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Transport of volatile organic compounds across the capillary fringe

Physical experiments were conducted to investigate the transport of a dissolved volatile organic compound (trichloroethylene, TCE) from shallow groundwater to the unsaturated zone under a variety of conditions including changes in the soil moisture profile and water table position. Experimental data indicated that at moderate groundwater velocities (0.1 m/d), vertical mechanical dispersion was negligible and molecular diffusion was the dominant vertical transport mechanism. Under these conditions, TCE concentrations decreased nearly 3 orders of magnitude across the capillary fringe and soil gas concentrations remained low relative to those of underlying groundwater. Data collected during a water table drop showed a short-term increase in concentrations throughout most of the unsaturated zone, but these concentrations quickly declined and approached initial values after the water table was returned to its original level. In the deep part of the unsaturated zone, the water table drop resulted in a long-term decrease in concentrations, illustrating the effects of hysteresis in the soil moisture profile. A two-dimensional random walk advection-diffusion model was developed to simulate the experimental conditions, and numerical simulations agreed well with experimental data. A simpler, one-dimensional finite-difference diffusion-dispersion model was also developed. One-dimensional simulations based on molecular diffusion also agreed well with experimental data. Simulations which incorporated mechanical dispersion tended to overestimate flux across the capillary fringe. Good agreement between the one- and two-dimensional models suggested that a simple, one-dimensional approximation of vertical transport across the capillary fringe can be useful when conditions are appropriate.

Water Resources Research↗

Selenium loading through the Blackfoot River watershed--linking sources to ecosystem

The upper Blackfoot River watershed in southeast Idaho receives drainage from 11 of 16 phosphate mines that have extracted ore from the Phosphoria Formation, three of which are presently active. Toxic effects from selenium (Se), including death of livestock and deformity in aquatic birds, were documented locally in areas where phosphatic shales are exposed ( Piper et al., 2000 ; Presser et al., Chapter 11). Current drainage conditions are leading to Se bioaccumulation at concentrations that pose a risk to fish in the Blackfoot River and its tributaries (Hamilton et al., Chapter 18). A gaging station on the Blackfoot River was re-activated in April 2001 to assess hydrologic conditions and concentration, load, and speciation for Se discharges on a watershed scale. The gaging-station data are considered to represent regional drainage conditions in the upper Blackfoot River water- shed because of its location near the outlet of the watershed and directly upstream of the Blackfoot Reservoir. Watershed discharges for 2001 and 2002 were below minimum hydrologic conditions for the gage as documented by the historical record. Drought emergencies were declared in the area in both 2001 and 2002. Unmonitored diversions for irrigation that routinely take place during the snowmelt season also affected conditions downstream. Annual cycles in Se concentration, load, and selenate (Se 6+ ) reached maxima in the spring during the period of maximum flow at the gaging station. Thirty-seven to 44% of annual flow occurred dur- ing the three-month high-flow season (April through June) in 2001 and 56% of annual flow occurred during that time period in 2002. Extrapolation from historical hydrographs for average and wet years and a limited data set of regional Se concentrations for 2001 and 2002 indicated potential for a 3.6- to 7.4-fold increase in Se loading because of increased seasonal flows in the Blackfoot River watershed. Supplementation data indicate that: (a) the difference between total Se and dissolved Se, as a measure of the contribution of particulate Se, was < 10% except at the peak of con- centration when total Se was 18% more than dissolved Se; (b) selenite (Se 4+ ) represented less than 10% of the dissolved species during all months of 2001; and (c) dissolved Se was approximately a 50:50 mixture of selenate and organic selenide (operationally defined Se 2- ) during summer 2001 (June through August). Ecological risk based on regional Se drainage occurred during both the high- and low-flow seasons. Seventy to 83% of the Se load occurred during the high-flow season. During early May of both years, dissolved-Se concentrations exceeded the criterion for the protection of aquatic life and the ecological threshold of 5 gL 1 Se at which sub- stantive risk occurs. During the majority of the three-month high-flow season, dissolved- Se concentrations exceeded the 2 gL 1 Se concern level for aquatic biota. The Se concentration in suspended material during high flow in 2002 was within the range of marginal risk to aquatic life (2-4 gg 1 Se, dry weight). Selenate was the major species during peak flows, with both selenate and organic selenide being major species during relatively low-flow periods in summer. A change in speciation to reduced Se may indicate elevated biotic productivity during summer months and could result in enhanced Se uptake in food webs. In addition to the magnitude of regional Se release in the Blackfoot River watershed, Se concentrations in individual source drains and waste-rock seeps, and those predicted by experimental column leaching of proposed mining overburden materials, also indicate that drainage options that currently meet existing demands for phosphate mining cause eco- logical risk thresholds to be exceeded. At times, the drinking-water Se standard (50 g L 1 Se) and the criterion for hazardous Se waste (1000 L -1 Se) ( US Department of the Interior, 1998 ; US Environmental Protection Agency, 1987 ) are also exceeded. For water-years 2001 and 2002, seasonal increased input of water in the mining area resulted in increased Se transport, suggesting a mechanism of contamination that involves a significant Se reservoir. Hence, recognition and monitoring of Se loading to the envi- ronment on a mass balance basis (i.e. inputs, fluxes and storage within environmental media, and outputs) are essential to evaluating how to control Se concentrations within environmentally protective ranges ( Presser and Piper, 1998 ). In areas where release of Se to aquatic systems is anticipated as a product of future expansion of phosphate mining, continuous monitoring of flow and development of seasonal Se loading patterns would help to model watersheds in terms of sources, flow periods, and environmental-Se con- centrations that most influence bioavailability. These data, in turn, could be linked to Se- bioaccumulation models specific to food webs and vulnerable species of the impacted areas to accurately project ecological effects. Gaging at this site on the Blackfoot River is planned to continue in order to establish a long-term (>10 year) record of hydrologic conditions.

