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Satellite time series analysis to quantify changing climax ciénegas using a state and transition model approach

Ciénegas are rare wetlands in arid landscapes of the North American Southwest, historically providing critical ecological and hydrological functions but increasingly threatened by changing climate and land use pressures. This study quantifies changes in ciénega condition and floodplain dynamics using a state-and-transition model (STM) informed by expert knowledge and remote sensing. Key factors include woody plant encroachment, water availability, and soil aggradation. We mapped 31 ciénegas with high-resolution imagery and analyzed Landsat data (1985–2023) to assess vegetation health and moisture using the Normalized Difference Vegetation Index (NDVI) and Normalized Difference Infrared Index (NDII). Results show substantial interannual variability in phenology, water stress, and soil moisture, with regional drying and elevation strongly influencing ciénega resilience. We classified ciénegas into three functional states—healthy, desiccated, and dormant—and mapped their 2023 condition. Trend analyses indicate most ciénegas exhibit greening despite drought, though localized variability underscores the need for site-specific management. None are in a stable climax (reference) state; rather, they transition among states in response to external drivers. Increasing woody plant cover and surface drying, likely linked to declining regional water tables, favor deep-rooted species over wetland grasses—a pattern mirrored in adjacent control plots. Spatially explicit analysis revealed intra-ciénega variability often masked by aggregated data, highlighting the importance of high-resolution monitoring. Seasonal and long-term trends provide context for understanding ciénega dynamics, including degradation and restoration pathways. This study emphasizes the importance of groundwater conservation and demonstrates how remote sensing supports long-term monitoring. The STM framework offers a practical tool for adaptive management to sustain freshwater resources in arid environments.

Arizona, New Mexico

Pesticides in surface waters of the Upper Colorado River Basin, Colorado, 1996-98

Forty-four river, stream, and drain sites in the Upper Colorado River Basin in Colorado were sampled during 1996-98 to determine the occurrence and distribution of pesticides in the basin. In a fixed-station study, 57 surface-water samples were collected from October 1996 through January 1998 at four sites. Each site was sampled approximately monthly for up to a year, with more frequent sampling during the spring and summer growing season. In a synoptic study, surface-water samples were collected at 43 sites in the agricultural areas of the Grand Valley and the Uncompahgre River Valley in May 1998. Each site was sampled once. Pesticide concentrations generally were low and varied seasonally and across land uses. Thirty-five pesticides were detected at least once in the two studies, and 11 pesticides accounted for almost 82 percent of the detections. Herbicides were more commonly detected than insecticides, and only the herbicides alachlor and atrazine were detected in more than 50 percent of the samples. Carbofuran was the most commonly detected insecticide and was detected in 19 percent of the samples. Pesticide detections increased and were measured at higher concentrations in the summer months and at the agriculture sites. All pesticide concentrations were less than drinking-water standards, and most complied with human-health advisories and criteria for the protection of freshwater aquatic life. Pesticides in the Upper Colorado River Basin in Colorado were detected slightly less frequently and generally at lower concentrations than in 20 National Water-Quality Assessment Program study-unit basins that collected water-quality data from 1992 through 1996. Results from surface-water sampling conducted during 1996?98 in the Upper Colorado River Basin in Colorado indicate that beneficial uses of water were not being impaired by the presence of pesticides in surface waters in the basin.

Colorado

Recent scientific contributions by the U.S. Geological Survey in the San Francisco Bay and Sacramento–San Joaquin Delta Estuary

Introduction The San Francisco Bay and Sacramento–San Joaquin Delta Estuary (hereafter, Bay-Delta) is the largest estuary on the West Coast of the United States. The Bay-Delta covers more than 1,600 square miles and drains a watershed of more than 75,000 square miles, which is greater than 40 percent of California. The region surrounding the Bay-Delta is home to about 10 million people, and its habitats (fig. 1) support more than 800 plant and animal species. The waterways of the Bay-Delta are the central hub of California’s extensive freshwater delivery system, supplying water to more than 27 million Californians and 4 million acres of farmland in the Central Valley. The U.S. Geological Survey (USGS) is the primary science agency of the U.S. Department of the Interior, providing a broad range of Earth, water, biological, and mapping data and expertise to inform natural resource management across the country. This fact sheet focuses on research conducted by the USGS in the Bay-Delta region, mostly within the past 5 years. The fact sheet is organized across five major themes: water flow and water quality, fish and wildlife, wetland restoration, invasive species, and hazards. In each of these areas, the USGS works closely with Federal, State, and local agencies; academia; and non-governmental organizations to provide objective, evidence-based science. The data and knowledge gained from USGS research and monitoring are publicly available and are routinely used by agencies, including the U.S. Bureau of Reclamation, U.S. Army Corps of Engineers, U.S. Fish and Wildlife Service, California Department of Water Resources, California Department of Fish and Wildlife, California State Water Resources Control Board, Delta Stewardship Council, and many additional organizations and stakeholders to inform management of the Bay-Delta region and its resources.

