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Lead and cadmium associated with saltwater intrusion in a New Jersey aquifer system

The U.S. Geological Survey collected ground-water samples from the upper and middle aquifers of the Potomac-Raritan-Magothy aquifer system in a 400-square-mile area of New Jersey from 1984 through 1986. Concentrations of lead were greater than the U.S. Environmental Protection Agency maximum contaminant level (MCL) of 50 micrograms per liter in water from 16 to 239 wells. The concentrations of cadmium were greater than the MCL of 10 micrograms per liter in water from 10 to 241 wells. One-half of the wells that exceeded the lead MCL were in known areas of saltwater intrusion, as were all 10 wells that exceeded the cadmium MCL. The association of elevated concentrations of these metals with elevated concentrations of chloride indicates a mechanism related to saltwater intrusion.

Water Resources Bulletin

Preservation of samples for dissolved mercury

Water samples for dissolved mercury requires special treatment because of the high chemical mobility and volatility of this element. Widespread use of mercury and its compounds has provided many avenues for contamination of water. Two laboratory tests were done to determine the relative permeabilities of glass and plastic sample bottles to mercury vapor. Plastic containers were confirmed to be quite permeable to airborne mercury, glass containers were virtually impermeable. Methods of preservation include the use of various combinations of acids, oxidants, and complexing agents. The combination of nitric acid and potassium dichromate successfully preserved mercury in a large variety of concentrations and dissolved forms. Because this acid-oxidant preservative acts as a sink for airborne mercury and plastic containers are permeable to mercury vapor, glass bottles are preferred for sample collection. To maintain a healthy work environment and minimize the potential for contamination of water samples, mercury and its compounds are isolated from the atmosphere while in storage. Concurrently, a program to monitor environmental levels of mercury vapor in areas of potential contamination is needed to define the extent of mercury contamination and to assess the effectiveness of mercury clean-up procedures.Water samples for dissolved mercury require special treatment because of the high chemical mobility and volatility of this element. Widespread use of mercury and its compounds has provided many avenues for contamination of water. Two laboratory tests were done to determine the relative permeabilities of glass and plastic sample bottles to mercury vapor. Plastic containers were confirmed to be quite permeable to airborne mercury, glass containers were virtually impermeable. Methods of preservation include the use of various combinations of acids, oxidants, and complexing agents. The combination of nitric acid and potassium dichromate successfully preserved mercury in a large variety of concentrations and dissolved forms.

Water Resources Bulletin

Manganese oxidation model for rivers

The presence of manganese in natural waters (>0.05 mg/L) degrades water-supply quality. A model was devised to predict the variation of manganese concentrations in river water released from an impoundment with the distance downstream. The model is one-dimensional and was calibrated using dissolved oxygen, biochemical oxygen demand, pH, manganese, and hydraulic data collected in the Duck River, Tennessee. The results indicated that the model can predict manganese levels under various conditions. The model was then applied to the Chattahoochee River, Georgia. Discrepancies between observed and predicted may be due to inadequate pH data, precipitation of sediment particles, unsteady flow conditions in the Chattahoochee River, inaccurate rate expressions for the low pH conditions, or their combinations.

Water Resources Bulletin

Spreadsheet WATERSHED modeling for nonpoint-source pollution management in a Wisconsin basin

Although several sophisticated nonpoint pollution models exist, few are available that are easy to use, cover a variety of conditions, and integrate a wide range of information to allow managers and planners to assess different control strategies. Here, a straightforward pollutant input accounting approach is presented in the form of an existing model (WATERSHED) that has been adapted to run on modern electronic spreadsheets. As an application, WATERSHED is used to assess options to improve the quality of highly eutrophic Delavan Lake in Wisconsin. WATERSHED is flexible in that several techniques, such as the Universal Soil Loss Equation or unit-area loadings, can be used to estimate nonpoint-source inputs. Once the model parameters are determined (and calibrated, if possible), the spreadsheet features can be used to conduct a sensitivity analysis of management options. In the case of Delavan Lake, it was concluded that, although some nonpoint controls were cost-effective, the overall reduction in phosphorus would be insufficient to measurably improve water quality.A straightforward pollutant input accounting approach is presented in the form of an existing model (WATERSHED) that has been adapted to run on modern electronic spreadsheets. As an application, WATERSHED is used to assess options to improve the quality of highly eutrophic Delavan Lake in Wisconsin. WATERSHED is flexible in that several techniques, such as the Universal Soil Loss Equation or unit-area loadings, can be used to estimate nonpoint-source inputs. Once the model parameters are determined (and calibrated, if possible), the spreadsheet features can be used to conduct a sensitivity analysis of management options. In the case of Delavan Lake, it was concluded that, although some nonpoint controls were cost-effective, the overall reduction in phosphorus would be insufficient to measurably improve water quality.