Idaho↗

Evaluation of management practices in wetland meadows at Grays Lake National Wildlife Refuge, Idaho, 1997-2000

We assessed the relative values of 4 management practices (idle, late season grazing, fall prescribed burning, and rotation of idle and summer grazing) to biotic resources of the grassland-wetland meadow ecosystem at Grays Lake during 1997-2000. Three replicates of each treatment were randomly assigned to 12 experimental units that bordered the deep emergent marsh. Biotic factors examined included the breeding bird community and abundance, nesting activity and nest success, small mammal abundance, plant community, and annual plant biomass production. Fall burns achieved treatment objectives, removing most residual vegetation across a range of cover types. Objectives for grazing treatments were mostly attained; however, vegetation use levels were insufficient for consistent attainment of treatment objectives. Savannah sparrow, American coot, Canada goose, sandhill crane, mallard, and yellow-headed blackbird were the most common bird species present. Densities of 2 bird species (savannah sparrow and red-winged blackbird) were related to year effect only. The effect of unit on densities of redhead, lesser scaup, ruddy duck, sora, long-billed curlew, and common snipe likely reflects habitat differences among units. Densities of 6 species (eared grebe, canvasback, American coot, American avocet, willet, and common yellowthroat) were related to both year and unit effects. Treatment affected densities of 6 of the 29 species examined (mallard, northern shoveler, cinnamon teal, blue-winged teal, American crow, and yellow-headed blackbird); we found no common trend in response to treatments among those species. Overall, idled habitat did not stand out to be a valuable treatment, whereas grazing tended to have positive responses for a number of species. Burning was more likely to result in reduced bird densities than other treatments. We also describe the distribution of species observations among 8 different habitat types. Of the 23 nesting species sampled in the experimental units, the most common were American coot, sandhill crane, Canada goose, American avocet, mallard, and cinnamon teal. Daily survival rates (DSRs) of dabbling duck nests (all species pooled) were negatively affected by fall grazing. We detected no effects of treatments on DSRs of Canada geese or sandhill crane nests. DSRs for sandhill crane nests were higher in 1998 than in 1999 or 2000 and were slightly higher than that in 1997. DSRs for coot nests were affected by both year and treatment; within-treatment differences among years were extensive, In 1998, when all units were idled, DSRs for coot nests were higher in units assigned to idle treatment than those assigned to fall-grazed or rotation treatment. DSRs for coot nests did not differ among treatment blocks in 1997 (all units idled) or 1999 (first year after treatments). We speculate that compaction of residual vegetation by snowpack reduced any differences between idle and treated units and thus lessened the value of idle habitat for most nesting birds. Nesting densities and nest success rates of Canada geese, dabbling ducks, and sandhill cranes were lower those that reported from Steel's (1952) study in 1949-1950, but differences in habitats and areas searched relative to our study make comparisons difficult. Nest success rates of sandhill cranes also were lower than those reported by Drewien (1973). Declines in nest success probably are related to changes in predator community. We captured 5 species of small mammals (meadow vole, montane vole, deer mouse, vagrant shrew, and ermine). Populations of meadow and montane voles irrupted in 1998 then crashed in spring 1999; the most marked changes were in montane vole numbers. Capture rates of ermine and observation rates for striped skunks and raptors suggested a numerical response (higher recruitment) by these predators to higher prey abundance and possibly distributional shifts (movement into areas of more abundant microtines). We did not detect differences

