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Episodic sediment-discharge events in Cascade Springs, southern Black Hills, South Dakota

Cascade Springs is a group of artesian springs in the southern Black Hills, South Dakota, with collective flow of about 19.6 cubic feet per second. Beginning on February 28, 1992, a large discharge of red suspended sediment was observed from two of the six known discharge points. Similar events during 1906-07 and 1969 were documented by local residents and newspaper accounts. Mineralogic and grain-size analyses were performed to identify probable subsurface sources of the sediment. Geochemical modeling was performed to evaluate the geochemical evolution of water discharged from Cascade Springs. Interpretations of results provide a perspective on the role of artesian springs in the regional geohydrologic framework. X-ray diffraction mineralogic analyses of the clay fraction of the suspended sediment were compared to analyses of clay-fraction samples taken from nine geologic units at and stratigraphically below the spring-discharge points. Ongoing development of a subsurface breccia pipe(s) in the upper Minnelusa Formation and/or Opeche Shale was identified as a likely source of the suspended sediment; thus, exposed breccia pipes in lower Hell Canyon were examined. Upper Minnelusa Formation breccia pipes in lower Hell Canyon occur in clusters similar to the discrete discharge points of Cascade Springs. Grain-size analyses showed that breccia masses lack clay fractions and have coarser distributions than the wall rocks, which indicates that the red, fine-grained fractions have been carried out as suspended sediment. These findings support the hypothesis that many breccia pipes were formed as throats of abandoned artesian springs. Geochemical modeling was used to test whether geochemical evolution of ground water is consistent with this hypothesis. The evolution of water at Cascade Springs could not be suitably simulated using only upgradient water from the Minnelusa aquifer. A suitable model involved dissolution of anhydrite accompanied by dedolomitization in the upper Minnelusa Formation, which is caused by upward leakage of relatively fresh water from the Madison aquifer. The anhydrite dissolution and dedolomitization account for the net removal of minerals that would lead to breccia pipe formation by gravitational collapse. Breccia pipes in the lower Minnelusa Formation are uncommon; however, networks of interconnected breccia layers and breccia dikes are common. These networks, along with vertical fractures and faults, are likely pathways for transmitting upward leakage from the Madison aquifer. It is concluded that suspended sediment discharged at Cascade Springs probably results from episodic collapse brecciation that is caused by subsurface dissolution of anhydrite beds and cements of the upper Minnelusa Formation, accompanied by replacement of dolomite by calcite. It is further concluded that many breccia pipes probably are the throats of artesian springs that have been abandoned and exposed by erosion. The locations of artesian spring-discharge points probably have been shifting outwards from the center of the Black Hills uplift, essentially keeping pace with regional erosion over geologic time. Thus, artesian springflow probably is a factor in controlling water levels in the Madison and Minnelusa aquifers, with hydraulic head declining over geologic time, in response to development of new discharge points. Development of breccia pipes as throats of artesian springs would greatly enhance vertical hydraulic conductivity in the immediate vicinity of spring-discharge points. Horizontal hydraulic conductivity in the Minnelusa Formation also may be enhanced by dissolution processes related to upward leakage from the Madison aquifer. Potential processes could include dissolution resulting from leakage in the vicinity of breccia pipes that are abandoned spring throats, active spring discharge, development of subsurface breccias with no visible surface expression or spring discharge, as well as general areal leakage from the Madison aquifer into the Minnelusa Formation.

South Dakota

Comparative assessment of STIC sensors, streamflow and rain gauges for quantifying river connectivity in intermittent systems

In intermittent stream systems, including those occurring in Texas, USA, the severity of low-flow conditions, duration of seasonal disconnection, and frequency of no-flow events have been amplified by drought. Documentation of these no-flow events is necessary to evaluate ecosystem health. However, many intermittent reaches remain un-gauged given that perennial river sec-tions are often prioritized for gauge placement. Our objectives were to 1) document stream flow using Stream Temperature, Intermittency, and Conductivity (STIC) loggers to determine the frequency and duration of no-flow events in intermittent tributaries of the Colorado River, Texas and 2) compare logger data to publicly available data from streamflow discharge and precipitation gauge networks to understand differences among these data types for drying event characterization. We use these comparisons to summarize benefits and limitations of the application of in-stream data loggers. STIC loggers were deployed at 19 sites, one in each pool and riffle habitat of a stream reach. STIC loggers recorded a measurement of relative conductance every six hours from June 2022 to March 2024, which was used to determine the presence or absence of flow connectivity in a reach. No-flow duration among intermittent reaches varied between 37 and 270 days across tributaries during an ongoing drought in the study area. Overall, logger data was more precise than discharge data for characterizing no-flow events or precipitation data when documenting presence of water in the stream channel due to runoff. Lack of discharge gauges in intermittent tributaries left large sections of stream reaches undocumented and resulted in mischaracterization of flow patterns. Drought severity across the tributaries did not follow longitudinal patterns that would be expected by the climatic precipitation gradient of the study area. More research is needed to determine if factors such as population size affect severity. Likewise, precipitation data did not correlate well with logger water presence data, lacking consideration for groundwater recharge, soil hydrophobicity, and surface compaction. This study shows that to monitor no-flow events, detailed spatial datasets are necessary and that STIC loggers are useful tools that provide data to fill spatial information gaps and facilitate more accurate flow characterization and water presence data in intermittent systems.

