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39 records · Page 3Linked to original sources
USGS2009

Hydrochemical analysis of groundwater using multivariate statistical methods - The Volta region, Ghana

Q and R-mode multivariate statistical analyses were applied to groundwater chemical data from boreholes and wells in the northern section of the Volta region Ghana. The objective was to determine the processes that affect the hydrochemistry and the variation of these processes in space among the three main geological terrains: the Buem formation, Voltaian System and the Togo series that underlie the area. The analyses revealed three zones in the groundwater flow system: recharge, intermediate and discharge regions. All three zones are clearly different with respect to all the major chemical parameters, with concentrations increasing from the perceived recharge areas through the intermediate regions to the discharge areas. R-mode HCA and factor analysis (using varimax rotation and Kaiser Criterion) were then applied to determine the significant sources of variation in the hydrochemistry. This study finds that groundwater hydrochemistry in the area is controlled by the weathering of silicate and carbonate minerals, as well as the chemistry of infiltrating precipitation. This study finds that the ??D and ?? 18 O data from the area fall along the Global Meteoric Water Line (GMWL). An equation of regression derived for the relationship between ??D and ?? 18 O bears very close semblance to the equation which describes the GMWL. On the basis of this, groundwater in the study area is probably meteoric and fresh. The apparently low salinities and sodicities of the groundwater seem to support this interpretation. The suitability of groundwater for domestic and irrigation purposes is related to its source, which determines its constitution. A plot of the sodium adsorption ratio (SAR) and salinity (EC) data on a semilog axis, suggests that groundwater serves good irrigation quality in the area. Sixty percent (60%), 20% and 20% of the 67 data points used in this study fall within the medium salinity - low sodicity (C2-S1), low salinity -low sodicity (C1-S1) and high salinity - low sodicity (C3-S1) fields, which ascribe good irrigation quality to groundwater from this area. Salinities range from 28.1 to 1956 ??S/cm, whilst SAR values fall within the range 0-3. Extremely low sodicity waters of this kind, with salinities lower than 600 ??S/cm, have the tendency to affect the dispersive properties of irrigation soils when used for irrigation. About 50% of the groundwater in the study area fall within this category and need prior treatment before usage. ?? 2009 Korean Society of Civil Engineers and Springer-Verlag Berlin Heidelberg GmbH.

KSCE Journal of Civil Engineering↗
USGS2004

Evaluation of multidimensional transport through a field-scale compacted soil liner

A field-scale compacted soil liner was constructed at the University of Illinois at Urbana-Champaign by the U.S. Environmental Protection Agency (USEPA) and Illinois State Geological Survey in 1988 to investigate chemical transport rates through low permeability compacted clay liners (CCLs). Four tracers (bromide and three benzoic acid tracers) were each added to one of four large ring infiltrometers (LRIs) while tritium was added to the pond water (excluding the infiltrometers). Results from the long-term transport of Br - "> Br - from the localized source zone of LRI are presented in this paper. Core samples were taken radially outward from the center of the Br - "> Br - LRI and concentration depth profiles were obtained. Transport properties were evaluated using an axially symmetric transport model. Results indicate that (1) transport was diffusion controlled; (2) transport due to advection was negligible and well within the regulatory limits of k sat ⩽ 1 × 10 - 7 cm / s ; "> k sat ⩽ 1 × 10 − 7 cm / s; (3) diffusion rates in the horizontal and vertical directions were the same; and (4) small positioning errors due to compression during soil sampling did not affect the best fit advection and diffusion values. The best-fit diffusion coefficient for bromide was equal to the molecular diffusion coefficient multiplied by a tortuosity factor of 0.27, which is within 8% of the tortuosity factor (0.25) found in a related study where tritium transport through the same liner was evaluated. This suggests that the governing mechanisms for the transport of tritium and bromide through the CCL were similar. These results are significant because they address transport through a composite liner from a localized source zone which occurs when defects or punctures in the geomembrane of a composite system are present.

Journal of Geotechnical and Geoenvironmental Engin↗
USGS2021

Advances in the use of lampricides to control sea lampreys in the Laurentian Great Lakes, 2000–2019

The periodic application of chemical lampricides that selectively kill larval sea lampreys ( Petromyzon marinus ) in their nursery habitats remains a primary component of the Great Lakes Fishery Commission’s (GLFC) Sea Lamprey Control Program in the Laurentian Great Lakes. Lampricides include 3-trifluoromethyl-4-nitrophenol (TFM) and niclosamide, the 2-aminoethanol salt of 2′, 5-dichloro-4′-nitrosalicylanilide, which may be used as an additive to TFM during stream treatments, or alone in a granular, bottom-release formulation to target sea lamprey larvae in deepwater environments where dilution would render TFM ineffective. During the early 1990s, the GLFC identified lampricide reduction targets in response to societal concerns with pesticide use, rising lampricide costs, and promising research into alternative controls. By 1999, the GLFC’s control agents, Fisheries and Oceans Canada (DFO) and the U.S. Fish and Wildlife Service (USFWS), had reduced TFM use by 36%. However, without effective alternative methods to compensate for increasing larval and juvenile production, sea lamprey abundance and lake trout ( Salvelinus namaycush ) marking rates rose throughout the Great Lakes. Beginning in the early 2000s, the GLFC and its control agents responded to burgeoning sea lamprey populations by implementing measures to advance the use of lampricides, which included: 1) assessing and controlling sea lamprey larvae that survived treatment; 2) enhancing treatment efficacy; 3) developing new technology to effectively treat larval populations that inhabit deepwater environments; 4) increasing operational capacity to treat more tributaries and lentic areas at shorter intervals; and, 5) conducting large-scale and targeted treatment strategies. When comparing lampricide use between the decades of 1990–1999 and 2010–2019, significant increases occurred in the mean number of treatments and amounts of TFM and niclosamide applied annually. Concurrent with these actions, researchers undertook studies to identify factors that erode lampricide treatment efficiency, elucidate physiological mode of action, and investigate lethal and sub-lethal impacts of lampricide exposure on aquatic organisms. By integrating new operational tactics and strategies with advances in science and technology, the GLFC, DFO, and USFWS, with support from the U.S. Geological Survey and the U.S. Army Corps of Engineers, have achieved unprecedented suppression of sea lampreys and reduction in lake trout marking in the Great Lakes. However, emerging challenges potentially threaten the future use of lampricides.

Journal of Great Lakes Research↗