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At least 541 records · Page 30Linked to original sources
USGS2006

Environmental Setting of the Lower Merced River Basin, California

In 1991, the U.S. Geological Survey began to study the effects of natural and anthropogenic influences on the quality of ground water, surface water, biology, and ecology as part of the National Water-Quality Assessment (NAWQA) Program. As part of this program, the San Joaquin-Tulare Basins study unit is assessing parts of the lower Merced River Basin, California. This report provides descriptions of natural and anthropogenic features of this basin as background information to assess the influence of these and other factors on water quality. The lower Merced River Basin, which encompasses the Mustang Creek Subbasin, gently slopes from the northeast to the southwest toward the San Joaquin River. The arid to semiarid climate is characterized by hot summers (highs of mid 90 degrees Fahrenheit) and mild winters (lows of mid 30 degrees Fahrenheit). Annual precipitation is highly variable, with long periods of drought and above normal precipitation. Population is estimated at about 39,230 for 2000. The watershed is predominately agricultural on the valley floor. Approximately 2.2 million pounds active ingredient of pesticides and an estimated 17.6 million pounds active ingredient of nitrogen and phosphorus fertilizer is applied annually to the agricultural land.

Scientific Investigations Report↗
USGS2012

The occurrence of trace elements in bed sediment collected from areas of varying land use and potential effects on stream macroinvertebrates in the conterminous western United States, Alaska, and Hawaii, 1992-2000

As part of the National Water-Quality Assessment Program of the U.S. Geological Survey, this study examines the occurrence of nine trace elements in bed sediment of varying mineralogy and land use and assesses the possible effects of these trace elements on aquatic-macroinvertebrate community structure. Samples of bed sediment and macroinvertebrates were collected from 154 streams at sites representative of undeveloped, agricultural, urban, mined, or mixed land-use areas and 12 intermediate-scale ecoregions within the conterminous western United States, Alaska, and Hawaii from 1992 to 2000. The nine trace elements evaluated during this study—arsenic (As), cadmium (Cd), chromium (Cr), copper (Cu), lead (Pb), mercury (Hg), nickel (Ni), selenium (Se), and zinc (Zn)—were selected on the basis of potential ecologic significance and availability of sediment-quality guidelines. At most sites, the occurrence of these trace elements in bed sediment was at concentrations consistent with natural geochemical abundance, and the lowest concentrations were in bed-sediment samples collected from streams in undeveloped and agricultural areas. With the exception of Zn at sampling sites influenced by historic mining-related activities, median concentrations of all nine trace elements in bed sediment collected from sites representative of the five general land-use areas were below concentrations predicted to be harmful to aquatic macroinvertebrates. The highest concentrations of As, Cd, Pb, and Zn were in bed sediment collected from mined areas. Median concentrations of Cu and Ni in bed sediment were similarly enriched in areas of mining, urban, and mixed land use. Concentrations of Cr and Ni appear to originate largely from geologic sources, especially in the western coastal states (California, Oregon, and Washington), Alaska, and Hawaii. In these areas, naturally high concentrations of Cr and Ni can exceed concentrations that may adversely affect aquatic macroinvertebrates. Generally, Hg concentrations were below the sediment-quality guideline for this trace element but appeared elevated in urbanized areas and at sites contaminated by historic mining practices. Lastly, although there was no distinctive pattern in Se concentrations with land use, median bed-sediment concentrations were slightly elevated in urbanized areas. Macroinvertebrate community structure was influenced by topographic, geologic, climatic, and in-stream characteristics. To account for inherent distribution patterns resulting from these influences, samples of macroinvertebrates were stratified by ecoregion to assess the influence of trace elements on community structure. Cumulative toxic units (CTUs) were used to evaluate gradients in trace-element concentrations in mixture. Correlation analyses among the trace elements under different land-use conditions indicate that trace-element mixtures vary among bed sediment and can have a marked influence on CTU composition. Macroinvertebrate response to bed-sediment trace-element exposure was evident only at the most highly contaminated sites, notably at sites classified as contaminated by the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) as a result of historic mining activities. Results of this study agree with the findings of other studies evaluating trace-element exposure to in-stream macroinvertebrate community structure in that generally lower richness metrics and taxa dominance occur in streams where high trace-element enrichment occurs; however, not all streams in all areas have the same characterizing taxa. In the mountain and xeric ecosystems, the mayfly, Baetis sp.; the Diptera, Simulium sp.; caddisflies in the family Hydropsychiidae; midges in the family Orthocladiinae; and the worms belonging to Turbellaria and Naididae all demonstrated resilience to trace-element exposure and, in some cases, possible changes in physical habitat within stream ecosystems. The taxa characteristics within the Ozark Highland ecoregion were different than other ecoregions as evidenced by generally more diverse mayfly populations. In addition, Baetis sp. was common and dominated many of the mayfly populations found in the Rocky Mountain streams within the Mountain Southern Rockies and Mountain Northern Rockies ecoregions; however, within the Ozark Highland ecoregion, Tricorythodes sp. appeared to be more common than Baetis sp.