Texas

Evaluation of submersible pressure transducers for streamflow monitoring in small streams

Compact streamgages requiring minimal infrastructure and equipped with submersible pressure transducers (PTs) are increasingly used to monitor small streams, yet disparate implementations obscure their accuracy under real-world conditions. This study isolated instrumentation-derived uncertainty in stage monitoring by co-locating various combinations of commercial vented and unvented PTs with seven U.S. Geological Survey (USGS) reference streamgages on small streams. Multi-year PT stage records from compact streamgages, collected and corrected following USGS protocols, were compared to concurrent reference observations. Vented PTs demonstrated an average measurement uncertainty of ±0.005 m and mean absolute percent error (MAPE) of ±0.2%. Unvented PTs exhibited higher uncertainty, averaging ±0.009 m and ±0.4% MAPE. Although both sensor types had stage errors up to ±0.3 m, 95% of vented PT and unvented PT observations were within 0.01 and 0.02 m of reference stage, respectively. Analysis of additional unvented PTs revealed stage errors of up to ±1.2% when using barometric sensors within 15 km of the in-water sensor. Propagation of stage error to discharge using reference rating models resulted in cumulative discharge MAPEs of ±4.5% for vented and ±5.5% for unvented PTs. These findings highlight PTs as practical alternatives to reference instrumentation when deployed with standardized procedures, potentially expanding access to reliable streamflow data.

conterminous United States

PFAS remediation in a bioelectrochemical system inoculated with the west branch consortium (WBC-2)

Groundwater contamination by per - and polyfluoroalkyl substances (PFAS) poses a persistent environmental and public health concern. This study evaluates a two-chambered bioelectrochemical system (BES) inoculated with the West Branch Consortium (WBC-2) for PFAS remediation. Under an applied cathodic potential of −450 mV (versus Ag/AgCl), the BES with active WBC-2 achieved >99.0% perfluorooctanesulfonic acid (PFOS) removal within 21 days in deionized water with culture medium and > 98.9% removal of PFOS, perfluorooctanoic acid (PFOA), perfluorohexanoic acid (PFHxA), and perfluorohexanesulfonic acid (PFHxS) in contaminated groundwater after 102 days. Intermediate formation (e.g., PFOA, 6:2 fluorotelomer sulfonate (6:2 FTS), perfluoropropionic acid (PFPrA), perfluorobutanoic acid (PFBA)) and background-corrected fluoride release were consistent with PFOS transformation under anaerobic reducing conditions potentially involving defluorination. Following repeated PFOS spikes (100 μg/L on Days 0, 50, and 399), PFOA, PFPrA, and PFBA accumulated over 664 days. Despite being the dominant accumulated compound, PFOA accounted for <1.8% of the total spiked PFOS mass. Minimal PFOS transformation occurred in controls without active WBC-2, highlighting the importance of microbial metabolism. Biofilm analysis revealed dense colonization of rod-shaped bacteria on carbon fiber brushes. Enrichment of Bacillus , Agrobacterium , and other low-abundance taxa suggests selective adaptation to BES and PFAS conditions. These findings highlight BES driven by electrochemically stimulated microbial activity as a promising strategy for PFAS remediation.

Journal of Water Process Engineering

Transit time modeling framework for predicting freshwater salinization in urban catchments

The salinity of inland freshwaters is rising globally, particularly in urban watersheds where winter road deicers are widely applied. Attributing stream salinity dynamics to specific sources and transport pathways remains challenging due to episodic salt inputs, engineered drainage, and strong coupling between hydrology and subsurface storage. We present a modeling framework that couples climate-driven deicer build-up and wash-off with transient transit time distribution theory to simulate salt transport through drainage, interflow, and groundwater pathways. Applied to an urban watershed in Northern Virginia (USA), the model reproduces ten years of high-frequency stream salinity measurements across daily-to-decadal timescales. The calibrated model implies an average deicer application of 206 tonnes Cl −1 yr −1 , or roughly one 20 kg bag of rock salt person −1 yr −1 when normalized by the 20,000 people living in the watershed. In winter months, higher infiltration routes a large fraction of snowmelt and deicers into shallow subsurface pathways, enhancing vadose-zone and interflow contributions to stream salinity. Limited subsurface storage capacity and seasonal hydrologic turnover flush excess chloride from the vadose zone and groundwater during subsequent summer storms. By linking climate-driven deicer inputs, hydrologic connectivity, and stream water age, the framework provides a transferable basis for diagnosing and managing freshwater salinization in urban watersheds.

