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Geologic framework, age, and lithologic characteristics of the North Park Formation in North Park, north-central Colorado

Deposits of the North Park Formation of late Oligocene and Miocene age are locally exposed at small, widely spaced outcrops along the margins of the roughly northwest-trending North Park syncline in the southern part of North Park, a large intermontane topographic basin in Jackson County in north-central Colorado. These outcrops suggest that rocks and sediments of the North Park Formation consist chiefly of poorly consolidated sand, weakly cemented sandstone, and pebbly sandstone; subordinate amounts of pebble conglomerate; minor amounts of cobbly pebble gravel, siltstone, and sandy limestone; and rare beds of cobble conglomerate and altered tuff. These deposits partly filled North Park as well as a few small nearby valleys and half grabens. In North Park, deposits of the North Park Formation probably once formed a broad and relatively thick sedimentary apron composed chiefly of alluvial slope deposits (mostly sheetwash and stream-channel alluvium) that extended, over a distance of at least 150 kilometers (km), northwestward from the Never Summer Mountains and northward from the Rabbit Ears Range across North Park and extended farther northwestward into the valley of the North Platte River slightly north of the Colorado-Wyoming border. The maximum preserved thickness of the formation in North Park is about 550 meters near the southeastern end of the North Park syncline. The deposition of the North Park Formation was coeval in part with local volcanism, extensional faulting, development of half grabens, and deposition of the Browns Park Formation and Troublesome Formation and was accompanied by post-Laramide regional epeirogenic uplift. Regional deposition of extensive eolian sand sheets and loess deposits, coeval with the deposition of the North Park Formation, suggests that semiarid climatic conditions prevailed during the deposition of the North Park Formation during the late Oligocene and Miocene. The North Park Formation locally contains a 28.1-mega-annum (Ma, million years ago) ash-flow tuff near its base at Owl Ridge and is interbedded with 29-Ma rhyodacite lava flows and volcanic breccia at Owl Mountain. The formation locally contains vertebrate fossils at least as young as Barstovian age (about 15.9–12.6 Ma) and overlies rocks as young as the White River Formation, which contains vertebrate fossils of Chadronian age (about 37–33.8 Ma) in North Park and a bed of 36.0-Ma volcanic ash in the upper part of the Laramie River valley about 30 km northeast of Walden, Colorado. Based on the ages of the vertebrate fossils, folding of the rocks and sediments in the North Park syncline may be much younger than about 16 Ma. Bedding characteristics of the North Park Formation suggest that (1) some or much of the sand, sandstone, and pebbly sandstone may have been deposited as sheetwash alluvium; (2) much of the siltstone may have been deposited as sheetwash alluvium or ephemeral pond or marsh deposits; (3) beds of sandy limestone probably were deposited as ephemeral pond or marsh deposits; and (4) altered tuff probably was deposited in ephemeral ponds or marshes. Most of the conglomerate and gravel in the North Park Formation are stream-channel deposits that were deposited by high-energy ephemeral or intermittent streams that issued from volcanic terrain rather than debris-flow deposits in relatively near-source fan deposits dominated by sediment gravity flow. Laccolithic doming, uplift, and tilting in the Never Summer Mountains near the Mount Richthofen stock, as well as the formation of volcanic edifices in the Never Summer Mountains and the Rabbit Ears Range during the late Oligocene and Miocene, significantly steepened stream gradients and greatly increased the erosive power and transport capacity of streams that transported large rock fragments and finer sediment eroded from volcanic and sedimentary sources and deposited them in the North Park Formation. Much of the material that makes up the rocks and sediments of the North Park Formation was derived from the erosion of volcanic, intrusive, and sedimentary rocks. Clasts in the North Park Formation were derived chiefly from the erosion of volcanic and intrusive igneous rocks of late Oligocene and Miocene age that range in composition from rhyolite to trachybasalt. These rocks are locally exposed along the west flank of the Never Summer Mountains, the north flank of the Rabbit Ears Range, and the east flank of the Park Range at and near Rabbit Ears Peak. The minor amount of igneous and metamorphic clasts of Proterozoic age in the North Park Formation are commonly composed of durable rock types that are resistant to both physical and chemical weathering. Many of these clasts may have been derived from the erosion of conglomerate and conglomeratic sandstone in the Coalmont Formation rather than from basement rocks currently at or near the ground surface in the Never Summer Mountains. Much of the sand and finer grained particles in the North Park Formation probably were derived from the erosion of sandstone, shale, and sandy claystone of the Coalmont Formation. Likewise, much of the abundant sand-sized quartz and feldspar in sand, sandstone, and pebbly sandstone of the North Park Formation probably was derived from the erosion of sandstone, conglomeratic sandstone, and conglomerate of the Coalmont Formation. Some of the fine sand, very fine sand, and silt in very fine grained sandstone and siltstone of the North Park Formation may be derived from the erosion of coeval eolian sand and loess in the Browns Park Formation that was transported across the Park Range by westerly or southwesterly winds.

Colorado↗

Field-trip guide to Columbia River flood basalts, associated rhyolites, and diverse post-plume volcanism in eastern Oregon

