1,282,000 square meters, in the during classification was 1,064,000 square meters, and in the after classification was 1,108,000 square meters. The qualitative comparison of the three images shows that there was an overall decrease in vegetation classified as Arundo cane throughout the study area.

Texas

Monitoring marine eruptions

Introduction Submarine volcanoes produce much of the same seismicity and eruptive activity as subaerial volcanoes and can pose hazards to society. Although they can be monitored with similar techniques and methods as described in other chapters of this volume, their submerged location brings unique challenges. This chapter addresses these challenges and provides recommendations for monitoring volcanoes fully or partly in marine environments to meet the capabilities described in other chapters of this volume. The United States and its territories host dozens of submarine volcanoes with most (around 60) in the Commonwealth of the Northern Mariana Islands. Approximately 20 of the Northern Mariana Islands submarine volcanoes are known to be hydrothermally active, and 10 have confirmed eruptions since the 1950s (for example, Baker and others, 2008; Tepp and others, 2019a). Nine of those volcanoes were considered by the National Volcanic Threat Assessment (Ewert and others, 2018) to have a combination of eruptive type and summit depth that poses a higher risk of hazardous eruptions, although only one was listed as a moderate (level 3) threat. Other notable submarine volcanoes of interest to the United States that have historically erupted are Axial Seamount off the Washington State coast, Kamaʻehuakanaloa in Hawaiʻi, and Vailuluʻu seamount in American Samoa. All of these, however, have a low risk of hazards because of their depth (greater than 600 meters below sea level) and eruptive type and so are not included in the National Volcanic Threat Assessment. In addition to submarine volcanoes, the submerged flanks of island volcanoes can also be a source of hazardous submarine eruptions—for example, the 1877 eruption of Mauna Loa, Hawai‘i, in Kealakekua Bay (Wanless and others, 2006). The most notable submarine eruption in recent times was the 2022 eruption of Hunga Tonga–Hunga Haʻapai in Tonga, which was one of the largest eruptions on Earth in the past 100 years. It created a massive volcanic plume, unprecedented shock waves, and far-reaching tsunami (Lynett and others, 2022). Other recent submarine eruptions in the Pacific Ocean Basin have produced subaerial plumes that reached aircraft heights (Carey and others, 2014) and large pumice rafts that can affect marine traffic and harbors (for example, Jutzeler and others, 2014; Kornei, 2019). These examples illustrate the potential hazards of major submarine eruptions. Yet, submarine volcanoes are largely unmonitored, and many eruptions occur that are unnoticed or only identified hours or days afterward. Within U.S. territory, submarine volcanoes in the Northern Mariana Islands have been known to produce eruptive activity that can affect society. Reports from fishermen and other marine vessels in the Northern Mariana Islands have noted underwater explosions, sea-surface discoloration, and bubbling water, all of which are known to be signs of submarine volcanic activity. South Sarigan seamount, located about 160 kilometers (km) north of Saipan, erupted in 2010 from greater than 150 meters below the sea surface, resulting in a gas and ash plume that reached more than 11.9 km into the atmosphere (for example, Searcy, 2013; Embley and others, 2014), high enough to affect international air traffic. Precursory and co-eruptive seismicity was detected on the regional Northern Mariana Islands seismic network (Searcy, 2013) and on global monitoring instruments (Green and others, 2013). Monitoring of submarine volcanoes is best accomplished with marine-based instrumentation, which is also useful for monitoring small island volcanoes that may not have the land area necessary for comprehensive subaerial monitoring. The primary marine-based instrumentation used for submarine volcanoes includes ocean-bottom pressure sensors to assess sea-floor deformation, ocean-bottom seismometers (OBSs) to detect seismicity, and both moored and ocean-bottom hydrophones to detect submarine explosions. Other sensors offer important monitoring data, such as turbidity, temperature, and chemistry of hydrothermal emissions. Marine-based instruments are typically deployed in campaign-style networks with no real-time telemetry owing to cost considerations and technical limitations. However, when necessary, marine instruments can be operated in real time using cables to transmit data to land-based facilities; other technologies for this purpose are in use or in development, such as acoustic transmission from the instrument to a moored buoy (Matsumoto and others, 2016) and a winch-based system with a satellite antenna that is part of the instrument mooring (Matsumoto and others, 2019). Emerging technologies for marine-based monitoring may be considered as part of a future monitoring plan. These technologies include ocean gliders and floats with on-board hydrophones that have been used to record earthquakes and submarine eruptions (for example, Matsumoto and others, 2013; Sukhovich and others, 2015) and fiber-optic cables that have been used as strainmeters to detect earthquakes (for example, Marra and others, 2018; Lindsey and others, 2019). Land-based instruments and satellites can also provide some capability for monitoring submarine volcanoes, but they provide more limited observations than marine-based instrumentation.

