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At least 541 records · Page 30Linked to original sources

Chemical quality of water in the Walnut River basin, south-central Kansas

Improper disposal of oil-field brine and other wastes has adversely affected the naturally diverse chemical quality of much of the water in the Walnut River basin, south-central Kansas. The basin is an area of about 2,000 square miles in the shape of a rough triangle with its apex toward the south. The Whitewater River, a principal tributary, and the Walnut River below its junction with the Whitewater River flow southward toward the Arkansas River along courses nearly coincident with the contact of the Chase and overlying Sumner Groups of Permian age. The courses of many minor tributaries are parallel to a well-developed joint system in the Permian rock. Thick interbedded limestone and shale of the Chase Group underlie the more extensive, eastern part of the basin. Natural waters are dominantly of the calcium bicarbonate type. Shale and subordinate strata of limestone, gypsum, and dolomite of the Sumner Group underlie the western part of the basin. Natural waters are dominantly of the calcium sulfate type. Inflow from most east-bank tributaries dilutes streamflow of the Walnut River; west-bank tributaries, including the Whitewater River, contribute most of the sulfate. Terrace deposits and alluvial fill along the stream channels are assigned to the Pleistocene and Holocene Series. Calcium bicarbonate waters are common as a result of the dissolution of nearly ubiquitous fragments of calcareous rock, but the chemical quality of the water in the discontinuous aquifers depends mainly on the quality of local recharge. Concentrations of dissolved solids and of one or more ions in most well waters exceeded recommended maximums for drinking water. Nearly all the ground water is hard to very hard. High concentrations of sulfate characterize waters from gypsiferous aquifers; high concentrations of chloride characterize ground waters affected by drainage from oil fields. Extensive fracture and dissolution of the Permian limestones facilitated pollution of ground water by oil-field brine and migration of the polluted water into adjacent areas. Ground water containing more than 1,000 mg/o=l (milligrams per liter) dissolved solids .and more than 100 mg/o=l chloride is common near oil fields but is exceptional elsewhere. The concentration of nitrate in about 25 percent of the sampled well waters exceeded the recommended maximum for drinking water. High concentrations of nitrate generally were associated with shallow aquifers, local sources of organic pollution, and stagnation. Sodium and chloride are the principle ionic constituents of oil-field brine but are minor constituents of natural surface waters or shallow ground water in the basin. The ratios of the concentrations of sodium to chloride in brine from different oil fields varied within a narrow range from a mean of 0.52. Concentrations of chloride exceeding 50 mg/o=l in streamflow and 100 mg/l in ground water generally signified the presence of oil-field brine if the sodium-chloride ratios were less than 0.60. Higher sodium-chloride ratios characterized relatively rare occurrences of high concentrations of the ions that might have originated in evaporite minerals or in sewage. The concentration of chloride during low flow of the major streams generally increased, and the sodium-chloride ratio decreased, in a downstream direction from about 0.65 near the headwaters to about 0.51, which is characteristic of oil-field brine. The changes were most abrupt where polluted ground-water effluent augmented low streamflow adjacent to old oil fields. With increased direct runoff, the sodium-chloride ratio normally increased, and these ions constituted a smaller percentage of the dissolved-solids load. Annual runoff .decreased progressively from above normal to below normal during water years 1962-64. Higher concentrations .of the ions in streamflow persisted for longer periods during the periods of low runoff

Water Supply Paper↗

Role of transient water pressure in quarrying: A subglacial experiment using acoustic emissions

Probably the most important mechanism of glacial erosion is quarrying: the growth and coalescence of cracks in subglacial bedrock and dislodgement of resultant rock fragments. Although evidence indicates that erosion rates depend on sliding speed, rates of crack growth in bedrock may be enhanced by changing stresses on the bed caused by fluctuating basal water pressure in zones of ice-bed separation. To study quarrying in real time, a granite step, 12 cm high with a crack in its stoss surface, was installed at the bed of Engabreen, Norway. Acoustic emission sensors monitored crack growth events in the step as ice slid over it. Vertical stresses, water pressure, and cavity height in the lee of the step were also measured. Water was pumped to the lee of the step several times over 8 days. Pumping initially caused opening of a leeward cavity, which then closed after pumping was stopped and water pressure decreased. During cavity closure, acoustic emissions emanating mostly from the vicinity of the base of the crack in the step increased dramatically. With repeated pump tests this crack grew with time until the step's lee surface was quarried. Our experiments indicate that fluctuating water pressure caused stress thresholds required for crack growth to be exceeded. Natural basal water pressure fluctuations should also concentrate stresses on rock steps, increasing rates of crack growth. Stress changes on the bed due to water pressure fluctuations will increase in magnitude and duration with cavity size, which may help explain the effect of sliding speed on erosion rates. Copyright 2006 by the American Geophysical Union.

