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USGS1999

Streamflow, base flow, and ground-water recharge in the Housatonic River basin, western Massachusetts and parts of eastern New York and northwestern Connecticut

Streamflows for selected flow durations from 1 to 99 percent and the August median streamflows were estimated for 11 long-term streamflow-gaging stations in and near the study area. Estimates of streamflow and associated standard errors were determined for selected flow durations from 50 to 99 percent and the August median streamflows for 21 low-flow partial-record stations and for selected flow durations from 1 to 99 percent and the August median streamflows for two partial-record stations and seven short-term discontinued streamflow-gaging stations. Median streamflows per square mile for the 10-, 50-, and 90-percent flow durations and the August median streamflows were 3.90, 1.01, 0.185, and 0.248 cubic feet per second per square mile. Streamflows per square mile at selected flow-duration discharges between 1 and 99 percent at the 41 stations were related to basin characteristics to explain differences in streamflow characteristics. Basin characteristics included basin elevations, extent of stratified-drift deposits, land use, aspect, and underlying bedrock geology types. Most streamflow differences were positively correlated to basin elevation differences, most likely because precipitation increases with elevation, and to stratified-drift deposits, which allow more precipitation to recharge the ground water and to discharge later than do till and bedrock deposits. Mean base flow was computed from continuous records of daily mean discharge at 11 long-term streamflow-gaging stations in and near the study area. Mean annual base flow ranged from 13.4 to 24.5 inches per year. Minimum annual base flow ranged from 45 to 72 percent of mean annual rates at the 11 long-term stations, and the ratio of base flow to streamflow (base-flow index) ranged from 0.55 to 0.80. Base-flow durations between 1 and 99 percent were calculated from streamflow records at the 11 long-term streamflow-gaging stations. Base flow accounted for 45.5 to 85.0 percent of total annual streamflow at the 1- and 99-percent flow durations. Ground-water-recharge rates were computed from continuous records of daily mean discharge at 11 long-term streamflow-gaging stations in and near the study area. Mean annual ground-water-recharge rates ranged from 17.5 to 22.4 inches per year at 10 of the 11 long-term stations. Mean annual ground-water-recharge rates ranged from 2 to 7 inches per year higher than base flow. Minimum annual ground-water-recharge rates ranged from 48 to 72 percent of mean annual ground-water-recharge rates. Mean annual potential ground-water recharge was estimated from monthly climatological data collected at six climatological stations in and near the study area. Mean potential ground-water recharge ranged from about 17.9 to 28.9 inches per year, with a median value of 22.6 inches per year. This median value compares well to that calculated by use of streamflow records at the 11 streamflow-gaging stations (20.0 inches per year). Streamflows per square mile for the 10-, 50-, and 90-percent flow durations at stations in and near the study area were similar to those computed for other unregulated long-term continuous streamflow-gaging stations in central and eastern Massachusetts. Base-flow and ground-water-recharge rates in the study area compared closely to results from other studies in southeastern Massachusetts and Rhode Island, which were based on the same computational methods.

Connecticut, Massachusetts, New York↗
USGS2024

The addition of 144Nd atomic mass to routine ICP-MS analysis as a Quick Screening Tool for Approximating Rare Earth Elements (Q-STAR) in natural waters

Rare earth elements (REEs) are a class of critical minerals, all of which can have supply chain vulnerability that impacts economic security. These elements are widely measured in environmental matrices via inductively coupled plasma mass spectrometry (ICP-MS); however, successful quantification can require time-consuming, sample-specific optimization. While a sample-by-sample approach is appropriate for targeted quantification studies, this approach is not suitable for mineral exploration efforts where rapidly screening thousands of samples for the presence of REEs is desired. Here, we demonstrated the use of a Quick Screening Tool for Approximating REEs (Q-STAR) to detect REEs in surface water and groundwater matrices, collected as part of existing environmental studies. A mass-to-charge ratio of 144 ( m / z = 144) was added to an ICP-MS method to screen for REEs in filtered water samples submitted for metals analyses to the U.S. Geological Survey (USGS) National Water Quality Laboratory. We detected the presence of REEs above a reference threshold of 1200 counts per second in 18 % of pre-selected 6626 samples. Using this screened dataset, we mapped estimated dissolved REE concentrations across the United States in relation to ecoregions and underlying geology. Data are constrained to where sample collection took place but nevertheless show estimated aqueous dissolved REE concentrations on a geographic scale that has not yet been studied. To validate Q-STAR, REEs were measured in a USGS standard reference sample, a subset of 88 archived filtered water samples, and in fresh filtered surface water samples. Our targeted analyses demonstrated a strong linear relationship between Q-STAR predicted and measured values in all archived samples for Nd (r 2 = 0.94), and light REEs (LREEs) such as lanthanum (La) (r 2 = 0.93), praseodymium (Pr) (r 2 = 0.94) and samarium (Sm) (r 2 = 0.94). Using Q-STAR screen values, nine field sites were identified and surface water samples recollected to confirm the continued presence of Nd and LREEs. Q-STAR can be used to screen an unlimited number of water samples for the presence of REEs prior to time-intensive and costly quantitative analyses and to generate large REE datasets for further investigation.