The Miocene Columbia River Basalt Group (CRBG) is the youngest and best preserved continental flood basalt province on Earth, linked in space and time with a compositionally diverse succession of volcanic rocks that partially record the apparent emergence and passage of the Yellowstone plume head through eastern Oregon during the late Cenozoic. This compositionally diverse suite of volcanic rocks are considered part of the La Grande - Owyhee eruptive axis (LOEA), an approximately 300-kilometer-long (185 mile), north - northwest - trending, middle Miocene to Pliocene volcanic belt located along the eastern margin of the Columbia River flood basalt province. Volcanic rocks erupted from and preserved within the LOEA form an important regional stratigraphic link between the (1) flood basalt - dominated Columbia Plateau on the north, (2) bimodal basalt - rhyolite vent complexes of the Owyhee Plateau on the south, (3) bimodal basalt-rhyolite and time-transgressive rhyolitic volcanic fields of the Snake River Plain - Yellowstone Plateau, and (4) the High Lava Plains of central Oregon. This field-trip guide describes a 4 - day geologic excursion that will explore the stratigraphic and geochemical relationships among mafic rocks of the Columbia River Basalt Group and coeval and compositionally diverse volcanic rocks associated with the early “Yellowstone track” and High Lava Plains in eastern Oregon. Beginning in Portland, the Day 1 log traverses the Columbia River gorge eastward to Baker City, focusing on prominent outcrops that reveal a distal succession of laterally extensive, large-volume tholeiitic flood lavas of the Grande Ronde, Wanapum, and Saddle Mountains Basalt formations of the CRBG. These “great flows” are typical of the well-studied flood basalt-dominated Columbia Plateau, where interbedded silicic and calc-alkaline lavas are conspicuously absent. The latter part of Day 1 will highlight exposures of middle to late Miocene silicic ash-flow tuffs, rhyolite domes, and calc-alkaline lava flows overlying the CRBG across the northern and central parts of the LOEA. The Day 2 field route migrates to southern parts of the LOEA, where rocks of the CRBG are associated in space and time with lesser known and more complex silicic volcanic stratigraphy associated with middle Miocene, large-volume, bimodal basalt-rhyolite vent complexes. Key stops will provide a broad overview of the structure and stratigraphy of the middle Miocene Mahogany Mountain caldera and middle to late Miocene calc-alkaline lavas of the Owyhee basalt. Stops on Day 3 will progress westward from the eastern margin of the LOEA, examining a transition linking the Columbia River Basalt-Yellowstone province with a northwestward-younging magmatic trend of silicic volcanism that underlies the High Lava Plains of eastern Oregon. Initial field stops on Day 3 will examine key outcrops demonstrating the intercalated nature of middle Miocene tholeiitic CRBG flood basalts, prominent ash-flow tuffs, and “Snake River-type” large-volume rhyolite lava flows exposed along the Malheur River. Subsequent stops on Day 3 will focus upon the volcanic stratigraphy northeast of the town of Burns, which includes regional middle to late Miocene ash-flow tuffs, and lava flows assigned to the Strawberry Volcanics. The return route to Portland on Day 4 traverses across the western axis of the Blue Mountains, highlighting exposures of the widespread, middle Miocene Dinner Creek Tuff and aspects of Picture Gorge Basalt flows and northwest-trending feeder dikes situated in the central part of the CRBG province.

Oregon↗

Paleoliquefaction field reconnaissance in eastern North Carolina—Is there evidence for large magnitude earthquakes between the central Virginia seismic zone and Charleston seismic zone?

In June 2016, approximately 64 kilometers (km) of riverbank were examined along the Tar and Neuse Rivers near Tarboro and Kinston, North Carolina, for evidence of liquefaction-forming earthquakes. The study area is in the vicinity of the Grainger’s fault zone in eastern North Carolina. The Grainger’s fault zone is a fault zone in the inner Coastal Plain Province that has well-documented Paleogene and younger deformation of Cretaceous to Eocene strata. Low-magnitude earthquakes near the fault zone (for example, magnitude [M] 2.1 in 2013, 13 km south-southwest of Kinston) suggest larger earthquakes may have struck this region in the past. The study area is about equidistant from newly documented Holocene paleoliquefaction sites in the Central Virginia Seismic Zone (CVSZ) and liquefaction sites formed during the 1886 M7.1 Charleston, South Carolina earthquake. The northernmost Holocene paleoliquefaction features associated with the Charleston Seismic Zone (CSZ) are in Southport, North Carolina. Conditions suitable for liquefaction were identified at 38 sites on both rivers, but only one site was classified as highly susceptible. Stratigraphy consists of Paleozoic gneiss; Cretaceous sandstone/shale; Paleocene mudstone/claystone to Eocene fossiliferous limestone; Quaternary unconsolidated, crossbedded sand and gravel; and Holocene alluvium. Three sets of stratigraphic conditions suitable for liquefaction—unconsolidated source sand beneath capping strata—were identified in detailed examinations at 105 sites: (1) Holocene alluvial sand beneath alluvial silt and clay beds; (2) Quaternary terrace sand beneath beds of silt and clay; and (3) Holocene alluvial sand or Quaternary terrace sand capped by clay-rich Bt soil horizons. Weathered and unconsolidated Cretaceous sand capped by a Bt soil horizon was identified at one site, but the weathered sand is likely too compacted to liquefy readily. One outcrop containing three small sand dikes, and four outcrops of soft-sediment deformation features—mostly load casts—were observed, but none of these features could be conclusively established as seismogenic. A few examples of pseudo-sand-dikes were also identified: sand-filled cypress root casts and pedogenic weathering fronts created the appearance of sand dikes and sills. A comparable survey in 2015 of 119 km of riverbank exposures in the CVSZ yielded 19 paleoliquefaction sites of probable earthquake origin; these features formed from at least one M~6 earthquake in the past 6,000 years (6 ka). This survey in eastern North Carolina revealed no definitive paleoliquefaction features; earthquakes of sufficient magnitude to produce liquefaction likely have not affected this region during the Holocene.

North Carolina↗

Evaluation of groundwater resources in the Spanish Valley Watershed, Grand and San Juan Counties, Utah

Groundwater resources in the Spanish Valley watershed in southern Utah were quantified for the first time since the early 1970s. The primary objectives of this study were (1) to better understand sources of recharge to, groundwater flow directions within, and discharge points for both the valley-fill and Glen Canyon Group aquifers (VFA and GCGA), and (2) to quantify groundwater budget components of the combined VFA and GCGA, including both recharge and discharge. Based on both groundwater chemistry (stable isotopes, major ions, and noble gases) and environmental tracers in vadose-zone pore water of the Navajo Sandstone outcrop along Sand Flats Road, most recharge to the GCGA occurs high in the La Sal Mountains, and not on the sandstone outcrop area. The same groundwater chemistry and environmental tracer evidence from the saturated zone indicates that Pack Creek, rather than GCGA groundwater, is the primary source of recharge to the VFA. Groundwater recharge in the study area occurs mostly from infiltration of precipitation (in the form of snowmelt) at high altitudes. Additional recharge occurs from the infiltration of runoff along losing reaches of stream channels, or as unconsumed surface-water and groundwater irrigation. Average annual recharge to the Moab-Spanish Valley watershed part of the Spanish Valley study area was estimated to be between 9,550 and 30,000 acre-feet. Based on water-levels collected in the current study, groundwater in both the GCGA and the VFA generally moves downgradient parallel to the topographic slope of the watershed towards the Colorado River. Groundwater discharge measurements, and hydraulic-flux estimates at the lower end of Spanish Valley, provide a more robust estimate of the groundwater budget than evaluating recharge. The primary base-flow discharge components in the study area include groundwater discharge to gaining reaches of streams, groundwater discharge to springs, and well withdrawals. Based on 3 years of measurements (2014–16) and hydraulic-flux calculations at the lower end of Spanish Valley, total groundwater discharge was estimated to be 14,000 to 16,000 acre-feet per year (acre-ft/yr) for the entire watershed, or 13,000 to 15,000 acre-ft/yr, excluding the watershed areas of Grandstaff (formerly Negro Bill) and Ice Box Canyons (compared to the 1971 Sumsion estimate of 22,000 acre-ft/yr). The primary difference is this study’s estimate of subsurface outflow to the Colorado River of only 300 to 1,000 acre-ft/yr, compared to 11,000 acre-ft/yr estimated by Sumsion. Because the study period (2014–16) experienced above average precipitation for 2 of the 3 years, the discharge estimates may be slightly higher than long-term average annual discharge from the groundwater system.

