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Summary appraisals of the nation's ground-water resources – California region

Most people in the California Region live in a semiarid or arid climate, with precipitation less than the potential evapotranspiration- environments of perennial water deficiency. The deficiency becomes most onerous during the characteristically rainless summers and during recurrent droughts that may continue for 10--20 years. However, water from winter rain and snow can be stored for use during the dry summer months, and water stored during a wet climatic period can be used in a succeeding dry period; moreover, perennial deficiency can be overcome by bringing water from areas of perennial surplus. Ground-water reservoirs have especial significance in arid and semiarid regions as repositories where water is stored or can be stored with minimum loss by evaporation. Nearly all the ground-water reservoirs of the California Region are in alluvial sediments of valleys and plains that flank the mountain ranges. The largest, underlying the vast Central Valley, occupies 10 percent of the area of the region, has an estimated usable capacity exceeding 100 million acre-feet (125 cubic kilometres), and has an annual pumpage from wells of about 13 million acre-feet (16 cubic kilometres). Another 10 percent of the region is occupied by 55 developed ground-water reservoirs that are widely distributed; aggregate annual pumpage from them is about 3 1/2 million acre-feet (4 cubic kilometres). In the southeastern desert about 60 ground-water reservoirs occupy still another 10 percent of the region; these have been explored only enough to show that most have some usable water, but current use is negligible. In northeastern California and adjacent Oregon and Nevada, ground-water reservoirs are identified only in valleys and lowlands where wells are feasible, but basaltic rocks of the Cascade Range and Modoc Plateau are excellent aquifers distributed over an area constituting about 15 percent of the region. In sum, slightly less than half the California Region is underlain by ground-water reservoirs, either in valley fill or in volcanic rocks, which can yield significant quantities of water to wells. The rest of the California Region includes the mountains, canyons, slopes, and foothills of the Sierra Nevada, Coast Ranges, and Basin Ranges, whose consolidated rocks and products of their weathering may be permeable locally but are not generally so. Here, the prevailing method of ground-water development is still mostly trial and error, and while in many places a well can yield enough water for a family, some families might have to do without amenities such as flush toilets and automatic washers. For more than half a century the California Region has led all others in North America in pumping of ground water as well as in the area, variety, yield, and export of crops irrigated by water from wells. It has led in the development and use of deep-well turbine pumps for large yield and in the drilling of water wells to great depths. At the same time, such developments have resulted in the elimination of artesian pressures that produced thousands of flowing wells in the 19th century and led to the wide distribution of "falling water tables." Also, California was first to induce encroachment of seawater into wells (in 1906); first to recognize subsidence of land caused by pumping from wells (in 1933), generating news about land sinking in San Jose, Long Beach, and along the Delta-Mendota and Friant-Kern Canals; and first to experience pollution of ground-water reservoirs by brines, chemicals, industrial wastes, and petroleum byproducts including gasoline. The region has led in research in several fields leading to solution of many of these problems. Ground-water problems developed rapidly after World War II with booming population, agriculture, industry, and water demand during several years of regionwide drought. Water levels in wells trended downward almost everywhere as a natural effect of the drought and at accelerated rates in areas of pumping for new enterprises or to supplement subnormal surface-water supplies. The declines in many pumping areas exceeded 100 feet (30 metres), and in some confined aquifers the potentiometric surface was drawn down more than 330 feet (100 metres). The depletion of ground-water storage has had "permanent" side effects, including subsidence of the land exceeding 10 feet (3 metres) in extensive areas, and seawater intrusion that ended the useful lives of many wells along the coast and as much as 6 miles (10 kilometres) inland. Some problems have been solved, but these solutions have at times created other problems. Many ground-water reservoirs have gone through one or more stages - exploration for productive aquifers, exploitation and development for use of the water, restriction to the perennial supply or "safe" yield, importation of surface water, artificial recharge of ground water, conjunctive use of surface and ground water, protection of water quality, and integrated management of use and disposal of water. This evolutionary sequence is unique for each reservoir, and so generalizations become difficult in a regional appraisal; also, the changes with time are significant and varied, and knowledge of prior events is a prerequisite in an appraisal of the resource in a specific year. As of 1970, water levels in many wells had risen significantly from the minimum levels of record reached during the 1960's or earlier; only in areas of new development and in desert areas of long-continued "mining" of nonreplenished water was ground-water storage still being depleted. Land subsidence has continued at diminishing rates and practically has come to a halt in some areas; invading seawater has been stopped or nudged back in most places where problems were significant. The current, favorable situation has been helped by climatic variations, from drought in 1945-52 and exceedingly dry years in 1959 and 1961 to above-normal precipitation in 1969 and 1970; but most of the serious problems have been solved by human efforts, including especially the implementation of the California Water Plan, transporting water from areas of perennial surplus to areas where it is used in lieu of ground water or for ground-water replenishment. All major urban areas now import water to supplement or replace the water pumped from wells. Extensive agricultural areas that formerly were irrigated solely by ground water now obtain some of their water from surface reservoirs and canals, especially in the Central Valley. With surface water available as an alternative supply, well owners can view their ground water with complacency. But complacency can lead to neglect and carelessness and consequent deterioration of the ground-water resource by pollution. Claiming heritage from the English Common Law, the existing California law grants to the landowner (riparian) and private enterprise (appropriator) rights to the water stored in ground-water reservoirs or discharged from them, including the base flow of streams. Ground-water development has been by private and local enterprise, and the California legislature has protected and encouraged local responsibility, control, and management of ground water. As to surface water, a constitutional amendment in 1928 limited riparian rights to the quantities of water that were "reasonably required for the beneficial use to be served." The surpluses have become public waters which are collected, stored, transported, and delivered under various contracts by Federal, State, and other agencies. The agencies have not stored water underground because of uncertainty as to their rights, but some local agencies have been encouraged with favorable pricing schedules to undertake the artificial recharge and management of ground-water reservoirs. Thus, conjunctive use of surface and ground water has become a matter of interagency negotiation. Of all the constraints on effective use of ground-water reservoirs, the most formidable may be the attitudes of people. Assurance of water supply is vital in areas of water deficiency, and Government has assumed increasing responsibility for the welfare of people in these areas. Unfortunately, when Government provides this assurance, most beneficiaries demand continued subsidy to the exclusion of perhaps cheaper private development. Indeed, as the water resources are presently segregated-with private rights predominant in ground water and public interest dominant in surface water-ground-water development has suffered for lack of public concern. The region has the scientific and technologic capability for effective use of groundwater reservoirs, as shown by the achievements and programs of several districts, but many districts are not organized or staffed for such comprehensive management and will need assistance and scientific expertise available from State and Federal agencies. Those agencies, in turn, may not have the scientific data that are essential to prevent haphazard activities and to enable programs to be organized for the most effective and attractive utilization of the water resources. In these days of increasing concern over pollution, existing data are generally inadequate to assess the natural deterioration of ground waters as a basis for defining pollution.