Virginia

Completion summary for monitor wells NRF-17 and NRF-18 at the Naval Reactors Facility, Idaho National Laboratory, Idaho

The U.S. Geological Survey (USGS)—in cooperation with the U.S. Department of Energy (DOE) for the Naval Reactors Laboratory Field Office that supports operations for the Naval Reactors Facility (NRF) located at the Idaho National Laboratory (INL)—drilled and constructed well NRF-17 (formerly borehole USGS 151) and well NRF-18 (formerly borehole USGS 152) for stratigraphic framework analyses and water-quality monitoring at the Idaho National Laboratory (INL) near the NRF, in southeastern Idaho. Borehole USGS 151 was continuously cored from about 48 to 1,070 feet (ft) below land surface (BLS); rotary drilled from approximately 1,070 to 1,720 ft BLS; and re-drilled to complete construction as a monitor well NRF-17, completed to 461 ft BLS. Borehole USGS 152 was continuously cored from approximately 19 to 1,259 ft BLS; rotary drilled from approximately 1,259 to 1,630 ft BLS; and re-drilled to complete construction as a monitor well NRF-18, completed to 450 ft BLS. Geophysical data were examined with photographed core material to record lithologic descriptions and to suggest zones where groundwater flow was anticipated. Basalt flows varied from highly fractured to dense, with high-to-low vesiculation. Well NRF-17 generally was constructed in mostly dense basalt (greater than 75 percent), and well NRF-18 was constructed in primarily fractured and (or) vesicular basalt. In well NRF-17, the well capacity is directly affected by the limited amount of fractured basalt, which serves as the primary pathway for groundwater. This effect was observed during the pumping test conducted after the well's final construction. Single-well aquifer tests were done at wells NRF-17 and NRF-18 to provide estimates of transmissivity and hydraulic conductivity after final well construction and initial well development. Estimated values of transmissivity and hydraulic conductivity for well NRF-17 were 8.81 feet squared per day (ft 2 /d) and 1.04×10 -2 feet per day (ft/d), respectively. Estimated values of transmissivity and hydraulic conductivity for well NRF-18 were 4.77×10 3 ft 2 /d and 5.61 ft/d, respectively. The NRF-17 pump test resulted in 19.41 ft of measured drawdown at a sustained average pumping rate of 3.3 gallons per minute (gal/min). The NRF-18 pump test resulted in 0.55 ft of measured drawdown at a sustained average pumping rate of 31.0 gal/min. Water-quality samples collected from the two wells were analyzed for cations, anions, metals, nutrients, volatile organic compounds, stable isotopes, and radionuclides. Water samples for select inorganic constituents showed concentrations consistent with signatures from tributary valley groundwater with influences from ephemeral surface-water recharge from the Big Lost River. Water-quality samples analyzed for stable isotopes of oxygen and hydrogen are consistent with signatures from tributary valley groundwater and surface-water recharge inputs to the aquifer. No measured water-quality results were greater than their respective maximum contaminant levels for public drinking-water supplies. Inorganic and nutrient water-quality results for well NRF-17 and well NRF-18 suggest the groundwater in this area is potentially affected by industrial wastewater disposal.

Idaho

U.S. Geological Survey Earthquake Hazards Program decadal science strategy, 2024–33