Utah↗

Sediment classification and the characterization, identification, and mapping of geologic substrates for the glaciated Gulf of Maine seabed and other terrains, providing a physical framework for ecological research and seabed management

A geologic substrate is a surface (or volume) of sediment or rock where physical, chemical, and biological processes occur, such as the movement and deposition of sediment, the formation of bedforms, and the attachment, burrowing, feeding, reproduction, and sheltering of organisms. Seabed mapping surveys in the Stellwagen Bank region off Boston, Massachusetts, from 1993 to 2004 have led to the development of a methodology for characterizing, identifying, and mapping geologic substrates. The resulting high-resolution interpretive maps (1:25,000) show the distribution of substrates in a glaciated terrain of banks and basins in water depths of 30 to 185 meters. Data sources used to characterize substrates are multibeam sonar bathymetric and backscatter imagery to document seabed topography and patterns of sediment and rock distribution, grain-size analyses of sediment samples to determine substrate composition, and video and photographic imagery of the seabed to aid in the interpretation of multibeam sonar imagery and to provide information on substrate layering and mobility, seabed structures, and sediments and nonsediment materials that cannot be physically sampled. Sediment composition is a major property of many seabed substrates. Sediment grains belong to a continuum of grain-diameter sizes previously classified into grades (for example, fine sand, medium sand) and into aggregates (mud, sand, gravel). The definition of grade and aggregate boundaries in a classification is arbitrary, and a useful classification is limited to as few classes as are needed to effectively organize and apply information. For the purpose of mapping substrates, sediment grades and aggregates were simplified and re-classified into eight composite grades based on grain-size content, mode of transport, and ecological role. Five composite grades are identified using grain-size analysis and three are identified using video and photographic imagery of the seabed. Naturally occurring sediments contain various amounts of the aggregates mud, sand, and gravel. The separation of naturally occurring sediments into sediment classes, based on grain-size analysis, requires that limits be set on the amount of mud, sand, and gravel each class contains. Fifteen previously identified basic sediment classes provided interpretive information on sediment transport by emphasizing gravel content (a low 0.01-weight-percent threshold) and on winnowing processes based on the sand-to-mud ratio. The present study recognizes 20 basic sediment classes that are combinations of aggregates in which the lower limits for recognition of mud and sand are 10 weight percent and of gravel, 25 weight percent. These sediment classes can be made more specific by listing their content of the composite grades fine-grained sand (3 and 4 phi), which is transported in suspension, and coarse-grained sand (0, 1, and 2 phi), which is transported as bedload. Additional sediment classes and nonsediment classes that cannot be sampled are recognized on the basis of visual analysis of seabed video and photographic imagery and include pebble, cobble, and boulder gravel, rock outcrops, and shell beds, among others. Substrates are not classified because their properties are too varied for a classification to be concise and useful. Rather, substrates are characterized and identified by sediment grain-size composition (the sediment class); the distribution, in millimeters, of grain diameters in the sediment; the presence of nonsediments (for example, rock outcrops); substrate mobility based on the presence of sediment ripples; substrate layering (for example, a partial veneer of sand on gravel); and seabed structures. These properties have interpretive value by providing information about sedimentary processes acting on a substrate and about its ecological function. A geologic substrate, when it is associated with one or more species, is an important element of a habitat. This methodology was developed to map a glaciated terrain characterized by geologic substrates that typify a wide range of erosional and depositional sedimentary environments, and it likely will be useful for mapping substrates in other terrains. Substrate maps provide the physical framework required for identifying sediment transport processes, validating sediment transport models, studying the ecology of species and communities, and managing marine resources and seabed usage.

Massachusetts↗

Hydrogeology and shallow groundwater quality in the tidal Anacostia River watershed, Washington, D.C.

Groundwater hydrology and geochemistry within the tidal Anacostia River watershed of Washington, D.C. are related to natural and human influences. The U.S. Geological Survey, in cooperation with the District Department of Energy & Environment, began investigating the hydrogeology and groundwater quality of the watershed in 2002. Lithologic coring, groundwater-level and tidal monitoring, and water-quality sampling have been conducted to improve understanding of the groundwater-flow system, geochemistry, water quality, and the likely interaction between groundwater and the tidal Anacostia River. The flow and interaction of shallow groundwater with the tidal Anacostia River and other area streams are affected by diversions, pumping, land reclamation, and other human activities in this highly urbanized watershed. The tidal Anacostia River watershed is underlain by a wedge of unconsolidated sediments that is part of the Atlantic Coastal Plain Physiographic Province. These sediments form a system of confined and unconfined aquifers. The coarse sediments of the Potomac Group sand-dominated lithofacies form the Patuxent aquifer. The Patuxent aquifer crops out and subcrops in the northwestern part of the study area, but is confined to the southeast by the overlying Potomac Group clay-dominated lithofacies. Overlying the Potomac Group is a series of interbedded sands and clays that form an unconfined surficial aquifer system. Regional correlation in the unconfined surficial aquifer system is complicated by local heterogeneity in aquifer sediments. Local perched and semi-confined conditions occur in some areas. Recharge of the confined Patuxent aquifer occurs primarily in the outcrop and subcrop area, although some recharge may also occur through overlying confining units. Recharge to the unconfined surficial aquifer system occurs through infiltration of precipitation and possible artificial recharge from structures such as underground water or sewer pipes. In the Patuxent aquifer, hydraulic gradients indicate downward movement in the outcrop area, whereas hydraulic heads beneath the Anacostia River are higher than land surface, indicating an upward hydraulic gradient. In the unconfined surficial aquifer system, groundwater generally flows from upland recharge areas towards discharge areas near the Anacostia River and its tributaries. Groundwater from the confined part of the Patuxent aquifer also may discharge to the Anacostia River in locations where the overlying clay-dominated lithofacies of the Potomac Group is absent as a result of past geologic and (or) alluvial processes. Geochemistry and groundwater quality are affected by hydrologic conditions as well as anthropogenic influences. Local variability in groundwater quality reflects local variability in hydrogeologic conditions and sources of chemicals. Groundwater ranges from anoxic and iron- or calcium-bicarbonate type, to oxic with elevated nitrate. The occurrence and distribution of pesticides, volatile organic compounds, and other selected chemical compounds in groundwater reflect the multitude of sources common to urban areas, as well as variable hydrogeologic and geochemical conditions that affect their fate and transport in the environment. Overall, concentrations of only a few of the over 200 chemical constituents included in laboratory analyses exceeded regulatory standards or guidance values. These include tetrachloroethene and arsenic, which were each detected one time in different wells. There were also several detections of iron and manganese that exceeded regulatory standards or guidance values that are associated with reducing conditions in aquifer sediments.