Journal of Geochemical Exploration↗
USGS2025

Characterization of stream water quality and groundwater levels in the Central Pine Barrens region, Suffolk County, New York, 2017–23

The area locally known as the “Central Pine Barrens” region, located in Suffolk County, New York, contains most of Long Island’s preserved and undeveloped land. This region overlays an aquifer system that provides potable groundwater for residents of Suffolk County. Between 2017 and 2023, the U.S. Geological Survey, in cooperation with the Central Pine Barrens Joint Planning & Policy Commission and the Town of Brookhaven, monitored groundwater levels and stream water quality in this region. Groundwater levels were measured monthly at five wells and continuously (15-minute intervals) at a sixth well. Water quality was monitored at five locations in the Carmans River and at two locations in the Peconic River, and samples were analyzed for major ions, trace elements, nutrients, pharmaceuticals, and pesticides. The major ion compositions at the sites were mainly sodium-chloride type waters, and compositions varied the most at the furthest upstream sites in both streams. Concentrations above aquatic-life criteria thresholds also occurred most frequently at the furthest upstream sites. The seasonal patterns of nutrient loads and concentrations varied between the Carmans and Peconic Rivers. Several organic compounds including pharmaceuticals, domestic use products, and pesticides were detected at low concentrations in both streams. Metformin was the most frequently detected pharmaceutical compound, and herbicides were the most frequently detected pesticide class. Water-quality conditions influenced by anthropogenic contributions are a result of current and historical land use, and these contributions include onsite wastewater disposal systems, commercial or domestic fertilizers and pesticides, and urban or industrial contaminants in road runoff. This study characterizes and improves understanding of the current hydrologic conditions in the Central Pine Barrens region and the study findings can help inform the development of plans to manage, protect, and restore water resources.

New York↗
USGS2000

Assessment of potential for natural attenuation of chlorinated ethenes and ethanes in ground water at a petrochemical reclamation site, Harris County, Texas

Redox conditions in the Numerous Sand Channels Zone beneath a petrochemical reclamation site in Harris County, Texas, range from sulfate reducing to methanogenic as indicated by the presence of methane in ground water and the range of molecular hydrogen concentrations. Assessment of the potential for reductive dechlorination using BIOCHLOR as a screening tool indicated conditions favoring anaerobic degradation of chlorinated organic compounds in the Numerous Sand Channels Zone. Evidence supporting reductive dechlorination includes apparently biogenic cis -1,2-dichloroethene; an increased ratio of 1,2-dichloroethane to 1,1,2-trichloroethane downgradient from the assumed contaminant source area; ethene and methane concentrations greater than background concentrations within the area of the contaminant plume; and a positive correlation of the ratio of ethene to vinyl chloride as a function of methane concentrations. The body of evidence presented in this report argues for hydrogenolysis of trichloroethene to cis -1,2-dichloroethene; of 1,1,2-trichloroethane to 1,2-dichloroethane; and of vinyl chloride to ethene within the Numerous Sand Channels Zone. Simulations using BIOCHLOR yielded apparent first-order decay constants for reductive dechlorination in the sequence tetrachloroethene trichloroethene cis -1,2-dichloroethene vinyl chloride ethene within the range of literature values reported for each compound and apparent first-order decay constants for reductive dechlorination in the sequence 1,1,2-trichloroethane 1,2-dichloroethane slightly greater than literature values reported for each compound along the upgradient segment of a simulated ground-water flowpath. Except for vinyl chloride, apparent rates of reductive dechlorination for all simulated species show a marked decrease along the downgradient segment of the simulated ground-water flowpath. Evidence for reductive dechlorination of chlorinated ethenes within the Numerous Sand Channels Zone indicates potential for natural attenuation of chlorinated ethenes. Reductive dechlorination of chlorinated ethanes apparently occurs to a lesser extent, indicating relatively less potential for natural attenuation of chlorinated ethanes. Additional data are needed on the concentrations and distribution of chlorinated ethenes and ethanes in individual fine sand intervals of the Numerous Sand Channels Zone. This information, combined with lower minimum reporting levels for future chloroethane analyses, might enable a more complete and quantitative assessment of the potential for natural attenuation at the site.

Texas↗
USGS1997

Hydrologic and water-quality conditions in the Horse Creek basin, west-central Florida, October 1992-February 1995

A baseline study of the 241-square-mile Horse Creek basin was undertaken from October 1992 to February 1995 to assess the hydrologic and water-quality conditions of one of the last remaining undeveloped basins in west-central Florida. During the period of the study, much of the basin remained in a natural state, except for limited areas of cattle and citrus production and phosphate mining. Rainfall in 1993 and 1994 in the Horse Creek basin was 8 and 31 percent, respectively, above the 30-year long-term average. The lowest and highest maximum instantaneous peak discharge of the six daily discharge stations occurred at the Buzzard Roost Branch and the Horse Creek near Arcadia stations with 185 to 4,180 cubic feet per second, respectively. The Horse Creek near Arcadia station had the lowest number of no-flow days with zero days and the Brushy Creek station had the highest number with 113 days. During the study, the West Fork Horse Creek subbasin had the highest daily mean discharge per square mile with 30.6 cubic feet per second per square mile, and the largest runoff coefficient of 43.7 percent. The Buzzard Roost Branch subbasin had the lowest daily mean discharge per square mile with 5.05 cubic feet per second per square mile, and Brushy Creek and Brandy Branch shared the lowest runoff coefficient of 0.6 percent. Brandy Branch had the highest monthly mean runoff in both 1993 and 1994 with 11.48 and 19.28 inches, respectively. During the high-baseflow seepage run, seepage gains were 8.87 cubic feet per second along the 43-mile Horse Creek channel. However, during the low-baseflow seepage run, seepage losses were 0.88 cubic foot per second. Three methods were used to estimate average annual ground-water recharge in the Horse Creek basin: (1) well hydrograph, (2) chloride mass balance, and (3) streamflow hydrograph. Estimated average annual recharge using these three methods ranged from 3.6 to 8.7 inches. The high percentage of carbonate plus bicarbonate analyzed at the Carlton surficial aquifer well could indicate an upward ground-water flow from the underlying intermediate aquifer system. Based on constituent concentrations in water samples from the six daily discharge stations, concentrations generally are lower in the upper three subbasins, West Fork Horse Creek, Upper Horse Creek, and Brushy Creek than in the lower three subbasins. Typically, concentrations were highest for major ions at Buzzard Roost Branch and nutrients at Brushy Creek.