California

Status of water-quality conditions in the United States, 2010–20

Degradation of water quality can make water harmful or unusable for humans and ecosystems. Although many studies have assessed the effect of individual constituents or narrow suites of constituents on freshwater systems, no consistent, comprehensive assessment exists over the wide range of water-quality effects on water availability. Using published studies, data, and models completed at regional or national scales in the United States during 2010–20, this chapter moves towards a comprehensive assessment by summarizing how selected anthropogenic and geogenic water-quality constituents affect national-scale water availability for human and ecosystem needs. Several types of human health, agricultural, ecological, and beneficial-use standards or thresholds were used to provide context for categorizing surface-water and groundwater quality. Water availability for human and ecological use is limited by elevated concentrations of geogenic and anthropogenic constituents in surface and groundwater. Elevated concentrations of five geogenic constituents (arsenic, manganese, strontium, radium, and adjusted gross alpha) are common in groundwater and collectively affect the drinking water supply to over 30 million people. Surface water sourced drinking water supplies are impaired in about a third of assessed stream miles, most commonly because of non-mercury metals and salinity. Health-based violations at community water systems may disproportionately affect socially vulnerable communities. Ecological water uses are predominantly limited by nutrients, sediment, temperature, pathogens, salinity, and pesticides. Water availability for human and ecological use is adversely affected by human activities including human contaminant sources (for example, wastewater, agriculture), processes (for example, dredging, groundwater pumping), or permanent landscape modifications (for example, dams, urbanization). Primary contaminant sources vary spatially and include fertilizer and manure, atmospheric deposition, wastewater treatment plants, urban land, and a range of natural sources. Contaminants of emerging concern, contaminants without regulatory thresholds, and mixtures of geogenic and anthropogenic water contaminants also contribute to ecological degradation and human exposure.

conterminous United States

Sources of water and salts for the Zuni Salt Lake in west-central New Mexico

The Zuni Salt Lake is located in a maar in west-central New Mexico and contains hypersaline water that has long been used by Native Americans for religious purposes and the collection of salt. There have been several investigations suggesting different sources for the water and salt to the lake. Springs, seeps, and ephemeral streamflow have all been observed to contribute freshwater to the lake, and brackish to hypersaline seeps have been documented along the banks of the lake. This report summarizes the findings of a study that characterizes the lake’s hydrology, its water and salinity sources, and the hydrogeologic conceptual model. Regional groundwater levels indicate that each of the aquifers in the area have the potential to discharge groundwater to the lake. There is also evidence of vertical groundwater flow pathways at the maar that were likely created by the igneous intrusion that fractured the intersecting aquifers. A detailed water budget was constructed from continuous lake stage, precipitation, and evaporation data to estimate the groundwater inflow to the Zuni Salt Lake. It was determined that groundwater inflow to the lake is 441 ±94 acre-feet per year, which composes as much as 77 percent of the total inflows. The high sodium and chloride concentrations measured in two hypersaline samples collected near the lake indicate that the majority of the dissolved solids entering the lake are from a hypersaline groundwater source. The geochemical and isotopic compositions measured in the lake and surrounding features support the interpretation that hypersaline groundwater is the primary source of salts to the lake, which is likely sourced from the older (and deeper) Permian units. The hypersaline groundwater samples collected during this investigation have a unique aqueous chemistry relative to each of the mapped aquifers, and variability in groundwater compositions is interpreted to result from differences in minerology and residence time.