Washington, D.C.↗

Hydrogeologic characteristics of Hourglass and New Years Cave Lakes at Jewel Cave National Monument, South Dakota, from water-level and water-chemistry data, 2015–21

Jewel Cave National Monument is in the western Black Hills of South Dakota and contains an extensive cave network, including various subterranean water bodies (cave lakes) that are believed to represent the regionally important Madison aquifer. Recent investigations have sought to improve understanding of hydrogeologic characteristics of cave lakes in Jewel Cave. The U.S. Geological Survey, in cooperation with the National Park Service, collected water-level and water-chemistry data within and near Jewel Cave to better understand groundwater interactions in Jewel Cave and to evaluate recharge characteristics of cave lakes. Continuous water-level data were collected at two cave lakes (Hourglass and New Years Lakes) from 2018 to 2021, and discrete measurements were collected by National Park Service staff from 2015 to 2021. Water samples were collected from one stream, one rain collector, three springs, and two cave lakes. The approach for this study included comparing water-level data collected from two cave lakes to historical climate data and using multivariate statistical analyses to evaluate water samples collected during this study and from previous investigations. This study builds on interpretations from previous investigations that collected similar datasets and performed similar analyses. Hydrographs of Hourglass and News Years Lakes from 2015 to 2021 demonstrated the variability of groundwater levels in Jewel Cave in response to dry and wet climate conditions. Hourglass Lake displayed small (up to 4.8 feet), gradual water-level changes, whereas New Years Lake displayed relatively large (up to at least 27.5 feet) and rapid water-level changes. Hourglass and New Years Lakes are about 0.4 mile apart at the land surface, and the water-level elevation between the lakes varied from 61 to 93.5 feet from 2016 to 2021. The proximity and relatively small elevation difference of Hourglass and New Years Lakes indicated different recharge sources and (or) mechanisms were responsible for hydrograph dissimilarities. Water-level changes at Hourglass Lake were similar to water-level changes at a well completed in the Madison aquifer about 9 miles south of Jewel Cave National Monument, which indicated Hourglass Lake may be recharged similar to the regional Madison aquifer along outcrops north of Jewel Cave. New Years Lake displayed almost no similarities to the well completed in the Madison aquifer—indicating a more direct connection to local recharge rather than solely from outcrops recharging the regional Madison aquifer. Results from multivariate statistical analyses of water-chemistry data were used to evaluate recharge observations from water-level data. The water chemistry of Hourglass Lake indicated its water was chemically more similar to precipitation than other groundwater sites sampled. A conceptual karst recharge model indicated that the dominant recharge source to Hourglass Lake was diffuse allogenic recharge from vertical movement of infiltrated precipitation through vertical or near-vertical fractures that extend through the Minnelusa Formation and unsaturated zone of the Madison Limestone. The water chemistry of New Years Lake was chemically similar to Hell Canyon Creek about 0.2 mile from New Years Lake at the land surface. Streamflow loss zones (concentrated allogenic recharge) along Hell Canyon Creek have not been mapped, but their presence in the Jewel Cave area has been speculated by previous investigations. A fault observed in the cave ceiling above New Years Lake by National Park Service staff could provide a natural conduit for direct recharge from Hell Canyon Creek to New Years Lake if the fault is extensive. Additional water-chemistry and water-level data, as well as streamflow data upstream and downstream of the potential streamflow loss zone along Hell Canyon Creek, are needed to prove the presence of this loss zone and discern further correlations between streamflow and water levels in New Years Lake. Observations from previous investigations and this study indicated recharge to Jewel Cave is complex and occurs on various timescales that are affected temporally by precipitation patterns and spatially by hydrologic connection with the overlying Minnelusa aquifer of the Minnelusa Formation.

South Dakota↗

Reconnaissance for radioactive materials in northeastern United States during 1952