Alaska, Arizona, California, Colorado, Hawai'i, Id↗
USGS2019

Anthropogenic and geologic causes of anomalously high uranium concentrations in groundwater used for drinking water supply in the southeastern San Joaquin Valley, CA

Concentrations of uranium (U) >30 µg/L in groundwater are relatively uncommon in drinking water in the United States but can be of concern in those areas where complex interactions of aquifer materials and anthropogenic alterations of the natural flow regime mobilize uranium. High concentrations (>30 µg/L) of U in the southeastern San Joaquin Valley, California, USA, have been detected in 24 percent of 257 domestic, irrigation, and public-supply wells sampled across an approximately 110,000 km2 area. The location of high concentrations depends on the interactions of U sources from fluvial fans that originate in the Sierra Nevada to the east and seepage of irrigation water that contains high concentrations of HCO3 that leaches U from the sediments. In addition, interactions with phosphate (PO4) from fertilized irrigated fields may sequester U in the aquifer. Principal component analysis of the data demonstrates that HCO3 and ions associated with high total dissolved solids in the aquifer and the percentage of agriculture near the well sampled are associated with high U concentrations. Nitrate concentrations do not appear to control release of U to the aquifer. Age dating of the groundwater and generally increasing U concentrations of the past 25 years in resampled wells where irrigation is prevalent suggests that high U concentrations are associated with younger water, indicating that irrigation of fields over the past 100 years has significantly contributed to increasing concentrations and mobilizing U. In some places, the groundwater is supersaturated with uranyl-containing minerals, as would be expected in roll front deposits. In general, the interaction of natural geological sources high in U, the anthropogenically driven addition of HCO3 and possibly phosphate fertilizer, control the location and concentration of U in each individual fluvial fan, but the addition of nitrate in fertilizer does not appear control the location of high U. These geochemical interactions can be used to determine controls on anomalously high U in alluvial aquifers

California↗
USGS2007

Concentration, UV-spectroscopic characteristics and fractionation of DOC in stormflow from an urban stream, Southern California, USA

The composition of dissolved organic carbon (DOC) in stormflow from urban areas has been greatly altered, both directly and indirectly, by human activities and there is concern that there may be public health issues associated with DOC, which has unknown composition from different sources within urban watersheds. This study evaluated changes in the concentration and composition of DOC in stormflow in the Santa Ana River and its tributaries between 1995 and 2004 using a simplified approach based on the differences in the optical properties of DOC and using operationally defined differences in molecular weight and solubility. The data show changes in the composition of DOC in stormflow during the rainy season and differences associated with runoff from different parts of the basin, including extensive upland areas burned prior to the 2004 rainy season. Samples were collected from the Santa Ana River, which drains ~6950 km 2 of the densely populated coastal area of southern California, during 23 stormflows between 1995 and 2004. Dissolved organic carbon (DOC) concentrations during the first stormflows of the ‘winter’ (November to March) rainy season increased rapidly with streamflow and were positively correlated with increased faecal indicator bacteria concentrations. DOC concentrations were not correlated with streamflow or with other constituents during stormflows later in the rainy season and DOC had increasing UV absorbance per unit carbon as the rainy season progressed. DOC concentrations in stormflow from an urban drain tributary to the river also increased during stormflow and were greater than concentrations in the river. DOC concentrations in stormflow from a tributary stream, draining urban and agricultural land that contained more than 320 000 animals, mostly dairy cows, were higher than concentrations in stormflow from the river and from the urban drain. Fires that burned large areas of the basin before the 2004 rainy season did not increase DOC concentrations in the river during stormflow after the fires – possibly because the large watershed of the river damped the effect of the fires. However, the fires increased the hydrophobic neutral organic carbon fraction of DOC in stormflow from the urban drain and the tributary stream.