California

Analytical volcano deformation source models

Primary volcanic landforms are created by the ascent and eruption of magma. The ascending magma displaces and interacts with surrounding rock and fluids as it creates new pathways, flows through cracks or conduits, vesiculates, and accumulates in underground reservoirs. The formation of new pathways and pressure changes within existing conduits and reservoirs stress and deform the surrounding rock. Eruption products load the crust. The pattern and rate of surface deformation around volcanoes reflect the tectonic and volcanic processes transmitted to the surface through the mechanical properties of the crust.

Book chapter

Geology, mineralization, and hydrothermal alteration and relationships to acidic and metal-bearing surface waters in the Palmetto Gulch area, southwestern Colorado

The Palmetto Gulch area is affected by low pH and metal-bearing drainage from abandoned mines, and perhaps, from natural weathering around vein zones. To investigate these anthropogenic and potential natural sources of acidity and metals, we mapped the geology, veins, and hydrothermally altered areas; conducted mine dump leachate studies; and collected reconnaissance water quality data. Several small abandoned mines are present in the Palmetto Gulch area that produced small amounts of relatively high-grade silver ore from fault-controlled polymetallic vein deposits. These veins are hosted in lavas, breccias, and related volcaniclastic sediments that ponded within the 28 Ma San Juan-Uncompahgre caldera complex. These rock units generally have conformable contacts and have shallow dips to the northwest. Lava flows of pyroxene andesite, which host the Roy-Pray mine, are massive near their base and typically grade upward into tightly jointed rock with 2-15 cm joint spacing. In general, most hydrothermally altered rock within the Palmetto Gulch area is restricted to envelopes surrounding the mineralized veins and faults. Composite zones of vein-related alteration vary from about 50 to 80 m wide along the high ridgelines and narrow to less than 10 to 15 m beneath an elevation of about 5,462 m. Where unaffected by surficial oxidation, these altered zones contain as much as 7 to 10 volume percent finely-disseminated pyrite. The majority of rocks in the area were affected by regional and vein-related propylitic alteration. These greenish-colored rocks have alteration products consisting of chlorite, illite, and calcite; and feldspars are typically weakly altered. Most of these rocks have detectable amounts of calcite, while as much as 11 percent by weight was detected in samples collected during this study. The Palmetto Gulch area is affected by low pH and metal-bearing drainage from abandoned mines, and perhaps, from natural weathering around vein zones. To investigate these anthropogenic and potential natural sources of acidity and metals, we mapped the geology, veins, and hydrothermally altered areas; conducted mine dump leachate studies; and collected reconnaissance water quality data. Several small abandoned mines are present in the Palmetto Gulch area that produced small amounts of relatively high-grade silver ore from fault-controlled polymetallic vein deposits. These veins are hosted in lavas, breccias, and related volcaniclastic sediments that ponded within the 28 Ma San Juan-Uncompahgre caldera complex. These rock units generally have conformable contacts and have shallow dips to the northwest. Lava flows of pyroxene andesite, which host the Roy-Pray mine, are massive near their base and typically grade upward into tightly jointed rock with 2-15 cm joint spacing. In general, most hydrothermally altered rock within the Palmetto Gulch area is restricted to envelopes surrounding the mineralized veins and faults. Composite zones of vein-related alteration vary from about 50 to 80 m wide along the high ridgelines and narrow to less than 10 to 15 m beneath an elevation of about 5,462 m. Where unaffected by surficial oxidation, these altered zones contain as much as 7 to 10 volume percent finely-disseminated pyrite. The majority of rocks in the area were affected by regional and vein-related propylitic alteration. These greenish-colored rocks have alteration products consisting of chlorite, illite, and calcite; and feldspars are typically weakly altered. Most of these rocks have detectable amounts of calcite, while as much as 11 percent by weight was detected in samples collected during this study.

Colorado

Mesozoic magmatism and base-metal mineralization in the Fortymile mining district, eastern Alaska — Initial results of petrographic, geochemical, and isotopic studies in the Mount Veta area