Report↗

Experimentally determined solidi in the Ca-bearing granite system NaAlSi3O8-CaAl2Si2O8-KAlSi3O8-SiO2-H2O-CO2

The phase relationships of melting of synthetic granite in the presence of an H2O-CO2 fluid were determined. These results provide constraints on the maximum temperatures of regional metamorphism attainable in vapor-saturated metapelitic and quartzofeldspathic rocks that escaped widespread melting. At pressures below 10 kbar, a fluid phase of XH2O = 0.75, 0.5, and 0.25 limits temperatures to below ~700-725, ~800-825, and ~850-875??C, respectively. As a consequence, the formation of granulite does not require CO2 concentrations in a coexisting fluid to exceed an XCO2 of 0.25-0.5. -from Authors

American Mineralogist↗

Warming and increased precipitation frequency on the Colorado Plateau: Implications for biological soil crusts and soil processes

Aims Changes in temperature and precipitation are expected to influence ecosystem processes worldwide. Despite their globally large extent, few studies to date have examined the effects of climate change in desert ecosystems, where biological soil crusts are key nutrient cycling components. The goal of this work was to assess how increased temperature and frequency of summertime precipitation affect the contributions of crust organisms to soil processes. Methods With a combination of experimental 2°C warming and altered summer precipitation frequency applied over 2 years, we measured soil nutrient cycling and the structure and function of crust communities. Results We saw no change in crust cover, composition, or other measures of crust function in response to 2°C warming and no effects on any measure of soil chemistry. In contrast, crust cover and function responded to increased frequency of summer precipitation, shifting from moss to cyanobacteria-dominated crusts; however, in the short timeframe we measured, there was no accompanying change in soil chemistry. Total bacterial and fungal biomass was also reduced in watered plots, while the activity of two enzymes increased, indicating a functional change in the microbial community. Conclusions Taken together, our results highlight the limited effects of warming alone on biological soil crust communities and soil chemistry, but demonstrate the substantially larger effects of altered summertime precipitation.