California↗
USGS2017

Changes in the abundance and distribution of waterfowl wintering in the Central Valley of California, 1973–2000

The Central Valley of California is one of the most important areas for wintering waterfowl in the world and the focus of extensive conservation efforts to mitigate for historical losses and counter continuing stressors to habitats. To guide conservation, we analyzed trends in the abundance and distribution (spatiotemporal abundance patterns) of waterfowl and their habitats in the Central Valley and its major subregions (Sacramento Valley, Suisun Marsh, Delta, San Joaquin Valley), from 1973 through 2000. We used existing databases, satellite imagery, and aerial photography to measure habitat area, and aerial surveys and radio telemetry to track the abundance and distribution of wintering waterfowl. Wetlands increased throughout the Central Valley, but agricultural fields flooded after harvest increased greatly to the north in the Sacramento Valley and decreased to the south in the San Joaquin Valley, resulting in an overall increase in the relative availability of winter habitat in the former region. Reflecting the continental decline of the most abundant wintering species (Northern Pintail, Anas acuta ), the overall abundance of wintering waterfowl in the Central Valley declined during our study. By contrast, numbers of the American Wigeon ( A. americana ), Mallard ( A. platyrhynchos ), and Northern Shoveler ( A. clypeata ) were stable, and numbers of the Green-winged Teal ( A. crecca ), Gadwall ( A. strepera ), diving ducks, and geese increased from 1973–1982 to 1998–2000. The areas of greatest abundance of wintering waterfowl within the Central Valley shifted northward as many species responded to changes in the distribution of habitats. Wintering waterfowl migrated earlier in fall and winter from the San Joaquin Valley, Suisun Marsh, and Delta to the Sacramento Valley, and fewer waterfowl emigrated from the Sacramento Valley to other parts of the Central Valley. Because changes in waterfowl distribution were primarily a response to the increase of a beneficial agricultural practice (i.e., the flooding of rice after harvest) in the Sacramento Valley, changing agro-economics, reduction of water supplies, or other factors that reduce this practice could change the abundance and distribution of wintering waterfowl in the Central Valley rapidly. Thus to maintain abundant suitable habitat and restore the historical distribution of wintering waterfowl, our results suggest a continuing need for the conservation of wetlands and other waterfowl habitats with secure water supplies throughout the Central Valley. Despite our findings, achieving goals for winter waterfowl populations in the Central Valley likely will depend on a combination of factors including some acting in breeding ranges farther north or elsewhere outside of the valley.

California↗
USGS2012

Groundwater simulation and management models for the upper Klamath Basin, Oregon and California

The upper Klamath Basin encompasses about 8,000 square miles, extending from the Cascade Range east to the Basin and Range geologic province in south-central Oregon and northern California. The geography of the basin is dominated by forested volcanic uplands separated by broad interior basins. Most of the interior basins once held broad shallow lakes and extensive wetlands, but most of these areas have been drained or otherwise modified and are now cultivated. Major parts of the interior basins are managed as wildlife refuges, primarily for migratory waterfowl. The permeable volcanic bedrock of the upper Klamath Basin hosts a substantial regional groundwater system that provides much of the flow to major streams and lakes that, in turn, provide water for wildlife habitat and are the principal source of irrigation water for the basin's agricultural economy. Increased allocation of surface water for endangered species in the past decade has resulted in increased groundwater pumping and growing interest in the use of groundwater for irrigation. The potential effects of increased groundwater pumping on groundwater levels and discharge to springs and streams has caused concern among groundwater users, wildlife and Tribal interests, and State and Federal resource managers. To provide information on the potential impacts of increased groundwater development and to aid in the development of a groundwater management strategy, the U.S. Geological Survey, in collaboration with the Oregon Water Resources Department and the Bureau of Reclamation, has developed a groundwater model that can simulate the response of the hydrologic system to these new stresses. The groundwater model was developed using the U.S. Geological Survey MODFLOW finite-difference modeling code and calibrated using inverse methods to transient conditions from 1989 through 2004 with quarterly stress periods. Groundwater recharge and agricultural and municipal pumping are specified for each stress period. All major streams and most major tributaries for which a substantial part of the flow comes from groundwater discharge are included in the model. Groundwater discharge to agricultural drains, evapotranspiration from aquifers in areas of shallow groundwater, and groundwater flow to and from adjacent basins also are simulated in key areas. The model has the capability to calculate the effects of pumping and other external stresses on groundwater levels, discharge to streams, and other boundary fluxes, such as discharge to drains. Historical data indicate that the groundwater system in the upper Klamath Basin fluctuates in response to decadal climate cycles, with groundwater levels and spring flows rising and declining in response to wet and dry periods. Data also show that groundwater levels fluctuate seasonally and interannually in response to groundwater pumping. The most prominent response is to the marked increase in groundwater pumping starting in 2001. The calibrated model is able to simulate observed decadal-scale climate-driven fluctuations in the groundwater system as well as observed shorter-term pumping-related fluctuations. Example model simulations show that the timing and location of the effects of groundwater pumping vary markedly depending on the pumping location. Pumping from wells close (within a few miles) to groundwater discharge features, such as springs, drains, and certain streams, can affect those features within weeks or months of the onset of pumping, and the impacts can be essentially fully manifested in several years. Simulations indicate that seasonal variations in pumping rates are buffered by the groundwater system, and peak impacts are closer to mean annual pumping rates than to instantaneous rates. Thus, pumping effects are, to a large degree, spread out over the entire year. When pumping locations are distant (more than several miles) from discharge features, the effects take many years or decades to fully impact those features, and much of the pumped water comes from groundwater storage over a broad geographic area even after two decades. Moreover, because the effects are spread out over a broad area, the impacts to individual features are much smaller than in the case of nearby pumping. Simulations show that the discharge features most affected by pumping in the area of the Bureau of Reclamation's Klamath Irrigation Project are agricultural drains, and impacts to other surface-water features are small in comparison. A groundwater management model was developed that uses techniques of constrained optimization along with the groundwater flow model to identify the optimal strategy to meet water user needs while not violating defined constraints on impacts to groundwater levels and streamflows. The coupled groundwater simulation-optimization models were formulated to help identify strategies to meet water demand in the upper Klamath Basin. The models maximize groundwater pumping while simultaneously keeping the detrimental impacts of pumping on groundwater levels and groundwater discharge within prescribed limits. Total groundwater withdrawals were calculated under alternative constraints for drawdown, reductions in groundwater discharge to surface water, and water demand to understand the potential benefits and limitations for groundwater development in the upper Klamath Basin. The simulation-optimization model for the upper Klamath Basin provides an improved understanding of how the groundwater and surface-water system responds to sustained groundwater pumping within the Bureau of Reclamation's Klamath Project. Optimization model results demonstrate that a certain amount of supplemental groundwater pumping can occur without exceeding defined limits on drawdown and stream capture. The results of the different applications of the model demonstrate the importance of identifying constraint limits in order to better define the amount and distribution of groundwater withdrawal that is sustainable.

