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54 records · Page 3Linked to original sources
USGS1995

Distribution of phytobenthos in the Yakima River basin, Washington, in relation to geology, land use and other environmental factors

Benthic-algal distributions in the Yakima River, Washington, basin were, examined in relation to geology, land use, water chemistry, and stream habitat using indicator-species classification ( TWINSPAN ) and canonical correspondence analysis (CCA). Algal assemblages identified by TWINSPAN were each associated with a narrow range of water-quality conditions. In the Cascade geologic province, where timber harvest and grazing are the dominant land uses, differences in community structure (CCA site scores) and concentrations of major ions (Ca and Mg) and nutrients (solute P, SiO 2 and inorganic N) varied with dominant rock type of the basin. In agricultural areas of the Columbia Plateau province, differences in phytobenthos structure were based primarily on the degree of enrichment of dissolved solids, inorganic N, and solute P from irrigation-return flows and subsurface drainage. Habitat characteristics strongly correlated with community structure included reach altitude, turbidity, substratum embeddedness (Columbia Plateau), large woody-debris density (Cascade Range), and composition and density of the riparian vegetation. Algal biomass (AFDM) correlated with composition and density of the riparian vegetation but not with measured chemical-constituent concentrations. Nitrogen limitation in streams of the Cascade Range favored nitrogen-fixing blue-green algae and diatoms with endosymbiotic blue-greens, whereas nitrogen heterotrophs were abundant in agricultural areas of the Columbia Plateau.

Canadian Journal of Fisheries and Aquatic Sciences↗
USGS2018

Changes in long-term water quality of Baltimore streams are associated with both gray and green infrastructure

The steadily rising global urban population has placed substantial strain on urban water quality, and this strain is projected to increase for the foreseeable future. Considerable attention has been given to the hydrological and physico-chemical effects of urbanization on stream ecosystems. However, due to the relative infancy of the field of urban ecology, long-term water quality analyses in urban streams are sparse. Using a 15-year stream chemistry monitoring record from Baltimore, MD, USA, we quantified long-term trends in nitrate, phosphate, total nitrogen, total phosphorus, chloride, and sulfate export at several sites along a rural-urban gradient. We found no significant change in solute export at most sites, although we did find specific patterns of interest for certain solutes. For example, nitrogen export declined at the most headwater urban site, while phosphorus export declined at the most downstream urban site. Coupling long-term monitoring with data on gray and green infrastructure management throughout the landscape, we established relationships between solute export at the most downstream urban monitoring site and sanitary sewer overflows (SSOs), best management practice (BMP) implementation, and road salt application rates. Phosphorus export was correlated with BMP implementation in the watershed, whereas nitrogen export was related to SSOs. Despite highly urbanized watersheds, water quality does not appear to be declining at most of these sites, suggesting that current management may have limited further impairment. Results of our study suggest that both gray and green infrastructure are key for maintaining and improving water quality in this highly urbanized watershed.

Maryland↗
USGS2008

Groundwater's significance to changing hydrology, water chemistry, and biological communities of a floodplain ecosystem, Everglades, South Florida, USA

The Everglades (Florida, USA) is one of the world's larger subtropical peatlands with biological communities adapted to waters low in total dissolved solids and nutrients. Detecting how the pre-drainage hydrological system has been altered is crucial to preserving its functional attributes. However, reliable tools for hindcasting historic conditions in the Everglades are limited. A recent synthesis demonstrates that the proportion of surface-water inflows has increased relative to precipitation, accounting for 33% of total inputs compared with 18% historically. The largest new source of water is canal drainage from areas of former wetlands converted to agriculture. Interactions between groundwater and surface water have also increased, due to increasing vertical hydraulic gradients resulting from topographic and water-level alterations on the otherwise extremely flat landscape. Environmental solute tracer data were used to determine groundwater's changing role, from a freshwater storage reservoir that sustained the Everglades ecosystem during dry periods to a reservoir of increasingly degraded water quality. Although some of this degradation is attributable to increased discharge of deep saline groundwater, other mineral sources such as fertilizer additives and peat oxidation have made a greater contribution to water-quality changes that are altering mineral-sensitive biological communities. ?? Springer-Verlag 2008.