Journal of Geophysical Research F: Earth Surface↗

Defining opportunities for collaboration across data life cycles

Monitoring natural resources - water, forests, and animal populations—is required to support effective management of natural resources. However, because monitoring activities are often specific to a discipline, issue, or agency, it is typically difficult to integrate data to answer questions that transcend geopolitical and jurisdictional boundaries. How do we reach the better data integration we need?

Eos, Transactions, American Geophysical Union↗

Climax-type porphyry molybdenum deposits

Climax-type porphyry molybdenum deposits, as defined here, are extremely rare; thirteen deposits are known, all in western North America and ranging in age from Late Cretaceous to mainly Tertiary. They are consistently found in a postsubduction, extensional tectonic setting and are invariably associated with A-type granites that formed after peak activity of a magmatic cycle. The deposits consist of ore shells of quartz-molybdenite stockwork veins that lie above and surrounding the apices of cupola-like, highly evolved, calc-alkaline granite and subvolcanic rhyolite-porphyry bodies. These plutons are invariably enriched in fluorine (commonly >1 percent), rubidium (commonly >500 parts per million), and niobium-tantalum (Nb commonly >50 parts per million). The deposits are relatively high grade (typically 0.1-0.3 percent Mo) and may be very large (typically 100-1,000 million tons). Molybdenum, as MoS2, is the primary commodity in all known deposits. The effect on surface-water quality owing to natural influx of water or sediment from a Climax-type mineralized area can extend many kilometers downstream from the mineralized area. Waste piles composed of quartz-silica-pyrite altered rocks will likely produce acidic drainage waters. The potential exists for concentrations of fluorine or rare metals in surface water and groundwater to exceed recommended limits for human consumption near both mined and unmined Climax-type deposits.

Open-File Report↗

Historical ground-water-flow patterns and trends in iron concentrations in the Potomac-Raritan-Magothy aquifer system in parts of Philadelphia, Pennsylvania, and Camden and Gloucester Counties, New Jersey

The Potomac-Raritan-Magothy (PRM) aquifer system is an important sole-source ground-water supply in Camden and Gloucester Counties, N.J. Elevated iron concentrations are a persistent water-quality problem associated with ground water from the PRM. In Philadelphia, the PRM no longer is usable as a water supply because of highly elevated concentrations of iron (as high as 429 mg/L [milligrams per liter]), manganese (as high as 4 mg/L), and sulfate (as high as 1,720 mg/L). A strongly reducing environment in the PRM in south Philadelphia causes these constituents to be remobilized by reductive dissolution of the aquifer matrix. By the 1920s, ground-water pumping changed the natural ground-water-flow patterns, and ground water flowed toward pumping centers in Philadelphia. By 1940, recharge areas changed from the topographically high areas east of Trenton, N.J., to the outcrop area of the PRM in Philadelphia, and the Delaware River became a source of recharge instead of a point of ground-water discharge. By 1954, the cone of depression caused by pumping at the former Philadelphia Naval Ship Yard (PNSY) exceeded 50 feet below NGVD 29, and the direction of ground-water flow was from New Jersey toward Philadelphia. Because of highly elevated concentrations of iron and manganese, pumping at the former PNSY ceased in the mid-1960s. Beginning about 1951, increased ground-water withdrawals from the PRM in New Jersey reversed the hydraulic gradient so that ground-water flow was from Philadelphia toward New Jersey under the Delaware River, making Philadelphia a recharge area for the PRM aquifer system in parts of Camden and Gloucester Counties. By 1988, water levels in the lower aquifer of the PRM in New Jersey had declined to 103 feet below NAVD 88. In 1943, dissolved iron concentrations ranged from 0.07 to 0.6 mg/L at the former PNSY. By 1967 when the wells at the PNSY were abandoned, dissolved iron concentrations had reached 46 mg/L. Dissolved iron concentrations in water from industrial wells in Philadelphia increased from 0.17 mg/L in 1949 to 19 mg/L in 1979. The concentration of dissolved iron in water from wells screened in the lower aquifer in New Jersey also increased with time. By 1985, dissolved iron concentrations were as high as 16 mg/L for Eagle Point refinery wells.