New Mexico

Assessment of the interconnection between Tampa Bay and the Floridan aquifer system: Historical groundwater data compilation and analysis, 1976–2022

The U.S. Geological Survey used existing data collected after the last major navigational channel modification in the mid-1980s to investigate groundwater levels and chloride concentrations in wells in the Floridan aquifer system and other aquifers beneath and near Tampa Bay. Tampa Bay is located on the west-central coast of Florida and provides access for commercial shipping. In 2021, the U.S. Army Corps of Engineers began to investigate alternatives to improve the efficiency of the deep-draft navigation channels within Tampa Bay, reduce costs, improve safety, and analyze the implications of modifying navigational channels. The Floridan aquifer system underlies Tampa Bay and is the primary source of public water supply in the region. Modifications to the channels have the potential to expose the Floridan aquifer system to the saltwater in Tampa Bay, with the potential to increase salinity in wells in the region. Other factors affecting the groundwater levels and the location of the freshwater/saltwater interface were also examined, including changes in sea level, groundwater extraction, and variations in climate. Groundwater levels and well-construction reports were used to identify whether different aquifer units are well-connected. Twelve wells had available data before and after the last major channel modifications, which took place in the 1980s, with six datasets of chloride concentration available in areas along the northern and eastern coastline of Tampa Bay, which is nearest to historical dredging activities. Of these six, Kendall’s τ and p -values indicated increasing trends in chloride concentration for three datasets (TR 11-2, TR 10-2, 51), no trend in chloride concentration for two datasets (TR 9-3, 50), and a decreasing trend in chloride concentration for one dataset (TR 9-1). The upward trends in chloride concentration observed for TR 10-2 and 51 are likely the result of changes in local groundwater withdrawals. Well TR 11-2 had a gradual increasing trend in chloride concentration, fresh groundwater throughout the period of record, and a 3- to 4-foot increase in hydraulic head during the period of record, possibly caused by the construction and control of the Tampa Bypass Canal, resulting in changes to the regional potentiometric surface.

Florida

Simulated hydrologic responses to proposed wastewater-returnflow scenarios in Falmouth, Massachusetts

The Cape Cod aquifer is the sole source of drinking water for communities on Cape Cod, Massachusetts, including the Town of Falmouth, where the aquifer is currently threatened by contamination from septic-system-derived nitrogen. To address this problem, the Town is proposing to sewer areas of Falmouth, treat the wastewater at the Town’s Main Wastewater Treatment Facility (a nitrogen removing/tertiary treatment facility), and discharge the treated wastewater to an ocean outfall pipe in Nantucket Sound. The U.S. Geological Survey, in cooperation with the Town of Falmouth, updated a three-dimensional steady-state groundwater flow model to represent current (defined as 2019–23) average hydrologic conditions and to simulate the long-term average freshwater hydrologic response to two wastewater-return-flow scenarios. Scenario 1 involves the sewering of all properties south of Route 28 in Falmouth, which approximates the Town’s possible sewer expansion over the next 20–30 years. Scenario 2 involves sewering of all properties in Falmouth to demonstrate the maximum potential effect of sewering on the aquifer. Overall, the simulated hydrologic response of water-table altitudes and streamflow in both scenarios was relatively small compared to fluctuations from natural recharge. In scenario 1, the water-table altitude decreased by about 0.1 feet south of Route 28, where the conversion to municipal sewers removed wastewater-return flow from onsite septic systems. The water-table altitude decreased by about 0.1–0.2 feet over a larger area in Falmouth under town-wide sewering in scenario 2. The greatest decrease in water-table altitude in both scenarios occurred near the Main Wastewater Treatment Facility, with a decrease of about 1.1 feet in scenario 1 and about 1.3 feet in scenario 2. Simulated decreases in streamflow also were estimated for six selected streams in Falmouth and Mashpee. In both scenarios, the largest simulated decreases in streamflow were at the Coonamessett River, which is the closest stream to the Main Wastewater Treatment Facility. In scenario 1, the average annual decrease in flow at the Coonamessett River was 0.1 cubic feet per second, a 1.1 percent decrease from current (2019–23) conditions. In scenario 2, streamflow at the Coonamessett River decreased by 0.6 cubic feet per second, a 5.4 percent decrease from current (2019–23) conditions.