We present here the initial results of a petrographic, geochemical, and isotopic study of Mesozoic intrusive rocks and spatially associated Zn-Pb-Ag-Cu-Au prospects in the Fortymile mining district in the southern Eagle quadrangle, Alaska. Analyzed samples include mineralized and unmineralized drill core from 2006 and 2007 exploration by Full Metal Minerals, USA, Inc., at the Little Whiteman (LWM) and Fish prospects, and other mineralized and plutonic samples collected within the mining district is part of the USGS study. Three new ion microprobe U-Pb zircon ages are: 210 ± 3 Ma for quartz diorite from LWM, 187 ± 3 Ma for quartz monzonite from Fish, and 70.5 ± 1.1 Ma for altered rhyolite porphyry from Fish. We also present 11 published and unpublished Mesozoic thermal ionization mass spectrometric U-Pb zircon and titanite ages and whole-rock geochemical data for the Mesozoic plutonic rocks. Late Triassic and Early Jurassic plutons generally have intermediate compositions and are slightly foliated, consistent with synkinematic intrusion. Several Early Jurassic plutons contain magmatic epidote, indicating emplacement of the host plutons at mesozonal crustal depths of greater than 15 km. Trace-element geochemical data indicate an arc origin for the granitoids, with an increase in the crustal component with time. Preliminary study of drill core from the LWM Zn-Pb-Cu-Ag prospect supports a carbonate-replacement model of mineralization. LWM massive sulfides consist of sphalerite, galena, and minor pyrite and chalcopyrite, in a gangue of calcite and lesser quartz; silver resides in Sb-As-Ag sulfosalts and pyrargyrite, and probably in submicroscopic inclusions within galena. Whole-rock analyses of LWM drill cores also show elevated In, an important metal in high-technology products. Hypogene mineralized rocks at Fish, below the secondary Zn-rich zone, are associated with a carbonate host and also may be of replacement origin, or alternatively, may be a magnetite-bearing Zn skarn. Cu-Zn-Pb-Ag-Au showings at the Oscar pros-pect occur in marble-hosted magnetite and pyrrhotite skarn that is spatially related to the stocks, dikes, and sills of the Early Jurassic syenite of Mount Veta. Mineralized rocks at the Eva Creek Ag-Zn-Pb-Cu prospect are within 1.5 km of the Mount Veta pluton, which is epidotized and locally altered along its contact with metamorphosed country rock east of the prospect. We report five new sulfide Pb-isotopic analyses from the LWM, Oscar, and Eva Creek prospects and compare these sulfide Pb-isotopic ratios with those for sulfides from nearby deposits and prospects in the Yukon-Tanana Upland and with feldspar Pb-isotopic ratios for Mesozoic plutons in the region. Disparities between the Pb-isotopic ratios for sulfides and igneous feldspars are consistent with a carbonate-replacement model for both the LWM and Eva Creek prospects. The presence in the Fortymile district of base-metal sulfides within both calc-silicate-rich skarns and the calc-silicate-free carbonate replacement deposits may reflect multistage mineralization by magmatic-hydrothermal systems during the emplacement of two or more magmatically unrelated igneous intrusions. Alternatively, all of the mineralized occurrences could be products of one regionally zoned system that formed during the intrusion of a single pluton. In addition to the likely origin of some of the base-metal occurrences by intrusion-related hydrothermal fluids, proximity of the LWM prospect to the northeast-striking, high-angle Kechumstuk Fault suggests that fluid flow along the fault also played an important role during carbonate-replacement mineralization.

Alaska

A lithologic-tectonic framework for the metallogenic provinces of California

The lithologic-tectonic framework of California developed principally during Mesozoic time when various terranes of oceanic crust and island-arc crust were accreted to older sialic crust, resulting in westward growth of the continent. Emplacement of great batholithic masses of granitoid rocks cutting all these crustal types also took place during the Mesozoic period. The discrete tectonostratigraphic terranes that resulted from these events and subsequent Tertiary and Quaternary volcanic events are characterized by specific types of metallic mineral deposits or, in some terranes, by the virtual absence of deposits. Lead-silver-zinc replacement-type deposits are common in the Paleozoic carbonate terrane in the eastern part of the state and occur sporadically elsewhere in the miogeoclinal and cratonal terranes but are absent from the oceanic and island-arc terranes. The vast majority of contact metasomatic tungsten deposits, including all the large ones, are in pendants of miogeoclinal rocks in the Sierra Nevada batholith, but the important Atolia deposits reside in granitoid rocks that invade oceanic terrane. Molybdenum distribution closely follows that of tungsten. All the large contact metasomatic iron deposits in California are in craton and miogeoclinal terranes, but sparse small deposits of this type also occur in island-arc terranes of the northern Sierra Nevada and eastern Klamath Mountains. Lode gold deposits, although widely scattered, show a marked preference for oceanic and island-arc terranes that have been invaded by granitoid plutons. All the major deposits, including late Tertiary bonanza deposits such as Bodie, are in such terranes. It appears that magmatic processes were responsible for mobilizing and transporting the gold, but the metal was perhaps derived from the eugeosynclinal rocks, notably the mafic volcanics. Most mercury deposits are found in the Coast Ranges, where they commonly occur in silica-carbonate rock, an alteration product of serpentinite. The deposits appear to be spatially related to the Coast Range thrust, and the source of the mercury may have been sedimentary rocks of the underlying Franciscan assemblage. Epigenetic mineralization occurred at several different times during the Mesozoic, and again during Miocene and Pliocene time. The timing of mineralization events and the distribution of various deposit types indicate that no broad-scale zoning of epigenetic deposits exists around the Sierra Nevada batholith.Syngenetic deposits are represented mainly by massive sulfides, chert-associated manganese, and chromite. The massive sulfide deposits, with one exception, are restricted to island-arc terranes, and nearly all of these deposits are in silicic volcanic rocks. They are interpreted to be syngenetic with the enclosing rocks, although some redistribution of metals may have occurred after the original deposition. The deposits occur in volcanic sequences of at least five different ages ranging from Early Devonian to Late Jurassic or Early Cretaceous and, along with their enclosing rocks, were probably formed at some distance from their present sites. Chert-associated manganese deposits occur mainly in exotic blocks of oceanic crust in melange and probably formed in fairly deep ocean environments. Chromite is confined to ultramafic rock, much of which occupies suture zones separating various accreted terranes.