Executive Summary Earthquakes represent one of our Nation’s most significant and costly natural hazards, with estimated annual loses from earthquakes close to $15 billion in 2023. Over the past two centuries, 37 U.S. States have experienced an earthquake exceeding a magnitude of 5, and 50 percent of States have a significant potential for future damaging shaking; these statistics speak to the need for nationwide interest and investment in earthquake hazard characterization and risk reduction. Authorized under the Earthquake Hazards Reduction Authorization Act, the U.S. Geological Survey (USGS) Earthquake Hazards Program (EHP) provides the scientific information, situational awareness, and knowledge necessary to reduce deaths, injuries, and economic losses from earthquakes and earthquake-induced tsunamis, landslides, and soil liquefaction. The EHP supports activities in three focused topical areas: (1) earthquake monitoring, (2) hazard assessment, and (3) applied research, using the results of each—and the coordination among them—to further support risk translation and communication in regions at risk nationwide. For earthquake monitoring, the Advanced National Seismic System (ANSS), a cooperative effort of USGS networks, university partner regional seismic networks, and real-time geodetic networks, collects and analyzes data on earthquakes; issues timely, reliable notifications of their occurrence and impacts; and provides data for earthquake research, hazard, and risk assessment as a foundation for building an earthquake-resilient Nation. The USGS-operated ShakeAlert Earthquake Early Warning system is a recent addition to EHP’s ANSS infrastructure. In the realm of earthquake hazard assessment, the EHP contributes to earthquake risk mitigation strategies by developing the National Seismic Hazard Model and maps, and other related products, that describe the likelihood and potential effects of earthquakes nationwide, especially in the urban areas of highest risk. The EHP also conducts research on the causes, characteristics, and effects of earthquakes and prioritizes work that directly increases the accuracy and precision of earthquake hazards assessments, earthquake forecasts, and earthquake monitoring and situational-awareness products and that supports the Nation’s earthquake mitigation practices. Bridging the EHP’s efforts across research, hazard assessments, and earthquake monitoring is a broad and comprehensive collection of earthquake information products, including the National Seismic Hazard Model, ShakeAlert, and other products describing impact, such as ShakeMap and PAGER (Prompt Assessment of Global Earthquakes for Response), which have been developed and integrated into EHP’s real-time monitoring systems. EHP funds external partners to carry out many important collaborative activities through an active external grants program—one of the largest in the USGS—and through cooperative agreements with other partners such as the university-operated regional seismic networks, funded as part of the ANSS. To continue its support of earthquake hazard characterization and risk reduction, the EHP aims to strengthen its foundational products and practices while positioning itself to respond to the evolving needs of the Nation and follow best practices of the scientific community. This document describes a strategy for the program to ensure it can meet these demands. The foundational priorities outlined in this strategy represent those activities that remain critical to the core functionality of the program and those that can be supported under current fiscal year 2024-level appropriations. Priorities described as aspirational are important for future growth, and to maintain the program’s position as a leading global resource in earthquake science, but would require increases in appropriated funding to be fully realized. Across the program’s portfolio of activities, several major themes have been identified as the most critical activities to advance EHP science over the coming decade. Together, these activities provide the framework necessary to integrate critical hazard characterization and risk reduction activities across the program. They provide the structure for research to advance the understanding of where, when, and why earthquakes occur and how we can use improved knowledge to drive short-term and actionable forecasts of seismic activity. They expand the usefulness of critical earthquake products and advance the sophistication of those products to keep pace with the rapidly evolving needs of an ever-expanding user base while maintaining the position of the USGS as a global leader in earthquake science. Focus on system-level science. Establish an automated earthquake-processing pipeline. Enhance the accuracy and reliability of the ShakeAlert Earthquake Early Warning system and plan for extension to other regions. Implement time-dependent earthquake forecasting. Develop physically realistic models. Expand computational capacity. This science strategy is organized into three primary sections. The first section provides an overview of the EHP and its budget, governance, and program council. Readers familiar with the program may wish to focus on the second section, which describes the core of the science strategy, including priorities across each of the EHP’s major program activities in monitoring, hazard assessment, and targeted research. The third section outlines science priorities that cut across program activities, including those involving collaborations external to the EHP.

American Samoa, Guam, Northern Marianas Islands, U

An evaluation of the effects of different deicing salt application rates on three watersheds in Essex County, New York

The U.S. Geological Survey, in cooperation with the New York State Department of Transportation, evaluated the effects of different deicing salt application rates on surface water, groundwater, and highway runoff quality near State highways in northern New York. Three reaches of State highways were tested with different deicing treatments between October 2019 and November 2022: a salt-sand mixture (Treatment A), a salt mixture applied at a lower rate (Treatment B), and a control mixture consistent with typical deicing salt amounts and application rates. Data on pavement conditions and the quality of surface water, highway runoff, and groundwater were collected. Surface electromagnetic data were also collected. Surface-water and groundwater quality downgradient from the State highways were compared with water quality at upgradient locations. The percentage of snow or ice coverage was used to evaluate the effectiveness of the salt applications. This report provides an overview of the transport of deicing salt. The Treatment B watershed had deicing mixture applied more frequently than other highway reaches, which caused it to have the highest annual total chloride application. Despite differences in chloride application, flow-weighted mean chloride concentrations in highway runoff were comparable across treatments. Chloride concentrations were elevated in surface water and groundwater downgradient from highways relative to chloride concentrations upgradient from highways. A chloride mass balance, calculated for one treatment watershed, indicated that groundwater affected by legacy deicing practices may be contributing additional chloride to surface water. Spatial patterns from electromagnetic surveys show a shallow saline plume alongside the highway in that area. Differences in winter severity and pavement-surface conditions drove deicing salt applications in the treatment areas. This study found that several factors affect chloride loads in the watersheds, including variable winter conditions, adaptive snow and ice management, legacy management practices, and area-specific aquifer and groundwater conditions.