Water Resources Bulletin

Comparison of methods for estimating flood magnitudes on small streams in Georgia

The U.S. Geological Survey has collected flood data for small, natural streams at many sites throughout Georgia during the past 20 years. Flood-frequency relations were developed for these data using four methods: (1) observed (log-Pearson Type III analysis) data, (2) rainfall-runoff model, (3) regional regression equations, and (4) map-model combination. The results of the latter three methods were compared to the analyses of the observed data in order to quantify the differences in the methods and determine if the differences are statistically significant.

Water Resources Bulletin

Effects of municipal wastewater discharges on aquatic communities, Boise River, Idaho

Aquatic communities in the Boise River were examined from October 1987 to March 1988 to determine whether they were adversely affected by trace elements in effluents from two Boise wastewater treatment facilities. Trace-element concentrations in the Boise River were less than or near analytical-detection levels and were less than chronic toxicity criteria when detectable. Insect communities colonizing artificial substrates upstream and downstream from the wastewater treatment facilities were strongly associated, and coefficients of community loss indicated that effluents had benign enriching effects. The distributions of trace-element-intolerant mayflies indicated that trace-element concentrations in effluents did not adversely affect intolerant organisms in the Boise River. Condition factor of whitefish was significantly increased downstream from the Lander Street wastewater treatment facility and was significantly decreased downstream from the West Boise wastewater treatment facility.

Water Resources Bulletin

Climate factor for small-basin flood frequency

A climate factor, CT, (T = 2-, 25-, and 100-year recurrence intervals) that delineates regional trends in small-basin flood frequency was derived using data from 71 long-term rainfall record sites. Values of CT at these sites were developed by a regression analysis that related rainfall-runoff model estimates of T-year floods to a sample set of 50 model calibrations. CT was regionalized via kriging to develop maps depicting its geographic variation for a large part of the United States east of the 105th meridian. Kriged estimates of CT and basin-runoff characteristics were used to compute regionalized T-year floods for 200 small drainage basins. Observed T-year flood estimates also were developed for these sites. Regionalized floods are shown to account for a large percentage of the variability in observed flood estimates with coefficients of determination ranging from 0.89 for 2-year floods to 0.82 for 100-year floods. The relative importance of the factors comprising regionalized flood estimates is evaluated in terms of scale (size of drainage area), basin-runoff characteristics (rainfall-runoff model parameters), and climate (CT).

Water Resources Bulletin

Effects of climatic change on the Thornthwaite moisture index

The Thornthwaite moisture index is a useful indicator of the supply of water (precipitation) in an area relative to the demand for water under prevailing climatic conditions (potential evapotranspiration). This study examines the effects of changes in climate (temperature and precipitation) on the Thornthwaite moisture index in the conterminous United States. Estimates of changes in mean annual temperature and precipitation for doubled-atmospheric CO2 conditions derived from three general circulation models (GCMs) are used to study the response of the moisture index under steady-state doubled-CO2 conditions. Results indicate that temperature and precipitation changes under doubled-CO2 conditions generally will cause the Thornthwaite moisture index to decrease, implying a drier climate for most of the United States. The pattern of expected decrease is consistent among the three GCMs, although the amount of decrease depends on which GCM climatic-change scenario is used. Results also suggest that changes in the moisture index are related mainly to changes in the mean annual potential evapotranspiration as a result of changes in the mean annual temperature, rather than to changes in the mean annual precipitation.

Water Resources Bulletin

Application of the DR3M watershed model on a small urban basin

Data collected at a 79-acre urban watershed in Albuquerque, New Mexico, were used to calibrate and verify the Distributed Routing Rainfall-Runoff Model, a parametric watershed model. Standard errors of estimate for the 38 calibration storms were 33 percent and 38 percent, respectively, for volumes and peaks; and for the 46 verification storms were 29 percent and 37 percent, respectively, for volumes and peaks. Correlation coefficients for peaks were 0.8 and 0.95, respectively, for calibration and verification storms.

Water Resources Bulletin

Fast algorithm for automatically computing Strahler stream order

An efficient algorithm was developed to determine Strahler stream order for segments of stream networks represented in a Geographic Information System (GIS). The algorithm correctly assigns Strahler stream order in topologically complex situations such as braided streams and multiple drainage outlets. Execution time varies nearly linearly with the number of stream segments in the network. This technique is expected to be particularly useful for studying the topology of dense stream networks derived from digital elevation model data.