Hydrogeology Journal↗
USGS2013

Shallow groundwater and soil chemistry response to 3 years of subsurface drip irrigation using coalbed-methane-produced water

Disposal of produced waters, pumped to the surface as part of coalbed methane (CBM) development, is a significant environmental issue in the Wyoming portion of the Powder River Basin, USA. High sodium adsorption ratios (SAR) of the waters could degrade agricultural land, especially if directly applied to the soil surface. One method of disposing of CBM water, while deriving beneficial use, is subsurface drip irrigation (SDI), where acidified CBM waters are applied to alfalfa fields year-round via tubing buried 0.92 m deep. Effects of the method were studied on an alluvial terrace with a relatively shallow depth to water table (∼3 m). Excess irrigation water caused the water table to rise, even temporarily reaching the depth of drip tubing. The rise corresponded to increased salinity in some monitoring wells. Three factors appeared to drive increased groundwater salinity: (1) CBM solutes, concentrated by evapotranspiration; (2) gypsum dissolution, apparently enhanced by cation exchange; and (3) dissolution of native Na–Mg–SO 4 salts more soluble than gypsum. Irrigation with high SAR (∼24) water has increased soil saturated paste SAR up to 15 near the drip tubing. Importantly though, little change in SAR has occurred at the surface.

Wyoming↗
USGS2001

Seasonal and event-scale variations in solute chemistry for four Sierra Nevada catchments

Hydrobiogeochemical processes controlling stream water chemistry were examined in four small (<5 km2) catchments having contrasting bedrock lithologies in the western Sierra Nevada foothills of California. The Mediterranean climate with its cool/wet and hot/dry cycle produces strong seasonal patterns in hydrological, biological and geochemical processes. Stream water solutes fall into three general groups according to seasonal fluctuation in concentration: Strong, rainy season minimum-dry season maximum (Cl-, SO42-, base cations); weak, rainy season minimum-dry season maximum (Si); and rainy season maximum-dry season minimum (NO3- and K+). Solute dynamics in soil solutions and stream water suggest that mixing of drainage waters from bedrock and soil sources regulate stream water solute concentrations. Patterns are further altered by the leaching of solutes accumulated in the soil over the summer period of desiccation and the temporal discoupling of nutrient cycles that occurs due to differences in the timing between vegetation growth (late spring) and leaching (early winter). Solute concentrations are remarkably similar between watersheds with varying bedrock types, with the exception of nitrate, sulfate and bicarbonate. Three watersheds have nitrogen-bearing metasedimentary bedrock that contributes to elevated nitrate concentrations in stream waters. Watersheds whose bedrock includes mineralized veins of sulfide and carbonate minerals similarly have greater sulfate and bicarbonate concentrations in stream water. Hydrobiogeochemical processes are highly dynamic at the seasonal and storm-event temporal scales and spatially complex at the watershed scale making management of stream water chemical composition, such as nitrate concentrations, very challenging. ?? 2001 Elsevier Science B.V.

Journal of Hydrology↗
USGS2010

Source and fate of inorganic solutes in the Gibbon River, Yellowstone National Park, Wyoming, USA. II. Trace element chemistry

The Gibbon River in Yellowstone National Park receives inflows from several geothermal areas, and consequently the concentrations of many trace elements are elevated compared to rivers in non-geothermal watersheds. Water samples and discharge measurements were obtained from the Gibbon River and its major tributaries near Norris Geyser Basin under the low-flow conditions of September 2006 allowing for the identification of solute sources and their downstream fate. Norris Geyser Basin, and in particular Tantalus Creek, is the largest source of many trace elements (Al, As, B, Ba, Br, Cs, Hg, Li, Sb, Tl, W, and REEs) to the Gibbon River. The Chocolate Pots area is a major source of Fe and Mn, and the lower Gibbon River near Terrace Spring is the major source of Be and Mo. Some of the elevated trace elements are aquatic health concerns (As, Sb, and Hg) and knowing their fate is important. Most solutes in the Gibbon River, including As and Sb, behave conservatively or are minimally attenuated over 29 km of fluvial transport. Some small attenuation of Al, Fe, Hg, and REEs occurs but primarily there is a transformation from the dissolved state to suspended particles, with most of these elements still being transported to the Madison River. Dissolved Hg and REEs loads decrease where the particulate Fe increases, suggesting sorption onto suspended particulate material. Attenuation from the water column is substantial for Mn, with little formation of Mn as suspended particulates.