Oregon;California↗
USGS1999

Predatory bird populations in the east Mojave Desert, California

We surveyed 7 species of predatory birds weekly during a 12-month period (December 1992 through November 1993) in the east Mojave Desert, California. The Common Raven (Corvus corax) was the most frequently observed species with an average of 6.9 sightings per 100 km. Turkey Vultures (Cathartes aura), Red-tailed Hawks (Buteo jamaicensis), Loggerhead Shrikes (Lanius ludovicianus), American Kestrels (Falco sparverius), Golden Eagles (Aquila chrysaetos), and Prairie Falcons (Falco mexicanus) were seen in decreasing order of frequency of observation through the study period. Ravens, Red-tailed Hawks, Loggerhead Shrikes, American Kestrels, and Prairie Falcons were seen throughout the year. Turkey Vultures were not present during winter months, while Golden Eagles were seen only during November and December. Turkey Vultures, Red-tailed Hawks, and ravens were most numerous on agricultural lands, while Loggerhead Shrikes were most Common at urban areas. Raven numbers increased with increasing number of linear rights-of-way parallel to the survey route. Perching was the most common behavior type, although Turkey Vultures and ravens were often observed soaring, flying, or standing on the ground near highways. Transmission powerline towers and telephone poles were used as perch sites disproportionately to availability.

Great Basin Naturalist↗
USGS2022

Linkages between land-use change and groundwater management foster long-term resilience of water supply in California

Study Region We created a 270-m coupled model of land-use and groundwater conditions, LUCAS-W[ater], for California’s Central Coast. This groundwater-dependent region is undergoing a dramatic reorganization of groundwater management under California’s 2014 Sustainable Groundwater Management Act (SGMA). Study Focus Understanding land-use and land-cover change supports long-term sustainable water management. Anthropogenic water demand has depleted groundwater aquifers worldwide, while future water shortages will likely affect land-use change, creating system feedbacks. Our novel participatory approach fused changes in land-use and associated water use from county-scale data to local water agencies’ estimates of total sustainable supply, scaling up local hydro-geologic knowledge from heterogeneous aquifers and diverse management approaches to a regional level. We assessed five stakeholder-driven scenarios with the same historic rates of urban and agricultural land-use change, but different water and land-use management, analyzing how management strategies altered both the spatial pattern of development and subsequent water sustainability from 2001 to 2061. New Hydrological Insights for the Region Transformative strategies using demand-side interventions that coupled water availability to land-use more effectively achieved long-term sustainability than adaptive strategies using supply-side interventions to increase water supplies. Limiting water withdrawals within SGMA regulated basins resulted in leakage of development into unregulated basins, increasing groundwater pumping there. Protecting ecosystems, farmlands, and recharge areas from development reduced leakage into undeveloped basins without negatively affecting water sustainability.