Reconnaissance for radioactive materials was made in parts of Maine, New York, New Jersey, and Pennsylvania. The primary objective was to examine the iron ore deposits and associated rocks in the Adirondack Mountains of New York and the Highlands of New Jersey. In addition, several deposits known or reported to contain radioactive minerals were examined to delimit their extent. Most of the deposits examined are not significant as possible sources of radioactive elements and the data pertaining to them are summarized in table form. Deposits that do warrant more description than can be given in table form are: Benson Mines, St. Lawrence County, N. Y.; Rutgers mine, Clinton County, N. Y.; Mineville Mines, Essex County, N. Y.l Canfield phosphate mine, Morris County, N. J.; Mullgan quarry, Hunterdon County, N. J.; and the Chestnut Hill-Marble Mountain area, Pennsylvania and New Jersey. The Old Bed in the Mineville district is the only deposit that may be economically significant. Apatite from Old Bed ore contains as much as 4.9 percent total rare earth. 0.04 percent thorium, and 0.018 percent uranium. Magnetite ore at the Rutgers mine contains radioactive zircon and apatite. Radioactivity measurements of outcrops and dump material show that the ore contains from 0.005 to 0.010 percent equivalent uranium. One sample of lean magnetite ore contains 0.006 percent equivalent uranium. Garnet-rich zones in the Benson Mines magnetite deposit contain as much as 0.017 equivalent uranium. Most of the rock and ore, however, contains about 0.005 percent equivalent uranium. Available data indicate that the garnet-rich zones are enriched in radioactive allanite. A shear zone in the Kittatinny limestone of Cambrian age at the Mulligan quarry contains uraniferous material. Radioactivity anomalies elsewhere in the quarry and in adjacent fields indicate that there may be other uraniferous shear zones. Assays of samples and measurements of outcrop radioactivity indicate that the uranium content of these zones is low; samples contain from 0.008 to 0.068 percent equivalent uranium. The anomalies, however, may indicate greater concentrations of uranium below surficial leached zones. The Chestnut Hill-Marble Mountain area contains radioactivity anomalies for about 2 miles along the strike of the contact of pre-Cambrian Pickering gneiss and Franklin limestone formations. In places this contact is injected with pegmatite, which probably was the source of the radioelements. The most favorable area for further study is at Marble Mountain, where a nearly continuous anomaly extends for about 1500 feet. Samples from part of this area contain as much as 0.044 percent equivalent uranium and 0.005 percent uranium. Radioactive hematite and florencite, in which thorium may have substituted for cerium, are the only radioactive minerals observed in the Marble Mountain area.

New Jersey;New York;Pennsylvania↗

Reconnaissance for uranium in black shale, Northern Rocky Mountains and Great Plains, 1953

Reconnaissance examinations for uranium in 22 formations containing black shale were conducted in parts of Montana, North Dakota, Utah, Idaho, and Oregon during 1953. About 150 samples from 80 outcrop localities and 5 oil and gas wells were submitted for uranium determinations. Most of the black shale deposits examined contain less than 0.003 percent uranium; however, thin beds of black shale at the base of the Mississippian system contain 0.005 percent uranium at 2 outcrop localities in southwestern Montana and as much as 0.007 percent uranium in a well in northeastern Montana. An eight-foot bed of phosphatic black shale at the base of the Brazer limestone of Late Mississippian age in Rich County, Utah, contains as much as 0.009 percent uranium. Commercial gamma ray logs of oil and gas wells drilled in Montana and adjacent parts of the Dakotas indicate that locally the Heath shale of Late Mississippian age contains as much as 0.01 percent equivalent uranium, and black shales of Late Cretaceous age contain as much as 0.008 percent equivalent uranium.

Idaho;Montana;North Dakota;Oregon;Utah↗

Chatanooga shale investigations along the Sequatchie anticline of Tennessee and Alabama

In 1953 the Chattanooga shale in the Sequatchie anticline was tested for its uranium content by seven diamond drill cores. Concurrent with the drilling, geologic field work was done to determine the distribution, thickness, and structural setting of the shale. The results of this investigation indicate that the Chattanooga shale in the Sequatchie Valley has a higher uranium content than the shale along the Eastern Highland Rim but is more folded and faulted. For the purposes of these investigations the anticline is roughly divisible into three subequal parts, designated as northern, central, and southern. In the northern part the Gassaway member of the Chattanoooga shale is 13 to 21 feet thick and probably contains from 0.0060 to 0.0076 percent uranium. An unusual thickness of the phosphatic interval in one core suggests some duplication of strata. Similar deformation could cause erratic distirbution of the more uraniferous beds. In the central part of the anticline the Dowelltown member of the shale is overlapped by the Gassaway member so that only the latter is present in the central and southern parts of the anticline. The Gassaway is thin and poorly exposed between the State line and Guntersville, Ala., but southward it thickens again to about 40 feet near Blountsville. In the southern part the uranium content of the shale, as determined from three drill cores, is surprisingly low when compared with analyses of 1952 outcrop samples from three sides of the area. On the basis of available data, 20 feet of shale in the area between hole AL-66, 3 miles southwest of Blountsville, and locality 4G-1 at Blount Springs may contain between 0.0057 and 0.0070 percent uranium, but more drilling would have to be done to check the higher figure, which is based on outcrop samples. Data are too sparse to permit reliable estimates of grade and tonnage. More geologic work and drilling are needed to block out the most favorable areas.

Alabama;Georgia;Tennessee↗

Radioactivity and uranium content of the Sharon Springs member of the Pierre shale and associated rocks in western Kansas and eastern Colorado

As a part of the Geological Survey's program of investigating uranium-bearing carbonaceous rocks on behalf of the Division of Raw Materials of the U.S. Atomic Energy Commission, a reconnaissance of the Sharon Springs member of the Pierre shale in western Kansas and eastern Colorado was conducted during 1954. The Sharon Springs member of the Pierre shale and its lateral equivalents ranges from 155 to about 500 feet in thickness and generally contains about 0.001 percent uranium, but some beds contain larger amounts. A 6-foot thick shale bed in Cheyenne County, Colo., contains about 0.006 percent uranium, a 4 1/2-foot thick sequence of beds in Crowley County, Colo., is estimated to contain between 0.004 and 0.005 percent uranium, and a 3 1/2-foot thick sequence of beds in Kiowa County, Colo., contains about 0.004 percent uranium. At several outcrop localities, sequences of beds as much as 9 1/2 feet thick contain about 0.003 percent uranium. Data from wells indicate that the 4 1/2-foot thick sequence of beds in Crowley County, Colo., may have a lateral extent of at least 5 1/2 miles. A gamma-ray log of a well in Yuma County, Colo., indicates the presence of a sequence of beds 66 feet thick which contains 0.005 to 0.010 percent equivalent uranium. No definite pattern of areal distribution of radioactivity and uranium content in the Sharon Springs is indicated by available data. Lateral variation in uranium content of individual beds was not noted in outcrops, which seldom extend more than 150 feet, but subsurface data from gamma-ray logs of wells indicate that both the maximum radioactivity and the thickness of radioactive beds are variable within distances of a few miles. Vertical variation in radioactivity and uranium content of the more radioactive beds is usually abrupt, but in the rocks as a whole the range of uranium content is so small that large variations in content are absent. In most of the gamma-ray logs examined there is only part of the sequence of rocks comprising the Pierre shale and Niobrara formation that exhibits radioactivity in excess of the average radioactivity of the two formations. Comparison of features of gamma-ray logs of wells in north-eastern Colorado suggests that the most radioactive part referred to above is a laterally correlatable sequence of beds. The stratigraphic position of the radioactive unit relative to the Pierre shale-Niobrara formation contact in oil industry scout reports, as identified from electric logs and wells, is variable within short distances. This may indicate that some of the Pierre-Niobrara contacts picked from electric logs may not correspond to the boundary that would be selected by examination of the rocks themselves, or may indicate that there is a facies relationship between teh lowermost part of the Pierre shale and the uppermost part of the Niobrara formation.