Wyoming↗
USGS2007

Scales of equilibrium and disequilibrium during cleavage formation in chlorite and biotite-grade phyllites, SE Vermont

Detailed electron microprobe analyses of phyllosilicates in crenulated phyllites from south-eastern Vermont show that grain-scale zoning is common, and sympathetic zoning in adjacent minerals is nearly universal. We interpret this to reflect a pressure-solution mechanism for cleavage development, where precipitation from a very small fluid reservoir fractionated that fluid. Multiple analyses along single muscovite, biotite and chlorite grains (30–200 μ m in length) show zoning patterns indicating Tschermakitic substitutions in muscovite and both Tschermakitic and di/trioctahedral substitutions in biotite and chlorite. Using cross-cutting relationships and mineral chemistry it is shown that these patterns persist in cleavages produced at metamorphic conditions of chlorite-grade, chlorite-grade overprinted by biotite-grade and biotite-grade. Zoning patterns are comparable in all three settings, requiring a similar cleavage-forming mechanism independent of metamorphic grade. Moreover, the use of 40 Ar/ 39 Ar geochronology demonstrates this is true regardless of age. Furthermore, samples with chlorite-grade cleavages overprinted by biotite porphyroblasts suggest the closure temperatures for the diffusion of Al, Si, Mg and Fe ions are greater than the temperature of the biotite isograd (>∼400 °C). Parallel and smoothly fanning tie lines produced by coexisting muscovite–chlorite, and muscovite–biotite pairs on compositional diagrams demonstrate effectively instantaneous chemical equilibrium and probably indicate simultaneous crystallization. These results do not support theories suggesting cleavages form in fluid-dominated systems. If crenulation cleavages formed in systems in which the chemical potentials of all major components are fixed by an external reservoir, then the compositions of individual grains defining these cleavages would be uniform. On the contrary, the fine-scale chemical zoning observed probably reflects a grain-scale process consistent with a pressure-solution mechanism in which the aqueous activities of major components are defined by local dissolution and precipitation. Thus the role of fluids was probably limited to one of catalysing pressure-solution and fluids apparently did not drive cleavage development.

Journal of Metamorphic Geology↗
USGS1993

Factors controlling the geochemical evolution of fumarolic encrustations, Valley of Ten Thousand Smokes, Alaska

Factor and canonical correlation analysis of geochemical data from eight fossil fumaroles suggest that six major factors controlled the formation and evolution of fumarolic encrustations on the 1912 ash-flow sheet in the Valley of Ten Thousand Smokes (VTTS). The six-factor solution model explains a large proportion (low of 74% for Ni to high of 99% for Si) of the individual element data variance. Although the primary fumarolic deposits have been degraded by secondary alteration reactions and up to 75 years of weathering, the relict encrustations still preserve a signature of vapor-phase element transport. This vapor-phase transport probably occurred as halide or oxyhalide species and was significant for As, Sb and Br. At least three, and possibly four, varied temperature leaching events affected the fumarolic deposits. High-temperature gases/liquids heavily altered the ejecta glass and mineral phases adjacent to the fumarolic conduit. As the fumaroles cooled. Fe-rich acidic condensate leached the ejecta and primary fumarolic deposits and resulted in the subsequent precipitation of Fe-hydroxides and/or Fe-oxides. Low- to ambient-temperature leaching and hydration reactions generated abundant hydrated amorphous phases. Up to 87% of the individual element data variance is apparently controlled by the chemistry of the ejecta on which the relict encrustations are found. This matrix chemistry factor illustrates that the primary fumarolic minerals surrounding the active VTTS vents observed by earlier workers have been effectively removed by the dissolution reactions. Element enrichment factors calculated for the VTTS relict encrustations support the statistical factor interpretations. On the average, the relict encrustations are enriched, relative to visibly unaltered matrix protolith, in As, Br, Cr, Sb, Cu, Ni, Pb, Fe, and LOI (an indirect measure of sample H2O content). ?? 1993.