Plant and Soil↗

Managed flood effects on beaver pond habitat in a desert riverine ecosystem, bill williams river, Arizona USA

The ecological effects of beaver in warm-desert streams are poorly documented, but potentially significant. For example, stream water and sediment budgets may be affected by increased evaporative losses and sediment retention in beaver ponds. We measured physical attributes of beaver pond and adjacent lotic habitats on a regulated Sonoran Desert stream, the Bill Williams River, after ???11 flood-free months in Spring 2007 and Spring 2008. Neither a predicted warming of surface water as it passed through a pond nor a reduction in dissolved oxygen in ponds was consistently observed, but bed sediment sorted to finest in ponds as expected. We observed a river segment-scale downstream rise in daily minimum stream temperature that may have been influenced by the series of ??100 beaver ponds present. Channel cross-sections surveyed before and after an experimental flood (peak flow 65 m3/s) showed net aggradation on nine of 13 cross-sections through ponds and three of seven through lotic reaches. Our results indicate that beaver affect riverine processes in warm deserts much as they do in other biomes. However, effects may be magnified in deserts through the potential for beaver to alter the stream thermal regime and water budget. ?? Society of Wetland Scientists 2011.

Wetlands↗

Solubility measurements in the system CaSO4-NaCL-H2O at 35°, 50°, and 70°cand one atmosphere pressure

The solubilities in the system CaSO 4 - NaCl -H 2 O, at 1 atm pressure and 35° , 50° , and 70°C, have been determined by approaching the solubility curves from both the undersaturation and supersaturation sides. The experimental runs are of long duration, as much as 3 months; these rates should be commensurate with those of the appropriate geological processes, and so the results should be directly applicable to the interpretation of evaporite deposits.

Journal of Petrology↗

Relation of inversely graded deposits to suspended-sediment grain-size evolution during the 1996 flood experiment in Grand Canyon

Before Glen Canyon Dam was completed upstream from Grand Canyon, floods scoured sand from the channel bed and deposited sand on bars within recirculating eddies. After completion of Glen Canyon Dam in 1963, peak discharge of the mean annual floods dropped front about 2600 to 900 m3/s, and 85% of the sediment supply was eliminated. Under the postdam flow regime, sand bars in eddies have degraded. In an experiment to study, in part, the effects of floods in rebuilding these bars, a controlled flood was released from Glen Canyon Dam in late March and early April 1996. Although fluvial sequences characteristically fine upward, the deposits of the experimental flood systematically coarsen upward. Measurements of suspended-sediment concentration and grain size and of bed-material grain size suggest that the upward coarsening results from the channel becoming relatively depleted of fine-grained sediment during the seven days of the high-flow experiment. Predam flood beds of the Colorado River also coarsen upward, indicating that supply-limitation and grain-size evolution are natural processes that do not require the presence of a dam.

Geology↗

Evolution of fluid transmissivity and strength recovery of shear fractures under hydrothermal conditions

Geothermal systems rely on the presence of long-lived and high-volume, permeable fracture systems. The creation, reactivation, and sustainability of these systems depend on complex coupling among thermal, hydraulic, mechanical, and chemical (THMC) processes occurring in geothermal reservoirs. In part due to a paucity of experimental data, the evolution of fractures at geothermal conditions in response to THMC processes is poorly understood, particularly during the process of shear. We present preliminary results of triaxial slide-hold-slide experiments, with hold periods ranging in duration from 103 s to 106 s, to constrain rates and mechanisms of healing and sealing. Experiments were conducted on simulated fault gouge composed of Westerly granite and on bare surfaces of Westerly granite. The tests were run at temperatures of 22˚ and 200˚C with confining and average pore pressures of 30 MPa and 10 MPa, respectively. We used an axial displacement rate of 0.1 μm/s during sliding periods. Deionized water was continuously flowed along the simulated fracture so we could determine in-plane transmissivity during the tests. In gouge and bare surface experiments conducted at 200˚C, we observe significant decreases in transmissivity over the course of the experiments. For the hydrothermal gouge experiment we measured an order of magnitude net reduction in transmissivity from 1.73x10-18 to 0.17x10-18 m3, over the course of 220 hours while in the room temperature gouge experiment transmissivity only decreased by 0.35x10-18 m3 over the same amount of time. In the experiments, we observe an up to 16% recovery in transmissivity during sliding periods. At room temperature the friction data showed limited fault re-strengthening with time; healing rates are on the order of 0.1 MPa/decade. A similar healing rate was observed at 200˚C in the gouge but we observe an increase in the healing rate, to 0.75 MPa/decade, for a bare surface experiment at 200˚C. The differences in the healing rate of the gouge and bare surface experiments suggest that the generation of fine particles by grinding down of asperities on the bare surface promote quartz dissolution and reprecipitation at elevated temperatures. Further work is needed to test this possibility and provide better constraints on factors influencing the evolution of fluid transport properties and strength of shear fractures at geothermal conditions.