Water Resources Bulletin

Effects of advanced wastewater treatment on the quality of White River, Indiana

In 1983, the City of Indianapolis, Indiana, completed construction of advanced wastewater treatment (AWT) systems to enlarge and upgrade its existing Belmont Road and Southport Road secondary treatment plants. A nonparametric statistical procedure, a modified form of the Wilcoxon-Mann-Whitney rank-sum test, was used to test for trends in water quality at two upstream and two downstream sites on White River and at the two treatment plants. Results comparing the pre- (1978-1980) and post- (1983-1988) AWT periods show statistically significant improvements in the quality of the treated effluent and of the White River downstream from the plants. Water quality at sites upstream from the city was relatively constant during the period of study. Total ammonia (as N) decreased 14.6 mg/L and BOD5 (five-day biochemical oxygen demand) decreased 10 to 19 mg/L in the two effluents. Total ammonia in the river downstream from the plants decreased 0.8 to 1.9 mg/L and BOD5 decreased 2.3 to 2.5 mg/L. Nitrate (as N) increased 14.5 mg/L in the plant effluents and 2.0 to 2.4 mg/L in the river because of in-plant nitrification. Dissolved oxygen concentration in the river increased about 3 mg/L because of reduced oxygen demand for nitrification and biochemical oxidation processes.

Indiana

Identification of dissolved-constituent sources in mine-site ground water using batch mixing

Batch-mixing experiments were used to help identify lithologic and mineralogic sources of increased concentrations of dissolved solids in water affected by surface coal mining in northwestern Colorado. Ten overburden core samples were analyzed for mineral composition and mixed with distilled water for 90 days until mineral-water equilibrium was reached. Between one day and 90 days after initial contact, specific conductance in the sample mixtures had a median increase of 306 percent. Dissolved-solids concentrations ranged from 200 to 8,700 mg/L in water samples extracted from the mixtures after 90 days. Mass-balance simulations were conducted using the geochemical models BALANCE and WATEQF to quantify mineral-water interactions occurring in five selected sample mixtures and in water collected from a spring at a reclaimed mine site. The spring water is affected by mineral-water interactions occurring in all of the lithologic units comprising the overburden. Results of the simulations indicate that oxidation of pyrite, dissolution of dolomite, gypsum, and epsomite, and cation-exchange reactions are the primary mineral-water interactions occurring in the overburden. Three lithologic units in the overburden (a coal, a sandstone, and a shale) probably contribute most of the dissolved solids to the spring water. Water sample extracts from mixtures using core from these three units accounted for 85 percent of the total dissolved solids in the 10 sample extracts. Other lithologic units in the over-burden probably contribute smaller quantities of dissolved solids to the spring water.

Water Resources Bulletin

Geochemical characterization of streambed sediment in the upper Illinois River basin

Geochemistry of fine-fraction streambed sediments collected from the upper Illinois River basin was surveyed in the fall of 1987 as part of the U.S. Geological Survey National Water-Quality Assessment pilot projects. The survey included 567 samples analyzed for 46 elements. Three distinctive distribution patterns were found for seven U.S. Environmental Protection Agency priority pollutants surveyed, as well as for boron and phosphorus: (1) enrichment of elements in the Chicago urban area and in streams draining the urban area relative to rural areas, (2) enrichment in main stems relative to tributaries, and (3) enrichment in low-order streams at high-population-density sites relative to low-population-density sites. Significant differences in background concentrations, as measured by samples from low-order streams, were observed among five subbasins in the study area. Uncertain geochemical correspondence between low-order, background sites and high-order, generally metal enriched sites prevented determination of background levels that would be appropriate for high-order sites. The within-sample ratio of enriched elements was variable within the Chicago area but was constant in the Illinois River downstream from Chicago. Element ratios imply a composite fine-fraction sediment in the Illinois River of 35-40 percent Des Plaines River origin and 60-65 percent Kankakee River origin.

Water Resources Bulletin

Variations in northern Sierra Nevada streamflow. Implications of climate change

Historical records of streamflow for an eastward- and a westward-draining stream in the northern Sierra Nevada have been analyzed for evidence of changes in runoff characteristics and patterns of variability. A trend of increasing and more variable winter streamflow began in the mid-1960s. Mean monthly streamflow during December through March was substantially greater for water years 1965-1990 compared to water years 1939-1964. Increased winter and early-spring streamflow during the later period is attributed to small increases in temperature, which increase the rain-to-snow ratio at lower altitudes and cause the snowpack to melt earlier in the season at higher altitudes. The timing of snowmelt runoff on the western slope of the Sierra Nevada is more sensitive than it is on the eastern slope to changes in temperature, owing to predominantly lower altitudes on the west side. This difference in sensitivity suggests that basins on the east side of the Sierra Nevada have a more reliable water supply (as snow storage) than western-slope basins during warming trends.