Journal of Volcanology and Geothermal Research↗
USGS2010

Source and fate of inorganic solutes in the Gibbon River, Yellowstone National Park, Wyoming, USA: I. Low-flow discharge and major solute chemistry

The Gibbon River in Yellowstone National Park (YNP) is an important natural resource and habitat for fisheries and wildlife. However, the Gibbon River differs from most other mountain rivers because its chemistry is affected by several geothermal sources including Norris Geyser Basin, Chocolate Pots, Gibbon Geyser Basin, Beryl Spring, and Terrace Spring. Norris Geyser Basin is one of the most dynamic geothermal areas in YNP, and the water discharging from Norris is much more acidic (pH 3) than other geothermal basins in the upper-Madison drainage (Gibbon and Firehole Rivers). Water samples and discharge data were obtained from the Gibbon River and its major tributaries near Norris Geyser Basin under the low-flow conditions of September 2006. Surface inflows from Norris Geyser Basin were sampled to identify point sources and to quantify solute loading to the Gibbon River. The source and fate of the major solutes (Ca, Mg, Na, K, SiO 2 , Cl, F, HCO 3 , SO 4 , NO 3 , and NH 4 ) in the Gibbon River were determined in this study and these results may provide an important link in understanding the health of the ecosystem and the behavior of many trace solutes. Norris Geyser Basin is the primary source of Na, K, Cl, SO 4 , and N loads (35–58%) in the Gibbon River. The largest source of HCO 3 and F is in the lower Gibbon River reach. Most of the Ca and Mg originate in the Gibbon River upstream from Norris Geyser Basin. All the major solutes behave conservatively except for NH 4 , which decreased substantially downstream from Gibbon Geyser Basin, and SiO 2 , small amounts of which precipitated on mixing of thermal drainage with the river. As much as 9–14% of the river discharge at the gage is from thermal flows during this period.

Wyoming↗
USGS2026

Water volumes, heat flow, and solute discharge from Old Faithful Geyser eruptions, Yellowstone National Park, USA

The iconic Old Faithful Geyser in Yellowstone National Park, USA, has attracted a significant amount of research because of the relative regularity and impressive size of its eruptions. Numerous studies have included observations, measurements, and analyses that informed models of geyser eruptions. However, fundamental quantities, including the associated mass and heat discharged, remain poorly constrained. In April 2025 we measured the volume of water from 45 Old Faithful Geyser eruptions using a portable flume in an outflow channel and specific conductance measurements in the Firehole River. We used high-speed video to perform velocimetry, measured changes in water chemistry to calculate the volume of water evaporated along the outflow channels, and used thermodynamic calculations to estimate the volume of water erupted as steam and to quantify the geyser's heat output. The calculated average volume of water discharged by Old Faithful Geyser in each eruption is 27.9 ± 9.4 m 3 , with no relation between eruption volume and the length of the preceding eruption interval. Video analysis of the eruption's liquid-dominated phase yields similar volumes of 21–30 m 3 . The calculated heat flow from the geyser is 2.2–2.4 MW and the average annual discharge of chloride, fluoride, and arsenic are 63 tons, 3.9 tons, and 241 kg, respectively. Average annual silica deposition rate on the geyser cone and along the outflow channels is 7 tons. This study provides a methodology for future studies at geysers worldwide and a baseline for monitoring future activity changes at Old Faithful.

Wyoming↗
USGS1996

Exchangeable hydrogen explains the pH of spodosol Oa horizons

The chemistry of extremely acid Oa horizons does not conform to traditional pH, Al, and base saturation relationships. Results from two separate studies of northeastern U.S. forested soils were used to investigate relationships between pH in water or dilute salt solutions and other soil characteristics. In Oa horizons with pH below 4, soil pH in dilute CaCl 2 solution was correlated with exchangeable H + measured either by titration ( r = −0.88, P = 0.0001, n = 142) or by electrode ( r = −0.89, P = 0.0001, n = 45). Exchangeable H + expressed as a percentage of the cation-exchange capacity (CEC) was linear with pH and showed similar slopes for data from both studies. For all samples, pHw = 4.21 − 1.80 × H + /CEC ( R 2 = 0.69, n = 194). The reciprocal of the H + /CEC ratio is base saturation with Al added to the bases. Because of the low pH, exchangeable Al does not appear to behave as an acid. Exchangeable H + remains an operationally defined quantity because of the difficulty in separating exchange and hydrolysis reactions. In a variety of neutral-salt extractants, concentrations of H + were correlated with 0.1 M BaCl 2 -exchangeable H + ( r > 0.91, P = 0.0001, n = 26) regardless of the strength of the extract. Nine successive extractions with 0.33 m M CaCl 2 removed more H + than was removed by single batch extractions with either 1 M KCl or 0.1 M BaCl 2 (average H + of 70, 43, and 49 mmol kg −1 , respectively for 26 samples). The data showed little difference in the chemical behavior of Oa horizons from a variety of geographical sites and vegetation types.