Colorado;Kansas↗

Uranium content and leachability of some igneous rocks and their geochemical significance

The uranium content and its leachability in 442 igneous rocks if wide variety were measured. Four-gram samples, crushed below 38 mesh, were leached in in 0.05 M HNO 3 for half an hour at 80 to 85° C; the leachate and undissolved residue were analyzed fluorimetrically. This study explored the relation of uranium content and leachability to petrography. With few exceptions, the relations between uranium content, uranium leachability, rock leachability, rock type, and mineral composition seem to be random. Uranium content and leachability in homogeneous outcrops vary erratically, in heterogeneous outcrops the variation appears nonsystematic. Correlations with geologic environment indicate that uranium content and leachability are largely controlled by geologic processes during and after crystallization.

Trace Elements Investigations↗

Reconnaissance of radioactive rocks of Maine

The state of Maine was traversed with car-mounted Geiger-Mueller equipment in the late summer of 1948 and the radioactivity of approximately 4,600 miles of road was logged. All samples were analyzed, both in the field by comparing the radioactivity of each sample to the radioactivity of a stranded measured with a simple scaling modification of a portable counter, and in the Geological Survey’s Trace Elements Section Washington Laboratory. Differences between both types of analyses were negligible. The maximum equivalent uranium content of the most radioactive rocks thus analyzed was 0.008 percent. A 1,400-square-mile abnormally radioactive province in southwestern Maine was outlined. The outcrop data obtained from car traversing are evaluated statistically. Cumulative frequency distribution curves are drawn to show the distribution of outcrops at various levels of radioactivity, and straight-line extensions are made to show to maximum probable grade for various rock types and areas in Maine. A maximum grade of 0.055 percent equivalent uranium is thus predicted for the entire state. This prediction necessarily is a broad generalization because large areas of Main are inaccessible for car traversing. A concept of evaluation of an area for possible mineral deposits is proposed on the basis of lithology, and observed and indicated ranges in grade.

Maine↗

Potentiometric surfaces of aquifers in the Cockfield Formation in southeastern Arkansas and the Wilcox Group in southern and northeastern Arkansas, 2000

The Cockfield and lower Wilcox aquifers are sources of water for local use in southern and northeastern Arkansas, where in 1995 more than 51 million gallons per day of water was withdrawn. During January through April 2000, 54 water-level measurements were made in wells completed in the Cockfield aquifer, 13 water-level measurements were made in wells completed in the lower Wilcox aquifer in southern Arkansas, and 43 water-level measurements were made in wells completed in the lower Wilcox aquifer in northeastern Arkansas. The potentiometric surface data reveal spatial trends in both aquifers across the study areas. The regional direction of ground-water flow of the Cockfield aquifer is generally toward the east and south, away from the outcrop area, except in areas of intense ground-water withdrawals. The configuration of the potentiometric surface indicates that heavy pumpage has probably altered or reversed the natural direction of flow in these areas. A potentiometric low caused by the pumpage near Greenville, Mississippi, extends into Chicot, Desha, and Drew Counties. Water levels in five wells showed average declines between 0.5 and 0.8 foot per year. The regional direction of ground-water flow in the lower Wilcox aquifers is generally east and south, away from the outcrop, except in areas of intense ground-water withdrawals. Potentiometric depressions, where flow is toward centers of pumping, indicate that heavy pumpage has probably altered or reversed the natural direction of flow. Two potentiometric depressions are centered in the vicinity of Paragould and West Memphis, Arkansas, where ground-water withdrawals probably have altered the natural direction of flow. Long-term hydrographs of seven wells show water-level declines in the lower Wilcox aquifer in northeastern Arkansas. The average water-level decline in two wells was between 0.8 and 1.0 foot per year and in five wells was between 1.2 and 1.8 foot per year.

Arkansas↗

Seepage investigation for Leap, South Ash, Wet Sandy, and Leeds creeks in the Pine Valley Mountains, Washington County, Utah, 1998

Seepage loss-gain data were collected along four creeks (Leap, South Ash, Wet Sandy, and Leeds) that drain the eastern flank of the Pine Valley Mountains in southwestern Utah. Streamflow was measured at a minimum of eight sites on each of the four creeks during each of three (four on South Ash) seepage investigations at higher streamflows in May and June, and at lower streamflows during August, October, and November 1998. Only two reaches on Leap and Leeds Creeks showed a significant reversal of loss or gain trends between high and low streamflow where the difference in streamflow exceeded the measurement error. Error analyses were computed both for individual reaches between consecutive measurement sites and for composite reaches between specified, nonconsecutive measurement sites to determine if seepage losses or gains exceed the error associated with measurement of streamflow. Computed losses or gains at 31 individual reaches exceed the normalized measurement error; 16 were along channel reaches that traverse unconsolidated deposits, 7 were associated with reaches that traverse sedimentary rocks other than Navajo Sandstone, 6 were associated with reaches that traverse the Navajo Sandstone, and 2 were associated with reaches that traverse rocks of igneous origin. Composite reaches that encompass the outcrop of one of four hydrogeologic units (Navajo Sandstone, unconsolidated deposits, igneous rocks, or sedimentary rocks other than Navajo Sandstone) were used to compute the loss or gain based on the amount measured at the upstream and downstream nonconsecutive sites. For composite reaches that traverse outcrops of Navajo Sandstone, less water was measured at (or near) the downstream contact than at (or near) the upstream contact for 11 of the 13 seepage investigations. Of those 11 investigations with computed losses, the normalized difference (N d) was greater than the normalized error (N e ) for 6 investigations and confirms that a source of recharge to the Navajo Sandstone is seepage loss from the measured streams.