Economic Geology

Mapping of hydrothermally altered rocks using airborne multispectral scanner data, Marysvale, Utah, mining district

Multispectral data covering an area near Marysvale, Utah, collected with the airborne National Aeronautics and Space Administration (NASA) 24-channel Bendix multispectral scanner, were analyzed to detect areas of hydrothermally altered, potentially mineralized rocks. Spectral bands were selected for analysis that approximate those of the Landsat 4 Thematic Mapper and which are diagnostic of the presence of hydrothermally derived products. Hydrothermally altered rocks, particularly volcanic rocks affected by solutions rich in sulfuric acid, are commonly characterized by concentrations of argillic minerals such as alunite and kaolinite. These minerals are important for identifying hydrothermally altered rocks in multispectral images because they have intense absorption bands centered near a wavelength of 2.2 ??m. Unaltered volcanic rocks commonly do not contain these minerals and hence do not have the absorption bands. A color-composite image was constructed using the following spectral band ratios: 1.6??m/2.2??m, 1.6??m/0.48??m, and 0.67??m/1.0??m. The particular bands were chosen to emphasize the spectral contrasts that exist for argillic versus non-argillic rocks, limonitic versus nonlimonitic rocks, and rocks versus vegetation, respectively. The color-ratio composite successfully distinguished most types of altered rocks from unaltered rocks. Some previously unrecognized areas of hydrothermal alteration were mapped. The altered rocks included those having high alunite and/or kaolinite content, siliceous rocks containing some kaolinite, and ash-fall tuffs containing zeolitic minerals. The color-ratio-composite image allowed further division of these rocks into limonitic and nonlimonitic phases. The image did not allow separation of highly siliceous or hematitically altered rocks containing no clays or alunite from unaltered rocks. A color-coded density slice image of the 1.6??m/2.2??m band ratio allowed further discrimination among the altered units. Areas containing zeolites and some ash-fall tuffs containing montmorillonite were readily recognized on the color-coded density slice as having less intense 2.2-??m absorption than areas of highly altered rocks. The areas of most intense absorption, as depicted in the color-coded density slice, are dominated by highly altered rocks containing large amounts of alunite and kaolinite. These areas form an annulus, approximately 10 km in diameter, which surrounds a quartz monzonite intrusive body of Miocene age. The patterns of most intense alteration are interpreted as the remnants of paleohydrothermal convective cells set into motion during the emplacement of the central intrusive body. ?? 1983.

Advances in Space Research

Fluvial sediments a summary of source, transportation, deposition, and measurement of sediment discharge

This paper presents a broad but undetailed picture of fluvial sediments in streams, reservoirs, and lakes and includes a discussion of the processes involved in the movement of sediment by flowing water. Sediment is fragmental material that originates from the chemical or physical disintegration of rocks. The disintegration products may have many different shapes and may range in size from large boulders to colloidal particles. In general, they retain about the same mineral composition as the parent rocks. Rock fragments become fluvial sediment when they are entrained in a stream of water. The entrainment may occur as sheet erosion from land surfaces, particularly for the fine particles, or as channel erosion after the surface runoff has accumulated in streams. Fluvial sediments move in streams as bedload (particles moving within a few particle diameters of the streambed) or as suspended sediment in the turbulent flow. The discharge of bedload varies with several factors, which may include particle size and a type of effective shear on the surface of the streambed. The discharge of suspended sediment depends partly on concentration of moving sediment near the streambed and hence on discharge of bedload. However, the concentration of fine sediment near the streambed varies widely, even for equal flows, and, therefore, the discharge of fine sediment normally cannot be computed theoretically. The discharge of suspended sediment also depends on velocity, turbulence, depth of flow, and fall velocity of the particles. In general, the coarse sediment transported by a stream moves intermittently and is discharged at a rate that depends on properties of the flow and of the sediment. If an ample supply of coarse sediment is available at the surface of the streambed, the discharge of the coarse sediment, such as sand, can be roughly computed from properties of the available sediment and of the flow. On the other hand, much of the fine sediment in a stream usually moves nearly continuously at about the velocity of the flow, and even low flows can transport large amounts of fine sediment. Hence, the discharge of fine sediments, being largely dependent on the availability of fine sediment upstream rather than on the properties of the sediment and of the flow at a cross section, can seldom be computed from properties, other than concentrations based directly on samples, that can be observed at the cross section. Sediment particles continually change their positions in the flow; some fall to the streambed, and others are removed from the bed. Sediment deposits form locally or over large areas if the volume rate at which particles settle to the bed exceeds the volume rate at which particles are removed from the bed. In general, large particles are deposited more readily than small particles, whether the point of deposition is behind a rock, on a flood plain, within a stream channel, or at the entrance to a reservoir, a lake, or the ocean. Most samplers used for sediment observations collect a water-sediment mixture from the water surface to within a few tenths of a foot of the streambed. They thus sample most of the suspended sediment, especially if the flow is deep or if the sediment is mostly fine; but they exclude the bedload and some of the suspended sediment in a layer near the streambed where the suspended-sediment concentrations are highest. Measured sediment discharges are usually based on concentrations that are averages of several individual sediment samples for a cross section. If enough average concentrations for a cross section have been determined, the measured sediment discharge can be computed by interpolating sediment concentrations between sampling times. If only occasional samples were collected, an average relation between sediment discharge and flow can be used with a flow-duration curve to compute roughly the average or the total sediment discharges for any periods of time for which the flow-duration c

Bulletin

Maps showing petroleum exploration intensity and production in major Cambrian to Ordovician reservoir rocks in the Anadarko Basin