Florida↗
USGS2000

Hydrology and water and sediment quality at James Campbell National Wildlife Refuge near Kahuku, Island of Oahu, Hawaii

The James Campbell National Wildlife Refuge occupies two lowland marsh and pond complexes on the northern coastal plain of Oahu: the mostly natural ponds and wetlands of the Punamano Unit and the constructed ponds of the Kii Unit. The U.S. Fish and Wildlife Service manages the Refuge primarily to protect and enhance habitat for four endangered species of Hawaiian waterbirds. Kii Unit is fed by artesian wells and rainfall, whereas Punamano Unit is fed naturally by rainfall, runoff, and ground-water seepage. Streams drain from the uplands into lowland ditches that pass through Kii Unit on their way to the ocean. A high-capacity pump transfers water from the inner ditch terminus at Kii to the ocean outlet channel. Stormwaters also exit the inner ditch system over flood-relief swales near the outlet pump and through a culvert with a one-way valve. A hydrologic investigation was done from November 1996 through February 1998 to identify and quantify principal inflows and outflows of water to and from the Refuge, identify hydraulic factors affecting flooding, document ground-water/surface-water interactions, determine the adequacy of the current freshwater supply, and determine water and sediment quality. These goals were accomplished by installing and operating a network of stream-gaging stations, meteorology stations, and shallow ground-water piezometers, by computing water budgets for the two Refuge units, and by sampling and analyzing water and pond-bottom sediments for major ions, trace metals, and organic compounds. Streamflow during the study was dominated by winter stormflows, followed by a gradual recession of flow into summer 1997, as water that had been stored in alluvial fans drained to lowland ditches. Outflow at the ditch terminus in 1997 was 125 million gallons greater than measured inflow to the coastal plain, mainly reflecting gains from ground water along the ditches between outlying gages and the ditch terminus. Of the measured 1997 outflow, 98 percent was through the Kii outlet pump, with the outlet culvert valve only opening for brief periods during storms. Large volumes of stormflow overflowed the flood-relief swales unmeasured. The largest storm of the study, in November 1996, was estimated to have a flood frequency of about 3 to 4 years. Streamflow exceeded culvert capacity and overtopped Kamehameha Highway at Kalaeokahipa Stream and Hospital ditch. Slight overbank flooding in Kii ditch resulted strictly from high discharge. Minor overbank flooding farther out on the coastal plain probably was caused mainly by the small hydraulic gradients available to convey stormflows along the lowland ditches. Stormwaters flooded Kii ponds and flowed back upstream along Punamano ditch into Punamano marsh, introducing suspended sediment and possibly other contaminants to the Refuge. Two smaller storms in January 1997 resulted in smaller flows and no overbank flooding. The Kii outlet pump ran continuously for 7 days during the November 1996 storm and for 1 to 2 days during the January 1997 storms. During all three storms, the outlet culvert valve opened and the inner ditches overtopped the flood-relief swales, allowing free outflow of water from the inner ditch. Backwater effects hindered drainage during the January 1997 storms at Hospital ditch at Kamehameha Highway, and at Punamano ditch at Nudist Camp Road (where the backflow into Punamano marsh in November 1996 constituted an extreme backwater effect). A probable marine backwater effect was imposed at the ocean outlet ditch during the November 1996 storm through a combination of high spring tides and wave setup from large surf. Whether this backwater effect propagated upstream in the ditches to affect inland sites could not be determined conclusively. A sand plug may have built up in the ocean outlet channel before the November 1996 storm, but if so, it probably washed out prior to, or early in the storm, and was not present at the time of peak stage at inland sites. A season-long buildup of the sand plug in late 1997 was inferred from rising water levels in the outlet ditch. Seawater flows up the outlet channel or over the sand berm and into the outer ditch system on most high tides, and particularly during spring high tides. Ponds and ditches of the Refuge and surrounding lowlands have mud- and clay-lined bottoms that form an effective confining unit and inhibit interaction with an underlying shallow limestone aquifer. At Kii Unit, pond levels are higher than adjacent ditch levels and underlying ground-water levels, establishing lateral and downward head gradients that could foster seepage losses from the ponds. Regional ground-water discharge from the Koolau aquifer to the coastal-plain sediments is mostly diffuse, but is concentrated where ridges of Koolau Basalt plunge beneath coastal-plain sediments near Punamano Unit and at the head of Hospital ditch. Kii ditch gains brackish ground water downstream of Kamehameha Highway. Wastewater disposal from the sewage treatment plant adjoining Kii Unit poses little or no threat to Refuge habitat. Disposal is at six injection wells located 0.45 mi away at Kahuku, and the wells inject into confined limestone aquifers that do not extend to Kii Unit. The natural freshwater supply to Punamano Unit is adequate for maintaining the wildlife habitat, judging from stable pond levels and low salinities there. A monthly water budget for Punamano showed an apparent annual deficit in measurable flows in 1997, requiring unmeasured ground-water gains equalling 51 inches of water. The freshwater supply to Kii Unit is inadequate according to Refuge managers, because there is not enough water to manipulate levels adequately in the ponds during most of the year, and particularly during the driest months. This is confirmed by monthly deficits in the water budget for the Kii ponds during summer months. However, the Kii budget showed an annual surplus in measurable flows for 1997 equalling 24 inches of water. Unmeasured losses are required to explain the apparent annual surplus, such as discharge to the ditches through pond water-control structures and downward and/or lateral ground-water seepage. The apparent surplus at Kii is strictly hydrologic and is not a surplus in a management sense; it cannot be stored or used to supply the Refuge, but instead reflects losses from the system that render this amount of water unavailable for use. The budget year, 1997, was drier than normal (24 percent below long-term mean rainfall) and so the measured potential evaporation for 1997 was probably higher than the long-term mean. Few metals or organic compounds of potential concern were detected in pond and ditch waters and in pond-bottom sediments. Detected pesticides were at trace levels or just above minimum reporting limits. Exceptions that exceeded quality guidelines for freshwater sediment were copper and zinc in sediment from Kii ponds C and D, and copper in sediment from Punamano north pond. Therefore, urban and agricultural runoff probably have contributed little in the way of harmful metals or organic compounds to the Refuge, although the potential for such contribution remains from periodic flooding of the ponds by ditch stormflows. Salinity was low throughout most Refuge waters, qualifying as fresh to slightly brackish and suitable for the environmental needs of Refuge fauna. Higher salinities have been observed in ditches during past periods of sugarcane cultivation and saltwater aquaculture, however. Resumption of saltwater aquaculture could raise ditch salinities if saltwater effluents are disposed directly into the ditches, as they were in the past.