New York

Simulated mean monthly groundwater-transported nitrogen loads in watersheds on the north shore of Long Island Sound, 1993–2022

Elevated nitrogen loads are pervasive in the Long Island Sound, an estuary that receives freshwater and nutrients from both surface-water and groundwater discharge. Surface-water nitrogen loads to the Long Island Sound are relatively well characterized, but less is known about groundwater-transported nitrogen loads. Prior work on the northern shore of Long Island Sound (Connecticut and areas of New York and Rhode Island) suggested that groundwater travel times are relatively short (median less than 2 years) and that decade-long nutrient legacies are not widespread. Because the travel times are short, groundwater flow and nutrient loads likely vary substantially between months. In the current study, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency’s Long Island Sound Study and the Connecticut Department of Energy and Environmental Protection, developed a set of models to better characterize spatial and temporal patterns of groundwater-transported nitrogen loading from atmospheric deposition, septic systems, and fertilizers within the study area. The models provide an estimate, with uncertainty, of groundwater-transported nitrogen loads in the study area, filling a key gap in the nitrogen budget for Long Island Sound. The models also highlight the spatial and temporal variation in nitrogen loading throughout the study area. The modeling workflow involved four models. (1) A soil-water-balance model was developed by using the Soil-Water-Balance software to simulate groundwater recharge across the study area for water years 2005 through 2022. The simulated mean monthly recharge from the soil-water-balance model was used as input into a groundwater-flow model. (2) The groundwater-flow model was developed by using the MODFLOW 6 software and data for water years 1993 through 2022 and simulates average monthly hydrologic conditions. The groundwater-flow model was calibrated by using the Iterative Ensemble Smoother method within the PEST++ software. The Iterative Ensemble Smoother method generates an ensemble of sets of parameter values, with each set producing reasonable simulated hydrologic parameter values. (3) An ensemble of MODPATH particle-tracking simulations were run to generate particle flow paths and travel times, with each simulation using a different set of the flow model parameters. (4) A nitrogen load model uses the MODPATH simulation outputs to track nitrogen from the land surface through multiple attenuation zones until it discharges into fresh or saline surface water. As with the groundwater-flow model, the nitrogen model simulated average monthly groundwater-transported nitrogen loads for water years 1993 through 2022. One novel aspect of the nitrogen load model is that the nitrogen attenuation parameters were calibrated to observed nitrogen loads. Across the ensemble of simulated nitrogen loads, the median study-area-wide monthly simulated nitrogen loads from the aquifer to Long Island Sound throughout the year ranged from 900 to 18,600 kilograms of nitrogen per day, with a median load of 5,100 kilograms of nitrogen per day. The simulated loads were based on average monthly conditions for water years 1993 through 2022. Loads were highest during the winter and early spring and lowest during the late summer. However, simulated travel times for groundwater and nitrogen loads discharged to Long Island Sound during summer were longer than travel times for groundwater and loads discharged during the winter, indicating that, on average, groundwater discharged during summer traveled along different, and longer, flow paths, than groundwater discharged during winter. This indicates that summer loads would respond more slowly to changes in nitrogen inputs at the water table than winter loads. Over the entire study area, approximately 15 percent of the simulated load is from atmospheric deposition sources, 30 to 40 percent is from fertilizer, and 50 to 60 percent is from septic systems. The final analysis of the study involved simulating the change in groundwater-transported nitrogen load in response to upgrading septic systems or reducing fertilizing inputs to areas of turf grass. Both management interventions reduced the groundwater-transported nitrogen load, and reductions were greater in areas with greater loads from septic systems or turf-grass fertilizers. The delay between management actions and substantial reductions in groundwater-transported nitrogen loads varied seasonally; loads during the late summer months remained elevated longer than the winter loads.

Connecticut, Rhode Island

Effects of snowmobile use on snowpack chemistry in Yellowstone National Park, 1998

Snowmobile use in Yellowstone National Park has increased substantially in the past three decades. In areas of greatest snowmobile use, elevated levels of by-products of gasoline combustion such as ammonium and benzene have been detected in snowpack samples. Annual snowpacks and snow-covered roadways trap deposition from local and regional atmospheric emissions. Snowpack samples representing most of the winter precipitation were collected at about the time of maximum annual snow accumulation at a variety of locations in the park to observe effects of a range of snowmobile traffic levels. Concentrations of organic and inorganic compounds in snow samples from pairs of sites located directly in and off snow-packed roadways used by snowmobiles were compared to concentrations in samples collected at nearby off-road sites. Concentrations of ammonium were 2 to 5 times higher for the in-road snow compared to off-road snow for each pair of sites. Thus, concentrations decreased rapidly with distance from roadways. In addition, concentrations of ammonium, nitrate, sulfate, benzene, and toluene in snow were positively correlated with snowmobile use.