Maine, New Hampshire, New York, Vermont↗
USGS2006

Atmospheric chemistry of a 33-34 hour old volcanic cloud from Hekla Volcano (Iceland): Insights from direct sampling and the application of chemical box modeling

On 28 February 2000, a volcanic cloud from Hekla volcano, Iceland, was serendipitously sampled by a DC-8 research aircraft during the SAGE III Ozone Loss and Validation Experiment (SOLVE I). It was encountered at night at 10.4 km above sea level (in the lower stratosphere) and 33-34 hours after emission. The cloud is readily identified by abundant SO2 (???1 ppmv), HCl (???70 ppbv), HF (???60 ppbv), and particles (which may have included fine silicate ash). We compare observed and modeled cloud compositions to understand its chemical evolution. Abundances of sulfur and halogen species indicate some oxidation of sulfur gases but limited scavenging and removal of halides. Chemical modeling suggests that cloud concentrations of water vapor and nitric acid promoted polar stratospheric cloud (PSC) formation at 201-203 K, yielding ice, nitric acid trihydrate (NAT), sulfuric acid tetrahydrate (SAT), and liquid ternary solution H2SO4/H2O/HNO3 (STS) particles. We show that these volcanically induced PSCs, especially the ice and NAT particles, activated volcanogenic halogens in the cloud producing >2 ppbv ClOx. This would have destroyed ozone during an earlier period of daylight, consistent with the very low levels of ozone observed. This combination of volcanogenic PSCs and chlorine destroyed ozone at much faster rates than other PSCs that Arctic winter. Elevated levels of HNO3 and NOy in the cloud can be explained by atmospheric nitrogen fixation in the eruption column due to high temperatures and/or volcanic lightning. However, observed elevated levels of HOx remain unexplained given that the cloud was sampled at night. Copyright 2006 by the American Geophysical Union.

Journal of Geophysical Research D: Atmospheres↗
USGS2008

Tile drainage as karst: Conduit flow and diffuse flow in a tile-drained watershed

The similarity of tiled-drained watersheds to karst drainage basins can be used to improve understanding of watershed-scale nutrient losses from subsurface tile drainage networks. In this study, short-term variations in discharge and chemistry were examined from a tile outlet collecting subsurface tile flow from a 963 ha agricultural watershed. Study objectives were to apply analytical techniques from karst springs to tile discharge to evaluate water sources and estimate the loads of agricultural pollutants discharged from the tile with conduit, intermediate and diffuse flow regimes. A two-member mixing model using nitrate, chloride and specific conductance was used to distinguish rainwater versus groundwater inputs. Results indicated that groundwater comprised 75% of the discharge for a three-day storm period and rainwater was primarily concentrated during the hydrograph peak. A contrasting pattern of solute concentrations and export loads was observed in tile flow. During base flow periods, tile flow consisted of diffuse flow from groundwater sources and contained elevated levels of nitrate, chloride and specific conductance. During storm events, suspended solids and pollutants adhered to soil surfaces (phosphorus, ammonium and organic nitrogen) were concentrated and discharged during the rapid, conduit flow portion of the hydrograph. During a three-day period, conduit flow occurred for 5.6% of the time but accounted for 16.5% of the total flow. Nitrate and chloride were delivered primarily with diffuse flow (more than 70%), whereas 80-94% of total suspended sediment, phosphorus and ammonium were exported with conduit and intermediate flow regimes. Understanding the water sources contributing to tile drainage and the manner by which pollutant discharge occurs from these systems (conduit, intermediate or diffuse flow) may be useful for designing, implementing and evaluating non-point source reduction strategies in tile-drained landscapes. ?? 2007 Elsevier B.V. All rights reserved.

