USGS Science⌕ Search

SEARCH · USGS Science

Results for “Computers and Chemical Engineering”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

46 records · Page 3Linked to original sources

Projected effects of proposed chloride-control projects on shallow ground water– Preliminary results for the Wichita River basin, Texas

The U.S. Army Corps of Engineers' plan to control the natural chloride pollution in the Wichita River basin includes the construction of Truscott Brine Lake on a tributary of the North Wichita River. In connection with the proposed brine lake, the U.S. Geological Survey was requested to: (1) Define the existing ground-water conditions in the shallow fresh-water system of the project area; and (2) project the post-construction effects of the proposed lake on the fresh-water aquifer, especially in relation to hydraulic-head changes but also with respect to possible changes in the chemical quality of the ground water. The fresh-water aquifer in the project area is a shallow water-table system with relatively fresh water (generally a calcium sulfate type) that contains approximately 500 to 5,000 milligrams per liter of dissolved solids. The aquifer consists of Permian rocks with very small values of hydraulic conductivity and overlies a brine system (sodium chloride type) that is even less permeable. A thin transition zone separates the fresh-water aquifer and the brine system. Small quantities of infiltration from precipitation throughout the area's watershed constitute the recharge to the aquifer. Discharge from the aquifer consists of the small base flow along creeks; well discharge is negligible. Two-dimensional mathematical computer models were developed for aquifer simulation of: (1) Steady-state conditions in a fresh-water system and (2) transient conditions in a brine- fresh-water system where the density effects of the brine are considered. The main results 'of projecting the effects of the proposed Truscott Brine Lake on the fresh-water aquifer are: (1) Hydraulic head rises of 5 to 40 feet would be confined to areas near the proposed dam and along the lake shoreline, and (2) migration of salt water downstream from the dam generally would be limited to less than 1 mile and apparently would not reach equilibrium during the 100-year duration of the project. The modeling efforts did not include possible effects related to hydrodynamic dispersion in the brine- fresh-water system. Possible changes in the hydraulic conductivity of the aquifer, due to physical and chemical interactions in the brine and fresh-water environments, also were not considered.

Texas↗

Computer-model analysis of ground-water flow and simulated effects of contaminant remediation at Naval Weapons Industrial Reserve Plant, Dallas, Texas

In June 1993, the Department of the Navy, Southern Division Naval Facilities Engineering Command (SOUTHDIV), began a Resource Conservation and Recovery Act (RCRA) Facility Investigation (RFI) of the Naval Weapons Industrial Reserve Plant (NWIRP) in north-central Texas. The RFI has found trichloroethene, dichloroethene, vinyl chloride, as well as chromium, lead, and other metallic residuum in the shallow alluvial aquifer underlying NWIRP. These findings and the possibility of on-site or off-site migration of contaminants prompted the need for a ground-water-flow model of the NWIRP area. The resulting U.S. Geological Survey (USGS) model: (1) defines aquifer properties, (2) computes water budgets, (3) delineates major flowpaths, and (4) simulates hydrologic effects of remediation activity. In addition to assisting with particle-tracking analyses, the calibrated model could support solute-transport modeling as well as help evaluate the effects of potential corrective action. The USGS model simulates steadystate and transient conditions of ground-water flow within a single model layer. The alluvial aquifer is within fluvial terrace deposits of Pleistocene age, which unconformably overlie the relatively impermeable Eagle Ford Shale of Late Cretaceous age. Over small distances and short periods, finer grained parts of the aquifer are separated hydraulically; however, most of the aquifer is connected circuitously through randomly distributed coarser grained sediments. The top of the underlying Eagle Ford Shale, a regional confining unit, is assumed to be the effective lower limit of ground-water circulation and chemical contamination. The calibrated steady-state model reproduces long-term average water levels within +5.1 or –3.5 feet of those observed; the standard error of the estimate is 1.07 feet with a mean residual of 0.02 foot. Hydraulic conductivity values range from 0.75 to 7.5 feet per day, and average about 4 feet per day. Specific yield values range from 0.005 to 0.15 and average about 0.08. Simulated infiltration rates range from 0 to 2.5 inches per year, depending mostly on local patterns of ground cover. Computer simulation indicates that, as of December 31, 1998, remediation systems at NWIRP were removing 7,375 cubic feet of water per day from the alluvial aquifer, with 3,050 cubic feet per day coming from aquifer storage. The resulting drawdown prevented 1,800 cubic feet per day of ground water from discharging into Cottonwood Bay, as well as inducing another 1,325 cubic feet per day into the aquifer from the bay. An additional 1,200 cubic feet of water per day (compared to pre-remediation conditions) was prevented from discharging into the west lagoon, east lagoon, Mountain Creek Lake, and Mountain Creek swale. Particle-tracking simulations, assuming an aquifer porosity of 0.15, were made to delineate flowpath patterns, or contaminant “capture zones,” resulting from 2.5- and 5-year periods of remediation activity at NWIRP. The resulting flowlines indicate three such zones, or areas from which ground water is simulated to have been removed during July 1996–December 1998, as well as extended areas from which ground water would be removed during the next 2.5 years (January 1999– June 2001). Simulation indicates that, as of December 31, 1998, the recovery trench was intercepting about 827 cubic feet per day of ground water that—without the trench—would have discharged into Cottonwood Bay. During this time, the trench is simulated to have removed about 3,221 cubic feet per day of water from the aquifer, with about 934 cubic feet per day (29 percent) coming from the south (Cottonwood Bay) side of the trench.