New Jersey, Pennsylvania↗

Evaluation of hydrologic data collected at the North Penn Area 12 Superfund Site, Montgomery County, Pennsylvania

The North Penn Area 12 Superfund Site is underlain by the Lockatong Formation, which consists of interbedded gray to black siltstone and shale. The beds of the Lockatong Formation strike northeast and dip about 10d to 20d to the northwest in the vicinity of the site. Ground water moves through fractures that are nearly vertical and horizontal in the shale and siltstone. Permeability and storage are very low. Borehole-geophysical logs were obtained from eight wells to determine the location of fractures, water-producing and water-receiving intervals, and intervals of borehole flow. The logs also were used to quantify fluid movement in the borehole, to characterize the lithology, and to obtain data on well construction. The logs indicate fractures at depths less than 100 feet are more frequent and generally are more productive than fractures at depths greater than 100 feet. The fluid resistivity of water in shallow intervals usually was greater than that in deeper intervals. The rate and direction of fluid movement under nonpumping conditions differs in the boreholes logged. In the northwest part of the site, no vertical flow was detected in three wells and very small amounts of flow were measured in two wells. In the southwest part of the site, downward flow was measured in two wells. Aquifer-isolation tests in three wells provided information on hydraulic heads and specific capacities in discrete vertical intervals and allowed collection of water samples form discrete water-bearing intervals. Natural annual fluctuations of water levels in 11 wells ranged form 11.4 to 28.3 feet. Seven of the 11 wells gave very similar water-level hydrographs. The four southernmost wells on the site show rises in water levels after precipitation much sooner than the other seven wells. Two other wells show daily fluctuations caused by pumping. A potentiometric-surface map of the site and vicinity was prepared from water-level measurements made in late July 1995. The map can be used to determine the approximate direction of ground-water flow.

Water-Resources Investigations Report↗

Hydrology of the cavernous limestones of the Mammoth Cave area, Kentucky

The Mammoth Cave National Park in central Kentucky offers a unique opportunity to study the occurrence of ground water in limestone under natural conditions. Ground water occurs as perched and semiperched bodies in alternate sandstone, shale, and limestone formations and under water-table conditions at the approximate level of the Green River in thick soluble limestone. Three continuous recorders that operated for 5 years indicate that precipitation on the Mammoth Cave plateau recharges the underlying sandstone rapidly. Ground water from the sandstone discharges horizontally to the edges of the plateau and vertically to underlying formations. Some of the precipitation recharges underlying formations almost immediately through overland flow to sinkholes and free fall through open shafts to pools at the water table. Much of the precipitation on the Pennyroyal plain flows overland into sinkholes and then through solution openings to the Green River. Water from the Green River flows into limestone solution channels under Mammoth Cave plateau at some stages, and this water discharges again to the Green River downstream. The presence of salt water, high in chloride in the Green River, makes it possible to trace the movement of the river water through the underground streams. Graphs show relationships of chloride concentration, stage of the Green River, time, precipitation, ground-water levels, and stratigraphy.

Water Supply Paper↗

Ground-water resources and simulated effects of withdrawals in the East Shore area of Great Salt Lake, Utah

The ground-water resources in the East Shore area of Great Salt Lake, Utah, were studied to better define the ground-water system; to document changes in ground-water levels, quality, and storage; and to simulate effects of an increase in ground-water withdrawals. The East Shore aquifer system is in basin-fill deposits, and is primarily a confined system with unconfined parts near the mountain front. Recharge to and discharge from the East Shore aquifer system were estimated to average about 160,000 acre-feet per year during 1969-84, with minor amounts of water being removed from storage during that period. Major sources of ground-water recharge are seepage from surface water in natural channels and irrigation canals, and subsurface inflow from consolidated rock to the basin-fill deposits. Discharge of ground water is primarily to wells, water courses, springs, and as diffuse seepage to Great Salt Lake. Average annual surface-water inflow to the study area was estimated to be 860,000 acre-feet for the period 1969-84. Annual withdrawal of ground water for municipal and industrial use increased from about 10,000 acre-feet in 1960 to more than 30,000 acre-feet in 1980 to supply a population that increased from 175,000 in 1960 to 290,000 in 1980. Long-term trends of ground-water levels indicate a steady decline at most observation wells since 1952, despite near normal or increased precipitation since the late 1960's. Water levels declined as much as 50 feet near the principal pumping center in the east-central part of the study area. They declined as much as 35 feet more than five miles from the pumping center. The increase in withdrawals and subsequent water-level declines have caused about 700 wells within 30 square miles to cease flowing since 1954. A numerical model of the East Shore aquifer system in the Weber Delta area was constructed and calibrated using water-level data and changes in ground-water withdrawals for 1955-85. Predictive simulations were made based on doubling the 1980-84 rate of municipal and industrial withdrawals for 20 years, and using both average and below-average recharge rates. The simulations indicated water-level declines of an additional 35 to 50 feet near the principal pumping center; a decrease in natural discharge to drains, evapotranspiration, and Great Salt Lake; and a decrease in ground-water storage of 80,000 to 115,000 acre-feet after 20 years.