Utah↗

Hydrogeology and simulation of ground-water flow and land-surface subsidence in the Chicot and Evangeline aquifers, Houston area, Texas

In November 1997, the U.S. Geological Survey, in cooperation with the City of Houston Utilities Planning Section and the City of Houston Department of Public Works & Engineering, began an investigation of the Chicot and Evangeline aquifers in the greater Houston area in Texas to better understand the hydrology, flow, and associated land-surface subsidence. The principal part of the investigation was a numerical finite-difference model (MODFLOW) developed to simulate ground-water flow and land-surface subsidence in an 18,100-square-mile area encompassing greater Houston. The focus of the study was Harris and Galveston Counties, but other counties were included to achieve the appropriate boundary conditions. The model was vertically discretized into three 103-row by 109-column layers resulting in a total of 33,681 grid cells. Layer 1 represents the water table using a specified head, layer 2 represents the Chicot aquifer, and layer 3 represents the Evangeline aquifer. Simulations were made under transient conditions for 31 ground-water-withdrawal (stress) periods spanning 1891–1996. The years 1977 and 1996 were chosen as potentiometric-surface calibration periods for the model. Simulated and measured potentiometric surfaces of the Chicot and Evangeline aquifers for 1977 match closely. Waterlevel measurements indicate that by 1977, large ground-water withdrawals in east-central and southeastern areas of Harris County had caused the potentiometric surfaces to decline as much as 250 feet below sea level in the Chicot aquifer and as much as 350 feet below sea level in the Evangeline aquifer. Simulated and measured potentiometric surfaces of the Chicot and Evangeline aquifers for 1996 also match closely. The large potentiometric-surface decline in 1977 in the southeastern Houston area showed significant recovery by 1996. The 1996 centers of potentiometric-surface decline are located much farther northwest. Potentiometric-surface declines of more than 200 feet below sea level in the Chicot aquifer and more than 350 feet below sea level in the Evangeline aquifer were measured in observation wells and simulated in the flow model. Simulation of land-surface subsidence and water released from storage in the clay layers was accomplished using the Interbed-Storage Package of the MODFLOW model. Land-surface subsidence was calibrated by comparing simulated long-term (1891–1995) and short-term (1978–95) land-surface subsidence with published maps of land-surface subsidence for about the same period until acceptable matches were achieved. Simulated 1996 Chicot aquifer flow rates indicate that a net flow of 562.5 cubic feet per second enters the Chicot aquifer in the outcrop area, and a net flow of 459.5 cubic feet per second passes through the Chicot aquifer into the Evangeline aquifer. The remaining 103.0 cubic feet per second of flow is withdrawn as pumpage, with a shortfall of about 84.9 cubic feet per second supplied to the wells from storage in sands and clays. Water simulated from storage in clays in the Chicot aquifer is about 19 percent of the total water withdrawn from the aquifer. Simulated 1996 Evangeline aquifer flow rates indicate that a net flow of 14.8 cubic feet per second enters the Evangeline aquifer in the outcrop area, and a net flow of 459.5 cubic feet per second passes through the Chicot aquifer into the Evangeline aquifer for a total inflow of 474.3 cubic feet per second. A greater amount, 528.6 cubic feet per second, is withdrawn by wells; the shortfall of about 54.8 cubic feet per second is supplied from storage in sands and clays. Water simulated from storage in clays in the Evangeline aquifer is about 10 percent of the total water withdrawn from the aquifer.

Texas↗

Water quality and environmental isotopic analyses of ground-water samples collected from the Wasatch and Fort Union Formations in areas of coalbed methane development — Implications to recharge and ground-water flow, eastern Powder River Basin, Wyoming

Chemical analyses of ground-water samples were evaluated as part of an investigation of lower Tertiary aquifers in the eastern Powder River Basin where coalbed methane is being developed. Ground-water samples were collected from two springs discharging from clinker, eight monitoring wells completed in the Wasatch aquifer, and 13 monitoring or coalbed methane production wells completed in coalbed aquifers. The ground-water samples were analyzed for major ions and environmental isotopes (tritium and stable isotopes of hydrogen and oxygen) to characterize the composition of waters in these aquifers, to relate these characteristics to geochemical processes, and to evaluate recharge and ground-water flow within and between these aquifers. This investigation was conducted in cooperation with the Wyoming State Engineer's Office and the Bureau of Land Management. Water quality in the different aquifers was characterized by major-ion composition. Samples collected from the two springs were classified as calcium-sulfate-type and calcium-bicarbonate-type waters. All ground-water samples from the coalbed aquifers were sodium-bicarbonate-type waters as were five of eight samples collected from the overlying Wasatch aquifer. Potential areal patterns in ionic composition were examined. Ground-water samples collected during this and another investigation suggest that dissolved-solids concentrations in the coalbed aquifers may be lower south of the Belle Fourche River (generally less than 600 milligrams per liter). As ground water in coalbed aquifers flows to the north and northwest away from an inferred source of recharge (clinker in the study area), dissolved-solids concentrations appear to increase. Variation in ionic composition in the vertical dimension was examined qualitatively and statistically within and between aquifers. A relationship between ionic composition and well depth was noted and corroborates similar observations by earlier investigators in the Powder River Basin in both Wyoming and Montana. This relationship results in two different water-quality zones with different characteristics - a shallow zone, comprising the upper part of the Wasatch aquifer, characterized by mixed cation composition and either sulfate or bicarbonate as the dominant anion; and a deeper zone, comprising the lower (deeper) part of the Wasatch aquifer and the underlying coalbed aquifers, characterized by sodium-bicarbonate-type waters. The zonation appears to be related to geochemical processes described by earlier investigators such as dissolution and precipitation of minerals, ion exchange, sulfate reduction, and mixing of waters. Qualitative and statistically significant differences were observed in sulfate concentrations between the coalbed aquifers and the overlying Wasatch aquifer. Ionic composition suggests that bacterially mediated redox processes such as sulfate reduction were probably the dominant geochemical processes in the anaerobic coalbed aquifers. Tritium was used to qualitatively estimate the time of ground-water recharge. Tritium concentrations in both springs suggests that both were recharged after 1952 and contain modern water. Tritium was not detected at concentrations suggestive of modern water in any ground-water samples collected from the coalbed aquifers or in six of eight ground-water samples collected from the overlying Wasatch aquifer. Tritium concentrations in the remaining two wells from the Wasatch aquifer suggest a mixture between submodern (recharged before 1952) and modern water, although the low concentrations suggest that ground water in these two wells have very little modern water. The relative absence of modern water in all aquifers in the study area suggests that recharge processes to these aquifers are probably very slow. Paired d 2 H (deuterium/hydrogen isotopic ratio) and d 18 O (oxygen-18/oxygen-16 isotopic ratio) values for samples collected from the springs and all aquifers are close to the Global Meteoric Water Line, a meteoric water line for North American continental precipitation, and an estimated local meteoric water line, suggesting the water in the aquifers is of meteoric origin. The d 2 H and d 18 O values suggest that the waters were recharged in a colder climate or temperature, mid-latitudes, and mid-continent. In general, the samples do not form separate groups based on aquifer origin; this suggests either intermixing of the waters in the aquifers or that the different aquifers are subject to similar recharge and/or evolutional paths for the water. However, examination of the differences in the values of d 2 H and d 18 O, in combination with major-ion chemistry at three monitoring-well clusters, suggest that changes in the values with depth may represent different timing or sources of recharge to the different aquifers. The areal distribution of d 2 H was examined and an apparent break in the d 2 H along a northwest to southeast trend was observed. In the coalbed aquifers, all but one ground-water sample (collected from the Big George coal bed), show a pattern where the d 2 H values become more negative towards the center of the Powder River Basin and values greater (less negative) than an arbitrary reference value of -140 ‰ (per mil or parts per thousand) were observed near the outcrop area of the Wyodak-Anderson coal zone. In the overlying Wasatch aquifer, the d 2 H values became less negative towards the center of the basin. The values more negative than -140 ‰ are near the outcrop area and the values that are less negative than -140 ‰ are closer to the basin center. It is unclear if this pattern is a result of sample size, different recharge mechanisms, geochemical processes, or if the processes producing these differences are independent or unrecognized. Results of water-quality sampling were compared with selected regulatory and non-regulatory standards as well as commonly-used guidelines for proposed water uses. Dissolved solids was the measure that most frequently exceeded U.S. Environmental Protection Agency public water-supply standards and State of Wyoming domestic-use standards in ground-water samples collected from the Wasatch aquifer and coalbed aquifers. The State of Wyoming agricultural standards (irrigation) for sulfate and dissolved solids were exceeded in some samples collected from the Wasatch aquifer and coalbed aquifers. The State of Wyoming livestock standard for pH was exceeded in some samples collected from the Wasatch aquifer. Water from the Wasatch aquifer ranged from soft to very hard, and water from the coalbed aquifers ranged from moderately hard to very hard. Samples collected from wells completed in both the Wasatch aquifer and coalbed aquifers plotted in a wide range of both sodium- and salinity-hazard classes, but most samples clustered in or near the combined medium-sodium-hazard—high-salinity-hazard classes.