California↗
USGS2005

Occurrence and distribution of volatile organic compounds and pesticides in ground water in relation to hydrogeologic characteristics and land use in the Santa Ana basin, southern California

This report presents an evaluation of the occurrence and distribution of VOCs and pesticides in the Santa Ana ground-water basins in relation to two types of explanatory factors: hydrogeologic characteristics and land use. The Santa Ana Basin is subdivided into the San Jacinto, the Inland, and the Coastal ground-water basins. Most wells sampled were deep and used for public supply. Data from regional studies were used to evaluate the occurrence and distribution of pesticides and volatile organic compounds (VOCs) in relation to hydrogeologic characteristics and land uses that could potentially explain variations between basins. Additional data from special studies (flow path and aquifer susceptibility) were used to evaluate potential factors affecting water quality for individual basins. The hydrogeologic characteristics evaluated in this report were hydrogeologic setting, ground-water age, depth to the top of the well screen (top of well perforations), and proximity to engineered recharge facilities. Urban land use, agricultural land use, and population density were characterized within a 500-meter radius of sampled wells and at the basin scale. Aquifers in the San Jacinto Basin are generally unconfined, and major land-use categories are urban (33 percent), agricultural (37 percent), and undeveloped (25 percent). Recharge is primarily from the overlying landscape, but engineered recharge is locally important in the Hemet area. VOCs and pesticides were detected more frequently in younger ground water (less than 50 years old) than in older ground water, and more frequently in shallower wells than deeper wells; the numbers of VOCs and pesticides detected also were significantly higher in the younger ground water and in the shallower wells. In the Hemet area of the San Jacinto Basin, VOCs and pesticides were detected more frequently in wells proximal to engineered recharge facilities than in distal wells. These patterns illustrate the importance of proximity to sources of recharge in relation to the occurrence and distribution of VOCs and pesticides in ground water. Aquifers in the Inland Basin also are generally unconfined, and the major land-use category is urban (58 percent), with lesser amounts of agricultural (13 percent) and undeveloped (28 percent) land. Recharge is from engineered facilities that utilize local runoff and imported water and from vertical infiltration. VOCs and pesticides were detected more frequently in younger ground water than in older ground water, and more frequently in shallower wells than deeper wells. The number of VOCs detected per well also was significantly higher in the younger ground water and in the shallower wells. Several solvent plumes extending between 5 and 10 kilometers illustrate the large distances that contaminants travel in basins with intensive use of ground water. Aquifers in the Coastal Basin, in contrast to the other basins, are generally confined. Land use in the basin is largely urban (80 percent), with lesser amounts of agricultural (7 percent) and undeveloped (12 percent) land. Recharge is primarily from engineered facilities that utilize water diverted from the Santa Ana River and imported water. Consequently, VOCs and pesticides were detected more frequently in wells proximal to engineered recharge facilities than in distal wells. These compounds were also detected more frequently in the unconfined area than in the confined area of the basin. In the confined area, the numbers of VOCs and pesticides detected per well were not significantly different in wells with shallower and deeper screens. This distribution reflects the dominance of lateral flow and insulation from overlying land use in the confined aquifers of the Coastal Basin. In the unconfined area of the Coastal Basin, the numbers of VOCs and pesticides detected per well were significantly higher in shallower wells than in deeper wells. VOC and pesticide detections were not statist

Scientific Investigations Report↗
USGS1984

Salinity, alkalinity, and dissolved and particulate organic carbon in the Sacramento River water at Rio Vista, California, and at other locations in the Sacramento-San Joaquin Delta, 1980

Salinity, alkalinity, and dissolved and particulate organic carbon (DOC and POC respectively) concentrations in the Sacramento River water at Rio Vista were measured every three to five days during 1980 as part of an effort to identify time-dependent variations in the composition of the freshwater flow from the Sacramento-San Joaquin Delta to San Francisco Bay. Concentration ranges were generally small compared to the seasonal range of river flow rate; transport rates to the Delta and to the Bay varied primarily as a function of flow rate. Surface runoff from winter storms diluted salinity and alkalinity concentrations. DOC and POC were generally more concentrated during winter than during other times of the year. Variations in tributary flows resulted in sometimes-large salinity and alkalinity variations during spring through fall. Late summer concentrations were high because of large inflows of agricultural waste waters. POC and DOC concentrations were lowest during summer.

California↗
USGS2010

An initial SPARROW model of land use and in-stream controls on total organic carbon in streams of the conterminous United States