Utah↗

Changes in the water supply in the Upper Republican Natural Resources District, Southwest Nebraska, from 1952-75

Use of ground water for irrigation has increased rapidly in the Upper Republican Natural Resources District in southwestern Nebraska in recent years. The principal aquifer being developed is composed of saturated sand and gravel of the Ogallala Formation of Tertiary age. Water-level declines of as much as 16 feet (4.9 metres) have occurred. Base flow of major streams draining the aquifer was reduced by as much as 19 percent between 1967 and 1975. Recoverable ground water in storage was reduced by about 1 percent. Net withdrawal of ground water in 1975 was about 250,000 acre-feet (308 million cubic metres), compared with an estimated recharge from precipitation of 176,000 acre-feet (217 million cubic metres). Water levels and streamflow will continue to decline if ground-water withdrawals continue at or greater than the 1975 rate.

Nebraska↗

Flood- and drought-related natural hazards activities of the U.S. Geological Survey in New England

The U.S. Geological Survey (USGS) has many ongoing and recent water-related natural hazard activities in New England that can be used to help mitigate the effects of natural hazards in cooperation with other agencies. The themes related to potential hazards and the tools and science to better understand and address them include the following: Erosion and landslides • Fluvial erosion (sediment transport, bridge scour, and bankfull channel geometry characterization) • Current and historic landslide mapping Flood documentation and assessment • Flood high-water marks • Flood modeling and frequency analysis • Flood inundation mapping • Peak-flow regression equations Drought documentation and assessment • Drought frequency analysis • Low-flow frequency and flow duration statistics • Water use and availability during drought Hydrologic monitoring • Streamflow monitoring network • Groundwater monitoring network • Tidal monitoring network • Snow surveys and ice jam monitoring Tools for natural hazard assessment and mitigation • Light detection and ranging (lidar) remote sensing technology • StreamStats Web-based tool for streamflow statistics • Flood inundation mapper

New England↗

Are mangroves in the tropical Atlantic ripe for invasion? Exotic mangrove trees in the forests of South Florida

Two species of mangrove trees of Indo-Pacific origin have naturalized in tropical Atlantic mangrove forests in South Florida after they were planted and nurtured in botanic gardens. Two Bruguiera gymnorrhiza trees that were planted in the intertidal zone in 1940 have given rise to a population of at least 86 trees growing interspersed with native mangrove species Rhizophora mangle , Avicennia germinans and Laguncularia racemosa along 100 m of shoreline; the population is expanding at a rate of 5.6% year −1 . Molecular genetic analyses confirm very low genetic diversity, as expected from a population founded by two individuals. The maximum number of alleles at any locus was three, and we measured reduced heterozygosity compared to native-range populations. Lumnitzera racemosa was introduced multiple times during the 1960s and 1970s, it has spread rapidly into a forest composed of native R. mangle , A. germinans , Laguncularia racemosa and Conocarpus erectus and now occupies 60,500 m 2 of mangrove forest with stem densities of 24,735 ha −1 . We estimate the population growth rate of Lumnitzera racemosa to be between 17 and 23% year −1 . Populations of both species of naturalized mangroves are dominated by young individuals. Given the long life and water-dispersed nature of propagules of the two exotic species, it is likely that they have spread beyond our survey area. We argue that the species-depauperate nature of tropical Atlantic mangrove forests and close taxonomic relatives in the more species-rich Indo-Pacific region result in the susceptibility of tropical Atlantic mangrove forests to invasion by Indo-Pacific mangrove species.

Florida↗

Magnitude and distribution of flows into northeastern Florida Bay

Changes in water-management practices have been made to accommodate a large and rapidly growing urban population along the Atlantic Coast and to meet the demand for intensive agricultural activities. These changes have resulted in a highly managed hydrologic system consisting of numerous canals, levees, control structures, and pumping stations that have altered the hydrology of the Everglades and Florida Bay ecosystems. Over the past decade, Florida Bay has experienced sea-grass die-off and algal blooms, which are indicators of ecological change attributed primarily to the increase in salinity and nutrient content of bay waters. Because plans are to restore sheetflow in the Everglades wetlands to its natural state, water managers anticipate a change in the magnitude and timing of freshwater exiting the mainland through the creeks that cut through the embankment or as sheetflow into Florida Bay.