Wyoming↗

Simulation of ground-water/surface-water flow in the Santa Clara-Calleguas ground-water basin, Ventura County, California

Ground water is the main source of water in the Santa Clara-Calleguas ground-water basin that covers about 310 square miles in Ventura County, California. A steady increase in the demand for surface- and ground-water resources since the late 1800s has resulted in streamflow depletion and ground-water overdraft. This steady increase in water use has resulted in seawater intrusion, inter-aquifer flow, land subsidence, and ground-water contamination. The Santa Clara-Calleguas Basin consists of multiple aquifers that are grouped into upper- and lower-aquifer systems. The upper-aquifer system includes the Shallow, Oxnard, and Mugu aquifers. The lower-aquifer system includes the upper and lower Hueneme, Fox Canyon, and Grimes Canyon aquifers. The layered aquifer systems are each bounded below by regional unconformities that are overlain by extensive basal coarse-grained layers that are the major pathways for ground-water production from wells and related seawater intrusion. The aquifer systems are bounded below and along mountain fronts by consolidated bedrock that forms a relatively impermeable boundary to ground-water flow. Numerous faults act as additional exterior and interior boundaries to ground-water flow. The aquifer systems extend offshore where they crop out along the edge of the submarine shelf and within the coastal submarine canyons. Submarine canyons have dissected these regional aquifers, providing a hydraulic connection to the ocean through the submarine outcrops of the aquifer systems. Coastal landward flow (seawater intrusion) occurs within both the upper- and lower-aquifer systems. A numerical ground-water flow model of the Santa Clara-Calleguas Basin was developed by the U.S. Geological Survey to better define the geohydrologic framework of the regional ground-water flow system and to help analyze the major problems affecting water-resources management of a typical coastal aquifer system. Construction of the Santa Clara-Calleguas Basin model required the compilation of geographic, geologic, and hydrologic data and estimation of hydraulic properties and flows. The model was calibrated to historical surface-water and ground-water flow for the period 1891-1993. Sources of water to the regional ground-water flow system are natural and artificial recharge, coastal landward flow from the ocean (seawater intrusion), storage in the coarse-grained beds, and water from compaction of fine-grained beds (aquitards). Inflows used in the regional flow model simulation include streamflows routed through the major rivers and tributaries; infiltration of mountain-front runoff and infiltration of precipitation on bedrock outcrops and on valley floors; and artificial ground-water recharge of diverted streamflow, irrigation return flow, and treated sewage effluent. Most natural recharge occurs through infiltration (losses) of streamflow within the major rivers and tributaries and the numerous arroyos that drain the mountain fronts of the basin. Total simulated natural recharge was about 114,100 acre-feet per year (acre-ft/yr) for 1984-93: 27,800 acre-ft/yr of mountain-front and bedrock recharge, 24,100 acre-ft/yr of valley-floor recharge, and 62,200 acre-ft/yr of net streamflow recharge. Artificial recharge (spreading of diverted streamflow, irrigation return, and sewage effluent) is a major source of ground-water replenishment. During the 1984-93 simulation period, the average rate of artificial recharge at the spreading grounds was about 54,400 acre-ft/yr, 13 percent less than the simulated natural recharge rate for streamflow infiltration within the major rivers and tributaries. Estimated recharge from infiltration of irrigation return flow on the valley floors averaged about 51,000 acre-ft/yr, and treated sewage effluent averaged about 9,000 acre-ft/yr. Artificial recharge as streamflow diversion to the spreading grounds has occurred since 1929, and treated-sewage effluent has been discharged to stream channels since 1930. Under

Water-Resources Investigations Report↗