Watersheds play many important roles in the carbon cycle: (1) they are a site for both terrestrial and aquatic carbon dioxide (CO2) removal through photosynthesis; (2) they transport living and decomposing organic carbon in streams and groundwater; and (3) they store organic carbon for widely varying lengths of time as a function of many biogeochemical factors. Using the U.S. Geological Survey (USGS) Spatially Referenced Regression on Watershed Attributes (SPARROW) model, along with long-term monitoring data on total organic carbon (TOC), this research quantitatively estimates the sources, transport, and fate of the long-term mean annual load of TOC in streams of the conterminous United States. The model simulations use surrogate measures of the major terrestrial and aquatic sources of organic carbon to estimate the long-term mean annual load of TOC in streams. The estimated carbon sources in the model are associated with four land uses (urban, cultivated, forest, and wetlands) and autochthonous fixation of carbon (stream photosynthesis). Stream photosynthesis is determined by reach-level application of an empirical model of stream chlorophyll based on total phosphorus concentration, and a mechanistic model of photosynthetic rate based on chlorophyll, average daily solar irradiance, water column light attenuation, and reach dimensions. It was found that the estimate of in-stream photosynthesis is a major contributor to the mean annual TOC load per unit of drainage area (that is, yield) in large streams, with a median share of about 60 percent of the total mean annual carbon load in streams with mean flows above 500 cubic feet per second. The interquartile range of the model predictions of TOC from in-stream photosynthesis is from 0.1 to 0.4 grams (g) carbon (C) per square meter (m-2) per day (day-1) for the approximately 62,000 stream reaches in the continental United States, which compares favorably with the reported literature range for net carbon fixation by phytoplankton in lakes and streams. The largest contributors per unit of drainage area to the mean annual stream TOC load among the terrestrial sources are, in descending order: wetlands, urban lands, mixed forests, agricultural lands, evergreen forests, and deciduous forests . It was found that the SPARROW model estimates of TOC contributions to streams associated with these land uses are also consistent with literature estimates. SPARROW model calibration results are used to simulate the delivery of TOC loads to the coastal areas of seven major regional drainages. It was found that stream photosynthesis is the largest source of the TOC yields ( about 50 percent) delivered to the coastal waters in two of the seven regional drainages (the Pacific Northwest and Mississippi-Atchafalaya-Red River basins ), whereas terrestrial sources are dominant (greater than 60 percent) in all other regions (North Atlantic, South Atlantic-Gulf, California, Texas-Gulf, and Great Lakes).

Conterminous United States↗
USGS2013

Trends in concentrations of nitrate and total dissolved solids in public supply wells of the Bunker Hill, Lytle, Rialto, and Colton groundwater subbasins, San Bernardino County, California: Influence of legacy land use

Concentrations and temporal changes in concentrations of nitrate and total dissolved solids (TDS) in groundwater of the Bunker Hill, Lytle, Rialto, and Colton groundwater subbasins of the Upper Santa Ana Valley Groundwater Basin were evaluated to identify trends and factors that may be affecting trends. One hundred, thirty-one public-supply wells were selected for analysis based on the availability of data spanning at least 11 years between the late 1980s and the 2000s. Forty-one of the 131 wells (31%) had a significant (p < 0.10) increase in nitrate and 14 wells (11%) had a significant decrease in nitrate. For TDS, 46 wells (35%) had a significant increase and 8 wells (6%) had a significant decrease. Slopes for the observed significant trends ranged from − 0.44 to 0.91 mg/L/yr for nitrate (as N) and − 8 to 13 mg/L/yr for TDS. Increasing nitrate trends were associated with greater well depth, higher percentage of agricultural land use, and being closer to the distal end of the flow system. Decreasing nitrate trends were associated with the occurrence of volatile organic compounds (VOCs); VOC occurrence decreases with increasing depth. The relations of nitrate trends to depth, lateral position, and VOCs imply that increasing nitrate concentrations are associated with nitrate loading from historical agricultural land use and that more recent urban land use is generally associated with lower nitrate concentrations and greater VOC occurrence. Increasing TDS trends were associated with relatively greater current nitrate concentrations and relatively greater amounts of urban land. Decreasing TDS trends were associated with relatively greater amounts of natural land use. Trends in TDS concentrations were not related to depth, lateral position, or VOC occurrence, reflecting more complex factors affecting TDS than nitrate in the study area.

California↗
USGS2017

Persistence of historical population structure in an endangered species despite near-complete biome conversion in California's San Joaquin Desert

Genomic responses to habitat conversion can be rapid, providing wildlife managers with time-limited opportunities to enact recovery efforts that use population connectivity information that reflects predisturbance landscapes. Despite near-complete biome conversion, such opportunities may still exist for the endemic fauna and flora of California's San Joaquin Desert, but comprehensive genetic data sets are lacking for nearly all species in the region. To fill this knowledge gap, we studied the rangewide population structure of the endangered blunt-nosed leopard lizard Gambelia sila , a San Joaquin Desert endemic, using restriction site-associated DNA (RAD), microsatellite and mtDNA data to test whether admixture patterns and estimates of effective migration surfaces (EEMS) can identify land areas with high population connectivity prior to the conversion of native xeric habitats. Clustering and phylogenetic analyses indicate a recent shared history between numerous isolated populations and EEMS reveals latent signals of corridors and barriers to gene flow over areas now replaced by agriculture and urbanization. Conflicting histories between the mtDNA and nuclear genomes are consistent with hybridization with the sister species G. wislizenii , raising important questions about where legal protection should end at the southern range limit of G. sila . Comparative analysis of different data sets also adds to a growing list of advantages in using RAD loci for genetic studies of rare species. We demonstrate how the results of this work can serve as an evolutionary guidance tool for managing endemic, arid-adapted taxa in one of the world's most compromised landscapes.