Wyoming

Irrigated agriculture influences selenium levels in an endangered marsh bird

Selenium bioaccumulation in aquatic food webs poses risks to wildlife, particularly in wetlands receiving irrigation runoff. The Salton Sea, California’s largest lake, is primarily sustained by agricultural drainage. This drainage creates wetland habitat along the lakeshore that many bird species depend on, including the federally endangered Yuma Ridgway’s rail ( Rallus obsoletus yumanensis ). However, these marshes may pose an ecological trap – attracting rails despite high selenium exposure. We captured rails during the 2020–2023 breeding seasons and compared rail selenium levels within three types of marshes (fed with irrigation runoff, Colorado River water, or groundwater). We collected blood, breast feathers, and head feathers of rails in all three water sources for selenium comparisons. We tagged adult rails with GPS transmitters to locate nests and foraging locations where we collected eggshells, unhatched eggs, and prey. We assessed selenium exposure by collecting multiple prey species commonly eaten by rails in all three water sources. Selenium concentrations varied among sampling locations. Selenium concentrations in most sample types were predominately influenced by water source and marsh inflow velocity (sometimes in combination with marsh size). Distance to inflow, however, did not influence selenium concentrations in any sample type. Selenium concentrations were highest in agricultural-fed marshes compared to river-fed and spring-fed marshes. Increased marsh inflow velocities resulted in lower selenium concentrations. Given the risk of an ecological trap, our results suggest that supplementing wetlands with Colorado River water could mitigate selenium bioaccumulation in Yuma Ridgway’s rails.

California

Arsenic and isotope concentrations in the lower Platte River valley of eastern Nebraska, early 1970s to 2023

The City of Lincoln, Nebraska, has been monitoring concentrations of arsenic in their source water and evaluating their options for treatment and removal since at least 2002. In 2022, the City of Lincoln, Nebr., with funding assistance from the Nebraska Water Sustainability Fund, began cooperating with the U.S. Geological Survey to examine arsenic concentrations in surface water and groundwater in the lower Platte River valley and the area around City of Lincoln Water System (LWS) well field. Arsenic data collected from the Platte River since 1974 were examined using the “weighted regression on time, discharge, and season” model, which compared the streamflow (also referred to as “discharge”), time of year, and season to estimate concentrations of arsenic. Annual mean arsenic concentrations modeled for more than 49 years at the Platte River at Louisville, Nebr., U.S. Geological Survey streamgage (station 06805500), indicated a significant increasing trend. Arsenic concentrations in the Platte River were seasonal, with the highest concentrations being observed during mid- to late summer. When seasonal patterns and streamflow were combined with arsenic concentrations in the Platte River during low streamflow conditions, groundwater contributions, which can have higher arsenic concentrations, make up a larger portion of the streamflow. Arsenic samples were collected from upstream rivers in 2022 and 2023 and were paired to analyze the arsenic contributions at the U.S. Geological Survey streamgage on the Platte River near Ashland, Nebr. (station 06801000), near the City of Lincoln well field. The arsenic concentrations from the streamgage on the Platte River near Ashland, Nebr., location, were higher than the U.S. Geological Survey streamgage on the Elkhorn River at Waterloo, Nebr. (station 06800500), and significantly lower than at the U.S. Geological Survey streamgage on the Platte River near Leshara, Nebr.(station 06796500), indicating that the Platte River usually contributes a higher concentration of arsenic than does the Elkhorn River as they join near Ashland, Nebr. During 1991–2023, six groundwater monitoring wells were analyzed to identify trends in arsenic concentrations. Two of the six wells had a positive trend during the 33-year period. One monitoring well did not reveal a long-term trend during this period but showed a trend during 2019–23, correlating to a period when the island in the middle of the Platte River was connected to the east bank of the river when manganese reducing conditions were present and groundwater levels were declining in the well. Across all wells the oxidation and reduction (redox) condition during the time of sampling was assessed. Mixed anoxic and (or) oxic redox condition was the most common redox process and the highest sampled arsenic concentrations in monitoring wells were observed in anoxic conditions driven by manganese reduction. Groundwater arsenic concentrations had seasonal variation around the City of Lincoln well field, with higher arsenic concentrations tending to be further south in comparison to samples collected further north. Isotope samples were collected and analyzed in surface water and groundwater around the LWS well field. The samples indicate that the proportion of surface water present in the LWS production wells can be higher in the spring and lower in the summer. With higher arsenic concentrations observed in the stream water during the summer period, the LWS source water can be affected by these elevated arsenic concentrations even though the proportion of surface water is lower.