The Anadarko basin is a large, deep, two-stage Paleozoic basin (Feinstein, 1981) that is petroleum rich and generally well explored. The Anadarko basin province, a geogrphic area used here mostly for the convenience of mapping and data management, is defined by political boundaries that include the Anadarko basin proper. The boundaries of the province are identical to those used by the U.S. Geological Survey (USGS) in the 1995 National Assessment of United Stated Oil and Gas Resources. The data in this report, also identical to those used in the national assessment, are from several computerized data bases including Nehring Research Group (NRG) Associates Inc., Significant Oil and Gas Fields of the United States (1992); Petroleum Information (PI), Inc., Well History Control System (1991); and Petroleum Information (PI), Inc., Petro-ROM: Production data on CD-ROM (1993). Although generated mostly in response to the national assessment, the data presented here arc grouped differently and arc displayed and described in greater detail. In addition, the stratigraphic sequences discussed may not necessarily correlate with the "plays" of the 1995 national assessment. This report uses computer-generated maps to show drilling intensity, producing wells, major fields, and other geologic information relevant to petroleum exploration and production in the lower Paleozoic part of the Anadarko basin province as defined for the U.S. Geological Survey's 1995 national petroleum assessment. Hydrocarbon accumulations must meet a minimum standard of 1 million barrels of oil (MMBO) or 6 billion cubic feet of gas (BCFG) estimated ultimate recovery to be included in this report as a major field or revoir. Mapped strata in this report include the Upper Cambrian to Lower Ordovician Arbuckle and Low Ordovician Ellenburger Groups, the Middle Ordovician Simpson Group, and the Middle to Upper Ordovician Viola Group.

Colorado, Kansas, Oklahoma, Texas

Geologic assessment of undiscovered oil and gas resources in the Albian Clastic and Updip Albian Clastic Assessment Units, U.S. Gulf Coast Region

U.S. Geological Survey National Oil and Gas Assessments (NOGA) of Albian aged clastic reservoirs in the U.S. Gulf Coast region indicate a relatively low prospectivity for undiscovered hydrocarbon resources due to high levels of past production and exploration. Evaluation of two assessment units (AUs), (1) the Albian Clastic AU 50490125, and (2) the Updip Albian Clastic AU 50490126, were based on a geologic model incorporating consideration of source rock, thermal maturity, migration, events timing, depositional environments, reservoir rock characteristics, and production analyses built on well and field-level production histories. The Albian Clastic AU is a mature conventional hydrocarbon prospect with undiscovered accumulations probably restricted to small faulted and salt-associated structural traps that could be revealed using high resolution subsurface imaging and from targeting structures at increased drilling depths that were unproductive at shallower intervals. Mean undiscovered accumulation volumes from the probabilistic assessment are 37 million barrels of oil (MMBO), 152 billion cubic feet of gas (BCFG), and 4 million barrels of natural gas liquids (MMBNGL). Limited exploration of the Updip Albian Clastic AU reflects a paucity of hydrocarbon discoveries updip of the periphery fault zones in the northern Gulf Coastal region. Restricted migration across fault zones is a major factor behind the small discovered fields and estimation of undiscovered resources in the AU. Mean undiscovered accumulation volumes from the probabilistic assessment are 1 MMBO and 5 BCFG for the Updip Albian Clastic AU.

Gulf Coast Region

The Mt. Montro kyanite deposit, Grand Bassa County, Liberia

The Mt. Montro kyanite deposit, 14 miles north of Buchanan, Grand Bassa County, Liberia, is near the middle of a belt of kyanite-bearing gneisses and schists that is 9 miles long and 1 mile wide. The deposit, which seems to be the most persistent and the largest single body of kyanite rocks in the belt, is approximately 12, 600 feet long, as much as 480 feet in outcrop width, and from 25 to 350 feet thick. Kyanite-quartz-biotite-feldspar-garnet-muscovite gneiss, local interbeds of kyanite-mica schist, and lesser amounts of biotite-quartz gneiss, are the principal rocks in the deposit. Other rocks in the kyanite belt include garnet-biotite gneiss, undifferentiated quartzo-feldspathic gneiss, quartzite, and amphibolite. The rocks are the product of regional metamorphism to almandine amphibolite facies. The regional strike is northwest and dips are southwest. Kyanite crystals are as much as 3 inches long. The kyanite content ranges from 5. 8 to 46. 7 percent, but most rocks contain between 10 and 35 percent. Garnetiferous beds contain as much as 15 percent red garnets that range to half an inch in diameter. In general, the garnet-rich beds are found in the upper part of the deposit. he total reserves of the Mt. Montro kyanite deposit are estimated at about 10 million tons of kyanitic rock containing approximately 2.5 million tons of kyanite. These estimates include measured, indicated, and inferred reserves, calculated to depths of 25 to 100 feet, on the assumption that open-cut mining to those depths would be feasible. The largest part of the deposit underlies Mt. Montro and contains about 8 million tons of kyanitic rock containing nearly 1.9 million tons of kyanite. Residual soil overlying the deposit averages about 5 feet in thickness and is estimated to comprise slightly more than 400,000 cubic yards of material containing about 186,000 tons of kyanite. The proximity of the kyanite deposit to a paved highway, to port facilities at Buchanan, and to water, electrical power, and timber resources are considered favorable factors relevant to possible development.

Grand Bassa County

Distribution of gold, tellurium, silver, and mercury in part of the Cripple Creek district, Colorado

Geochemical exploration studies were undertaken in the Cripple Creek district to test the possibility that large low-grade gold deposits might be found. Surface rock samples taken throughout the district indicate that the volcanic rocks between the productive veins contain an average of about 0.6 ppm (part per million) gold. In an area above 3,800 feet long and 500 feet wide near the Cresson mine in the south-central part of the district, scattered surface samples show that the rocks contain an average of 2.5 ppm gold, equivalent to $2.50 per ton. Inasmuch as veins that contain more than 2.5 ppm may also exist in the area, systematic sampling by trenching and drilling is warranted.