Scientific Investigations Report

Volcanic gas monitoring

Introduction As magma rises through the crust, decreasing pressure conditions allow volatiles to exsolve from the magma. These volatiles then migrate upward through the crust, where they can be stored at shallower levels or escape to the atmosphere. Rising magma also heats rock masses beneath volcanic centers, causing water in shallow aquifers and hydrothermal systems to boil and release additional gases and steam (see chapter F , this volume; Ingebritsen and Hurwitz, 2024). The chemistry and quantity of gases that reach the surface during periods of quiescence or volcanic unrest can reveal that gas-rich magma is ascending, crystallizing, or alternatively stalling, with important implications for volcanic hazard (for example, Sutton and others, 1992; Aiuppa and others, 2007, 2021; Werner and others, 2009, 2011, 2012; Moretti and others, 2013; de Moor and others, 2016; Lewicki and others, 2019; Edmonds and others, 2022; Kern and others, 2022; Kunrat and others, 2022). Most volcanoes in Alaska and the western United States are characterized by weak degassing, with one or more low-temperature fumaroles (typically near the local boiling temperature of water) and connect to a deeper and sometimes extensive hydrothermal system (for example, McGee and others, 2001; Symonds and others, 2003a, b). Hydrothermal systems will affect the chemistry of rising gases exsolved from deeper magma (Symonds and others, 2001), including sulfur dioxide (SO 2 ), hydrogen chloride (HCl), and water vapor (for example, Doukas and Gerlach, 1995; Gerlach and others, 1998, 2008; Symonds and others, 2001; Werner and others, 2013). As an example, depending on factors such as temperature, pressure, and oxidation state, rising SO 2 will react with groundwater to form hydrogen sulfide (H 2 S) gas, dissolved sulfate (SO 4 2− ), or elemental sulfur (Christenson, 2000; Symonds and others, 2001; Werner and others, 2008). The reaction and dissolution of SO 2 into shallow groundwater is commonly referred to as scrubbing, and can reduce the likelihood that ascending, degassing magma can be detected. Carbon dioxide, however, in addition to exsolving from magma early in the ascent process, is not easily removed by hydrothermal fluids (Lowenstern, 2001). As scrubbing and other processes take place, the SO 2 /H 2 S, CO 2 /SO 2 , and CO 2 /H 2 S ratios may change. High rates of SO 2 emission indicate that magma has moved to relatively shallow levels in the volcano and that the system has heated up enough to establish dry pathways from depth to the surface. Monitoring multiple gas species and the total output of those species is thereby useful for volcano monitoring during both periods of quiescence, to establish background degassing conditions, and during unrest, when gas geochemistry and emission rates can provide information on changing conditions, such as magma ascent. To provide context for multidisciplinary volcano forecasts, we focus on the following two key required capabilities: (1) characterizing baseline geochemistry and gas discharge from volcanoes and volcanic regions and (2) monitoring changes in gas geochemistry and discharge to inform forecasts of volcanic eruptions and their effects. Sufficient baseline data must be collected to identify and interpret anomalous degassing associated with volcanic unrest (for example, Sorey and others, 1998; Rouwet and others, 2014). Differences in volcano type, baseline degassing rates, local hydrology, and geography (for example, high versus low latitude) will result in a different baseline for each volcano. Volcanoes of any threat level that exhibit one or more degassing phenomena would ideally be monitored by techniques needed to establish baseline degassing data, with the sampling frequency of baseline data dictated by the threat level (table E1). Additional monitoring techniques become necessary during periods of unrest. In general, three of the most important techniques for gas monitoring are (1) direct sampling of fumarole, spring, and soil gases for laboratory geochemical measurements, (2) measurements of the chemical composition of the volcanic plume and emission rates of major gas species (for example, H 2 O, CO 2 , SO 2 , and H 2 S) by satellite, airborne, or ground-based techniques, and (3) measurements of diffuse emissions of CO 2 and other gases through soils. Various methods and instruments may be useful both for baseline studies and during unrest.

Scientific Investigations Report