Massachusetts

Water use across the conterminous United States, water years 2010–20

Withdrawals of water for human use are fundamental to the evaluation of the Nation’s water availability. This chapter provides an analysis of public supply, crop irrigation, and thermoelectric power water use for the conterminous United States (CONUS) during water years 2010–20. These three categories account for about 90 percent of water withdrawals in the Nation. The values presented here are based on modeling approaches that estimate water use at temporal (monthly) and spatial scales (12-digit hydrologic unit code—small watersheds sized 50–100 square kilometers) compatible for integration into a broader national assessment of water availability. Models also provide an understanding of factors that influence water use. An estimated 244,817 million gallons per day (Mgal/d; 28,677 million cubic meters per month [Mm 3 /mo]) were withdrawn on average within the CONUS during water years 2010–20 from fresh water and saline water for crop irrigation, public supply, and thermoelectric power, with shares of 43, 14.5, and 42.5 percent for each of these categories, respectively. In the same period, estimated withdrawals and consumptive use (1) for public supply were 35,400 and 4,219 Mgal/d (4,081 and 486 Mm 3 /mo), respectively; (2) for crop irrigation were 105,497 and 75,698 Mgal/d (12,147 and 8,716 Mm 3 /mo), respectively; and (3) for thermoelectric power from fresh water were 82,656 and 2,904 Mgal/d (9,952 and 345 Mm 3 /mo), respectively. Withdrawals for these categories of water use are highly spatially variable, with western States dominated by crop irrigation and eastern States dominated by thermoelectric-power water use. Public supply accounts for the largest percentage of water use in several heavily populated northeastern States. Reliance on groundwater compared to surface water depends on the availability of water sources and the type of water use. For public supply, withdrawals from groundwater are greater than withdrawals from surface water in the Western aggregated hydrologic regions, whereas the balance shifts to more surface water for the rest of the CONUS. In all aggregated hydrologic regions, the predominant source of water for crop irrigation is groundwater. Most thermoelectric power facilities in the eastern half of the CONUS use surface water from freshwater and saline sources; most thermoelectric power facilities in the western half of the CONUS use groundwater.

conterminous United States

The value of electronic tagging and tracking studies for understanding fish–hypoxia interactions

Objective Hypoxia (i.e., low dissolved oxygen availability) is a natural phenomenon but can also be induced by human activities (e.g., nutrient enrichment from runoff). Given that dissolved oxygen is essential for aquatic life, periods of hypoxia tend to have negative consequences (e.g., sublethal disturbances, mortality) for most fishes. Extensive laboratory research has documented hypoxia thresholds and physiological and behavioral outcomes for a variety of freshwater and marine fishes and there is also an extensive body of fieldwork assessing population-level responses (e.g., survival, distribution). Yet, studying how individual fish respond to hypoxia in the wild has proved challenging; electronic tagging and tracking tools (e.g., biotelemetry, biologging) have made it easier to study individual responses to hypoxia and complement other tools like hydroacoustics that tend to focus on population-level responses. Methods We review what has been learned from contemporary studies that employ electronic tagging and tracking tools to understand how fish respond to hypoxia in the wild. Topics explored include identifying and validating hypoxia thresholds, habitat compression, connectivity, mortality, physiological and bioenergetic consequences, and extreme weather conditions. We also consider what we have learned about evaluating various management plans for hypoxia and reflect on how electronic tags have also been used in aquaculture systems and in hybrid studies that combine laboratory and field research. We highlight fishes in Lake Erie as a research narrative to demonstrate how electronic tagging and tracking have markedly improved our understanding of a longstanding hypoxia issue. Results Our synthesis revealed that electronic tagging and tracking have provided critical information on how fish respond to hypoxia in the field, revealing complex trade-offs and compensatory mechanisms as well as cryptic hypoxia-induced mortality. Beyond just illuminating space use and mortality, tags equipped with various sensors are revealing how fish deal with hypoxia in real time in terms of physiology, bioenergetics, and behavior. Conclusions As electronic tagging and tracking methods experience further innovation and are increasingly applied to understand the effects of hypoxia on fish, we expect more unanticipated findings about the effects of hypoxia on fish in all aquatic ecosystems, which will strengthen our ability to manage and mitigate hypoxia. Combining tools and approaches (e.g., lab and field) is perhaps the best way to generate comprehensive understanding.