California↗
USGS2006

Ground-water surface-water interactions and long-term change in riverine riparian vegetation in the southwestern United States

Riverine riparian vegetation has changed throughout the southwestern United States, prompting concern about losses of habitat and biodiversity. Woody riparian vegetation grows in a variety of geomorphic settings ranging from bedrock-lined channels to perennial streams crossing deep alluvium and is dependent on interaction between ground-water and surface-water resources. Historically, few reaches in Arizona, southern Utah, or eastern California below 1530 m elevation had closed gallery forests of cottonwood and willow; instead, many alluvial reaches that now support riparian gallery forests once had marshy grasslands and most bedrock canyons were essentially barren. Repeat photography using more than 3000 historical images of rivers indicates that riparian vegetation has increased over much of the region. These increases appear to be related to several factors, notably the reduction in beaver populations by trappers in the 19th century, downcutting of arroyos that drained alluvial aquifers between 1880 and 1910, the frequent recurrence of winter floods during discrete periods of the 20th century, an increased growing season, and stable ground-water levels. Reductions in riparian vegetation result from agricultural clearing, excessive ground-water use, complete flow diversion, and impoundment of reservoirs. Elimination of riparian vegetation occurs either where high ground-water use lowers the water table below the rooting depth of riparian species, where base flow is completely diverted, or both. We illustrate regional changes using case histories of the San Pedro and Santa Cruz Rivers, which are adjacent watersheds in southern Arizona with long histories of water development and different trajectories of change in riparian vegetation.

Conference Paper↗
USGS2019

Factors affecting 1,2,3-trichloropropane contamination in groundwater in California

1,2,3-Trichloropropane (1,2,3-TCP) is a volatile organic chemical of eminent concern due to its carcinogenic, mutagenic, and reproductive effects, and its frequent occurrence at concentrations of concern worldwide. In California, 1,2,3-TCP was detected in 6.5% of 1237 wells sampled by the U. S. Geological Survey (USGS). About 8% of domestic wells had a detection of 1,2,3-TCP, compared to 5% of public-supply wells. 1,2,3-TCP was detected in 5.5% of most recent samples from 7787 public-supply well sources of the California State Water Resources Control Board Division of Drinking Water (DDW). Concentrations ranged from <0.005 to 2.7 μg/L. The California maximum contaminant level (MCL) is 0.005 μg/L. Most of the detections occurred in the San Joaquin Valley, where 1,2,3-TCP was detected above the MCL in 16% of USGS sampled wells and 18% of DDW wells. 1,2,3-TCP occurrence and concentrations are related to legacy fumigant use and hydrogeologic factors. Understanding factors affecting 1,2,3-TCP will aid in determining vulnerability and long term persistence in the San Joaquin Valley, which can help focus efforts to manage drinking water resources on the most vulnerable areas and also inform efforts in other areas of the state and worldwide. Widespread occurrence of 1,2,3-TCP is related to nonpoint source agricultural contaminant inputs. High concentrations of 1,2,3-TCP are in young, shallow, oxic groundwater beneath primarily orchard/vineyard crops. These areas are in coarse-grained sediments that promote rapid recharge, related to proximal alluvial fan sediments deposited by large streams that drain glaciated watersheds of the Sierra Nevada. 1,2,3-TCP co-occurs with 1,2-dibromo-3-chloropropane (DBCP) and 1,2-dichloropropane (1,2-DCP) throughout modern age groundwater, indicating its long term persistence with little degradation. The highest concentrations of 1,2,3-TCP were observed at point source cleanup sites in urban areas; depending on the age and source of groundwater to nearby public-supply wells, these areas may see increasing concentrations of 1,2,3-TCP.