Journal of Hydrology↗
USGS2007

Nitrate dynamics within the Pajaro River, a nutrient-rich, losing stream

The major ion chemistry of water from an 11.42-km reach of the Pajaro River, a losing stream in central coastal California, shows a consistent pattern of higher concentrations during the 2nd (dry) half of the water year. Most solutes are conserved during flow along the reach, but [NO3−] decreases by ~30% and is accompanied by net loss of channel discharge and extensive surface–subsurface exchange. The corresponding net NO3− uptake length is 37 ± 13 km (42 ± 12 km when normalized to the conservative solute Cl−), and the areal NO3− uptake rate is 0.5 μmol m−2 s−1. The observed reduction in [NO3−] along the reach results from one or more internal sinks, not dilution by ground water, hill-slope water, or other water inputs. Observed reductions in [NO3−] and channel discharge along the experimental reach result in a net loss of 200–400 kg/d of NO3−-N, ~50% of the input load. High-resolution (temporal and spatial) sampling indicates that most of the NO3− loss occurs along the lower part of the reach, where there is the greatest seepage loss and surface–subsurface exchange of water. Stable isotopes of NO3−, total dissolved P concentrations, and streambed chemical profiles suggest that denitrification is the most significant NO3− sink along the reach. Denitrification efficiency, as expressed through downstream enrichment in 15N-NO3−, varies considerably during the water year. When discharge is greater (typically earlier in the water year), denitrification is least efficient and downstream enrichment in 15N-NO3− is greatest. When discharge is lower, denitrification in the streambed appears to occur with greater efficiency, resulting in lower downstream enrichment in 15N-NO3−.

California↗
USGS1996

Numerical evaluation of static-chamber measurements of soil-atmospheric gas exchange--Identification of physical processes

The exchange of gases between soil and atmosphere is an important process that affects atmospheric chemistry and therefore climate. The static-chamber method is the most commonly used technique for estimating the rate of that exchange. We examined the method under hypothetical field conditions where diffusion was the only mechanism for gas transport and the atmosphere outside the chamber was maintained at a fixed concentration. Analytical and numerical solutions to the soil gas diffusion equation in one and three dimensions demonstrated that gas flux density to a static chamber deployed on the soil surface was less in magnitude than the ambient exchange rate in the absence of the chamber. This discrepancy, which increased with chamber deployment time and air-filled porosity of soil, is attributed to two physical factors: distortion of the soil gas concentration gradient (the magnitude was decreased in the vertical component and increased in the radial component) and the slow transport rate of diffusion relative to mixing within the chamber. Instantaneous flux density to a chamber decreased continuously with time; steepest decreases occurred so quickly following deployment and in response to such slight changes in mean chamber headspace concentration that they would likely go undetected by most field procedures. Adverse influences of these factors were reduced by mixing the chamber headspace, minimizing deployment time, maximizing the height and radius of the chamber, and pushing the rim of the chamber into the soil. Nonlinear models were superior to a linear regression model for estimating flux densities from mean headspace concentrations, suggesting that linearity of headspace concentration with time was not necessarily a good indicator of measurement accuracy.

Soil Science Society of America Journal↗
USGS2012

Chemistry and geothermometry of brine produced from the Salton Sea Scientific drill hole, Imperial Valley, California

The December 29–30, 1985, flow test of the State 2–14 well, also known as the Salton Sea Scientific drill hole, produced fluid from a depth of 1865–1877 m at a reservoir temperature of 305° ± 5°C. Another flow test at a depth of 3170 m produced brine contaminated by drilling fluid and diesel oil. Therefore we focus on the first flow test. Samples were collected at five different flashing pressures. The brines are Na-Ca-K-Cl-type waters with very high metal and low SO 4 and HCO 3 contents. Compositions of the flashed brines were normalized relative to the 25°C densities of the solutions, and an ionic charge balance was achieved by adjusting the Na concentration. The composition of the preflashed reservoir fluid was calculated using enthalpy-chloride relations applied to the normalized and charge-balanced brines. The calculated total dissolved solids in the preflashed reservoir fluid ranges from about 24.8 wt %, assuming insignificant thermal losses from the erupting fluid before sampling, to 26.0 wt %, assuming a 10% enthalpy loss by conduction of thermal energy through casing and surface piping. The preferred total dissolved solids of the reservoir fluid is 25.05 wt %. The calculated specific density of the preflashed reservoir fluid at 305°C and 1870 m depth ranges from 0.9980 (no thermal loss prior to sampling) to 1.0107 ± 0.0023 g cm −3 (10% thermal loss). Of the various cation geothermometers that are now in common use, the Na-K-Ca method gives a temperature (310°C) closest to the measured temperature (305°C) in the production horizon. Calculated Na/K geothermometer temperatures, using equations suggested by different investigators, range from 326° to 364°C. The Mg/K 2 method gives a temperature of about 350°C, Mg/Li 2 about 282°, and Na/Li 395°–418°C.