Nebraska

The 3D National Topography Model Call for Action—Part 1. The 3D Hydrography Program

The U.S. Geological Survey is initiating the 3D Hydrography Program (3DHP), the first systematic remapping of the Nation’s surface waters since the original 1:24,000-scale topographic mapping program was active from 1947 to 1992. Building on decades of experience maintaining the National Hydrography Dataset (NHD), the Watershed Boundary Dataset (WBD), and the NHDPlus High Resolution (NHDPlus HR), the 3DHP will completely refresh the Nation’s hydrography data and improve discovery and sharing of water-related data. The design of the 3DHP is based on the results of a study that estimated that the fully implemented program would have the potential to provide more than $1 billion in benefits to Federal, State, Tribal, Territorial, and local governments and to private and nonprofit organizations every year, in addition to myriad societal benefits. The 3DHP would directly support better decision making regarding water resources by providing more accurate, complete, and integrated information than is currently available. The 3DHP datasets will include a three-dimensional (3D) hydrography network generated from and integrated with elevation data from the 3D Elevation Program (3DEP) to better represent stream gradients and channel conditions, along with waterbodies, hydrologic units, hydrologically enhanced elevation and other surfaces, and more consistent and accurate attributes. The 3DHP datasets will inherit key attributes of the NHD, WBD, and NHDPlus HR, and they also will include new attributes and links to other data such as the U.S. Fish and Wildlife Service National Wetlands Inventory, groundwater data, and engineered hydrologic systems such as stormwater networks. The 3DHP will be designed to provide a set of open and interoperable web-based tools, maps, and data catalogs, creating a robust system for users to reference their information about water; the system elements are collectively referred to as the “infostructure.” The 3DHP and the infostructure can provide a foundational geospatial underpinning for the Internet of Water, a community-based effort to modernize tools and technologies to share water data. As proposed, the 3DHP would begin providing products and services to the public in 2024.

Circular

A spatial analysis of the groundwater emergence flood hazard in Long Island, New York and near coastal areas surrounding Long Island Sound in New York, Connecticut, and Rhode Island

Long Island, New York and near coastal areas surrounding Long Island Sound are densely populated and, like other coastal areas, are susceptible to flooding from several potential sources, including stormwater from precipitation events, tidal flooding and storm surge, and groundwater inundation or groundwater emergence flooding. The latter refers to the intersection of a rising water table with land surface or critical infrastructure. Many studies of flood drivers either neglect or only briefly discuss how shallow groundwater conditions may contribute to or exacerbate flood conditions. As part of a comprehensive study of compound flood hazards in the near coastal areas surrounding Long Island and Long Island Sound, a spatial analysis was completed, in cooperation with the Environmental Protection Agency’s Long Island Sound Study, using available regional datasets to characterize the potential hazard for groundwater emergence flooding. The approximately 3,100 square mile study area was subdivided into 11,407 900-meter by 900-meter (approximately 3,000-feet by 3,000-feet) grid cells, for the purposes of integrating the spatial datasets to calculate and map the groundwater emergence flood hazard. The depth to the water table, hydrologic soil groups, and National Land Cover Database were harmonized to the common grid. A groundwater emergence flood hazard rank was calculated for each grid cell for current average conditions following a set of rules accounting for the depth to the water table and the percent of area within each cell with slow infiltrating soils. A higher sea level position scenario was also calculated for the Long Island part of the study area. The calculated groundwater emergence flood hazard rank was reviewed in concert with the National Land Cover Data Base to identify developed areas and associated infrastructure that may be at risk to groundwater emergence flooding. Study results indicate that the groundwater emergence flood hazard is highest in coastal areas and near surface water where the water table is close to ground surface. Inland areas away from surface water bodies are not likely to be exposed to groundwater emergence flooding. For Long Island, under a scenario with higher sea level position, a greater groundwater emergence flood hazard is calculated in some locations closer to the coast and where land is submerged. Away from the coast and surface-water drainage, the groundwater emergence flood hazard is similar between the current average sea level condition and a higher sea level position scenario.

EarthArXiv

Airborne geophysical analysis to decipher salinization for coastal Louisiana

Coastal Louisiana is known for saltwater intrusion that threatens wetlands, aquifers, and rivers. However, the extent of saltwater intrusion is not well understood. This study develops an innovative framework with airborne electromagnetic (AEM) data to map chloride concentration distributions for wetlands in the Mississippi River deltaic plain and Chenier plain as well as for the Mississippi River Valley alluvial aquifer (MRVA) and Chicot aquifer. Moreover, the framework maps chloride concentrations along the Mississippi River and Atchafalaya River. Key components in the framework include the establishment of resistivity-to-chloride concentration transformation, 3D resistivity architecture building through geostatistics, and the employment of a lithologic model. The transformation functions correlate AEM resistivity data with porewater salinity measurements and groundwater and river chloride samples. The results show that AEM data reliably infers soil water chloride concentrations and correlates well with the distribution of various marsh types. AEM data reveals extensive saltwater presence at depth and near the coast, originating from salt domes and the Gulf of Mexico, respectively. The saltwater upconing pattern in the Chicot aquifer is likely due to excessive groundwater withdrawals. The AEM data also confirms a distinct tongue of saltwater intruding into the Atchafalaya Basin from the Gulf. The AEM data helps to identify faults that are obscured or eroded at the surface, which appear as leaky barriers in the subsurface where dramatic changes in chloride concentration are apparent. Finally, this study uses the AEM data to infer the presence of an extensive seawater wedge in the Mississippi River and Atchafalaya River.