Hawaii↗
USGS2025

A spatiotemporal deep learning approach for predicting daily air-water temperature signal coupling and identification of key watershed physical parameters in a montane watershed

Seasonal shifts from runoff to groundwater dominance influence daily headwater stream temperatures, especially where local groundwater input is strong. This input buffers temperature during hot periods, supporting cold-water habitats. Recent studies use air–water temperature signal metrics to identify zones of strong stream–groundwater connectivity. While Previous studies used air–water signal ratios as proxies for groundwater influence but were limited to specific sites and periods, without dynamic forecasting. This study is the first to forecast daily A r as a spatiotemporal signal using a Graph Convolutional Network–Long Short-Term Memory (GCN-LSTM) model. The model was trained using hydroclimate data (air temperature, precipitation, shortwave radiation, streamflow) and watershed physical features (e.g., sand content, slope). Results showed high predictive skill, achieving R 2 (NSE, RMSE) of 0.86 (0.73, 0.0004) for one-day-ahead to 0.52 (0.50, 0.0009) for seven-days ahead forecasts. Prior studies often have not explicitly incorporated spatial hydrogeologic drivers, but this model explicitly incorporates them to assess their impact on A r forecasting and stream-groundwater connectivity. Feature analysis identified mean sand, elevation, slope, clay, and TWI as key predictors of A r . Stronger groundwater signals appeared in hillslopes, elevations, and tributaries, highlighting watershed influence on streamflow. However, limitations include reliance on historical air–water temperature patterns for training and limited representation of extreme climate conditions. Despite these limitations, unlike previous studies relying on measured in-situ stream and air temperature, this study forecasts A r directly from climate and physiographic features after training, avoiding in-situ data requirements. Findings aiding predictions of stream ecosystem resilience.

New York↗
USGS2026

Effects of groundwater withdrawals for water bottling and municipal use, Wards Brook Valley, Maine and New Hampshire

Hydrologic models for the Wards Brook valley near Fryeburg, Maine were developed for historical (2016 – 2021) and hypothetical future conditions (2046 – 2065 and 2080 – 2099) to understand the effects of groundwater withdrawals for bottled water and municipal use on hydrologic conditions (stream base flows and groundwater levels). Analyses showed that the simulated base flows in Wards Brook were reduced because of pumping for both municipal water supplies and for water bottling, and about half of the total pumping impact on the base flows in Wards Brook was from the bottled water extraction. Simulated flows were greater than the minimum recommended streamflow of 2,180 cubic meters per day (400 gallons per minute) throughout the historical period. Simulated groundwater levels at two of three nearby ponds (Round Pond and Davis Pond) were minimally affected by pumping conditions, and effects were primarily from the municipal well closest to the ponds. Several estimates of future projected recharge were used to understand the potential effects of groundwater withdrawals on hydrologic conditions under multiple hypothetical climate conditions. Annual projected recharge rates in the mid- and late-21st century from two climate scenarios (stabilized greenhouse-gas emissions and high greenhouse-gas emissions) were similar to rates for 2016 – 2021. However, monthly recharge patterns for the future periods shifted toward more recharge in the winter months (December, January, and February) and less recharge in April, May, and October relative to 2016 – 2021. The lowest mean monthly base flows from the future emission scenarios all remain larger than the minimum recommended streamflow and indicate no long-term declines in flow relative to historical conditions. However, simulated base flows during hypothetical 3-year drought scenarios declined below minimum recommended streamflow during the summer months in the stabilized- and high-emission scenarios in the mid-21st century. Although water is generally plentiful in the Wards Brook valley, reduced pumping may be needed to maintain streamflows in Wards Brook under future climate conditions similar to modeled drought scenarios.

