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Results for “Clays and Clay Minerals”

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At least 55 records · Page 3Linked to original sources
USGS1999

Adsorption of bacteriophages on clay minerals

The ability to predict the fate of microorganisms in soil is dependent on an understanding of the process of their sorption on soil and subsurface materials. Presently, we have focused on studying the thermodynamics of sorption of bacteriophages (T-2, MS-2, and φX-174) on clays (hectorite, saponite, kaolinite, and clay fraction of samples collected from a landfill site). The thermodynamic study not only determines the feasibility of the process but also provides information on the relative magnitudes of the different forces under a particular set of conditions. The total free energy of interaction during sorption of bacteriophages on clays (Δ G ) has been assumed to be the summation of Δ G H (Δ G due to hydrophobic interactions) and Δ G EL (Δ G due to electrostatic interactions). The magnitude of Δ G H was determined from the different interfacial tensions (γ) present in the system, while Δ G EL was calculated from ζ-potentials of the colloidal particles. Calculated results show that surface hydrophobicities of the selected sorbents and sorbates dictate sorption. Among the selected bacteriophages, maximum sorption was observed with T-2, while hectorite has the maximum sorption capacity. Experimental results obtained from the batch adsorption studies also corroborated those obtained from the theoretical study.

Environmental Science & Technology↗
USGS1953

Geochemical studies of clay minerals III. The determination of free silica and free alumina in montmorillonites

Determination of free silica by the method proposed made possible the derivation of logical formulas for several specimens of montmorillonites for which the formulas could not be derived from the analyses alone. Other montmorillonites, for which logical formulas could be derived from their analyses, were found to contain small amounts of free silica or free alumina. Others were found to contain neither free silica nor free alumina. The method consists of the following steps: (1) digestion of 1 g of the specimen with 0.5 N NaOH solution in a covered platinum crucible or dish on a steam bath for 4 hrs, stirring the mixture at 30-min intervals, (2) filtration of the undissolved material, followed by washing several times with 1% NaOH solution, (3) neutralization of the filtrate with HCl, addition of 5 ml HCl in excess and determination of SiO and Al 2 O 3 in the usual way and (4) calculation of the amount of free SiO 2 or free Al 2 O 3 if any and the amount of attack of the clay structure by the treatment from the ratio of SiO 2 to Al 2 O 3 dissolved and the ratio of SiO 2 to Al 2 O 3 obtained on analysis. Tests with 5% Na 2 CO 3 solution, the reagent formerly used for the solution of free SiO 2 in rocks and minerals, showed that solution of opal by this reagent is always fractional, never complete, no matter how small the amount present or how long the period of treatment. Re-treatment of the sample results in 90–95% solution if 10 mg or less of opal is present, but for larger amounts of opal the percentage dissolved decreases as the amount present increases. On the other hand, 75 ml of 0.5 N NaOH completely dissolves as much as 400 mg of opal in 4 hrs digestion in a covered platinum crucible or dish, on a steam bath. However, a weaker solution or a shorter period of digestion does not effect complete solution. The same amount (75 ml) of 0.5 N NaOH also dissolves 90 mg of cristobalite and 57 mg of quartz having a grain size of less than 2 microns. Use of NaOH also permits determination of the amount of alumina dissolved, and estimation of the extent to which the clay structure was attacked by the treatment.

Geochimica et Cosmochimica Acta↗
USGS1989

Relationship of clay-mineral diagenesis to temperature, age, and hydrocarbon generation–an example from the Anadarko Basin, Oklahoma

Randomly interstratified illite/smectite (I/S) is present in Springeran and Morrowan rocks (Late Mississippian and Early Pennsylvanian) of the Anadarko basin, Oklahoma, at present-day depths <2,750 m, but disappears at depths of 2,750-3,050 m. Only ordered I/S is found in samples below 3,050 m. The work reported here relates the diagenesis of I/S to burial history and oil generation in the Anadarko basin and tests the dependence of the smectite-to-illite reaction on temperature and time. Published temperature models of clay diagenesis suggest that, for Tertiary and Cretaceous rocks, the transition from randomly interstratified I/S to ordered I/S occurs at 100-110°C. Burial reconstructions for the Anadarko basin indicate that maximum temperatures of 100-110°C correspond to present-day burial depths between 2,700 and 3,100 m. These independently calculated depths for the 100-110°C isotherm match the depths at which randomly interstratified I/S is observed to disappear in Morrowan-Springeran rocks. Thus, random I/S disappears at the same temperature in rocks that differ in age by some 300 m.y. Although the extent of the smectite-to-illite reaction is controlled by kinetics, and effects of time are apparent in laboratory experiments and short-lived geologic systems, the results of this study suggest that time plays a secondary role in long-term diagenetic settings.

Oklahoma↗
USGS1959

Leaching of clay minerals in a limestone environment

Water saturated with CO 2 at about 25°C was percolated through mixed beds of limestone or marble fragments and montmorillonite, “illite” and kaolinite in polyethylene tubes for six and fortyfive complete runs. The leachates were analysed for SiO 2 , A1 2 O 3 and Fe 2 O 3 , but only SiO 2 was found. The minerals lost SiO 2 in this order: montmorillonite > kaolinite > “illite”. The differential removal of SiO 2 during the short period of these experiments suggests a mechanism for the accumulation of bauxite deposits associated with limestones.

Geochimica et Cosmochimica Acta↗
USGS2021

Brine-driven destruction of clay minerals in Gale crater, Mars

Mars’ sedimentary rock record preserves information on geological (and potential astrobiological) processes that occurred on the planet billions of years ago. The Curiosity rover is exploring the lower reaches of Mount Sharp, in Gale crater on Mars. A traverse from Vera Rubin ridge to Glen Torridon has allowed Curiosity to examine a lateral transect of rock strata laid down in a martian lake ~3.5 billion years ago. We report spatial differences in the mineralogy of time-equivalent sedimentary rocks <400 meters apart. These differences indicate localized infiltration of silica-poor brines, generated during deposition of overlying magnesium sulfate–bearing strata. We propose that destabilization of silicate minerals driven by silica-poor brines (rarely observed on Earth) was widespread on ancient Mars, because sulfate deposits are globally distributed.

Science↗
USGS1987

Diagenesis and fluid flow in the San Juan Basin, New Mexico - regional zonation in the mineralogy and stable isotope composition of clay minerals in sandstone.

The Westwater Canyon Member of the Upper Jurassic Morrison Formation is a relatively homogeneous, hydrologically continuous 100-m-thick sequence of massive fluvial sandstone, bounded above and below by relatively heterogeneous, hydrologically discontinuous units and has served as a primary conduit for fluids within this stratigraphic interval. Patterns of mineral-fluid reactions suggest a basinwide hydrologic regime in which warm, evolved fluids migrated up-dip from the center of the basin under the influence of a regional hydraulic head. -from Authors

American Journal of Science↗