Journal of Geophysical Research Solid Earth↗
USGS1998

Changes in the isotopic and chemical composition of ground water resulting from a recharge pulse from a sinking stream

The Little River, an ephemeral stream that drains a watershed of approximately 88 km2 in northern Florida, disappears into a series of sinkholes along the Cody Scarp and flows directly into the carbonate Upper Floridan aquifer, the source of water supply in northern Florida. The changes in the geochemistry of ground water caused by a major recharge pulse from the sinking stream were investigated using chemical and isotopic tracers and mass-balance modeling techniques. Nine monitoring wells were installed open to the uppermost part of the aquifer in areas near the sinks where numerous subterranean karst solution features were identified using ground penetrating radar. During high-flow conditions in the Little River, the chemistry of water in some of the monitoring wells changed, reflecting the mixing of river water with ground water. Rapid recharge of river water into some parts of the aquifer during high-flow conditions was indicated by enriched values of delta 18O and delta deuterium (-1.67 to -3.17 per mil and -9.2 to -15.6 per mil, respectively), elevated concentrations of tannic acid, higher (more radiogenic) 87Sr/86Sr ratios, and lower concentrations of 222Rn, silica, and alkalinity compared to low-flow conditions. The proportion of river water that mixed with ground water ranged from 0.10 to 0.67 based on binary mixing models using the tracers 18O, deuterium, tannic acid, silica, 222Rn, and 87Sr/86Sr. On the basis of mass-balance modeling during steady-state flow conditions, the dominant processes controlling carbon cycling in ground water are the dissolution of calcite and dolomite in aquifer material, and aerobic degradation of organic matter.The Little River of northern Florida disappears into a series of sinkholes along the Cody Scarp and flows directly into the carbonate Upper Floridan aquifer. The changes in the geochemistry of ground water caused by a major recharge pulse from the sinking stream were investigated using chemical and isotopic tracers and mass-balance modeling techniques. Nine monitoring wells were installed open to the uppermost part of the aquifer. During high-flow conditions in the Little River, the chemistry of water in some of the monitoring wells changed, reflecting the mixing of river water with ground water. Based on mass-balance modeling during steady-state flow conditions, it was found that the dominant processes controlling carbon cycling in ground water are the dissolution of calcite and dolomite in aquifer material, and aerobic degradation of organic matter.

Journal of Hydrology↗
USGS2002

Development of sulfide calibration standards for the laser ablation inductively-coupled plasma mass spectrometry technique

The requirements of standard materials for LA-ICP-MS analysis have been difficult to meet for the determination of trace elements in sulfides. We describe a method for the production of synthetic sulfides by precipitation from solution. The method is detailed by the production of approximately 200 g of a material, PS-1, with a suite of chalcophilic trace elements in an Fe-Zn-Cu-S matrix. Preliminary composition data, together with an evaluation of the homogeneity for individual elements, suggests that this type of material meets the requirements for a sulfide calibration standard that allows for quantitative analysis. Contamination of the standard with Na suggests that H2S gas may prove a better sulfur source for future experiments. We recommend that calibration data be collected in whatever mode is closest to that employed for the analysis of the unknown material, because of variable fractionation effects as a function of analytical mode. For instance, if individual spot analyses are attempted on unknown sample, then a raster of several individual spot analyses, not a continuous scan, should be collected and averaged for the standard. Hg and Au are exceptions to the above and calibration data should always be collected in a scanning mode. Au is more heterogeneously distributed than other trace metals and large-area scans are required to provide an average value for calibration purposes. We emphasize that the values given in Table 1 are preliminary values. Further chemical characterization of this standard, through a round-robin analysis program, will allow the USGS to provide both certified and recommended values for individual elements. The USGS has developed PS-1 as a potential new LA-ICP-MS standard for use by the analytical community, and requests for this material should be addressed to S. Wilson. However, it is stressed that an important aspect of the method described here is the flexibility for individual investigators to produce sulfides with a wide range of trace metals in variable matrices. For example, PS-1 is not well suited to the analysis of galena, and it would be relatively straightforward for other standards to be developed with Pb present in the matrix as a major constituent. These standards can be made easily and cheaply in a standard wet chemistry laboratory using equipment and chemicals that are readily available.

Journal of Analytical Atomic Spectrometry↗