Transactions of the American Fisheries Society

Assessment of channel morphology, hydraulics, and bedload transport along the Siletz River, western Oregon

Significant Findings Chinook salmon ( Oncorhynchus tshawytscha ) and Pacific lamprey ( Entosphenus tridentatus ) are native, anadromous fish species in the Siletz River Basin, western Oregon, that face many threats to their survival in freshwater and the ocean. The Confederated Tribes of Siletz Indians of Oregon seek to mitigate freshwater threats to Chinook salmon and Pacific lamprey, where possible, with habitat conservation and restoration efforts. This study was conducted to assist the Confederated Tribes of Siletz Indians of Oregon in documenting and understanding the hydrogeomorphic processes shaping present-day habitat conditions and assessing future habitat implications for Chinook salmon and Pacific lamprey along the main-stem Siletz River. As such, this study focused on understanding geomorphic processes and patterns of channel change, including lateral and vertical adjustments in channel position and changes in bed-material sediment (sands, gravels, and cobbles that mantle the channel bed), which collectively determine overall patterns of channel morphology and fluvial habitats. Objective One was to evaluate lateral changes in channel position, vertical changes in bed elevation, and longitudinal patterns in bed-material particle size along the Siletz River using detailed channel maps developed from aerial photographs collected from 1939 to 2016, long-term records of stage and discharge collected by the U.S. Geological Survey (USGS) near the City of Siletz, and sediment particle size data. Objective Two was to assess hydraulic conditions using one- and two-dimensional hydraulic models and transport capacity of bed-material sediment using bedload transport models and sediment particle size data for a range of discharge conditions. Objective Three was to identify potential burrowing habitat for lamprey larvae (PBH) along the Siletz River network and provide insights in local factors influencing PBH along the main-stem Siletz River. The overall findings are synthesized to describe habitat implications for Chinook salmon and Pacific lamprey under present-day and future conditions. Results of Objective One, an evaluation of changes in channel position and bed elevations and longitudinal patterns in bed-material particle size along the Siletz River, include the following From 1939 to 2016, channel planform and the mapped area of gravel bars did not change considerably along the 97.2-kilometers (km) of Siletz River between Elk Creek and Millport Slough, except for in short sections generally less than 1 km long. This inherent lateral channel stability results from the resistant bedrock and terraces that bound most of the channel and limit lateral changes in channel position. Intermittent sections along the study reach where the active channel widened at channel bends displayed noticeable planform changes and increases in mapped bar area. From water year (WY; a 12-month period from October 1 through September 30 and named for the year in which it ends) 1906 to 2021, changes in the stage-discharge relation interpreted as rising and lowering channel bed levels were observed at the USGS streamgage 14305500 (Siletz River at Siletz, OR) in response to floods (such as high flows in February 1996 and January 2002 that exceeded 0.1 and 0.667 annual exceedance probabilities [AEP] events, respectively). However, the rating curve representing the stage-discharge relation did not change in response to high-magnitude floods between 2007 and 2021. Along the approximately 54-km of the Siletz River between Moonshine Park and the Bulls Bag area, surficial particle distributions varied considerably between sampling sites in response to changes in channel width and gradient, sediment inputs from tributaries, and basin geology. Despite this variability, median particle sizes tended to decrease in size in the downstream direction over the 54 km. Results of Objective Two, an evaluation of hydraulic and bedload transport conditions along the Siletz River, include the following The most substantial increases in maximum and mean water velocity and bedload sediment transport capacity occurred at events between the 0.995 and 0.50 AEPs. Events of these magnitudes occur approximately every 1–2 years. Smaller events (0.995 AEP) are generally contained by the banks of the main channel, whereas larger events (0.50 AEP) generally spill over the banks and inundate high-elevation bar and low-elevation floodplain surfaces. Multiple smaller floods within a WY that exceed the 0.995 and 0.50 AEPs (such as in WY 1996) can transport as much or more bed-material sediment than a single, higher magnitude event (such as the maximum event recorded in WY 2000 with an estimated AEP of around 0.002). Bedload transport capacity generally exceeds sediment supply (greater than 2 millimeters [mm]) for most of the study area from Wildcat Creek to the City of Siletz as evidenced by substantial in-channel bedrock. Despite overall conditions of limited sediment supply, transport capacity still varies considerably within and between years with discharge magnitude and spatially in relation to local hydraulics imposed by bedrock, channel morphology, and human infrastructure (such as bridges). Results of Objective Three, an analysis of PBH for lamprey larvae, include the following About 28 percent of the Siletz River network meets the mean annual suspended sediment loads and channel slope criteria for PBH. Along the main-stem Siletz River, in-channel bedrock outcrops and high transport capacity are expected to further constrain PBH. Together, these results suggest that most of the Siletz River between Wildcat Creek and the City of Siletz has had only modest vertical and lateral change between the 1930s and 2010s because of the bedrock in and along the main channel and the river’s relatively high transport capacity relative to bed-material sediment supply. However, localized sections of the Siletz River where the active channel widens, particularly at channel bends, exhibited some change in channel planform and the locations and area of gravel bars. In the future, moderate increases in autumn-winter discharge may not result in substantial changes in coarse gravel bars along the Siletz River but may result in selective transport of finer bed-material sediment (gravel, sands, and silts) that provide spawning habitats for Chinook salmon and Pacific lamprey and burrowing habitats for lamprey larvae. Assuming no substantial changes in bed-material sediment supply, increased bedload transport capacity may cause frequent entrainment of lamprey larvae that are burrowed in coarse sand deposits, suspension and downstream transport of salmon eggs incubating in gravels, and reductions in the areas of spawning gravels for Chinook salmon and Pacific lamprey. Exact implications of current and future discharge conditions for these species along the Siletz River depends on many factors, including sediment supply, local hydraulics, and the timing of flood events relative to fish life stages.