EarthArXiv↗
USGS2025

The systematics of stable hydrogen (δ2H) and oxygen (δ18O) isotopes and tritium (3H) in the hydrothermal system of the Yellowstone Plateau volcanic field, USA

To improve our understanding of hydrothermal activity on the Yellowstone Plateau volcanic field, we collected and analyzed a large data set of δ 2 H, δ 18 O, and the 3 H concentrations of circum-neutral and alkaline waters. We find that (a) hot springs are fed by recharge throughout the volcanic plateau, likely focused through fractured, permeable tuff units. Previous work had stressed the need for light δ 2 H water recharge restricted to the northern part of the plateau or recharge during past cold periods. However, new data from the Y-7 drill hole suggests that recharge is not restricted to a certain area or a cold period. (b) δ 18 O values of thermal waters in the geyser basins are shifted from the global meteoric water line by temperature-dependent water-rock reactions with higher subsurface temperatures resulting in a greater shift. (c) Large temporal variations in the isotopic composition of meteoric water recharge and small temporal variability in the isotopic composition of hot spring discharge implies that the volume of groundwater in, and around the Yellowstone caldera is substantially larger than the volume of annual water recharge. (d) Hot springs discharged through different rhyolitic units correlate with identifiable differences in δ 2 H and δ 18 O compositions, 3 H concentrations, and water chemistry that imply equilibration at different temperatures and travel along different flow paths. (e) Based on measured 3 H concentrations, we calculate that hot spring waters in the central part of the geyser basins mostly contain <2% post-1950 meteoric water, whereas waters discharged at the basin margins contain larger fractions of post-1950s meteoric water.

Wyoming↗
USGS2025

Groundwater hydrology, groundwater and surface-water interactions, water quality, and groundwater-flow simulations for the Wet Mountain Valley alluvial aquifer, Custer and Fremont Counties, Colorado, 2017–19

In 2017, the U.S. Geological Survey, in cooperation with the Upper Arkansas Water Conservancy District, began a study to provide a comprehensive analysis of the Wet Mountain Valley alluvial aquifer, Custer and Fremont Counties, Colorado. The study included collection of data pertaining to groundwater hydrology, groundwater and surface-water interactions, and water quality in the alluvial aquifer. In addition to providing foundational information on the hydrology of the alluvial aquifer, a numerical groundwater-flow model was developed to estimate the potential effects of additional storage of groundwater in the alluvial aquifer. Groundwater-level elevation data from 30 wells were used to estimate groundwater-flow directions in the alluvial aquifer, which were generally from the southwest to northeast, away from the Sangre de Cristo Mountains and towards perennial streams in the center of the valley. Although some seasonal variation was apparent in groundwater-level elevation records, no statistically significant seasonal trends were indicated. Statistically significant long-term trends were indicated in groundwater-level elevation records for 8 of the 30 wells, and of these wells with statistically significant trends, all but 1 indicated a negative trend of groundwater-level elevations. Spatial evaluation of wells with statistically significant negative groundwater-level elevation trends showed many are in areas of denser well drilling for domestic or other uses, indicating increasing groundwater use could potentially be causing groundwater-level elevation declines. There were instances of wells with no statistically significant groundwater-level elevation trends also located in areas of greater density of well completions. Additional investigations may be necessary to more fully characterize the processes responsible for negative groundwater-level elevation trends. Streamflow gain or loss calculations were completed for low flow in 2017–19 and for high flow in 2018 in nine reaches of streams within the study area. Stream reaches of the upper Texas Creek, upper Grape Creek, upper-middle Grape Creek, and Taylor Creek displayed consistent streamflow loss in each period from 2017 to 2019. These stream reaches represent long-term sources of recharge to the alluvial aquifer. Streamflow gain or loss varies through time in other stream reaches (lower Texas Creek, lower-middle Grape Creek, lower Grape Creek below Westcliffe, and lower Grape Creek above DeWeese Reservoir). The temporally variable behavior indicates these stream reaches may be sources of groundwater recharge or areas of groundwater discharge, likely depending on temporal dynamics between the elevation of the water table and the stream. Water-quality samples were collected from 10 groundwater wells and 10 stream sites during September through November 2019. All groundwater and stream samples were analyzed for major and trace elements and stable isotopes of water. A subset of groundwater samples was also analyzed for the environmental tracers sulfur hexafluoride, tritium, and noble gases. Comparison of water-quality results to U.S. Environmental Protection Agency drinking water-quality standards indicated no constituents exceeded primary standards for human health. Spatial evaluation of water quality indicated the concentrations of various constituents are likely controlled by groundwater and surface-water interactions and by spatial variability in bedrock geology underlying the alluvial aquifer. Specifically, streams shown to gain from groundwater had water chemistry constituent compositions similar to groundwater, whereas streams exiting the Sangre de Cristo Mountains tended to have compositions consistent with snowmelt. Groundwater geochemistry appeared to be partially controlled by oxidation-reduction processes and by proximity to igneous rocks in the Wet Mountains. Environmental tracers used to estimate groundwater age indicated all sampled groundwater contained tracers representing modern recharge (approximately less than 65 years old) but mixing of premodern recharge (approximately more than 65 years old) also occurs. Spatial evaluation of environmental tracers indicated large faults may be conduits for upwelling of older groundwater. No trends were observed in groundwater age with well depth, indicating all sampled wells are located within the zone of active groundwater flow. The presence of modern groundwater in wells with statistically significant negative groundwater-level elevation trends indicates groundwater storage depletions may be partially offset by capture of modern recharge. Repeated sampling of groundwater age would be necessary, however, to determine if any trends in groundwater age exist, which may indicate changing groundwater recharge, storage, or discharge. Additional investigations could also consider quantifying groundwater age in deeper wells to more fully define the depth of active groundwater flow. A numerical groundwater-flow model was developed to estimate components of the water budget, simulate groundwater and surface-water interactions, and evaluate the potential effects of aquifer storage and recovery. Simulated groundwater-level elevations from the calibrated groundwater-flow model are similar to the observed pattern of groundwater-level elevations with higher elevations in the western part of the study area along the Sangre de Cristo Mountains. Simulated water-budget components indicate most of the recharge to the alluvial aquifer is derived from streamflow losses, which is consistent with observations of losing streams along the mountain front. The largest groundwater discharge component of the alluvial aquifer was to streams in the center of the valley, where observations of stream gain or loss indicated the predominance of gaining conditions. Comparison of groundwater and surface-water interactions between the calibrated groundwater-flow model for 2000-19 (the base-case model) and a simulation including additional recharge, representing potential aquifer storage and recovery operations, indicated the additional recharge distributed throughout the area had minimal effects on streamflow in the nearby Grape Creek. An analysis of subregional groundwater budgets showed approximately 54 percent of the additional recharge flowed back to nearby Grape Creek, and the other 46 percent was distributed laterally into adjacent cells in the alluvial aquifer. The comparison of simulations and subregional water budget show the additional recharge did not substantially alter groundwater-level elevations or basin wide groundwater storage. Although the analysis of additional recharge provided in the numerical groundwater-flow model considers only one of many possible recharge scenarios, the model provides a useful tool that could be modified for various scenarios to understand potential effects of managed aquifer recharge.