Conference Paper↗

Susceptibility of Pallid Sturgeon to viral hemorrhagic septicemia virus genotype IVb

Objective Viral hemorrhagic septicemia virus (VHSV) is an aquatic rhabdovirus causing severe disease in freshwater and saltwater fish species. The susceptibility of endangered Pallid Sturgeon Scaphirhynchus albus to VHSV genotype IVb (VHSV-IVb) infection was investigated. Methods An in vitro assessment using two Pallid Sturgeon cell lines derived from skin and spleen tissue and in vivo evaluation of juvenile Pallid Sturgeon after exposure to VHSV-IVb were performed. Result Plaque assay and RT-PCR results confirmed VHSV-IVb replication in Pallid Sturgeon cell lines. Sturgeon were also susceptible to VHSV-IVb infection after immersion and injection exposures during laboratory experiments. However, after widespread mortality occurred in all treatment groups, including negative control fish, it was determined that the Pallid Sturgeon stock fish were infected with Missouri River sturgeon iridovirus (MRSIV) prior to experimental challenge. Nevertheless, mortalities were equal or higher among VHSV-exposed fish than among negative controls (MRSIV infected), and histopathological assessments indicated reduced hematopoietic cells in spleen and kidney tissues and hemorrhage in the gastrointestinal organs only in fish from the VHSV treatment. Conclusion These results indicate that Pallid Sturgeon is a susceptible host for VHSV-IVb, but the degree of pathogenicity was confounded by the underlying MRSIV infection. Research comparing susceptibility of specific pathogen-free and MRSIV-infected fish to VHSV-IVb is needed to accurately assess the vulnerability of Pallid Sturgeon to VHSV-IVb.

Journal of Aquatic Animal Health↗

Shading decreases the abundance of the herbivorous California horn snail, Cerithidea californica

Most of the intertidal zone in estuaries of California, USA and Baja California, Mexico is covered with vascular vegetation. Shading by these vascular plants influences abiotic and biotic processes that shape benthic community assemblages. We present data on the effects of shading on the California horn snail, Cerithidea californica . This species is important because it is the most common benthic macrofaunal species in these systems and acts as an obligate intermediate host of several species of rematode parasites that infect several other species. Using observational and experimental studies, we found a negative effect of shade on the distribution and abundance of the California horn snail. We hypothesized that shading reduces the abundance of the epipelic diatoms that the snails feeds on, causing snails to leave haded areas. We observed a negative relationship between vascular plant cover, sub-canopy light levels, and snail density in Mugu Lagoon. Then we experimentally manipulated light regimes, by clipping vegetation and adding shade structures, and found higher snail densities at higher light levels. In Goleta Slough, we isolated the effect of shade from vegetation by documenting a negative relationship between the shade created by two bridges and diatom and snail densities. We also found that snails moved the greatest distances over shaded channel banks compared to unshaded channel banks. Further, we documented the effect of water depth and channel bank orientation on shading in this system. An additional effect of shading is the reduction of temperature, providing an alternative explanation for some of our results. These results broaden our knowledge of how variation in the light environment influences the ecology of estuarine ecosystems.