Oregon

Investigation of drivers and sources of potential harmful algal blooms in Lake Anna, Virginia, 2023-24

Algal blooms in freshwater reservoirs are an increasing concern because of the risk to aquatic ecosystem health, recreational use, and water quality. Among the taxa that comprise an algal bloom, cyanobacteria are of particular concern due to the potential to produce toxic compounds which can cause acute and chronic illness in humans if ingested through contaminated water or shellfish. When toxins are above a toxin-specific threshold in the water column, the Commonwealth of Virginia categorizes the bloom as a harmful algal bloom (HAB), distinguishing it from an algal bloom without toxins present. Toxins are of particular concern in bodies of water which serve as major recreational areas, such as Lake Anna in central Virginia. Lake Anna is a 27 km-long and 47 km2 reservoir in central Virginia. Since the Commonwealth of Virginia revised the HAB monitoring framework in 2018, algal bloom advisories for potentially toxigenic blooms have been issued in the western, riverine zone of the reservoir. There were detections of microcystin and anatoxin production but no detections of cylindrospermopsin and saxitoxin production in Lake Anna; however, toxin concentrations were low, at values less than 0.65 µg/L. In 2023, the U.S. Geological Survey, in cooperation with Virginia Department of Environmental Quality, initiated a 19-month intensive and extensive study of western Lake Anna and its tributaries (North Anna River and Pamunkey Creek) to (1) characterize the algal community, biomass, and toxin production; (2) identify potential drivers leading to algal bloom initiation, persistence, and decline; and (3) assess the primary sources of the drivers contributing to algal blooms. Continuous and discrete monitoring of water quality within the lake, watershed inputs, meteorological conditions, and algal communities were monitored. Multiple modeling scenarios identified that the formation and persistence of algal blooms in Lake Anna are driven by interactions among chemical, macro- and micronutrient, and physical factors. Key drivers include total nitrogen, total phosphorus, water temperature, suspended sediment concentration, wind speed, copper, iron, molybdenum, nickel, sodium, and alkalinity. During this study, winter stormflow events delivered the highest loading of macro- and micronutrients from the tributaries to the lake. The lake is a sink for these nutrients in the water column or in the lake-bed sediments. During high-occupancy and recreation periods on the lake in the summer months, boating activity can promote internal loading by the resuspension of the lake-bed sediments, thereby increasing the nutrient availability for algal uptake. Thermal stratification and hypoxic conditions were observed, which can contribute to the passive release of nutrients into the water column, further facilitating algal bloom proliferation. These processes may create a positive feedback loop that supports the formation, persistence, and annual recurrence of algal blooms in the western region of Lake Anna. Continued water-quality monitoring of early warning indicators may improve the detection and forecasting of algal growth in the lake and help managers proactively manage water quality and algal growth.