Colorado↗
USGS2025

Geochemistry and Soils of the Big Smoky Valley Fens, Nevada

Fens are groundwater-fed wetlands that can provide habitat for plants and animals. Due to anthropogenic activities and climate change, many fens around the world are at risk. This paper presents the results of a study of the hydrology and geochemistry of fens in Big Smoky Valley, central Nevada to support the Bureau of Land Management’s activities in the area. A water sample from the largest fen in the study area was analyzed for its water chemistry and compared to a nearby alluvial aquifer and hot spring. The high SiO 2 concentration of the fen sample implies that the fen water may originate from geothermal water. A soil core was taken to analyze radiocarbon age and soil type. A majority of the core was composed of silt and clay interlayered with water-filled voids. Changes in the character of the clay with depth suggest that there may have been changes in the depositional environment over time. Radiocarbon dating of Ruppia seeds showed longevity of the fen, with the minimum 14 C age of the core as 4,375±40 years. This paper provides reconnaissance-level information on the Big Smoky Valley fens, but further information would be needed to better understand the source of water to the fens or how the fen environment has changed over time with climate.

Nevada↗
USGS2025

Assessing flood water infiltration and storage in a restored floodplain

In urban areas, floodplain restoration is gaining prominence as a strategy for restoring the natural functions of floodplain ecosystems and reducing flood risk. This has spurred research into potential interactions between floodwaters, the hyporheic zone, and the floodplain aquifer. An urban restored stream in Wisconsin, USA, was used as a case study to examine four methods to estimate floodplain infiltration and storage during overbank floods. We characterised flood-related infiltration over a 4-year period from 2018 through 2021 by simultaneously and continuously measuring groundwater levels and vertical temperature profiles with stream water levels linked to high-resolution flood inundation maps. High-resolution topographic data helped to quantify surface floodplain storage and the unsaturated soil volume relative to flood stage. Infiltration estimates from the simple methods align well with those from the more complex methods; however, the complex methods provide additional insights about the factors influencing infiltration. Results from all methods indicate that the volume of water that vertically infiltrates during floods is likely small relative to the total volume of the flood, with 0.08%–0.52% of flood water infiltrating into the floodplain, on average. Spatially variable vertical hydraulic gradients, driven by flood depth, groundwater level, and permeability, imply heterogeneous patterns of infiltration across the floodplain. Gradients favourable for infiltration typically occurred during the onset of flooding but, over the study period, were mostly (98% of the time) favourable for groundwater discharge to the channel (non-flood periods). These findings highlight the importance of considering surface-groundwater dynamics, floodplain soils, and unsaturated floodplain volume in defining the benefits of floodplain infiltration for flood attenuation.