Circular

U/Th series radionuclides as coastal groundwater tracers

The study of coastal groundwater has recently surfaced as an active interdisciplinary area of research, driven foremost by its importance as a poorly quantified pathway for subsurface material transport into coastal ecosystems. Key issue in coastal groundwater research include a complete geochemical characterization of the groundwater(s); quantification of the kinetics of subsurface transport, including rock-water interactions; determination of groundwater ages; tracing of groundwater discharge into coastal waters using radiochemical fingerprints; and an assessment of the potential ecological impact of such subsurface flow to a reviving water body. For such applications, the isotopic systemics of select naturally occurring radionucludes in the U/Th series has proven to be particularly useful. These radionuclides (e.g., U, Th, Ram and Rn) are ubiquitous in all groundwaters ad are represented by several isotopes with widely different half-lives and chemistries (Figure 1). As a result, varied biogeochemical processes occurring over a broad range of time scales can be studied. In source rock, most U/Th series isotopes in secular equilibrium; that is, the rate of decay of a daughter isotope is equal to that of it radiogenic parent, and so will have equal activities (in this context, the specific activity is simply a measure of the amount of radioactivity per unit amount). In contrast, these nuclides exhibit strong fractionations within the surrounding groundwaters because of their respective physiochemical differences. Disequilibria in U/Th series radionuclides can thus be used to identify distinct water masses, quantify release rates from source rocks, assess groundwater migration rates, and assess groundwater discharge rates in coastal waters., Large isotopic variations also have the potential for providing precise fingerprints for groundwaters from specific aquifers and have been explored as a means for calculating groundwater ages and estuarine water mass transit times. The highly fractionated nature of U/Th series nuclides in groundwater is illustrated by the range in some measured activities. highest activities are typically observed for 222 Rn, reflecting the inert nature of this noble gas. Groundwater 222 Rn (t 1/2 =3.8) activities are thus controlled only by rapid in situ decay (Table 1) and production within host rocks, without the added complications of reversible removal via absorption or precipitation. Uranium, which is soluble as U(VI) in oxidizing waters, is present in intermediate activities in groundwaters that are moderated by redox-initiated removal onto aquifer rocks. The alkaline earth Ra and, to a greater extent, the less soluble actinide Th are readily removed from groundwater by water -- rock interactions and so are strongly depleted. Both of these elements have very short-lived as well as longer-lived isotopes, and so isotopes compositions reflect processes over a range of time scales. Many studies have evaluated and behavior of select radionuclides in groundwater and surface water systems. Recent advances in high-=precision mass spectrometry have opted new possibilities for more subtle interpretations in select long-lived U/Th series isotopes, such as U, Ra, Pa, and Th. However, these techniques have yet to be fully developed, ahns as a consequence, such data remain largely scarce and underutilized. Although many different approaches have been developed to study radionucluide behavior in groundwater, all are based on principles of radioactive production and decay and knowledge of source terms from weathering and recoil processes, as well as removal terms from the interaction with aquifer host rock surface by sorption and precipitation. This review is structured to present first a brief description of the background, driving forces, scales, and ecological significance of submarine groundwater discharge. Following this, a description of the geochemistry and behavior of select radionuclides in groundwater will be presented, and their application to tracing submarine groundwater discharge will be discussed.

Chemical Reviews

Undiscovered phosphate resources in the Caribbean region and their potential value for agricultural development

The countries of the world's humid tropical regions lack the soil fertility necessary for high agricultural productivity. A recently developed agricultural technology that increases soil fertility can make tropical agriculture highly productive, but the technique requires large inputs into the soil of phosphorus and other fertilizers and soil amendments. Use of fertilizers derived from phosphate rock is increasing greatly throughout the world, and fertilizer raw materials are being produced more and more frequently from phosphate rock deposits close to the areas of use. An increased understanding of the origin of phosphate rock in ancient oceans has enabled exploration geologists to target areas of potential mineral resource value and to search directly for deposits. However, because of the difficulty of prospecting for mineral deposits in forested tropical regions, phosphate rock deposits are not being explored for in the countries of the humid tropics, including most countries of the Caribbean region. As a result, the countries of the Caribbean must import phosphate rock or phosphorus fertilizer products. In the present trade market, imports of phosphate are too low for the initiation of new agricultural technology in the Caribbean and Central American region. A newly proposed program of discovery and development of undiscovered phosphate rock deposits revolves around reconnaissance studies, prospecting by core drilling, and analysis of bulk samples. The program should increase the chance of discovering economic phosphate rock deposits. The search for and evaluation of phosphate rock resources in the countries of the Caribbean region would take about 5 years and cost an average of $15 million per country. The program is designed to begin with high risk-low cost steps and end with low risk-high cost steps. A successful program could improve the foreign exchange positions of countries in the Caribbean region by adding earnings from agricultural product exports and by substituting domestically produced phosphate rock and fertilizer products for imported phosphate fertilizers. A successful program also could provide enough domestically produced phosphorus fertilizer products to allow initiation of new agricultural technology in the region and thus increase domestic food production. Finally, a new phosphorus fertilizer industry would create new jobs in the mining, chemical, and transportation industries of the Caribbean region.

Circular

Fish and habitat assessment in Rock Creek, Klickitat County, Washington 2016–17

Executive Summary Intermittent streams are important and productive for salmonid habitat. Rock Creek, in southeastern Washington, flows south to the Columbia River at river kilometer (rkm) 368 and is an intermittent stream of great significance to the Yakama Nation and to the Kah-miltpah (Rock Creek) Band in particular. Historically, native steelhead (anadromous form of rainbow trout [ Oncorhynchus mykiss ]) and bridgelip sucker ( Catostomus columbianus ) populations were used by the Kah-miltpah Band for sustenance, trade, and traditional practices. Anadromous salmonid populations currently present and being monitored in the Rock Creek subbasin include Coho ( O. kisutch ) salmon and steelhead. Resident rainbow trout are also present and monitored (rainbow trout and steelhead will be collectively referred to as O. mykiss throughout this report). Streamflow is a limiting habitat factor in this system, but despite this, steelhead and Coho salmon still successfully return to spawn, rear, out-migrate, and survive over-summer in many of the isolated pools. We completed habitat surveys during 2015–17 to assess the perennial pools during low-flow conditions. The lower river sections (rkm 2–13) had proportionately more dry sections than the upper river sections (rkm 14–22) for all years surveyed and had higher variability among habitat types across years. The surveyed dry sections within the lower river ranged from 44 to 57 percent, with 2015 (a drought year) as the highest and 2017 the lowest. The percentage of pool habitat in the lower river was 21−24 percent, with 2015 as the lowest and 2016 and 2017 both at 24 percent. The upper river sections had a relatively high percentage of non-pool wet habitat (49−51 percent), followed by dry (33−36 percent) and pool habitat (17−18 percent). In Walaluuks Creek, the percentage of pool habitat was the most consistent across the years, ranging from 10 to 13 percent.