Texas↗

Adaptive moving mesh methods for simulating one-dimensional groundwater problems with sharp moving fronts

Accurate modelling of groundwater flow and transport with sharp moving fronts often involves high computational cost, when a fixed/uniform mesh is used. In this paper, we investigate the modelling of groundwater problems using a particular adaptive mesh method called the moving mesh partial differential equation approach. With this approach, the mesh is dynamically relocated through a partial differential equation to capture the evolving sharp fronts with a relatively small number of grid points. The mesh movement and physical system modelling are realized by solving the mesh movement and physical partial differential equations alternately. The method is applied to the modelling of a range of groundwater problems, including advection dominated chemical transport and reaction, non-linear infiltration in soil, and the coupling of density dependent flow and transport. Numerical results demonstrate that sharp moving fronts can be accurately and efficiently captured by the moving mesh approach. Also addressed are important implementation strategies, e.g. the construction of the monitor function based on the interpolation error, control of mesh concentration, and two-layer mesh movement. Copyright ?? 2002 John Wiley and Sons, Ltd.

International Journal for Numerical Methods in Eng↗

NetpathXL - An excel interface to the program NETPATH

NetpathXL is a revised version of NETPATH that runs under Windows? operating systems. NETPATH is a computer program that uses inverse geochemical modeling techniques to calculate net geochemical reactions that can account for changes in water composition between initial and final evolutionary waters in hydrologic systems. The inverse models also can account for the isotopic composition of waters and can be used to estimate radiocarbon ages of dissolved carbon in ground water. NETPATH relies on an auxiliary, database program, DB, to enter the chemical analyses and to perform speciation calculations that define total concentrations of elements, charge balance, and redox state of aqueous solutions that are then used in inverse modeling. Instead of DB, NetpathXL relies on Microsoft Excel? to enter the chemical analyses. The speciation calculation formerly included in DB is implemented within the program NetpathXL. A program DBXL can be used to translate files from the old DB format (.lon files) to NetpathXL spreadsheets, or to create new NetpathXL spreadsheets. Once users have a NetpathXL spreadsheet with the proper format, new spreadsheets can be generated by copying or saving NetpathXL spreadsheets. In addition, DBXL can convert NetpathXL spreadsheets to PHREEQC input files. New capabilities in PHREEQC (version 2.15) allow solution compositions to be written to a .lon file, and inverse models developed in PHREEQC to be written as NetpathXL .pat and model files. NetpathXL can open NetpathXL spreadsheets, NETPATH-format path files (.pat files), and NetpathXL-format path files (.pat files). Once the speciation calculations have been performed on a spreadsheet file or a .pat file has been opened, the NetpathXL calculation engine is identical to the original NETPATH. Development of models and viewing results in NetpathXL rely on keyboard entry as in NETPATH.