California↗

Experimental evaluation of factors affecting temporal variability of water samples obtained from long-screened wells

As a well is pumped through time, concentrations of specific constituents in the water discharging from the well may change as a result of their transport within the well and the aquifer. A series of experiments conducted at a research site on Cape Cod, Massachusetts, examined the effects of transport on the chemistry of water samples obtained from a long-screened well. Analyses of time series of constituent concentrations in water pumped from the long-screened well showed persistent temporal trends during the first experiment. Iron concentrations decreased over a five-hour test (15 casing volumes), whereas the calcium and magnesium concentrations increased. In contrast, the time series of constituent concentrations of water discharging from the same well showed less change with time during a later experiment. Numerical simulations were undertaken to test the relative importance of several possible factors affecting the temporal variations of these constituents. During the process of quantitatively explaining the changes in concentrations over time observed in the two experiments, different system conceptualizations were used, including (1) flow and transport in the aquifer without wellbore transport, (2) flow and transport in the aquifer with advective flow and transport in the wellbore, and (3) flow and transport in the aquifer with advective flow and transport in the wellbore and a thin layer (skin) of water surrounding the well with constituent concentrations that had been altered by the presence of the well. The conjectured skin of wellbore water, which could have invaded the aquifer because of nearby sampling or dispersion and diffusion near the wellbore, in conjunction with flow and transport in the aquifer and advective transport within the wellbore, produced a reasonable match between the simulated and observed concentrations. The data analysis confirms the known fact that long-screened wells provide mechanisms for the redistribution of chemical constituents in the aquifer. The analysis provides new insight into the mechanisms responsible for the observed changes in concentrations during the sampling of long-screened wells. The analysis quantifies the effects of the various conceptual models of flow and transport in and around wells on the interpretation and meaning of chemical analyses of water withdrawn from long-screened wells.A series of experiments was conducted at a research site on Cape Cod, Massachusetts, to examine the effects of transport on the chemistry of water samples obtained from a long-screened well. A time-series analysis of the constituents concentration in pumped water revealed a persistent temporal trend during the first experiment. Iron concentrations decreased over a five-hour test, while calcium and magnesium concentrations increased. Numerical simulations were undertaken to test the relative importance of several possible factors affecting the temporal variations of the constituents to quantify the effects of the various conceptual models of flow and transport in and around the wells.

Ground Water↗

Effects of turbidity, light level, and cover on predation of white sturgeon larvae by prickly sculpins

White sturgeon Acipenser transmontanus occur in rivers of the western United States and southwestern Canada, but some populations are in decline because of recruitment failure. Many river systems in this area have been altered as a result of development that has caused major environmental changes. Our goal was to examine how three changes - lower turbidity levels, higher light levels, and altered substrates - might affect predation by prickly sculpin Cottus asper on white sturgeon larvae. We experimentally investigated predation at various turbidity levels and found that significantly more white sturgeon yolk sac larvae were eaten at lower turbidity levels. The effects of light level (1-4 and 7-15 1x), the presence or absence of rocks as cover, and prey size (14-17 mm and 20-24 mm total length) on the outcome of predator-prey interactions were also examined. Significantly fewer white sturgeon were eaten during trials that combined the lowest light level, cover, and the smallest larvae. Our results suggest that altered river conditions caused by impoundment and other factors have increased predation on white sturgeon larvae. ?? Copyright by the American Fisheries Society 2005.

Transactions of the American Fisheries Society↗

Effects of earthworms on slopewash, surface runoff, and fine-litter transport on a humid-tropical forested hillslope in eastern Puerto Rico: Chapter G in Water quality and landscape processes of four watersheds in eastern Puerto Rico