Florida↗

Hydrogeology of the Cambrian-Ordovician aquifer system in the northern Midwest, United States with a section on ground-water quality

The Cambrian-Ordovician aquifer system contains the most extensive and continuous aquifers in the northern Midwest of the United States. It is the source of water for many municipalities, industries, and rural water users. Since the beginning of ground-water development from the aquifer system in the late 1800's, hydraulic heads have declined hundreds of feet in the heavily pumped Chicago-Milwaukee area and somewhat less in other metropolitan areas. The U.S. Geological Survey has completed a regional assessment of this aquifer system within a 161,000-square-mile area encompassing northern Illinois, northwestern Indiana, Iowa, southeastern Minnesota, northern Missouri, and Wisconsin. Consolidated sedimentary rocks in the northern Midwest range in age from Precambrian to Cretaceous and crop out in generally concentric, arcuate patterns, dipping away from structural highs (arches) on the Precambrian basement in northern Minnesota and Wisconsin toward structural lows (basins) to the south and east. The sedimentary bedrock is generally overlain by a veneer of glacial drift. Thickness of the sedimentary sequence increases to about 5,000 feet in the Forest City basin of southwestern Iowa and to about 14,000 and more than 15,000 feet in the Illinois and Michigan basins, respectively. Cambrian and Ordovician age rocks, mainly marine sandstone and carbonate rocks, compose much of the sedimentary sequence and form the Cambrian-Ordovician aquifer system. The aquifer system lies on the Precambrian basement, regarded as a regional confining unit. Six hydrogeologic units are defined; they are arranged as alternating pairs of an aquifer and an overlying confining. unit. The units are named using the predominant geologic nomenclature of the upper Mississippi Valley, which includes most of the study area. In the southern quarter of the area, the hydrogeologic units consist of equivalent formations of the Ozark area (mostly carbonate rocks). The uppermost part of the aquifer system is the Maquoketa confining unit, which consists of the Maquoketa Shale and the underlying dolomite and shale of the Galena Dolomite and the Decorah, Platteville, and Glenwood Formations. The underlying St. Peter-Prairie du Chien-Jordan aquifer is an important source of ground water in the western part of the area in Iowa and Minnesota, where the uniform Jordan Sandstone is hydraulically connected to overlying fractured dolomite of the Prairie du Chien Group. The unit is less important in the eastern part of Wisconsin and Illinois because the Jordan Sandstone is absent and the Prairie du Chien Group is thin or absent due to pre-St. Peter Sandstone erosion. Equivalent rocks in northern Missouri-the Roubidoux Formation and the Gasconade and Eminence Dolomites-are mainly carbonate rocks that are somewhat permeable and contain some sandstone. The St. Lawrence and Franconia Formations underlying the St. Peter-Prairie du Chien-Jordan aquifer consist generally of silty and shaly, fine-grained, poorly sorted, and dolomitic sandstones that restrict vertical movement of ground water and form a regional confining unit. In the southern and eastern parts of the area, the Potosi and Derby-Doerun Dolomites and the upper part of the Davis Formation are the equivalent rocks (mainly carbonate rocks). In the east-central part of the area in Illinois and Wisconsin, the Ironton-Galesville aquifer forms the most important aquifer of the Cambrian-Ordovician aquifer system, contributing about one-third of the yield from wells in the aquifer system in the Chicago area. The aquifer terminates to the west, south, and east, where the sandstones grade into less permeable carbonate rocks in central Iowa, central Illinois, and northwestern Indiana, respectively. The underlying Eau Claire Formation and its partial equivalent to the southwest, the Bonneterre Formation, form an important confining unit above the Mount Simon aquifer throughout much of the study area. Siltstone and shale are fairly common in the upper part of the Eau Claire Formation but less so in its northernmost extent in Wisconsin. Dolomite content increases southward and westward, where a middle dolomite facies grades laterally into the Bonneterre in Missouri, southwestern Minnesota, extreme south-central Wisconsin, and possibly in western Iowa. The basal unit in the Cambrian-Ordovician aquifer system, the Mount Simon aquifer, is present throughout the study area, except where it is absent over local highs of the Precambrian basement. It consists primarily of the Mount Simon Sandstone in the north and its equivalent in northern Missouri, the Lamotte Sandstone. The underlying Hinckley Sandstone of Precambrian age is included in Minnesota, as is the overlying Elmhurst Sandstone Member of the Eau Claire Formation in northern Illinois. The aquifer increases greatly in thickness and the water is progressively more saline away from the northern structural highs toward the basins. Much of the movement and discharge of ground water in the northern Midwest occurs in local, unconfined, shallow flow systems within a few miles of points of recharge. The rest of the water is semiconfined or confined in intermediate or regional flow systems within the bedrock, where flow is deeper, slower, and traverses much longer distances from recharge areas to discharge areas. The major areas of recharge to regional confined flow are in northwestern Iowa, southeastern Minnesota, western, southern, and eastern Wisconsin, and