EarthArXiv

Ground-water flow in the surficial aquifer system and potential movement of contaminants from selected waste-disposal sites at Naval Station Mayport, Florida

Ground-water flow through the surficial aquifer system at Naval Station Mayport near Jacksonville, Florida, was simulated with a two-layer finite-difference model as part of an investigation conducted by the U.S. Geological Survey. The model was calibrated to 229 water-level measurements from 181 wells during three synoptic surveys (July 17, 1995; July 31, 1996; and October 24, 1996). A quantifiable understanding of ground-water flow through the surficial aquifer was needed to evaluate remedial-action alternatives under consideration by the Naval Station Mayport to control the possible movement of contaminants from sites on the station. Multi-well aquifer tests, single-well tests, and slug tests were conducted to estimate the hydraulic properties of the surficial aquifer system, which was divided into three geohydrologic units�an S-zone and an I-zone separated by a marsh-muck confining unit. The recharge rate was estimated to range from 4 to 15 inches per year (95 percent confidence limits), based on a chloride-ratio method. Most of the simulations following model calibration were based on a recharge rate of 8 inches per year to unirrigated pervious areas. The advective displacement of saline pore water during the last 200 years was simulated using a particle-tracking routine, MODPATH, applied to calibrated steady-state and transient models of the Mayport peninsula. The surficial aquifer system at Naval Station Mayport has been modified greatly by natural and anthropogenic forces so that the freshwater flow system is expanding and saltwater is being flushed from the system. A new MODFLOW package (VAR1) was written to simulate the temporal variation of hydraulic properties caused by construction activities at Naval Station Mayport. The transiently simulated saltwater distribution after 200 years of displacement described the chloride distribution in the I-zone (determined from measurements made during 1993 and 1996) better than the steady-state simulation. The advective movement of contaminants from selected sites within the solid waste management units to discharge points was simulated using MODPATH. Most of the particles were discharged to the nearest surface-water feature after traveling less than 1,000 feet in the ground-water system. Most areas within 1,000 feet of a surface-water feature or storm sewer had traveltimes of less than 50 years, based on an effective porosity of 40 percent. Contributing areas, traveltimes, and pathlines were identified for 224 wells at Naval Station Mayport under steady-state and transient conditions by back-tracking a particle from the midpoint of the wetted screen of each well. Traveltimes to contributing areas that ranged between 15 and 50 years, estimated by the steady-state model, differed most from the transient traveltime estimates. Estimates of traveltimes and pathlines based on steady-state model results typically were 10 to 20 years more and about twice as long as corresponding estimates from the transient model. The models differed because the steady-state model simulated 1996 conditions when Naval Station Mayport had more impervious surfaces than at any earlier time. The expansion of the impervious surfaces increased the average distance between contributing areas and observation wells.

Florida

Evidence of nitrate attenuation in intertidal and subtidal groundwater in a subterranean estuary at a Cape Cod embayment, East Falmouth, Massachusetts, 2015–16