Washington

Plate tectonics and volcanism in western California

Introduction Western California is home to a variety of volcanic rocks. The locations, ages, and chemical compositions of these volcanic rocks help tell part of the fascinating story of California’s plate tectonic evolution over the past 40 million years. These volcanic rocks are a product of multiple tectonic processes, including subduction of divergent and transform plate boundaries beneath continental North America, opening of a slab window, creation and migration of a tectonic triple junction, and the birth and growth of the San Andreas Fault. This fact sheet explains these tectonic processes and discusses their role in shaping the volcanic history of western California over the past 40 million years. By studying the volcanic rock record in western California, geologists are able to piece together how regional volcanism and plate tectonics are linked in space and time. Recognizing this linkage helps scientists to understand possible future volcanism in the region, potential hazards associated with this volcanism, and the impacts these hazards may have on population and infrastructure. The U.S. Geological Survey California Volcano Observatory (CalVO) closely monitors the parts of western California with the greatest potential for volcanism.

California

Hydrogeology and ground-water quality of northern Bucks County, Pennsylvania

The 187-square mile study area is in the Triassic-Jurassic Newark Basin. Most of the area is underlain by sedimentary rocks of Upper Triassic age (74 percent) and intrusive diabase of Jurassic age (12 percent) and includes two southwest-northeast trending valleys underlain by carbonate and crystalline rock. Ground water in the sedimentary rocks of Triassic age moves through a network of interconnecting secondary openings fractures, bedding planes, and joints. The ground-water system consists of beds with a relatively high transmissivity separated by beds with a relatively low transmissivity that form a leaky, multiaquifer system. Ground water is unconfined in the shallower part of the aquifer and confined or semiconfined in the deeper part of the aquifer. Most deep wells are open to several water-bearing zones and are multiaquifer wells. The frequency of occurrence of water-bearing zones decreases with depth. Sixty-five percent of water-bearing zones for all hydrogeologic units are within 200 feet of land surface, and 85 percent are within 300 feet of land surface. On the basis of the median specific capacity of nondomestic wells, carbonate rocks, the Brunswick Group, and the Stockton Formation are the most productive hydrogeologic units. Carbonate rocks and the Stockton Formation have the highest median nondomestic well yields (156 and 120 gallons per minute, respectively) among the hydrogeologic units. Thirty-four percent of domestic wells drilled in diabase, 30 percent in the Lockatong Formation, and 21 percent in carbonate rock yield less than 5 gallons per minute. Average water budgets for the Cooks, Tinicum, Paunnacussing, and Mill Creek Basins weighted by drainage area were calculated for 1991-92. Average annual precipitation was 41.7 in. (inches); average annual evapotranspiration (ET) and other losses were 26.2 in. or 63 percent of precipitation; average annual streamflow was 15.9 in., or 38 percent of the average precipitation; and the average annual change in ground-water storage was a decrease of 0.3 in., or less than 1 percent of the average annual precipitation. Average estimated recharge for 1991-92 weighted by drainage area was 10.1 in. [0.485 (Mgal/d)/mi 2 (million gallons per day per square mile)]; this is equal to a recharge rate of 758 gallons per day per acre. Water budgets for the Tohickon Creek Basin were calculated for 1968-91 (prior to regulation of the stream by Lake Nockamixon). The average annual precipitation was 47.2 in.; average annual ET and other losses were 24.3 in., or 51 percent of the average annual precipitation; and annual streamflow was 22.6 in., or 48 percent of the average annual precipitation. Streamflow hydrographs for 1991-92 for Cooks, Tinicum, Paunnacussing, and Mill Creeks were separated into baseflow and surface-runoff components. Average annual ground-water discharge to streams weighted by drainage area was 8.4 in. [0.403 (Mgal/d)/mi 2 ], which was 20 percent of the average annual precipitation and 53 percent of the average annual streamflow. Average annual surface runoff weighted by drainage area was 7.4 in., which was 18 percent of the average annual precipitation and 47 percent of the average annual streamflow. Annual base flow for 1936-71 for Tohickon Creek ranged from 2.5 in. [0.12 (Mgal/d)/mi 2 ] in 1965 to 8.4 in. [0.40 (Mgal/d)/mi 2 ] in 1945. The median base flow was 5.3 in. [0.25 (Mgal/d)/mi 2 ]. Water from wells in the crystalline rocks has the lowest median pH (5.8), the lowest median specific conductance (139 microsiemens per centimeter), the lowest median alkalinity [16 mg/L (milligrams per liter) as CaCOg], and the highest dissolved oxygen concentration (9.0 mg/L) of the hydrogeologic units. Water from wells in carbonate rocks has the highest median pH (7.8) and the highest median alkalinity (195 mg/L as CaCO3) of the hydrogeologic units. Water from wells in the Lockatong Formation has the highest median specific conductance (428 microsiemens per centimeter) and the lowest dissolved oxygen concentration (0.8 mg/L) of the hydrogeologic units. Water from wells in crystalline rocks contains the lowest concentrations of total dissolved solids (TDS) of the hydrogeologic units. Water from the Lockatong Formation contains the highest concentration of TDS of the hydrogeologic units. Water from only 1 of 83 wells sampled exceeded the U.S. Environmental Protection Agency (USEPA) secondary maximum contaminant level (SMCL) for TDS; the well is in the Lockatong Formation. Five of 86 samples (6 percent) and 6 of 75 samples (8 percent) exceed the USEPA SMCL for iron and manganese, respectively. Nitrate is the most prevalent nitrogen species in ground water. The median nitrate concentration for all hydrogeologic units is 2.3 mg/L. Of 71 water samples from wells, no concentrations of nitrate exceed the USEPA maximum contaminant level. The median dissolved radon-222 activity was highest for water samples from wells in crystalline rock [3,600 pCi/L (picocuries per liter)] and lowest for water samples from wells in the Lockatong Formation (340 pCi/L) and diabase (350 pCi/L). Water samples for analysis for volatile organic compounds (VOC's) were collected from 34 wells in areas where the potential existed for the presence of VOC's in ground water. VOC's were detected in 23 percent of the 34 wells sampled. The most commonly detected compound was trichloroethylene (13 percent of sampled wells).