northern Illinois. Although the rate of flow is small, significant recharge to the Cambrian-Ordovician aquifer system also occurs as leakage through the Maquoketa confining unit, where the vertical hydraulic gradient is downward. Ground water in much of the confined aquifer system moves laterally from recharge areas toward the major river valleys and Lake Michigan or down dip toward the structural basins. The longest flow paths extend as much as 400 miles from northwestern Iowa southeast toward the Illinois basin or to the Mississippi River and Missouri River valleys near their confluence. Other major confined flow is from eastern Wisconsin toward the Michigan basin and southward flow from northeastern Illinois toward the Illinois basin. Regional ground-water discharge from the aquifer system is mainly diffuse upward leakage from confined aquifers along flow paths toward the structural basins. Very saline water around and brines within the basins restrict regional flow into the basins, forcing ground water to discharge upward. Water in intermediate flow systems discharges upward to the major river valleys. Original heads of more than 100 feet above land surface were recorded in the aquifer system near Lake Michigan in eastern Wisconsin and at Dubuque, Iowa, along the Mississippi River. The Cambrian-Ordovician aquifer system was developed rapidly in the late 1800's after the first deep well was drilled in Chicago in 1864. Many flowing wells were not controlled, which caused water levels in deep wells to decline, and many no longer flowed by the early 1900's. Heads in the aquifers have declined very little in most of the recharge or unconfined areas since ground-water withdrawal began, but major declines have occurred in confined areas. The largest declines in head are at Chicago, Illinois, Milwaukee and Green Bay, Wisconsin, and Mason City, Iowa, where the aquifer system is confined by the Maquoketa confining unit. The composite head in the aquifer system declined more than 900 feet in the deepest cones of depression in the Chicago area from 1864 to 1980 and about 375 feet in the cone at Milwaukee from 1880 to 1980. More than 200 feet of decline has occurred at Mason City. The head declined as much as 440 feet in Green Bay from 1886 to 1957, when the city discontinued use of its deep wells and began using water from Lake Michigan. The largest centers of pumping are in the Chicago and Twin Cities (Minneapolis-St. Paul, Minnesota) metropolitan areas about 180 million gallons per day each in 1980. Pumpage exceeded 10 million gallons per day in only a few other areas in 1980. Ground water in the Cambrian-Ordovician aquifer system in the northern Midwest is characterized by an extreme range of mineralization, but its quality in most of the area is good. The major cations are calcium, magnesium, and sodium, and the major anions are bicarbonate, sulfate, and chloride. Sodium, sulfate, and chloride distributions are closely related to the distribution pattern of dissolved solids but not in the same proportion. Dissolved-solids concentration is generally less than 1,000 milligrams per liter in the recharge areas of Wisconsin, southern Minnesota, northeastern Iowa, and north-central Illinois where the aquifer system crops out or subcrops beneath glacial drift. Ground water there is the Ca-Mg-HC03 type, derived from and identical to that in the overlying glacial drift. In northwestern Iowa and southwestern Minnesota, the water in both the glacial drift and the Cambrian-Ordovician aquifer system is a Ca-Na-S04HC03 type, derived from oxidation of pyrite in the overlying Cretaceous Dakota Formation. Transition to higher dissolved solids in the confined areas commonly is accompanied by increased sulfate concentration and· the occurrence of Ca-Na-S04-type water. Salinity of the ground water increases progressively toward the .basins, where dissolved solids exceed 200,000 milligrams per liter. Saline water is present in the Mount Simon aquifer near Lake Michigan in eastern Wisconsin and northeastern Illinois but occurs in successively younger rocks to the east and south as they dip toward the basins. Similarly, salinity increases down dip in Iowa to the southwest and south; however, regional ground-water flow in Iowa is from northwest to southeast. Much of the ground water in the confined aquifer system is isotopically depleted in 0180 and OD with respect to modern precipitation-an indication that the water originated as precipitation in a much colder climate than the present and probably was derived from recharge of glacial meltwater. On the basis of o34S values for sulfur in sulfate, it is believed that isostatic loading from glacial ice over the Michigan basin reversed the hydraulic gradient to trend westward, opposite from the present gradient, causing saline water in the Michigan basin to discharge westward through the present recharge areas. Natural water-quality problems in the Cambrian-Ordovician aquifer system are mainly the high dissolved-solids concentrations and associated high concentrations of sulfate and chloride, which limit the use of the water for municipal and domestic purposes in much of the confined aquifer system in central and southern Illinois, Indiana, southern and western Iowa, and northern Missouri. Another concern is that radium activity exceeds normal background concentrations of a few picocuries per liter in much of the confined aquifer system in eastern Wisconsin, northeastern Illinois, and central Iowa. Other common problems are high hardness and locally excessive concentrations of iron and hydrogen sulfide.