Techniques and Methods↗

Visualization of Flow Alternatives, Lower Missouri River

Background The U.S. Army Corps of Engineers (COE) 'Missouri River Master Water Control Manual' (Master Manual) review has resulted in consideration of many flow alternatives for managing the water in the river (COE, 2001; 1998a). The purpose of this report is to present flow-management alternative model results in a way that can be easily visualized and understood. This report was updated in October 2001 to focus on the specific flow-management alternatives presented by the COE in the 'Master Manual Revised Draft Environmental Impact Statement' (RDEIS; COE, 2001). The original version (February 2000) is available by clicking here. The COE, U.S. Fish and Wildlife Service (FWS), Missouri River states, and Missouri River basin tribes have been participating in discussions concerning water management of the Missouri River mainstem reservoir system (MRMRS), the Missouri River Bank Stabilization and Navigation Project, and the Kansas River reservoir system since 1986. These discussions include general input to the revision of the Master Manual as well as formal consultation under Section 7 of the Endangered Species Act. In 2000, the FWS issued a Biological Opinion that prescribed changes to reservoir management on the Missouri River that were believed to be necessary to preclude jeopardy to three endangered species, the pallid sturgeon, piping plover, and interior least tern (USFWS, 2000). The combined Missouri River system is large and complex, including many reservoirs, control structures, and free-flowing reaches extending over a broad region. The ability to assess future impacts of altered management scenarios necessarily involves complex, computational models that attempt to integrate physical, chemical, biological, and economic effects. Graphical visualization of the model output is intended to improve understanding of the differences among flow-management alternatives.

Colorado, Iowa, Kansas, Missouri, Montana, Nebrask↗

Water resources data for Missouri, water year 1973

Water resources data for the 1973 water year for Missouri including records of streamflow or reservoir storage at gaging stations, partial-record stations, and miscellaneous sites, and records of water-quality data on the chemical and physical characteristics of surface water, are given in this report. In Part 1, records are included for 146 gaging stations of which 139 are streamflow discharge stations, and 7 are reservoir or lake stations; also are included records for 106 crest-stage partial-record stations. Locations of gaging stations are shown in figure 1. In Part 2, data on the quality of surface water (chemical, temperature, and sediment) were collected from designated sampling sites at predetermined intervals such as once daily, weekly, monthly, or less frequently, and at some sites data were recorded on punched paper tape at 30-, or 60minute intervals. Records are given for 114 sampling stations of which 25 are partial-record stations, and 30 are miscellaneous sites. Locations of water-quality stations are shown in figure 2. A few pertinent stations (not included above) in bordering states are also included in this report. The records were collected and computed by the Water Resources Division of the U.S. Geological Survey under the direction of Anthony Homyk, district chief. These data represent that portion of the National Water Data System collected by the U.S. Geological Survey and cooperating State and Federal agencies in Missouri. Beginning with the 1961 water year, streamflow records and related data have been released by the Geological Survey in annual reports on a State-boundary basis. Water-quality records beginning with the 1964 water year have been similarly released either in separate reports or in conjunction with streamflow records. These reports are for limited distribution and are designed primarily for rapid release of data shortly after the end of the water year.

Missouri↗

Water resources data for Louisiana, water year 1970

Water-resources data for the 1970 water year for Louisiana, including records of streamflow or reservoir storage at gaging stations, partial-record stations, and miscellaneous sites, and records of water quality data on the chemical and physical characteristics of surface water are given in this report. Records for a few pertinent gaging stations in bordering States are also included. The records were collected and computed by the Water Resources Division of the U.S. Geological Survey under the direction of Rex R. Meyer, district chief. These data represent that portion of the National Water Data System collected by the U.S. Geological Survey and cooperating State and federal agencies in Louisiana. Through September 30, 1960, the records of discharge and stage of streams and contents and stage of lakes or reservoirs were published in an annual series of U.S. Geological Survey water-supply papers entitled, "Surface Water Supply of the United States." Beginning with the 1961 water year, streamflow records and related data have been released by the Geological Survey in annual reports on a State-boundary basis. Distribution of these reports is limited; they are designed primarily for rapid release of data shortly after the end of the water year to meet local needs. Records will be published in Geological Survey water-supply papers at 5-year intervals. The Geological Survey has published records of chemical quality, suspended sediment, and water temperatures since 1941 in an annual series of water-supply papers entitled, "Quality of Surface Waters of the United States." Beginning with the 1964 water year, water-quality records also have been released on a State-boundary basis in conjunction with streamflow records or in a separate volume.