California↗
USGS2025

Relations of groundwater quality to long-term surface disposal of produced water near the Midway-Sunset and Buena Vista Oil Fields, California, USA

Contamination of groundwater by oil-field fluids in proximity to oil and gas development has been an issue of concern to water users and regulators given long histories of development and legacy disposal practices. A robust set of geochemical tracers including petroleum hydrocarbon compounds, thermogenic gases, inorganic ion concentrations, stable isotopes, radioactive isotopes, and noble gases were used to assess if oil-field fluids mixed with groundwater near the Midway-Sunset and Buena Vista Oil Fields in California, USA. Results show evidence of mixing of oil-field fluids with groundwater within the study area from either anthropogenic or natural processes. Produced water plumes associated with modern surface disposal facilities, used since the late 1950s, extend up to 1.5 km and currently remain within the boundaries of the oil fields. Plumes associated with earlier routing of produced water down natural drainages and in large retention structures (Midway Basin and Sunset Basin) near the Buena Vista Lake Bed are present in groundwater east of the oil fields. Based on geochemical tracer evidence, aerial imagery, and aerial electromagnetic surveys, these legacy plumes reach the western portion of the Central Valley aquifer system, an important groundwater resource for agricultural and domestic supply. The legacy plume associated with Sunset Basin may further be detected downgradient in deeper groundwater beneath the southern extent of the Buena Vista Lake Bed based on the presence of thermogenic gases and petroleum hydrocarbon compounds.

California↗
USGS2009

Regression models for explaining and predicting concentrations of organochlorine pesticides in fish from streams in the United States

Empirical regression models were developed for estimating concentrations of dieldrin, total chlordane, and total DDT in whole fish from U.S. streams. Models were based on pesticide concentrations measured in whole fish at 648 stream sites nationwide (1992-2001) as part of the U.S. Geological Survey's National Water Quality Assessment Program. Explanatory variables included fish lipid content, estimates (or surrogates) representing historical agricultural and urban sources, watershed characteristics, and geographic location. Models were developed using Tobit regression methods appropriate for data with censoring. Typically, the models explain approximately 50 to 70% of the variability in pesticide concentrations measured in whole fish. The models were used to predict pesticide concentrations in whole fish for streams nationwide using the U.S. Environmental Protection Agency's River Reach File 1 and to estimate the probability that whole-fish concentrations exceed benchmarks for protection of fish-eating wildlife. Predicted concentrations were highest for dieldrin in the Corn Belt, Texas, and scattered urban areas; for total chlordane in the Corn Belt, Texas, the Southeast, and urbanized Northeast; and for total DDT in the Southeast, Texas, California, and urban areas nationwide. The probability of exceeding wildlife benchmarks for dieldrin and chlordane was predicted to be low for most U.S. streams. The probability of exceeding wildlife benchmarks for total DDT is higher but varies depending on the fish taxon and on the benchmark used. Because the models in the present study are based on fish data collected during the 1990s and organochlorine pesticide residues in the environment continue to decline decades after their uses were discontinued, these models may overestimate present-day pesticide concentrations in fish. ?? 2009 SETAC.

Environmental Toxicology and Chemistry↗
USGS2010

Groundwater Quality in the Central Eastside San Joaquin Valley, California

The Central Eastside study unit is located in California's San Joaquin Valley. The 1,695 square mile study unit includes three groundwater subbasins: Modesto, Turlock, and Merced (California Department of Water Resources, 2003). The primary water-bearing units consist of discontinuous lenses of gravel, sand, silt, and clay, which are derived largely from the Sierra Nevada Mountains to the east. Public-supply wells provide most of the drinking water supply in the Central Eastside. Consequently, the primary aquifer in the Central Eastside study unit is defined as that part of the aquifer corresponding to the perforated interval of wells listed in the California Department of Public Health database. Public-supply wells are typically drilled to depths of 200 to 350 feet, consist of solid casing from the land surface to a depth of about 100 to 200 feet, and they are perforated below the solid casing. Water quality in the shallower and deeper parts of the aquifer system may differ from that in the primary aquifer. The Central Eastside study unit has hot and dry summers and cool, moist, winters. Average annual rainfall ranges from 11 to 15 inches. The Stanislaus, Tuolumne, and Merced Rivers, with headwaters in the Sierra Nevada Mountains, are the primary streams traversing the study unit. Land use in the study unit is approximately 59 percent (%) agricultural, 34% natural (primarily grassland), and 7% urban. The primary crops are almonds, walnuts, peaches, grapes, grain, corn, and alfalfa. The largest urban areas (2003 population in parentheses) are the cities of Modesto (206,872), Turlock (63,467), and Merced (69,512). Municipal water use accounts for about 5% of the total water use in the Central Eastside study unit, with the remainder used for irrigated agriculture. Groundwater accounts for about 75% of the municipal supply, and surface water accounts for about 25%. Recharge to the groundwater flow system is primarily from percolation of irrigation return, precipitation, seepage from reservoirs and rivers, and urban return (Burow and others, 2004; Phillips and others, 2007). The primary sources of discharge are pumping for irrigation and municipal supply, evaporation from areas with a shallow depth to water, and discharge to streams. Recharge at shallow depths and pumping from wells at greater depths causes downward movement of groundwater in the aquifer in the Central Eastside. This vertical movement of water has the potential to carry chemical constituents from shallow depths to the greater depths where supply wells commonly are perforated.

Fact Sheet↗