Iowa, Illinois, Indiana, Michigan, Minnesota, Miss↗

Application guide for AFINCH (Analysis of Flows in Networks of Channels) described by NHDPlus

AFINCH (Analysis of Flows in Networks of CHannels) is a computer application that can be used to generate a time series of monthly flows at stream segments (flowlines) and water yields for catchments defined in the National Hydrography Dataset Plus (NHDPlus) value-added attribute system. AFINCH provides a basis for integrating monthly flow data from streamgages, water-use data, monthly climatic data, and land-cover characteristics to estimate natural monthly water yields from catchments by user-defined regression equations. Images of monthly water yields for active streamgages are generated in AFINCH and provide a basis for detecting anomalies in water yields, which may be associated with undocumented flow diversions or augmentations. Water yields are multiplied by the drainage areas of the corresponding catchments to estimate monthly flows. Flows from catchments are accumulated downstream through the streamflow network described by the stream segments. For stream segments where streamgages are active, ratios of measured to accumulated flows are computed. These ratios are applied to upstream water yields to proportionally adjust estimated flows to match measured flows. Flow is conserved through the NHDPlus network. A time series of monthly flows can be generated for stream segments that average about 1-mile long, or monthly water yields from catchments that average about 1 square mile. Estimated monthly flows can be displayed within AFINCH, examined for nonstationarity, and tested for monotonic trends. Monthly flows also can be used to estimate flow-duration characteristics at stream segments. AFINCH generates output files of monthly flows and water yields that are compatible with ArcMap, a geographical information system analysis and display environment. Chloropleth maps of monthly water yield and flow can be generated and analyzed within ArcMap by joining NHDPlus data structures with AFINCH output. Matlab code for the AFINCH application is presented.

Scientific Investigations Report↗

Hydrogeology and Simulated Effects of Ground-Water Withdrawals in the Big River Area, Rhode Island

The Rhode Island Water Resources Board is considering expanded use of ground-water resources from the Big River area because increasing water demands in Rhode Island may exceed the capacity of current sources. This report describes the hydrology of the area and numerical simulation models that were used to examine effects of ground-water withdrawals during 1964?98 and to describe potential effects of different withdrawal scenarios in the area. The Big River study area covers 35.7 square miles (mi2) and includes three primary surface-water drainage basins?the Mishnock River Basin above Route 3, the Big River Basin, and the Carr River Basin, which is a tributary to the Big River. The principal aquifer (referred to as the surficial aquifer) in the study area, which is defined as the area of stratified deposits with a saturated thickness estimated to be 10 feet or greater, covers an area of 10.9 mi2. On average, an estimated 75 cubic feet per second (ft3/s) of water flows through the study area and about 70 ft3/s flows out of the area as streamflow in either the Big River (about 63 ft3/s) or the Mishnock River (about 7 ft3/s). Numerical simulation models are used to describe the hydrology of the area under simulated predevelopment conditions, conditions during 1964?98, and conditions that might occur in 14 hypothetical ground-water withdrawal scenarios with total ground-water withdrawal rates in the area that range from 2 to 11 million gallons per day. Streamflow depletion caused by these hypothetical ground-water withdrawals is calculated by comparison with simulated flows for the predevelopment conditions, which are identical to simulated conditions during the 1964?98 period but without withdrawals at public-supply wells and wastewater recharge. Interpretation of numerical simulation results indicates that the three basins in the study area are in fact a single ground-water resource. For example, the Carr River Basin above Capwell Mill Pond is naturally losing water to the Mishnock River Basin. Withdrawals in the Carr River Basin can deplete streamflows in the Mishnock River Basin. Withdrawals in the Mishnock River Basin deplete streamflows in the Big River Basin and can intercept water flowing to the Flat River Reservoir North of Hill Farm Road in Coventry, Rhode Island. Withdrawals in the Big River Basin can deplete streamflows in the western unnamed tributary to the Carr River, but do not deplete streamflows in the Mishnock River Basin or in the Carr River upstream of Capwell Mill Pond. Because withdrawals deplete streamflows in the study area, the total amount of ground water that may be withdrawn for public supply depends on the minimum allowable streamflow criterion that is applied for each basin.