Louisiana↗

Water resources data for West Virginia, water year 1972

Water resources data for the 1972 water year for West Virginia including records of streamflow or reservoir storage at gaging stations, partial-record stations, and miscellaneous sites, and records of water-quality data on the chemical and physical characteristics of surface water, are given in this report. In Part 1, records are included for 126 gaging stations of which 119 are streamflow discharge stations, 1 is stage only streamflow station, and 6 are reservoir or lake stations; also included are records for 7 low-flow partial record stations, 42 crest-stage partial-record stations, and 12 miscellaneous sites. Locations of gaging stations are shown in Figure 1. In Part 2, data on the quality of surface water (chemical, temperature, and sediment) were collected from designated sampling sites at predetermined intervals, such as once daily, weekly, monthly, or less frequently, and at some sites data were recorded on punched paper tape at 15-, 30-, or 60-minute intervals. Records are given for 30 sampling stations of which 18 are continuous record stations, and 12 are partial-record stations. Locations of water-quality stations are shown in Figure 1. A few pertinent stations (not included above) in bordering States are also included in this report. The records were collected and computed by the Water Resources Division of the U.S. Geological Survey under the direction of Edwin E. Harris, district chief. These data represent that portion of the National Water Data System collected by the U.S. Geological Survey and cooperating State and Federal agencies in West Virginia. Beginning with the 1961 water year, streamflow records and related data have been released by the Geological Survey in annual reports on a State-boundary basis. Water-quality records beginning with the 1964 water year have been similarly released either in separate reports or in conjunction with streamflow records. These reports are for limited distribution and are designed primarily for rapid release of data shortly after the end of the water year. Records of discharge and stage of streams, and contents and stage of lakes and reservoirs are published in a series of U.S. Geological Survey water-supply papers entitled, "Surface Water. Supply of the United States." Through September 30, 1960, these water-supply papers were in an annual series and since then are in a 5-year series. Records of chemical quality, water temperatures, and suspended sediment have been published since 1941 in an annual series of water-supply papers entitled, "Quality of Surface Waters of the United States." More information is given under the headings "Publications" on pages 15 and 20.

West Virginia↗

Water resources data for West Virginia, water year 1974

Water resources data for the 1974 water year for West Virginia including records of streamflow or reservoir storage at gaging stations, partial-record stations, and miscellaneous sites, records of water-quality data on the chemical and physical characteristics of surface water, and records of ground-water levels at index wells are given in this report. In Part 1, records are included for 131 gaging stations of which 124 are streamflow discharge stations, 1 is stage only streamflow station, and 6 are reservoir or lake stations; also included are records for 12 low-flow partial-record stations, 38 crest-stage partial-record stations and 13 miscellaneous sites. Locations of gaging stations are shown in Figure 1, and location of partial-record stations are shown in Figure 2. In Part 2, data on the quality of surface water (chemical, temperature, and sediment) were collected from designated sampling sites at predetermined intervals, such as once daily, weekly, monthly, or less frequently, and at some sites data were recorded on punched paper tape at 15-, 30-, or 60-minute intervals. Records are given for 42 sampling stations of which 30 are continuous record stations, and 12 are partial-record stations. Locations of water-quality stations are shown in Figure 1. A few pertinent stations (not included above) in bordering States are also included in this report. In Part 3, records are included for 37 observation wells of which 8 are equipped with water-level recorders that give a continuous graph of the fluctuations, 3 are equipped with digital recorders that punch the water level on a tape at hourly intervals, at 26 manual reading are made with a steel tape by observers on the days indicated. Locations of index wells are shown in Figure 2. The records were collected and computed by the Water Resources Division of the U.S. Geological Survey under the direction of Edwin E. Harris, district chief. These data represent that portion of the National Water Data System collected by the U.S. Geological Survey and cooperating State and Federal agencies in West Virginia. Beginning with the 1961 water year, streamflow records and related data have been released by the Geological Survey in annual reports on a State-boundary basis. Water-quality records beginning with the 1964 water year have been similarly released either in separate reports or in conjunction with streamflow records. These reports are for limited distribution and are designed primarily for rapid release of data shortly after the end of the water year. Records of discharge and stage of streams, and contents and stage of lakes and reservoirs are published in a series of U.S. Geological Survey water-supply papers entitled, "Surface Water Supply of the United States." Through September 30, 1960, these water-supply papers were in an annual series and since then are in a 5-year series. Records of chemical quality, water temperatures, and suspended sediment have been published since 1941 in an annual series of water-supply papers entitled, "Quality of Surface Waters of the United States." More information is given under the headings "Publications" on page 24. Records of ground water levels are published in a series of water supply papers entitled, "Ground-water Levels in the United States". Through 1955 these were in an annual series but are now in a 5-year series. More information is given under the heading "Publications" on page 25.