Rainfall, slopewash (the erosion of soil particles), surface runoff, and fine-litter transport were measured in tropical wet forest on a hillslope in the Luquillo Experimental Forest, Puerto Rico, from February 1998 until April 2000. Slopewash data were collected using Gerlach troughs at eight plots, each 2 square meters in area. Earthworms were excluded by electroshocking from four randomly selected plots. The other four (control) plots were undisturbed. During the experiment, earthworm population in the electroshocked plots was reduced by 91 percent. At the end of the experiment, the electroshocked plots had 13 percent of earthworms by count and 6 percent by biomass as compared with the control plots. Rainfall during the sampling period (793 days) was 9,143 millimeters. Mean and maximum rainfall by sampling period (mean of 16 days) were 189 and 563 millimeters, respectively. Surface runoff averaged 0.6 millimeters and 1.2 millimeters by sampling period for the control and experimental plots, equal to 0.25 and 0.48 percent of mean rainfall, respectively. Disturbance of the soil environment by removal of earthworms doubled runoff and increased the transport (erosion) of soil and organic material by a factor of 4.4. When earthworms were removed, the erosion of mineral soil (soil mass left after ashing) and the transport of fine litter were increased by a factor of 5.3 and 3.4, respectively. It is assumed that increased runoff is a function of reduced soil porosity, resulting from decreased burrowing and reworking of the soil in the absence of earthworms. The background, or undisturbed, downslope transport of soil, as determined from the control plots, was 51 kilograms per hectare and the "disturbance" rate, determined from the experimental plots, was 261 kilograms per hectare. The background rate for downslope transport of fine litter was 71 kilograms per hectare and the disturbance rate was 246 kilograms per hectare. Data from this study indicate that the reduction in soil macrofauna population, in this case, earthworms, plays a key role in increasing runoff and soil erosion and, therefore, has important implications for forest and water management.

Luquillo Experimental Forest↗

Field measurement of basal forces generated by erosive debris flows

It has been proposed that debris flows cut bedrock valleys in steeplands worldwide, but field measurements needed to constrain mechanistic models of this process remain sparse due to the difficulty of instrumenting natural flows. Here we present and analyze measurements made using an automated sensor network, erosion bolts, and a 15.24 cm by 15.24 cm force plate installed in the bedrock channel floor of a steep catchment. These measurements allow us to quantify the distribution of basal forces from natural debris‒flow events that incised bedrock. Over the 4 year monitoring period, 11 debris‒flow events scoured the bedrock channel floor. No clear water flows were observed. Measurements of erosion bolts at the beginning and end of the study indicated that the bedrock channel floor was lowered by 36 to 64 mm. The basal force during these erosive debris‒flow events had a large‒magnitude (up to 21 kN, which was approximately 50 times larger than the concurrent time‒averaged mean force), high‒frequency (greater than 1 Hz) fluctuating component. We interpret these fluctuations as flow particles impacting the bed. The resulting variability in force magnitude increased linearly with the time‒averaged mean basal force. Probability density functions of basal normal forces were consistent with a generalized Pareto distribution, rather than the exponential distribution that is commonly found in experimental and simulated monodispersed granular flows and which has a lower probability of large forces. When the bed sediment thickness covering the force plate was greater than ~ 20 times the median bed sediment grain size, no significant fluctuations about the time‒averaged mean force were measured, indicating that a thin layer of sediment (~ 5 cm in the monitored cases) can effectively shield the subjacent bed from erosive impacts. Coarse‒grained granular surges and water‒rich, intersurge flow had very similar basal force distributions despite differences in appearance and bulk‒flow density. These results demonstrate that debris flows can have strong control on rates of steepland evolution and contribute to a foundation needed for modeling debris‒flow incision stochastically.