Nitrogen dynamics in intertidal and nearshore subtidal groundwater (subterranean estuary) adjacent to the Seacoast Shores peninsula, Falmouth, Massachusetts, were investigated during 2015–16 by the U.S. Geological Survey. The peninsula is a densely populated residential area with septic systems and cesspools that are substantial sources of nitrogen to groundwater. The study area is in the Eel River, an estuarine saltwater embayment connected to the ocean adjacent to the western shore of the peninsula, that was the subject of an earlier study by Colman and others (2018, https://doi.org/10.3133/sir20185095 ) on nitrogen transport and transformations in groundwater between onshore and offshore locations. The previous study documented the distribution of nitrate concentrations and nitrate attenuation reactions in fresh groundwater beneath the peninsula and the estuary. The current study extended those observations with more detailed sampling and analysis of shallow groundwater from wells near discharge sites beneath the estuary. The current field investigation included sampling of existing wells and installation and sampling of clusters of wells and temporary sampling points in the subterranean estuary, including (1) shallow transects 0.3 to 1.2 meters (m) deep extending from 1 to 13.5 m offshore and (2) deeper wells (from 1.83 to 4.88 m deep) extending from 4.3 to 14.3 m offshore. Measurements of hydraulic-head gradients 2–5 m below the sediment/water interface in the intertidal and nearshore subtidal zones indicated that groundwater flow generally was upwards (towards the estuary) under all tide conditions in October 2016. The magnitude of the gradient was greatest during low tide conditions, indicating that groundwater discharge likely decreased during high tides. Measurements of specific conductance in shallow groundwater in the subterranean estuary in three transects perpendicular to shore were consistent with the existence of saltwater flow cells (infiltration of overlying saline water, mixing with fresh groundwater, and discharge to the overlying saline water) in the intertidal and nearshore subtidal regions. The size of these flow cells was variable in space and time and dependent on the elevation of the tide (spring or neap). At this location in the Eel River subterranean estuary, and offshore to at least 13.5 m, offshore flow of fresh groundwater apparently prevented a deeper saltwater wedge from discharging to the surface. Nitrate concentrations in shallow groundwater (30 to 122 centimeters [cm] depth) were variable in space and time, ranging from not detectable to 600 micromoles per liter (μmol/L) (8.4 milligrams per liter as N), and were highest in June 2016 at depths from 61 to 122 cm below the sediment/water interface and from 4 to 9 m offshore. Nitrate generally was not detectable in saline shallow groundwater at 30-cm depth or at any depth from 30 to 122 cm from 10 to 13.5 m offshore. Dissolved oxygen concentrations were suboxic (less than 16 μmol/L) in 60 percent of the sampled subterranean groundwater beneath the intertidal and subtidal zones. In the remaining sites, the range of dissolved oxygen concentrations was from 18 to 272 μmol/L and the median concentration was 43 μmol/L. Evidence for microbial nitrate reduction (denitrification and possibly anammox) was provided by the distribution of the reaction product nitrogen gas (excess N 2 , or N 2MIC ), as determined from analysis of the dissolved nitrogen gas and argon gas (Ar) concentrations in groundwater samples. Excess nitrogen gas provided evidence for nitrate reduction in shallow groundwater below the subtidal and, to a lesser extent, intertidal zones adjacent to the Seacoast Shores peninsula. These zones, where evidence for nitrate reduction was detected, were in fresh and brackish groundwater near subtidal or intertidal saltwater cells where discharging fresh groundwater mixed with infiltrating saline water. Infiltrating seawater may have supplied organic carbon, one of several potential electron donors that are required for denitrification. Other potential electron donors, such as organic carbon, iron, manganese, hydrogen, methane, ammonium, elemental sulfur, or sulfide phases, may have been supplied by the estuarine sediments. Drainage from surface runoff near the shore also may have supplied organic carbon to fresh groundwater near the intertidal saltwater cell. The highest amounts of nitrate converted to excess nitrogen gas were estimated to be in the range of 230 to 430 μmol/L in nearly fresh groundwater near the subtidal saltwater cell at depths of 61 to 122 cm below the sediment/water interface and from 10 to 13.5 m offshore. Evidence of denitrification within 10 m of the shore was sparse (generally limited to less than 50 μmol/L of N 2 -N) despite the presence of high nitrate concentrations. The spatial distribution of estimated nitrate reduction in the intertidal and nearshore subtidal fresh and brackish groundwater may be related to local variability in the distribution of reactive electron donors in those zones. Variations in the amount of nitrate reduction to nitrogen gas were not clearly related to potential aqueous electron donors such as dissolved organic carbon, nor to potential reaction products such as alkalinity, but may have been controlled by combinations of aqueous and solid-phase reactants. The distribution of relatively shallow fresh groundwater containing nitrate could indicate potential nitrate discharge areas in the lower intertidal zone and uncertain locations farther offshore; however, the data did not extend all the way to the sediment/water interface or to the offshore freshwater limit. This study confirmed substantial loss of nitrate from some of the fresh and brackish groundwater in shallow subestuarine sediments prior to discharge but did not quantify how much nitrate eventually discharged to the estuary.

Massachusetts