Water-Resources Investigations Report↗

Use of double-mass curves to determine drawdown in a long-term aquifer test in north-central Volusia County, Florida

A test well withdrew water from the upper Floridan aquifer system at an average of 530 gallons per minute from June 1978 to July 1979. Ground-water levels were monitored in wells open to the upper Floridan (artesian) aquifer system and in wells open to the surficial (water-table) aquifer. Double-mass curves were used to separate drawdown from natural water-level fluctuations. Drawdowns in the Floridan were 4.3 feet at a site 350 feet away from the pumped well, 4.1 feet at a site 1,000 feet away, 1.0 foot at a site 1.0 mile away, and 0.4 foot at a site 5.8 miles away. After an initial drawdown of 0.2 foot at a surficial aquifer well 1,000 feet from the pumped well, there was some recovery, and long-term drawdown averaged less than 0.2 foot. In a five-day aquifer test during a period of no rainfall in 1976, the ratio of surficial aquifer drawdown to Floridan aquifer system drawdown reached equilibrum at 0.05. The results of the long-term test indicate that this ratio is the upper limit of long-term drawdown because of capture of evapotranspiration and runoff during the long-term test. (USGS)

Water-Resources Investigations Report↗

Potential contribution of microbial degradation to natural attenuation of MTBE in surface water systems

To evaluate the potential contribution of in situ biodegradation as a mechanism for natural attenuation of MTBE in surface water, surface water sediments were collected from streams and lakes at 11 sites throughout the US and the ability of the indigenous microorganisms to mineralize [U-14C] MTBE to 14CO2 under aerobic conditions was examined. Mineralization of [U-14C] MTBE to 14CO2 ranged from 15 to 66% over 50 days and did not differ significantly between sediments collected from MTBE contaminated sites and from sites with no history of MTBE exposure. The microorganisms, which inhabit the bed sediments of streams and lakes could degrade MTBE efficiently and this capability is widespread in the environment. Microbial degradation of [U-14C] MTBE was observed in surface-water-sediment microcosms under anaerobic conditions, but the efficiency and products of anaerobic MTBE biodegradation were strongly dependent on the predominant terminal electron accepting conditions. Microorganisms inhabiting the bed sediments of streams and lakes could degrade MTBE effectively under a range of anaerobic terminal electron accepting conditions. Thus, anaerobic bed sediment microbial processes also might contribute to natural attenuation of MTBE in surface water systems throughout the US.

Conference Paper↗

Pilot study of natural attenuation of arsenic in well water discharged to the Little River above Lake Thunderbird, Norman, Oklahoma, 2012

The City of Norman, Oklahoma, wanted to augment its water supplies to meet the needs of an increasing population. Among the city’s potential water sources are city wells that produce water that exceeds the 10 micrograms per liter primary drinking-water standard for arsenic. The City of Norman was interested in investigating low-cost means of using natural attenuation to remove arsenic from well water and augment the water supply of Lake Thunderbird, the primary water source for the city. The U.S. Geological Survey, in cooperation with the City of Norman, conducted a preliminary investigation (pilot study) to determine if discharge of water from those wells into the Little River over a 12-day period would reduce arsenic concentrations through natural-attenuation processes. Water in the Little River flows into Lake Thunderbird, the principal water source for the city, so the discharged well water would improve the water balance of that reservoir. During this pilot study, 150–250 gallons per minute from each of six city wells were discharged to the Little River over a 12-day period. Water-quality samples were collected from the wells during discharge and from the river before, during, and after well discharges. Streambed-sediment samples were collected at nine sites in the river before and after the well-discharge period. Water discharge from the six wells added 0.3 kilogram per day of arsenic to the river at the nearest downstream streamflow-gaging station. Dissolved arsenic concentration in the Little River at the closest downstream sampling site from the wells increased from about 4 micrograms per liter to as much as 24 micrograms per liter. Base flow in the river increased by about 1.7 cubic feet per second at the nearest downstream streamflow-gaging station. Streamflow in the river was two-thirds of that expected from the amount of water discharged from the wells because of seepage to soils and evapotranspiration of well water along drainage ways to the river. Arsenic concentrations at the nearest downstream streamflow-gaging station were less than arsenic concentrations measured in many of the well-water samples during the well-pumping period. Arsenic concentrations, loads, and yields in the Little River generally decreased downstream from the closest streamflow-gaging station to the wells by 50 percent or more, indicating removal of about 0.25 kilogram or 0.53 pound per day of arsenic during base-flow conditions. Measured river-water arsenic concentrations near the confluence of the Little River with Lake Thunderbird were in compliance with the primary drinking-water standard. Arsenic concentrations measured at four downstream stations in the Little River also were less than established criteria set for protection of aquatic biota. After well discharges to the Little River were stopped, arsenic concentrations, loads, and yields in the river gradually decreased over 14 days to concentrations measured prior to the well-water discharges. Cumulative loads of arsenic discharged at the wells and the closest and farthest downstream streamflow-gaging stations indicated removal of about 2.5 kilograms of arsenic as well-water flowed to and down the river. Arsenic concentrations in streambed-sediment samples collected before and after the well-water discharges were not significantly different. Results of this pilot study indicate that using natural-attenuation processes to remove arsenic from water and supplement city water supplies may be a viable, relatively low-cost method for attenuating arsenic in well water and for augmenting the water supply of Lake Thunderbird.

Oklahoma↗