Wisconsin↗
USGS2026

Scenarios to assess the future water availability in the Mississippi River Valley Alluvial Aquifer for the Cache River and Grand Prairie Regions of Arkansas

The U.S. Geological Survey, as part of the Arkansas Groundwater Initiative, developed forecast scenarios using previously calibrated MODFLOW 6 groundwater models that focused on the Cache and Grand Prairie Critical Groundwater Areas to assess the impact of future climate and water management strategies on the Mississippi River Valley alluvial aquifer. A Soil Water Balance model was used to forecast recharge and irrigation water use. The forecast scenario period was from January 1, 2019, through December 31, 2055, with monthly stress periods. Twenty scenarios were simulated and included seven alternate climate forecasts, five 13 general groundwater pumping reduction scenarios (round 1), and groundwater pumping reduction scenarios by crop type and for the Bayou Meto Water Management Project and Grand Prairie Area Demonstration Project (round 2). Declines in saturated thickness within the Cache Critical Groundwater Area were larger for 18 of the 20 scenarios as compared to outside of the Critical Groundwater Area. The largest average increase in saturated thickness inside the Critical Groundwater Area was 6.4 m which occurred for the round 1, 50 percent reduction scenario. Automatic reductions in groundwater pumping by MODFLOW 6 in the Cache simulation ranged from 0.02 to 13.1 percent of total groundwater pumping. For the Grand Prairie model domain, the average change in saturated thickness of the Mississippi River Valley alluvial aquifer inside the Critical Groundwater Area for the forecast period ranged between -6.6 to 1.7 m. The average saturated thickness of the Mississippi River Valley alluvial aquifer inside the Grand Prairie Critical Groundwater Area declined for 16 of the 20 scenarios. The average reduction in requested groundwater pumping for all scenarios inside the Grand Prairie Critical Groundwater Area was 25.1 percent, and the largest reduction was 46.5 percent.

ESS Open Archive↗
USGS2024

Assessing potential effects of oil and gas development activities on groundwater quality near and overlying the Elk Hills and North Coles Levee Oil Fields, San Joaquin Valley, California

Groundwater resources are utilized near areas of intensive oil and gas development in California’s San Joaquin Valley. In this study, we examined chemical and isotopic data to assess if thermogenic gas or saline water from oil producing formations have mixed with groundwater near the Elk Hills and North Coles Levee Oil Fields in the southwestern San Joaquin Valley. Major ion concentrations and stable isotope compositions were largely consistent with natural processes, including mixing of different recharge sources and water-rock interactions. Trace methane concentrations likely resulted from microbial rather than thermogenic sources. Trace concentrations of benzene and other dissolved hydrocarbons in three wells had uncertain sources that could occur naturally or be derived from oil and gas development activities or other anthropogenic sources. In the mid-1990s, two industrial supply wells had increasing Cl and B concentrations likely explained by mixing with up to 15 percent saline oil-field water injected for disposal in nearby injection disposal wells. Shallow groundwater along the western margin of Buena Vista Lake Bed had elevated Cl, B, and SO 4 concentrations that could be explained by accumulation of salts during natural wetting and drying cycles or, alternatively, legacy surface disposal of saline oil-field water in upgradient ephemeral drainages. This study showed that groundwater had relatively little evidence of thermogenic gas or saline water from oil and gas sources in most parts of the study area. However, the evidence for groundwater mixing with injected disposal water, and possibly legacy surface disposal water, demonstrates produced water management practices as a potential risk factor for groundwater-quality degradation near oil and gas fields. Additional studies in the San Joaquin Valley and elsewhere could improve understanding of such risks by assessing the locations, volumes, and types of produced water disposal practices used during the life of oil fields.

California↗
USGS2025

Preserving and increasing water resources—Natural infrastructure in dryland streams in Baja California Sur, Mexico

The Los Planes watershed of Baja California Sur, Mexico, and its underlying aquifer are experiencing groundwater decline owing to low average annual rainfall (28.1 centimeters per year) and rising water demand from population growth and agricultural activities. This decline in water availability can lead to desertification—a process that changes arable land to desert by degrading soil and vegetation—and can pose serious challenges to livelihoods that depend on the land. To address these issues, a ranch in the Los Planes watershed has installed many natural infrastructures in dryland streams (NIDS) in channels for soil and water conservation. In 2022, the U.S. Geological Survey (USGS) began working with regional researchers and land managers to investigate the effects of NIDS on natural biological, geochemical, and physical processes and determine the efficacy of NIDS for water augmentation in the Los Planes watershed. The USGS also worked with local academic institutions and nonprofit organizations to create public educational opportunities focused on the area’s hydrogeology. These and other collaborative efforts with the U.S. Water Partnership and Innovaciones Alumbra aim at enhancing water resources in the Baja California Sur region and promoting water security and safeguarding community well-being. Resume La cuenca de Los Planes, ubicada en Baja California Sur, México, y su acuífero subyacente, están sufriendo una disminución de las aguas subterráneas debido a la baja precipitación media anual (28.1 centímetros por año) y la alta demanda de agua por parte de una población creciente y la actividad agrícola. Esta disminución de la disponibilidad de agua puede conducir a la desertificación—un proceso que por medio de la degradación del suelo y la vegetación convierte a la tierra cultivable en desierto—representando un serio desafío para los medios de vida de las personas. Para abordar estos problemas, un rancho en la cuenca de Los Planes ha instalado numerosas obras de Infraestructura Natural en Arroyos de Tierras Áridas (INATS) para conservación del suelo y del agua. En 2022, el Servicio Geológico de los Estados Unidos (USGS, por sus siglas en inglés) comenzó a trabajar con investigadores regionales y gestores de tierras para estudiar los efectos de INATS en los procesos biológicos, geoquímicos y físicos, y determinar su eficacia en el aumento de los recursos hídricos en la cuenca de Los Planes. El USGS se ha asociado con instituciones académicas y organizaciones locales sin fines de lucro para crear oportunidades educativas públicas centradas en la hidrogeología de la zona. Estos y otros esfuerzos colaborativos con la Asociación del Agua de Estados Unidos (U.S. Water Partnership) e Innovaciones Alumbra, tienen como objetivo mejorar el uso de los recursos hídricos en la región de Baja California Sur, promover la seguridad hídrica y proteger el bienestar de la comunidad.