Journal of Geophysical Research F: Earth Surface↗

Temperature profile around a basaltic sill intruded into wet sediments

The transfer of heat into wet sediments from magmatic intrusions or lava flows is not well constrained from field data. Such field constraints on numerical models of heat transfer could significantly improve our understanding of water&ndash;lava interactions. We use experimentally calibrated pollen darkening to measure the temperature profile around a basaltic sill emplaced into wet lakebed sediments. It is well known that, upon heating, initially transparent palynomorphs darken progressively through golden, brown, and black shades before being destroyed; however, this approach to measuring temperature has not been applied to volcanological questions. We collected sediment samples from established Miocene fossil localities at Clarkia, Idaho. Fossils in the sediments include pollen from numerous tree and shrub species. We experimentally calibrated changes in the color of Clarkia sediment pollen and used this calibration to determine sediment temperatures around a Miocene basaltic sill emplaced in the sediments. Results indicated a flat temperature profile above and below the sill, with T > 325 &deg;C within 1 cm of the basalt-sediment contact, near 300 &deg;C at 1&ndash;2 cm from the contact, and ~ 250 &deg;C at 1 m from the sill contact. This profile suggests that heat transport in the sediments was hydrothermally rather than conductively controlled. This information will be used to test numerical models of heat transfer in wet sediments on Earth and Mars.

Journal of Volcanology and Geothermal Research↗

In‐stream sorption of fulvic acid in an acidic stream: A stream‐scale transport experiment

The variation of concentration and composition of dissolved organic carbon (DOC) in stream waters cannot be explained solely on the basis of soil processes in contributing subcatchments. To investigate in‐stream processes that control DOC, we injected DOC‐enriched water into a reach of the Snake River (Summit County, Colorado) that has abundant iron oxyhydroxides coating the streambed. The injected water was obtained from the Suwannee River (Georgia), which is highly enriched in fulvic acid. The fulvic acid from this water is the standard reference for aquatic fulvic acid for the International Humic Substances Society and has been well characterized. During the experimental injection, significant removal of sorbable fulvic acid occurred within the first 141 m of stream reach. We coinjected a conservative tracer (lithium chloride) and analyzed the results with the one‐dimensional transport with inflow and storage (OTIS) stream solute transport model to quantify the physical transport mechanisms. The downstream transport of fulvic acid as indicated by absorbance was then simulated using OTIS with a first‐order kinetic sorption rate constant applied to the sorbable fulvic acid. The “sorbable” fraction of injected fulvic acid was irreversibly sorbed by streambed sediments at rates (kinetic rate constants) of the order of 10 −4 –10 −3 s −1 . In the injected Suwannee River water, sorbable and nonsorbable fulvic acid had distinct chemical characteristics identified in 13 C‐NMR spectra. The 13 C‐NMR spectra indicate that during the experiment, the sorbable “signal” of greater aromaticity and carboxyl content decreased downstream; that is, these components were preferentially removed. This study illustrates that interactions between the water and the reactive surfaces will modify significantly the concentration and composition of DOC observed in streams with abundant chemically reactive surfaces on the streambed and in the hyporheic zone.

Water Resources Research↗

Brood size affects future reproduction in a long-lived bird with precocial young

Estimation of trade-offs between current reproduction and future survival and fecundity of long-lived vertebrates is essential to understanding factors that shape optimal reproductive investment. Black brant geese (Branta bernicla nigricans) fledge more goslings, on average, when their broods are experimentally enlarged to be greater than the most common clutch size of four eggs. Thus, we hypothesized that the lesser frequency of brant clutches exceeding four eggs results, at least partially, from a future reduction in survival, breeding probability, or clutch size for females tending larger broods. We used an eight-year mark-recapture dataset (Barker robust design) with five years of clutch and brood manipulations to estimate long-term consequences of reproductive decisions in brant. We did not find evidence of a trade-off between reproductive effort and true survival or future initiation date and clutch size. Rather, future breeding probability was maximized (0.92 ± 0.03 [se]) for manipulated females tending broods of four goslings and lower for females tending smaller (one gosling; 0.63 ± 0.09 [se]) or larger broods (seven goslings; 0.52 ± 0.15 [se]). Our results suggest that demographic trade-offs for female brant tending large broods may reduce the fitness value of clutches larger than four and, therefore, contribute to the paucity of larger clutches. The lack of a trade-off between reproductive effort and survival provides evidence that survival, to which fitness is most sensitive in long-lived animals, is buffered against temporal variation in brant.

American Naturalist↗