Louisiana

Models no not provide proof: An example of model ambiguity and application of isotopic data in a mine pit lake

Geochemical and hydrologic models of pit lakes are commonly used in environmental regulatory decisions to predict future water quality and hydrologic conditions and to understand existing pit lakes. Models may be used to quantify sulfide oxidation, predict thermal/chemical stratification and mixing, and better understand connections between pit lakes and aquifers. One concern related to the hydrologic character of pit lakes is if they are terminal (a groundwater sink with no outflow) or flowthrough (both receiving groundwater inflow and discharging to groundwater). This question was pertinent to the Liberty pit lake, a small acidic pit lake formed in a former Cu deposit in south-central Nevada where potentiometric and geochemical data potentially indicate pit-lake outflow. Potential discharge to groundwater from the pit lake was evaluated using a water-balance model, but uncertainty in hydraulic parameters led to ambiguity in the hydrologic character. Stable isotopes of water were then sampled from the pit lake and adjacent groundwater wells, which unambiguously indicated the lack of an evaporative signature in downgradient groundwater because the groundwater did not plot on a hypothetical mixing line between evaporated pit lake water and observed meteoric recharge. This methodology provided a more effective and more data-driven approach for understanding pit-lake hydrology. Although predictive models are required to quantify reasonable bounds on future conditions, many models contain substantial uncertainty and are not well suited in some environments. Datasets that provide more clear lines of evidence could be collected from existing pit lakes whenever possible to inform water-rock interaction, limnological behavior, and connectivity to adjacent groundwater.

Nevada

Preferential groundwater discharges along stream corridors are disregarded sources of greenhouse gases

Groundwater delivery of greenhouse gases (GHGs) to stream banks and riparian areas, before mixing with surface waters, has not been well quantified. We measured preferential groundwater delivery of GHGs to stream banks within three stream reaches, and found that stream banks with discharging groundwater emitted more CO 2 and were sources of N 2 O compared to stream banks without actively discharging groundwater, which emitted less CO 2 and were N 2 O sinks. At one of our stream reaches, groundwater CO 2 and N 2 O concentrations were 1.4–19.2 and 1.1–40.6 times higher than those in surface water, respectively, and groundwater delivery rates of CO 2 and N 2 O were 1.5 and 1.6 times higher than surface water emissions per unit area. On average, 21% (range 0%–100%) of CO 2 and N 2 O were emitted at the stream bank before mixing with surface waters. Preferential groundwater GHG emissions may contribute substantially to stream corridor emissions and may be underestimated when using a channel-centric approach to estimate riverine GHG budgets.

JGR Biogeosciences

Groundwater quality and groundwater levels in Dougherty County, Georgia, April 2020 through January 2023

The Upper Floridan aquifer is the uppermost reliable groundwater source in southwest Georgia. The aquifer lies on top of the Claiborne, Clayton, and Cretaceous aquifers, all of which exhibited water-level declines in the 1960s and 1970s. The U.S. Geological Survey has been working cooperatively with Albany Utilities to monitor groundwater quality and availability in these aquifers since 1977. Flow direction in the Upper Floridan aquifer is to the south and toward the Flint River. During the past 3 years, water levels varied above and below period-of-record median values. Water levels in the Upper Floridan aquifer were primarily above or at median levels during 2020 and 2021 and at or below median levels during 2022. Water levels in the Claiborne aquifer were above median levels, whereas water levels in the Clayton aquifer were at or below median levels, and in the Cretaceous aquifer system were close to median levels. During January 2021, eight wells were sampled for major ions, including nitrate plus nitrite as nitrogen (N). Nitrate plus nitrite as N concentrations ranged from 2.3 to 10.5 milligrams per liter (mg/L). During December 2021, seven wells were sampled for major ions, including nitrate plus nitrite as N. Nitrate plus nitrite as N concentrations ranged from 3.9 to 9.9 mg/L. During November 2022, eight wells were sampled for major ions, including nitrate plus nitrite as N. Nitrate plus nitrite as N concentrations ranged from 3.9 to 10.0 mg/L. Two wells were also sampled for per- and polyfluoroalkyl substances during November 2022.

Georgia