Water Resources Bulletin

Simulation and mapping of soil-water conditions in the Great Plains

Soil-water conditions provide valuable insight into the hydrologic system in an area. A soil-water balance quantitatively summarizes soil-water conditions and is based on climatic, soil, and vegetation characteristics that vary spatially and temporally. Soil-water balances in the Great Plains of the central United States were simulated for 1951-1980. Results of the simulations were mean annual estimates of infiltration, runoff, actual evapotranspiration, potential recharge, and consumptive water and irrigation requirements at 152 climatic data stations. A method was developed using a geographic information system to integrate and map the simulation results on the basis of spatially variable climatic, soil, and vegetation characteristics. As an example, simulated mean annual potential recharge was mapped. Mean annual potential-recharge rates ranged from less than 0.5 inch in much of the north-central and southwestern Great Plains to more than 10 inches in parts of eastern Texas and southwestern Arkansas.

Water Resources Bulletin

Distribution and grain-size partitioning of metals in bovfom sediments of an experimentally acidified Wisconsin lake

A study of concentrations and distribution of major and trace elements in surficial bottom sediments of Little Rock Lake in northern Wisconsin included examination of spatial variation and grain-size effects. No significant differences with respect to metal distribution in sediments were observed between the two basins of the lake, despite the experimental acidification of one of the basins from pH 6.1 to 4.6. The concentrations of most elements in the lake sediments were generally similar to soil concentrations in the area and were well below sediment quality criteria. Two exceptions were lead and zinc, whose concentrations in July 1990 exceeded the criteria of 50 μg/g and 100 μg/g, respectively, in both littoral and pelagic sediments. Concentrations of some elements, particularly Cu, Pb, and Zn, increased along transects from nearshore to midlake, following a similar gradient of sedimentary organic carbon. In contrast, Mn, Fe, and alkali/alkaline-earth elements were at maximum concentrations in nearshore sediments. These elements are less likely to partition to organic particles, and their distribution is more dependent on mineralogical composition, grain size, and other factors. Element concentrations varied among different sediment grain-size fractions, although a simple inverse relation to grain size was not observed. Fe, Mn, Pb, and Zn were more concentrated in a grain-size range 20–60 tm than in either the very fine or the coarse fractions, possibly because of the aggregation of smaller particles cemented together by organic and Fe/Mn hydrous-oxide coatings.

Wisconsin

Potential effects of development on flow characteristics of two streams in the Raritan River Basin, New Jersey

Parts of the Raritan River basin in central New Jersey have undergone increasing development over the last several decades. The increasing population relies on the region's ground water and surface water sources for its residential, commercial, and industrial water supply. Urbanization, regionalized wastewater‐treatment facilities, stream channel alterations, and interbasin transfers of water can all affect water availability. This pilot study was conducted to determine whether significant trends exist in the base‐flow and overland‐runoff characteristics of streams in two subbasins with different percentages of urban/built‐up land (Anderson et at ., 1976). Changes in flow characteristics that could indicate future reductions in safe water yield of the Raritan River basin were examined. Flow and flow variability of the steams draining these two subbasins have increased over time. Many of the flow measures studied experienced pronounced trend shifts about 1960. The cause of these changes cannot be readily determined from the data, nor is it clear whether the increased flow variability lies outside the natural range of flow variability of the streams draining the subbasins.

New Jersey

Sensitivity of northern Sierra Nevada streamflow to climate change

The sensitivity of streamflow to climate change was investigated in the American, Carson, and Truckee River Basins, California and Nevada. Nine gaging stations were used to represent streamflow in the basins. Annual models were developed by regressing 1961-1991 streamflow data on temperature and precipitation. Climate-change scenarios were used as inputs to the models to determine streamflow sensitivities. Climate-change scenarios were generated from historical time series by modifying mean temperatures by a range of +4??C to -4??C and total precipitation by a range of +25 percent to -25 percent. Results show that streamflow on the warmer, lower west side of the Sierra Nevada generally is more sensitive to temperature and percipitation changes than is streamflow on the colder, higher east side. A 2??C rise in temperature and a 25-percent decrease in precipitation results in streamflow decreases of 56 percent on the American River and 25 percent on the Carson River. A 2??C decline in temperature and a 25-percent increase in precipitation results in streamflow increases of 102 percent on the American River and 22 percent on the Carson River.

Water Resources Bulletin