Baja California Sur↗
USGS1977

Leachate plumes in ground water from Babylon and Islip landfills, Long Island, New York

Landfills operated by the Towns of Babylon and Islip in southwest and central Suffolk County contain urban refuse, incinerated garbage, and scavenger (cesspool) waste; some industrial refuse is deposited at the Babylon site. The Islip landfill was started in 1933, the Babylon landfill in 1947. The landfills are in contact with and discharge leachate into the highly permeable upper glacial aquifer (hydraulic conducitvity 190 to 500 ft/d [feet per day]). The aquifer is 74 feet thick at the Babylon landfill and 170 feet thick at the Islip landfill. The leachate-enriched water occupies the entire thickness of the aquifer beneath both landfills, but hydrologic boundaries retard downward migration of the plumes to deeper aquifers. The Babylon plume is 1,900 feet wide at the landfill and narrows to about 700 feet near its terminus 10,000 feet from the landfill. The Islip plume is 1,400 feet wide at the landfill and narrows to 500 feet near its terminus 5,000 feet from the landfill. Hydrochemical maps and sections show the distribution of the major chemical constituents of the plumes. The most highly leachate-enriched ground water obtained was from the Babylon site; it contained 860 mg/L (milligrams per liter) sodium, 110 mg/L potassium, 565 mg/L calcium, 100 mg/L magnesium, 2,700 mg/L bicarbonate, and 1,300 mg/L chloride. Sulfate was notably absent or in low concentration in most parts of both plumes. Nitrogen in plume water was mostly in the form NH4+, and concentrations as high as 90 mg/L were found; concentrations of nitrogen as N in the plume were less than 10 mg/L. As much as 440 mg/L iron and 190 mg/L manganese were found in the leachate-enriched water. Samples were also tested for arsenic, boron, cadmium, cobalt, chromium, copper, mercury, nickel, lead, selenium, strontium, and zinc. Boron was more or less ubiquitous and was found in concentrations as high as 2 mg/L. Organic carbon was found in concentrations as high as 2,250 mg/L in the most highly leachate-enriched water but attenuated rapidly to less than 20 mg/L. Dissolved-solids concentrations near the landfills were between 400 and 3,000 mg/L at Babylon and between 500 and 1,500 mg/L at Islip. Ground-water temperatures near the landfills exceed those in ambient water by as much as 7°C at Babylon and 16°C at Islip. Heat contributed by the landfills was mostly dissipated within 0.4 mi of the landfill, butat Islip, the warm leachate-enriched water extended 0.5 mi downgradient. The entrance of leachate into the less dense ground water as pulsations after rainfall may explain the presence of high leachate enrichment near the bottom of the aquifer. A comparison of the physical characteristics of leachate-enriched ground water with those of ambient water suggests that the downward movement of leachate results from its greater density. Simulation of the movement and dispersion of the Babylon plume with a mathematical dispersion model indicated the coefficient of longitudinal dispersion to be about 60 ft 2 /d (feet squared per day) and the ground-water velocity to be 1 ft/d. However, the velocity determined from the hydraulic gradient and public-supply wells in the area was 4 ft/d, which would cause a plume four times as long as that predicted by the mathmatical dispersion model. At the Islip site, the plume was one-third the length calculated on the basis of the age of the landfill. The shortness of the plumes has not been explained; it may be a result of the leachate's having been too dilute to form a plume during the early years of the landfills.

New York↗
USGS2025

Sources of water and salts for the Zuni Salt Lake in west-central New Mexico

The Zuni Salt Lake is located in a maar in west-central New Mexico and contains hypersaline water that has long been used by Native Americans for religious purposes and the collection of salt. There have been several investigations suggesting different sources for the water and salt to the lake. Springs, seeps, and ephemeral streamflow have all been observed to contribute freshwater to the lake, and brackish to hypersaline seeps have been documented along the banks of the lake. This report summarizes the findings of a study that characterizes the lake’s hydrology, its water and salinity sources, and the hydrogeologic conceptual model. Regional groundwater levels indicate that each of the aquifers in the area have the potential to discharge groundwater to the lake. There is also evidence of vertical groundwater flow pathways at the maar that were likely created by the igneous intrusion that fractured the intersecting aquifers. A detailed water budget was constructed from continuous lake stage, precipitation, and evaporation data to estimate the groundwater inflow to the Zuni Salt Lake. It was determined that groundwater inflow to the lake is 441 ±94 acre-feet per year, which composes as much as 77 percent of the total inflows. The high sodium and chloride concentrations measured in two hypersaline samples collected near the lake indicate that the majority of the dissolved solids entering the lake are from a hypersaline groundwater source. The geochemical and isotopic compositions measured in the lake and surrounding features support the interpretation that hypersaline groundwater is the primary source of salts to the lake, which is likely sourced from the older (and deeper) Permian units. The hypersaline groundwater samples collected during this investigation have a unique aqueous chemistry relative to each of the mapped aquifers, and variability in groundwater compositions is interpreted to result from differences in minerology and residence time.

New Mexico↗