Pennsylvania

Distribution, facies, ages, and proposed tectonic associations of regionally metamorphosed rocks in east- and south-central Alaska

Most of the exposed bedrock in east- and south-central Alaska has been regionally metamorphosed and deformed during Mesozoic and early Cenozoic time. All the regionally metamorphosed rocks are assigned to metamorphic-facies units on the basis of their temperature and pressure conditions and metamorphic age. North of the McKinley and Denali faults, the crystalline rocks of the Yukon- Tanana upland and central Alaska Range compose a sequence of dynamothermally metamorphosed Paleozoic and older(?) metasedimentary rocks and metamorphosed products of a Devonian and Mississippian continental-margin magmatic arc. This sequence was extensively intruded by postmetamorphic mid-Cretaceous and younger granitoids. Many metamorphic-unit boundaries in the Yukon-Tanana upland are low-angle faults that juxtapose units of differing metamorphic grade, which indicates that metamorphism predated final emplacement of the fault-bounded units. In some places, the relation of metamorphic grade across a fault is best explained by contractional faulting; in other places, it is suggestive of extensional faulting. Near the United States-Canadian border in the central Yukon- Tanana upland, metamorphism, plutonism, and thrusting occurred during a latest Triassic and Early Jurassic event that presumably resulted from the accretion of a terrane that had affinities to the Stikinia terrane onto the continental margin of North America. Elsewhere in the Yukon-Tanana upland, metamorphic rocks give predominantly late Early Cretaceous isotopic ages. These ages are interpreted to date either the timing of a subsequent Early Cretaceous episode of crustal thickening and metamorphism or, assuming that these other areas were also originally heated during the latest Triassic to Early Jurassic and remained buried, the timing of their uplift and cooling. This uplift and cooling may have resulted from extension. South of the McKinley and Denali faults and north of the Border Ranges fault system, medium-grade metamorphism across much of the southern Peninsular and Wrangellia terranes was early to synkinematic with the intrusion of tonalitic and granodioritic plutons of primarily Early and Middle Jurassic age in the Peninsular terrane and Late Jurassic age in the Wrangellia terrane. Areas metamorphosed during the Jurassic episode that crop out near the Border Ranges fault system were subsequently retrograded and deformed in Cretaceous and early Tertiary time during accretion of younger units to the south. North of the Jurassic metamorphic and plutonic complex, low-grade metamorphism affected the rest of the Wrangellia terrane sometime during Jurassic and (or) Cretaceous time. North of the Wrangellia terrane and immediately south of the McKinley and Denali faults, flyschoid rocks, which were deposited within a basin that separated the Wrangellia terrane from the western margin of North America, form a northeastward-tapering wedge. Within the western half of the wedge, flysch and structurally interleaved tectonic fragments were highly deformed and weakly metamorphosed; much of the metamorphism and deformation probably occurred sometime during mid- to Late Cretaceous time. In the eastern half of the wedge, flyschoid rocks form an intermediate-pressure Barrovian sequence (Maclaren metamorphic belt). Metamorphism of the Maclaren metamorphic belt was synkinematic with the Late Cretaceous to earliest Tertiary intrusion of foliated plutons of intermediate composition. Isotopic data suggest metamorphism extended into the early Tertiary and was accompanied by rapid uplift and cooling. Low- to medium-grade metamorphism throughout the wedge was probably associated with the accretion of the outboard Wrangellia terrane, as has been proposed for the Maclaren metamorphic belt. South of the Border Ranges fault system lie variably metamorphosed sequences of oceanic rocks that comprise the successively accreted Chugach, Yakutat, Ghost Rocks, and Prince William terranes. The Chugach terrane consists of three successively accreted sequences of differing metamorphic histories. Metamorphism in all the sequences was associated with north-directed underthrusting beneath either the combined Peninsular-Wrangellia terrane or the older and inner parts of the Chugach terrane. These sequences, from innermost to outermost are: (1) intermediate- to highpressure, transitional greenschist- to blueschist-facies metabasalt and metasedimentary rocks that were metamorphosed during the Early and Middle Jurassic; (2) prehnite-pumpellyite-facies melange that was metamorphosed sometime during the Jurassic and Cretaceous; and (3) low-pressure prehnite-pumpellyite- or greenschist- facies flysch and metavolcanic rocks that were initially metamorphosed during latest Cretaceous to early Tertiary time and, in the eastern Chugach Mountains, were subsequently overprinted by low-pressure amphibolite-facies metamorphism that accompanied widespread intrusion during Eocene time. A similar low-pressure-facies series also developed within melange and flysch of the Yakutat terrane; these rocks are also intruded by Eocene plutons and are correlated with similar rocks of the Chugach terrane. Seaward of the Chugach terrane are the strongly deformed but weakly metamorphosed (prehnite-pumpellyite-facies) deep-sea metasedimentary rocks and oceanic metavolcanic rocks of the Ghost Rocks and Prince William terranes. Metamorphism and deformation occurred during underthrusting of these terranes beneath the Chugach terrane in early Tertiary time and predated, perhaps by very little, intrusion by early Tertiary granitoids.

Alaska