West Virginia↗

Water quality of storm runoff and comparison of procedures for estimating storm-runoff loads, volume, event-mean concentrations, and the mean load for a storm for selected properties and constituents for Colorado Springs, southeastern Colorado, 1992

The U.S. Environmental Protection Agency requires that municipalities that have a population of 100,000 or greater obtain National Pollutant Discharge Elimination System permits to characterize the quality of their storm runoff. In 1992, the U.S. Geological Survey, in cooperation with the Colorado Springs City Engineering Division, began a study to characterize the water quality of storm runoff and to evaluate procedures for the estimation of storm-runoff loads, volume and event-mean concentrations for selected properties and constituents. Precipitation, streamflow, and water-quality data were collected during 1992 at five sites in Colorado Springs. Thirty-five samples were collected, seven at each of the five sites. At each site, three samples were collected for permitting purposes; two of the samples were collected during rainfall runoff, and one sample was collected during snowmelt runoff. Four additional samples were collected at each site to obtain a large enough sample size to estimate storm-runoff loads, volume, and event-mean concentrations for selected properties and constituents using linear-regression procedures developed using data from the Nationwide Urban Runoff Program (NURP). Storm-water samples were analyzed for as many as 186 properties and constituents. The constituents measured include total-recoverable metals, vola-tile-organic compounds, acid-base/neutral organic compounds, and pesticides. Storm runoff sampled had large concentrations of chemical oxygen demand and 5-day biochemical oxygen demand. Chemical oxygen demand ranged from 100 to 830 milligrams per liter, and 5.-day biochemical oxygen demand ranged from 14 to 260 milligrams per liter. Total-organic carbon concentrations ranged from 18 to 240 milligrams per liter. The total-recoverable metals lead and zinc had the largest concentrations of the total-recoverable metals analyzed. Concentrations of lead ranged from 23 to 350 micrograms per liter, and concentrations of zinc ranged from 110 to 1,400 micrograms per liter. The data for 30 storms representing rainfall runoff from 5 drainage basins were used to develop single-storm local-regression models. The response variables, storm-runoff loads, volume, and event-mean concentrations were modeled using explanatory variables for climatic, physical, and land-use characteristics. The r2 for models that use ordinary least-squares regression ranged from 0.57 to 0.86 for storm-runoff loads and volume and from 0.25 to 0.63 for storm-runoff event-mean concentrations. Except for cadmium, standard errors of estimate ranged from 43 to 115 percent for storm- runoff loads and volume and from 35 to 66 percent for storm-runoff event-mean concentrations. Eleven of the 30 concentrations collected during rainfall runoff for total-recoverable cadmium were censored (less than) concentrations. Ordinary least-squares regression should not be used with censored data; however, censored data can be included with uncensored data using tobit regression. Standard errors of estimate for storm-runoff load and event-mean concentration for total-recoverable cadmium, computed using tobit regression, are 247 and 171 percent. Estimates from single-storm regional-regression models, developed from the Nationwide Urban Runoff Program data base, were compared with observed storm-runoff loads, volume, and event-mean concentrations determined from samples collected in the study area. Single-storm regional-regression models tended to overestimate storm-runoff loads, volume, and event-mean con-centrations. Therefore, single-storm local- and regional-regression models were combined using model-adjustment procedures to take advantage of the strengths of both models while minimizing the deficiencies of each model. Procedures were used to develop single-stormregression equations that were adjusted using local data and estimates from single-storm regional-regression equations. Single-storm regression models developed using model- adjustment proce

Colorado↗